INTEGRATED CIRCUIT HAVING MIM CAPACITOR WITH REFRACTORY METAL SILICIDED STRAP AND METHOD TO FABRICATE SAME
A method includes forming a trench in a Silicon substrate; depositing metal on sidewalls and a bottom of the trench; annealing to react the metal with underlying Si and form metal silicide adjacent to sidewalls and bottom of the trench; removing unreacted metal and depositing a dielectric layer on the metal silicide, a metal layer over the dielectric layer and polysilicon to fill a remainder of the trench thereby forming top plate electrode of a MIM capacitor. The method further forms a transistor adjacent to a top of the trench, where the transistor is connected to the top plate electrode of the MIM capacitor via a strap interface that comprises a portion of the metal silicide layer at the top of the trench. The portion of the metal silicide layer can be disposed in an SOI layer, and silicide in the Si substrate forms a bottom plate of the capacitor.
The various embodiments of this invention relate generally to semiconductor devices and fabrication techniques and, more specifically, relate to the fabrication of semiconductor transistor devices that are connected with metal-insulator-metal (MIM) trench capacitors for use in memory and other circuitry.
BACKGROUNDA MIM capacitor can be considered as a trench-type parasitic capacitor with an insulator layer disposed between two metal layers. A conventional connection (strap) interface between a deep trench (DT) MIM capacitor and an adjacent transistor, e.g., a planar field effect transistor (FET) or a FinFET, typically suffers from having a high resistance due at least to the area of the strap. The high interface resistance can detrimentally affect performance, such as when the DT MIM capacitor is used in a dynamic random access memory (DRAM) application such as an embedded DRAM (eDRAM) application.
SUMMARYIn a first aspect thereof the embodiments of this invention provide a method that comprises forming a trench in a Silicon substrate; depositing metal on sidewalls and a bottom of the trench; annealing the deposited metal to react the metal with underlying Si and form a layer of metal silicide adjacent to sidewalls and the bottom of the trench; removing unreacted deposited metal; depositing a dielectric layer on the layer of metal silicide, a metal layer over the dielectric layer and polysilicon to fill the remainder of the trench thereby forming a top plate electrode of a metal-insulator-metal (MIM) capacitor in the trench; and forming a transistor adjacent to a top of the trench, where the transistor is connected to the top plate electrode of the MIM capacitor via a strap interface that comprises a portion of the metal silicide layer at the top of the trench.
In a second aspect thereof the embodiments of this invention provide a method that comprises forming a deep trench in a semiconductor on insulator (SOI) structure through a layer of SOI, a BOX layer and into a Si substrate; depositing a metal on deep trench sidewalls and bottom; annealing to form silicide on SOI and substrate trench sidewalls and bottom by reacting the metal with Si of the layer of SOI and the substrate; removing unreacted metal; depositing a high-k dielectric layer on trench sidewalls and bottom; depositing a second metal on top of the high-k dielectric layer to form a MIM capacitor in the trench; and forming a transistor with one of its source or drain terminals electrically connected to the silicide on SOI sidewalls.
In another aspect thereof the embodiments of this invention provide a DRAM cell that comprises a structure comprising a Si substrate having an overlying oxide layer and a semiconductor on insulator (SOI) layer disposed on the oxide layer. The structure is comprised of a trench that extends through the SOI layer and through the oxide layer into the Si substrate. The structure is further comprised of a trench capacitor formed in the trench and a transistor formed in the SOI layer. In the DRAM cell a silicide on trench sidewalls in the SOI layer and in the underlying Si substrate simultaneously serves, in the Si substrate, as a bottom electrode of the trench capacitor, and in the SOI layer serves as an electrical connection between the transistor and the trench capacitor to reduce strap interface resistance.
The word “exemplary” is used herein to mean “serving as an example, instance, or illustration.” Any embodiment described herein as “exemplary” is not necessarily to be construed as preferred or advantageous over other embodiments. All of the embodiments described in this Detailed Description are exemplary embodiments provided to enable persons skilled in the art to make or use the invention and not to limit the scope of the invention which is defined by the claims.
The terms “epitaxial growth and/or deposition” and “epitaxially formed and/or grown” mean the growth of a semiconductor material on a deposition surface of a semiconductor material, in which the semiconductor material being grown has the same crystalline characteristics as the semiconductor material of the deposition surface. In an epitaxial deposition process, the chemical reactants provided by source gases are controlled and the system parameters are set so that the depositing atoms arrive at the deposition surface of the semiconductor substrate with sufficient energy to move around on the surface and orient themselves to the crystal arrangement of the atoms of the deposition surface. Therefore, an epitaxial semiconductor material has the same crystalline characteristics as the deposition surface on which it is formed. For example, an epitaxial semiconductor material deposited on a <100> crystal surface will take on a <100> orientation. In some embodiments, epitaxial growth and/or deposition processes are selective to forming on semiconductor surface, and do not deposit material on dielectric surfaces, such as silicon dioxide or silicon nitride surfaces.
Examples of various epitaxial growth process apparatuses and methods that are suitable for use in implementing the embodiments of this invention can include, but are not limited to, chemical vapor deposition (CVD) such as, for example, rapid thermal chemical vapor deposition (RTCVD), atmospheric pressure chemical vapor deposition (APCVD), low pressure chemical vapor deposition (LPCVD) and ultra-high vacuum chemical vapor deposition (UHVCVD). Other suitable epitaxial growth processes can include, but are not limited to, molecular beam epitaxy (MBE) and low-energy plasma deposition (LEPD). The temperature for an epitaxial deposition process typically ranges from about 300° C. to about 900° C. Although higher temperature will typically result in faster deposition of the semiconductor material, the faster deposition may also result in crystal defects and film cracking.
In at least one embodiment thereof this invention can employ semiconductor on insulator (SOI) technology where a thin semiconductor layer, such as a layer of SiGe or a layer of Si, is formed over an insulating layer, such as silicon oxide, which in turn is formed over a (bulk) substrate, such as a Si substrate. The insulating layer can be referred to as a buried oxide (BOX) layer or simply as a BOX. For a single BOX SOI wafer the SOI layer can be divided into active regions by shallow trench isolation (STI) which intersects the BOX and provides total isolation for active device regions formed in the SOI layer. For FinFET devices fin structures can be defined in the SOI layer and sources and drains can be formed, for example, by ion implantation of N-type or P-type dopants into the fins. A FET channel region between a source/drain pair can be created so as to underlie a gate structure.
In at least one conventional approach the strap interface between the FinFET and the DT MIM capacitor can be N+ SOI/nitride/N+ polysilicon (poly). For a case of a Fin height of approximately 35 nm and a Fin width of approximately 10 nm the strap interface contact area can be about 100 nm2-500 nm2 and the contact resistance can be about 10 k ohm/cell. As an example, with a contact area of 10 nm×35 nm, or about 350 nm2, the specific contact resistivity is 10K ohm×350 nm2=3×10−8 ohm cm2.
The exemplary embodiments of this invention significantly reduce the specific contact resistivity by instead using for the strap interface N+ SOI/metal silicide such as N-metal TiSi2/N+ poly. The TiSi2/N+ Si specific contact resistivity can be about 10−8 ohm cm2, so as a result 10−8 ohm cm2/(350×10−14 cm2)=3 k ohm per interface.
With the FIN-DT structure made possible by the use of the exemplary embodiments of this invention the strap area of the FIN connection to the DT poly can be reduced by as much as about 30 times. If one assumes that the connection in the conventional case between the FIN and a DT 14 nm SOI has an interface resistance of about 10K ohms/cell, by using silicide in the Fin/poly interface the total resistance can be reduced to only about 330 ohm/cell (two sides).
As will be described in detail below, the embodiments of the method of this invention employ chemical vapor deposition (CVD) or atomic layer deposition (ALD) of a metal, such as Nickel (Ni), Tungsten (W), Titanium (Ti), Cobalt (Co), Platinum (Pt) or Ruthenium (Ru), with high conformality into deep trenches at a temperature in a range of about 400° C. to about 600° C. so as to form a thin metal layer (e.g., about 5 nm to about 20 nm thick) on exposed Si. An anneal operation is performed to form self-aligned refractory silicide where the Si is exposed. The method then selectively etches away unreacted metal, leaving metal silicide on top of the Si, a bottom capacitor plate and a SOI sidewall. A high dielectric constant insulator layer is then deposited followed by a conductive layer, e.g., a metal layer comprised of TiN, followed by a polysilicon fill forming the MIM capacitor. A conventional eDRAM process flow can then be performed to form a transistor structure connected to the MIM capacitor via a metal silicide strap interface, without other major process changes being required.
As can be seen in
It is to be understood that the exemplary embodiments discussed above with reference to FIGS. 1-11 can be used with common variants of a FET device including, e.g., FET devices with multi-fingered FIN and/or gate structures and FET devices of varying gate width and length. Moreover, transistor devices can be connected to metalized pads or other devices by conventional ultra-large-scale integration (ULSI) metalization and lithographic techniques.
Integrated circuit dies can be fabricated with various devices such as a field-effect transistors, bipolar transistors, metal-oxide-semiconductor transistors, diodes, resistors, capacitors, inductors, etc. An integrated circuit in accordance with the present invention can be employed in applications, hardware, and/or electronic systems. Suitable hardware and systems in which such integrated circuits can be incorporated include, but are not limited to, personal computers, communication networks, electronic commerce systems, portable communications devices (e.g., cell phones), solid-state media storage devices, functional circuitry, etc. Systems and hardware incorporating such integrated circuits are considered part of this invention. Given the teachings of the invention provided herein, one of ordinary skill in the art will be able to contemplate other implementations and applications of the techniques of the invention.
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises” and/or “comprising,” when used in this specification, specify the presence of stated features, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components, and/or groups thereof.
The corresponding structures, materials, acts, and equivalents of all means or step plus function elements in the claims below are intended to include any structure, material, or act for performing the function in combination with other claimed elements as specifically claimed. The description of the present invention has been presented for purposes of illustration and description, but is not intended to be exhaustive or limited to the invention in the form disclosed. Many modifications and variations will be apparent to those of ordinary skill in the art without departing from the scope and spirit of the invention. The embodiment was chosen and described in order to best explain the principles of the invention and the practical application, and to enable others of ordinary skill in the art to understand the invention for various embodiments with various modifications as are suited to the particular use contemplated.
As such, various modifications and adaptations may become apparent to those skilled in the relevant arts in view of the foregoing description, when read in conjunction with the accompanying drawings and the appended claims. As but some examples, the use of other similar or equivalent semiconductor fabrication processes, including deposition processes and etching processes and etching chemistries may be used by those skilled in the art. Further, the exemplary embodiments are not intended to be limited to only those materials, metals, insulators, dopants, dopant concentrations, layer thicknesses, anneal temperatures and the like that were specifically disclosed above. Any and all such and similar modifications of the teachings of this invention will still fall within the scope of this invention.
Claims
1. A method comprising:
- forming a trench in a Silicon substrate;
- depositing metal on sidewalls and a bottom of the trench;
- annealing the deposited metal to react the metal with underlying Si and form a layer of metal silicide adjacent to sidewalls and the bottom of the trench;
- removing unreacted deposited metal;
- depositing a dielectric layer on the layer of metal silicide, where the layer of metal silicide functions as a bottom plate, a metal layer over the dielectric layer to form a top plate and electrically conductive polysilicon to fill the remainder of the trench thereby forming a top plate electrode of a metal-insulator-metal (MIM) capacitor in the trench; and
- after forming the top plate electrode of the MIM capacitor in the trench, forming a transistor adjacent to a top of the trench, where the transistor is formed so as to be connected to the top plate electrode of the MIM capacitor via a self-aligned strap interface that comprises a portion of the metal silicide layer that is disposed at the top of the trench.
2. The method of claim 1, where the Si substrate has an overlying oxide layer and a semiconductor on insulator (SOI) layer disposed on the oxide layer, where the trench extends through the SOI layer and through the oxide layer, and where the portion of the metal silicide layer at the top of the trench is located in the SOI layer.
3. The method of claim 1, where the dielectric layer is a high dielectric constant layer comprised of a metal oxide, and where the metal layer is comprised of Titanium Nitride (TiN).
4. The method of claim 1, where the metal deposited on sidewalls of the trench is comprised of one of Nickel (Ni), Tungsten (W), Titanium (Ti), Cobalt (Co), Platinum (Pt) or Ruthenium (Ru).
5. The method of claim 1, where the step of depositing metal on sidewalls of the trench comprises an initial step of enlarging a bottom portion of the trench to increase the surface area.
6. The method of claim 2, where the layer of metal silicide is present only in the SOI layer and in the Si substrate, where the step of depositing the dielectric layer on the layer of metal silicide, the metal layer over the dielectric layer and the polysilicon further comprises removing from a top portion of the trench down and into the oxide layer the deposited metal layer over the dielectric layer, the dielectric layer and the polysilicon.
7. The method of claim 6, further comprising depositing additional polysilicon into the top portion of the trench to comprise a top portion of the top plate electrode.
8. A method comprising:
- forming a deep trench in a semiconductor on insulator (SOI) structure through a layer of SOI, a BOX layer and into a Si substrate;
- depositing a metal on deep trench sidewalls and bottom;
- annealing to form silicide on SOI and substrate trench sidewalls and bottom by reacting the metal with Si of the layer of SOI and the substrate;
- removing unreacted metal;
- depositing a high-k dielectric layer on trench sidewalls and bottom;
- depositing a second metal on top of the high-k dielectric layer and electrically conductive polysilicon to cover the second metal to form a MIM capacitor in the trench; and
- after forming the MIM capacitor in the trench, forming a transistor in the layer of SOI with one of its source or drain terminals electrically connected to the silicide on SOI sidewalls, where the silicide on the SOI sidewalls functions as a self-aligned silicide strap to electrically couple one of the transistor source or drain terminals to the second metal via the electrically conductive polysilicon, where the second metal functions as a top plate of the MIM capacitor and where the silicide disposed on the substrate trench sidewalls and bottom functions as a bottom plate of the MIM capacitor.
9. The method of claim 8, where the high-k dielectric layer is comprised of a metal oxide, and where the second metal is comprised of Titanium Nitride (TiN).
10. The method of claim 8, where the metal deposited on deep trench sidewalls and bottom is comprised of one of Nickel (Ni), Tungsten (W), Titanium (Ti), Cobalt (Co), Platinum (Pt) or Ruthenium (Ru).
11. The method of claim 8, where the step of depositing a metal on deep trench sidewalls and bottom comprises an initial step of enlarging a bottom portion of the trench to increase the surface area.
12. The method of claim 8, where the steps of depositing the high-k dielectric layer and the second metal layer on the high-k dielectric layer further comprises depositing first polysilicon to fill a remainder of the trench, and the method further comprises removing from a top portion of the trench down and into the BOX layer the deposited second metal layer, the dielectric layer and the first polysilicon.
13. The method of claim 12, further comprising depositing additional polysilicon into the top portion of the trench to comprise a top portion of a top plate electrode.
14. A DRAM cell comprising:
- a structure comprising a Si substrate having an overlying oxide layer and a semiconductor on insulator (SOI) layer disposed on the oxide layer, the structure comprised of a trench that extends through the SOI layer and through the oxide layer into the Si substrate;
- a trench capacitor formed in the trench; and
- a transistor formed in the SOI layer, where a silicide layer on trench sidewalls in the SOI layer and in the underlying Si substrate simultaneously serves, in the Si substrate, as a bottom plate of the trench capacitor, and in the SOI layer serves as a self-aligned electrical silicide strap connection between the transistor and the trench capacitor to reduce strap interface resistance;
- where the trench capacitor is a MIM capacitor comprised of the bottom plate that comprises the silicide in the Si substrate, a dielectric insulator layer disposed over the silicide, and a top plate that comprises a metal layer disposed over the dielectric insulator layer; and
- where a remainder of the trench is filled with electrically conductive polysilicon that comprises a top plate electrode of the MIM capacitor, whereby the transistor is electrically coupled by the self-aligned silicide strap to the top plate of the MIM capacitor via the top plate electrode comprised of the electrically conductive polysilicon.
15-16. (canceled)
17. The DRAM cell of claim 14, where the metal layer disposed over the high-k dielectric layer is comprised of Titanium Nitride (TiN).
18. The DRAM cell of claim 14, where the silicide is one of a Nickel (Ni), Tungsten (W), Titanium (Ti), Cobalt (Co), Platinum (Pt) or Ruthenium (Ru) silicide.
19. The DRAM cell of claim 14, where the Si substrate is doped so as to be electrically conductive and further comprising a bottom plate electrode that extends through the SOI layer and the dielectric layer into the Si substrate, the bottom plate electrode being electrically connected via the Si substrate to the bottom plate that comprises the silicide.
Type: Application
Filed: Nov 30, 2015
Publication Date: Jun 1, 2017
Inventors: Qing Cao (Yorktown Heights, NY), Kangguo Cheng (Schenectady, NY), Zhengwen Li (Scarsdale, NY), Fei Liu (Yorktown Heights, NY), Zhen Zhang (Ossining, NY)
Application Number: 14/953,754