Abstract: A process to manufacture a waste material composite and article is described. One embodiment comprises waste material particles or fibers mixed with water to form a mash, blending a chemical binder with the mash, mixing in a cementious material and a filler agent. In another embodiment the chemical binder is added after the filler agent is added, but prior to the cemetious material. In yet another process, the mash which comprises water and paper particles is mixed with wheat residue and the chemical binder and then formed into a paper-wheat article which is pressed until cured. Still, in yet another process, rubber particles are heated, blended with the chemical binder, blended with cement, cooled, blended with ash, formed into an article and pressed until cured to form a cement-rubber composite article. The filler agent comprises calcium hydroxide, hydrated lime, carbonated lime or ash.

Abstract: Powdered and liquid fluid loss additives are disclosed for use in cementing wellbores, particularly oil and gas wellbores. Excellent fluid loss control is achieved over a wide range of conditions using various cements systems. The invention utilizes polyvinyl acetate polymers as a fluid loss additive. The polyvinyl acetate polymer is used in conjunction with a dispersing sulfonated polymer and surfactant. This highly effective combination is then adjusted to individual well conditions with chelating agent, cross-linking agent, biocides, antifoams, or combinations of these. The dispersants are novel dispersing agent polymers such as melamine sulfonate polymer, vinyl sulfonate polymer and styrene sulfonate polymer and mixtures of these. These dispersant materials are usually prepared at low pH and can be used in the acid form, or neutralized to form salts of the polymers, wherein the salt can be a Group I or Group II metal salt, or ammonium salts (common salts).

Abstract: An aqueous composition for coloring cement based compositions comprising water, pigment, a suspension enhancing agent and latex polymer solids.

Abstract: A cementitious composition comprising 0.1 to about 7.5 percent by weight of a solid residual oxidation product from the combustion of an aqueous emulsion of a naturally occurring asphalt from the Orinoco Belt of Venezuela which contains from about 100 to about 1500 ppm by weight of magnesium in the form of a water soluble magnesium salt, which product from the combustion contains magnesium sulfate present in the amount of from about 0.05 to about 4 percent by weight of the cementitious composition and from about 92.5 to about 99.95 percent by weight of a hydraulic silicate cement material.

Abstract: A high early strength admixture for precast hydraulic cement comprises a calcium salt and a copolymer having a carbon-containing backbone to which are attached cement-anchoring members, such as carboxyl groups, and to which are also attached oxyalkylene pendant groups by linkages selected from the group consisting of amide and imide members. The copolymers used are preferably formed by reacting an acrylic polymer with ammonia or an alkoxylated amine. The calcium salt, preferably calcium nitrite, and the copolymer can be added simultaneously as one admixture, or separately. The invention relates also to methods for enhancing high early strength in concrete, cement, masonry, and mortar mixtures generally, and to precast concrete particarly, and also pertains to such hydraulic mixtures containing the calcium salt and copolymer.

Abstract: A dental investing material is disclosed which comprises a combination of: (a) quartz and/or cristobalite, (b) a phosphate binder, and (c) aluminous cement, wherein said dental investing material is further added with tridymite and magnesium silicate. The disclosed dental investing material shows minimized expansion during hardening, significant expansion during heating and develops no cracks when heated at a conventional heating rate.

Abstract: The invention concerns a MDF cement material showing better impact strength meant as an increase in the breaking total energy, by fibers addition.

Abstract: A system is provided including smart fibers which are employed to deliver agents or components to a matrix before or during cure to affect matrix cure or shaping reactions and final cured structures. The delivered agents may be reactants or catalysts to initiate or modify curing, or other agents such as heat, steam, or a coolant, for example. The system may be used to simulate bone formation, growth, and repair.

Abstract: A method for producing cement useful for preparing pastes, mortars, concretes and other cement-based materials, having a high workability with reduced water content, high strength and density, and a rapid development of strength, which method includes a mechanicochemical treatment of cement. The method includes a two-stage mechanicochemical treatment of a mixture of cement and at least one of two components, the first component being a SiO.sub.2 -containing microfiller and the second component being a polymer in the form of a powdery water-reducing agent. In the first stage the cement and the first and/or the second component are intensively mixed in a dry state, whereby particles of the first and/or the second component are adsorbed on the cement particles.

Abstract: Mortar cement additives provide workability while retaining strength by employing a multi-stage polymer comprising a hydrophobically-modified, ionically-soluble polymer stage, the polymer being soluble at a pH of 6 and above; and an air-entraining agent. The additives also employ, as optional ingredients, set retarding agents and superplasticizers. Examplary methods of the invention involve addition of the multi-stage polymer and an air entraining agent to the mortar cement, preferably during intergrinding of Portland cement in the mill. Cement compositions comprising the polymer and an air-entraining agent are also disclosed.

Abstract: The present invention provides resilient cement compositions and methods which are particularly useful in the construction and repair of oil and gas wells. The compositions have improved expansion properties and are basically comprised of a hydraulic cementitious material, rubber particles derived from automobile tires, sufficient water to form a pumpable slurry, and a dispersing agent.

Abstract: A cellular drainage structure is formed of a predetermined volume of a settable, water permeable, cellular concrete product. A concrete mix is formed of a uniformly graded aggregate in the size range from 1/16 inch to two inches and in a quantity corresponding to the predetermined volume; a cementitious component in the quantity range from 141 to 658 pounds per cubic yard of product; water in quantity sufficient to create a water-to-cement ratio in the approximate range from 0.30 to 0.55 and sufficient to wet the aggregate, establishing a cementitious-component-and-water matrix of determinable volume; a pre-formed surfactant foam, generated from an aqueous surfactant mixture at a dilution of from approximately 3 to 25 grams per liter of surfactant in water, wherein the pre-formed foam is in the density range of from 2.0 to 3.0 pcf, and the foam is added in the quantity range of 5% to 30% of the volume of the cementitious-component-and-water matrix.

Abstract: A cement setting and hardening accelerator having the formulaAl(OH).sub.x (R).sub.ywherein R is a basic anion which is not sulphate, and x+y=3. The anion is preferably derived from an acid RH.sub.n which is preferably an organic acid. The accelerator gives excellent performance in shotcrete and is alkali-free.

Abstract: To treat waste containing harmful netals such as lead, cadmium, mercury, chromium, copper, nickel, zinc, etc., the waste is mixed with a treating agent containing, as the essential constituent component, solid acid(s) and/or cement and additionally a caking inhibitor, kneaded with water where necessary, then solidified by curing. Harmful metals are thereby stabilized in the thus-solidified cakes and are not released therefrom.

Abstract: A way of using fly ash and water to make a road base material is disclosed. Class C fly ash, which sets up very quickly, is mixed with a hydrating liquid and compacted prior to initial set. To facilitate mixing, transportation and placement of the wet mixture, a set sequestering additive may be added to the water before mixing the water and the fly ash. Also disclosed is a mixing device designed to be attached to the underside of a tanker trailer of the type used to transport dry fly ash. The mixer introduces water to the inside and outside areas of a falling tubular stream of fly ash.

Abstract: Whole waste tires are shredded and ground down to particulates and used as aggregates for concrete compositions in the construction field.

Abstract: The fluidity characteristics of cementitious compositions may be rapidly altered by the addition thereto of an aqueous dispersion of at least one comb polymer which comprises carboxylic moieties. The invention works especially well when the polymer is combined with an accelerator which is at least one of aluminium hydroxide or aluminium hydroxysulphate.

Abstract: Mortar formulations comprising a hydraulic cement and a PVOH stabilized acrylic latex or a spray dried redispersible powder made from the PVOH stabilized acrylic latex are disclosed. These include formulations suitable for use as tile mortars, patching mortars, EIFS base coats and grouts. An acrylic latex that, when formulated with hydraulic cement, has performance advantages over other latex resins in mortar, patch and exterior insulation and finishing systems. The spray dried, redispersible acrylic emulsion polymer that, when formulated with hydraulic cement, has comparable or better performance than a liquid latex in mortars and patches.

Abstract: The hardenable mortar composition consists of a bonding agent component including a hydraulic bonding agent, such as cement, gypsum or mortar, and a paste-forming agent consisting of a liquid solvent inert with respect to the hydraulic bonding agent, and an aqueous component kept separate from the bonding agent component until the two components are mixed to form a hardened mortar composition. The aqueous component includes water and a hydrophobic adsorbent or absorbent. The hydrophobic adsorbent or absorbent is included in the aqueous component to avoid the emergence of the paste-forming agent, which is at the very least unsightly, when the aqueous component is mixed with the bonding agent component. The hydrophobic adsorbent or absorbent binds the paste-forming agent which would otherwise escape during mixing and remains as an inert additive in the setting mortar composition, without reducing the hardness thereof.

Abstract: Additive which simultaneously provides water-repellency and flexural bond strength improvement in mortar, concrete, or cement. An exemplary composition include calcium stearate and a flexural bond strength enhancing material comprising a polymer having a backbone to which are attached carboxyl cement anchoring groups. A cementious composition and method for enhancing water-repellency and flexural bond strength in a mortar are also disclosed.

Abstract: Powdered and liquid fluid loss additives are disclosed for use in cementing wellbores, particularly oil and gas wellbores. Excellent fluid loss control is achieved over a wide range of conditions using various cements systems. The invention utilizes polyvinyl acetate polymers as a fluid loss additive. The polyvinyl acetate polymer is used in conjunction with a dispersing sulfonated polymer and surfactant. This highly effective combination is then adjusted to individual well conditions with chelating agent, cross-linking agent, biocides, antifoams, or combinations of these. The dispersants are novel dispersing agent polymers such as melamine sulfonate polymer, vinyl sulfonate polymer and styrene sulfonate polymer and mixtures of these. These dispersant materials are usually prepared at low pH and can be used in the acid form, or neutralized to form salts of the polymers, wherein the salt can be a Group I or Group II metal salt, or ammonium salts (common salts).

Abstract: The present invention is directed to a polyoxyalkylene ammonium salt of an imidized polycarboxylic acid polymer cement admixture, storage stable aqueous solutions of said polymer, and to improved cement compositions containing said polymer.

Abstract: This invention relates generally to a gypsum composition having improved setting and strength characteristics. More specifically, this invention relates to a gypsum composition comprising an acrylic latex and an aliphatic alcohol wherein the composition has a retarded setting rate. This gypsum composition may further comprise a melamine-formaldehyde polymer and/or a styrene butadiene latex. This invention further relates to an artificial marble gypsum composition.

Abstract: A hydraulic composition comprising a water-soluble polymer in the form of a polyalkylene oxide derivative having a hydroxyl number of at most 50 KCH-mg/g in terms of terminal hydroxyl groups rendered hydrophobic, a surfactant having a weight-average molecular weight of at most 5,000, a superplasticizer, and a hydraulic powder, which can be endowed with high flowability, aggregate segregation resistance, and strength to remarkably improve the method of using concrete and the method of placing concrete and to thereby greatly enhance the far-reaching effect of eliminating noise pollution particularly in the production of concrete products and streamlining the production of the concrete products.

Abstract: A cement pumpability-enhancing additive which comprises polyethylene glycol and diethylene glycol monobutyl ether and/or a derivative thereof, and optionally polysaccharide. The additive is especially useful for high-strength, high-flow concretes for use in construction.

Abstract: A grouting material which is self-dispersing when brought into contact with a volume of water containing liquor or slurry and is settable to a solid mass after such dispersion, the material being in the form of self-dispersing granules or pellets and comprising a blend of component (A): a cementive constituent forming from 10 per cent to 95 per cent by weight of the composition; component (B): a dispersing constituent forming from 2 per cent to 75 per cent by weight of the composition; optional component (C): a swelling constituent which forms from 0 per cent to 50 per cent by weight of the composition; and component (D): a binder constituent which forms from 0.1 per cent to 10 per cent by weight of the composition; the percentages of components A, B, C and D adding to 100 per cent.

Abstract: An admixture for concrete comprising, as an essential component, a copolymer prepared by copolymerizing (a) a polyalkylene glycol monoester monomer having 110 to 300 mols of an oxyalkylene group(s) each having 2 to 3 carbon atoms, with (b) at least one monomer selected from among acrylic monomers, unsaturated dicarboxylic monomers and allylsulfonic monomers. When this admixture is used in preparing concrete, the resulting concrete composition undergoes little change in the slump for a lengthened time, so that the quality of the concrete composition can be easily controlled.

Abstract: Efflorescence of building material, such as portland cement based building products, masonry, brick, concrete, and mortar, can be retarded by contacting the building material with polyvinylalcohol (PVOH). The PVOH may be dissolved in solvent, preferably water, and either applied to a surface of the building material, or added to the components that form the building material. The PVOH has a hydrolysis percentage above about 90%.

Abstract: In a method for blending of admixtures in a concrete mass which is transported through pipes/hoses to a casting site and in which the mass shall have a consistency which is suitable for casting of the mass on wall or roof surfaces there are used admixtures consisting of two components which react with each other. The two components are mixed into the mass at different points in time, possibly in combination with normally used additional admixtures for the mass.

Abstract: The present invention is directed to a polyoxyalkylene ammonium salt of an imidized polycarboxylic acid polymer cement admixture, storage stable aqueous solutions of said polymer, and to improved cement compositions containing said polymer.

Abstract: A binder composition for three dimensional printing of parts is disclosed which is stable during storage and passage through a printhead, yet able to gel under the conditions existing in a powder bed. The binder composition comprises colloidal silica, a catalyst able to promote gelation of the composition when the composition is below a predetermined pH value, and a base able to maintain the pH of the composition above the predetermined value at which the composition gels. Preferably, the catalyst is polyethylene glycol or another ethylene oxide-derived polymer, and the base is triethanolamine. Upon impact with a powder bed, the pH of the binder composition is reduced, as by adding an acid such as citric acid to the powder, thereby causing the binder to gel in the powder.

Abstract: Self-repairing, fiber reinforced matrix materials include a matrix material including inorganic as well as organic matrices. Disposed within the matrix are hollow fibers having a selectively releasable modifying agent contained therein. The hollow fibers may be inorganic or organic and of any desired length, wall thickness or cross-sectional configuration. The modifying agent is selected from materials capable of beneficially modifying the matrix fiber composite after curing. The modifying agents are selectively released into the surrounding matrix in use in response to a predetermined stimulus be it internal or externally applied. The hollow fibers may be closed off or even coated to provide a way to keep the modifying agent in the fibers until the appropriate time for selective release occurs.

Abstract: An oil and gas well cementing composition and method are shown utilizing hydraulic cement, water a cement hydration retarder and an additive which is effective over a selected time period degrade the retarder. The additive is a controlled release oxidizer which releases nascent oxygen over time to gradually oxidize the cement hydration retarder, thereby providing a single cement slurry design for cementing pipes for oil and gas wells where wide temperature differentials exist between the two ends of the pipe.

Abstract: When a cement dispersant comprising a polymer which is obtained by co-condensating monomers comprising monomer (A) and monomer (B) with formaldehyde, or a salt obtained by neutralizing the polymer, wherein the monomer (A) is an aromatic compound having, on the average, 1 to 300 mol per molecule of at least one member selected from the group consisting of oxyethylene group and oxypropylene group, and the monomer (B) is an aromatic compound having a carboxyl group; or another cement dispersant comprising a polymer which is obtained by co-condensating monomers comprising the above-described monomer (A), the above-described monomer (B) and monomer (C) which is an aromatic compound having a sulfonic acid group with formaldehyde, or a salt obtained by neutralizing the polymer is used as one component of a hydraulic composition, the fluidity of the hydraulic composition is maintained for a long time. Therefore, no trouble on transportation is caused during the force feeding of the hydraulic composition with a pump.

Abstract: Foamable magnesite cement, comprising a cement selected from magnesium oxychloride and magnesium oxysulphate cement, or a mixture thereof, together with one or more organic carboxylic acid(s) having a foaming coefficient lower than 1.80, and/or their anhydride(s) and/or their salt(s).

Abstract: Graded fiber additives for addition to proportioned concrete comprising a mixture of fibers having deniers ranging from about 3 to about 5000 and lengths ranging from about 0.0625 to 3 inches (0.16 to 7.6 cm), graded to provide pluralities of different fiber designs comprising variations in at least three of lengths, widths, thicknesses, deniers, fibrillations, cross-sections or aspect ratios, prior to their addition to concrete, or at least two of lengths, widths, thicknesses, deniers, fibrillations or aspect ratios, prior to their addition to concrete, or at least two of widths, thicknesses, deniers, fibrillations, cross-sections or aspect ratios, prior to their addition to the concrete, so as to accommodate the mortar factions within proportioned concrete containing graded aggregate, provide a continuous distribution of fibers therein and thereby inhibit the initiation of cracking.

Abstract: A method of rapidly forming in place a cementitious structure comprising mixing a cement composition with an amount of a water soluble citrate effective to accelerate the setting of the cement in the presence of sufficient water for hydraulic setting of the cement, and delivering the resulting composition while fluid to the place for forming the cementitious structure.

Abstract: A concrete composition capable of inhibiting shrinkage of structural concrete structures is disclosed. The concrete is formed with an admixture composed of at least one secondary/tertiary alkanediol.

Abstract: A cement admixture composition composed of a mixture of alkylene glycol and fume silica to provide a means of inhibiting drying shrinkage and enhancing compressive strength.

Abstract: A cement admixture composed of a mixture of certain lower alkyl ether oxyalkylene adducts with certain higher alkylene diols to provide cement compositions of mortar and concrete which inhibit drying shrinkage while permitting substantial air entrainment and enhanced compressive strength.

Abstract: Cement comprising hydraulic cement and polymer precursor such as alcohol-soluble phenol resin precursor that is substantially anhydrous and generates water by polymerization.

Abstract: A process for modifying the slump of a concrete or mortar by the addition at different times of a water-soluble poly(alkylene oxide) and a .beta.-naphthalene sulphonate-formaldehyde condensate, a plasticizer or superplasticizer which is selected from lignosulphonates, melamine sulphonate formaldehyde condensates, carboxylates and selected styrene-maleic anhydride copolymers. The poly(alkylene oxide) is preferably partially replaced by a (hydroxy)alkyl cellulose. The process is advantageously used in shotcreting.

Abstract: Compositions useful for making lightweight roof tiles. The compositions comprise in percent by weight: between about 2.0 to 4.1 latex (solids basis), between about 20.0 to 28.0 cement, between about 28.0 to 55.0 lightweight aggregate, between about 9.0 to 15.0 water, between about 5.0 to 35.0 standard weight aggregate such as sand, between about 0.0 to 8.0 filler such as limestone, and between 0.0 to 1.5 accelerating additive such as calcium chloride. Methods for making the compositions e.g. into lightweight roof tiles, are also disclosed.

Abstract: The subject invention is directed to a cement admixture composition composed of certain alkylene glycols and copolymers of alkenyl ether and maleic anhydride. The present admixture provides a means to inhibit drying shrinkage of cement compositions while enhancing the compressive strength of the set composition.

Abstract: A cement admixture composition composed of at least one oxyalkylene compound and an ammonium salt of tall oil fatty acid.

Abstract: An anti-efflorescence admixture for concrete products comprising a tall oil fatty acid and a fatty acid, a portion of the acid content of the tall oil fatty acid and/or fatty acid optionally being present in salt form with an alkanolamine or alkylamine, which admixture is effective in controlling both primary and secondary efflorescence.

Abstract: The present invention relates to a cement composition containing water, hydraulic cement, inert products and a foaming agent obtained by reacting ethylene oxide with a substrate deriving from the production of synthetic alcohols by the oxosynthesis of normal-olefins, sulfating the ethoxylate compound thus obtained with sulfuric anhydride and neutralizing the sulfated acid product with a base of an alkaline, earth-alkaline metal or ammonia.The cement composition can optionally contain conventional additives such as stabilizers, set retarders or accelerators and disperding agents suitable for lowering the viscosity of the composition.This cement composition has improved processability characteristics and enables the production of lightweight concretes having greater mechanical resistance and durability and lower thermal conductivity particularly appropriate for the building industry.

Abstract: The present invention is directed to concrete compositions prepared using firm aqueous gels (aquagels) as all or part of the aggregate in a concrete mix. The concrete sets around the aquagels in the initial set stage. Because the aquagels maintain the pore structure of the concrete while it sets, a concrete product can be obtained that has substantially uniform density regardless of depth. During the curing and/or drying stages, the moisture migrates out of the concrete and the aquagels, and the aquagels dry to a fraction of the size of the original aquagel in the cell or pore in the concrete. This results in cellular, lightweight concrete having reduced density, reduced weight, reduced thermal conductivity, and reduced sound transmission compared to concrete prepared without using aquagels.

Abstract: An improved lightweight cementitious product made up of an aqueous cementitious mixture that can incorporate fly ash, portland cement, sand, lime, and the weight saving component, which is micronized polystyrene particles having particle sizes in the range of 50 to 2000 microns. The final mix can be poured into molded products such as foundation walls, roof tiles, bricks and the like. The product can also be used as a mason's mortar, a plaster, a stucco or a texture.

Abstract: The mortar composition for fixing an anchoring element in a drilled hole in a substrate consists of a water component and a mineral mortar paste held separately from the water component in a crushable container. The mineral mortar paste includes a mixture of mineral mortar and a liquid solvent chemically inert towards the mineral mortar and the mineral mortar paste is hardenable with the water component to form a hardened mortar compound. The water component consists of water and a thixotropic agent so that the water component acts like a paste when not subject to shear forces but flows when subject to shear forces such as those created by the anchoring element advancing in the drilled hole. The thixotropic agent is advantageously amorphous pyrogenic silicic acid.