Tin Containing Patents (Class 148/433)
  • Patent number: 11315702
    Abstract: A covered electrical wire comprises a conductor and an insulating covering layer provided outside the conductor, the conductor being a stranded wire composed of a strand of a plurality of copper alloy wires: composed of a copper alloy containing Fe in an amount of 0.2% by mass or more and 1.6% by mass or less, P in an amount of 0.05% by mass or more and 0.4% by mass or less, and Sn in an amount of 0.05% by mass or more and 0.7% by mass or less, with the balance being Cu and impurities, and having a mass ratio of Fe/P of 4.0 or more; and having a wire diameter of 0.5 mm or less.
    Type: Grant
    Filed: December 28, 2016
    Date of Patent: April 26, 2022
    Assignees: Sumitomo Electric Industries, Ltd., AutoNetworks Technologies, Ltd., Sumitomo Wiring Systems, Ltd.
    Inventors: Kei Sakamoto, Akiko Inoue, Tetsuya Kuwabara, Minoru Nakamoto, Yusuke Oshima, Yoshihiro Nakai, Kazuhiro Nanjyo, Taichiro Nishikawa, Kiyotaka Utsunomiya, Yasuyuki Ootsuka, Kinji Taguchi, Hiroyuki Kobayashi
  • Patent number: 11315701
    Abstract: A covered electrical wire comprising a conductor and an insulating covering layer provided outside the conductor, the conductor being a stranded wire composed of a strand of a plurality of copper alloy wires: composed of a copper alloy containing Fe in an amount of 0.1% by mass or more and 1.6% by mass or less, P in an amount of 0.05% by mass or more and 0.7% by mass or less, and Sn in an amount of 0.05% by mass or more and 0.7% by mass or less, with the balance being Cu and impurities; and having a wire diameter of 0.5 mm or less, the copper alloy wire having a tensile strength of 385 MPa or more and a work-hardening exponent of 0.1 or more.
    Type: Grant
    Filed: June 21, 2017
    Date of Patent: April 26, 2022
    Assignees: Sumitomo Electric Industries, Ltd., AutoNetworks Technologies, Ltd., Sumitomo Wiring Systems. Ltd.
    Inventors: Kei Sakamoto, Akiko Inoue, Tetsuya Kuwabara, Minoru Nakamoto, Yusuke Oshima, Yoshihiro Nakai, Kazuhiro Nanjo, Taichiro Nishikawa, Kiyotaka Utsunomiya, Yasuyuki Ootsuka, Kinji Taguchi, Hiroyuki Kobayashi
  • Patent number: 11237520
    Abstract: A pivot arbor for a timepiece movement includes a pivot made of a first non-magnetic metal material at at least one end in order to limit the sensitivity to magnetic fields. An outer surface of the pivot is coated with a first layer of a second material such as Ni, NiB, and/or NiP. The first layer of the second material is partially coated with a second layer of a third material selected from gold, silver, copper, platinum, rhodium, palladium and their alloys.
    Type: Grant
    Filed: July 18, 2017
    Date of Patent: February 1, 2022
    Assignee: Nivarox-FAR S.A.
    Inventors: Alexandre Fussinger, Christian Charbon, Marco Verardo
  • Patent number: 11047023
    Abstract: A copper alloy sheet material that is excellent in surface smoothness of an etched surface has a composition containing, (mass %), from 1.0 to 4.5% of Ni, from 0.1 to 1.2% of Si, from 0 to 0.3% of Mg, from 0 to 0.2% of Cr, from 0 to 2.0% of Co, from 0 to 0.1% of P, from 0 to 0.05% of B, from 0 to 0.2% of Mn, from 0 to 0.5% of Sn, from 0 to 0.5% of Ti, from 0 to 0.2% of Zr, from 0 to 0.2% of Al, from 0 to 0.3% of Fe, from 0 to 1.0% of Zn, the balance Cu and unavoidable impurities. A number density of coarse secondary phase particles has a major diameter of 1.0 ?m or more of 4.0×103 per square millimeter or less. KAM value measured with a step size of 0.5 ?m is more than 3.00.
    Type: Grant
    Filed: October 14, 2016
    Date of Patent: June 29, 2021
    Assignee: DOWA METALTECH CO., LTD.
    Inventors: Toshiya Shutoh, Hisashi Suda, Fumiaki Sasaki
  • Patent number: 10718037
    Abstract: A copper alloy material production method is provided. A copper raw material including not higher than 30 ppm by mass of oxygen is melted to form a molten copper. Not lower than 4 ppm by mass and not higher than 55 ppm by mass of titanium is added to the molten copper. After the adding of the titanium, not lower than 100 ppm by mass and not higher than 7000 ppm by mass of magnesium is added.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: July 21, 2020
    Assignee: HITACHI METALS, LTD.
    Inventors: Shohei Hata, Takayuki Tsuji, Hiromitsu Kuroda, Keisuke Fujito
  • Patent number: 10711328
    Abstract: The present invention relates to a copper-zinc alloy with low lead content, as well as a process for the manufacturing of the same. The obtained allow allows the restriction of the amount of the generated Beta phase, thereby causing a lower deterioration of the materials due to the loss of zinc during its exposure to ponded, low movement or slightly acid waters.
    Type: Grant
    Filed: August 16, 2017
    Date of Patent: July 14, 2020
    Inventors: Jaime Rodríguez Angoli, Julio Alberto Rosas Franco, Roberto Montoya Rodriguez
  • Patent number: 10557185
    Abstract: This free-cutting copper alloy contains 75.0%-78.5% Cu, 2.95%-3.55% Si, 0.07%-0.28% Sn, 0.06%-0.14% P, and 0.022%-0.25% Pb, with the remainder being made up of Zn and inevitable impurities. The composition satisfies the following relations: 76.2?f1=Cu+0.8×Si?8.5×Sn+P+0.5×Pb?80.3, 61.5?f2=Cu?4.3×Si?0.7×Sn?P+0.5×Pb?63.3. The area ratios (%) of the constituent phases satisfy the following relations: 25???65, 0???1.5, 0???0.2, 0???2.0, 97.0?f3=?+?, 99.4?f4=?+?+?+?, 0?f5=?+??2.5, 27?f6=?+6×?1/2+0.5×??70. The long side of the ? phase does not exceed 40 ?m, the long side of the ? phase does not exceed 25 ?m, and the ? phase is present within the ? phase.
    Type: Grant
    Filed: February 13, 2019
    Date of Patent: February 11, 2020
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventors: Keiichiro Oishi, Kouichi Suzaki, Shinji Tanaka, Takayuki Oka
  • Patent number: 10533244
    Abstract: To contribute to an improvement in a dezincification resistance of a copper alloy, focusing attention on a relation between a dezincification resistance of a copper alloy and the crystal grain size of an ? phase, and the specific object is to provide a method of producing a hot forged product using a lead-free brass capable of ensuring corrosion resistances such as a prescribed dezincification resistance and the like even at sites of different thickness and shape, a hot forged product, and a wetted product such as a valve and a water faucet, molded using the same. A method of producing a hot forged product using a brass, comprising heat-treating a raw material to be subjected to forging work using a brass having a composition containing at least 59.2 to 63.0% by mass of Cu, 1.00 to 2.00% by mass of Sn and 0.05 to 0.25% by mass of Pb and containing the residue composed of Zn and inevitable impurities at a heating rate of 5.2° C./s or more from 350° C. until reaching the forging temperature.
    Type: Grant
    Filed: April 30, 2015
    Date of Patent: January 14, 2020
    Assignee: KITZ CORPORATION
    Inventors: Junichi Hanaoka, Kazuhito Kurose
  • Patent number: 10533098
    Abstract: A conductive paste having excellent electroconductivity and thermal conductivity is provided. A conductive paste comprising a conductive filler comprising a copper alloy powder comprising at least one transition metal belonging to group 8 to group 10 of the periodic table, and a carbon allotrope covering a surface of the copper alloy powder; and a binder resin.
    Type: Grant
    Filed: July 29, 2014
    Date of Patent: January 14, 2020
    Assignee: SEKISUI CHEMICAL CO., LTD.
    Inventor: Shigekatsu Ohnishi
  • Patent number: 10518950
    Abstract: Cable ties including an antimicrobial component and optionally a detectable component are disclosed. More particularly, cable ties including a composition having a base plastic, an antimicrobial additive and optionally a detectable additive selected from a detectable metal additive, an X-ray detectable additive and combinations thereof as well as methods of making the same are disclosed. Also, cable ties including an antimicrobial metallic barb and a composition having a base plastic and optionally an antimicrobial additive and/or a detectable additive selected from a detectable metal additive, an X-ray detectable additive and combinations thereof are disclosed.
    Type: Grant
    Filed: September 9, 2015
    Date of Patent: December 31, 2019
    Assignee: Thomas & Betts International LLC
    Inventor: Yan Gao
  • Patent number: 10357943
    Abstract: Various touch surfaces can lead to the spread of many types of secondary infections. Although copper has some capacity for conveying antiseptic properties, it can be problematic to form a copper-containing surface upon an article that does not otherwise contain copper. Copper nanoparticles can be used to address this situation by forming a plurality of copper islands upon the substructure of an article. Articles having antiseptic properties can include an exposed surface coating containing a plurality of copper islands, and a substructure underlying the exposed surface coating, in which the substructure contains a material differing from copper. The copper nanoparticles can remain in their original form in the exposed surface coating, or at least a portion of the copper nanoparticles can be fused together to form the copper islands. Biocidal activity beyond limiting transfer of secondary infections can also be expressed in the articles.
    Type: Grant
    Filed: January 11, 2016
    Date of Patent: July 23, 2019
    Assignee: Lockheed Martin Corporation
    Inventor: Alfred A. Zinn
  • Patent number: 10167397
    Abstract: Method and apparatus for determining a quality or characteristic of connectors in electronic components is provided. Methods include applying a UV-responsive indicator solution active for Pd, Ni, or Cu to a connector on an electrical component; irradiating the connector with UV radiation; detecting a response to the UV radiation; and determining a quality of the connector based on the response to the UV radiation. Apparatus includes an enclosure; a support; a dispenser oriented toward the substrate support; a source of UV-responsive indicator solution active for Pd, Ni, or Cu ions fluidly coupled to the dispenser; a UV source coupled to the enclosure; and a radiation sensor positioned to detect light inside the enclosure.
    Type: Grant
    Filed: December 6, 2017
    Date of Patent: January 1, 2019
    Assignee: International Business Machines Corporation
    Inventors: Eric J. Campbell, Sarah K. Czaplewski, Joseph Kuczynski, Timothy J. Tofil
  • Patent number: 10023941
    Abstract: By enhancing a stress corrosion cracking resistance in a leadless brass alloy, specifically by suppressing a velocity of propagation of corrosion cracks in the brass alloy, a straight line crack peculiar to the leadless brass alloy is suppressed, a probability of cracks coming into contact with ? phases is heightened and local corrosion on the brass surface is prevented to suppress induction of cracks by the local corrosion, thereby providing a leadless brass alloy contributable to enhancement of the stress corrosion cracking resistance. The present invention is directed to an Sn-containing Bi-based, Sn-containing Bi+Sb-based or Sn-containing Bi+Se+Sb-based leadless brass alloy excellent in stress corrosion cracking resistance, having an ?+? structure or ?+?+? structure and having ? phases distributed uniformly therein at a predetermined proportion to suppress local corrosion and induction of stress corrosion cracks.
    Type: Grant
    Filed: December 27, 2012
    Date of Patent: July 17, 2018
    Assignee: KITZ CORPORATION
    Inventors: Hidenobu Tameda, Kazuhito Kurose, Teruhiko Horigome, Tomoyuki Ozasa, Hisanori Terui, Masaru Yamazaki, Hideki Kotsuji
  • Patent number: 10020088
    Abstract: A copper alloy sheet for terminal and connector materials contains 4.5 mass % to 12.0 mass % of Zn, 0.40 mass % to 0.9 mass % of Sn, 0.01 mass % to 0.08 mass % of P, and 0.20 mass % to 0.85 mass % of Ni with a remainder being Cu and inevitable impurities, a relationship of 11?[Zn]+7.5×[Sn]+16×[P]+3.5×[Ni]?19 is satisfied, a relationship of 7?[Ni]/[P]?40 is satisfied in a case in which the content of Ni is in a range of 0.35 mass % to 0.85 mass %, an average crystal grain diameter is in a range of 2.0 ?m to 8.0 ?m, an average particle diameter of circular or elliptical precipitates is in a range of 4.0 nm to 25.0 nm or a proportion of the number of precipitates having a particle diameter in a range of 4.0 nm to 25.0 nm in the precipitates is 70% or more, an electric conductivity is 29% IACS or more, a percentage of stress relaxation is 30% or less at 150° C. for 1000 hours as stress relaxation resistance, bending workability is R/t?0.
    Type: Grant
    Filed: November 19, 2015
    Date of Patent: July 10, 2018
    Assignees: MITSUBISHI SHINDOH CO., LTD., MITSUBISHI MATERIALS CORPORATION
    Inventors: Keiichiro Oishi, Takashi Hokazono, Michio Takasaki, Yosuke Nakasato
  • Patent number: 9994933
    Abstract: A copper alloy sheet has a chemical composition containing 0.7 to 4.0 wt % of Ni, 0.2 to 1.5 wt % of Si, and the balance being copper and unavoidable impurities, the copper alloy sheet having a crystal orientation which satisfies I{200}/I0{200}?1.0, assuming that the intensity of X-ray diffraction on the {200} crystal plane on the surface of the copper alloy sheet is I{200} and that the intensity of X-ray diffraction on the {200} crystal plane of the standard powder of pure copper is I0{200}, and which satisfies I{200}/I{422}?15, assuming that the intensity of X-ray diffraction on the {422} crystal plane on the surface of the copper alloy sheet is I{422}.
    Type: Grant
    Filed: April 26, 2010
    Date of Patent: June 12, 2018
    Assignee: DOWA METAL TECH CO., LTD.
    Inventors: Weilin Gao, Tomotsugu Aoyama, Hisashi Suda, Hiroto Narieda, Akira Sugawara, Akifumi Onodera
  • Patent number: 9982327
    Abstract: A brass alloy is provided having good mechanical properties and castability, and excellent general-purpose properties, while its dezincification corrosion is inhibited. The brass alloy contains 0.4% by mass or more and 3.2% by mass or less of Al; 0.001% by mass or more and 0.3% by mass or less of P; 0.1% by mass or more and 4.5% by mass or less of Bi; 0% by mass or more and 5.5% by mass or less of Ni; 0% by mass or more and 0.5% by mass or less of Mn, Fe, Pb, Sn, Si, Mg, and Cd, respectively; and Zn; the balance being Cu and a trace element or elements. The zinc equivalent (Zneq) calculated from the content of Zn and other elements, and the content of Al (% by mass) satisfy the following Equations (1) and (2): Zneq+1.7×Al?35.0??(1) Zneq?0.45×Al?37.0??(2).
    Type: Grant
    Filed: February 21, 2013
    Date of Patent: May 29, 2018
    Assignee: KURIMOTO, LTD.
    Inventors: Hiroshi Yamada, Masaaki Yamamoto
  • Patent number: 9845521
    Abstract: A copper alloy containing Ni: 1.5%-3.6% and Si: 0.3%-1.0% in terms of mass percent with the remainder consisting of copper and unavoidable impurities, wherein: the average crystal grain size of the crystal grains in the copper alloy is 5 to 30 ?m; the area ratio of the crystal grains having crystal grain sizes not less than twice the average crystal grain size is not less than 3%; and the ratio of the area of cube orientation grains to the area of the crystal grains having crystal grain sizes not less than twice the average crystal grain size is not less than 50%.
    Type: Grant
    Filed: November 18, 2011
    Date of Patent: December 19, 2017
    Assignee: Kobe Steel, Ltd.
    Inventors: Hisao Shishido, Shinya Katsura, Yasuhiro Aruga, Katsushi Matsumoto
  • Patent number: 9751760
    Abstract: The invention provides a process for exfoliating a 3-dimensional layered material to produce a 2-dimensional material, said process comprising the steps of mixing the layered material in a solvent to provide a mixture; applying energy, for example ultrasound, to said mixture, and removing the energy applied to the mixture, such that sedimentation of the 2-dimensional material out of solution as a weakly re-aggregated, exfoliated 2-dimensional material is produced. The invention provides a fast, simple and high yielding process for separating 3-dimensional layered materials into individual 2-dimensional layers or flakes, which do not strongly re-aggregate, without utilising hazardous solvents.
    Type: Grant
    Filed: June 28, 2013
    Date of Patent: September 5, 2017
    Assignee: The Provost, Fellows, Foundation Scholars, and the Other Members of Board of the College of the Holy and Undivided Trinity of Queen Elizabeth Near Dublin
    Inventors: Jonathan Coleman, Umar Khan
  • Patent number: 9394589
    Abstract: Disclosed is a Ni—Si—Co copper alloy that is suitable for use for various kinds of electronic parts and has particularly good uniform plating adhesion properties. The copper alloy for electronic materials comprises Ni: 1.0-2.5 mass %, Co: 0.5-2.5 mass % and Si: 0.3-1.2 mass % and the remainder is made of Cu and unavoidable impurities. For the copper alloy for electronic materials, the mean crystal size, at the plate thickness center, is 20 ?m or less, and there are five or fewer crystal particles that contact the surface and have a long axis of 45 ?m or greater per 1 mm rolling direction length. The copper alloy may comprise a maximum of 0.5 mass % Cr and may comprise a maximum in total of 2.0 mass % of one, two or more selected from a group comprising Mg, P, As, Sb, Be, B, Mn, Sn, Ti, Zr, Al, Fe, Zn and Ag.
    Type: Grant
    Filed: December 11, 2009
    Date of Patent: July 19, 2016
    Inventor: Hiroshi Kuwagaki
  • Patent number: 9074629
    Abstract: A multi-layer slide member has a back metal layer mainly composed of a steel plate and a porous layer having a metallic porous member and a resin composition filled in the metallic porous member. The metallic porous member has granular portions and narrow portions and includes a structure, in which the granular portions are connected with each other through the narrow portion. Parts or the entirety of the narrow portions have a Bi phase and a Sn—Ni—Cu intermetallic compound phase.
    Type: Grant
    Filed: November 18, 2013
    Date of Patent: July 7, 2015
    Assignee: DAIDO METAL COMPANY LTD.
    Inventors: Takayoshi Yamauchi, Kentaro Tsujimoto
  • Patent number: 9034123
    Abstract: This invention provides a copper alloy sheet material containing, in mass %, Ni: 0.7%-4.2% and Si: 0.2%-1.0%, optionally containing one or more of Sn: 1.2% or less, Zn: 2.0% or less, Mg: 1.0% or less, Co: 2.0% or less, and Fe: 1.0% or less, and a total of 3% or less of one or more of Cr, B, P, Zr, Ti, Mn and V, the balance being substantially Cu, and having a crystal orientation satisfying Expression (1): I{420}/I0{420}>1.0??(1), where I{420} is the x-ray diffraction intensity from the {420} crystal plane in the sheet plane of the copper alloy sheet material and I0{420} is the x-ray diffraction intensity from the {420} crystal plane of standard pure copper powder. The copper alloy sheet material has highly improved strength, post-notching bending workability, and stress relaxation resistance property.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: May 19, 2015
    Assignee: DOWA METALTECH CO., LTD.
    Inventors: Weilin Gao, Hisashi Suda, Hiroto Narieda, Akira Sugawara
  • Patent number: 8992706
    Abstract: One aspect of this method of producing a copper alloy sheet includes: a hot rolling process; a cold rolling process; a recrystallization heat treatment process; and a finish cold rolling process in this order, wherein a hot rolling initiation temperature is 800° C. to 940° C., a cooling rate from a temperature after final rolling or 650° C. to 350° C. is 1° C./second or more, and a cold working rate is 55% or more. In the recrystallization heat treatment process, 550?Tmax?790, 0.04?tm?2, and 460?{Tmax?40×tm?1/2?50×(1?RE/100)1/2}?580 are fulfilled, in which Tmax is the highest arrival temperature, tm (min) is a retention time in a temperature range from a temperature lower than the highest arrival temperature by 50° C. to the highest arrival temperature, and RE (%) is a cold working rate.
    Type: Grant
    Filed: December 5, 2013
    Date of Patent: March 31, 2015
    Assignees: Mitsubishi Shindoh Co., Ltd., Mitsubishi Materials Corporation
    Inventor: Keiichiro Oishi
  • Patent number: 8986471
    Abstract: A high strength and high thermal conductivity copper alloy tube contains: Co of 0.12 to 0.32 mass %; P of 0.042 to 0.095 mass %; and Sn of 0.005 to 0.30 mass %, wherein a relationship of 3.0?([Co]?0.007)/([P]?0.008)?6.2 is satisfied between a content [Co] mass % of Co and a content [P] mass % of P, and the remainder includes Cu and inevitable impurities. Even when a temperature is increased by heat generated by a drawing process, a recrystallization temperature is increased by uniform precipitation of a compound of Co and P and by solid-solution of Sn. Thus, the generation of recrystallization nucleuses is delayed, thereby improving heat resistance and pressure resistance of the high strength and high thermal conductivity copper alloy tube.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: March 24, 2015
    Assignee: Mitsubishi Shindoh Co., Ltd.
    Inventor: Keiichiro Oishi
  • Publication number: 20150044089
    Abstract: The free-cutting copper alloy according to the present invention contains a greatly reduced amount of lead in comparison with conventional free-cutting copper alloys, but provides industrially satisfactory machinability. The free-cutting alloys comprise 69 to 79 percent, by weight, of copper, 2.0 to 4.0 percent, by weight, of silicon, 0.02 to 0.4 percent, by weight, of lead, and the remaining percent, by weight, of zinc.
    Type: Application
    Filed: August 19, 2014
    Publication date: February 12, 2015
    Inventor: Keiichiro Oishi
  • Patent number: 8871354
    Abstract: Provided is a copper-based sliding material including a steel back-metal layer and a Cu alloy layer. The Cu alloy layer contains, by mass %, 10 to 30% of Bi, 0.5 to 5% of an inorganic compound, and the balance being Cu and inevitable impurities. The Cu alloy layer may further contain 0.5 to 5% of Sn and/or at least one element selected from the group consisting of Ni, Fe, P and Ag in a total amount of 0.1 to 10%. The inorganic compound has an average particle size of 1 to 5 ?m and a specific gravity of 70 to 130% relative to the specific gravity of Bi. Bi phase is formed in the Cu alloy layer in an average particle size of 2 to 15 ?m, and the Bi phase is dispersed in the Cu alloy layer and isotropic.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: October 28, 2014
    Assignee: Daido Metal Company Ltd.
    Inventors: Takuo Imai, Kouji Zusi, Kentaro Tujimoto
  • Publication number: 20140311633
    Abstract: A spinodal copper-nickel-tin alloy with a combination of improved impact strength, yield strength, and ductility is disclosed. The alloy is formed by process treatment steps including solution annealing, cold working and spinodal hardening. These include such processes as a first heat treatment/homogenization step followed by hot working, solution annealing, cold working, and a second heat treatment/spinodally hardening step. The spinodal alloys so produced are useful for applications demanding enhanced strength and ductility such as for pipes and tubes used in the oil and gas industry.
    Type: Application
    Filed: April 23, 2014
    Publication date: October 23, 2014
    Applicant: Materion Corporation
    Inventors: W. Raymond Cribb, Chad A. Finkbeiner, Fritz C. Grensing
  • Publication number: 20140305551
    Abstract: A copper alloy material for electrical and electronic components and a method of preparing the same are disclosed. In particular, a copper alloy material with excellent mechanical strength characteristics, high electrical conductivity, and high thermal stability as a material for information transmission and electrical contact of connectors or the like for home appliances and automobiles, including semiconductor lead frames and a method of preparing the same are disclosed.
    Type: Application
    Filed: October 22, 2013
    Publication date: October 16, 2014
    Applicant: POONGSAN CORPORATION
    Inventors: CHEOL MIN PARK, In Youb Hwang
  • Patent number: 8834747
    Abstract: Compositions containing tin nanoparticles and electrically conductive particles are described herein. The tin nanoparticles can have a size below about 25 nm so as to make the compositions fusable at temperatures below that of bulk tin (m.p.=232° C.). Particularly, when the tin nanoparticles are less than about 10 nm in size, the compositions can have a fusion temperature of less than about 200° C. The compositions can contain a whisker suppressant to inhibit or substantially minimize the formation of tin whiskers after tin nanoparticle fusion. In some embodiments, the compositions contain tin nanoparticles, electrically conductive particles comprising copper particles, and a whisker suppressant comprising nickel particles. Methods for using the present compositions are also described herein. The present compositions can be used as a lead solder replacement that allows rework to be performed.
    Type: Grant
    Filed: March 3, 2011
    Date of Patent: September 16, 2014
    Assignee: Lockheed Martin Corporation
    Inventor: Alfred A. Zinn
  • Patent number: 8821655
    Abstract: A copper base alloy achieves a breakthrough electrical conductor product of strength, flexure and conductivity of minimal inverse in relationship of at least 85% IACS electrical conductivity while providing an 80 to 85 ksi tensile strength, an increase of at least 33% in strength compared to prior art and is made from an alloy containing 0.2-0.5 w/o chromium, 0.02-0.20 w/o silver and 0.04-0.16 w/o of a third metallic component selected from tin, magnesium and tin/magnesium together.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: September 2, 2014
    Assignee: Fisk Alloy Inc.
    Inventor: Joseph Saleh
  • Patent number: 8795446
    Abstract: A copper alloy material, having an alloy composition containing any one or both of Ni and Co in an amount of 0.4 to 5.0 mass % in total, and Si in an amount of 0.1 to 1.5 mass %, with the balance being copper and unavoidable impurities, wherein a ratio of an area of grains in which an angle of orientation deviated from S-orientation {2 3 1}<3 4 6> is within 30° is 60 % or more, according to a crystal orientation analysis in EBSD measurement; an electrical or electronic part formed by working the copper alloy material; and a method of producing the copper alloy material.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: August 5, 2014
    Assignee: Furukawa Electric Co., Ltd.
    Inventors: Hiroshi Kaneko, Kiyoshige Hirose, Tatsuhiko Eguchi
  • Patent number: 8715431
    Abstract: A Cu—Fe—P copper alloy sheet which has the high strength and the high electrical conductivity compatible with excellent bendability is provided. The Cu—Fe—P copper alloy sheet contains 0.01% to 3.0% of Fe and 0.01% to 0.3% of P on a percent by mass basis, wherein the orientation density of the Brass orientation is 20 or less and the sum of the orientation densities of the Brass orientation, the S orientation, and the Copper orientation is 10 or more and 50 or less in the microstructure of the copper alloy sheet.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: May 6, 2014
    Assignee: Kobe Steel, Ltd.
    Inventors: Yasuhiro Aruga, Katsura Kajihara
  • Patent number: 8652274
    Abstract: A copper alloy includes Si to facilitate deoxidation, and can be easily manufactured even when including elements such as Cr or Sn. The copper alloy has high conductivity and high workability without negatively affecting the tensile strength. The copper alloy contains 0.2 to 0.4 wt % of Cr, 0.05 to 0.15 wt % of Sn, 0.05 to 0.15 wt % of Zn, 0.01 to 0.30 wt % of Mg, 0.03 to 0.07 wt % of Si, with the remainder being Cu and inevitable impurities. A method for manufacturing the copper alloy includes obtaining a molten metal having the described composition; obtaining an ingot; heating the ingot at a temperature of 900-1000° C. to perform a hot rolling process; cold rolling; performing a first aging process at a temperature of 400-500° C. for 2 to 8 hours; cold rolling; and performing a second aging process at a temperature of 370-450° C. for 2 to 8 hours.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: February 18, 2014
    Assignee: Poonsgan Corporation
    Inventors: Dae Hyun Kim, Dong Woo Lee, In Dal Kim, Sang Young Choi, Ji Hoon Lee, Bo Min Jeon
  • Patent number: 8641838
    Abstract: A copper alloy sheet material, having a composition containing any one or both of Ni and Co in an amount of 0.5 to 5.0 mass % in total, and Si in an amount of 0.3 to 1.5 mass %, with the balance of copper and unavoidable impurities, wherein an area ratio of cube orientation {0 0 1} <1 0 0> is 5 to 50%, according to a crystal orientation analysis in EBSD measurement.
    Type: Grant
    Filed: December 1, 2010
    Date of Patent: February 4, 2014
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Hiroshi Kaneko, Kiyoshige Hirose, Koji Sato
  • Patent number: 8641837
    Abstract: A Cu—Ni—Sn—P alloy is provided, which is excellent in stress relaxation property in a direction perpendicular to a rolling direction, and has any of high strength, high conductivity, and excellent bendability. A copper alloy contains 0.1 to 3.0% of Ni, 0.1 to 3.0% of Sn, and 0.01 to 0.3% of P in mass percent respectively, and includes copper and inevitable impurities as the remainder; wherein in a radial distribution function around a Ni atom according to a XAFS analysis method, a first peak position is within a range of 2.16 to 2.35 ?, the position indicating a distance between a Ni atom in Cu and an atom nearest to the Ni atom. Thus, distances to atoms around the Ni atom in Cu are comparatively increased, so that the stress relaxation property in a direction perpendicular to the rolling direction of the copper alloy is improved.
    Type: Grant
    Filed: September 1, 2006
    Date of Patent: February 4, 2014
    Assignee: Kobe Steel, Ltd.
    Inventors: Yasuhiro Aruga, Katsura Kajihara
  • Patent number: 8603390
    Abstract: A brazing alloy including copper (Cu), phosphorus (P), and strontium (Sr) and any one element of indium (In), boron (B), silver (Ag), tin (Sn), cesium (Cs), germanium (Ge), and nickel (Ni). The brazing alloy includes 5.0 to 7.5 wt % of phosphorus (P) and 0.1 to 5.0 wt % of strontium (Sr) and the remainder is composed of copper (Cu). The brazing alloy includes copper (Cu), phosphorus (P), and strontium (Sr) unlike the existing alloy element. The brazing alloy further includes, as alloy components, one or more elements of indium (In), boron (B), silver (Ag), and tin (Sn). The brazing alloy includes no silver (Ag) or the silver (Ag) content is reduced compared to an existing brazing alloy containing silver (Ag).
    Type: Grant
    Filed: May 8, 2012
    Date of Patent: December 10, 2013
    Assignee: Alcoma, Ltd.
    Inventor: Chu Hyon Cho
  • Publication number: 20130284327
    Abstract: A copper alloy for an electric device contains Mg in a range of 1.3 atomic % or more and less than 2.6 atomic %, Al in a range of 6.7 atomic % or more and 20 atomic % or less, and the balance substantially consisting of Cu and unavoidable impurities. A method of producing a copper alloy includes: performing heating of a copper material to a temperature of not lower than 500° C. and not higher than 1000° C.; performing quenching to cool the heated copper material to 200° C. or lower with a cooling rate of 200° C./min or more; and performing working of the cooled copper material, wherein the copper material is composed of a copper alloy containing Mg in a range of 1.3 atomic % or more and less than 2.6 atomic %, Al in a range of 6.7 atomic % or more and 20 atomic % or less.
    Type: Application
    Filed: November 24, 2011
    Publication date: October 31, 2013
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Kazunari Maki, Yuki Ito
  • Publication number: 20130276938
    Abstract: The free-cutting copper alloy according to the present invention contains a greatly reduced amount of lead in comparison with conventional free-cutting copper alloys, but provides industrially satisfactory machinability. The free-cutting alloys comprise 69 to 79 percent, by weight, of copper, 2.0 to 4.0 percent, by weight, of silicon, 0.02 to 0.4 percent, by weight, of lead, and the remaining percent, by weight, of zinc.
    Type: Application
    Filed: March 14, 2013
    Publication date: October 24, 2013
    Inventor: Mitsubishi Shindoh Co., Ltd.
  • Patent number: 8562764
    Abstract: A copper alloy tube according to the present invention includes Sn 0.1 to 2.0 mass %, P 0.005 to 0.1 mass %, S 0.005 mass % or less, O 0.005 mass % or less, and H 0.0002 mass % or less, and the remainder has a composition consisting of Cu and unavoidable impurities. And, as is annealed, the copper alloy tube has the following characteristics: a tensile strength in the longitudinal direction of the copper alloy tube is 250 N/mm2 or more; an average grain diameter is 30 ?m or less when measured in the direction perpendicular to the thickness direction of the tube, in the cross section perpendicular to the tube axis; and assuming that a tensile strength in the longitudinal direction of the copper alloy tube is ?L, and a tensile strength in the circumferential direction of the same is ?T, ?T/?L>0.93 holds.
    Type: Grant
    Filed: October 2, 2008
    Date of Patent: October 22, 2013
    Assignee: Kobelco & Materials Copper Tube, Ltd.
    Inventors: Masato Watanabe, Takashi Shirai
  • Patent number: 8518192
    Abstract: A lead-free copper alloy includes, in combination by weight, about 10.0% to about 20.0% bismuth, about 0.05% to about 0.3% phosphorous, about 2.2% to about 10.0% tin, up to about 5.0% antimony, and up to about 0.02% boron, the balance essentially copper and incidental elements and impurities. The alloy contains no more than about 0.05 wt. % or 0.10 wt. % lead.
    Type: Grant
    Filed: March 2, 2010
    Date of Patent: August 27, 2013
    Assignee: QuesTek Innovations, LLC
    Inventors: Abhijeet Misra, Jason Sebastian, James A. Wright
  • Patent number: 8470100
    Abstract: Alloys containing copper, iron, tin and, optionally, phosphorus or copper, zinc, tin and, optionally, phosphorus, which can be used in, for example, a copper alloy tube for heat exchangers that provides excellent fracture strength and processability for reducing the weight of the tube and for use in high pressure applications with cooling media such as carbon dioxide.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: June 25, 2013
    Assignee: Luvata Espoo Oy
    Inventors: M. Parker Finney, Larz Ignberg, Claes Anders Kamf, Timothy L. Goebel, Ying Gong, Edward G. Rottmann
  • Patent number: 8449697
    Abstract: A silicon bearing, copper-nickel corrosion resistant and gall resistant alloy with the following weight percentage range is disclosed: Ni=10-40; Fe=1-10; Si=0.5-2.5; Mn=3-15; Sn=0-3; Cu=Balance. Embodiments of the alloy may be used in various sliding applications, such as bearings, bushings, gears and guides. The alloy is particularly suited for use in parts used in food processing equipment.
    Type: Grant
    Filed: February 27, 2011
    Date of Patent: May 28, 2013
    Inventors: Sudhari Sahu, Alpana Pradipkumar Sahu
  • Patent number: 8444779
    Abstract: The invention provides Cu—Ni—Si—Co alloys having excellent strength, electrical conductivity, and press-punching properties. In one aspect, the invention is a copper alloy for electronic materials, containing 1.0 to 2.5 mass % of Ni, 0.5 to 2.5 mass % of Co, and 0.30 to 1.2 mass % of Si, the balance being Cu and unavoidable impurities, wherein the copper alloy for electronic material has a [Ni+Co+Si] content in which the median value ? (mass %) satisfies the formula 20 (mass %)???60 (mass %), the standard deviation ? (Ni+Co+Si) satisfies the formula ? (Ni+Co+Si)?30 (mass %), and the surface area ratio S (%) satisfies the formula 1%?S?10%, in relation to the compositional variation and the surface area ratio of second-phase particles size of 0.1 ?m or greater and 1 ?m or less when observed in a cross section parallel to a rolling direction.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: May 21, 2013
    Assignee: JX Nippon Mining & Metals Co., Ltd.
    Inventors: Naohiko Era, Hiroshi Kuwagaki
  • Patent number: 8435361
    Abstract: A novel copper-zinc alloy is particularly suited for a valve guide. The copper-zinc alloy contains 59 to 73% copper, 2.7 to 8.3% manganese, 1.5 to 6% aluminum, 0.2 to 4% silicon, 0.2 to 3% iron, 0 to 2% lead, 0 to 2% nickel, 0 to 0.2% tin, remainder zinc and inevitable impurities.
    Type: Grant
    Filed: June 1, 2007
    Date of Patent: May 7, 2013
    Assignee: Diehl Metall Stiftung & Co. KG
    Inventors: Norbert Gaag, Alexander Dehnelt
  • Patent number: 8430979
    Abstract: A copper alloy having an improved combination of yield strength and electrical conductivity contains, by weight, from 1% to 2.5% of nickel, from 0.5% to 2.0% of cobalt, with a total nickel plus cobalt content of from 1.7% to 4.3%, from 0.5% to 1.5% of silicon with a ratio of (Ni+Co)/Si of between 3.5 and 6, and the balance copper and inevitable impurities wherein the wrought copper alloy has an electrical conductivity in excess of 40% IACS. A further increase in the combination of yield strength and electrical conductivity as well as enhanced resistance to stress relaxation is obtained by a further inclusion of up to 1% of silver.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: April 30, 2013
    Assignee: GBC Metals, LLC
    Inventors: Frank N. Mandigo, Peter W. Robinson, Derek E. Tyler, Andreas Boegel, Hans-Achim Kuhn, Frank M. Keppeler, Joerg Seeger
  • Publication number: 20130087255
    Abstract: Disclosed is a Cu—Co—Si-based copper alloy for electronic materials, which is capable of achieving high levels of strength, electrical conductivity, and also anti-setting property; and contains 0.5 to 3.0% by mass of Co, 0.1 to 1.0% by mass of Si, and the balance of Cu and inevitable impurities; wherein out of second phase particles precipitated in the matrix a number density of the particles having particle size of 5 nm or larger and 50 nm or smaller is 1×1012 to 1×1014 particles/mm3, and a ratio of the number density of particles having particle size of 5 nm or larger and smaller than 10 nm relative to the number density of particles having particle size of 10 nm or larger and 50 nm or smaller is 3 to 6.
    Type: Application
    Filed: April 8, 2011
    Publication date: April 11, 2013
    Applicant: JX Nippon Mining & Metals Corporation
    Inventor: Hiroshi Kuwagaki
  • Publication number: 20130056116
    Abstract: A copper alloy for an electronic device containing Mg in a range of 2.6 atomic % or more and 9.8 atomic % or less, Al in a range of 0.1 atomic % or more and 20 atomic % or less, and the balance substantially consisting of Cu and unavoidable impurities.
    Type: Application
    Filed: May 12, 2011
    Publication date: March 7, 2013
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Yuki Ito, Kazunari Maki
  • Patent number: 8366840
    Abstract: By enhancing a stress corrosion cracking resistance in a leadless brass alloy, specifically by suppressing a velocity of propagation of corrosion cracks in the brass alloy, a straight line crack peculiar to the leadless brass alloy is suppressed, a probability of cracks coming into contact with ? phases is heightened and local corrosion on the brass surface is prevented to suppress induction of cracks by the local corrosion, thereby providing a leadless brass alloy contributable to enhancement of the stress corrosion cracking resistance. The present invention is directed to an Sn-containing Bi-based, Sn-containing Bi+Sb-based or Sn-containing Bi+Se+Sb-based leadless brass alloy excellent in stress corrosion cracking resistance, having an ?+? structure or ?+?+? structure and having ? phases distributed uniformly therein at a predetermined proportion to suppress local corrosion and induction of stress corrosion cracks.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: February 5, 2013
    Assignee: Kitz Corporation
    Inventors: Hidenobu Tameda, Kazuhito Kurose, Teruhiko Horigome, Tomoyuki Ozasa, Hisanori Terui, Masaru Yamazaki, Hideki Kotsuji
  • Publication number: 20130014861
    Abstract: The distribution of Ni—Si compound grains is controlled to thereby improve the properties of Corson alloys. The copper alloy for electronic materials comprises 0.4 to 6.0% mass of Ni and 0.1 to 1.4% by mass of Si, with the balance being Cu and unavoidable impurities. The copper alloy comprising: small particles of Ni—Si compound having a particle size of equal to or greater than 0.01 ?m and smaller than 0.3 ?m; and large particles of Ni—Si compound having a particle size of equal to of greater than 0.3 ?m and smaller than 1.5 ?m. The number density of the small particles is 1 to 2000 pieces/?m2 and the number density of the large particles is 0.05 to 2 pieces/?m2.
    Type: Application
    Filed: April 2, 2010
    Publication date: January 17, 2013
    Applicant: JX Nippon Mining & Metal Corporation
    Inventor: Mitsuhiro Ookubo
  • Patent number: 8349097
    Abstract: A dezincification-resistant copper alloy and a method for producing a product containing the same are proposed by the present invention. The dezincification-resistant alloy of the present invention contains 59.5 to 64 wt % of copper (Cu); 0.1 to 0.5 wt % of bismuth (Bi); 0.08 to 0.16 wt % of arsenic (As); 5 to 15 ppm of boron (B); 0.3 to 1.5 wt % of tin (Sn); 0.1 to 0.7 wt % of zirconium (Zr); less than 0.05 wt % of lead (Pb); and zinc (Zn) in balance. The dezincification-resistant copper alloy of the present invention has excellent casting properties, good toughness and machinability, and can be corrosion-resistant. Thus, the alloy can reduce dezincification on the surfaces.
    Type: Grant
    Filed: September 17, 2009
    Date of Patent: January 8, 2013
    Assignee: Modern Islands Co., Ltd.
    Inventors: Wen Lin Lo, Xiao Rong Fang
  • Publication number: 20120312430
    Abstract: The present invention relates to a copper alloy having particular benefits for electronic parts and a method for making the same. The alloy having the composition of 0.05 wt % of Fe, 0.025˜0.15 wt % P, 0.01˜0.25 wt % Cr, 0.01˜0.15 wt %, Si 0.01˜0.25 wt % Mg, and the balance of Cu and minor impurities. The method of making the copper alloy includes: forming the molten alloy, casting to obtain an ingot, hot rolling the ingot at 850˜1,000° C., cooling, cold rolling the hot rolled product (after cooling the same), annealing the cold rolled product at 400˜600° C. for 1˜10 hours, intermediate rolling the annealed product with a reduction ratio of 30˜70%, heat treating the intermediate rolled product at 500˜800° C. for 30˜600 seconds, and finishing rolling the heat treated product with a reduction ratio of 20˜40%.
    Type: Application
    Filed: October 28, 2010
    Publication date: December 13, 2012
    Inventors: Dae Hyun Kim, Dong Woo Lee, In Dal Kim, Sang Young Choi, Ji Hoon Lee, Bo Min Jeon