Using An Energy Beam Or Field, A Particle Beam Or Field, Or A Plasma (e.g., Mbe) Patents (Class 117/108)
  • Patent number: 6194353
    Abstract: A process for preparing an oxide superconductor thin film which has a high crystalline, clean and excellent superconductive surface on a substrate by MBE. The MBE is effected under a condition that the substrate is heated and an oxidizing gas is locally supplied to the proximity of the substrate so that the pressure of the proximity of the substrate becomes 6×10−6 to 8×10−5 Torr at a background pressure.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: February 27, 2001
    Assignee: Sumitomo Electric Industries Ltd.
    Inventor: Takao Nakamura
  • Patent number: 6183552
    Abstract: A crystal growth method for thin films of oxides wherein a vapor-phase deposition method is used to grow crystals for Bi2Sr2CanCun+1O6+2n oxide thin film 304, where n is an integer equal to 1 or greater, includes a first step of growing a Bi2Sr2CuO6 oxide thin film 302 to an arbitrary number of molecular layers by setting a growth environment to conditions in which oxides of bismuth alone are not formed, but intended multi-element oxide is formed, and supplying the growth environment with an excess of bismuth compared with other elements, thereby preventing deficiency of bismuth and also evaporating excess bismuth from the thin film, a second step of causing a layer 303 containing calcium atoms and copper atoms each in the amount of n/2 of the number of strontium atoms contained in the Bi2Sr2CuO6 oxide thin film to accumulate upon the Bi2Sr2CuO6 oxide thin film, and a third step of, in a state in which environmental temperature is set higher than the environmental temperature in the first step, caus
    Type: Grant
    Filed: March 8, 1999
    Date of Patent: February 6, 2001
    Assignee: Agency Industrial Science & Technology, Ministry of International Trade & Industry
    Inventors: Shigeki Sakai, Shinji Migita
  • Patent number: 6176926
    Abstract: A laser irradiating apparatus includes a cylindrical lens group that divides a laser beam and a cylindrical lens that re-couples a laser beam as divided. The cylindrical lens is shaped in a parallelogram whose angles are not a right angle, thereby being capable of dispersing a portion where interference is strengthened in a laser beam to restrain irradiation unevenness.
    Type: Grant
    Filed: April 16, 1998
    Date of Patent: January 23, 2001
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventor: Koichiro Tanaka
  • Patent number: 6172008
    Abstract: A process for preparing an oxide thin film which has a crystalline, clean and smooth surface on a substrate. The process is conducted by using an apparatus comprising a vacuum chamber in which an oxidizing gas of O2 including O3 can be supplied near the substrate so that pressure around the substrate can be increased while maintaining high vacuum near an evaporation source and Knudsen cell evaporation sources arranged in the vacuum chamber wherein the substrate is heated, molecular beam of constituent atoms of the oxide excluding oxygen are supplied from the K cell evaporation sources, an oxidizing gas is locally supplied to the vicinity of the substrate and a growing thin film is illuminated by ultraviolet.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: January 9, 2001
    Assignee: Sumitomo Electric Industries Ltd.
    Inventor: Takao Nakamura
  • Patent number: 6146458
    Abstract: A method of growing a layer of Group III nitride material on a substrate by molecular beam epitaxy includes the steps of (i) disposing a substrate in a vacuum chamber, (ii) reducing the pressure in the vacuum chamber to a pressure suitable for epitaxial growth by molecular beam epitaxy, (iii) supplying ammonia through an outlet of a first supply conduit into the vacuum chamber so that the ammonia flows towards the substrate; and (iv) supplying a Group III element in elemental form through an outlet of a second supply conduit into the vacuum chamber so that said Group III element flows towards the substrate. The method causes a layer containing Group III nitride to be grown on the substrate by molecular beam epitaxy. In the method, the outlet of the first supply conduit is disposed nearer to the substrate than the outlet of the second supply conduit.
    Type: Grant
    Filed: March 12, 1998
    Date of Patent: November 14, 2000
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Stewart Edward Hooper, Alistair Henderson Kean, Geoffrey Duggan
  • Patent number: 6143072
    Abstract: A process for growing a crystalline oxide epitaxially upon the surface of a Group IV semiconductor, as well as a structure constructed by the process, is described. The semiconductor can be germanium or silicon, and the crystalline oxide can generally be represented by the formula (AO).sub.n (A'BO.sub.3).sub.m in which "n" and "m" are non-negative integer repeats of planes of the alkaline earth oxides or the alkaline earth-containing perovskite oxides. With atomic level control of interfacial thermodynamics in a multicomponent semiconductor/oxide system, a highly perfect interface between a semiconductor and a crystalline oxide can be obtained.
    Type: Grant
    Filed: April 6, 1999
    Date of Patent: November 7, 2000
    Assignee: UT-Battelle, LLC
    Inventors: Rodney A. McKee, Frederick J. Walker, Matthew F. Chisholm
  • Patent number: 6139629
    Abstract: The present invention comprises growing gallium nitride films in the presence of bismuth using MBE at temperatures of about 1000 K or less. The present invention further comprises the gallium nitride films fabricated using the inventive fabrication method. The inventive films may be doped with magnesium or other dopants. The gallium nitride films were grown on sapphire substrates using a hollow anode Constricted Glow Discharge nitrogen plasma source. When bismuth was used as a surfactant, two-dimensional gallium nitride crystal sizes ranging between 10 .mu.m and 20 .mu.m were observed. This is 20 to 40 times larger than crystal sizes observed when GaN films were grown under similar circumstances but without bismuth. It is thought that the observed increase in crystal size is due bismuth inducing an increased surface diffusion coefficient for gallium. The calculated value of 4.7.times.10.sup.-7 cm.sup.2 /sec. reveals a virtual substrate temperature of 1258 K which is 260 degrees higher than the actual one.
    Type: Grant
    Filed: April 3, 1998
    Date of Patent: October 31, 2000
    Assignee: The Regents of the University of California
    Inventors: Christian K. Kisielowski, Michael Rubin
  • Patent number: 6113691
    Abstract: Semiconductor compounds and a method for producing the same are provided wherein a method for growing at least one epitaxial layer of a II-VI semiconductor compound using MOVPE is used, the method including the steps of subjecting a substrate to organometallic and hydride precursor compounds in a MOVPE reactor at ultra low pressure, i.e. a pressure in the range of about 10 to 1 mTorr, whereby the organometallic and hydride precursor compounds react at a substrate surface without substantial reaction in the gas phase. The epitaxial layers and semiconductor compounds are useful in blue laser devices.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: September 5, 2000
    Assignee: Philips Electronics North America Corporation
    Inventors: Nikhil R. Taskar, Donald R. Dorman, Dennis Gallagher
  • Patent number: 6113690
    Abstract: A method of preparing crystalline alkaline earth metal oxides on a Si substrate wherein a Si substrate with amorphous silicon dioxide on a surface is provided. The substrate is heated to a temperature in a range of 700.degree. C. to 800.degree. C. and exposed to a beam of alkaline earth metal(s) in a molecular beam epitaxy chamber at a pressure within approximately a 10.sup.-9 -10.sup.-10 Torr range. During the molecular beam epitaxy the surface is monitored by RHEED technique to determine a conversion of the amorphous silicon dioxide to a crystalline alkaline earth metal oxide. Once the alkaline earth metal oxide is formed, additional layers of material, e.g. additional thickness of an alkaline earth metal oxide, single crystal ferroelectrics or high dielectric constant oxides on silicon for non-volatile and high density memory device applications.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: September 5, 2000
    Assignee: Motorola, Inc.
    Inventors: Zhiyi Jimmy Yu, Jerald A. Hallmark, Jonathan K. Abrokwah, Corey D. Overgaard, Ravi Droopad
  • Patent number: 6110840
    Abstract: A method of passivating the surface of a Si wafer is disclosed including the steps of cleaning the surface of the Si wafer and depositing an alkaline earth metal on the clean surface at a wafer temperature in a range of approximately 400.degree. C. to 750.degree. C. The surface is monitored during deposition to detect a (4.times.2) surface reconstruction pattern indicating approximately a one-quarter monolayer of alkaline earth metal is formed. The wafer is annealed at a temperature in a range of 800.degree. C. to 900.degree. C. until the alkaline earth metal forms an alkaline earth metal silicide with a (2.times.1) surface pattern on the surface.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: August 29, 2000
    Assignee: Motorola, Inc.
    Inventors: Zhiyi Jimmy Yu, Corey D. Overgaard, Ravi Droopad, Jonathan K. Abrokwah, Jerald A. Hallmark
  • Patent number: 6106613
    Abstract: In a semiconductor substrate comprising a silicon substrate having a porous region, and a semiconductor layer provided on the porous region, the semiconductor layer comprises a single-crystal compound and is formed on the surface of the porous region with its pores having been sealed at the surface. This substrate can be produced by a process comprising the steps of heat-treating the silicon substrate 11 having a porous region, to seal pores at the surface of the porous region 13, and forming a single-crystal compound-semiconductor layer 14 by heteroepitaxial growth on the porous region having the pores sealed by the heat treatment.Single-crystal compound semiconductor films with less crystal defects can be formed on large-area silicon substrates in a high productivity, a high uniformity, a high controllability and a great economical advantage.
    Type: Grant
    Filed: March 12, 1998
    Date of Patent: August 22, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventors: Nobuhiko Sato, Takao Yonehara
  • Patent number: 6106615
    Abstract: Specific alloys, in particular Ni-based alloys, that can be biaxially textured, with a well-developed, single component texture are disclosed. These alloys have a significantly reduced Curie point, which is very desirable from the point of view of superconductivity applications. The biaxially textured alloy substrates also possess greatly enhanced mechanical properties (yield strength, ultimate tensile strength) which are essential for most applications, in particular, superconductors. A method is disclosed for producing complex multicomponent alloys which have the ideal physical properties for specific applications, such as lattice parameter, degree of magnetism and mechanical strength, and which cannot be in textured form. In addition, a method for making ultra thin biaxially textured substrates with complex compositions is disclosed.
    Type: Grant
    Filed: February 16, 1999
    Date of Patent: August 22, 2000
    Inventors: Amit Goyal, Eliot D. Specht, Donald M. Kroeger, Mariappan Paranthaman
  • Patent number: 6103010
    Abstract: A thin ferromagnetic film is deposited directly onto the surface of a waveguide. The crystalline orientation of the ferromagnetic film is restricted to a predetermined orientation by pulverizing nuclei that do not have the predetermined orientation.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: August 15, 2000
    Assignee: Alcatel
    Inventor: Christian Belouet
  • Patent number: 6099640
    Abstract: A method of promoting evaporation of excess indium from a surface of an indium containing compound semiconductor single crystal layer during a discontinuation of a molecular beam epitaxial growth. Substantial supply of all elements for the indium containing compound semiconductor single crystal layer are stopped at least until a substrate temperature rises to a predetermined temperature of not less than an indium re-evaporation initiation temperature.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: August 8, 2000
    Assignee: NEC Corporation
    Inventor: Hitoshi Negishi
  • Patent number: 6090358
    Abstract: A novel material Si.sub.X C.sub.y N.sub.z, having a crystal structure similar to that of a.Si.sub.3 N.sub.4 with carbon atoms substituting most of the Si sites, is synthesized in crystalline form onto crystalline Si substrates by microwave plasma enhanced decomposition of carbon, silicon and nitrogen containing gasses.
    Type: Grant
    Filed: August 20, 1997
    Date of Patent: July 18, 2000
    Assignee: National Science Council of Republic of China
    Inventors: Li-Chyong Chen, Kuei-Hsien Chen, Dhananjay Manohar Bhusari, Chun-Ku Chen
  • Patent number: 6068739
    Abstract: A method of manufacturing a data recording medium for recording and reproducing data by use of a magnetic field or light and formed of an ordered alloy thin film comprising the steps of forming at least one underlayer principally containing an element or a compound selected from the group consisting of Cr, Pt, Pd, Au, Fe, Ni, MgO, NiO and controlled in such a way that a crystal plane having a crystal lattice face of a Miller index (100) is in parallel to a substrate, and forming an ordered alloy layer with L1.sub.0 crystal structure by sputter deposition within the range satisfying Equation 1: P.times.D>3000, where P is Ar sputter-gas pressure (Pa) and D is a target-substrate distance (mm), is disclosed.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: May 30, 2000
    Assignee: Governor of Akita Prefecture
    Inventors: Toshio Suzuki, Naoki Honda, Kazuhiro Ouchi
  • Patent number: 6054063
    Abstract: The high-frequency electric field is subjected to pulse modulation for 10 to 100 .mu.sec; the rise time of pulse is controlled to be not shorter than 2 .mu.sec but not longer than 50 .mu.sec; and the descent time of pulse is controlled to be not shorter than 10 .mu.sec but not longer than .phi..mu.sec. Thereby, the electron temperature in plasma is controlled at 2 eV or lower and the fluctuation of the density of negative ion in plasma is controlled at 20% or smaller.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: April 25, 2000
    Assignee: NEC Corporation
    Inventors: Hiroto Ohtake, Seiji Samukawa
  • Patent number: 6037614
    Abstract: Sn.sub.x Ge.sub.1-x alloys that are substantially free of compositional inhomogeneities and Sn segregation, and have a measurable direct band gap. Methods for making the Sn.sub.x Ge.sub.1-x alloys are also disclosed.
    Type: Grant
    Filed: March 6, 1998
    Date of Patent: March 14, 2000
    Assignee: California Institute of Technology
    Inventors: Gang He, Harry A. Atwater
  • Patent number: 6033471
    Abstract: By using a dual ion-beam sputtering apparatus, an aluminum thin-film is formed on a glass substrate made of an amorphous material. While radiating an ion beam for assisting the film formation from an ion source onto the glass substrate, the aluminum thin-film is formed by depositing the sputtering ions which are generated by radiating an ion beam onto an aluminum target.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: March 7, 2000
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Hidefumi Nakanishi, Atsushi Sakurai, Masato Kobayashi, Yukio Yoshino
  • Patent number: 6022410
    Abstract: A method of forming a thin silicide layer on a silicon substrate 12 including heating the surface of the substrate to a temperature of approximately 500.degree. C. to 750.degree. C. and directing an atomic beam of silicon 18 and an atomic beam of an alkaline-earth metal 20 at the heated surface of the substrate in a molecular beam epitaxy chamber at a pressure in a range below 10.sup.-9 Torr. The silicon to alkaline-earth metal flux ratio is kept constant (e.g. Si/Ba flux ratio is kept at approximately 2:1) so as to form a thin alkaline-earth metal silicide layer (e.g. BaSi.sub.2) on the surface of the substrate. The thickness is determined by monitoring in situ the surface of the single crystal silicide layer with RHEED and terminating the atomic beam when the silicide layer is a selected submonolayer to one monolayer thick.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: February 8, 2000
    Assignee: Motorola, Inc.
    Inventors: Zhiyi Yu, Jun Wang, Ravindranath Droopad, Daniel S. Marshall, Jerald A. Hallmark, Jonathan K. Abrokwah
  • Patent number: 6007623
    Abstract: A method for producing a horizontal magnetic recording medium that has as its magnetic film a granular film with grains of a chemically-ordered FePt or FePtX (or CoPt or CoPtX) alloy in the tetragonal L1.sub.0 structure uses an etched seed layer beneath the granular film. The granular magnetic film reveals a very high magnetocrystalline anisotropy within the individual grains. The film is produced by sputtering from a single alloy target or cosputtering from several targets. The granular structure and the chemical ordering are controlled by means of sputter parameters, e.g., temperature and deposition rate, and by the use of the etched seed layer that provides a structure for the subsequently sputter-deposited granular magnetic film. The structure of the seed layer is obtained by sputter etching, plasma etching, ion irradiation, or laser irradiation. The magnetic properties, i.e., H.sub.c and areal moment density M.sub.
    Type: Grant
    Filed: August 29, 1997
    Date of Patent: December 28, 1999
    Assignee: International Business Machines Corporation
    Inventors: Jan-Ulrich Thiele, Dieter Klaus Weller
  • Patent number: 5993542
    Abstract: A method for fabricating nitride III-V compound semiconductor layers of substrate, of GaN for example, comprises the steps of: growing a first B.sub.w Al.sub.x Ga.sub.y In.sub.z N layer 2 (where 0.ltoreq.w.ltoreq.1, 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.1, 0.ltoreq.y.ltoreq.1 and w+x+y+z=1) on a sacrificial sapphire substrate 1 by MOCVD at a growth rate not higher than 4 .mu.m/h; growing a second B.sub.w Al.sub.x Ga.sub.y In.sub.z N layer 3 (where 0.ltoreq.w.ltoreq.1, 0.ltoreq.x.ltoreq.1, 0.ltoreq.y.ltoreq.1, 0.ltoreq.y.ltoreq.1 and w+x+y+z=1) on the first B.sub.w Al.sub.x Ga.sub.y In.sub.z N layer by hydride VPE at a growth rate higher than 4 .mu.m/h and not higher than 200 .mu.m/h; and removing the sacrificial substrate 1.
    Type: Grant
    Filed: December 4, 1997
    Date of Patent: November 30, 1999
    Assignee: Sony Corporation
    Inventors: Katsunori Yanashima, Masao Ikeda, Satoshi Tomioka
  • Patent number: 5989339
    Abstract: A molecular beam epitaxy system having a plurality of chambers which contain at least a first chamber and a second chamber. The first chamber is used to form II-VI column compound semiconductor layers not containing Te. The second chamber is used to form II-VI column compound semiconductor layers containing at least Te. A semiconductor device having an ohmic characteristics can be fabricated without mixing Te into other layers.
    Type: Grant
    Filed: September 13, 1995
    Date of Patent: November 23, 1999
    Assignee: Sony Corporation
    Inventors: Koshi Tamamura, Hironori Tsukamoto, Masao Ikeda
  • Patent number: 5989511
    Abstract: An article and method of manufacture of a nanocrystalline diamond film. The nanocrystalline film is prepared by forming a carbonaceous vapor, providing an inert gas containing gas stream and combining the gas stream with the carbonaceous containing vapor. A plasma of the combined vapor and gas stream is formed in a chamber and fragmented carbon species are deposited onto a substrate to form the nanocrystalline diamond film having a root mean square flatness of about 50 nm deviation from flatness in the as deposited state.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: November 23, 1999
    Assignee: The University of Chicago
    Inventors: Dieter M. Gruen, Alan R. Krauss, Ali Erdemir, Cuma Bindal, Christopher D. Zuiker
  • Patent number: 5985025
    Abstract: Molecular beam epitaxy (202) with growing layer thickness control (206) by feedback of mass spectrometer (204) signals based on a process model. Examples include III-V compound structures with multiple AlAs, InGaAs, and InAs layers as used in resonant tunneling diodes.
    Type: Grant
    Filed: February 1, 1995
    Date of Patent: November 16, 1999
    Assignee: Texas Instruments Incorporated
    Inventors: Francis G. Celii, Alan J. Katz, Yung-Chung Kao, Theodore S. Moise
  • Patent number: 5980631
    Abstract: A method for manufacturing III-V semiconductor layers containing nitrogen whereby during the growth of the layers, the setting of the material sources for Al, In and Ga remains fixed. During the transition to the growth of a layer with another mixed-crystal composition, the nitrogen flow is altered. A greater nitrogen flow leads to an increased installation of the more weakly bound group III elements into the growing material.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: November 9, 1999
    Assignee: Siemens Aktiengesellschaft
    Inventors: Helmut Tews, Meinrad Schienle, Robert Averbeck
  • Patent number: 5976958
    Abstract: A method of growing a p-type doped Group II-VI semiconductor film includes the steps of forming a lattice comprising a Group II material and a Group VI material and generating a first Group V flux by evaporating a solid Group V source material. The first Group V flux is then decomposed to generate a second Group V flux, which is, in turn, provided to the lattice to p-type dope the growing film. The Group V source material may by arsenic such that the second Group V flux may predominantly include dimeric arsenic decomposed from tetrameric arsenic to improve the incorporation of arsenic into the Group VI sublattice of the lattice.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: November 2, 1999
    Assignee: Hughes Electronics Corporation
    Inventors: Rajesh D. Rajavel, Owen K. Wu, Peter D. Brewer, Terence J. deLyon
  • Patent number: 5935374
    Abstract: An electronic device fabrication apparatus a reaction chamber; a cathode electrode and an anode electrode opposed to each other in the reaction chamber; a gas introduction pipe introduced into the reaction chamber for supplying reaction gas into the reaction chamber, the gas introduction pipe being electrically connected to the cathode electrode; and a high frequency power generation device for applying high frequency lower having a high exciting frequency which is included in one of a VHF band and a UHF band to the cathode electrode through the gas introduction pipe for exciting the reaction gas into a plasma state. The gas introduction pipe includes an impedance adjusting device for adjusting an impedance of the gas introduction pipe.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: August 10, 1999
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Yasuhiko Ito, Osamu Sakai
  • Patent number: 5932006
    Abstract: Metal insulator semiconductor field effect transistors (MISFETs), charge coupled devices (CCDs), and capacitors based on an epitaxial barium fluoride (BF.sub.2) insulator layer deposited directly onto a single crystal gallium arsenide (GaAs) substrate.
    Type: Grant
    Filed: March 25, 1996
    Date of Patent: August 3, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Francisco Santiago, Tak Kin Chu
  • Patent number: 5907792
    Abstract: A method of forming a silicon nitride layer or film on a semiconductor wafer structure includes forming a silicon nitride layer on the surface of a wafer structure using a molecular beam of high purity elemental Si and an atomic beam of high purity nitrogen. In a preferred embodiment, a III-V compound semiconductor wafer structure is heated in an ultra high vacuum system to a temperature below the decomposition temperature of said compound semiconductor wafer structure and a silicon nitride layer is formed using a molecular beam of Si provided by either thermal evaporation or electron beam evaporation, and an atomic nitrogen beam provided by either RF or microwave plasma discharge.
    Type: Grant
    Filed: August 25, 1997
    Date of Patent: May 25, 1999
    Assignee: Motorola,Inc.
    Inventors: Ravi Droopad, Jonathan K. Abrokwah, Matthias Passlack, Zhiyi Jimmy Yu
  • Patent number: 5904770
    Abstract: A method of manufacturing a semiconductor device which has a crystalline silicon film comprises the steps of forming crystal nuclei in a surface region of an amorphous silicon film and then growing the crystals from the nuclei by a laser light. Typically the crystal nuclei are silicon crystals or metal silicides having an equivalent structure as silicon crystal.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: May 18, 1999
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Hisashi Ohtani, Akiharu Miyanaga, Junichi Takeyama
  • Patent number: 5900057
    Abstract: A planar waveguide and a process for making a planar waveguide is disclosed. The waveguide has a layer of dope host material formed on a substrate. The host material is a trivalent material such as a metal fluoride, wherein the metal is selected from the Group III B metals and the lanthanide series rare earth metals of the Mendeleevian Periodic Table. The dopant is a rare earth metal such as erbium. The waveguide has an emission spectrum with a bandwidth of about 60 nm for amplification of an optical signal at a wavelength of about 1.51 .mu.m to about 1.57 .mu.m. The waveguide is made by forming the layer of doped host material on a substrate. The film is formed by evaporating materials from two separate sources, one source for the dopant material and a separate source for the host material and forming a film of the evaporated materials on a substrate.
    Type: Grant
    Filed: June 5, 1996
    Date of Patent: May 4, 1999
    Assignee: Lucent Technologies Inc.
    Inventors: Christoph J. Buchal, Theo Siegrist
  • Patent number: 5891243
    Abstract: In a process for growing a ZnSe crystal by an MBE or MOCVD process, N.sub.2 gas dissociated by electromagnetic waves and vapor In are prepared at a ratio of N:In being 2:1. The atomic gases may be prepared by decomposing InN at a high temperature with electromagnetic irradiation and adding N.sub.2 gas to the decomposed product. The atomic gases are fed onto a substrate in a crystal growth region, so as to simultaneously dope ZnSe with In and N at a ratio of 1:2. A n-type dopant In substitutionally occupying a position of Zn makes a 1:1 couple with a p-type dopant N substitutionally occupying a position of Se, and another one N atom coordinates near the atomic couple and serves as an acceptor. As a result, the acceptor is kept in activated state up to higher concentration, and the ZnSe crystal can be heavily doped with the p-type dopant N.
    Type: Grant
    Filed: August 7, 1997
    Date of Patent: April 6, 1999
    Assignee: Japan Science and Technology Corporation
    Inventor: Hiroshi Yoshida
  • Patent number: 5891241
    Abstract: Hydrogenated amorphous carbon mainly composed of sp.sup.3 structure is prepared by adding hydrogen to carbon or decomposing hydrogenated carbon gas, and then rapidly cooling the mixed or decomposed gas on a substrate. The hydrogenated amorphous carbon is irradiated with X rays to excite electrons on the 1s shells of carbon atoms. The carbon atoms are rendered to a state excited with 2.sup.+ ion due to Auger effect caused by the exciation, so as to form atomic vacancies and interlattice atomic couples. The hydrogenated amorphous carbon is then annealed, and carbon atoms are rearranged to rotated triangular pattern. Thus, diamond good of crystallinity useful as a high-temperature semiconductor device, ultraviolet laser diode or protective film can be synthesized at a relatively low temperature and a low pressure. The process is applicable for the growth of a diamond single crystal thin film on a single crystal substrate such as amorphous carbon, silicon, or a Group III-V or II-VI compound semiconductor.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: April 6, 1999
    Assignee: Research Development Corporation of Japan
    Inventor: Hiroshi Yoshida
  • Patent number: 5888294
    Abstract: An improved epitaxial growth rate varying method for a side surface of a semiconductor pattern capable of controlling a growth rate of a side surface of a semiconductor pattern by controlling the amount of CCl.sub.4 gas supplied when forming an epitaxial layer on a patterned GaAs substrate in a metalorganic chemical deposition method, thus fabricating a desired quantum wire, and which is characterized by controlling a side-surface growth rate of an epitaxial layer in accordance with the CCl.sub.4 doping gas flow rate while an epitaxial layer is formed on a patterned GaAs substrate in a metalorganic chemical deposition method and in achieving a desired substantial flatness.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: March 30, 1999
    Assignee: Korea Institute of Science and Technology
    Inventors: Suk-Ki Min, Moo Sung Kim, Yong Kim
  • Patent number: 5885665
    Abstract: A method for forming crystallographically coherent precipitates of vanadium dioxide in the near-surface region of sapphire and the resulting product is disclosed. Ions of vanadium and oxygen are stoichiometrically implanted into a sapphire substrate (Al.sub.2 O.sub.3), and subsequently annealed to form vanadium dioxide precipitates in the substrate. The embedded VO.sub.2 precipitates, which are three-dimensionally oriented with respect to the crystal axes of the Al.sub.2 O.sub.3 host lattice, undergo a first-order monoclinic-to-tetragonal (and also semiconducting-to-metallic) phase transition at .about.77.degree. C. This transformation is accompanied by a significant variation in the optical transmission of the implanted region and results in the formation of an optically active, thermally "switchable" surface region on Al.sub.2 O.sub.3.
    Type: Grant
    Filed: May 9, 1997
    Date of Patent: March 23, 1999
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Laurence A. Gea, Lynn A. Boatner
  • Patent number: 5879450
    Abstract: A method and an apparatus have been developed to deposit heteroepitaxial beta-silicon carbide films on silicon using bias-assisted hot filament chemical vapor deposition (BA-HFCVD). The apparatus includes a graphite plate as the carbon source and the silicon substrate as the silicon source. Hydrogen was the only feeding gas to the system.
    Type: Grant
    Filed: August 13, 1997
    Date of Patent: March 9, 1999
    Assignee: City University of Hong Kong
    Inventors: Shuit Tong Lee, Chun Sing Lee, Bello Igor, Yat Wah Lam, Hin Koon Woo
  • Patent number: 5855669
    Abstract: A grating coupler is formed by growing an optical waveguide layer on a substrate by an epitaxial growing process such as a metalorganic chemical vapor deposition and a molecular beam deposition. The optical waveguide layer has a surface on which a cross-hatch pattern serving as the grating is continuously formed. The optical waveguide layer is formed with a material having a reflective index greater than a reflective index of the substrate or an atmosphere. Specifically, the substrate is formed with GaAs and the optical waveguide layer is formed with InGaAs. Further, the substrate is an on-substrate having an orientation coinciding with a ?100! plane, so as to form the optical waveguide layer having continuous cross-hatch patterns on the surface thereof. The spacing between the cross-hatch patterns can be varied according to variation of a growth temperature of the optical waveguide layer.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: January 5, 1999
    Assignee: Electronics And Telecommunications Research Institute
    Inventors: Jong-Hyeob Baek, Bun Lee
  • Patent number: 5830270
    Abstract: A structure including a film of a desired perovskite oxide which overlies and is fully commensurate with the material surface of a semiconductor-based substrate and an associated process for constructing the structure involves the build up of an interfacial template film of perovskite between the material surface and the desired perovskite film. The lattice parameters of the material surface and the perovskite of the template film are taken into account so that during the growth of the perovskite template film upon the material surface, the orientation of the perovskite of the template is rotated 45.degree. with respect to the orientation of the underlying material surface and thereby effects a transition in the lattice structure from fcc (of the semiconductor-based material) to the simple cubic lattice structure of perovskite while the fully commensurate periodicity between the perovskite template film and the underlying material surface is maintained.
    Type: Grant
    Filed: August 5, 1996
    Date of Patent: November 3, 1998
    Assignee: Lockheed Martin Energy Systems, Inc.
    Inventors: Rodney Allen McKee, Frederick Joseph Walker
  • Patent number: 5827802
    Abstract: Method of vacuum depositing a monomolecular layer on a surface, the monomolecular layer comprising at least one element selected from groups IIa, IIIa, IVa, VIIIa, Ib, IIb, IIIb, Vb of the periodic table. The method consists in heating said surface to a predetermined temperature (T) of less than 600.degree. C. and vacuum evaporating at least the above-mentioned element for the purpose of depositing it on the receptor surface, the total atomic flow of the element(s) onto the receptor surface being from 10.sup.12 to 10.sup.15 atoms/cm.sup.2 s. According to the invention, the formation of the monomolecular layer is monitored in real time, and evaporation of the element is stopped when the complete formation of the monomolecular layer is detected.
    Type: Grant
    Filed: July 8, 1996
    Date of Patent: October 27, 1998
    Assignee: Ufinnova
    Inventor: Michel Lagues
  • Patent number: 5814149
    Abstract: A method is related to grow monocrystalline diamond films by chemical vapor deposition on large area at low cost. The substrate materials are either bulk single crystals of Pt or its alloys, or thin films of those materials deposited on suitable supporting materials. The surfaces of those substrates must be either (111) or (001), or must have domain structures consisting of (111) or (001) crystal surfaces. Those surfaces can be inclined within .+-.10 degree angles from (111) or (001). In order to increase the nucleation density of diamond, the substrate surface can be scratched by buff and/or ultrasonic polishing, or carbon implanted. Monocrystalline diamond films can be grown even though the substrate surfaces have been roughened. Plasma cleaning of substrate surfaces and annealing of Pt or its alloy films are effective in growing high quality monocrystalline diamond films.
    Type: Grant
    Filed: November 17, 1995
    Date of Patent: September 29, 1998
    Assignee: Kabushiki Kaisha Kobe Seiko Sho
    Inventors: Yoshihiro Shintani, Takeshi Tachibana, Kozo Nishimura, Koichi Miyata, Yoshihiro Yokota, Koji Kobashi
  • Patent number: 5792270
    Abstract: A method and apparatus for producing a pattern of nucleation sites is disclosed. The method enables the growth of single crystal layers of a desired orientation on a suitable amorphous and/or non-single crystal surface. The method can be used to produce single crystal Si layers of a desired orientation on an amorphous layer, e.g. of SiO.sub.2 or Si.sub.3 N.sub.4. The method can provide for growth of (100) crystal orientation on SiO.sub.2. Semiconductor films may be accordingly grown on amorphous glass substrates for producing solar cells of high efficiency. A pattern of nucleation sites is created in amorphous layers, e.g. SiO.sub.2 on an IC wafer, by high-dose implantation through a single crystal mask having appropriate channeling directions at the desired lattice constants. Such implantation may be performed in a conventional ion implanter. Subsequent to creation of spaced-apart nucleation sites, epitaxial Si may be grown on such an SiO.sub.2 surface by CVD of Si.
    Type: Grant
    Filed: October 21, 1993
    Date of Patent: August 11, 1998
    Inventor: Arjun Saxena
  • Patent number: 5788767
    Abstract: The present invention is a method for using a single SiN layer as a passivation film. The single layer SiN can be strengthened to withstand stress by adjusting the process parameters during formation of the SiN layer. In general, the process can be changed by increasing the low frequency power 5% during the deposition. Alternatively, the pressure of the SiN deposition may be decreased about 20% in pressure.
    Type: Grant
    Filed: December 31, 1996
    Date of Patent: August 4, 1998
    Assignee: Vanguard International Semiconductor Corporation
    Inventors: Jun-Cheng Ko, Liang-Tung Tony Chang
  • Patent number: 5785756
    Abstract: A novel molecular beam epitaxy deposition process for precisely growing structurally robust films and coatings containing germanium and various fluoride compounds for use as an optical filter. The process comprises depositing two (2) materials having different indices of refraction via molecular beam epitaxy at a temperature significantly lower than the optimal growth temperature. At such lower temperature, layers of the respective compounds are grown, via molecular beam epitaxy, such that the layers contain large concentrations of dislocations. Once the film or coating has been grown to the desired thickness, the material deposited is allowed to cool to room temperature and may then be used in a wide range of applications.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: July 28, 1998
    Assignee: Northrop Grumman Corporation
    Inventor: Myung B. Lee
  • Patent number: 5773085
    Abstract: One kind of element belonging to I group or II group and one kind of binary compound including one kind of element belonging to III group and one kind of element selected from the group consisting of S, Se, Te and O are evaporated respectively by means of a vacuum vapor deposition method or molecular beam epitaxial method to produce a ternary compound semiconductor material having a low vapor pressure, and the thus produced ternary compound semiconductor material is deposited on a substrate to form a ternary compound semiconductor thin film. Particularly, when a phosphor thin film for electroluminescence emitting blue light is to be grown, an element Sr and a binary compound Ga.sub.2 S.sub.3 are respectively evaporated by the vacuum evaporation method or molecular beam epitaxial method to deposit a ternary compound semiconductor material SrGa.sub.2 S.sub.
    Type: Grant
    Filed: June 12, 1996
    Date of Patent: June 30, 1998
    Assignee: Nippon Hoso Kyokai
    Inventors: Yoji Inoue, Katsu Tanaka, Shinji Okamoto, Kikuo Kobayashi
  • Patent number: 5772758
    Abstract: Methods and apparatus are provided for monitoring deposition and pre-deposition characteristics such as the growth rates, oxide desorption, surface reconstruction, anion surface exchange reaction and smoothness of the surface of rotating substrates in near real-time during molecular beam epitaxy by processing the data in the time domain and for controlling a deposition apparatus in near real-time.
    Type: Grant
    Filed: February 15, 1996
    Date of Patent: June 30, 1998
    Assignee: California Institute of Technology
    Inventors: Douglas A. Collins, Thomas C. McGill, George O. Papa
  • Patent number: 5772760
    Abstract: A method and system for manufacturing nanocrystalline diamond film on a substrate such as field emission tips. The method involves forming a carbonaceous vapor, providing a gas stream of argon, hydrocarbon and possibly hydrogen, and combining the gas with the carbonaceous vapor, passing the combined carbonaceous vapor and gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the carbonaceous vapor and deposition of a diamond film on the field emission tip.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: June 30, 1998
    Assignee: The University Of Chicago
    Inventors: Dieter M. Gruen, Alan R. Krauss
  • Patent number: 5772759
    Abstract: Disclosed is a process for producing p-type doped layers, in particular, in II-VI semiconductors, in which the p-type doped layer is produced in a CVD-step by means of plasma activation of nitrogenated gases.
    Type: Grant
    Filed: October 8, 1996
    Date of Patent: June 30, 1998
    Assignee: Aixtron GmbH
    Inventors: Klaus Heime, Michael Heuken
  • Patent number: 5766345
    Abstract: An epitaxial growth method of semiconductor can reliably avoid irregularities from being produced when a II-VI compound semiconductor is grown epitaxially. When this method is applied to a method of manufacturing a semiconductor light-emitting device, it is possible to obtain a semiconductor light-emitting device having a long life and excellent light-emitting characteristic. When a II-VI compound semiconductor is grown epitaxially, a VI/II ratio, i.e., a supplying ratio of VI-group element and II-group element used in the epitaxial growth is selected in a range of from 1.3 to 2.5.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: June 16, 1998
    Assignee: Sony Corporation
    Inventors: Shigetaka Tomiya, Kazushi Nakano, Satoshi Ito, Rikako Minatoya
  • Patent number: 5762706
    Abstract: The present invention includes a process of growing a compound semiconductor layer locally, after applying radical particles that do not become an etchant of a compound semiconductor layer to an insulating mask so as to terminate the surface of the insulating mask in a state that the compound semiconductor layer is covered with the insulating mask, on the surface of the compound semiconductor layer exposed from the insulating mask.
    Type: Grant
    Filed: November 8, 1994
    Date of Patent: June 9, 1998
    Assignee: Fujitsu Limited
    Inventors: Junji Saito, Toshihide Kikkawa, Hirosato Ochimizu