Abstract: A method for forming a high capacitance charge storage structure that can be applied to a substrate wafer having MOS transistor already formed thereon. The method is to form an insulating layer above the substrate wafer. Next, a contact window exposing a source/drain region is formed in the insulating layer. Then, a tungsten suicide layer, which functions as a lower electrode for the charge storage structure, is formed over the substrate. Thereafter, a tungsten nitride layer is formed over the tungsten silicide layer, and then a dielectric layer is formed over the tungsten nitride layer. The dielectric layer is preferably a tantalum oxide layer. Finally, a titanium nitride layer, which functions as an upper electrode for the charge storage structure, is formed over the tantalum oxide layer.

Abstract: The present invention relates to a method of manufacturing semiconductor components having a titanium nitride layer including the steps of providing a semiconductor substrate with a transistor including a gate and source/drain regions, depositing an insulating layer above the semiconductor substrate, etching the insulating layer to form an opening exposing the source/drain region below, depositing an ultra-thin titanium nitride layer having a grainy particulate profile and a thickness of about 0.5 nm to 2 nm around the edge and at the bottom of the opening, depositing a metallic layer over various aforementioned layers, and forming a metal silicide layer by heating the semiconductor substrate to allow the metallic layer to react with silicon on the semiconductor substrate surface.