Nickel Containing Patents (Class 148/336)
  • Publication number: 20120295123
    Abstract: This steel plate for cold forging includes a hot-rolled steel plate, wherein the hot-rolled steel plate includes: in terms of percent by mass, C: 0.13% to 0.20%; Si: 0.01% to 0.8%; Mn: 0.1% to 2.5%; P: 0.003% to 0.030%; S: 0.0001% to 0.008%; Al: 0.01% to 0.07%; N: 0.0001% to 0.02%; and O: 0.0001% to 0.0030%, with a remainder being Fe and inevitable impurities, an A value represented by the following formula (1) is in a range of 0.0080 or less, a thickness of the hot-rolled steel plate is in a range of 2 mm to 25 mm, and an area percentage of pearlite bands having lengths of 1 mm or more in a region of 4/10t to 6/10t when a plate thickness is indicated by t in a cross section of a plate thickness that is parallel to a rolling direction of the hot-rolled steel plate is in a range of not more than a K value represented by the following formula (2), A value=O%+S%+0.033Al%??(1) K value=25.5×C%+4.5×Mn%?6??(2).
    Type: Application
    Filed: January 25, 2011
    Publication date: November 22, 2012
    Inventors: Masayuki Abe, Kengo Takeda, Shuji Yamamoto, Yasushi Tsukano, Shinichi Yamaguchi
  • Publication number: 20120279620
    Abstract: This high strength hot-rolled steel sheet includes: in terms of percent by mass, C: 0.05 to 0.12%; Si: 0.8 to 1.2%; Mn: 1.6 to 2.2%; Al: 0.30 to 0.6%; P: 0.05% or less; S: 0.005% or less; and N: 0.01% or less, with the remainder being Fe and unavoidable impurities, wherein a microstructure includes specific ranges (in area %) of ferrite phases as well as martensite phases, and a maximum concentration of Al detected by a glow discharge emission spectroscopic analysis is in a range of 0.75 mass % or less in a region from a surface of the steel sheet to a thickness of 500 nm after being acid-pickled.
    Type: Application
    Filed: November 16, 2010
    Publication date: November 8, 2012
    Applicant: NIPPON STEEL CORPORATION
    Inventors: Hiroyuki Tanahashi, Shinya Saitoh, Masashi Fukuda, Hiroyuki Okada, Kunio Hayashi, Toshimasa Tomokiyo, Nobuhiro Fujita
  • Patent number: 8303734
    Abstract: The present invention provides a high strength thick steel material excellent in toughness and weldability reduced in amount of C and amount of N, containing suitable amounts of Si, Mn, Nb, Ti, B, and O, having contents of C and Nb satisfying C—Nb/7.74?0.004, having a density of Ti-containing oxides of a particle size of 0.05 to 10 ?m of 30 to 300/mm2, and having a density of Ti-containing oxides of a particle size over 10 ?m of 10/mm2 or less, produced by treating steel by preliminary deoxidation to adjust the dissolved oxygen to 0.005 to 0.015 mass %, then adding Ti and, furthermore, vacuum degassing the steel for 30 minutes or more, smelting it, then continuously casting it to produce a steel slab or billet, heating the steel slab or billet to 1100 to 1350° C., hot rolling the slab or billet to a thickness of 40 to 150 mm, then cooling it.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: November 6, 2012
    Assignee: Nippon Steel Corporation
    Inventors: Suguru Yoshida, Hiroshi Kita, Teruhisa Okumura, Hirokazu Sugiyama, Teruyuki Wakatsuki
  • Publication number: 20120267014
    Abstract: There is provided a method for manufacturing a seamless steel pipe for line pipe, capable of improving the toughness of the seamless steel pipe for line pipe. A round billet having a chemical composition, by mass percent, of C: 0.02 to 0.15%, Si: at most 0.5%, and Mn: 0.5 to 2.5%, the balance being Fe and impurities, is heated. The heated round billet is piercing-rolled to produce a hollow shell. The hollow shell is elongated and rolled and sized to produce a seamless steel pipe. The seamless steel pipe is water cooled, and the water cooling is stopped when the temperature of the seamless steel pipe reaches at most 450° C. The water-cooled seamless steel pipe is quenched, and the quenched seamless steel pipe is tempered.
    Type: Application
    Filed: July 2, 2012
    Publication date: October 25, 2012
    Applicant: Sumitomo Metal Industries, Ltd.
    Inventors: Keisuke Hitoshio, Kunio Kondo, Yuji Arai
  • Publication number: 20120247621
    Abstract: A casting process for producing metal alloy castings, facecoats and apparatuses suitable for carrying out the process, and castings produced by the process. The casting process entails the use of a mold having a cavity with a continuous aluminum-containing solid facecoat on its surface. A molten quantity of a metal alloy is introduced into the mold cavity so that the molten alloy contacts the solid facecoat. The mold is then allowed to cool to solidify the molten alloy and form a cast product. During the casting process, aluminum in the solid facecoat diffuses into the cast product to form an aluminum-containing surface region at the casting surface. Following removal of the cast product from the mold, an alumina-containing scale grows on the casting surface as a result of oxidation of the casting surface region.
    Type: Application
    Filed: March 29, 2011
    Publication date: October 4, 2012
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: George Albert Goller, Dennis William Cavanaugh
  • Patent number: 8252125
    Abstract: The present invention, among other things, relates to a method for producing a workpiece by press hardening a semi-finished product, which is distinguished by the fact that the semi-finished product consists of a steel which has a high content of silicon of at least 0.9 wt. %, with a simultaneously small content of manganese of less than 0.9 wt. %, a small carbon content of less than 0.25 wt. %, and a high chromium content of more than 1.20 wt. %, and which by heating is brought to a state in which the structure of the steel that is used is at least partially transformed to austenite, also optionally fully transformed to austenite, and the thus-heated semi-finished product is hot shaped so that after the hot deformation shaping, a structure is present in the workpiece that has a complex phase structure with predominantly martensite and ferrite fractions. In addition, a workpiece is described, which is produced according to this method, as well as uses of such a workpiece.
    Type: Grant
    Filed: October 16, 2009
    Date of Patent: August 28, 2012
    Assignee: Benteler Automobiltechnik GmbH
    Inventors: Hubertus Giefers, Karsten Bake, Andreas Frehn, Alexander Redenius, Uwe Diekmann
  • Patent number: 8241559
    Abstract: The invention relates to a steel material having a high silicon content, and to a method for the production thereof, the steel material being particularly suitable for piston rings and cylinder sleeves. In addition to iron and production-related impurities, the steel material contains 0.5 to 1.2 wt. % carbon, 3.0 to 15.0 wt. % silicon and 0.5 to 4.5 wt. % nickel. Also, the steel material can contain small amounts of the following elements Mo, Mn, Al, Co Nb, Ti, V, Sn, Mg, B, Te Ta La, Bi, Zr, Sb, Ca, Sr, Cer, rare earth metals and nucleating agents such as NiMg, MiSiMg, FeMg and FeSIMg. due to the high Si content, a degree of saturation higher than 1.0 is attained, with the melting temperature of the steel material corresponding to normal cast iron. The steel material can be produced according to a conventional cast-iron technique and has a high resistance to wear and tear and a high structural strength (minimal distortion).
    Type: Grant
    Filed: May 7, 2007
    Date of Patent: August 14, 2012
    Assignee: Federal-Mogul Burscheid GmbH
    Inventor: Laszlo Pelsoeczy
  • Patent number: 8236111
    Abstract: The present invention provides a product for enameling and an enameled product that achieve adhesion, bubble/black spot defect resistance and fishscale resistance, even when preprocessing and ground coating are omitted, which product comprise a steel sheet having on the surface thereof an oxide film of 0.10 ?m to 400 ?m thickness comprising oxides of components of the steel sheet, which steel sheet comprises, in mass %, C: 0.0001% to 0.040%, Si: 0.0001% to 0.50%, Mn: 0.001% to 2.00%, P: 0.0001% to 0.10%, S: 0.0001% to 0.060%, Al: 0.0001% to 0.10%, N: 0.0001% to 0.015%, and O: 0.0001% to 0.070%, further comprises one or more of Ni: 0.01% to 2.00%, Co: 0.0005% to 2.00%, Cr: 0.001% to 2.00%, Cu: 0.01% to 2.00%, Mo: 0.0001% to 2.00%, and Ti: 0.0005% to 0.50%, where Ni+Co+Cr/2+Cu+Mo+Ti: 0.010% to 8.0%, the balance being Fe and unavoidable impurities.
    Type: Grant
    Filed: August 15, 2007
    Date of Patent: August 7, 2012
    Assignee: Nippon Steel Corporation
    Inventors: Hidekuni Murakami, Satoshi Nishimura
  • Publication number: 20120193000
    Abstract: Steel for induction hardening wherein coarsening of austenite crystal grains can be prevented even at a high temperature of over 1100° C. such as which occurs at projecting parts of steel parts at the time of induction hardening, the steel for induction hardening characterized by containing, by mass %, C: 0.35 to 0.6%, Si: 0.01 to 1%, Mn: 0.2 to 1.8%, S: 0.001 to 0.15%, Al: 0.001 to 1%, Ti: 0.05 to 0.2%, and Nb: 0.001 to 0.04%, restricting N: 0.0060% or less, P: 0.025% or less, and O: 0.0025% or less, satisfying Nb/Ti?0.015, and having a balance of iron and unavoidable impurities.
    Type: Application
    Filed: October 7, 2010
    Publication date: August 2, 2012
    Applicant: Nippon Steel Corporation
    Inventors: Shuji Kozawa, Manabu Kubota
  • Publication number: 20120180909
    Abstract: A multiphase steel sheet has a steel composition containing, in percent by mass, more than 0.015% to less than 0.100% of carbon, less than 0.40% of silicon, 1.0% to 1.9% of manganese, more than 0.015% to 0.05% of phosphorus, 0.03% or less of sulfur, 0.01% to 0.3% of soluble aluminum, 0.005% or less of nitrogen, less than 0.30% of chromium, 0.0050% or less of boron, less than 0.15% of molybdenum, 0.4% or less of vanadium, 0.02% or less of titanium, wherein [Mneq] is 2.0 to 2.8, the balance being iron and incidental impurities.
    Type: Application
    Filed: July 27, 2010
    Publication date: July 19, 2012
    Applicant: JFE STEEL CORPORATION
    Inventors: Yoshihiko Ono, Kenji Takahashi, Kaneharu Okuda, Shoichiro Taira, Michitaka Sakurai, Yusuke Fushiwaki
  • Publication number: 20120175028
    Abstract: A high strength steel sheet has a tensile strength of 980 MPa or higher includes a composition including, on a mass% basis, C: 0.1% or more and 0.3% or less, Si: 2.0% or less, Mn: 0.5% or more and 3.0% or less, P: 0.1% or less, S: 0.07% or less, Al: 1.0% or less, and N: 0.008% or less, with the balance being Fe and incidental impurities, wherein a steel micro-structure includes, on an area ratio basis, martensite: 50% or more, ferrite: 50% or less, bainite: 10% or less, and retained austenite: 10% or less; and the full-width at half maximum in a frequency distribution of nano-hardness, which is obtained by measuring a hardness distribution of the martensite, is 2.0 GPa or more.
    Type: Application
    Filed: July 28, 2010
    Publication date: July 12, 2012
    Applicant: JFE STEEL CORPORATION
    Inventors: Hiroshi Matsuda, Reiko Mizuno, Yoshimasa Funakawa
  • Publication number: 20120132327
    Abstract: Disclosed is a high strength steel sheet having excellent hydrogen embrittlement resistance. The steel sheet has a tensile strength of 1180 MPa or more, and satisfies the following conditions: with respect to an entire metallographic structure thereof, bainite, bainitic ferrite and tempered martensite account for 85 area % or more in total; retained austenite accounts for 1 area % or more; and fresh martensite accounts for 5 area % or less (including 0 area %).
    Type: Application
    Filed: May 28, 2010
    Publication date: May 31, 2012
    Applicants: VOESTALPINE STAHL GMBH, Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Yoichi Mukai, Kouji Kasuya, Michiharu Nakaya, Michitaka Tsunezawa, Fumio Yuse, Junichiro Kinugasa, Sandra Traint, Andreas Pichler
  • Patent number: 8177925
    Abstract: In a high-tensile steel plate according to the invention, the carbon equivalent Pcm represented in Expression (1) is from 0.180% to 0.220%, the surface hardness is a Vicker's hardness of 285 or less, the ratio of a Martensite Austenite constituent in the surface layer is not more than 10%, the ratio of a mixed structure of ferrite and bainite inside beyond the surface layer is not less than 90%, the ratio of the bainite in the mixed structure is not less than 10%, the thickness of the lath of bainite is not more than 1 ?m, the length of the lath is not more than 20 ?m, and the segregation ratio as the ratio of the Mn concentration in the center segregation part relative to the Mn concentration at a part in a depth equal to ¼ of the thickness of the plate from the surface is not more than 1.3. Pcm=C+Si/30+(Mn+Cu+Cr)/20+Ni/60+Mo/15+V/10+5B . . . (1) where the element symbols in Expression (1) represent the % by mass of the respective elements.
    Type: Grant
    Filed: March 8, 2006
    Date of Patent: May 15, 2012
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Nobuaki Takahashi, Masahiko Hamada, Shuji Okaguchi, Akihiro Yamanaka, Ichirou Seta
  • Patent number: 8168011
    Abstract: The invention provides wire rod excellent in drawability and steel wire made from the wire rod as starting material with high productivity at good yield and low cost. A hard steel wire rod of a specified composition is heated in a specified temperature range to conduct post-reaustenization patenting and thereby obtain a high-carbon steel wire excellent in ductility that has a pearlite structure of an area ratio of 97% or greater and the balance of non-pearlite structures including bainite, degenerate-pearlite and pro-eutectoid ferrite and whose fracture reduction of area RA satisfies Expressions (1), (2) and (3) below: RA?RAmin??(1), where RAmin=a?b×pearlite block size (?m), a=?0.0001187×TS (MPa)2+0.31814×TS (MPa)?151.32??(2) b=0.0007445×TS (MPa)?0.3753??(3).
    Type: Grant
    Filed: April 18, 2007
    Date of Patent: May 1, 2012
    Assignee: Nippon Steel Corporation
    Inventors: Shingo Yamasaki, Seiki Nishida, Makio Kikuchi
  • Patent number: 8142574
    Abstract: A steel product for welding includes the following component: by mass %, C: 0.3% or less, Si: 0.5% or less, Mn: 0.3˜2%, P: 0.03% or less, S: 0.03% or less, Al: 0.3˜5%, O: 0.003˜0.01%, and N: 0.006% or less; wherein the balance is composed of Fe and inevitable impurities; wherein Al-containing oxides having a size of 0.005 to 0.05 ?m are dispersed in steel at a ratio of 1×106/mm2 or more.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: March 27, 2012
    Assignee: Nippon Steel Corporation
    Inventors: Akihito Kiyose, Hideaki Yamamura, Tooru Matsumiya
  • Patent number: 8110292
    Abstract: The present invention provides high strength steel plate with excellent low temperature toughness, high strength steel pipe using this as a base metal, and methods of production of the same. The steel plate of the present invention contains Mo: 0.05 to 1.00% and B: 0.0003 to 0.0100%, has a Ceq of 0.30 to 0.53, has a Pcm of 0.10 to 0.20, and has a metal structure which has an area percentage of polygonal ferrite of 20 to 90% and has a balance of a hard phase comprised of one or both of bainite and martensite. To obtain this steel plate, strain-introducing rolling is performed with a start temperature of not more than Ar3+60° C., an end temperature of Ar3 or more, and a reduction ratio of 1.5 or more, then the plate is air-cooled and then acceleratedly cooled from Ar3?100° C. to Ar3?10° C. in temperature by 10° C./s or more.
    Type: Grant
    Filed: April 4, 2009
    Date of Patent: February 7, 2012
    Assignee: Nippon Steel Corporation
    Inventors: Taishi Fujishiro, Shinya Sakamoto, Takuya Hara, Hitoshi Asahi
  • Publication number: 20120012231
    Abstract: A cold-rolled steel sheet of the present invention which has a composition containing, in terms of % by mass, C: 0.05-0.30%, Si: 3.0% or less (including 0%), Mn: 0.1-5.0%, P: 0.1% or less (including 0%), S: 0.010% or less (including 0%), and Al: 0.001-0.10%, and remainder being mainly iron, and which has a structure comprising, in terms of area ratio, 10-80% ferrite, less than 5% (including 0%) of the sum of retained austenite and martensite, and a hard phase as the remainder. The steel sheet gives a KAM value frequency distribution curve in which the relationship between the proportion of frequency having a KAM value ?0.4, XKAM?0.4°, and the area ratio of ferrite, V? satisfies XKAM?0.4°/V??0.8 and the proportion of frequency having a KAM value in the range of 0.6-0.8, XKAM=0.6-0.8° is 10-20%. In the hard phase adjoining the ferrite, cementite, grains having an equivalent circle diameter of 0.1 ?m or larger exist so that three or less such cementite grains are dispersed per ?m2 of the hard phase.
    Type: Application
    Filed: April 2, 2010
    Publication date: January 19, 2012
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Toshio Murakami, Akira Ibano, Hideo Hata, Kenji Saito
  • Publication number: 20120014831
    Abstract: The present invention provides a wire rod with a composition at least including: C: 0.95-1.30 mass %; Si: 0.1-1.5 mass %; Mn: 0.1-1.0 mass %; Al: 0-0.1 mass %; Ti: 0-0.1 mass %; P: 0-0.02 mass %; S: 0-0.02 mass %; N: 10-50 ppm; O: 10-40 ppm; and a balance including Fe and inevitable impurities, wherein 97% or more of an area in a cross-section perpendicular to the longitudinal direction of the wire rod is occupied by a pearlite, and 0.5% or less of an area in a central area in the cross-section and 0.5% or less of an area in a first surface layer area in the cross-section are occupied by a pro-eutectoid cementite.
    Type: Application
    Filed: October 19, 2010
    Publication date: January 19, 2012
    Inventors: Shingo Yamasaki, Toshiyuki Manabe, Daisuke Hirakami, Nariyasu Muroga
  • Publication number: 20110315279
    Abstract: The high-strength galvanized steel sheet having excellent formability has a component composition containing, on the basis of mass percent, 0.05 to 0.2% C, 0.5 to 2.5% Si, 1.5 to 3.0% Mn, 0.001 to 0.05% P, 0.0001 to 0.01% S, 0.001 to 0.1% Al, and 0.0005 to 0.01% N, the balance being Fe and incidental impurities; and the steel sheet has a microstructure including a ferritic phase and a martensitic phase including a tempered-martensitic phase, the ferritic phase having an area fraction of 30% or more relative to an entirety of the microstructure, the martensitic phase having an area fraction of 30 to 50% relative to the entirety of the microstructure, and the tempered-martensitic phase having an area fraction of 70% or more relative to an entirety of the martensitic phase.
    Type: Application
    Filed: February 19, 2010
    Publication date: December 29, 2011
    Applicant: JFE STEEL CORPORATION
    Inventors: Shinjiro Kaneko, Yoshiyasu Kawasaki, Tatsuya Nakagaito, Saiji Matsuoka
  • Patent number: 8083990
    Abstract: An iron-based alloy having shape memory properties and superelasticity, which has a composition comprising 25-35% by mass of Ni, 13-25% by mass of Co, 2-8% by mass of Al, and 1-20% by mass in total of at least one selected from the group consisting of 1-5% by mass of Ti, 2-10% by mass of Nb and 3-20% by mass of Ta, the balance being substantially Fe and inevitable impurities, and a recrystallization texture substantially comprising a ? phase and a ?? phase, particular crystal orientations of the ? phase being aligned, and the difference between a reverse transformation-finishing temperature and a martensitic transformation-starting temperature being 100° C. or less in the thermal hysteresis of martensitic transformation and reverse transformation.
    Type: Grant
    Filed: November 2, 2006
    Date of Patent: December 27, 2011
    Assignee: Japan Science and Technology Agency
    Inventors: Kiyohito Ishida, Ryosuke Kainuma, Yuji Sutou, Yuuki Tanaka
  • Patent number: 8084144
    Abstract: The present invention provides high strength thick welded steel pipe for line pipe superior in low temperature toughness, and a method of production of the same. A base material steel plate containing C: 0.010 to 0.050%, Si: 0.01 to 0.50%, Mn: 0.50 to 2.00%, Al: 0.020% or less, Ti: 0.003 to 0.030%, and Mo: 0.10 to 1.50%, having a carbon equivalent Ceq of 0.30 to 0.53, having a crack susceptability parameter Pcm of 0.10 to 0.20, satisfying formula 3, comprised an area ratio of 20% or less of polygonal ferrite and an area ratio of 80% or more of bainite, and having an effective crystal grain size of 20 ?m or less is formed into a pipe shape, then seam welded to make the effective crystal grain size of the heat affected zone 150 ?m or less: 10C+100Al+5Mo+5Ni<3.3??formula 3.
    Type: Grant
    Filed: December 4, 2007
    Date of Patent: December 27, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Takuya Hara, Hitoshi Asahi
  • Patent number: 8070889
    Abstract: The invention is directed to providing, for application in automobiles, construction materials, household appliances and the like, high-strength sheets excellent in formability properties such as hole expansibility and ductility, and also in fatigue resistance, characterized in comprising, in specified contents expressed in mass %, C, Si, Mn, P, S, Al, N and O and a balance of iron and unavoidable impurities, and having a steel sheet structure composed mainly of ferrite and hard structures, a crystal orientation difference between some ferrite adjacent to hard structures and the hard structures of less than 9°, and a maximum tensile strength of 540 MPa or greater.
    Type: Grant
    Filed: April 9, 2009
    Date of Patent: December 6, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Masafumi Azuma, Noriyuki Suzuki, Naoki Maruyama, Naoki Yoshinaga, Akinobu Murasato
  • Patent number: 8071018
    Abstract: A high carbon hot-rolled steel sheet which is a hot-rolled spheroidizing annealed material, including 0.2 to 0.7% C, 2% or less Si, 2% or less Mn, 0.03% or less P, 0.03% or less S, 0.08% or less Sol.Al., and 0.01% or less N, by mass, which contains carbide having a particle size of smaller than 0.5 ?m in a content of 15% or less by volume to the total amount of carbide, and the difference between the maximum hardness Hv max and the minimum hardness Hv min, ?Hv (=Hv max?Hv min), in the sheet thickness direction being 10 or smaller.
    Type: Grant
    Filed: June 22, 2010
    Date of Patent: December 6, 2011
    Assignee: JFE Steel Corporation
    Inventors: Nobusuke Kariya, Norio Kanamoto, Hidekazu Ookubo, Yoshiharu Kusumoto, Takeshi Fujita
  • Patent number: 8052812
    Abstract: A high carbon cold-rolled steel sheet having both excellent stretch-flange formability and excellent homogeneity of hardness in the sheet thickness direction is provided by a manufacturing method having the steps of: hot-rolling a steel containing 0.2 to 0.7% C by mass at finishing temperatures of (Ar3 transformation point ?20° C.) or above to prepare a hot-rolled sheet; cooling the hot-rolled sheet to temperatures of 650° C. or below at cooling rates from 60° C./s or larger to smaller than 120° C./s; coiling the hot-rolled sheet after cooling at coiling temperatures of 600° C. or below; cold-rolling the coiled hot-rolled sheet at rolling reductions of 30% or more to prepare a cold-rolled sheet; and annealing the cold-rolled sheet at annealing temperatures from 600° C. or larger to Ac1 transformation point or lower.
    Type: Grant
    Filed: June 19, 2006
    Date of Patent: November 8, 2011
    Assignee: JFE Steel Corporation
    Inventors: Nobusuke Kariya, Norio Kanamoto, Hidekazu Ookubo, Yoshiharu Kusumoto, Takeshi Fujita
  • Patent number: 8048238
    Abstract: Steel sheet having a composition of ingredients containing substantially, by mass %, C: 0.005 to 0.200%, Si: 2.50% or less, Mn: 0.10 to 3.00%, N: 0.0100% or less, Nb: 0.005 to 0.100%, and Ti: 0.002 to 0.150% and satisfying the relationship of Ti?48/14×N?0.0005, having a sum of the X-ray random intensity ratios of the {100}<001> orientation and the {110}<001> orientation of a ? sheet thickness part of 5 or less, having a sum of the maximum value of the X-ray random intensity ratios of the {110}<111> to {110}<112> orientation group and the X-ray random intensity ratios of the {211}<111> orientation of 5 or more, and having a high rolling direction Young's modulus measured by the static tension method and a method of production of the same are provided.
    Type: Grant
    Filed: November 7, 2007
    Date of Patent: November 1, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Natsuko Sugiura, Naoki Maruyama, Manabu Takahashi, Yohji Nakamura, Koji Hanya
  • Publication number: 20110253264
    Abstract: An iron-carbon master alloy is described, with a C content of 0.3 to 8 wt % and an upper limit of alloying metals Ni<10 wt %, P<4 wt %, Cr<5 wt %, preferably<1 wt %, Mn<5 wt %, preferably<1 wt %, Mo<3 wt %, W<3 wt %, Cu<1 wt %, a particle size of >20 ?m and a hardness of <350 HV 0.01, and a method for the manufacture of said master alloy.
    Type: Application
    Filed: December 17, 2009
    Publication date: October 20, 2011
    Applicant: TECHNISCHE UNIVERSITAT WIEN
    Inventors: Christian Gierl, Herbert Danninger, Yousef Hemmatpour
  • Patent number: 8038809
    Abstract: A high-strength hot-rolled steel sheet containing C: 0.05 to 0.15%, Si: no more than 1.50% (excluding 0%), Mn: 0.5 to 2.5%, P: no more than 0.035% (excluding 0%), S: no more than 0.01% (including 0%), Al: 0.02 to 0.15%, and Ti: 0.05 to 0.2%, which is characterized in that its metallographic structure is composed of 60 to 95 vol % of bainite and solid solution-hardened or precipitation-hardened ferrite (or ferrite and martensite) and its fracture appearance transition temperature (vTrs) is no higher than 0° C. as obtained by impact tests. (% in terms of % by weight).
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: October 18, 2011
    Assignee: Kobe Steel, Ltd.
    Inventors: Motoo Satou, Tetsuo Soshiroda
  • Patent number: 8039118
    Abstract: The present invention provides high strength welded steel pipe for line pipe inexpensive in cost and superior in low temperature toughness, and a method of production of the same, produced by forming a base material steel plate containing, by mass %, C: 0.010 to 0.050%, Si: 0.01 to 0.50%, Mn: 0.50 to 2.00%, S: 0.0001 to 0.0050%, and Ti: 0.003 to 0.030%, limiting Al to 0.020% or less and Mo to less than 0.10%, having a carbon equivalent Ceq of 0.30 to 0.53 and a crack susceptibility parameter Pcm of 0.10 to 0.20, comprised of polygonal ferrite and residual bainite of an area rate of 20% or less, and having an effective crystal grain size of 20 ?m or less, into a pipe shape, then seam welding it and making the effective crystal grain size of the heat affected zone 150 ?m or less.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: October 18, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Takuya Hara, Hitoshi Asahi
  • Publication number: 20110226389
    Abstract: A pearlite rail contains, by mass %, 0.65 to 1.20% of C; 0.05 to 2.00% of Si; 0.05 to 2.00% of Mn; and the balance composed of Fe and inevitable impurities, wherein at least part of the head portion and at least part of the bottom portion has a pearlite structure, and the surface hardness of a portion of the pearlite structure is in a range of Hv320 to Hv500 and a maximum surface roughness of a portion of the pearlite structure is less than or equal to 180 ?m.
    Type: Application
    Filed: August 13, 2010
    Publication date: September 22, 2011
    Applicant: NIPPON STEEL CORPORATION
    Inventors: Masaharu Ueda, Kyohei Sonoyama, Takuya Tanahashi, Teruhisa Miyazaki, Katsuya Iwano
  • Publication number: 20110198002
    Abstract: A high-strength galvanized steel sheet has excellent mechanical properties such as a TS of 1200 MPa or more, an El of 13% or more, and a hole expansion ratio of 50% or more and a method for manufacturing the same. A high-strength galvanized steel sheet excellent in formability contains 0.05% to 0.5% C, 0.01% to 2.5% Si, 0.5% to 3.5% Mn, 0.003% to 0.100% P, 0.02% or less S, and 0.010% to 0.5% Al on a mass basis, the remainder being Fe and unavoidable impurities, and has a microstructure which contains 0% to 10% ferrite, 0% to 10% martensite, and 60% to 95% tempered martensite on an area basis as determined by structure observation and which further contains 5% to 20% retained austenite as determined by X-ray diffractometry.
    Type: Application
    Filed: January 28, 2009
    Publication date: August 18, 2011
    Applicant: JFE Steel Corporation
    Inventors: Tatsuya Nakagaito, Saiji Matsuoka, Yoshitsugu Suzuki, Yuki Toji
  • Patent number: 7998285
    Abstract: The invention concerns a method for making an abrasion resistant steel plate having a chemical composition comprising: 0.1%?C<0.23%; 0%?Si?2%; 0%?Al?2%; 0.5%?Si+Al?2%; 0%?Mn?2.5%; 0%?Ni?5%; 0%?Cr?5%; 0%?Mo?1%; 0%?W?2%; 0.05%?Mo+W/2?1%; 0%?Cu?1.5%; 0%?B?0.02%; 0%?Ti?0.67%; 0%?Zr?1.34%; 0.05%<Ti+Zr/2?0.67%; 0%?S?0.15%; N<0.03%, optionally 0% to 1.5% of Cu; optionally Nb, Ta and V such that Nb/2+Ta/4+V?0.5%; optionally Se, Te, Ca, Bi, Pb contents ?0.1%; the rest being iron impurities. Additionally: 0.095%?C*=C?Ti/4?Zr/8+7×N/8, Ti+Zr/2?7×N/2?0.05% and 1.05×Mn+0.54×Ni+0.50×Cr+0.3×(Mo+W/2)1/2+K>1.8, with K=1 if B?0.0005% and K=0 if B<0.0005%. After austenitization, the method consists in: cooling at a speed >0.5° C./s between a temperature between AC3 and T=800?270×C*?90×Mn?37×Ni?70×Cr?83×(Mo+W/2) and about T?50° C.; then cooling at a speed 0.1<Vr<1150×ep?1.7 between T and 100° C., (ep=plate thickness in mm); cooling down to room temperature and optionally planishing.
    Type: Grant
    Filed: June 18, 2008
    Date of Patent: August 16, 2011
    Assignee: Industeel Creusot
    Inventors: Jean Beguinot, Jean-Georges Brisson
  • Patent number: 7993542
    Abstract: A magnetic material for magnetic refrigeration has a composition represented by (R11-yR2y)xFe100-x (R1 is at least one of element selected from Sm and Er, R2 is at least one of element selected from Ce, Pr, Nd, Tb and Dy, and x and y are numerical values satisfying 4?x?20 atomic % and 0.05?y?0.95), and includes a Th2Zn17 crystal phase, a Th2Ni17 crystal phase, or a TbCu7 crystal phase as a main phase.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: August 9, 2011
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Shinya Sakurada, Akiko Saito, Tadahiko Kobayashi, Hideyuki Tsuji
  • Patent number: 7981224
    Abstract: The present invention provides a steel sheet excellent in both a balance between strength and elongation and a balance between strength and hole expandability, in other words, a multi-phase steel sheet having an excellent balance between strength and hole expandability. The present invention is a multi-phase steel sheet excellent in hole expandability characterized in that: the steel sheet contains, as chemical components in mass, C: 0.03 to 0.15%, P: not more than 0.010%, S: not more than 0.003%, and either one or both of Si and Al in a total amount of 0.5 to 4%, and one or more of Mn, Ni, Cr, Mo and Cu in a total amount of 0.
    Type: Grant
    Filed: December 18, 2003
    Date of Patent: July 19, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Osamu Kawano, Takehiro Hoshino
  • Publication number: 20110168302
    Abstract: The present invention provides a steel wire, including chemical components of: C: 0.7-1.2 mass %; Si: 0.05-2.0 mass %; and Mn: 0.2-2.0 mass %, with a balance including Fe and inevitable impurities, in which the steel wire has a pearlite structure, the average C concentration at a center portion of a ferrite phase in an outermost layer of the steel wire is 0.2 mass % or lower, and a residual compressive stress in the longitudinal direction of the steel wire in the outermost layer is 600 MPa or more.
    Type: Application
    Filed: April 21, 2010
    Publication date: July 14, 2011
    Inventors: Jun Takahashi, Makoto Kosaka, Junichi Kodama, Toshimi Tarui, Tamaki Suzuki
  • Publication number: 20110162762
    Abstract: A high strength steel sheet having composition includes, on a percent by mass basis, C: 0.17% to 0.73%; Si: 3.0% or less; Mn: 0.5% to 3.0%; P: 0.1% or less; S: 0.07% or less; Al: 3.0% or less; and N: 0.010% or less, satisfies Si+Al?0.7%, and the remainder includes Fe and incidental impurities, with a microstructure that has an area percentage of a total amount of lower bainite and whole martensite 10% to 90% relative to the whole steel sheet microstructure, an amount of retained austenite is 5% to 50%, an area percentage of bainitic ferrite in upper bainite is 5% or more relative to the whole steel sheet microstructure, as-quenched martensite is 75% or less of the total amount of lower bainite and whole martensite, and an area percentage of polygonal ferrite is 10% or less relative to the whole steel sheet microstructure, an average amount of C in retained austenite is 0.70% or more, and tensile strength is 980 MPa or more.
    Type: Application
    Filed: September 8, 2009
    Publication date: July 7, 2011
    Applicant: JFE STEEL CORPORATION
    Inventors: Hiroshi Matsuda, Yoshimasa Funakawa, Yasushi Tanaka
  • Publication number: 20110155290
    Abstract: This case hardening steel has a chemical composition including, by mass %: C: 0.1 to 0.6%; Si: 0.02 to 1.5%; Mn: 0.3 to 1.8%; P: 0.025% or less; S: 0.001 to 0.15%; Al: over 0.05 to 1.0%; Ti: 0.05 to 0.2%; N: 0.01% or less; and O: 0.0025% or less, and further including, by mass %, one or more of Cr: 0.4 to 2.0%, Mo: 0.02 to 1.5%, Ni: 0.1 to 3.5%, V: 0.02 to 0.5%, and B: 0.0002 to 0.005%, and the balance consisting of iron and unavoidable impurities.
    Type: Application
    Filed: January 13, 2010
    Publication date: June 30, 2011
    Inventors: Kei Miyanishi, Masayuki Hashimura, Shuuji Kozawa, Manabu Kubota, Tatsuro Ochi
  • Patent number: 7967923
    Abstract: The present invention provides a steel plate that exhibits excellent low-temperature toughness in a base material and a weld heat-affected zone and has small strength anisotropy, wherein the steel includes, by mass, C: 0.04%-0.10%; Si: 0.02%-0.40%; Mn: 0.5%-1.0%; P: 0.0010%-0.0100%; S: 0.0001%-0.0050%; Ni: 2.0%-4.5%; Cr: 0.1%-1.0%; Mo: 0.1%-0.6%; V: 0.005%-0.1%; Al: 0.01%-0.08%; and N: 0.0001%-0.0070%, with the balance including Fe and inevitable impurities, a Ni segregation ratio at a portion located at one-fourth of a thickness of the steel plate in a steel-plate thickness direction from a surface of the steel plate is 1.3 or lower, a degree of flatness of a prior austenite grain is in a range from 1.05 to 3.0, an effective diameter of crystal grain is 10 ?m or lower, and a Vickers hardness number is in a range of 265 HV to 310 HV.
    Type: Grant
    Filed: October 1, 2009
    Date of Patent: June 28, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Hitoshi Furuya, Naoki Saitoh, Motohiro Okushima, Yasunori Takahashi
  • Publication number: 20110146852
    Abstract: A high-strength steel sheet has good ductility and stretch-flangeability and has a tensile strength (TS) of 980 MPa or more. The steel sheet contains 0.17%-0.73% C, 3.0% or less Si, 0.5%-3.0% Mn, 0.1% or less P, 0.07% or less S, 3.0% or less Al, and 0.010% or less N, in which Si+Al is 0.7% or more.
    Type: Application
    Filed: September 4, 2009
    Publication date: June 23, 2011
    Applicant: JFE Steel Corporation
    Inventors: Hiroshi Matsuda, Yoshimasa Funakawa, Yasushi Tanaka
  • Publication number: 20110139315
    Abstract: A high-strength galvanized steel sheet has a TS of at least 590 MPa and excellent ductility and stretch flangeability and a method for manufacturing the high-strength galvanized steel sheet. The galvanized steel sheet contains, on the basis of mass percent, C: 0.05% to 0.3%, Si: 0.01% to 2.5%, Mn: 0.5% to 3.5%, P: 0.003% to 0.100% or less, S: 0.02% or less, and Al: 0.010% to 1.5%. The total of Si and Al is 0.5% to 2.5%. The remainder are iron and incidental impurities, contain 20% or more of ferrite phase, 10% or less of martensite phase, and 10% to 60% of tempered martensite, on the basis of area percent, and 3% to 10% of retained austenite phase on the basis of volume fraction. The retained austenite has an average grain size of 2.0 ?m or less.
    Type: Application
    Filed: January 19, 2009
    Publication date: June 16, 2011
    Applicant: JFE STEEL CORPORATION
    Inventors: Tatsuya Nakagaito, Saiji Matsuoka, Shinjiro Kaneko, Yoshiyasu Kawasaki, Yoshitsugu Suzuki
  • Patent number: 7959745
    Abstract: A high-strength steel pipe having a strength of API X65 grade or higher consisting essentially of, by mass %, 0.02 to 0.08% of C, 0.01 to 0.5% of Si, 0.5 to 1.8% of Mn, 0.01% or less of P, 0.002% or less of S, 0.01 to 0.7% of Al, 0.005 to 0.04% of Ti, 0.05 to 0.50% Mo, at least one element selected from 0.005 to 0.05% of Nb and 0.005 to 0.10% of V, and the balance being Fe, in which the volume percentage of the ferritic phase is 90% or higher, and complex carbides containing Ti, Mo, and at least one element selected from the group consisting of Nb and V are precipitated in the ferritic phase. The high-strength steel pipe has excellent HIC resistance and good toughness of a heat-affected zone, and can be manufactured stably at a low cost.
    Type: Grant
    Filed: May 15, 2006
    Date of Patent: June 14, 2011
    Assignee: JFE Steel Corporation
    Inventors: Nobuyuki Ishikawa, Toyohisa Shinmiya, Shigeru Endo, Minoru Suwa
  • Publication number: 20110126944
    Abstract: A thick-walled high-strength hot rolled steel sheet has a high tensile strength TS of 521 MPa or more and excellent low-temperature toughness. The steel material forming the sheet contains 0.02%-0.08% C, 0.01%-0.10% Nb, and 0.001%-0.05% Ti and is heated; C, Ti, and Nb satisfies (Ti+(Nb/2))/C<4.
    Type: Application
    Filed: July 31, 2009
    Publication date: June 2, 2011
    Applicant: JFE STEEL CORPORATION
    Inventors: Chikara Kami, Hiroshi Nakata, Kinya Nakagawa
  • Patent number: 7935197
    Abstract: A high strength steel plate containing 0.02 to 0.08% C, by mass, and has substantially a two phase microstructure of ferrite and bainite. The ferrite contains precipitates having a particle size of 30 nm or smaller grain size. The steel plate has a yield strength of 448 MPa or higher. A method for manufacturing the high strength steel plate which comprises hot rolling, accelerated cooling and reheating. The accelerated cooling is conducted down to a temperature of 300 to 600° C. at a cooling rate of 5° C./s or higher. The reheating is conducted up to a temperature of 550 to 700° C. at a heating rate of 0.5° C./s or higher.
    Type: Grant
    Filed: September 19, 2006
    Date of Patent: May 3, 2011
    Assignee: JFE Steel Corporation
    Inventors: Nobuyuki Ishikawa, Toyohisa Shinmiya, Minoru Suwa, Shigeru Endo
  • Patent number: 7931757
    Abstract: A thick-walled seamless steel pipe for line pipe which has a high strength and improved toughness and corrosion resistance in spite of the thick wall and which is suitable for use as a riser and flow line has a chemical composition comprising, in mass percent, C: 0.02-0.08%, Si: at most 0.5%, Mn: 1.5-3.0%, Al: 0.001-0.10%, Mo: greater than 0.4%-1.2%, N: 0.002-0.015%, at least one of Ca and REM in a total amount of 0.0002-0.007%, and a remainder of Fe and impurities, with the impurities having the content of P: at most 0.05%, S: at most 0.005%, and O: at most 0.005%, the chemical composition satisfying the inequality: 0.8?[Mn]×[Mo]?2.6, wherein [Mn] and [Mo] are the numbers equivalent to the contents of Mn and Mo, respectively, in mass percent.
    Type: Grant
    Filed: February 21, 2008
    Date of Patent: April 26, 2011
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kunio Kondo, Yuji Arai, Nobuyuki Hisamune
  • Patent number: 7922968
    Abstract: Provided are a steel sheet for an automotive muffler and a method for producing the steel sheet. The steel sheet includes 0.01% by weight or less of C, 0.1 to 0.3% by weight of Si, 0.3 to 0.5% by weight of Mn, 0.015% by weight or less of P, 0.015% or less by weight of S, 0.02 to 0.05% by weight of Al, 0.004% or less of N, 0.2 to 0.6% by weight of Cu, 0.01 to 0.04% by weight of Co, and a remainder of Fe and unavoidable impurities. The method includes 0.01% by weight or less of C, 0.1 to 0.3% by weight of Si, 0.3 to 0.5% by weight of Mn, 0.015% by weight or less of P, 0.015% or less by weight of S, 0.02 to 0.05% by weight of Al, 0.004% or less of N, 0.2 to 0.6% by weight of Cu, 0.01 to 0.
    Type: Grant
    Filed: October 25, 2006
    Date of Patent: April 12, 2011
    Assignee: Posco
    Inventors: Won-Ho Son, Jai-Ik Kim, Seung-Hee Lee, Jeong-Bong Yoon, Hee-Man Son
  • Patent number: 7922838
    Abstract: The present invention provides: a steel for a welded structure to be used for a crude oil tank that exhibits excellent general and local corrosion resistance in crude oil corrosion caused in a steel oil tank and is capable of suppressing the formation of corrosion products (sludge) containing solid sulfur; a method for producing said steel; a crude oil tank; and a method for preventing a crude oil tank against corrosion. The present invention makes it possible to obtain general and local corrosion resistance in a crude oil tank environment and suppress the formation of corrosion products (sludge) containing solid sulfur by using a steel: containing, in mass, 0.001 to 0.2% C, 0.01 to 2.5% Si, 0.1 to 2% Mn, 0.03% or less P, 0.007% or less S, 0.01 to 1.5% Cu, 0.001 to 0.3% Al, 0.001 to 0.01% N as basic components and, further, 0.01 to 0.2% Mo and/or 0.01 to 0.5% W; and preferably satisfying the following expression; Solute Mo+Solute W?0.005%.
    Type: Grant
    Filed: June 18, 2003
    Date of Patent: April 12, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Akira Usami, Kenji Katoh, Toshiei Hasegawa, Akira Shishibori
  • Patent number: 7914629
    Abstract: The present invention provides high strength thick steel plate superior in crack arrestability high in strength, free of deterioration of HAZ toughness, and free of anisotropy, that steel plate containing, by mass %, C: 0.03 to 0.15%, Si: 0.1 to 0.5%, Mn: 0.5 to 2.0%, P: ?0.02%, S: ?0.01%, Al: 0.001 to 0.1%, Ti: 0.005 to 0.02%, Ni: 0.15 to 2%, and N: 0.001 to 0.008% and having a balance of iron and unavoidable impurities as chemical components, having a microstructure of a ferrite and/or pearlite structure with bainite as a matrix phase, and having an average circle equivalent diameter of crystal grains with a crystal misorientation angle of 15° or more of 15 ?m or less in the regions of 10% of plate thickness from the front and rear surfaces and of 40 ?m or less in the other region including the center part of plate thickness.
    Type: Grant
    Filed: April 13, 2007
    Date of Patent: March 29, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Kiyotaka Nakashima, Masanori Minagawa, Kouji Ishida, Akira Ito
  • Publication number: 20110048589
    Abstract: An ultra-high strength steel sheet has a tensile strength of 1400 MPa or higher that can achieve both high strength and good formability and an advantageous method for manufacturing the steel sheet and includes a composition including, on a mass basis C: 0.12% or more and 0.50% or less; Si: 2.0% or less; Mn: 1.0% or more and 5.0% or less; P: 0.1% or less; S: 0.07% or less; Al: 1.0% or less; and N: 0.008% or less, with the balance Fe and incidental impurities. The steel microstructure includes, on an area ratio basis, 80% or more of autotempered martensite, less than 5% of ferrite, 10% or less of bainite, and 5% or less of retained austenite; and the mean number of precipitated iron-based carbide grains each having a size of 5 nm or more and 0.5 ?m or less and included in the autotempered martensite is 5×104 or more per 1 mm2.
    Type: Application
    Filed: January 29, 2009
    Publication date: March 3, 2011
    Applicant: JFE STEEL CORPORATION
    Inventors: Hiroshi Matsuda, Reiko Mizuno, Yoshimasa Funakawa, Yasushi Tanaka
  • Patent number: 7887648
    Abstract: The invention relates to an ultrahigh-strength thin steel sheet excellent in the hydrogen embrittlement resistance, the steel sheet including, by weight %, 0.10 to 0.60% of C, 1.0 to 3.0% of Si, 1.0 to 3.5% of Mn, 0.15% or less of P, 0.02% or less of S, 1.5% or less of Al, 0.003 to 2.0% of Cr, and a balance including iron and inevitable impurities; in which grains of residual austenite have an average axis ratio (major axis/minor axis) of 5 or more, the grains of the residual austenite have an average minor axis length of 1 ?m or less, and the grains of the residual austenite have a nearest-neighbor distance between the grains of 1 ?m or less.
    Type: Grant
    Filed: December 28, 2006
    Date of Patent: February 15, 2011
    Assignee: Kobe Steel, Ltd.
    Inventors: Junichiro Kinugasa, Fumio Yuse, Yoichi Mukai, Shinji Kozuma, Hiroshi Akamizu, Kouji Kasuya, Muneaki Ikeda, Koichi Sugimoto
  • Publication number: 20110024004
    Abstract: The invention is directed to providing, for application in automobiles, construction materials, household appliances and the like, high-strength sheets excellent in formability properties such as hole expansibility and ductility, and also in fatigue resistance, characterized in comprising, in specified contents expressed in mass %, C, Si, Mn, P, S, Al, N and O and a balance of iron and unavoidable impurities, and having a steel sheet structure composed mainly of ferrite and hard structures, a crystal orientation difference between some ferrite adjacent to hard structures and the hard structures of less than 9°, and a maximum tensile strength of 540 MPa or greater.
    Type: Application
    Filed: April 9, 2009
    Publication date: February 3, 2011
    Inventors: Masafumi Azuma, Noriyuki Suzuki, Naoki Maruyama, Naoki Yoshinaga, Akinobu Murasato
  • Patent number: 7875130
    Abstract: The present invention provides: a steel for a welded structure to be used for a crude oil tank that exhibits excellent general and local corrosion resistance in crude oil corrosion caused in a steel oil tank and is capable of suppressing the formation of corrosion products (sludge) containing solid sulfur; a method for producing said steel; a crude oil tank; and a method for preventing a crude oil tank against corrosion. The present invention makes it possible to obtain general and local corrosion resistance in a crude oil tank environment and suppress the formation of corrosion products (sludge) containing solid sulfur by using a steel: containing, in mass, 0.001 to 0.2% C, 0.01 to 2.5% Si, 0.1 to 2% Mn, 0.03% or less P, 0.007% or less S, 0.01 to 1.5% Cu, 0.001 to 0.3% Al, 0.001 to 0.01% N as basic components and, further, 0.01 to 0.2% Mo and/or 0.01 to 0.5% W; and preferably satisfying the following expression; Solute Mo+Solute W?0.005%.
    Type: Grant
    Filed: September 3, 2009
    Date of Patent: January 25, 2011
    Assignee: Nippon Steel Corporation
    Inventors: Akira Usami, Kenji Katoh, Toshiei Hasegawa, Akira Shishibori