Nickel Containing Patents (Class 148/414)
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Patent number: 12139783Abstract: A process for producing a copper-beryllium alloy product. The process comprises preparing a base alloy having 0.15 wt %-4.0 wt % beryllium and having grains and an initial cross section area. The process further comprises cold working the base alloy to a percentage of cold reduction of area (CRA) greater than 40%, based on the initial cross section area, and heat treating the cold worked alloy to produce the copper-beryllium alloy product. The grain structure of the copper-beryllium alloy product has an orientation angle of less than 45° when viewed along the direction of the cold working. The copper-beryllium alloy product demonstrates a fatigue strength of at least 385 MPa after 106 cycles of testing.Type: GrantFiled: May 5, 2020Date of Patent: November 12, 2024Assignee: Materion CorporationInventors: John E. Gatehouse, Michael J. Gedeon, Fritz Grensing, Bruce D. Schmeck, Jeffrey S. Hoyer, Michael F. Tyson, Karl R. Ziegler
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Patent number: 11946127Abstract: [Object] To provide a Cu—Ti-based copper alloy sheet material having a strength, an electrical conductivity, bending workability, and a stress relaxation property all at high levels in a good balance, and also having a reduced density (specific gravity). [Means for Solution] A copper alloy sheet material composed of, in mass %, Ti: 1.0 to 5.0%, Al: 0.5 to 3.0%, Ag: 0 to 0.3%, B: 0 to 0.3%, Be: 0 to 0.15%, Co: 0 to 1.0%, Cr: 0 to 1.0%, Fe: 0 to 1.0%, Mg: 0 to 0.5%, Mn: 0 to 1.5%, Nb: 0 to 0.5%, Ni: 0 to 1.0%, P: 0 to 0.2%, Si: 0 to 0.5%, Sn: 0 to 1.5%, V: 0 to 1.0%, Zn: 0 to 2.0%, Zr: 0 to 1.0%, S: 0 to 0.2%, rare earth elements: 0 to 3.0%, and the balance substantially being Cu, wherein a maximum width of a grain boundary reaction type precipitate existing region is 1000 nm or less, a KAM value when a boundary with a crystal orientation difference of 15° or more measured by EBSD (step size: 0.1 ?m) is rewarded as a crystal grain boundary is 3.Type: GrantFiled: March 8, 2023Date of Patent: April 2, 2024Assignee: DOWA METALTECH CO., LTD.Inventors: Takuya Hashimoto, Hiroshi Yorifuji, Hiroshi Hyodo
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Patent number: 11946129Abstract: To provide, as a sheet material of a Cu—Ni—Al based copper alloy having a compositional range exhibiting a whitish metallic appearance that is excellent in “strength-bending workability balance” and is excellent in discoloration resistance, a copper alloy sheet material having a composition containing, in terms of % by mass, Ni: more than 12.0% and 30.0% or less, Al: 1.80-6.50%, Mg: 0-0.30%, Cr: 0-0.20%, Co: 0-0.30%, P: 0-0.10%, B: 0-0.05%, Mn: 0-0.20%, Sn: 0-0.40%, Ti: 0-0.50%, Zr: 0-0.20%, Si: 0-0.50%, Fe: 0-0.30%, and Zn: 0-1.00%, with the balance of Cu and unavoidable impurities, and satisfying Ni/Al?15.0, and having a metallic structure having, on an observation plane in parallel to a sheet surface (rolled surface), a number density of fine secondary phase particles having a particle diameter of 20 to 100 nm of 1.0×107 per mm2 or more.Type: GrantFiled: August 20, 2019Date of Patent: April 2, 2024Assignee: DOWA METALTECH CO., LTD.Inventors: Toshiya Shutoh, Hisashi Suda
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Patent number: 11542573Abstract: A composition of a copper alloy for a laser cladding valve sheet is disclosed. The copper alloy includes a matrix structure and a hard phase, which includes 12 to 24 wt % of Ni, 2 to 4 wt % of Si, 8 to 30 wt % of Fe, more than 5 wt % and less than 10 wt % of Mo, 2 to 10 wt % of Al, and the balance Cu. The interfacial delamination may be suppressed in a fatigue environment by micronizing the hard phase and the distribution thereof, thereby improving fatigue resistance and wear resistance.Type: GrantFiled: February 10, 2020Date of Patent: January 3, 2023Assignees: HYUNDAI MOTOR COMPANY, KIA MOTORS CORPORATIONInventors: Min-Woo Kang, Soon-Woo Kwon, Chung-An Lee, Seung-Hyun Hong, Young-Nam Kim
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Patent number: 11530629Abstract: A system to attach valve seat inserts to an aluminum cylinder head of an automobile vehicle includes a cylinder head of an automobile vehicle engine having a valve seat portion. A valve seat insert is positioned in the valve seat portion of the cylinder head. A fusion bond is created between the valve seat insert and the valve seat portion by laser welding thereby fusing the valve seat insert to the valve seat portion.Type: GrantFiled: June 26, 2020Date of Patent: December 20, 2022Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Huaxin Li, Ronald J Petrus
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Patent number: 10961607Abstract: A hardfacing alloy satisfies the following condition when the hardfacing alloy as a whole is 100 mass % (also simply referred to as “%,” hereinafter), Ni: 10-25%, Si: 1-3%, Fe: 3-18%, the total of one or more elements of Mo, W, and Nb: 6.5-20%, and the balance: Cu and impurities. In particular, it preferably satisfies Fe+2Mo?22.6(%), Mo equivalent/Fe?1.17, and Mo equivalent=Mo+0.522W+1.033Nb. In a hardfacing part composed of the hardfacing alloy, coarse hard particles are formed to ensure the wear resistance, and a soft phase present in the hard particles ensures the machinability. This may be understood as a raw material powder for hardfacing treatment and may also be understood as a hardfacing member in which a hardfacing part is formed on a base material using the raw material powder.Type: GrantFiled: October 10, 2018Date of Patent: March 30, 2021Assignees: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Tadashi Oshima, Hajime Kato, Kouji Tanaka, Takashi Saito, Natsuki Sugiyama, Minoru Kawasaki, Jun Nomasaki, Hisao Fukuhara, Naoyuki Miyara, Hironori Aoyama
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Patent number: 10837554Abstract: A piston ring is made from a copper-containing alloy. This material permits the top compression ring of a piston to be moved closer to the piston crown, reducing crevice volume and reducing the tendency for pre-ignition. Ignition timing advance can be realized by installing the rings and letting the ECU advance the timing as the sensors allow, increasing efficiency. Also, shorter pistons and longer connecting rods are possible. The shorter pistons reduces the reciprocated mass in the engine and the longer connecting rods reduce the frictional loss caused by radial forces pushing the piston against the liner. Both reducing volume and tendency for pre-ignition increase engine efficiency.Type: GrantFiled: December 15, 2017Date of Patent: November 17, 2020Assignee: Materion CorporationInventors: David J. Krus, Steffen Mack, Andrew J. Whitaker
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Patent number: 10648067Abstract: A metal alloy article having a combination of mechanical properties which are uniform across a cross-sectional area of the article is disclosed. The metal alloy is a precipitation hardenable alloy, such as an aluminum, copper, nickel, iron, or titanium alloy. In specific embodiments, the metal alloy is a copper-nickel-tin alloy with a nominal composition of Cu—15Ni—8Sn. The article is strengthened by process treatment steps including solution annealing, cold working, and precipitation hardening. The article has a constant cross-section along a length thereof with a minimum 0.2% offset yield strength of about 70 ksi.Type: GrantFiled: December 15, 2017Date of Patent: May 12, 2020Assignee: MATERION CORPORATIONInventors: Christopher Damschroder, W. Raymond Cribb
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Patent number: 10126521Abstract: There is provided a leaf spring which can prevent a reduction in the spring strength and can also prevent a reduction in the electrical conductivity when the thickness of the leaf spring is decreased. The leaf spring includes an outer frame portion an inner frame portion 5b, 11b disposed inside the outer frame portion 5a, 11a, and spring portions provided between the inner frame portion and the outer frame portion The leaf spring is made of a Cu-based alloy, and has an electrical conductivity of not less than 8% IACS and a 0.2% proof stress of not less than 900 MPa.Type: GrantFiled: April 23, 2014Date of Patent: November 13, 2018Assignees: DAI NIPPON PRINTING CO., LTD., ALPS ELECTRIC CO., LTD.Inventors: Yoshihiko Ogino, Chikao Ikenaga, Takahiro Sahara, Masahiro Nagata
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Patent number: 9859031Abstract: A rolled Cu—Ni—Si based copper alloy having excellent strength, electric conductivity, and bending coefficient is provided. The rolled copper alloy comprises 1.2 to 4.5% by mass Ni, 0.25 to 1.0% by mass Si, and the balance Cu with inevitable impurities. In the direction transverse to the rolling direction, the rolled copper alloy has a bending coefficient of 130 GPa or more and an electrical conductivity of 30% ICAS or more.Type: GrantFiled: February 15, 2013Date of Patent: January 2, 2018Assignee: JX Nippon Mining & Metals CorporationInventor: Hiroshi Kuwagaki
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Patent number: 9121084Abstract: To provide a copper alloy sheet excellent in the balance of strength and electroconductivity and excellent in the balance of strength and bending workability also. A copper alloy contains predetermined amount of Cr, Ti, and Si so as to satisfy a mass ratio of the Cr to the Ti: 1.0?(Cr/Ti)?30, and a mass ratio of the Cr to the Si: 3.0?(Cr/Si)?30, the remainder including copper and unavoidable impurities, in which 70% or more out of total amount of Cr, Ti and Si contained in the copper alloy is precipitated, a number of piece of precipitates with 300 nm or more circle equivalent diameter observed by a SEM in a region of 25 ?m in the thickness direction from the surface of the copper alloy×40 ?m in the cross-sectional direction in a cross section in the width direction of the copper alloy is 50 pieces or less, and an average circle equivalent diameter of precipitates with less than 300 nm circle equivalent diameter observed by a TEM on the surface of the copper alloy is 15 nm or less.Type: GrantFiled: January 29, 2013Date of Patent: September 1, 2015Assignee: Kobe Steel, Ltd.Inventors: Hisao Shishido, Yuya Sumino, Akira Fugono
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Patent number: 9034123Abstract: This invention provides a copper alloy sheet material containing, in mass %, Ni: 0.7%-4.2% and Si: 0.2%-1.0%, optionally containing one or more of Sn: 1.2% or less, Zn: 2.0% or less, Mg: 1.0% or less, Co: 2.0% or less, and Fe: 1.0% or less, and a total of 3% or less of one or more of Cr, B, P, Zr, Ti, Mn and V, the balance being substantially Cu, and having a crystal orientation satisfying Expression (1): I{420}/I0{420}>1.0??(1), where I{420} is the x-ray diffraction intensity from the {420} crystal plane in the sheet plane of the copper alloy sheet material and I0{420} is the x-ray diffraction intensity from the {420} crystal plane of standard pure copper powder. The copper alloy sheet material has highly improved strength, post-notching bending workability, and stress relaxation resistance property.Type: GrantFiled: February 12, 2008Date of Patent: May 19, 2015Assignee: DOWA METALTECH CO., LTD.Inventors: Weilin Gao, Hisashi Suda, Hiroto Narieda, Akira Sugawara
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Patent number: 8951371Abstract: A method of producing a copper alloy containing a precipitate X composed of Ni and Si and a precipitate Y that includes (a) Ni and 0% Si, (b) Si and 0% Ni, or (c) neither Ni nor Si, wherein the precipitate X has a grain size of 0.001 to 0.1 ?m, and the precipitate Y has a grain size of 0.01 to 1 ?m.Type: GrantFiled: December 22, 2010Date of Patent: February 10, 2015Assignee: The Furukawa Electric Co., Ltd.Inventors: Kuniteru Mihara, Tatsuhiko Eguchi, Nobuyuki Tanaka, Kiyoshige Hirose
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Publication number: 20150000803Abstract: A Cu—Ni—Si-based copper alloy sheet of the invention has excellent mold abrasion resistance and shear workability while maintaining strength and conductivity, in which 1.0 mass % to 4.0 mass % of Ni is contained, 0.2 mass % to 0.9 mass % of Si is contained, the remainder is made up of Cu and inevitable impurities. The number of the Ni—Si precipitate particles having a grain diameter in a range of 20 nm to 80 nm in a surface layer that is as thick as 20% of the entire sheet thickness from the surface is represented by a particles/mm2, and the number of the Ni—Si precipitate particles having a grain diameter in a range of 20 nm to 80 nm in a portion below the surface layer is represented by b particles/mm2, a/b is in a range of 0.5 to 1.5.Type: ApplicationFiled: December 22, 2011Publication date: January 1, 2015Applicant: Mitsubishi Shindoh Co., LtdInventors: Jun-Ichi Kumagai, Yoshio Abe, Akira Saito, Shuzo Umezu, Ryo Iino
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Publication number: 20140318673Abstract: A copper alloy material, having an alloy composition containing any one or both of Ni and Co in an amount of 0.4 to 5.0 mass % in total, and Si in an amount of 0.1 to 1.5 mass %, with the balance being copper and unavoidable impurities, wherein a ratio of an area of grains in which an angle of orientation deviated from S-orientation {2 3 1} <3 4 6> is within 30° is 60% or more, according to a crystal orientation analysis in EBSD measurement; an electrical or electronic part formed by working the copper alloy material; and a method of producing the copper alloy material.Type: ApplicationFiled: June 24, 2014Publication date: October 30, 2014Inventors: Hiroshi KANEKO, Kiyoshige HIROSE, Tatsuhiko EGUCHI
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Publication number: 20140305551Abstract: A copper alloy material for electrical and electronic components and a method of preparing the same are disclosed. In particular, a copper alloy material with excellent mechanical strength characteristics, high electrical conductivity, and high thermal stability as a material for information transmission and electrical contact of connectors or the like for home appliances and automobiles, including semiconductor lead frames and a method of preparing the same are disclosed.Type: ApplicationFiled: October 22, 2013Publication date: October 16, 2014Applicant: POONGSAN CORPORATIONInventors: CHEOL MIN PARK, In Youb Hwang
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Publication number: 20140283963Abstract: A Cu—Ti based copper alloy sheet material contains, in mass %, from 2.0 to 5.0% of Ti, from 0 to 1.5% Ni, from 0 to 1.0% Co, from 0 to 0.5% Fe, from 0 to 1.2% Sn, from 0 to 2.0% Zn, from 0 to 1.0% Mg, from 0 to 1.0% Zr, from 0 to 1.0% Al, from 0 to 1.0% Si, from 0 to 0.1% P, from 0 to 0.05% B, from 0 to 1.0% Cr, from 0 to 1.0% Mn, and from 0 to 1.0% V, the balance substantially being Cu. The sheet material has a metallic texture wherein in a cross section perpendicular to a sheet thickness direction, a maximum width of a grain boundary reaction type precipitate is not more than 500 nm, and a density of a granular precipitate having a diameter of 100 nm or more is not more than 105 number/mm2.Type: ApplicationFiled: March 14, 2014Publication date: September 25, 2014Applicant: DOWA METAL TECH CO., LTD.Inventors: Weilin GAO, Motohiko Suzuki, Toshiya Kamada, Takashi Kimura, Fumiaki Sasaki, Akira Sugawara
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Publication number: 20140232254Abstract: An electrode core material that may be used in electrodes of spark plugs and other ignition devices to provide increased thermal conductivity to the electrodes. The electrode core material is a precipitate-strengthened copper alloy and includes precipitates dispersed within a copper (Cu) matrix such that the electrode core material has a multi-phase microstructure. In several exemplary embodiments, the precipitates include: particles of iron (Fe) and phosphorous, particles of beryllium, or particles of nickel and silicon.Type: ApplicationFiled: February 5, 2014Publication date: August 21, 2014Inventors: Shuwei Ma, Richard L. Keller, John A. Burrows
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Publication number: 20140190596Abstract: Disclosed is a beryllium-free copper alloy having high strength, high electric conductivity and good bending workability and a method of manufacturing the copper alloy. Provided is a copper alloy having a composition represented by the composition formula by atom %: Cu100-a-b-c(Zr, Hf)a(Cr, Ni, Mn, Ta)b(Ti, Al)c [wherein 2.5?a?4.0, 0.1<b?1.5 and 0?c?0.2; (Zr, Hf) means one or both of Zr and Hf; (Cr, Ni, Mn, Ta) means one or more of Cr, Ni, Mn and Ta; and (Ti, Al) means one or both of Ti and Al], and having Cu primary phases in which the mean secondary dendrite arm spacing is 2 ?m or less and eutectic matrices in which the lamellar spacing between a metastable Cu5(Zr, Hf) compound phase and a Cu phase is 0.2 ?m or less.Type: ApplicationFiled: March 29, 2012Publication date: July 10, 2014Applicant: TOHOKU UNIVERSITYInventors: Akihisa Inoue, Nobuyuki Nishiyama, Haruko Yamazaki
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Publication number: 20140116583Abstract: A Cu—Ni—Co—Si based copper alloy sheet material has second phase particles existing in a matrix, with a number density of ultrafine second phase particles is 1.0×109 number/mm2 or more. A number density of fine second phase particles is not more than 5.0×107 number/mm2. A number density of coarse second phase particles is 1.0×105 number/mm2 or more and not more than 1.0×106 number/mm2. The material has crystal orientation satisfying the following equation (1): I{200}/I0{200}?3.0??(1) wherein I{200} represents an integrated intensity of an X-ray diffraction peak of the {200} crystal plane on the sheet material sheet surface; and I0{200} represents an integrated intensity of an X-ray diffraction peak of the {200} crystal plane in a pure copper standard powder sample.Type: ApplicationFiled: October 31, 2013Publication date: May 1, 2014Applicant: DOWA METALTECH CO., LTD.Inventors: Toshiya KAMADA, Takashi KIMURA, Weilin GAO, Fumiaki SASAKI, Akira SUGAWARA
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Publication number: 20140010704Abstract: To provide a copper alloy wire being a filamentary material of a copper alloy containing, in percent by mass, Ni: 3.0 to 15.0%, Al: 0.5 to 5.0%, and Si: 0.1 to 3.0%, with the remainder being composed of Cu and incidental impurities, which is provided with the tensile strength (?B) of 900 to 1300 MPa and electrical conductivity of 10 to 22% IACS and, in addition to that property, satisfies an intensity ratio of A:B:C of 1.0:1.2 to 6.0:2.2 to 8.Type: ApplicationFiled: December 13, 2011Publication date: January 9, 2014Applicants: Nippon Seisen Co., Ltd.Inventors: Kiyohito Ishida, Takayuki Akizuki
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Publication number: 20130333812Abstract: To provide a copper alloy of the FCC structure containing Ni: 3.0 to 29.5 mass %, Al: 0.5 to 7.0 mass %, and Si: 0.1 to 1.5 mass %, with the remainder consisting of Cu and incidental impurities, wherein the copper alloy is of the high strength, but is excellent in workability, and has high electrical conductivity, and can control property thereof, by precipitating a ?? phase of the L12 structure including Si at an average particle diameter of 100 nm or less in a parent phase of the copper alloy.Type: ApplicationFiled: December 13, 2011Publication date: December 19, 2013Applicants: Tohoku Techno Arch Co., Ltd., Nippon Seisen Co., Ltd.Inventors: Kiyohito Ishida, Rysuke Kainuma, Ikuo Ohnuma, Toshihiro Omori, Takashi Miyamoto, Hiroki Sato
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Publication number: 20130263978Abstract: Cu—Ni—Si—Co copper alloy strip having excellent balance between strength and electrical conductivity which can prevent the drooping curl is provided. The copper alloy strip for an electronic materials contains 1.0-2.5% by mass of Ni, 0.5-2.5% by mass of Co, 0.3-1.2% by mass of Si, and the remainder comprising Cu and unavoidable impurities, wherein the copper alloy strip satisfies both of the following (a) and (b) as determined by means of X-ray diffraction pole figure measurement based on a rolled surface: (a) among a diffraction peak intensities obtained by ? scanning at ?=20° in a {200} pole figure, a peak height at ? angle 145° is not more than 5.2 times that of standard copper powder; (b) among a diffraction peak intensities obtained by ? scanning at ?=75° in a {111} pole figure, a peak height at ? angle 185° is not less than 3.4 times that of standard copper powder.Type: ApplicationFiled: November 11, 2011Publication date: October 10, 2013Applicant: JX NIPPON MINING & METALS CORPORATIONInventor: Hiroshi Kuwagaki
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Publication number: 20130180630Abstract: A Cu—Co—Si-based alloy that has even mechanical properties and that is provided with favorable mechanical and electrical properties as a copper alloy for an electronic material is provided. The copper alloy for an electronic material comprises 0.5% by mass to 3.0% by mass of Co, 0.1% by mass to 1.0% by mass of Si, and the balance Cu with inevitable impurities. An average grain size is in the range of 3 ?m to 15 ?m and an average difference between a maximum grain size and a minimum grain size in every observation field of 0.05 mm2 is 5 ?m or less.Type: ApplicationFiled: September 6, 2011Publication date: July 18, 2013Applicant: JX NIPPON MINING & METALS CORPORATIONInventors: Yasuhiro Okafuji, Takuma Onda, Hiroshi Kuwagaki
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Patent number: 8357248Abstract: A copper alloy having high strength, high electrical conductivity, and excellent bendability, the copper alloy containing, in terms of mass %, 0.4 to 4.0% of Ni; 0.05 to 1.0% of Si; and, as an element M, one member selected from 0.005 to 0.5% of P, 0.005 to 1.0% of Cr, and 0.005 to 1.0% of Ti, with the remainder being copper and inevitable impurities, in which an atom number ratio M/Si of elements M and Si contained in a precipitate having a size of 50 to 200 nm in a microstructure of the copper alloy is from 0.01 to 10 on average, the atom number ratio being measured by a field emission transmission electron microscope with a magnification of 30,000 and an energy dispersive analyzer. According to the invention, it is possible to provide a copper alloy having high strength, high electrical conductivity, and excellent bendability.Type: GrantFiled: June 8, 2012Date of Patent: January 22, 2013Assignee: Kobe Steel, Ltd.Inventors: Yasuhiro Aruga, Akira Fugono, Takeshi Kudo, Katsura Kajihara
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Publication number: 20120267013Abstract: A copper alloy sheet material, having an R value of 1 or greater, which is defined by: R=([BR]+[RDW]+[W])/([C]+[S]+[B]) wherein [BR], [RDW], [W], [C], [S], and [B] represent an area ratio of crystal texture orientation component of BR orientation {3 6 2}<8 5 3>, RD-rotated-cube orientation {0 1 2}<1 0 0>, cube orientation {1 0 0}<0 0 1>, copper orientation {1 2 1}<1 1 1>, S-orientation {2 3 1}<3 4 6>, and brass orientation {1 1 0}<1 1 2>, respectively, in crystal orientation analysis in an EBSD (electron back scatter diffraction) analysis, and having a proof stress of 500 MPa or greater, and an electrical conductivity of 30%IACS or higher; and a production method of the same.Type: ApplicationFiled: June 1, 2012Publication date: October 25, 2012Inventors: Hiroshi KANEKO, Koji Sato, Tatsuhiko Eguchi
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Publication number: 20120241056Abstract: {Problems} To provide a copper alloy material, having a low Young's modulus that is required of electrical or electronic parts, such as connectors. {Means to solve} A copper alloy sheet material for electrical or electronic parts, having an alloy composition containing any one or both of Ni and Co in an amount of 0.5 to 5.0 mass % in total, and Si in an amount of 0.2 to 1.5 mass %, with the balance being Cu and inevitable impurities, wherein the copper alloy sheet material has a 0.2% proof stress in the rolling direction of 500 MPa or more, an electrical conductivity of 30% IACS or more, a Young's modulus of 110 GPa or less, and a factor of bending deflection of 105 GPa or less.Type: ApplicationFiled: June 1, 2012Publication date: September 27, 2012Inventors: Koji SATO, Hiroshi KANEKO, Tatsuhiko EGUCHI
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Patent number: 8268098Abstract: The present invention relates to a copper alloy having high strength, high electrical conductivity, and excellent bendability, the copper alloy containing, in terms of mass %, 0.4 to 4.0% of Ni; 0.05 to 1.0% of Si; and, as an element M, one member selected from 0.005 to 0.5% of P, 0.005 to 1.0% of Cr, and 0.005 to 1.0% of Ti, with the remainder being copper and inevitable impurities, in which an atom number ratio M/Si of elements M and Si contained in a precipitate having a size of 50 to 200 nm in a microstructure of the copper alloy is from 0.01 to 10 on average, the atom number ratio being measured by a field emission transmission electron microscope with a magnification of 30,000 and an energy dispersive analyzer. According to the invention, it is possible to provide a copper alloy having high strength, high electrical conductivity, and excellent bendability.Type: GrantFiled: May 23, 2007Date of Patent: September 18, 2012Assignee: Kobe Steel, Ltd.Inventors: Yasuhiro Aruga, Akira Fugono, Takeshi Kudo, Katsura Kajihara
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Patent number: 8070893Abstract: The invention provides Cu—Ni—Si—Co—Cr copper alloys for electronic materials having excellent characteristics such as dramatically improved strength and electrical conductivity. In one aspect, the invention is a Cu—Ni—Si—Co—Cr copper alloy for electronic materials, containing about 0.5-about 2.5% by weight of Ni, about 0.5 -about 2.5% by weight of Co, about 0.30-about 1.2% by weight of Si, and about 0.09 -about 0.5% by weight of Cr, and the balance being Cu and unavoidable impurities, wherein the ratio of the total weight of Ni and Co to the weight of Si in the alloy composition satisfies the formula: about 4?[Ni+Co]/Si?about 5, and the ratio of Ni to Co in the alloy composition satisfies the formula: about 0.5?Ni/Co?about 2, and wherein Pc is equal to or less than about 15/1000 ?m2, or Pc/P is equal to or less than about 0.Type: GrantFiled: March 31, 2006Date of Patent: December 6, 2011Assignee: JX Nippon Mining & Metals CorporationInventors: Naohiko Era, Kazuhiko Fukamachi, Hiroshi Kuwagaki
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Publication number: 20110192505Abstract: A copper alloy material, having an alloy composition containing any one or both of Ni and Co in an amount of 0.4 to 5.0 mass % in total, and Si in an amount of 0.1 to 1.5 mass %, with the balance being copper and unavoidable impurities, wherein a ratio of an area of grains in which an angle of orientation deviated from S-orientation {2 3 1}<3 4 6> is within 30° is 60% or more, according to a crystal orientation analysis in EBSD measurement; an electrical or electronic part formed by working the copper alloy material; and a method of producing the copper alloy material.Type: ApplicationFiled: April 21, 2011Publication date: August 11, 2011Inventors: Hiroshi KANEKO, Kiyoshige HIROSE, Tatsuhiko EGUCHI
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Publication number: 20110186192Abstract: A copper alloy material for an electric/electronic part, having a composition comprising Co 0.5 to 2.0 mass % and Si 0.1 to 0.5 mass %, with the balance of Cu and inevitable impurities, in which a copper alloy of a matrix has a grain size of 3 to 35 ?m, a precipitate composed of Co and Si has a particle size of 5 to 50 nm, the precipitate has a density of 1×108 to 1×1010 number/mm2, and the copper alloy material has a tensile strength of 550 MPa and an electrical conductivity of 50% IACS or more.Type: ApplicationFiled: January 28, 2011Publication date: August 4, 2011Applicant: THE FURUKAWA ELECTRIC CO., LTD.Inventors: Kuniteru MIHARA, Ryosuke MATSUO, Tatsuhiko EGUCHI
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Publication number: 20110073221Abstract: A copper alloy sheet material, having a composition containing any one or both of Ni and Co in an amount of 0.5 to 5.0 mass % in total, and Si in an amount of 0.3 to 1.5 mass %, with the balance of copper and unavoidable impurities, wherein an area ratio of cube orientation {0 0 1} <1 0 0> is 5 to 50%, according to a crystal orientation analysis in EBSD measurement.Type: ApplicationFiled: December 1, 2010Publication date: March 31, 2011Inventors: Hiroshi KANEKO, Kiyoshige HIROSE, Koji SATO
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Publication number: 20100326573Abstract: An copper alloy material for electric/electronic components containing Co by 0.2 to 2 mass % and Si by 0.05 to 0.5 mass % and having a remaining component composed of Cu and unavoidable impurities, characterized in that its grain size is 3 to 35 ?m and size of precipitate containing the both of Co and Si is 5 to 50 nm, electric conductivity is 50% IACS or more, tensile strength is 500 MPa or more and bending workability (R/t) is 2 or less.Type: ApplicationFiled: January 30, 2009Publication date: December 30, 2010Inventors: Kuniteru Mihara, Ryosuke Matsuo, Tatsuhiko Eguchi
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Patent number: 7850795Abstract: While securing the building-up ability and crack resistance, to provide a build-up wear-resistant copper alloy and valve seat. The build-up wear-resistant copper alloy and valve seat are characterized by having a composition of nickel: 5.0-24.5%, iron: 3.0-20.0%, silicon: 0.5-5.0%, boron: 0.05-0.5%, chromium: 0.3-5.0%, one member or two members or more selected from the group consisting of molybdenum, tungsten and vanadium: 3.0-20.0%, by weight %, and the balance being copper and inevitable impurities.Type: GrantFiled: December 28, 2005Date of Patent: December 14, 2010Assignee: Toyota Jidosha Kabushiki KaishaInventors: Minoru Kawasaki, Takao Kobayashi, Tadashi Oshima, Kazuyuki Nakanishi
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Publication number: 20100269963Abstract: A copper alloy material according to the present invention is characterized in that the same comprises: Ni between 2.8 mass % and 5.0 mass %; Si between 0.4 mass % and 1.7 mass %; S of which content is limited to less than 0.005 mass %; and the balance of the copper alloy material is composed of copper and unavoidable impurity, wherein a proof stress is stronger than or equal to 800 MPa, and the same is superior in bending workability and in stress relaxation resistance.Type: ApplicationFiled: October 31, 2008Publication date: October 28, 2010Inventors: Kiyoshige Hirose, Kuniteru Mihara, Hiroshi Kaneko, Tatsuhiko Eguchi
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Patent number: 7815756Abstract: This is to provide a build-up wear-resistant copper-based alloy, which is advantageous for enhancing the cracking resistance and machinability, which is appropriate for cases of building up to form built-up layers especially, and which is equipped with the wear resistance, cracking resistance and machinability combinedly in a well balanced manner. A build-up wear-resistant copper-based alloy is characterized in that it has a composition, which includes nickel: 5.0-20.0%; silicon: 0.5-5.0%; manganese: 3.0-30.0%; and an element, which combines with manganese to form a Laves phase and additionally to form silicide: 3.0-30.0%; by weight %, and inevitable impurities; and additionally the balance being copper. The element can be one member or two or more members of titanium, hafnium, zirconium, vanadium, niobium and tantalum.Type: GrantFiled: September 15, 2006Date of Patent: October 19, 2010Assignee: Toyota Jidosha Kabushiki KaishaInventors: Minoru Kawasaki, Tadashi Oshima, Takao Kobayashi, Kazuyuki Nakanishi
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Publication number: 20100193092Abstract: A copper alloy for an electrical and electronic device in accordance with the present invention is characterized in that the copper alloy for an electrical and electronic device includes: nickel (Ni) between 1.5 mass % and 5.0 mass %; silicon (Si) between 0.4 mass % and 1.5 mass %; and a remaining portion formed of Cu and an unavoidable impurity, wherein a mass ratio between Nickel (Ni) and Silicon (Si) as Ni/Si is not smaller than two and not larger than seven, an average crystalline grain diameter is not smaller than 2 ?m and not larger than 20 ?m, and a standard deviation of the crystalline grain diameter is not larger than 10 ?m.Type: ApplicationFiled: March 26, 2008Publication date: August 5, 2010Inventors: Ryosuke Matsuo, Tatsuhiko Eguchi, Kuniteru Mihara, Hiroshi Kaneko, Kiyoshige Hirose
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Publication number: 20100170595Abstract: A copper alloy material according to the present invention is characterized in that the copper alloy material includes: an element X between 0.1% and 4% by mass, in which the element X represents one transition element or not less than two elements selected from Ni, Fe, Co and Cr; an element Y between 0.01% and 3% by mass, in which the element Y represents one element or not less than two elements selected from Ti, Si, Zr and Hf; and a remaining portion to be comprised of copper and an unavoidable impurity, wherein the copper alloy material has an electrical conductivity of not less than 50% IACS, an yield strength of not less than 600 MPa, and a stress relaxation rate of not higher than 20% as to be measured after the same is maintained for 1000 hours at a state under applying a stress of 80% of the yield strength.Type: ApplicationFiled: March 28, 2008Publication date: July 8, 2010Inventors: Hiroshi Kaneko, Kuniteru Mihara, Tatsuhiko Eguchi
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Publication number: 20100132851Abstract: A sheet material of a copper alloy has a chemical composition comprising 1.2 to 5.0 wt % of titanium, and the balance being copper and unavoidable impurities, the material having a mean crystal grain size of 5 to 25 ?m and (maximum crystal grain size?minimum crystal grain size)/(mean crystal grain size) being 0.20 or less, assuming that the maximum, minimum and mean values of mean values, each of which is the mean value of crystal grain sizes in a corresponding one of a plurality of regions which are selected from the surface of the sheet material at random and which have the same shape and size, are the maximum, minimum and mean crystal grain sizes, respectively, and the material having a crystal orientation satisfying I{420}/I0{420}>1.0, assuming that the intensities of X-ray diffraction on the {420} crystal plane of the surface of the material and the standard powder of pure copper are I{420} and I0{420}, respectively.Type: ApplicationFiled: November 24, 2009Publication date: June 3, 2010Applicant: DOWA METALTECH CO., LTD.Inventors: Weilin Gao, Hisashi Suda, Hiroto Narieda, Akira Sugawara
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Publication number: 20100006191Abstract: The electrical conductivity of a wrought processed, high strength, age hardened Be—Cu alloy is enhanced by overaging the alloy in manufacture.Type: ApplicationFiled: July 9, 2008Publication date: January 14, 2010Applicant: BRUSH WELLMAN, INC.Inventors: John F Wetzel, John C. Harkness
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Publication number: 20100000637Abstract: The present invention provides Cu—Ni—Si system alloys for electronic material that with the addition of other alloy elements minimized, simultaneously exhibits enhanced electric conductivity, strength, bendability and stress relaxation performance. There are provided Cu—Ni—Si system alloys comprising 1.2 to 3.5 mass % Ni, Si in a concentration (mass %) of ? to ¼ of Ni concentration (mass %) and the balance Cu and impurities whose total amount is 0.05 mass % or less, the Cu—Ni—Si system alloys having its configuration of crystal grains and width of a precipitate-free zone regulated so as to fall within appropriate ranges by controlling solution treatment conditions, aging treatment conditions and degree of a reduction ratio. Thus, there can be provided copper alloys strip of 55 to 62% IACS electric conductivity and 550 to 700 MPa tensile strength, being free from cracking at 180° bending test of 0 radius and exhibiting a stress relaxation ratio, as measured on heating at 150° C. for 1000 hr, of 30% or less.Type: ApplicationFiled: September 21, 2007Publication date: January 7, 2010Applicant: Nippon Mining & Metals Co., Ltd.Inventor: Takaaki Hatano
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Publication number: 20090301614Abstract: The invention provides Cu—Ni—Si—Co alloys having excellent strength, electrical conductivity, and press-punching properties. In one aspect, the invention is a copper alloy for electronic materials, containing 1.0 to 2.5 mass % of Ni, 0.5 to 2.5 mass % of Co, and 0.30 to 1.2 mass % of Si, the balance being Cu and unavoidable impurities, wherein the copper alloy for electronic material has a [Ni+Co+Si] content in which the median value ? (mass %) satisfies the formula 20 (mass %)???60 (mass %), the standard deviation ? (Ni+Co+Si) satisfies the formula ? (Ni+Co+Si)?30 (mass %), and the surface area ratio S (%) satisfies the formula 1%?S?10%, in relation to the compositional variation and the surface area ratio of second-phase particles size of 0.1 ?m or greater and 1 ?m or less when observed in a cross section parallel to a rolling direction.Type: ApplicationFiled: August 22, 2008Publication date: December 10, 2009Applicant: NIPPON MINING & METALS CO., LTD.Inventors: Naohiko Era, Hiroshi Kuwagaki
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Publication number: 20090229715Abstract: An apparatus for manufacturing wire comprising: a wire delivering equipment, a wire winding equipment, and an annealing while running equipment installed between the wire delivering equipment and the wire winding equipment, the age-precipitation copper alloy wire being passed in such manner that the wire turns around a plurality of times along a running route in the annealing while running equipment. The current applying equipment to raise a temperature of the age-precipitation copper alloy wire by generated Joule heat may be installed at upstream side of the annealing while running equipment. Another current applying equipment for solution treatment may be installed in tandem at upstream side of the annealing while running equipment. In place of the annealing while running equipment, a current applying equipment may be connected in tandem for age-treatment. By using those equipments, age-precipitation copper alloy wire having the diameter of from 0.03 mm to 3 mm may be obtained.Type: ApplicationFiled: March 5, 2009Publication date: September 17, 2009Applicant: THE FURUKAWA ELECTRIC CO., LTD.Inventors: Isao TAKAHASHI, Keisuke KITAZATO
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Publication number: 20090165902Abstract: A method of producing a copper alloy wire rod, containing: a casting step for obtaining an ingot by pouring molten copper of a precipitation strengthening copper alloy into a belt-&-wheel-type or twin-belt-type movable mold; and a rolling step for rolling the ingot obtained by the casting step, which steps are continuously performed, wherein an intermediate material of the copper alloy wire rod in the mid course of the rolling step or immediately after the rolling step is quenched.Type: ApplicationFiled: December 1, 2008Publication date: July 2, 2009Applicant: THE FURUKAWA ELECTRIC CO., LTD.Inventors: Hirokazu YOSHIDA, Tsukasa TAKAZAWA
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Publication number: 20090101243Abstract: The present invention relates to a copper alloy having high strength, high electrical conductivity, and excellent bendability, the copper alloy containing, in terms of mass %, 0.4 to 4.0% of Ni; 0.05 to 1.0% of Si; and, as an element M, one member selected from 0.005 to 0.5% of P, 0.005 to 1.0% of Cr, and 0.005 to 1.0% of Ti, with the remainder being copper and inevitable impurities, in which an atom number ratio M/Si of elements M and Si contained in a precipitate having a size of 50 to 200 nm in a microstructure of the copper alloy is from 0.01 to 10 on average, the atom number ratio being measured by a field emission transmission electron microscope with a magnification of 30,000 and an energy dispersive analyzer. According to the invention, it is possible to provide a copper alloy having high strength, high electrical conductivity, and excellent bendability.Type: ApplicationFiled: May 23, 2007Publication date: April 23, 2009Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Yasuhiro Aruga, Akira Fugono, Takeshi Kudo, Katsura Kajihara
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Publication number: 20090053090Abstract: It is an object to provide an inexpensive alloy for heat dissipation having a small thermal expansion coefficient as known composite materials, a large thermal conductivity as pure copper, and excellent machinability and a method for manufacturing the alloy. In particular, since various shapes are required of the alloy for heat dissipation, a manufacturing method by using a powder metallurgy method capable of supplying alloys for heat dissipation, the manufacturing costs of which are low and which take on various shapes, is provided besides the known melting method. The alloy according to the present invention is a Cu—Cr alloy, which is composed of 0.3 percent by mass or more, and 80 percent by mass or less of Cr and the remainder of Cu and incidental impurities and which has a structure in which particulate Cr phases having a major axis of 100 nm or less and an aspect ratio of less than 10 are precipitated at a density of 20 particles/?m2 in a Cu matrix except Cr phases of 100 nm or more.Type: ApplicationFiled: October 5, 2005Publication date: February 26, 2009Inventor: Hoshiaki Terao
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Publication number: 20090025840Abstract: The invention provides Cu—Ni—Si—Co—Cr copper alloys for electronic materials having excellent characteristics such as dramatically improved strength and electrical conductivity. In one aspect, the invention is a Cu—Ni—Si—Co—Cr copper alloy for electronic materials, containing about 0.5-about 2.5% by weight of Ni, about 0.5-about 2.5% by weight of Co, about 0.30-about 1.2% by weight of Si, and about 0.09-about 0.5% by weight of Cr, and the balance being Cu and unavoidable impurities, wherein the ratio of the total weight of Ni and Co to the weight of Si in the alloy composition satisfies the formula: about 4?[Ni+Co]/Si?about 5, and the ratio of Ni to Co in the alloy composition satisfies the formula: about 0.5?Ni/Co?about 2, and wherein Pc is equal to or less than about 15/1000 ?m2, or Pc/P is equal to or less than about 0.Type: ApplicationFiled: March 31, 2006Publication date: January 29, 2009Applicant: Nippon Mining & Metals Co., Ltd.Inventors: Naohiko Era, Kazuhiko Fukamachi, Hiroshi Kuwagaki
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Publication number: 20080202643Abstract: A process is provided for forming an age hardened wire for use as an electrical conductor, which wire is formed from a copper base alloy consisting of from 1.25 to 3.6 wt % nickel, from 0.25 to 0.45 beryllium, and the balance copper and impurities which do not affect the properties of said alloy, with the nickel and beryllium being present in the copper base alloy in a ratio of nickel to beryllium from 5.0 to 8.0. The process comprises the steps of providing a copper base alloy material consisting of from 1.25 to 3.6 wt % nickel, from 0.25 to 0.45 beryllium, and the balance copper and impurities which do not affect the properties of said alloy, which nickel and beryllium are present in the copper base alloy in a ratio of nickel to beryllium from 5.0 to 8.0, cold working the material in a single step; and age hardening the cold worked material in a single step to form a wire in a cold worked and aged hardened condition having an electrical conductivity of at least about 60% IACS.Type: ApplicationFiled: February 8, 2008Publication date: August 28, 2008Inventor: Joseph Saleh
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Publication number: 20080190523Abstract: This invention provides a copper alloy sheet material containing, in mass %, Ni: 0.7%-4.2% and Si: 0.2%-1.0%, optionally containing one or more of Sn: 1.2% or less, Zn: 2.0% or less, Mg: 1.0% or less, and Co: 2.0% or less, and a total of 3% or less of one or more of Cr, B, P, Zr, Ti, Mn and V, the balance being substantially Cu, and having a crystal orientation satisfying Expression (1): I{420}/I0{420}>1.0, ??(1) where I{420} is the x-ray diffraction intensity from the {420} crystal plane in the sheet plane of the copper alloy sheet material and I0{420} is the x-ray diffraction intensity from the {420} crystal plane of standard pure copper powder. The copper alloy sheet material has highly improved strength, post-notching bending workability, and stress relaxation resistance property.Type: ApplicationFiled: July 13, 2007Publication date: August 14, 2008Inventors: Weilin Gao, Hisashi Suda, Hiroto Narieda, Akira Sugawara
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Publication number: 20080121320Abstract: Superior bendability in a copper alloy and further strength improvement ensures characteristics which are sufficiently superior in view of essential qualities of strength of titanium-copper. 2.0 to 4.0 mass % of Ti, 0.01 to 0.50 mass % of one or more than one kind of element from among Fe, Co, Ni, Cr, V, Zr, B, and P as the third element group are contained, and not less than 50% of the total content of these elements is made to exist as second-phase particles.Type: ApplicationFiled: January 29, 2008Publication date: May 29, 2008Applicant: NIPPON MINING & METALS COMPANY, LIMITEDInventors: Yasutaka Sugawara, Kazuhiko Fukamachi