Organic Material Containing Patents (Class 106/802)
  • Patent number: 6358310
    Abstract: Additive for cementitious compositions, comprising: at least one admixture, such a shrinkage reducing admixture, an air entraining admixture, a water reducing admixture, an inorganic salt, a corrosion inhibitor, an accelerator, a retarder, or mixture thereof; and a triblock polyoxyalkene copolymer surfactant having the formula R1O—(A1O)x—(A2O)y—(A1O)x—R2 wherein R1 and R2 individually represent hydrogen, a C1-C7 alkyl group, a C5-C6 cycloalkyl group, or an aryl group; A1 represents a C2 alkyl group, A2 represents a branched or linear C3 alkyl group; “x” represents an integer of 42-133; and “y” represents an integer of 21 to 68.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: March 19, 2002
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Neal S. Berke, Maria C. Hicks, James J. Malone
  • Patent number: 6342101
    Abstract: A formulation for blending with raw concrete to form an admixture wherein a concrete plasticizer and migrating corrosion inhibitors are blended with concrete prior to pour. The plasticizer enhances the ability of the concrete to be worked and to be properly finished, and the migrating corrosion inhibitors provide protection of concrete reinforcements such as rebar against corrosion.
    Type: Grant
    Filed: October 11, 1999
    Date of Patent: January 29, 2002
    Assignee: Cortec Corporation
    Inventors: Boris A. Miksic, Dubravka Bjegovic, Alla Furman
  • Patent number: 6311448
    Abstract: A precast concrete plate, such as a roof tile, floor tile, wall tile or house siding, comprises in total from about 0.2% to about 5% by weight of a polymeric modifier having a Tg of above −40° C. The portion of said concrete which comprises no more than about 50% of the thickness of all the concrete which forms the plate, when measured from the bottom surface of the plate towards the top surface of the plate, includes at least about 60% by weight of said polymeric modifier. The plates have a relatively higher degree of resistance to flexural loadings and resistance to impact-impulse loadings in comparison to concrete plates which comprise no polymeric modifier, thus rendering them less likely to be broken or fractured during their storage, transfer and assembly.
    Type: Grant
    Filed: December 15, 1998
    Date of Patent: November 6, 2001
    Assignee: Rohm and Haas Company
    Inventors: Michael Damian Bowe, Roger Shan Chung Hsin
  • Patent number: 6309455
    Abstract: The present invention comprises a stable hydrocolloid composition in which preferably welan gum is uniformly dispersed in a superplasticizer solution such as sulfonated naphthalene, sulfonated melamine, modified lignosulfate, their derivatives and mixtures thereof. The solution is wet milled to form an extremely fine particle size distribution of the gum. The composition is rapidly hydratable and useful as a stabilizing additive in many cement and drilling fluid applications.
    Type: Grant
    Filed: August 21, 2000
    Date of Patent: October 30, 2001
    Assignee: CP Kelco U.S., Inc.
    Inventors: Bryan Skaggs, Harold Dial, Walter Rakitsky
  • Patent number: 6306210
    Abstract: The method of adding migrating corrosion inhibitors to a raw concrete mix by loading a migrating corrosion inhibitor in powder form within a container fabricated from a water soluble film, and thereafter depositing the container into a hydrated concrete mix for blending. The container is preferably fabricated from a film consisting of polyvinyl alcohol.
    Type: Grant
    Filed: August 31, 2000
    Date of Patent: October 23, 2001
    Assignee: Cortec Corporation
    Inventors: Boris A. Miksic, Margarita Kharshan
  • Patent number: 6302955
    Abstract: A composition for improving the freeze thaw durability of masonry concrete comprising (i) an alkylaryl polyether alcohol having the formula R-Ø-(OCH2CH2)xOH, wherein R is a C4-C8 alkyl group (preferably branched), Ø represents a phenol group, and “X” represents an integer in the range of 3-70; and (ii) at least one efflorescence control admixture, such as a C8-C30 fatty acid or its salt or derivative. An exemplary masonry concrete composition of the invention comprises an alkylaryl polyether alcohol having the formula R-Ø-(OCH2CH2)xOH, wherein R is a C4-C8 alkyl group, Ø represents a phenol group, and “X” represents an integer in the range of 3-70; the composition, when wet, having essentially zero slump when tested by the standard cone method for measuring slump. Methods of improving the freeze-thaw durability of masonry units are also disclosed.
    Type: Grant
    Filed: October 13, 1999
    Date of Patent: October 16, 2001
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Awdhoot V. Kerkar, Kati Hazrati
  • Patent number: 6294015
    Abstract: The present invention provides a cement admixture and a cement composition, both of which displays little dependence of the water-reducibility upon temperature in that these cement admixture and cement composition involve little slump loss at high temperature and little increase in the amount of addition at low temperature. The cement admixture comprises either or both of the following components: copolymer (A) which includes constitutional unit (I) of general formula (1) below and constitutional unit (II) of general formula (2) below as essential constitutional units and may further include constitutional unit (III) of general formula (3) below, wherein the content of constitutional unit (III) is 45 weight % or less of copolymer (A); and copolymer salt (B) which is obtained by further neutralizing copolymer (A) with an alkaline substance.
    Type: Grant
    Filed: January 1, 1999
    Date of Patent: September 25, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Akihiko Yamashita, Tsuyoshi Hirata, Tsutomu Yuasa, Hirokazu Niwa
  • Patent number: 6277190
    Abstract: Mortars and plasters containing additives which are alcohols having from 8 to 72 carbon atoms adsorbed on solid supports, and processes for the preparation of the additives.
    Type: Grant
    Filed: January 21, 2000
    Date of Patent: August 21, 2001
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Heinz-Guenther Schulte, Wolfgang Gress, Ralf Neumann, Sarantis Moustakas
  • Patent number: 6277191
    Abstract: The present invention relates to a method and air entraining admixtures (AEAs) for achieving satisfactory levels of air entrainment in a hydraulic cementitious composition, such as concrete or mortar, in which an oxyalkylene shrinkage reduction admixture (SRA) is used with, or to be used in combination with, a water soluble salt, such as a calcium salt. Addition of exemplary polyoxyalkylene copolymers, preferably nonionic and substantially di-block in structure, and preferably having a molecular weight of at least 1,000 and more preferably at least 2,000, are described for controlling air entrainment. Increased air entrainment effect is fiber realized when such polymers are used with conventional AEAs, such as tall oils and vinsol resin.
    Type: Grant
    Filed: December 11, 2000
    Date of Patent: August 21, 2001
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Noah D. Budiansky, Brent S. Williams, Byong-Wa Chun
  • Patent number: 6270567
    Abstract: A material for improving the surface appearance of cementitious mouldings comprises a polyalkylene oxide compound which is selected from polypropylene oxide adducts of either polyethylene glycol or polyethylene oxide-ethylene diamine adduct, polypropylene oxide chains being attached to all terminal groups. The material may be added to a cementitious composition as an admixture or applied to the surface of a moulding which has not yet hardened.
    Type: Grant
    Filed: December 14, 1998
    Date of Patent: August 7, 2001
    Assignee: MBT Holding AG
    Inventors: Shigemi Matsuo, Yasumasa Udagawa, Minoru Yaguchi
  • Patent number: 6264740
    Abstract: A method of producing a new type of cement, hereafter called Conch-krete. Conch-krete is created by adding sodium carbonate (also known as soda ash, natron, etc.) and one or more minerals from the calcium carbonate group (including aragonite, limestone, calcite, marble, dolomite, etc.) and the addition of water to the mix that will harden into a cement-like material. The combination of sodium carbonate and calcium carbonate can be either layered or in a mixed state. An exothermic reaction starts after the addition of water. The composition of Conch-krete can vary between 20% sodium carbonate and 80% calcium carbonate to 80% sodium carbonate and 20% calcium carbonate. Conch-Icrete can be used in a variety of applications not inclusive of forming bricks, interior architecture, table or counter tops, ornaments, repairing damaged cement products, casting and other applications not mentioned above.
    Type: Grant
    Filed: December 7, 1999
    Date of Patent: July 24, 2001
    Inventor: William J. McNulty, Jr.
  • Patent number: 6261360
    Abstract: Self-repairing, fiber reinforced matrix materials include a matrix material including inorganic as well as organic matrices. Disposed within the matrix are hollow fibers having a selectively releasable modifying agent contained therein. The hollow fibers may be inorganic or organic and of any desired length, wall thickness or cross-sectional configuration. The modifying agent is selected from materials capable of beneficially modifying the matrix fiber composite after curing. The modifying agents are selectively released into the surrounding matrix in use in response to a predetermined stimulus be it internal or externally applied. The hollow fibers may be closed off or even coated to provide a way to keep the modifying agent in the fibers until the appropriate time for selective release occurs.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: July 17, 2001
    Inventor: Carolyn M. Dry
  • Patent number: 6258162
    Abstract: The present invention provides a cement additive which can achieve excellent fluid retainability and has excellent mortar kneadability. The cement additive comprises copolymer (A) having polyalkylene glycol ester unit (I) and carboxylic unit (II) as repeating units, wherein polyalkylene glycol ester unit (I) has an oxyalkylene group with 3 to 7 carbon atoms on an ester bonding moiety.
    Type: Grant
    Filed: September 25, 1999
    Date of Patent: July 10, 2001
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Hirokatsu Kawakami, Hirokazu Niwa, Hiromichi Tanaka, Tsutomu Yuasa, Tsuyoshi Hirata
  • Patent number: 6251180
    Abstract: Shrinkage-reducing agent intended as additive in aqueous cement comprising compositions. The agent comprises at least one acetal, preferably a cyclic formal, of a tri- or polyhydric alcohol, which acetal comprises at least one 1,3-dioxa group. The acetal has preferably a water solubility of at least 1%. The agent can, in addition to said acetal, comprise at least one amorphous silica, preferably a powderous silica. The invention refers in a further aspect to the use of said agent in said compositions. The agent is, when used, added to said composition in an amount of 0.1-20% by weight.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: June 26, 2001
    Assignee: Perstorp AB
    Inventors: Jens Engstrand, Carl-Axel Sjögreen
  • Patent number: 6245143
    Abstract: A mortar composition for application of a regenerating and protective coating on cementitious materials by means of an airless pump contains cement, aggregate and synthetic resin emulsion in fixed quantities. It is prepared by mixing the ingredients in a cement mixer until a homogeneous, free-running mortar is obtained followed by pouring it into an agitator with low rpm and agitating until complete utilisation.
    Type: Grant
    Filed: July 2, 1998
    Date of Patent: June 12, 2001
    Inventor: Patrizio Agus
  • Publication number: 20010001381
    Abstract: Methods of improving the flow properties of one or more dry particulate cementitious materials are provided. The methods are basically comprised of dry-blending a particulate flow enhancing additive comprised of a particulate solid adsorbent material having a flow inducing polar molecule producing chemical adsorbed thereon with said cementitious materials.
    Type: Application
    Filed: January 12, 1999
    Publication date: May 24, 2001
    Applicant: Baireddy R. Reddy
    Inventors: BAIREDDY R. REDDY, RONALD E. SWEATMAN, JAMES F. HEATHMAN, RUSSELL M. FITZGERALD, RONALD J. CROOK
  • Patent number: 6210476
    Abstract: The present invention provides improved foamed well cement compositions and methods. The foamed cement compositions have improved properties and are basically comprised of hydraulic cement, amorphous silica surface treated with a mixture of organosilane coupling agents, sufficient water to form a slurry, sufficient gas to foam the slurry and a mixture of foaming and foam stabilizing surfactants present in an amount sufficient to facilitate the formation of the foam and stabilize the foamed composition.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: April 3, 2001
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Jiten Chatterji, Roger S. Cromwell, Baireddy R. Reddy, Clyde R. Anderson, David E. McMechan
  • Patent number: 6200380
    Abstract: A method of continuously producing a cementitious composition such as joint compound includes pre-mixing at least two dry ingredients and pre-mixing at least two liquid ingredients. The ingredients are provided in a continuous mixing apparatus and at least substantially continuously blended.
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: March 13, 2001
    Assignee: National Gypsum Company
    Inventors: Ronald S. Finkelstein, Jashbhai M. Patel
  • Patent number: 6182758
    Abstract: Biodegradable dispersing and fluid loss control additives for well cements, well cement compositions including the additives and methods of using the well cement compositions are provided. The well cement compositions are basically comprised of a hydraulic cement, water in an amount sufficient to form a slurry and a dispersing and fluid loss control additive comprised of casein. A second agent which also provides fluid loss control can optionally be included in the additive.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: February 6, 2001
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Jan Pieter Vijn
  • Patent number: 6176921
    Abstract: A cement dispersant composed of water-soluble vinyl copolymers which include specified kinds of constituent units at specified ratios and of which the weight average molecular weight pullulan converted by GPC method is 15000-150000 and the ratio of weight average molecular weight to number average molecular weight is 2-7 is used together with cement, aggregates and water to produce concrete with the water-to-cement ratio of 20-45%.
    Type: Grant
    Filed: February 17, 1999
    Date of Patent: January 23, 2001
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Mitsuo Kinoshita, Kazuhisa Okada, Masahiro Iida
  • Patent number: 6171386
    Abstract: A cement composition includes cement, water in an amount from about 30% to 200% by weight of cement, and an interpolymer latex in an amount from about 10% to 50% by weight of cement. The interpolymer latex includes at least one conjugated diene monomer having 4 to 8 carbon atoms in an amount from about 5% to 95% by weight of the interpolymer latex, at least one vinyl aromatic monomer having 8 to 12 carbon atoms in an amount from about 5% to 95% by weight of the interpolymer latex, and a copolymerizable functional monomer in an amount from about 0.5% to 50% by weight of the interpolymer latex. A method of making a cement composition involves placing the above ingredients in a suitable mixer well known to those of ordinary skill in the art and mixing the ingredients until they form the cement composition.
    Type: Grant
    Filed: January 21, 1999
    Date of Patent: January 9, 2001
    Assignee: Benchmark Research& Technology Inc.
    Inventor: Freddie Lynne Sabins
  • Patent number: 6165262
    Abstract: A novel cement admixture is provided which fulfills the function as a thickener basically, possesses an ability to inhibit segregation of materials, excels in workability as well, and permits a decrease in the amount of addition while keeping these functions intact. The cement admixture is characterized by comprising a cement additive formed of a polymer resulting from polymerizing a monomer mixture having methyl acrylate as a main component thereof and a cement water reducing agent.
    Type: Grant
    Filed: January 20, 1999
    Date of Patent: December 26, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Kono, Tsutomu Yuasa, Tsuyoshi Hirata
  • Patent number: 6153005
    Abstract: The present invention describes fluorochemical foam stabilizers used in combination with surfactants to yield foams that are exceptionally stable in cementitious media. The stabilized foams that incorporate these fluorochemical agents are useful as novel ultra-lightweight foam aggregates in concrete compositions of tailorable density, strength, and other properties. Methods of making concrete compositions that include such foam aggregates are also described.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: November 28, 2000
    Assignee: Charles D. Welker
    Inventors: Charles D. Welker, Martha A. Welker, Mark F. Welker, Mark A. Justman, Randy S. Hendricksen
  • Patent number: 6143069
    Abstract: The present invention provides light weight high temperature well cement compositions and methods. The compositions are basically comprised of calcium aluminate, ASTM class F fly ash and water.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: November 7, 2000
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Lance E. Brothers, Susan M. Turkett, Barry B. Ekstrand, D. Chad Brenneis, Jerry D. Childs
  • Patent number: 6139623
    Abstract: Exemplary emulsion admixture for use in hydraulic cement compositions formed by emulsifying an antifoaming agent, surfactant, and a comb polymer having a carbon-containing backbone to which are attached cement-anchoring members and oxyalkylene groups. A method of making a stable emulsion admixture comprising the comb polymer, as well as a hydraulic cement composition comprising the admixture, are also described.
    Type: Grant
    Filed: January 20, 1998
    Date of Patent: October 31, 2000
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: David Charles Darwin, Robert T. Taylor, Ara A. Jeknavorian, Ding Feng Shen
  • Patent number: 6126850
    Abstract: A freeze-preventing material comprises cement, salt, and water-absorbing resins. The freeze-preventing material is scattered on the pavement surface in the form of slurry to prevent the pavement surface from freezing. Thereby a freeze-preventing effect is maintained for a long period of time owing to the water-absorbing resins which absorb and retain the salt in large amounts. The anti-freezing effect can be restored by spraying the pavement with the salt again.
    Type: Grant
    Filed: October 6, 1998
    Date of Patent: October 3, 2000
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Nobuya Ishioka, Tetsuhiko Yamaguchi, Masaki Sazawa, Kenichi Kitamura
  • Patent number: 6110270
    Abstract: The moisture content within, and moisture flow in and out of, porous building materials such as masonry, brick, concrete, and mortar, can be affected by coating the building material with polyvinyl alcohol, or by incorporating polyvinyl alcohol into the building material. The resultant control of moisture movement can influence the suction of the building material, leading to improved bonding with adjacent building material, and can also retard efflorescence.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: August 29, 2000
    Inventor: Thomas Beckenhauer
  • Patent number: 6106608
    Abstract: The present invention provides a floor patching and leveling compound ingredient which provides a desired, smooth finish for a floor surface, the resultant floor and a method of making the same. In a preferred embodiment of the invention, the component includes about by weight of a dispersing agent, about 0.5 to 1.0% by weight of an alkali tartrate, and about 0.8 to 1.3% by weight of an alkali carbonate with this component being employed in the mortar in a proportion of about up to 6% of the mortar on a weight basis.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: August 22, 2000
    Inventors: Gerd Andree, Juergen Bartsch
  • Patent number: 6106603
    Abstract: The present invention comprises a stable hydrocolloid composition in which preferably welan gum is uniformly dispersed in a superplasticizer solution such as sulfonated naphthalene, sulfonated melamine, modified lignosulfate, their derivatives and solution thereof. The mixture is wet milled to form an extremely fine particle size, from about 3 microns to about 500 microns distribution of the gum. The composition is rapidly hydratable and useful as a stabilizing additive in many cement and drilling fluid applications.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: August 22, 2000
    Assignee: Pharmacia Corporation
    Inventors: Bryan Skaggs, Harold Dial, Walter Rakitsky
  • Patent number: 6099638
    Abstract: This invention relates to a cement or cementitious composition with synthetic or natural fibers and/or microfibers with caliber or gauge smaller than 0.0508 mm (2 mils), in a proportion from 0.2 to 1.5% of total weight of composition when dry. Aggregates and additives that achieve thixotropy, plasticity, which preserve its dimensional structure and integral mechanical bonds may also be included. These above ingredients are included to create a composition suitable for modeling (i.e., a petrified material, cement, mortar, or concrete with extraordinary and novel characteristics). This composition is also useful for constructing, machining, restoring or creating forms with or without structures. Furthermore, the composition solidifies without contractions, fissures or cracks.
    Type: Grant
    Filed: May 17, 1996
    Date of Patent: August 8, 2000
    Inventor: Carlos Javier Fernandez Garcia
  • Patent number: 6073410
    Abstract: The present invention resides in a wall unit and formulation which is particularly advantageous for the manufacture of prefabricated buildings. The wall unit uses a uniquely formulated exterior wall panel that is bonded to a frame of tri-chord steel beams. The unique cementitious composition of the wall unit allows it to be fire and insect resistant and generally impervious to moisture.
    Type: Grant
    Filed: October 14, 1998
    Date of Patent: June 13, 2000
    Assignee: Eco Buliding Systems, Inc.
    Inventors: Michael J. Schimpf, Marcus J. Harrel
  • Patent number: 6068697
    Abstract: A polysaccharide derivative prepared by replacing all or part of the hydroxyl hydrogen atoms of a polysaccharide or polysaccharide derivative by (A) a hydrophobic substituent having a C.sub.8 -C.sub.43 hydrocarbon chain as the partial structure and (B) an ionic hydrophilic substituent having at least one member selected from the group consisting of sulfonic, carboxyl phosphoric, and sulfate groups and salts thereof as the partial structure, wherein the average degree of replacement by the substituent (A) is 0.0001 or above but below 0.001 per constituent monosaccharide residue as determined by Zeisel's method or the diazomethane method and that by the substituent (B) is 0.01 to 2.0 per constituent monosaccharide residue as determined by colloidal titration. This polysaccharide derivative is useful as the admixture for hydraulic materials and can give stable hydraulic compositions excellent in dispersion.
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: May 30, 2000
    Assignee: Kao Corporation
    Inventors: Hotaka Yamamuro, Takeshi Ihara, Tomohito Kitsuki, Tetsuya Miyajima, Fujio Yamato, Makoto Kohama
  • Patent number: 6063184
    Abstract: The invention relates to a random styrene-maleic anhydride (SMA) copolymer in free acid or salt form wherein the copolymer has the following types and numbers of monomer units ##STR1## in which M is selected from hydrogen, a cation and a residue of a hydrophobic polyalkylene glycol or polysiloxane, R is the residue of methylpoly(ethylene)glycol of molecular weight (weight-average) 900-2000, x=0.35-0.75 and y=0.25-0.65. These copolymers are particularly useful as superplasticizers in cementitious compositions such as concretes and mortars.
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: May 16, 2000
    Assignee: MBT Holding AG
    Inventors: Bernhard Leikauf, Max Oppliger, Salvatore Valenti
  • Patent number: 6033469
    Abstract: Injection medium in the form of a dry mixture for preparing an injection suspension for sealing and/or reducing the penetrability of soils (loose rocks) and/or stone and/or structures against penetration by fluids, especially by water and gases, containing at least one mineral binder, especially a superfine binder, at least one stabilizer, at least one solvent and optionally other customary additives, such as at least one setting accelerator, an injection adjuvant and a water-retention agent, while the stabilizer is at least one organic thickener and the mixture additionally includes at least one essentially inert, superfine filler.
    Type: Grant
    Filed: February 18, 1998
    Date of Patent: March 7, 2000
    Assignee: Dyckerhuff AG
    Inventors: Horst-Dieter Teichert, Reinhard Umlauf
  • Patent number: 5993537
    Abstract: In accordance with the present invention, there are provided novel fiber reinforced building material formulations, comprised of an inorganic binding agent and synthetic fibers. The fibrous material employed in invention formulations is capable of undergoing progressive fibrillation upon agitation. As a result, fibers of lower initial aspect ratios, and higher addition rates than previously possible are disclosed, herein. Formulations containing Portland cement-based compositions and fibrillating synthetic fibers are also contemplated. In addition, there are provided methods of producing fiber reinforced building materials, including Portland cement-based compositions, and articles produced therefrom.
    Type: Grant
    Filed: March 11, 1998
    Date of Patent: November 30, 1999
    Assignee: Dalhousie University
    Inventors: Jean-Francois Trottier, Michael Mahoney
  • Patent number: 5989334
    Abstract: Self-repairing, fiber reinforced matrix materials include a matrix material including inorganic as well as organic matrices. Disposed within the matrix are hollow fibers having a selectively releasable modifying agent contained therein. The hollow fibers may be inorganic or organic and of any desired length, wall thickness or cross-sectional configuration. The modifying agent is selected from materials capable of beneficially modifying the matrix fiber composite after curing. The modifying agents are selectively released into the surrounding matrix in use in response to a predetermined stimulus be it internal or externally applied. The hollow fibers may be closed off or even coated to provide a way to keep the modifying agent in the fibers until the appropriate time for selective release occurs.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: November 23, 1999
    Inventor: Carolyn M. Dry
  • Patent number: 5968255
    Abstract: The present invention provides universal well cement additives and methods. The universal well cement additives improve the properties of a well cement slurry and can be comprised of iron chloride, a dispersing agent, an organic acid, a hydratable polymer and an ultra-fine particulate hydraulic cement.
    Type: Grant
    Filed: January 12, 1999
    Date of Patent: October 19, 1999
    Assignees: Halliburton Energy Services, Inc., Atlantic Richfield Company
    Inventors: Sudhir Mehta, Richard R. Jones, William J. Caveny, Rickey L. Morgan, Dennis W. Gray, Jiten Chatterji
  • Patent number: 5951752
    Abstract: An aqueous composition for coloring cement based compositions comprising water, pigment, a suspension enhancing agent and latex polymer solids.
    Type: Grant
    Filed: June 5, 1998
    Date of Patent: September 14, 1999
    Assignee: C-Cure Corporation
    Inventors: Charles J. Johansen, Jr., Ernest D. Hollas, Robert L. Vecchio, Hani Zoumut
  • Patent number: 5938835
    Abstract: A cement admixture comprised of a mixture of certain alkyl ether oxyalkylene adducts with certain oxyalkylene glycols to provide cement compositions of mortar and concrete which inhibit drying shrinkage while permitting substantial air entrainment and enhanced compressive strength.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: August 17, 1999
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Edward T. Shawl, Haven S. Kesling, Jr.
  • Patent number: 5925184
    Abstract: A cement composition excelling in the slump retaining property which comprises at least cement admixture comprising as a main ingredient thereof (I) a copolymer (A) of short-chain polyalkylene glycol (meth)acrylate (a), a long-chain polyalkylene glycol (meth)acrylate (b), a carboxylic acid monomer (c), and a monomer copolymerizable with the monomers mentioned above or a salt of the copolymer (B), (II) a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt thereof, (III) a mixture of a copolymer (A.sub.1) of the monomers (a), (c), and (d) mentioned above or a salt (B.sub.1) of thereof with a known cement admixture, or (IV) a polycarboxylic acid based polymer (A.sub.3) manifesting to a calcium sulfoaluminate based expansive additive an adsorption ratio of not less than 90% in 5 minutes at room temperature when added in an amount of 0.1% by weight as solids or a salt (B.sub.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: July 20, 1999
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Tsuyoshi Hirata, Tsutomu Yuasa, Toru Uno, Koichiro Nagare, Hideyuki Tahara, Shogo Iwai
  • Patent number: 5922124
    Abstract: An additive for, a method of adding thereof to uncured mixes for and resulting cured cement-type concreations such as cured embodiments of concrete, marcadam, and roof-top shingles each exhibiting improved heat and freeze-thaw durability resulting from reduced efflorescence and stability against sun ultraviolet light exposure.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: July 13, 1999
    Inventor: William W. Supplee
  • Patent number: 5918429
    Abstract: Disclosed is a method for providing an improved cementitious product which includes improved surface characteristics such as skid resistance, as well as improved structural characteristics such as flexural toughness. The product is provided by the inclusion of skid-resistant particles within an uncured cement product, such that the product eventually cures with the skid-resistant particles fixed at and adjacent to the surface, providing improved skid resistance to the cement product its supporting surface, which could be a pedestrian sidewalk, steps, a vehicle roadway, handicapped ramps, or other surfaces where skid resistance is required. The product is desirably softer in structure than traditional concrete structures to allow for desirable wearing by traffic thereon to continuously expose new rubber particles, while still having integral properties which discourage pullout of the particles.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: July 6, 1999
    Assignee: The Quikrete Companies
    Inventors: James K. Hicks, John O. Winchester, Richard R. Nicholson
  • Patent number: 5911819
    Abstract: A method for coating a substrate with a cementitious composition by spraying, comprising the addition to the initial cementitious mix one of a .beta.-naphthalene sulphonate-formaldehyde condensate and a water-soluble poly(alkylene oxide) of molecular weight from 100,000-8,000,000, the other being added at the spraying nozzle, there being additionally added at the nozzle (preferably as a single component with the other nozzle-added material) an accelerator selected from aluminium sulphate, aluminium hydroxide and aluminium hydroxysulphate. In a preferred embodiment, the material added at the nozzle also contains a superplasticiser.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: June 15, 1999
    Assignee: MBT Holding AG
    Inventors: Josef Franz Drs, Bernhard Leikauf, Max Oppliger
  • Patent number: 5911820
    Abstract: A concrete admixture is provided, which is effective in imparting fluidity to a hydraulic composition such as cement paste, mortar or concrete, particularly in maintaining the fluidity of the composition and which hardly retards the hardening property of the composition. The concrete admixture comprises a copolymer comprising, as structural units, units derived from an ethylenically unsaturated monomer (a) having 25 to 300 moles of C.sub.2 -C.sub.3 oxyalkylene groups per mole of copolymer and units derived from a monomer (b) of an alkyl, alkenyl or hydroxyalkyl ester of an ethylenically unsaturated mono- or di-carboxylic acid.
    Type: Grant
    Filed: February 20, 1998
    Date of Patent: June 15, 1999
    Assignee: Kao Corporation
    Inventors: Haruyuki Satoh, Fujio Yamato, Yoshinao Kono, Sayuri Nakamura
  • Patent number: 5897704
    Abstract: The properties of cement matrices are improved by one or more of the three processes, which can be performed individually, sequentially, or in any desired combination. In each instance a supercritical fluid is or includes a solvent for one of two (or more) reactants such as a monomer and a polymer initiator. The resulting mixture is infused into the matrix under supercritical conditions. The other reactant is placed into the matrix; for example, by incorporating it in the wet cement paste prior to curing. When the mixture is infused into the matrix, the reactants react and change the cement matrix in predictable, desired ways. The solvent itself may or may not be supercritical, and if it is not, it is mixed with a supercritical fluid, which might or might not be another solvent. In this manner, the inside of the matrix may be coated and/or sealed with a polymer, for example, or the entire cement matrix may be rendered relatively flexible and ductile.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: April 27, 1999
    Assignee: Materials Technology, Limited
    Inventor: Frank Geile Baglin
  • Patent number: 5897703
    Abstract: A hardening composition comprising a hardening component and hardening agents, said hardening component consisting essentially of magnesium oxide, said hardening agents consisting essentially of propylene carbonate and water, content of said magnesium oxide being 100 parts by weight, content of said propylene carbonate being 1 to 60 parts by weight, and content of said water being 20 to 135 parts by weight. Further disclosed are a hardened product prepared by hardening the hardening composition, and a method for producing the hardened product.
    Type: Grant
    Filed: August 1, 1997
    Date of Patent: April 27, 1999
    Assignee: Tokyo Chemical Co., Ltd
    Inventors: Yuji Hatakeyama, Hiroshi Inoue, Katsuhiko Yamamoto
  • Patent number: 5879825
    Abstract: A method of preparation and use of high-strength gypsum wallboard, as well as a core composition suitable for use therein, are disclosed. The core composition includes a slurry of calcium sulfate hemihydrate (stucco), water, and a strengthening agent. The strengthening agent includes an acrylic polymer composition having a glass transition temperature of about 15.degree. C. or greater, and preferably has good divalent ion stability. The method provides wallboard having increased core strength, paper-to-core bonding, and strength-to-weight ratio.
    Type: Grant
    Filed: January 7, 1997
    Date of Patent: March 9, 1999
    Assignee: National Gypsum Company
    Inventors: W. Roy Burke, Larry W. Kingston
  • Patent number: 5879446
    Abstract: A method of preparation of gypsum wallboard, as well as a core composition suitable for use therein, are disclosed. The core composition includes a slurry of calcium sulfate hemihydrate (stucco), water, and calcium aluminum lignosulfonate and/or aluminum lignosulfonate.
    Type: Grant
    Filed: August 21, 1998
    Date of Patent: March 9, 1999
    Assignee: National Gypsum Company
    Inventors: Jashbhai M. Patel, Ronald S. Finkelstein
  • Patent number: 5868830
    Abstract: A building and construction material and method of making the material utilizes water with cement which are mixed together and followed by mixing with a mineral filler material such as sand or gravel to produce concrete having micropores of about 0.01 to about 5.mu. in diameter. By eliminating from the mineral filler material all fine grains of less than 0.2 mm, it has been found that the strength of the concrete is improved and the amount of shrinkage is reduced.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: February 9, 1999
    Inventor: Hans Beat Fehlmann
  • Patent number: 5855665
    Abstract: An aqueous composition for coloring cement based compositions comprising water, pigment, a suspension enhancing agent and latex polymer solids.
    Type: Grant
    Filed: August 7, 1997
    Date of Patent: January 5, 1999
    Assignee: C-Cure Corporation
    Inventors: Charles J. Johansen, Jr., Ernest D. Hollas, Robert L. Vecchio, Hani Zoumut