Contains An Atom Of Chromium Patents (Class 148/258)
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Patent number: 5164235Abstract: A process for imparting tarnish resistance to copper and copper alloy materials, particularly copper foil. The material is first treated with an acidic chromium-containing solution to deposit chromium ions on said foil. Thereafter the material is treated with a basic zinc ion containing solution to deposit zinc ions thereon. Finally, the material is rinsed in distilled water to remove any residual basic solution.Type: GrantFiled: March 6, 1990Date of Patent: November 17, 1992Assignee: Olin CorporationInventor: Chung-Yao Chao
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Patent number: 5141575Abstract: Zinciferous surfaces, particularly those of galvanized steel, may be effectively protected against corrosion, either as treated or after painting, while remaining easy to weld, by contact with an aqueous solution containing chromium in both +6 and +3 valence states, phosphate, a tertiary alcohol or similar oxidation stable, water soluble organic compound as a wetting agent, and a silane coupling agent, followed by drying with a film from the solution still in place on the surface. A thin coating containing 10-200 mg/m.sup.2 of chromium is formed on the surface to provide a protective layer that is also an excellent base for paint.Type: GrantFiled: April 5, 1990Date of Patent: August 25, 1992Assignee: Henkel CorporationInventors: Noriaki Yoshitake, Kenshi Saeki, Takumi Honda, Takao Ogino
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Patent number: 5091023Abstract: The resistance of chromated zinc surfaced steel objects, particularly plates and sheets, to extraction of hexavalent chromium by alkaline degreasing solutions used on the chromated objects, can be substantially increased by utilizing an aqueous acidic liquid chromating composition containing (A) about 9.6 to about 96 g/L, expressed as its stoichiometric equivalent as chromic acid, of total chromium; (B) about 2 to about 35 g/L of trivalent chromium ions; (C) about 1 to about 128 g/L of phosphate ions; and (D) about 0.3 to about 4 g/L of fluorozirconate ions, with the chromium ratio in the aqueous acidic liquid composition being about 0.41 to about 0.70, the chromic acid/fluorozirconate weight ratio being about 10 to about 40, and the PO.sub.4 /Cr.sup.+3 ratio being greater than about 0.03, greater than or equal to about {(9.2) (the chromium ratio)-4.0}, and less than or equal to about {(9.2) (the chromium ratio)-1.2}. . .Type: GrantFiled: September 27, 1990Date of Patent: February 25, 1992Assignee: Henkel CorporationInventors: Kenshi Saeki, Noriaki Yoshitake
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Patent number: 5066540Abstract: A cured coating composition and substrate coated with the cured coating composition which coating is based upon an aqueous acid binder solution containing phosphate and chromate and/or molybdate ions into which has been dispersed a blend of metallic powder particles of three primary dimensions and flat metal flake materials, which can be applied to a substrate part to be coated more uniformly and thickly than conventional metal flake coatings, and which imparts better corrosion and impact resistance than conventional powder metal coatings.Type: GrantFiled: September 5, 1989Date of Patent: November 19, 1991Assignee: Sermatech International, Inc.Inventors: Mark F. Mosser, Kevin B. Eddinger, William J. Fabiny
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Patent number: 5039360Abstract: A method for coating a metal surface includes heating an untreated metal surface to a temperature of about 40.degree. C. to 250.degree. C. and spraying a coating composition onto the hot untreated metal surface, while continuously moving the metal surface, so that a corrosion resistant coating is formed on the surface, the coating composition having a pH of 0.5 to 1.5 and containing; (a) 20 to 40% by weight acrylic organic polymer in aqueous dispersion; (b) 1 to 5% by weight chromium in a soluble form and selected from the group of hexavalent chromium and mixtures of hexavalent and trivalent chromium wherein the trivalent is about 0.1 to 20% by weight of the total chromium in the mixture; (c) 1.5 to 4% by weight phosphoric acid; and (d) 0.1 to 1.5% by weight organic reducing agent.Type: GrantFiled: September 12, 1988Date of Patent: August 13, 1991Assignee: Procoat S.A.Inventors: Juan F. Brugarolas, Federico S. Rodellas
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Patent number: 4975330Abstract: A coating composition for providing a part with improved salt spray resistance, which includes undissolved solid hexavalent chromate in an aqueous acid solution which is the reaction product of phosphate ions with ions of the group consisting of chromate or molybdate ions, and their coatings and coated parts.Type: GrantFiled: May 23, 1989Date of Patent: December 4, 1990Assignee: Sermatech International, Inc.Inventor: Mark F. Mosser
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Patent number: 4971636Abstract: A method of producing highly corrosion-resistant surface-treated steel plates where Cr elusion is small in spite of drying at low temperatures and corrosion resistance is excellent. In a process for producing surface treated steels where Zn type plated steels are treated through (i) chromate treatment, (ii) coating a resin composition and (iii) baking treatment, zirconium fluoride ion and Zn ion of appropriate amounts are added into the chromate bath, and Cr.sup.6+ /Cr.sup.3+ ratio in the bath is controlled to be low. Further the resin composition to be coated after the chromate treatment is rendered a solvent type resin composition obtained by adding silica and/or sparingly water soluble Cr compound to basic epoxy resin.Type: GrantFiled: June 21, 1989Date of Patent: November 20, 1990Assignee: NKK CorporationInventors: Tsutomu Watanabe, Masaaki Yamashita, Takahiro Kuboto
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Patent number: 4865653Abstract: The present invention relates to a composition and process for metal finishing involving the formation of zinc phosphate coatings of desired morphology on a ferrous surface. The inclusion of a hydroxylamine agent in the phosphating bath expands the range of zinc concentrations over which the desired coating morphology is obtained. Zinc and aluminum surface can also be coated with this composition and process.Type: GrantFiled: October 30, 1987Date of Patent: September 12, 1989Assignee: Henkel CorporationInventor: Linda S. Kramer
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Patent number: 4863516Abstract: A coating composition based upon an aqueous acid binder solution containing phosphate and chromate and/or molybdate ions into which has been dispersed a blend of metallic powder particles of three primary dimensions and flat metal flake materials, which can be applied to a substrate part to be coated more uniformly and thickly than conventional metal flake coatings, and which imparts better corrosion and impact resistance than conventional powder metal coatings.Type: GrantFiled: August 16, 1988Date of Patent: September 5, 1989Assignee: Sermatech International, Inc.Inventors: Mark F. Mosser, Kevin B. Eddinger, William J. Fabiny
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Patent number: 4838942Abstract: Synthetic material substrates are protected against erosion and corrosion by a lacquer type coating which is baked or bonded onto the substrate at relatively low temperatures below 200.degree. C. to protect the synthetic material substrate against damage. The coating is a dispersion of metal powder in an aqueous solution of about equal weight proportions of phosphorous acid and phosphoric acid with an optional weight proportion of not more than 5 percent of aluminum phosphate, and about 10 to 20 weight percent of chromic acid. The remainder is water.Type: GrantFiled: December 23, 1987Date of Patent: June 13, 1989Assignee: MTU-Motoren-und Turbinen-Union Muenchen GmbHInventors: Frans Puchinger, Gerhard Wydra
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Patent number: 4812175Abstract: An aqueous acidic treating solution and process for forming a chromium-containing passivate coating on the surface of zinc or zinc-aluminum alloys to enhance bare corrosion resistance and inhibit discoloration thereof upon exposure to ambient environments. The treating solution contains as its essential constituents, chromium ions, nitrate ions, phosphate ions.Type: GrantFiled: June 10, 1987Date of Patent: March 14, 1989Assignee: Parker Chemical CompanyInventor: Gary A. Reghi