Using An Energy Beam Or Field, A Particle Beam Or Field, Or A Plasma (e.g., Mbe) Patents (Class 117/108)
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Patent number: 5759266Abstract: In a method for growing a CdTe layer on a clean surface of a Si substrate, the clean surface of the Si substrate is subjected to an irradiation of As at a temperature in the range of about 650.degree. C. to about 800.degree. C. so that Si atoms on terrace of the clean surface are replaced by As atoms, followed by carrying out a molecular beam epitaxy to grow a CdTe layer on the surface. It is preferable that the clean surface is subjected to an irradiation of Cd in addition to the irradiation of As.Type: GrantFiled: October 3, 1995Date of Patent: June 2, 1998Assignee: NEC CorporationInventor: Masaya Kawano
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Patent number: 5753040Abstract: In one form of the invention, a method for the growth of an epitaxial insulator-metal structure on a semiconductor surface comprising the steps of maintaining the semiconductor surface at a pressure below approximately 1.times.10.sup.-7 mbar, maintaining the semiconductor surface at a substantially fixed first temperature between approximately 25.degree. C. and 400.degree. C., depositing an epitaxial metal layer on the semiconductor surface, adjusting the semiconductor surface to a substantially fixed second temperature between approximately 25.degree. C. and 200.degree. C., starting a deposition of epitaxial CaF.sub.2 on the first metal layer, ramping the second temperature to a third substantially fixed temperature between 200.degree. C. and 500.degree. C. over a time period, maintaining the third temperature until the epitaxial CaF.sub.2 has deposited to a desired thickness, and stopping the deposition of epitaxial CaF.sub.2 on the first metal layer.Other devices, systems and methods are also disclosed.Type: GrantFiled: June 7, 1995Date of Patent: May 19, 1998Assignee: Texas Instruments IncorporatedInventor: Chih-Chen Cho
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Patent number: 5741360Abstract: In a method of selectively growing a crystal of a compound semiconductor layer which is composed of gallium and arsenic, a selective growth is selectively carried out on a substrate by using a combination of metallic gallium and a reactive gas, such as trisdimethylminoarsine, which includes a metallic compound of arsenic specified by at least one amine. The combination may includes organometallic gallium, such as trimethylgallium, triethylgallium instead of the metallic gallium. Such a combination serves to selectively deposit the compound semiconductor layer only on an exposed portion uncovered with a mask. Any other compound semiconductor layer may be selectively deposited on the exposed portion. The exposed portion may be composed of GaAs, AlGaAs, or InGaAs.Type: GrantFiled: August 11, 1995Date of Patent: April 21, 1998Assignee: Optoelectronics Technology Research CorporationInventors: Shigeo Goto, Yasuhiko Nomura, Yoshitaka Morishita, Seikoh Yoshida, Masahiro Sasaki
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Patent number: 5733370Abstract: A magnetic recording medium comprising a magnetic alloy layer having a bicrystal cluster microstructure and, hence, reduced medium noise, is formed by depositing a seed layer on a glass or a glass-ceramic material substrate, oxidizing the seed layer, depositing an underlayer, such as chromium, on the oxidized seed layer, whereby the underlayer exhibits a (200) crystallographic orientation. A magnetic alloy epitaxially grown on the underlayer having a (200) crystallographic orientation exhibits a bicrystal cluster microstructure.Type: GrantFiled: January 16, 1996Date of Patent: March 31, 1998Assignee: Seagate Technology, Inc.Inventors: Ga-Lane Chen, Qixu Chen
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Patent number: 5714006Abstract: A method of growing a compound semiconductor layer includes epitaxially growing a III-V compound semiconductor layer including nitrogen (N) for as the Group V element on a front surface of a semiconductor substrate of cadmium telluride (CdTe). Therefore, the atoms of the crystal lattice of the III-V compound semiconductor layer are periodically lattice-matched with the atoms of the crystal lattice of the CdTe semiconductor substrate, whereby the III-V compound semiconductor layer is epitaxially grown with high crystalline quality.Type: GrantFiled: December 18, 1995Date of Patent: February 3, 1998Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Hirotaka Kizuki, Yasutomo Kajikawa
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Patent number: 5714008Abstract: Apparati and methods for varying the flux of a molecular beam emanating from an effusion cell are disclosed. The apparatus includes a means for controllably adjusting the angular distribution of a molecular field effusing from a source material within the effusion cell, therein adjusting the flux of the beam. The method herein disclosed, with respect to the related apparati, including the step of selectively altering the angular distribution of an effusing molecular field, produced by a heated source material, which comprises the molecular beam, thereby varying the flux of the beam.Type: GrantFiled: April 29, 1996Date of Patent: February 3, 1998Assignee: Northrop Grumman CorporationInventors: Myung B. Lee, Jari Vanhatalo
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Patent number: 5705224Abstract: A vapor deposition apparatus and method in which pulse waveform light is applied to a sample sealed in a reaction chamber. The sample is exposed to gaseous material while the pulse waveform light is applied creating one or plural atomic layers. Alternate layers of plural substances or alternate multiple layers of plural substances can be formed by alternating the introduction of gaseous materials with the application of pulse waveform light.Type: GrantFiled: January 31, 1995Date of Patent: January 6, 1998Assignee: Kokusai Electric Co., Ltd.Inventors: Junichi Murota, Shoichi Ono, Masao Sakuraba, Nobuo Mikoshiba, Harushige Kurokawa, Fumihide Ikeda
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Patent number: 5693140Abstract: A process and structure wherein optical quality perovskites, such as BaTiO.sub.3 or SrTiO.sub.3, are grown upon a single crystal MgO substrate involves the epitaxial build up of alternating planes of TiO.sub.2 and metal oxide wherein the first plane grown upon the MgO substrate is a plane of TiO.sub.2. The layering sequence involved in the film build up reduces problems which would otherwise result from the interfacial electrostatics at the first atomic layers, and these oxides can be stabilized as commensurate thin films at a unit cell thickness or grown with high crystal quality to thicknesses of 0.5-0.7 .mu.m for optical device applications.Type: GrantFiled: September 18, 1995Date of Patent: December 2, 1997Assignee: Lockheed Martin Energy Systems, Inc.Inventors: Rodney Allen McKee, Frederick Joseph Walker
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Patent number: 5690737Abstract: A process for growing single crystal epitaxial BaF.sub.2 layers on gallium rsenide substrates by slowly reacting Ba, BaCl.sub.2, Bal.sub.2, BaBr.sub.2, BaF.sub.2 .cndot.BaCl.sub.2, BaF.sub.2 .cndot.BaBr.sub.2, BaF.sub.2 .cndot.BaI.sub.2, BaCl.sub.2 .cndot.BaBr.sub.2, Ba.sub.3 (GaF.sub.6).sub.2, BAH.sub.2, or BaO.sub.2 vapor with a clean, hot GaAs substrate at 500.degree. C. to 700.degree. C. in high vacuum until a uniform, thin (.about.12 .ANG.) layer of reaction product is formed and then vapor depositing BaF.sub.2 onto the reaction layer at room temperature to 400.degree. C. to form the single crystal, epitaxial BaF.sub.2 layer.Type: GrantFiled: May 31, 1995Date of Patent: November 25, 1997Assignee: The United States of America as represented by the Secretary of the NavyInventors: Francisco Santiago, Tak-Kin Chu, Michael Stumborg
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Patent number: 5660697Abstract: An electroluminescent display device with decreased voltage requirements comprises:(a) a substrate having a major surface;(b) a first electrode disposed over the major surface of the substrate;(c) a first insulating film disposed over the first electrode;(d) a light-emitting film disposed over the first insulating film;(e) a second insulating film disposed over the light-emitting film; and(f) a second electrode disposed over the second insulating film. The insulating films have a columnar structure oriented perpendicular to an electric field formed between the two electrodes, and either of the insulating films may be omitted.Type: GrantFiled: June 2, 1995Date of Patent: August 26, 1997Assignee: Fuji Electric Co., Ltd.Inventors: Tomoyuki Kawashima, Harutaka Taniguchi, Hisato Kato, Kazuyoshi Shibata
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Patent number: 5660628Abstract: There is provided a method for suppressing generation of cracks or damages on a compound semiconductor epitaxial wafer during an epitaxial growth due to growth of an epitaxial layer on the rear surface at the edge of the epitaxial layer which is located at the upstream side of the flow of the source gas. In manufacturing a semiconductor wafer by growing a single crystal semiconductor epitaxial layer having a zinc blend structure on a single crystal semiconductor substrate having a zinc blend structure, the surface of the single crystal semiconductor substrate has (100) surface orientation having an off angle and a source gas is supplied in the direction of the off angle or in a direction at 30.degree. or less to the direction at 180.degree. thereto.Type: GrantFiled: August 18, 1994Date of Patent: August 26, 1997Assignee: Mitsubishi Kasei Corp.Inventors: Tadashige Sato, Hitora Takahashi
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Patent number: 5657335Abstract: Several methods have been found to make p-type gallium nitride. P-type gallium nitride has long been sought for electronic devices. N-type gallium nitride is readily available. Discovery of p-type gallium nitride and the methods for making it will enable its use in ultraviolet and blue light-emitting diodes and lasers. pGaN will further enable blue photocathode elements to be made. Molecular beam epitaxy on substrates held at the proper temperatures, assisted by a nitrogen beam of the proper energy produced several types of p-type GaN with hole concentrations of about 5.times.10.sup.11 /cm.sup.3 and hole mobilities of about 500 cm.sup.2 /V-sec, measured at 250.degree. K. P-type GaN can be formed of unintentionally-doped material or can be doped with magnesium by diffusion, ion implantation, or co-evaporation. When applicable, the nitrogen can be substituted with other group III elements such as Al.Type: GrantFiled: November 1, 1993Date of Patent: August 12, 1997Assignee: The Regents, University of CaliforniaInventors: Michael Rubin, Nathan Newman, Tracy Fu, Jennifer Ross, James Chan
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Patent number: 5656538Abstract: A process for growing semi-insulating layers of indium phosphide and other group III-V materials through the use of halide dopant or etchant introduction during growth. Gas phase epitaxial growth techniques are utilized at low temperatures to produce indium phosphide layers having a resistivity greater than approximately 10.sup.7 ohm-cm. According to the preferred embodiment carbon tetrachloride is used as a dopant at flow rates above 5 sccm to grow the layers with substrate growth temperatures ranging from approximately 460.degree. C. to 525.degree. C. This temperature range provides an advantage over the transition metal techniques for doping indium phosphide since the high temperatures generally required for those techniques limit the ability to control growth. Good surface morphology is also obtained through the growth according to the present invention. The process may be used to form many types of group III-V semiconductor devices.Type: GrantFiled: March 24, 1995Date of Patent: August 12, 1997Assignee: The Board of Trustees of the University of IllinoisInventors: Nathan F. Gardner, Stephen A. Stockman, Quesnell J. Hartmann, Gregory E. Stillman
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Patent number: 5648127Abstract: Energy, such as from one or more lasers, is directed at the surface of a substrate to mobilize and vaporize a constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. An additional secondary element, which can be the same as or different from the constituent element, may optionally be directed (e.g., sprayed) onto the substrate to augment, enhance and/or modify the formation of the composite material, as well as to supply sufficient or additional material for fabricating one or more coatings on the surface of the substrate. The process can be carried out in an ambient environment (e.g., without a vacuum), and without pre-heating or post-cooling of the substrate. Articles formed by the disclosed processes are described, including three-dimensional objects.Type: GrantFiled: June 5, 1995Date of Patent: July 15, 1997Assignee: QQC, Inc.Inventors: Manuel C. Turchan, Pravin Mistry
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Patent number: 5645638Abstract: The present invention has been achieved by perceiving the fact to the effect that a semiconductor production process-like manner such as CVD method or the like by which materials and film thickness can be controlled in an atomic scale may be utilized in case of preparing thin-film crystal, and employing such semiconductor production process-like manner being quite different from conventional technique.Type: GrantFiled: January 29, 1996Date of Patent: July 8, 1997Assignee: Rikagaku KenkyushoInventors: Hiroshi Kumagai, Kouichi Toyoda
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Patent number: 5637530Abstract: Epitaxial layers of II-VI semiconductor compounds having low incidence of lattice defects such as stacking faults are produced by first depositing a fraction of a monolayer of the cation species of the compound, followed by depositing a thin layer of the compound by migration enhanced epitaxy (MEE). Growth of the remainder of the layer by MBE results in much lower defects than if the entire layer had been grown by MBE. Layers are useful in devices such as LEDs and injection lasers.Type: GrantFiled: June 10, 1996Date of Patent: June 10, 1997Assignee: U.S. Philips CorporationInventors: James M. Gaines, John Petruzzello
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Patent number: 5637146Abstract: A method for the growth of semiconducting nitrides, such as GaN, InN, AlN, and their alloys, in an ultra-high vacuum chamber, wherein low energy atomic nitrogen is generated by a plasma-excited radical atom source, the atom beam is introduced to the heated substrate within a short distance, other gaseous reactants and dopants, such as TMGa, TMIn, TMAj, DEZn, CP.sub.2 Mg, SiH.sub.4, and similar organmetallic and hydride sources, are injected from a circular injector located between the substrate and the atom source, and therefore large area epitaxy with high growth rate is obtained.Type: GrantFiled: March 30, 1995Date of Patent: June 10, 1997Assignees: Saturn Cosmos Co., Ltd., Jen-Inn ChyiInventor: Jen-Inn Chyi
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Patent number: 5635243Abstract: Energy, such as from one or more lasers, is directed at the surface of a substrate to mobilize and vaporize a constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. An additional secondary element, which can be the same as or different from the constituent element, may optionally be directed (e.g., sprayed) onto the substrate to augment, enhance and/or modify the formation of the composite material, as well as to supply sufficient or additional material for fabricating one or more coatings on the surface of the substrate. The process can be carried out in an ambient environment (e.g., without a vacuum), and without pre-heating or post-cooling of the substrate. Articles formed by the disclosed processes are described, including three-dimensional objects.Type: GrantFiled: June 5, 1995Date of Patent: June 3, 1997Assignee: QQC, Inc.Inventors: Manuel C. Turchan, Pravin Mistry
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Patent number: 5633193Abstract: Heteroepitaxial growth of phosphorus-containing III/V semiconductor material (e.g., InGaAsP) on a non-planar surface of a different phosphorus-containing III/V semiconductor material (e.g., InP) is facilitated by heating the non-planar surface in a substantially evacuated chamber to a mass-transport temperature, and exposing the surface to a flux of at least phosphorus form a solid phosphorus source. This mass-transport step is followed by in situ growth of the desired semiconductor material, with at least an initial portion of the growth being done at a first growth temperature that is not greater than the mass transport temperature. Growth typically is completed at a second growth temperature higher than the first growth temperature. A significant aspect of the method is provision of the required fluxes (e.g., phosphorus, arsenic, indium, gallium) from solid sources, resulting in hydrogen-free mass transport and growth, which can be carried out at lower temperatures than is customary in the prior art.Type: GrantFiled: May 22, 1996Date of Patent: May 27, 1997Assignee: Lucent Technologies Inc.Inventors: James N. Baillargeon, Alfred Y. Cho, Sung-Nee G. Chu, Wen-Yen Hwang
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Patent number: 5633194Abstract: A low temperature ion-beam assisted deposition process, comprising the steps of cleaning at least one substrate, subjecting the substrate to a vacuum of at least 2.times.10.sup.-4 Torr, heating the substrate to a temperature of at least 280.degree. C., and directing an ion beam at the substrate, wherein the ion beam comprises ion-associated gas molecules of Si or Ge, so as to grow a thin epitaxial film of Si or Ge on the substrate.Type: GrantFiled: April 19, 1995Date of Patent: May 27, 1997Assignee: The University of WaterlooInventors: C. R. Selvakumar, S. Mohajerzadeh, D. E. Brodie
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Patent number: 5633192Abstract: An epitaxial growth system comprises a housing around an epitaxial growth chamber. A substrate support is located within the growth chamber. A gallium source introduces gallium into the growth chamber and directs the gallium towards the substrate. An activated nitrogen source introduces activated nitrogen into the growth chamber and directs the activated nitrogen towards the substrate. The activated nitrogen comprises ionic nitrogen species and atomic nitrogen species. An external magnet and/or an exit aperture control the amount of atomic nitrogen species and ionic nitrogen species reaching the substrate.Type: GrantFiled: January 13, 1995Date of Patent: May 27, 1997Assignee: Boston UniversityInventors: Theodore D. Moustakas, Richard J. Molnar
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Patent number: 5620512Abstract: A method and system for manufacturing diamond film. The method involves forming a fullerene vapor, providing a noble gas stream and combining the gas with the fullerene vapor, passing the combined fullerene vapor and noble gas carrier stream into a chamber, forming a plasma in the chamber causing fragmentation of the fullerene and deposition of a diamond film on a substrate.Type: GrantFiled: October 27, 1993Date of Patent: April 15, 1997Assignee: University of ChicagoInventors: Dieter M. Gruen, Shengzhong Liu, Alan R. Krauss, Xianzheng Pan
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Patent number: 5616179Abstract: A process for depositing amorphous or nanophase diamondlike carbon (DLC) and a-C:H carbon/hydrogen films with variable and controllable properties on the surface of a substrate is disclosed. The process utilizes a combined hydrocarbon ion beam and plasma-activated hydrocarbon gaseous radical flux produced by an end-Hall ion source to yield a film with good electron-emissivity characteristics or high hardness and good optical transparency, as desired. A second ion source providing a beam of argon ions above or together in nitrogen is optionally directed at the substrate for cleaning prior to deposition and for ion-assisted deposition during deposition or for doping.Type: GrantFiled: December 21, 1993Date of Patent: April 1, 1997Assignee: Commonwealth Scientific CorporationInventors: David A. Baldwin, Stephen L. Michel
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Patent number: 5616177Abstract: In a Group II-VI semiconductor laser based on MgZnSSe, CdZnSSe, and MgCdZnSSe, adsorption layers containing crystal structure elements and doping impurities are successively grown as crystals on an n-type substrate, wherein the layers from the initial adsorption layer to the next-to-last p-type adsorption layer are formed using solid-source MBE, and the last p-type adsorption layer is formed using gas-source MBE or MOVPE; and wherein the last p-type adsorption layer is preferably grown under Group II rich conditions.Type: GrantFiled: February 22, 1995Date of Patent: April 1, 1997Assignee: Hewlett-Packard CompanyInventor: Norihide Yamada
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Patent number: 5607560Abstract: A diamond crystal forming method with which a diamond crystal is formed on a substrate by a sputtering process uses high-frequency energy in the frequency range of 40 MHz to 250 MHz to form plasma.Type: GrantFiled: October 10, 1995Date of Patent: March 4, 1997Assignee: Canon Kabushiki KaishaInventors: Keiji Hirabayashi, Atsushi Yamagami
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Patent number: 5603765Abstract: High breakdown voltages for AlInAs layers in InP-based devices, such as a gate layer in an InP HEMT or a collector layer in a heterojunction bipolar transistor, are achieved by growing the AlInAs layer by MBE at a substrate temperature about 70.degree.-125.degree. C. below the temperature at which a 2.times.4 reflective high energy diffraction pattern is observed. This corresponds to a growth temperature range of about 415.degree.-470.degree. C. for a 540.degree. 2.times.4 reconstruction temperature. Preferred growth temperatures within these ranges are 80.degree. C. below the 2.times.4 reconstruction temperature, or about 460.degree. C. Higher breakdown voltages are obtained than when the AlInAs layer is grown at either higher or lower temperatures.Type: GrantFiled: April 21, 1995Date of Patent: February 18, 1997Assignee: Hughes Aircraft CompanyInventors: Mehran Matloubian, Linda M. Jelloian, Mark Lui, Takyiu Liu
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Patent number: 5603766Abstract: A method for making oriented thin films of a ternary intermetallic compound and such films having a tetragonal structure and generally uniaxial magnetic, optical, electronic, and mechanical properties, as well as a generally lower Curie temperature than oriented binary intermetallic films. The steps of the method involve selecting a substrate material for biasing the orientation of the ternary intermetallic compound and exhibiting no chemical reactiveness to the ternary intermetallic compound. Preferably, such substrate is a single crystal, such as MgO or Al.sub.2 O.sub.3, or an amorphous material such as pure SiO.sub.2, amorphous carbon, or glass. In a second step the substrate is heated to a temperature above 450.degree. C. and then, a first metal, a second metal, and a third metal are simultaneously deposited on the substrate material.Type: GrantFiled: February 23, 1995Date of Patent: February 18, 1997Assignee: Board of Trustees of the Stanford Leland Junior UniversityInventors: Mark R. Visokay, Bruce M. Lairson, Robert Sinclair
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Patent number: 5599389Abstract: According to this invention, there is provided a compound semiconductor substrate including, on a compound semiconductor base containing a high-concentration impurity, a high-resistance single-crystal layer consisting of the same compound semiconductor as the compound semiconductor constituting the base. Active elements are formed in the high-resistance single-crystal layer.Type: GrantFiled: November 14, 1994Date of Patent: February 4, 1997Assignee: Kabushiki Kaisha ToshibaInventor: Hiroshi Iwasaki
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Patent number: 5588995Abstract: A system for monitoring the growth of crystalline films on stationary or rotating substrates includes a combination of some or all of the elements including a photodiode sensor for detecting the intensity of incoming light and converting it to a measurable current, a lens for focusing the RHEED pattern emanating from the phosphor screen onto the photodiode, an interference filter for filtering out light other than that which emanates from the phosphor screen, a current amplifier for amplifying and convening the current produced by the photodiode into a voltage, a computer for receiving the amplified photodiode current for RHEED data analysis, and a graphite impregnated triax cable for improving the signal to noise ratio obtained while sampling a stationary or rotating substrate. A rotating stage for supporting the substrate with diametrically positioned electron beam apertures and an optically encoded shaft can also be used to accommodate rotation of the substrate during measurement.Type: GrantFiled: May 3, 1995Date of Patent: December 31, 1996Assignee: Midwest Research InstituteInventor: Peter Sheldon
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Patent number: 5565030Abstract: A novel method is proposed for the preparation of a superlattice multilayered film, which has a multilayered structure alternately consisting of epitaxially grown layers of a metal and layers of a metal oxide formed on the surface of a substrate and is useful as high-speed electronic devices, soft X-ray reflectors, neutron beam polarizers and the like. According to the discovery leading to this invention, good epitaxial growth of the layers can be accomplished when the metal has a face-centered cubic lattice structure and the metal oxide has a sodium chloride-type cubic lattice structure and the difference in the lattice constant between the metal and the metal oxide is small enough as in the combinations of silver and nickel oxide or magnesium oxide and nickel and nickel oxide.Type: GrantFiled: March 9, 1995Date of Patent: October 15, 1996Assignee: Japan as represented by Director General of Agency of Industrial Science and TechnologyInventors: Tetsuo Kado, Shigeyuki Yamamoto
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Patent number: 5561088Abstract: In a heating method for semiconductor devices, gas is filled in a heat chamber in which a heat target (semiconductor device) is mounted, and then the gas is compressed to produce heat. The heat target is heated to a desired temperature by the produced heat. Before the gas compression is performed, the heat target is preferably pre-heated by a heater.Type: GrantFiled: January 30, 1995Date of Patent: October 1, 1996Assignee: Sony CorporationInventor: Toshiyuki Sameshima
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Patent number: 5558711Abstract: An electrode forming method for a surface acoustic wave device is adapted to form a film of an electrode material on a piezoelectric substrate to be crystallographically oriented in a constant direction while carrying out ion assistance at prescribed ion energy, in a film formation process employing a film forming method such as evaporation, sputtering, IBS (ion beam sputtering), CVD (chemical vapor deposition), plasma CVD, MBE (molecular beam epitaxy), ICB (ionized cluster beam) or laser ablation.Type: GrantFiled: December 5, 1994Date of Patent: September 24, 1996Assignee: Murata Manufacturing Co., Ltd.Inventor: Atsushi Sakurai
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Patent number: 5554415Abstract: Energy, such as from one or more lasers, is directed at the surface of a substrate to mobilize and vaporize a constituent element (e.g., carbide) within the substrate (e.g., steel). The vaporized constituent element is reacted by the energy to alter its physical structure (e.g., from carbon to diamond) to that of a composite material which is diffused back into the substrate as a composite material. An additional secondary element, which can be the same as or different from the constituent element, may optionally be directed (e.g., sprayed) onto the substrate to augment, enhance and/or modify the formation of the composite material, as well as to supply sufficient or additional material for fabricating one or more coatings on the surface of the substrate. The process can be carried out in an ambient environment (e.g., without a vacuum), and without pre-heating or post-cooling of the substrate.Type: GrantFiled: January 18, 1994Date of Patent: September 10, 1996Assignee: QQC, Inc.Inventors: Manuel C. Turchan, Pravin Mistry
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Patent number: 5544618Abstract: An apparatus for depositing a coating on a substrate substantially eliminates the occurrence of oval defects by creating a heated tortuous path through which the source material vapors must travel before depositing on the substrate. In addition, shut-off valves for each of the source materials are positioned in the reaction chamber in close proximity to the substrate, thereby enabling layers of different compositions to be deposited with sharp transitions between adjacent layers. The apparatus may be used to efficiently coat large areas uniformly, and works equally well with either elemental or chemical source materials, or certain combinations of both. The features of the coating apparatus may be embodied in replacement source cells for retrofitting in conventional molecular beam and chemical beam epitaxy units.Type: GrantFiled: May 23, 1994Date of Patent: August 13, 1996Inventors: Richard A. Stall, Gary S. Tompa, Alexander Gurary, Craig R. Nelson
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Patent number: 5537951Abstract: A crystal growth method is based on a molecular beam epitaxy method. The crystal growth method includes the steps of opening/closing a shutter member provided between a deposition source and a substrate in an ultra-high vacuum so as to form a region having a predetermined pattern on the substrate and forming a crystal growth layer only in the region having the pattern on the substrate during an epitaxial growth step.Type: GrantFiled: January 11, 1995Date of Patent: July 23, 1996Assignee: NEC CorporationInventor: Hideaki Saito
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Patent number: 5531184Abstract: The present invention provides a method for producing a synthetic diamond thin film which comprises decomposing with microwave a raw material gas containing at least one compound selected from the group consisting of carbon monoxide, carbon dioxide and a hydrocarbon and hydrogen or hydrogen and oxygen to produce a plasma and contacting the plasma with the surface of a substrate held outside the area irradiated with the microwave to form a diamond thin film on the substrate.The present invention further provides an apparatus for producing a synthetic diamond thin film and a synthetic diamond thin film and devices in which the synthetic diamond thin film is used.Type: GrantFiled: December 13, 1993Date of Patent: July 2, 1996Assignee: Hitachi, Ltd.Inventors: Yasushi Muranaka, Hisao Yamashita, Hiroshi Miyadera
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Patent number: 5529949Abstract: Thin films of 2H .alpha.-silicon carbide are produced by pulsed laser ablation.Type: GrantFiled: March 17, 1994Date of Patent: June 25, 1996Assignee: Kent State UniversityInventors: Mark A. Stan, Martin O. Patton, Joseph D. Warner
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Patent number: 5512541Abstract: The present invention is directed to a method for growing a superconductive film on a superconductive substrate in order to produce a bulk single crystal. According to a preferred embodiment, an oxide superconductive film of a material which is the same or similar to the substrate material is epitaxially grown at a temperature between 450.degree. C. and 800.degree. C. so that the film and substrate have the same lattice orientations. According to the present invention, problems associated with conventional films having non-superconductor substrates (e.g., MgO and SrTiO.sub.3) are avoided.Type: GrantFiled: September 12, 1994Date of Patent: April 30, 1996Assignees: Sumitomo Electric Industries, Ltd., International Superconductivity Technology CenterInventors: Masaya Konishi, Kunihiko Hayashi, Youichi Enomoto, Shoji Tanaka, Yasuji Yamada, Kanshi Ohtsu, Yasuo Kanamori, Yuh Shiohara
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Patent number: 5509189Abstract: An electrochemical device including a solid electrolyte and solid electrode composed of materials having different chemical compositions and characterized by different electrical properties but having the same crystalline phase is provided. A method for fabricating an electrochemical device having a solid electrode and solid electrolyte characterized by the same crystalline phase is provided.Type: GrantFiled: December 15, 1994Date of Patent: April 23, 1996Assignee: Massachusetts Institute of Technology, a MA corp.Inventors: Harry L. Tuller, Steve A. Kramer, Marlene A. Spears, Uday B. Pal
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Patent number: 5505159Abstract: In an epitaxial growth of a group III-V compound semiconductor crystal, there is provided a substrate on which group III element halide molecules are adsorbed. A beam of group V element hydride molecules is supplied toward the substrate for reaction of the group V element hydride and the group III element halide. The vibration energy of each of group V element hydride molecules is excited in the beam and the orientation of the group V element hydride molecules is aligned. As a result, the supplied group V atom directly combines with the group III atom.Type: GrantFiled: November 17, 1994Date of Patent: April 9, 1996Assignee: NEC CorporationInventors: Yuji Mochizuki, Akira Usui, Toshikazu Takada
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Patent number: 5501175Abstract: A process for preparing an oxide thin film which has a crystalline, clean and smooth surface on a substrate. The process is conducted by using an apparatus comprising a vacuum chamber in which an oxidizing gas of O.sub.2 including O.sub.3 can be supplied near the substrate so that pressure around the substrate can be increased while maintaining high vacuum near an evaporation source and Knudsen cell evaporation sources arranged in the vacuum chamber wherein the substrate is heated, molecular beam of constituent atoms of the oxide excluding oxygen are supplied from the K cell evaporation sources and an oxidizing gas is locally supplied to the vicinity of the substrate.Type: GrantFiled: July 1, 1994Date of Patent: March 26, 1996Assignee: Sumitomo Electric Industries, Ltd.Inventors: So Tanaka, Michitomo Iiyama
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Patent number: 5501174Abstract: Single crystal aluminum is deposited on SiGe structures to form metal interconnects. Generally, a method of forming single crystal aluminum on Si.sub.(1-x) Ge.sub.x is presented, including the steps of maintaining the substrate at certain temperature (e.g. between 300.degree. C. and 400.degree. C.) and pressure conditions (e.g. below 2.times.10.sup.-9 millibar) while aluminum atoms are deposited by a vacuum evaporation technique. This is apparently the first method of depositing single crystal aluminum on SiGe surfaces. Novel structures are made possible by the invention, including epitaxial layers 34 formed on single crystal aluminum 32 which has been deposited on SiGe 30. Among the advantages made possible by the methods presented are thermal stability and resistance to electromigration.Type: GrantFiled: April 7, 1994Date of Patent: March 26, 1996Assignee: Texas Instruments IncorporatedInventors: Chih-Chen Cho, Hung-Yu Liu
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Patent number: 5492080Abstract: A crystal-growth method includes a process of filling three materials separately, one being selected from a group consisting of elemental Mg, MgS and MgSe compounds, and the other two being ZnSe and ZnS compounds, in their respective effusion cells, and a crystal-growth process of a Zn.sub.1-Y Mg.sub.Y S.sub.Z Se.sub.1-Z (0<Y>1 and 0<Z>1) single-crystalline thin film on a heated substrate by controlling the temperatures of the effusion cells and the molecular beam intensities.Type: GrantFiled: December 21, 1994Date of Patent: February 20, 1996Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Kazuhiro Ohkawa, Tsuneo Mitsuyu
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Patent number: 5483920Abstract: A novel method of forming large area single crystal cubic boron nitride films on a silicon substrate by first treating the surface of the substrate with atomic hydrogen and then depositing a cubic boron nitride film by a reactive biased laser ablation technique.Type: GrantFiled: August 5, 1993Date of Patent: January 16, 1996Assignee: Board of Governors of Wayne State UniversityInventor: Roger W. Pryor
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Patent number: 5482003Abstract: A process and structure involving a silicon substrate utilize molecular beam epitaxy (MBE) and/or electron beam evaporation methods and an ultra-high vacuum facility to grow a layup of epitaxial alkaline earth oxide films upon the substrate surface. By selecting metal constituents for the oxides and in the appropriate proportions so that the lattice parameter of each oxide grown closely approximates that of the substrate or base layer upon which oxide is grown, lattice strain at the film/film or film/substrate interface of adjacent films is appreciably reduced or relieved.Type: GrantFiled: July 6, 1993Date of Patent: January 9, 1996Assignee: Martin Marietta Energy Systems, Inc.Inventors: Rodney A. McKee, Frederick J. Walker
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Patent number: 5477809Abstract: The invention provides an epitaxial growth method of CdTe on silicon by molecular beam epitaxy in which a Si(221) tilted by 6.degree. or less toward [-1 -1 4] is used, whose surface is rinsed in an ultra high vacuum for a subsequent epitaxial growth of CdTe on the rinsed surface of the Si(221)off substrate. The invention also provides an epitaxial growth method of CdTe on silicon by molecular beam epitaxy in which a silicon substrate is used, whose surface is rinsed for a Cd irradiation on the rinsed silicon surface and a subsequent epitaxial growth of CdTe thereon by molecular beam epitaxy. The Cd irradiation on the rinsed surface of the silicon may be carried out at a temperature in the range of from 670.degree. C. to 750.degree. C. Further, the Cd irradiation on the rinsed surface of the silicon is continued until an entire surface of the silicon is completely covered with CdTe in an epitaxial growth of CdTe by molecular beam epitaxy.Type: GrantFiled: June 23, 1994Date of Patent: December 26, 1995Assignee: NEC CorporationInventor: Masaya Kawano
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Patent number: 5476811Abstract: A method of growing a plurality of epitaxial layers each having a property which is different from each other simultaneously on a common substrate comprises steps of forming at least a first crystal surface and a second crystal surface which are crystallographically non-equivalent to each other on the substrate, introducing particles comprising constituent elements of the epitaxial layers into a region in the vicinity of the substrate, the particles including at least metal-organic molecules containing one of the elements constituting the epitaxial layers, decomposing the metal-organic molecules such that the layer constituting element therein is released as a result of the decomposition, and depositing the aforesaid particles including the element released by the decomposition of the metal-organic molecules on the first and second crystal surfaces so that a first epitaxial layer and a second epitaxial layer, respectively differing in properties from each other, are grown on respective the first and second crType: GrantFiled: March 23, 1995Date of Patent: December 19, 1995Assignee: Fujitsu LimitedInventors: Toshio Fujii, Adarsh Sandhu
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Patent number: 5471948Abstract: A doped or undoped photoresponsive material having metallic precipitates, and a PiN photodiode utilizing the material for detecting light having a wavelength of 1.3 micrometers. The PiN photodiode includes a substrate having a first compound semiconductor layer disposed thereon. The PiN photodiode further includes an optically responsive compound semiconductor layer disposed above the first compound semiconductor layer. The optically responsive layer includes a plurality of buried Schottky barriers, each of which is associated with an inclusion within a crystal lattice of a Group III-V material. The PiN device also includes a further compound semiconductor layer disposed above the optically responsive layer. For a transversely illuminated embodiment, waveguiding layers may also be disposed above and below the PiN structure. In one example the optically responsive layer is comprised of GaAs:As.Type: GrantFiled: May 11, 1994Date of Patent: December 5, 1995Assignees: International Business Machines Corporation, Purdue Research FoundationInventors: Jeremy Burroughes, Rodney T. Hodgson, David T. McInturff, Michael R. Melloch, Nobuo Otsuka, Paul M. Solomon, Alan C. Warren, Jerry M. Woodall
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Patent number: 5463977Abstract: In a method of and an apparatus for epitaxially growing a chemical-compound crystal, a plurality of raw-material gasses are alternately introduced into a closed chamber of a crystal growing device to grow the crystal placed within the closed chamber. At growing of the crystal, a light from a light source is emitted to a crystal growing film of the crystal. Intensity of a light reflected from the crystal growing film and received by a photo detector is measured. Charge amounts of the respective raw-material gasses are controlled by a control system on the basis of a change in the reflected-light intensity, thereby controlling a growing rate of the growing film.Type: GrantFiled: July 15, 1993Date of Patent: November 7, 1995Assignees: Research Development Corporation, Nobuaki Manada, Toru Kurabayashi, Jun-Ichi NishizawaInventors: Nobuaki Manada, Junji Ito, Toru Kurabayashi, Jun-ichi Nishizawa
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Patent number: 5462012Abstract: A novel substrate for growth of material by chemical phase deposition includes a temperature monitoring zone formed by applying a coating of growth preventing material (e.g., SiO.sub.x or SiN.sub.x) to a portion of the substrate. The temperature of the substrate can be monitored during growth of a desired material using an optical pyrometer having its field of view directed at the temperature monitoring zone.Type: GrantFiled: November 29, 1994Date of Patent: October 31, 1995Assignee: AT&T Corp.Inventor: Tien-Heng Chiu