Contains An Atom Of Chromium Patents (Class 148/258)
  • Patent number: 5164235
    Abstract: A process for imparting tarnish resistance to copper and copper alloy materials, particularly copper foil. The material is first treated with an acidic chromium-containing solution to deposit chromium ions on said foil. Thereafter the material is treated with a basic zinc ion containing solution to deposit zinc ions thereon. Finally, the material is rinsed in distilled water to remove any residual basic solution.
    Type: Grant
    Filed: March 6, 1990
    Date of Patent: November 17, 1992
    Assignee: Olin Corporation
    Inventor: Chung-Yao Chao
  • Patent number: 5141575
    Abstract: Zinciferous surfaces, particularly those of galvanized steel, may be effectively protected against corrosion, either as treated or after painting, while remaining easy to weld, by contact with an aqueous solution containing chromium in both +6 and +3 valence states, phosphate, a tertiary alcohol or similar oxidation stable, water soluble organic compound as a wetting agent, and a silane coupling agent, followed by drying with a film from the solution still in place on the surface. A thin coating containing 10-200 mg/m.sup.2 of chromium is formed on the surface to provide a protective layer that is also an excellent base for paint.
    Type: Grant
    Filed: April 5, 1990
    Date of Patent: August 25, 1992
    Assignee: Henkel Corporation
    Inventors: Noriaki Yoshitake, Kenshi Saeki, Takumi Honda, Takao Ogino
  • Patent number: 5091023
    Abstract: The resistance of chromated zinc surfaced steel objects, particularly plates and sheets, to extraction of hexavalent chromium by alkaline degreasing solutions used on the chromated objects, can be substantially increased by utilizing an aqueous acidic liquid chromating composition containing (A) about 9.6 to about 96 g/L, expressed as its stoichiometric equivalent as chromic acid, of total chromium; (B) about 2 to about 35 g/L of trivalent chromium ions; (C) about 1 to about 128 g/L of phosphate ions; and (D) about 0.3 to about 4 g/L of fluorozirconate ions, with the chromium ratio in the aqueous acidic liquid composition being about 0.41 to about 0.70, the chromic acid/fluorozirconate weight ratio being about 10 to about 40, and the PO.sub.4 /Cr.sup.+3 ratio being greater than about 0.03, greater than or equal to about {(9.2) (the chromium ratio)-4.0}, and less than or equal to about {(9.2) (the chromium ratio)-1.2}. . .
    Type: Grant
    Filed: September 27, 1990
    Date of Patent: February 25, 1992
    Assignee: Henkel Corporation
    Inventors: Kenshi Saeki, Noriaki Yoshitake
  • Patent number: 5066540
    Abstract: A cured coating composition and substrate coated with the cured coating composition which coating is based upon an aqueous acid binder solution containing phosphate and chromate and/or molybdate ions into which has been dispersed a blend of metallic powder particles of three primary dimensions and flat metal flake materials, which can be applied to a substrate part to be coated more uniformly and thickly than conventional metal flake coatings, and which imparts better corrosion and impact resistance than conventional powder metal coatings.
    Type: Grant
    Filed: September 5, 1989
    Date of Patent: November 19, 1991
    Assignee: Sermatech International, Inc.
    Inventors: Mark F. Mosser, Kevin B. Eddinger, William J. Fabiny
  • Patent number: 5039360
    Abstract: A method for coating a metal surface includes heating an untreated metal surface to a temperature of about 40.degree. C. to 250.degree. C. and spraying a coating composition onto the hot untreated metal surface, while continuously moving the metal surface, so that a corrosion resistant coating is formed on the surface, the coating composition having a pH of 0.5 to 1.5 and containing; (a) 20 to 40% by weight acrylic organic polymer in aqueous dispersion; (b) 1 to 5% by weight chromium in a soluble form and selected from the group of hexavalent chromium and mixtures of hexavalent and trivalent chromium wherein the trivalent is about 0.1 to 20% by weight of the total chromium in the mixture; (c) 1.5 to 4% by weight phosphoric acid; and (d) 0.1 to 1.5% by weight organic reducing agent.
    Type: Grant
    Filed: September 12, 1988
    Date of Patent: August 13, 1991
    Assignee: Procoat S.A.
    Inventors: Juan F. Brugarolas, Federico S. Rodellas
  • Patent number: 4975330
    Abstract: A coating composition for providing a part with improved salt spray resistance, which includes undissolved solid hexavalent chromate in an aqueous acid solution which is the reaction product of phosphate ions with ions of the group consisting of chromate or molybdate ions, and their coatings and coated parts.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: December 4, 1990
    Assignee: Sermatech International, Inc.
    Inventor: Mark F. Mosser
  • Patent number: 4971636
    Abstract: A method of producing highly corrosion-resistant surface-treated steel plates where Cr elusion is small in spite of drying at low temperatures and corrosion resistance is excellent. In a process for producing surface treated steels where Zn type plated steels are treated through (i) chromate treatment, (ii) coating a resin composition and (iii) baking treatment, zirconium fluoride ion and Zn ion of appropriate amounts are added into the chromate bath, and Cr.sup.6+ /Cr.sup.3+ ratio in the bath is controlled to be low. Further the resin composition to be coated after the chromate treatment is rendered a solvent type resin composition obtained by adding silica and/or sparingly water soluble Cr compound to basic epoxy resin.
    Type: Grant
    Filed: June 21, 1989
    Date of Patent: November 20, 1990
    Assignee: NKK Corporation
    Inventors: Tsutomu Watanabe, Masaaki Yamashita, Takahiro Kuboto
  • Patent number: 4865653
    Abstract: The present invention relates to a composition and process for metal finishing involving the formation of zinc phosphate coatings of desired morphology on a ferrous surface. The inclusion of a hydroxylamine agent in the phosphating bath expands the range of zinc concentrations over which the desired coating morphology is obtained. Zinc and aluminum surface can also be coated with this composition and process.
    Type: Grant
    Filed: October 30, 1987
    Date of Patent: September 12, 1989
    Assignee: Henkel Corporation
    Inventor: Linda S. Kramer
  • Patent number: 4863516
    Abstract: A coating composition based upon an aqueous acid binder solution containing phosphate and chromate and/or molybdate ions into which has been dispersed a blend of metallic powder particles of three primary dimensions and flat metal flake materials, which can be applied to a substrate part to be coated more uniformly and thickly than conventional metal flake coatings, and which imparts better corrosion and impact resistance than conventional powder metal coatings.
    Type: Grant
    Filed: August 16, 1988
    Date of Patent: September 5, 1989
    Assignee: Sermatech International, Inc.
    Inventors: Mark F. Mosser, Kevin B. Eddinger, William J. Fabiny
  • Patent number: 4838942
    Abstract: Synthetic material substrates are protected against erosion and corrosion by a lacquer type coating which is baked or bonded onto the substrate at relatively low temperatures below 200.degree. C. to protect the synthetic material substrate against damage. The coating is a dispersion of metal powder in an aqueous solution of about equal weight proportions of phosphorous acid and phosphoric acid with an optional weight proportion of not more than 5 percent of aluminum phosphate, and about 10 to 20 weight percent of chromic acid. The remainder is water.
    Type: Grant
    Filed: December 23, 1987
    Date of Patent: June 13, 1989
    Assignee: MTU-Motoren-und Turbinen-Union Muenchen GmbH
    Inventors: Frans Puchinger, Gerhard Wydra
  • Patent number: 4812175
    Abstract: An aqueous acidic treating solution and process for forming a chromium-containing passivate coating on the surface of zinc or zinc-aluminum alloys to enhance bare corrosion resistance and inhibit discoloration thereof upon exposure to ambient environments. The treating solution contains as its essential constituents, chromium ions, nitrate ions, phosphate ions.
    Type: Grant
    Filed: June 10, 1987
    Date of Patent: March 14, 1989
    Assignee: Parker Chemical Company
    Inventor: Gary A. Reghi