Fully Silicided Gate Electrodes and Method of Making the Same
The present invention relates to a method of selectively fabricating metal gate electrodes in one or more device regions by fully siliciding (FUSI) the gate electrode. The selective formation of FUSI enables metal gate electrodes to be fabricated on devices that are compatible with workfunctions that are different from conventional n+ and p+ doped poly silicon electrodes. Each device region consists of at least one Field Effect Transistor (FET) device which consists of either a polysilicon gate electrode or a fully silicided (FUSI) gate electrode. A gate electrode comprised of silicon and a Ge containing layer is used in combination with a selective removal process of the Ge containing layer. The Ge containing layer is not removed on devices with threshold voltages that are not compatible with the FUSI workfunction. Devices that are compatible with the FUSI workfunction have the Ge containing layer removed prior to the junction silicidation step. The remaining thin silicon layer of the gate electrode becomes fully silicided during the same step as the junction silicidation step.
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The present invention relates to manufacture of semiconductor devices. In particular, it relates to method of making fully silicided gate electrodes for field-effect-transistors.
BACKGROUND OF THE INVENTIONIt is well known in the art that polysilicon may be used as gate electrode in semiconductor devices such as, for example, field-effect-transistors (FETs) and in particular complementary metal-oxide-semiconductor field-effect-transistors (CMOS-FETs). On the other hand, with the continuing scaling down in dimensions of semiconductor devices, other types of gate electrodes such as, for example, metal and/or fully silicided (FUSI) gate electrodes are being used to replace the conventional polysilicon gate electrodes. Metal and/or FUSI gate electrodes may reduce and/or prevent depletion of charges, commonly known as poly-depletion, associated with polysilicon gate electrode. Occurring in the vicinity of an interface between a polysilicon gate electrode and a gate dielectric, poly-depletion may lead to less induced charges in the channel region of a FET device causing lower current and degraded performance. Compared with using polysilicon gate electrodes, the use of metal and/or FUSI gate electrodes may reduce an effective thickness of the gate dielectric, and thus increase the capacitance associated with the gate, or gate capacitance. The increase in gate capacitance effectively increases the amount of induced charges in the channel region of the FET device, which translates to higher drive currents and transistor performance.
On the other hand, there are situations where it may be difficult to use metal gate electrodes in certain device areas having devices with multiple threshold voltages. Metal gate and/or FUSI gate electrodes tend to have workfunctions near the mid-gap of silicon. Workfunctions near the mid-gap of silicon lead to higher than desirable threshold voltages. The standard way to reduce threshold voltage is to decrease the channel doping of the device; however, this leads to degraded short channel control. The net result is that metal gate electrodes with workfunctions near the mid-gap of silicon do not have a device design point for FETs with a low threshold voltage.
It is also known in the art that when FUSI is performed on a highly doped n+ polysilicon of a FET gate (nFET), the resultant FUSI gate electrode may have a workfunction value that is operational. However, performing FUSI on a FET gate with highly doped p+ polysilicon (pFET) may not necessarily create a workfunction value that is compatible or desirable for the intended devices.
For instance, with some state of the art FET devices, the magnitude of threshold voltages with highly doped n+ polysilicon electrodes may range from, for example, 0.15V-0.55 V depending upon the type of technology used. A threshold voltage is known to determine when a CMOS-FET turns on and/or off. Lower magnitudes of threshold voltage may create a FET with higher current and high power consumption while higher magnitudes of threshold voltage may result in a FET with lower current and lower power consumption. For example, magnitude of threshold voltage for a high performance device may be as low as 0.15V while for low power devices the threshold voltage may be as high as 0.55V. In general, multiple-threshold voltages are needed in semiconductor technology to provide flexibility in design for low-power, high-performance, and mixed-signal applications.
Applying FUSI using known methods may increase the magnitude of threshold voltage by around 250 mV to 500 mV due to changes in the workfunction of the gate electrode. This increase in threshold is often not desirable for FET devices that require low magnitudes of threshold voltage to achieve high performance. It is possible to apply FUSI to a FET device while maintaining a desired magnitude of threshold voltage by, for example, decreasing a doping concentration in a channel region of the substrate. This is because decreasing the channel doping may decrease the magnitude of the threshold voltage, countering the increase due to the application of FUSI. Nevertheless, decreasing the channel doping to a critical level may create a FET that does not function properly. If the substrate doping is too low then the source/drain regions may form a short circuit that may no longer be controllable by the gate electrode. This could lead to a FET that cannot be turned off and thus becomes useless. Specifically, FETs with already low magnitudes of threshold voltages (0.15V-0.25V) are not compatible with current state of the art FUSI. Using FUSI gate electrodes on these devices would result in FETs that cannot be turned off due to the reduction of substrate doping required in order to achieve the desired low magnitude of threshold voltage. However, FETs that have threshold voltages in the 0.3V-0.55V range are compatible with FUSI gate electrodes because the substrate doping is relatively high for these FETs when polysilicon gate electrodes are used. Using FUSI gate electrodes on FETs with threshold voltages in the range of 0.3V-0.55V may be achieved by decreasing the substrate doping to account for the 250 mV-500 mV increase caused by the change in FUSI gate electrode workfunction.
The present invention will be understood and appreciated more fully from the following detailed description of the invention, taken in conjunction with the accompanying drawings of which:
It will be appreciated that for simplicity and clarity of illustration, elements shown in the drawings have not necessarily been drawn to scale. For example, the dimensions of some of the elements may be exaggerated relative to other elements for clarity.
SUMMARY OF THE INVENTIONThere is a need to form fully silicided gate electrodes selectively on a semiconductor device. The present invention provides a method of forming fully silicided (FUSI) gate electrodes in selected device regions of an integrated circuit. For example, the present invention may enable FUSI gate electrodes be selectively formed on FET gate devices that require threshold voltages of a workfunction in 0.3V-0.5V range, where FUSI induced increase in threshold voltage may be accommodated by reduction in doping density of the substrate, while avoiding formation of FUSI gate electrode in other devices where FUSI is not desirable due to, for example, already low threshold voltage. In addition, the present invention forms FUSI gate electrodes during a source/drain silicidation process. The use of FUSI gate electrode may possibly reduce or eliminate the gate depletion and therefore increases the current drive of transistors.
One embodiment of the invention provides a method for selectively forming fully silicided (FUSI) gate electrode on gate dielectric. The method includes forming first and second sets of gate devices on a substrate; covering one or more of the first set of gate devices with a protective masking layer; removing selectively a Ge-containing silicon layer in a gate stack of one or more of the second set of gate devices to expose a silicon layer formed directly on top of a gate dielectric layer; removing the protective masking layer on the one or more first set of gate devices; covering the first and second sets of gate devices, including the exposed silicon layer, with a metal-containing layer; and annealing the first and second sets of gate devices to form selectively FUSI gate electrode directly on top of the gate dielectric layer of the one or more second set of gate devices.
According to one embodiment, the annealing includes subjecting the first and second sets of gate devices to a high temperature environment of about 400° C. to about 900° C., preferably from about 420° C. to about 700° C., a gas ambient including He, Ar, or N2, and to a process of rapid thermal annealing, spike annealing, or laser annealing in a time period from about 1 second to about 120 seconds. The silicon layer forming the FUSI gate electrode has a thickness in the range from about 10 nm to about 50 nm, and preferably between about 15 nm and about 30 nm.
According to another embodiment, the annealing also includes siliciding the source/drain regions of the first and second sets of gate devices, and at most a portion of a Ge-containing silicon layer in a gate stack of the one or more first set of gate devices.
Another embodiment of the invention provides a method for forming (FUSI) gate electrode for one or more n-type FETs (field-effect-transistors) on a semiconductor substrate, the semiconductor substrate includes one or more p-type FETs. The method includes covering the one or more p-type FETs with a protective masking layer; removing a Ge-containing silicon layer in a gate stack of the one or more n-type FETs to expose a silicon layer formed directly on top of a gate dielectric layer of the one or more n-type FETs; removing the protective masking layer on the one or more p-type FETs; covering the one or more p-type and n-type FETs, including the exposed silicon layer of the one or more n-type FETs, with a metal-containing layer; and annealing the one or more p-type and n-type FETs to form selectively the FUSI gate electrode directly on top of the gate dielectric layer of the one or more n-type FETs.
Yet, another embodiment of the invention provides a semiconductor device that includes one or more p-type field-effect-transistors (FETs) and one or more n-type FETs, wherein at least one of the n-type FETs includes a fully silicided (FUSI) gate electrode formed directly on top of a gate dielectric, the FUSI gate electrode having a thickness in the range between about 10 nm and about 50 nm, and wherein the one or more p-type FETs includes at most partially silicided gate electrode.
DETAILED DESCRIPTION OF THE INVENTIONIn the following detailed description, numerous specific details are set forth, such as particular structures, components, materials, dimensions, processing steps and/or techniques, in order to provide a thorough understanding of the present invention. However, it will be appreciated by a person of ordinary skill in the art that the present invention may be practiced without these specific details. In other instances, well-known structures and/or processing steps may not have been described in detail in order to avoid obscuring the description of the invention.
The present invention provides a method of forming fully silicided (FUSI) gate electrodes in selected device regions of an integrated circuit. For example, the present invention may enable FUSI gate electrodes be selectively formed on FET gate devices that require threshold voltages in the 0.3V-0.5V range, where FUSI induced increase in threshold voltage may be accommodated by reduction in doping density of the substrate, while avoiding formation of FUSI gate electrode in other devices where FUSI is not desirable due to, for example, much lower threshold voltage. In addition, the present invention forms FUSI gate electrodes during a source/drain silicidation process. The use of FUSI gate electrode may possibly reduce or eliminate gate depletion and thus increases the drive current of transistors such as field-effect-transistors (FETs).
According to one embodiment of the invention, full silicidation (FUSI) of gate electrodes may be performed or conducted selectively on certain types of devices. For example, FUSI may be performed on an nFET device, which is to be formed in device region 112, but not on a pFET device, which is to be formed in device region 111, as described below in detail with reference to
Materials of substrate 100 may include any types of semiconductors such as, for example, Si, SiGe, SiGeC, SiC, Ge alloys, GaAs, InAs, InP and other III/V or II/VI compound semiconductors. Substrate 100 may also include layered semiconductors such as, for example, Si/SiGe, Si/SiC, silicon-on-insulators (SOIs) or silicon germanium-on-insulators (SGOIs). Substrate 100 may be doped, undoped or contain both doped and undoped regions therein, and may be strained, unstrained or contain both strained and unstrained regions therein. Furthermore, substrate 100 may have a single crystal orientation or may be a hybrid semiconductor substrate having different crystal orientations.
According to one embodiment, device regions 111 and 112, for example, may be electrically isolated from each other by one or more field oxide isolation regions and/or shallow trench isolation (STI) regions formed within substrate 100. For example, STI regions 121, 122, and 123 may be formed or created to define device regions 111 and 112. The creation or formation of STI regions 121, 122, and 123 may be through well-known semiconductor processing technologies. For example, STI regions 121, 122, and 123 may be formed through a combination of steps of lithography and etching to first create trench openings in substrate 100, subsequently fill the openings with trench dielectric, for example oxide, through a chemical vapor deposition (CVD) process, and then planarize the surface of substrate 100 through for example a chemical mechanical planarization (CMP) process.
Gate dielectric 211 may be formed to have a thickness ranging from 1 to 3 nanometers (nm). Although a thickness of gate dielectric 211 around 1 nm is typical and/or more preferred, the invention is not limited in this respect and other thickness may be used. Materials of gate dielectric 211 may include, for example, silicon dioxide SiO2, silicon oxynitride SiON, HfO2, HfSiON and other materials that may be suitable for the gate as they are known in the art.
According to one embodiment, a thin layer of silicon 212 may be subsequently formed directly on top of gate dielectric layer 211. The formation of silicon layer 212 may be through, for example, CVD or other well-known and suitable semiconductor processes. According to one embodiment, silicon layer 212 may be deposited to have a thickness ranging from 10 nm to 50 nm and a range of 15 nm to 30 nm is generally preferred. Other thickness of silicon layer 212 may be used as well.
The etching may typically be performed utilizing a dry etching process such as a reactive-ion-etching (RIE), ion beam etching, or plasma etching, to name a few. However, the invention is not limited in this respect and other etching processes and/or methods such as a chemical wet etching process may be used. After forming gate stacks 421 and 422, spacers, such as spacers 431, 432, 433 and 434, may be formed on exposed sidewalls of the patterned gate stacks through processes such as a CVD deposition process followed by an etching process. Material of spacers 431, 432, 433 and 434 may include, for example, oxide, nitride, oxynitride, and/or any combination thereof. The width of spacers 431, 432, 433 and 434 may be formed sufficiently wide so as to prevent silicided contacts, to be formed subsequently on the source/drain regions of gate devices 411 and 412, from encroaching underneath the edge of the patterned gate stacks. For example, spacers 431 and 432 may be formed around gate stack 421 to provide isolation between the gate electrode (to be formed later) of gate stack 421 and source/drain regions next to spacers 431 and 432 in device region 111. The same is true for spacers 433 and 434 formed around gate stack 422.
Following the formation of gate stacks 421 and 422 and surrounding spacers 431, 432, 433 and 434, source/drain diffusion regions, for example diffusion regions 441, 442, 443 and 444, may be formed through an ion implantation process. Gate stacks 421 and 422, together with surrounding spacers 431, 432, 433 and 434, may serve as implantation masks in the formation of source/drain diffusion regions 441, 442, 443 and 444. The ion implantation process may be followed immediately by an annealing process although the annealing process may be preferably performed at a later stage, after the removal of Ge-containing layer 311b of gate stack 422 as described below in detail, in order to avoid, eliminate, and/or minimize possible Ge diffusion into silicon layer 212b. The annealing step serves to activate the dopants that are implanted during the ion implantation step. Temperature conditions for ion implantation and annealing are well known to those skilled in the art and generally range from 900° C. to 1300° C. depending on the annealing tool and technologies used. Annealing temperatures in the 1000° C.-1100° C. for less than one (1) second are generally preferred.
After removing Ge-containing silicon layer 311b at the top of gate stack 422, substrate 100 may undergo an annealing process, if having not been thermally processed as described above with reference to
After removing Ge-containing layer 311b and activating ions implanted in source/drain regions 441, 442, 443 and 444 through the annealing process, protective masking layer 511 may be selectively removed or lifted through, for example, a wet etching process although other removal processes may be used as well.
In one embodiment, metal-containing layer 711 used in forming a metal silicide may include at least one alloying additive in an amount of up to 50 atomic weight percent. The alloying additive, when present, may be formed at the same time as that of the metal-containing layer 711, or it may be introduced into an as-deposited metal-containing layer utilizing some well-known techniques such as, for example, ion implantation or gas phase doping. Examples of alloying additives may include C, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Ge, Y, Zr, Nb, Mo, Ru, Rh, Pd, In, Sn, La, Hf, Ta, W, Re, Ir, Pt, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Er and mixtures thereof. A person skilled in the art may appreciate that the above may not be an exclusive list of all the alloying additives and other additives may be used.
Following FUSI on gate stack 422 of gate device 412, metal or metal-containing layer 711 may be removed by applying selective etching as is known in the art. The underlying gate devices or structures 411 and 412, with partially silicided gate stack 421 and fully silicidated gate stack 422 with FUSI electrode 812, and silicided source/drain regions 821, 822, 823, and 824 are then exposed. FUSI electrode 812 has a low profile of less electrode area. The thinner FUSI electrode may reduce possible sidewall parasitic capacitance.
While certain features of the invention have been illustrated and described herein, many modifications, substitutions, changes, and equivalents will now occur to those of ordinary skill in the art. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes as fall within the spirit of the invention.
Claims
1-27. (canceled)
28. A semiconductor device comprising:
- one or more p-type field-effect-transistors (FETs); and
- one or more n-type FETs,
- wherein at least one of said n-type FETs comprises a gate dielectric and a fully silicided (FUSI) gate electrode formed directly on top of said gate dielectric, said FUSI gate electrode having a thickness in the range between about 10 nm and about 50 nm, and wherein said one or more p-type FETs comprises a gate electrode that is at most partially but not fully silicided.
29. The semiconductor device of claim 28, wherein said FUSI gate electrode comprises a metal element selected from the group consisting of Ni, Co, and Ti with Ni being preferable and said one or more n-type and p-type FETs comprises source and drain regions that are silicided with said metal element.
30. The semiconductor device of claim 28, wherein said FUSI gate electrode is formed directly on top of and in contact with said gate dielectrics said gate dielectric comprising one of silicon dioxide and silicon oxynitride, said gate dielectric having a thickness between about 1 nm and about 3 nm.
31. The semiconductor device of claim 28, wherein said one or more p-type FETs further comprises a gate dielectric, and said gate electrode of said one or more p-type FETs comprises a silicon layer formed directly on top of said gate dielectric of said one or more p-type FETs, said silicon layer being not silicided.
32. The semiconductor device of claim 28, wherein said FUSI gate electrode has a thickness between about 15 nm and about 30 nm.
33. A semiconductor device comprising:
- at least one of a first type of transistors; and
- at least one of a second type of transistors,
- wherein said one of the first type of transistors includes a fully silicided (FUSI) gate electrode and a gate dielectric, said FUSI gate electrode being formed directly on top of and in contact with said gate dielectric, said FUSI gate electrode having a thickness ranging from about 15 nm to about 30 nm, and wherein said one of the second type of transistors includes a gate electrode which has at least a part that is not silicided.
34. The semiconductor device of claim 33, wherein said first type of transistors is a n-type field-effect-transistor and said second type of transistors is a p-type field-effect-transistor.
35. The semiconductor device of claim 33, wherein said FUSI gate electrode comprises at least one metal element, said metal element being selected from the group consisting of Ni, Co, and Ti with Ni being preferable and said transistors of said first and second types comprise source and drain regions silicided with said metal element.
36. The semiconductor device of claim 33, wherein said gate dielectric is selected from silicon dioxide (SiO2), silicon oxynitride (SiON), HfO2, or HfSiON.
37. The semiconductor device of claim 33, wherein said gate dielectric has a thickness between about 1 nm and about 3 nm.
38. The semiconductor device of claim 33, wherein said gate dielectric has a thickness of about 2 nm.
39. The semiconductor device of claim 33, wherein said part of gate electrode of said one of the second type of transistors, which is not silicided, comprises a silicon layer formed on top of a gate dielectric of said one of the second type of transistors.
40. A semiconductor device comprising:
- one n-type field-effect-transistor (FET) that comprises a gate dielectric and a fully silicided (FUSI) gate electrode formed directly on top of said gate dielectric; and
- one p-type FET that comprises a gate electrode which is at most partially but not fully silicided, said gate electrode comprising a non-silicided silicon layer,
- wherein said FUSI gate electrode having a thickness in the range between about 15 nm and about 30 nm; comprising a metal element selected from the group consisting of Ni, Co, and Ti with Ni being preferable, and
- wherein said gate dielectric one of silicon dioxide and silicon oxynitride, said gate dielectric having a thickness between about 1 nm and about 3 nm.
41. The semiconductor device of claim 40, wherein said n-type and p-type FETs comprises source and drain regions that are silicided with said metal element.
Type: Application
Filed: Jul 30, 2007
Publication Date: Jan 31, 2008
Applicant: International Business Machines Corporation (Armonk, NY)
Inventors: William K. Henson (Peekskill, NY), Kem Rim (Yorktown Heights, NY)
Application Number: 11/830,312
International Classification: H01L 29/78 (20060101);