Nickel Containing Patents (Class 148/336)
  • Patent number: 6652991
    Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: November 25, 2003
    Assignee: The Governors of the University of Alberta
    Inventors: You Wang, Weixing Chen
  • Publication number: 20030201039
    Abstract: A cold-rolled steel sheet having an ultrafine grain structure including a ferrite phase is provided. The cold-rolled steel sheet contains C, Si, Mn, Ni, Ti, Nb, Al, P, S, N and Fe and incidental impurities. The ferrite phase has a content of 65 percent by volume or more and an average grain size of 3.5 &mgr;m or less.
    Type: Application
    Filed: March 18, 2003
    Publication date: October 30, 2003
    Applicant: Kawasaki Steel Corporation
    Inventors: Tetsuo Mochida, Kazuhiro Seto, Kei Sakata, Tomohisa Oonishi
  • Patent number: 6638371
    Abstract: A cold-rolled steel sheet having an ultrafine grain structure including a ferrite phase provided. The cold-rolled steel sheet contains C, Si, Mn, Ni, Ti, Nb, Al, P, S, N and Fe and incidental impurities. The ferrite phase has a content of 65 percent by volume or more and an average grain size of 3.5 &mgr;m or less.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: October 28, 2003
    Assignee: Kawasaki Steel Corporation
    Inventors: Tetsuo Mochida, Kazuhiro Seto, Kei Sakata, Tomohisa Oonishi
  • Patent number: 6635126
    Abstract: Steel alloys susceptible to case and core hardening comprising 0.05 to 0.24 weight percent carbon; 15 to 28 weight percent cobalt and 1.5 to 9.5 weight percent in nickel, small percentages of one or more additives: chromium, molybdenum, and vanadium; and the balance iron.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: October 21, 2003
    Assignee: Northwestern University
    Inventors: Charles J. Kuehmann, Gregory B. Olson, John P. Wise, Carelyn Campbell
  • Patent number: 6632298
    Abstract: The present invention aims at providing a sophisticated segregation reducing technique which a conventional technique cannot achieve by finding the relationship between the casting structure and the segregation of components at the time of solidification and the heat treatment conditions. That is, the present invention aims at providing material for shadow masks which exhibits excellent quality with respect to streaks. A material for a shadow mask of the present invention is formed of a casting slab for preparing the shadow mask which comprises an Ni—Fe alloy containing 30 to 45% of Ni. The casting slab has a cast structure comprising a columnar crystal and/or a chill crystal in an amount of 99% or more. In particular, it is preferred that the casting slab contains no equiaxed crystal.
    Type: Grant
    Filed: February 26, 2002
    Date of Patent: October 14, 2003
    Assignees: Toyo Kohan Co., Ltd., Nippon Yakin Kogyo Co., Ltd.
    Inventors: Syun-ichi Morita, Taizo Sato, Jun Agari, Tsutomu Omori, Tatsuya Itoh, Shigeru Hirata
  • Patent number: 6632296
    Abstract: The present invention provides a steel pipe excellent in formability during hydraulic forming and the like and a method to produce the same, and more specifically: a steel pipe excellent in formability having an r-value of 1.4 or larger in the axial direction of the steel pipe, and the property that the average of the ratios of the X-ray intensity in the orientation component group of {110}<110> to {332}<110> on the plane at the center of the steel pipe wall thickness to the random X-ray intensity is 3.5 or larger, and/or the ratio of the X-ray intensity in the orientation component of {110}<110> on the plane at the center of the steel pipe wall thickness to the random X-ray intensity is 5.
    Type: Grant
    Filed: February 6, 2002
    Date of Patent: October 14, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Naoki Yoshinaga, Nobuhiro Fujita, Manabu Takahashi, Yasuhiro Shinohara, Tohru Yoshida, Natsuko Sugiura
  • Patent number: 6605163
    Abstract: Process for manufacturing a strip made of an Fe—Ni alloy of the “&ggr;′ and/or &ggr;″ structural hardening” type, the thermal expansion coefficient between 20° C. and 150° C. of which is less than 7×10−6/K, in which a hot strip is manufactured either by hot rolling a semi-finished product or by direct casting of a thin strip which is optionally lightly hot-rolled, and the hot strip is subjected to a softening annealing operation consisting of a soak between 950° C. and 1200° C. followed by rapid cooling and optionally a pickling operation, in order to obtain a softened strip; a cold-worked strip is manufactured by cold rolling the said softened strip, with a reduction ratio of greater than 5%; and the cold-worked strip is subjected to a recrystallization annealing operation in an inert or reducing atmosphere, carried out either on the run with a residence time between 900° C. and 1200° C.
    Type: Grant
    Filed: August 27, 2001
    Date of Patent: August 12, 2003
    Assignee: Imphy Ugine Precision
    Inventors: Ricardo Cozar, Jean-Pierre Reyal, Pierre Louis Reydet
  • Patent number: 6600259
    Abstract: This invention provides, as a means of securing magnetic shield properties for a semi-tension mask and precluding color irregularity or mislanding on the phosphor due to beam drift, a Fe—Ni alloy for semi-tension mask comprising, in mass percentage (%), from 34 to 45% Ni, from 0.01 to 0.
    Type: Grant
    Filed: May 24, 2002
    Date of Patent: July 29, 2003
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventors: Toshiyuki Ono, Masazumi Mori
  • Patent number: 6596098
    Abstract: The present invention relates to a wire rod for high fatigue-strength steel wire of small diameter, and a wire rod used in steel wire obtained by twisting these together, a steel wire and a method of producing the same. The wire rod for steel wire and the steel wire have a microstructure obtained by controlled cooling following hot rolling of a steel, containing, in mass %, 0.6-1.3% of C, 0.1-1.5% of Si and 0.2-1.5% of Mn wherein the area ratio of upper bainite measured in a cross-section thereof is 5-50%, the remainder being substantially composed of pearlite. The production method thereof comprises drawing and patenting a wire rod of 5-16 mm diameter having the aforesaid composition to obtain a wire of 0.8-2.8 mm diameter, then austenitizing the wire, quenching it to a temperature range of 500-560° C.
    Type: Grant
    Filed: September 27, 2000
    Date of Patent: July 22, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Seiki Nishida, Atsuhiko Yoshie
  • Patent number: 6592810
    Abstract: Disclosed is an Fe—Ni alloy consisting of, by mass, 30 to 50% of Ni (or 27 to 47% Ni and not more than 22% Co), 0.005 to 0.1% of Nb, less than 0.01% of C, 0.002 to 0.02% of N, and the balance of Fe and inevitable impurities, wherein the equation “0.000013≦(% Nb)×(% N)≦0.002”, is fulfilled. In the alloy, preferably, the maximum grain size of compounds primarily containing Nb and nitrogen and other compounds primarily containing Nb and C is less than 0.5 &mgr;m, which can be observed at an fractional section of metal structure, and a total number of the compounds is not less than 50,000/mm2 at an fractional section. An average grain size of the alloy structure is not less than 10 by the crystal grain size number as defined in JIS G0551. The alloy may applied to shadow masks for the Braun tube and lead frames for semiconductor elements.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: July 15, 2003
    Assignee: Hitachi Metals, Ltd.
    Inventors: Junichi Nishida, Ryoji Inoue, Takehisa Seo
  • Patent number: 6589369
    Abstract: A compound structure steel sheet excellent in burring workability made of a steel containing, by mass, 0.01 to 0.3% of C, 0.01 to 2% of Si, 0.05 to 3% of Mn, 0.1% or less of P, 0.01% or less of S, and 0.005 to 1% or Al, and having the microstructure being a compound structure having ferrite as the main phase and martensite or retained austenite mainly as the second phase, the quotient of the volume percentage of the second phase divided by the average grain size of the second phase being 3 or more and 12 or less, and the quotient of the average hardness of the second phase divided by the average hardness of the ferrite being 1.5 or more and 7 or less; or a compound structure steel sheet excellent in burring workability made of a steel containing, by mass, 0.01 to 0.3% of C, 0.01 to 2% of Si, 0.05 to 3% of Mn, 0.1% or less of P, 0.01% or less of S, and 0.
    Type: Grant
    Filed: July 25, 2001
    Date of Patent: July 8, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Tatsuo Yokoi, Manabu Takahashi, Hiroyuki Okada, Toshimitsu Aso
  • Patent number: 6572714
    Abstract: The creep property of a shadow mask, which has cathode-ray passing apertures, in the form of dots or slots formed by etching, and to which tension is then applied without undergoing press-forming, is enhanced. The Fe—Ni alloy containing from 30-50% of Ni, the balance consisting of iron and unavoidable impurities, has cold working temper of not less than 30% and not more than 57% of the final working degree.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: June 3, 2003
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventors: Tetsuo Kawahara, Norio Yuki, Kazuhiro Taki
  • Publication number: 20030098098
    Abstract: Marine structures are provided that are constructed from ultra-high strength, low alloy steels containing less than 2.5 wt % nickel and having a tensile strength greater than 900 MPa (130 ksi). A primary benefit is that the marine structures of this invention have a cost per unit strength substantially lower than that of currently available marine structures.
    Type: Application
    Filed: November 25, 2002
    Publication date: May 29, 2003
    Inventors: Clifford W. Petersen, Moses Minta, Ann T. Leger
  • Patent number: 6565678
    Abstract: Weld metals suitable for joining high strength, low alloy steels are provided. These weld metals have microstructures of acicular ferrite interspersed in a hard constituent, such as lath martensite, yield strengths of at least about 690 MPa (100 ksi), and DBTTs lower than about −50° C. (−58° F.) as measured by a Charpy energy versus temperature curve. These weld metals include about 0.04 wt % to about 0.08 wt % carbon; about 1.0 wt % to about 2.0 wt % manganese; about 0.2 wt % to about 0.7 wt % silicon; about 0.30 wt % to 0.80 wt % molybdenum; about 2.3 wt % to about 3.5 wt % nickel; about 0.0175 wt % to about 0.0400 wt % oxygen, and at least one additive selected from the group consisting of (i) up to about 0.04 wt % zirconium, and (ii) up to about 0.02 wt % titanium.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: May 20, 2003
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Douglas P. Fairchild, Jayoung Koo, Narasimha-Rao V. Bangaru, Mario Luis Macia, Danny Lee Beeson, Adnan Ozekcin
  • Patent number: 6551419
    Abstract: The present invention provides a hot rolled steel wire rod or bar for machine structural use having, in the as-hot-rolled condition, cold workability equal to that of the conventional wire rods or bars softened through annealing after hot rolling, and a method to produce the same: and relates to a hot rolled steel wire rod or bar for machine structural use, characterized in that; the wire rod or bar is made from a steel consisting of, in weight, 0.1 to 0.5% of C, 0.01 to 0.5% of Si, 0.3 to 1.5% of Mn, and the balance comprising Fe and unavoidable impurities and containing strengthening elements as required; its microstructure consists of ferrite and pearlite; its ferrite crystal grain size number defined under Japanese Industrial Standard (JIS) G 0552 is 11 or higher; and a granular carbide 2 &mgr;m or less in circle-equivalent diameter and having an aspect ratio of 3 or less accounts for a percentage area of 3 to 15%.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: April 22, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Hideo Kanisawa, Tatsuro Ochi, Manabu Kubota, Koji Tanabe, Kiichiro Tsuchida
  • Patent number: 6547893
    Abstract: It is a Fe—Ni based shadow mask material of Fe—Ni alloy or Fe—Ni—Co alloy used as a material for a color television cathode tube or the like, and relates to a material wherein the material has a texture that an X-ray intensity ratio Ir of cubic orientation (100)<001> to twinning orientation (221)<212> thereof in a (111) pole figure is a range of 0.5-5:1 and segregation of Ni, Mn or the like is less, and a section cleanness defined according to JIS G0555 is made to be not more than 0.05% to reduce the occurrence of streak or mottling in the etching.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: April 15, 2003
    Assignee: Nippon Yakin Kogyo Co., Ltd.
    Inventors: Tatsuya Itoh, Tsutomu Omori
  • Patent number: 6547890
    Abstract: The present invention provides a steel wire rod for cold forging which can be spheroidizing-annealed in an as hot-rolled state without requiring preliminary drawing and can have high ductility after the spheroidizing annealing, and a method to produce the same: and is characterized in that; the steel contains, by weight, 0.1 to 0.5% of C, 0.01 to 0.5% of Si and 0.3 to 1.5% of Mn, with the balance consisting of Fe and unavoidable impurities, and further contains hardening elements as required; and the steel has a prior austenite grain size number, defined under Japanese Industrial Standard (JIS) G 0551, of 11 or higher, the amount of diffusible hydrogen in the steel measured by the programmed temperature gas chromatography being 0.2 ppm or less, and the hardness being Hv 250 to 700.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: April 15, 2003
    Assignee: Nippon Steel Corporation
    Inventors: Hideo Kanisawa, Tatsuro Ochi, Manabu Kubota, Koji Tanabe, Kiichiro Tsuchida
  • Patent number: 6544356
    Abstract: A steel sheet has composition consisting of 0.003-0.10 wt. % C, not more than 1.0 wt. % Si, 0.05-1.5 wt. % Mn, not more than 0.10 wt. % P, not more than 0.02 wt. % S, 1.5-8.0 wt. % Cr, 0.003-0.10 wt. % Al, at least one of 0.08-0.40 wt. % Ti, 0.08-0.40 wt. % Nb and 0.08-0.40 wt. % V, optionally at least one of Cu up to 2.0 wt. %, Ni up to 2.0 wt. %, 0.01-2.0 wt. % Mo, 0.01-2.0 wt. % W and 0.0003-0.0050 wt. % B and the balance being essentially Fe except inevitable impurities. The steel sheet is good of both a room-temperature strength and a high temperature strength. The new steel sheet is useful as a frame member of a color picture tube for stretching color selecting electrode elements, instead of an expensive ferritic stainless steel.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: April 8, 2003
    Assignees: Nisshin Steel Co., Ltd., Sony Corporation
    Inventors: Yukio Katagiri, Akito Kawamoto, Seiichi Hamanaka, Nobuo Ozawa, Takahide Sanma
  • Patent number: 6540848
    Abstract: A high-strength, high-toughness seamless steel pipe used for a line pipe contains 0.03 to 0.06% of C, 0.05 to 0.15% of Si, 1.6 to 2.0% of Mn, 0.010 to 0.10% of Al, 0.3 to 0.7% of Ni, 0.10 to 0.40% of Mo, 0.01 to 0.06% of V, 0.003 to 0.03% of Nb, 0.003 to 0.020% of Ti, and 0.0010 to 0.0100% of N, the relationships Mo+5V≧0.4% and 2Nb−V≦0% being satisfied, and the balance being Fe and incidental impurities. Consequently, it is possible to provide the high-strength, high-toughness seamless steel pipe used for a line pipe in which grade X80 strength and toughness are stably ensured, and the target strength can be easily attained regardless of the size.
    Type: Grant
    Filed: August 29, 2001
    Date of Patent: April 1, 2003
    Assignee: Kawasaki Steel Corporation
    Inventors: Yukio Miyata, Mitsuo Kimura, Takaaki Toyooka, Noritsugu Itakura
  • Patent number: 6528012
    Abstract: In a welded structure and welded pipe, having members joined to each other by welding wherein, at least one of the members is formed of Fe—Ni-base low thermal expansion coefficient alloy, there is provided a welded structure and welded pipe having a weld metal free from cracking and achieving an excellent toughness and stress corrosion cracking resistance. Further, a welding material is provided which can form such a weld metal and is excellent in workability and weldability in fabrication. The weld metal comprises, on the weight % basis, Ni: 30 to 45%, Co: 0 to 10%, C: 0.03 to 0.5%, Mn: 0.7% or less, either one of or the total of Nb and Zr: 0.05 to 4%, and rare earth element: 0 to 0.5%, with impurities being P: 0.02% or less, Al: 0.01% or less, and oxygen: 0.
    Type: Grant
    Filed: March 30, 2001
    Date of Patent: March 4, 2003
    Assignees: Sumitomo Metal Industries, Ltd., Osaka Gas Co., Ltd., Kawasaki Jukogyo Kabushiki Kaisha
    Inventors: Kazutoshi Nishimoto, Naoshige Kubo, Hiroshi Iwahashi, Shuji Yamamoto, Hidefumi Yamanaka, Shinji Koga, Yutaka Chida, Taketo Yamakawa, Kouji Michiba, Hiroyuki Hirata, Kazuhiro Ogawa, Toshinobu Nishibata
  • Patent number: 6508892
    Abstract: A shadow mask blank of Fe—Ni alloy which exhibits excellent uniformity of diameter of apertures formed by perforation with etching for the passage of electron beams, consisting of 34-38% Ni, 0.05-0.5% Mn, 4-20 ppm S, and the balance Fe and no more than specified limits of C, Si, Al, and P, with MnS inclusions 50-1,000 nm in diameter dispersed at the density of at least 1,500/mm2 or simply with etched holes 0.5-10 &mgr;m in diameter emerging at the density of at least 2,000/mm2 when the blank is immersed in a 3% nitric acid-ethyl alcohol solution at 20° C. for 30 seconds. A method of manufacturing the blank comprises hot rolling of a slab of the Fe—Ni alloy, cooling, recrystallization annealing, cold rolling, etc. under controlled conditions: e.g., hot rolling the slab at 950-1,250° C. to 2-6 mm thick, cooling the stock in the range of 900-700° C. at the rate of 0.5° C./second, continuously passing the stock through a heating furnace at 850-1,100° C.
    Type: Grant
    Filed: April 12, 2001
    Date of Patent: January 21, 2003
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventors: Takaaki Hatano, Yoshihisa Kita
  • Patent number: 6500281
    Abstract: In the production or a shadow mask, the through-holes for passing an electron beam are formed by etching of the Fe—Ni alloy. The variation in diameter of apertures is prevented by dispersing 2000 or more of precipitates and inclusions from 0.01 &mgr;m to 5 &mgr;m in diameter on the surface of said material per mm2. The Fe—Ni alloy of from 34 to 38% of Ni, not more than 0.5% of Mn, and if necessary, from 5 to 40 ppm of B, and from 5 to 40 ppm of N, the balance being Fe and unavoidable and incidental impurities with the proviso of 0.10% or less of C, 0.30% or less of Si, 0.30% or less of Al, 0.005% or less of S, and 0.005% or less of P.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: December 31, 2002
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventor: Ikuya Kurosaki
  • Patent number: 6485582
    Abstract: Steel alloys susceptible to case and core hardening comprising 0.05 to 0.24 weight percent carbon; 15 to 28 weight percent cobalt and 1.5 to 9.5 weight percent in nickel, small percentages of one or more additives: chromium, molybdenum, and vanadium; and the balance iron.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: November 26, 2002
    Inventors: Charles J. Kuehmann, Gregory B. Olson, John P. Wise, Carelyn Campbell
  • Patent number: 6475305
    Abstract: The present invention is directed to a steel product for machine structural use having excellent machinability and to a structural steel part for machinery manufactured from the steel product. More particularly, the invention is directed to a steel product for machine structural use having excellent machinability, particularly bringing about excellent “drill life” and exhibiting excellent “chip disposability” in the course of drilling, as well as to a structural steel part for machinery manufactured from the steel product. The steel product for machine structural use has a chemical composition comprising, in mass percent, C: 0.05% to 0.55%; Si: 0.50% to 2.5%; Mn: 0.01% to 2.00%; P: not greater than 0.035%; S: 0.005% to 0.2%; N: not greater than 0.0150%; elements to be added as needed: Cu, Ni, Cr, Mo, V, Nb, Ti, B, Al, Bi, Ca, Pb, Te, Nd, and Se; −23C+Si(5−2Si)−4Mn+104S−3Cr−9V+10≧0; 3.2C+0.8Mn+5.2S+0.5Cr−120N+2.
    Type: Grant
    Filed: September 26, 2000
    Date of Patent: November 5, 2002
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Koji Watari, Yasutaka Okada
  • Patent number: 6464801
    Abstract: Steel alloys susceptible to case and core hardening comprising 0.05 to 0.24 weight percent carbon; 15 to 28 weight percent cobalt and 1.5 to 9.5 weight percent in nickel, small percentages of one or more additives: chromium, molybdenum, and vanadium; and the balance iron.
    Type: Grant
    Filed: August 14, 2001
    Date of Patent: October 15, 2002
    Assignee: Northwestern University
    Inventors: Charles J. Kuehmann, Gregory B. Olson, John P. Wise, Carelyn Campbell
  • Publication number: 20020134469
    Abstract: Process for manufacturing a strip made of an Fe—Ni alloy of the “&ggr;′ and/or &ggr;″ structural hardening” type, the thermal expansion coefficient between 20° C. and 150° C. of which is less than 7×10−6/K, in which a hot strip is manufactured either by hot rolling a semi-finished product or by direct casting of a thin strip which is optionally lightly hot-rolled, and the hot strip is subjected to a softening annealing operation consisting of a soak between 950° C. and 1200° C. followed by rapid cooling and optionally a pickling operation, in order to obtain a softened strip; a cold-worked strip is manufactured by cold rolling the said softened strip, with a reduction ratio of greater than 5%; and the cold-worked strip is subjected to a recrystallization annealing operation in an inert or reducing atmosphere, carried out either on the run with a residence time between 900° C. and 1200° C.
    Type: Application
    Filed: August 27, 2001
    Publication date: September 26, 2002
    Inventors: Ricardo Cozar, Jean-Pierre Reyal, Pierre Louis Reydet
  • Publication number: 20020124913
    Abstract: Disclosed is a ferritic Fe—Cr—Ni—Al alloy having excellent oxidation resistance and high strength, which consists essentially of, by mass, 0.003 to 0.08% C, 0.03 to 2.0% Si, not more than 2.0% Mn, from more than 1.0% to not more than 8.0% Ni, from not less than 10.0% to less than 19.0% Cr, 1.5 to 8.0% Al, 0.05 to 1.0% Zr, and the balance of Fe and incidental impurities, wherein an F value is not less than 12% and an S value is not more than 25%, where the F value is defined by the following equation (1) and the S value is defined by the following equation (2): (1) F=−34.3C+0.48Si−0.012Mn−1.4Ni+Cr+2.48Al, and (2) S=Ni+Cr+Al. The Fe—Cr—Ni—Al alloy, after an annealing heat treatment at 600 to 1050° C., has 0.2% yield strength of 550 to 1,000 MPa by a tensile test at room temperature.
    Type: Application
    Filed: December 4, 2001
    Publication date: September 12, 2002
    Applicant: HITACHI METALS, LTD.
    Inventors: Toshihiro Uehara, Yoshihiro Minagi, Kenichi Inoue
  • Patent number: 6447622
    Abstract: The present invention provides a high carbon steel wire remarkably excellent in wire-drawability and fatigue resistance after wire drawing with a low cost due to reduced use of costly alloys. A high carbon steel wire according to the present invention is one excellent in wire-drawability and fatigue resistance after wire drawing, characterized in that; the total oxygen content is 15 to 50 ppm; among non-metallic inclusions included therein, the number of inviscid inclusions is 1.
    Type: Grant
    Filed: February 15, 2001
    Date of Patent: September 10, 2002
    Assignee: Nippon Steel Corporation
    Inventors: Wataru Yamada, Seiki Nishida, Satoshi Sugimaru, Naoshi Hikita, Hiromi Takahashi
  • Patent number: 6436340
    Abstract: Steel is obtained which comprises by wt %, C: 0.001-0.025%, Si: not more than 0.60%, Mn: 0.10-3.00%, P: 0.005-0.030%, S: not more than 0.01%, Al: not more than 0.10%, Cu: 0.1-1.5%, Ni: 0.1-6.0%, B: 0.0001-0.0050%, and the balance being Fe and inevitable impurities; since the steel contains C and P in small contents, stable amorphous rusts are formed on the surface thereof at an early stage; and steel simultaneously realizes excellent weather resistance, material weldability and toughness particularly in an environment such as a seashore district and the like where salt is present in a large amount.
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: August 20, 2002
    Assignee: Kawasaki Steel Corporation
    Inventors: Kazuhiko Shiotani, Akio Ohmori, Kimihiro Nishimura, Yasuyoshi Yamane, Fumimaru Kawabata, Keniti Amano
  • Patent number: 6432228
    Abstract: The present invention provides a ferritic steel sheet, the quasi-static strength of which is enhanced and further the dynamic strength of which is not lowered. There is provided a ferritic steel sheet excellent at strain rate sensitivity characterized in that: Co and/or Cr are contained at pot less than 0.01 mass % and not more than 4.0 mass % in total in the state of solid solution in the ferrite phase.
    Type: Grant
    Filed: July 28, 2000
    Date of Patent: August 13, 2002
    Assignee: Nippon Steel Corporation
    Inventors: Akihiro Uenishi, Yukihisa Kuriyama
  • Patent number: 6428633
    Abstract: In order to conduct welding so that the welded steel shows a decreased residual stress after welding without a post treatment such as a PWHT, the steel for welded structures and the welding wire of the present invention starts a transformation from austenite into martensite at a temperature (Ms temperature) from at least 200° C. to up to 350° C., and has a yield strength from at least 60 kg/mm2 to up to 120 kg/mm2 at the transformation starting temperature. The multipass welding process of the present invention comprises forming a weld metal having a Ms temperature of 150° C. to 300° C., and TIG remelt-run welding the surface of the final layer.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: August 6, 2002
    Assignee: Nippin Steel Corporation
    Inventors: Tadashi Kasuya, Shigeru Ohkita, Masao Fuji, Naoki Saitou, Junichi Kobayashi, Toshihiko Chiba
  • Patent number: 6406565
    Abstract: The present invention provides a spring steel showing a sufficient reduction in area and an impact toughness while the steel has a high strength, in particular a tensile strength as high as at least 1,500 Mpa. A high toughness spring steel according to the present invention comprises, based on mass, 0.45 to 0.85% of C, 0.9 to 2.5% of Si, 0.1 to 1.2% of Mn, 0.1 to 2.0% of Cr, 0.005 to 0.07% of Ti, 0.001 to 0.007% of N, the Ti content being greater than four times the N content in terms of percent by mass, 0.0005 to 0.0060% B, at least one of 0.0005 to 0.01% Mg, 0.0005 to 0.01% La, and 0.0005 to 0.01% Ce, P and S with restrictive contents of less than 0.020% and less than 0.020%, respectively, and the balance of Fe and unavoidable impurities, and selectively contains V, Nb, Ni, Mo and Cu. The percent area of oxides and sulfides is not more than 0.1%.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: June 18, 2002
    Assignee: Nippon Steel Corporation
    Inventors: Masayuki Hashimura, Hiroshi Hagiwara, Takanari Miyaki, Toshio Banno
  • Patent number: 6395108
    Abstract: A flat product made of multiphase steel and a method for preparing the steel includes hot rolling at a temperature at which the austenite phase is stable, then tempering to form a C and Mn-enriched phase in a matrix, followed by a heat treatment to form austenite islands and/or enriching in Mn the already formed austenite and cooling down to room temperature so as to obtain a final product with a ferrite matrix containing residual austenite, bainite and/or martensite islands.
    Type: Grant
    Filed: April 30, 2001
    Date of Patent: May 28, 2002
    Assignee: Recherche et Developpement du Groupe Cockerill Sambre
    Inventors: Klaus Eberle, Philippe Harlet, Pierre Cantinieaux
  • Publication number: 20020059967
    Abstract: A maraging steel strip or part and process for manufacture of a strip or of a part cut out of a strip of cold-rolled maraging steel and hardened by a hardening heat treatment. In the process, before the hardening heat treatment is performed, the strip or the part is subjected to cold plastic deformation with a degree of working greater than 30% and the strip or the part is subjected to recrystallization annealing in order to obtain a fine-grained structure with ASTM index higher than 8. The composition by weight of the maraging steel is: 12%≦Ni≦24.5%; 2.5%≦Mo≦12%; 4.17%≦Co≦20%, Al%≦0.15%; Ti≦0.1%; N≦0.003%; Si≦0.1%; Mn≦0.1%; C≦0.005%; S≦0.001%; P≦0.005%; H≦0.0003%; O≦0.001%; iron and impurities resulting from smelting, the chemical composition also satisfying the relationships: 20%≦Ni+Mo≦27%; 50≦Co×Mo≦200; Ti×N≦2×10−4.
    Type: Application
    Filed: November 19, 2001
    Publication date: May 23, 2002
    Applicant: IMPHY UGINE PRECISION
    Inventor: Lucien Coutu
  • Publication number: 20020043306
    Abstract: Fe—Ni—Co alloy whose chemical composition contains, by weight: 32%≦Ni≦34%, 3.5%≦Co≦6.5%, 0%≦Mn≦0.1%, 0%≦Si≦0.1%≦0%≦Cr≦0.1%, 0.005%≦C≦0.02%, S≦0.001%, 0.0001%≦Ca≦0.002%, 0.0001%≦Mg≦0.002%, the substantial remainder preferably being iron and impurities resulting from smelting; the chemical composition of the alloy furthermore satisfying the relationships: Co+Ni≦38.5%, Co+0.5×Ni≧20%, Co+5×Ni≧165.5% and S≦0.02≦Mn+0.8×Ca+0.6×Mg. Use of the alloy for the manufacture of a shadow mask for a display cathode ray tube.
    Type: Application
    Filed: August 29, 2001
    Publication date: April 18, 2002
    Applicant: IMPHY S.A.
    Inventors: Ricardo Cozar, Marie-Paul Solignac
  • Publication number: 20020043305
    Abstract: Weld metals suitable for joining high strength, low alloy steels are provided. These weld metals have microstructures of acicular ferrite interspersed in a hard constituent, such as lath martensite, yield strengths of at least about 690 MPa (100 ksi), and DBTTs lower than about −50° C. (−58° F.) as measured by a Charpy energy versus temperature curve. These weld metals include about 0.04 wt % to about 0.08 wt % carbon; about 1.0 wt % to about 2.0 wt % manganese; about 0.2 wt % to about 0.7 wt % silicon; about 0.30 wt % to 0.80 wt % molybdenum; about 2.3 wt % to about 3.5 wt % nickel; about 0.0175 wt % to about 0.0400 wt % oxygen, and at least one additive selected from the group consisting of (i) up to about 0.04 wt % zirconium, and (ii) up to about 0.02 wt % titanium.
    Type: Application
    Filed: August 2, 2001
    Publication date: April 18, 2002
    Applicant: EXXONMOBIL UPSTREAM RESEARCH COMPANY
    Inventors: Douglas P. Fairchild, Jayoung Koo, Narasimha-Rao V. Bangaru, Mario Luis Macia, Danny Lee Beeson, Adnan Ozekcin
  • Patent number: 6372058
    Abstract: A low-expansion Fe—Ni based alloy for semi-tension masks with excellent creep properties consists of, in mass percentage, from 34 to 38% Ni, from 0.01 to 0.5% Mn, from 0.0003 to 0.0015% B, from 0.0010 to 0.0050% N, and the balance Fe and unavoidable impurities. The alloy further includes from 0.005 to 0.20% Si and from 0.005 to 0.030% Al. Among the unavoidable impurities, C, P and S are controlled to no more than 0.010%, no more than 0.015%, and no more than 0.010%, respectively. The alloy is subjected, at least once after hot rolling or after cold rolling, to annealing in a non-oxidizing atmosphere at between 650 and 750° C. for from 30 minutes to less than 5 hours. The alloy is subjected to stress relief annealing after final cold rolling. A semi-tension mask using the alloy and a color picture tube using the semi-stretched-tension mask, are also provided.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: April 16, 2002
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventor: Toshiyuki Ono
  • Patent number: 6364968
    Abstract: The invention provides a thin high-strength hot-rolled steel sheet with a thickness of not more than 3.5 mm which has excellent stretch flangeability and high uniformity in both shape and mechanical properties of the steel sheet, as well as a method of producing the hot-rolled steel sheet. A slab containing C: 0.05-0.30 wt %, Si: 0.03-1.0 wt %, Mn: 1.5-3.5 wt %, P: not more than 0.02 wt %, S: not more than 0.005 wt %, Al: not more than 0.150 wt %, N: not more than 0.0200 wt %, and one or two of Nb: 0.003-0.20 wt % and Ti: 0.005-0.20 wt % is heated at a temperature of not higher than 1200° C. The slab is hot-rolled at a finish rolling end temperature of not lower than 800° C., preferably at a finish rolling start temperature of 950-1050° C. A hot-rolled sheet is started to be cooled within two seconds after the end of the rolling, and then continuously cooled down to a coiling temperature at a cooling rate of 20-150° C./sec. The hot-rolled sheet is coiled at a temperature of 300-550° C.
    Type: Grant
    Filed: June 2, 2000
    Date of Patent: April 2, 2002
    Assignee: Kawasaki Steel Corporation
    Inventors: Eiko Yasuhara, Akio Tosaka, Osamu Furukimi, Takao Uchiyama, Nobuo Yamada
  • Patent number: 6361625
    Abstract: A high-strength, high damage-resistant rail made of 0.6 to 0.85 wt % C, 0.1 to 1.0 wt % Si, 0.5 to 1.5 wt % Mn, 0.035 wt % or less P, 0.040 wt % or less S, and 0.05 wt % or less Al, with the balance being Fe and inevitable impurities, and having corner and head side portions having a Brinell hardness of 341 to 405, and a head top portion in which a Brinell hardness of a site 20-mm distant from the central portion of the head top portion in a width direction is 341 to 405, and a hardness of the central portion of the head top portion is at least 10 lower in Brinell hardness than that of the site 20-mm distant from the central portion.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: March 26, 2002
    Assignee: NKK Corporation
    Inventors: Masahisa Fujikake, Jun Furukawa, Kiyotaka Morioka, Kozo Fukuda, Hideyuki Yamanaka, Kazutaka Kobayashi, Shinichi Nagahashi
  • Patent number: 6344095
    Abstract: A low-thermal expansion cast steel having an average linear thermal expansion coefficient of less than 4.0×10−6/° C. in a range of room temperature to 100° C. and excellent machinability has a chemical composition (by mass) comprising 0.4-0.8% of C, 0.5% or less of Si, 1.0% or less of Mn, 0.01-0.3% of S, 30-40% of Ni, and 0.005-0.1% of Mg, the balance being substantially Fe and inevitable impurities, the contents of S and Mn satisfying S≦(1/4) Mn or (1/4) Mn<S≦(1/4) Mn+0.05.
    Type: Grant
    Filed: July 7, 2000
    Date of Patent: February 5, 2002
    Assignee: Hitachi Metals, Ltd.
    Inventors: Masahide Kawabata, Toshihiro Uehara
  • Publication number: 20020011287
    Abstract: In a welded structure and welded pipe, having members joined to each other by welding wherein, at least one of the members is formed of Fe—Ni-base low thermal expansion coefficient alloy, there is provided a welded structure and welded pipe having a weld metal free from cracking and achieving an excellent toughness and stress corrosion cracking resistance. Further, a welding material is provided which can form such a weld metal and is excellent in workability and weldability in fabrication.
    Type: Application
    Filed: March 30, 2001
    Publication date: January 31, 2002
    Inventors: Kazutoshi Nishimoto, Naoshige Kubo, Hiroshi Iwahashi, Shuji Yamamoto, Hidefumi Yamanaka, Shinji Koga, Yutaka Chida, Taketo Yamakawa, Kouji Michiba, Hiroyuki Hirata, Kazuhiro Ogawa, Toshinobu Nishibata
  • Publication number: 20020006350
    Abstract: Disclosed is an Fe—Ni alloy consisting of, by mass, 30 to 50% of Ni (or 27 to 47% Ni and not more than 22% Co), 0.005 to 0.1% of Nb, less than 0.01% of C, 0.002 to 0.02% of N, and the balance of Fe and inevitable impurities, wherein the equation “0.000013≦(% Nb)×(% N)≦0.002”, is fulfilled. In the alloy, preferably, the maximum grain size of compounds primarily containing Nb and nitrogen and other compounds primarily containing Nb and C is less than 0.5 &mgr;m, which can be observed at an fractional section of metal structure, and a total number of the compounds is not less than 50,000/mm2 at an fractional section. An average grain size of the alloy structure is not less than 10 by the crystal grain size number as defined in JIS G0551. The alloy may applied to shadow masks for the Braun tube and lead frames for semiconductor elements.
    Type: Application
    Filed: March 19, 2001
    Publication date: January 17, 2002
    Inventors: Junichi Nishida, Ryoji Inoue, Takehisa Seo
  • Publication number: 20020003008
    Abstract: The invention relates to a martensitic-hardenable heat-treated steel, having the following composition (data in % by weight): 9 to 13% Cr, 0.001 to 0.25% Mn, 2 to 7% Ni, 0.001 to 8% Co, at least one of W and Mo in total between 0.5 and 4%, 0.5 to 0.8% V, at least one of Nb, Ta, Zr and Hf in total between 0.001 and 0.1%, 0.001 to 0.05% Ti, 0.001 to 0.15% Si, 0.01 to 0.1% C, 0.12 to 0.18% N, at most 0.025% P, at most 0.015% S, at most 0.01% Al, at most 0.0012% Sb, at most 0.007% Sn, at most 0.012% As, remainder iron and customary impurities, and the proviso that the ratio by weight of vanadium to nitrogen V/N lies in the range between 3.5 and 4.2. After solution annealing at 1050 to 1250° C., cooling to a temperature below 300° C., tempering treatment, partial or complete reaustenitization at 600 to 900° C., cooling to a temperature below 300° C. and annealing at a temperature from 550 to 650° C., it has a high resistance to heat combined, at the same time, with a high ductility.
    Type: Application
    Filed: May 4, 2001
    Publication date: January 10, 2002
    Inventors: Alkan Goecmen, Peter Ernst
  • Publication number: 20010047839
    Abstract: A shadow mask blank of Fe—Ni alloy which exhibits excellent uniformity of diameter of apertures formed by perforation with etching for the passage of electron beams, consisting of 34-38% Ni, 0.05-0.5% Mn, 4-20 ppm S, and the balance Fe and no more than specified limits of C, Si, Al, and P, with MnS inclusions 50-1,000 nm in diameter dispersed at the density of at least 1,500/mm2 or simply with etched holes 0.5-10 &mgr;m in diameter emerging at the density of at least 2,000/mm2 when the blank is immersed in a 3% nitric acid-ethyl alcohol solution at 20° C. for 30 seconds. A method of manufacturing the blank comprises hot rolling of a slab of the Fe—Ni alloy, cooling, recrystallization annealing, cold rolling, etc. under controlled conditions: e.g., hot rolling the slab at 950-1,250° C. to 2-6 mm thick, cooling the stock in the range of 900-700° C. at the rate of 0.5° C./second, continuously passing the stock through a heating furnace at 850-1,100° C.
    Type: Application
    Filed: April 13, 2001
    Publication date: December 6, 2001
    Inventors: Takaaki Hatano, Yoshihisa Kita
  • Publication number: 20010045246
    Abstract: Iron/nickel alloy having a low coefficient of expansion, the chemical composition of which comprises iron, nickel, manganese, silicon, calcium, magnesium, less than 0.005% of aluminum, less than 0.001% of sulfur, less than 0.01% of oxygen, less than 0.005% of nitrogen, and less than 0.
    Type: Application
    Filed: July 30, 2001
    Publication date: November 29, 2001
    Applicant: IMPHY S.A.
    Inventors: Jacques Baudry, Michel Faral, Jean-Francois Tiers
  • Patent number: 6322642
    Abstract: Process for manufacturing a pressure vessel intended to work under pressure between −40° C. and 200° C. in the presence of H2S under conditions defined by the NACE MR 0175-97 standard, in which: components of the vessel are manufactured from a steel of chemical composition: 0.03%≦C≦0.15%; 0%≦Si≦0.5%; 0.4%≦Mn≦2.5%; 0.5%≦Ni≦3%; 0%≦Cr≦1%; 0%≦Mo≦0.5%; 0%≦Al≦0.070%; 0%≦Ti≦0.04%; 0%≦B≦0.004%; 0%≦V≦0.02%; 0%≦Nb≦0.05%; Cu≦1%; S≦0.015%; P≦0.03%; the balance being iron and impurities resulting from the smelting operation; CET=C+(Mn+Mo)/10+(Cr+Cu)/20+Ni/40<0.35; 800/500 cct<10 s; the components being quenched and tempered; the structure is martensitic or martensitic-bainitic with less than 10% ferrite; the temper temperature is <680° C. Optionally, a stress-relieving operation is carried out at a temperature ≧595° C.
    Type: Grant
    Filed: July 21, 1999
    Date of Patent: November 27, 2001
    Assignee: Creusot Loire Industrie
    Inventors: Pierre Bocquet, Philippe Mabelly, Philippe Bourges
  • Publication number: 20010010241
    Abstract: A hot worked steel material, such as a bar, or tube, has a surface layer improving its fatigue strength despite the non-metallic inclusions which it may contain, or the cracks which it may have. The surface layer is formed by heating a nickel layer on the steel surface to cause the diffusion of nickel therethrough.
    Type: Application
    Filed: January 17, 2001
    Publication date: August 2, 2001
    Inventors: Masayoshi Usui, Kikuo Asada
  • Patent number: 6267827
    Abstract: An Ni—Fe alloy material suitable for forming a ferromagnetic Ni—Fe alloy thin film is provided. The magnetic thin film produces a small number of particles during sputtering, and excels in corrosion resistance and magnetic properties. A method of manufacturing an Ni—Fe alloy sputtering target used to make the thin film is also provided. In addition, an Ni—Fe alloy sputtering target for forming magnetic thin films is provided. The sputtering target is characterized in that it has: an oxygen content of 50 ppm or less; an S content of 10 ppm or less; a carbon content of 50 ppm or less, and a total content of metal impurities other than the alloy components of 50 ppm or less. Such an Ni—Fe alloy target can be produced by melting and alloying high-purity materials obtained by dissolving the raw materials in hydrochloric acid, and performing ion exchange, activated-charcoal treatment, and electrolytic refining.
    Type: Grant
    Filed: March 11, 1999
    Date of Patent: July 31, 2001
    Assignee: Japan Energy Corporation
    Inventors: Yuichiro Shindo, Tsuneo Suzuki
  • Patent number: 6264760
    Abstract: An ultra-high strength steel having excellent ultra-low temperature toughness, a tensile strength of at least about 930 MPa (135 ksi), and a microstructure comprising predominantly fine-grained lower bainite, fine-grained lath martensite, or mixtures thereof, transformed from substantially unrecrystallized austenite grains and comprising iron and specified weight percentages of the additives: carbon, silicon, manganese, copper, nickel, niobium, vanadium, molybdenum, chromium, titanium, aluminum, calcium, Rare Earth Metals, and magnesium, is prepared by heating a steel slab to a suitable temperature; reducing the slab to form plate in one or more hot rolling passes in a first temperature range in which austenite recrystallizes; further reducing said plate in one or more hot rolling passes in a second temperature range below said first temperature range and above the temperature at which austenite begins to transform to ferrite during cooling; quenching said plate to a suitable Quench Stop Temperature; and stop
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: July 24, 2001
    Assignees: ExxonMobil Upstream Research Company, Nippon Steel Corporation
    Inventors: Hiroshi Tamehiro, Hitoshi Asahi, Takuya Hara, Yoshio Terada, Michael J. Luton, Jayoung Koo, Narasimha-Rao V. Bangaru, Clifford W. Petersen
  • Patent number: 6258181
    Abstract: A structural steel excellent in wear resistance and fatigue resistance property, for use as a structural member of a bridge, pylon or the like erected in a shore region where there is concern about steel corrosion and fatigue at weld joint owing to scattering of sea salt particles or in a region where snow-melting salt is used, is provided at low cost and by a simple production method. The hot rolled structural steel contains, in percentage by weight, C: 0.02-0.20%, and further added with small amounts of Ni, Cu and Mo as essential elements, that is a rolled steel excellent in wear resistance and fatigue resistance property having a Ni/Cu concentration ratio of not less than 0.8, a steel surface internal oxide layer of not greater than 2 &mgr;m, and a Ni, Cu and Mo concentrated layer of a thickness of not less than 2 &mgr;m on the internal oxide layer.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: July 10, 2001
    Assignee: Nippon Steel Corporation
    Inventors: Kouichi Yamamoto, Hironori Satoh