Tin Containing Patents (Class 148/433)
  • Patent number: 6896748
    Abstract: The sputter target has a composition selected from the group consisting of high-purity copper and copper-base alloys. The sputter target's grain structure is at least about 99 percent recrystallized; and the sputter target's face has a grain orientation ratio of at least about 10 percent each of (111), (200), (220) and (311). In addition, the sputter target has a grain size of less than about 10 ?m for improving sputter uniformity and reducing sputter target arcing.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: May 24, 2005
    Assignee: Praxair S.T. Technology, Inc.
    Inventors: Andrew C. Perry, Paul S. Gilman
  • Patent number: 6893514
    Abstract: A high-mechanical strength copper alloy, which comprises Ni 3.5 to 4.5% by mass, Si 0.7 to 1.0% by mass, Mg 0.01 to 0.20% by mass, Sn 0.05 to 1.5% by mass, Zn 0.2 to 1.5% by mass, and S less than 0.005% by mass (including 0% by mass), with the balance being made of Cu and inevitable impurities, wherein a crystal grain diameter is from more than 0.001 mm to 0.025 mm; and the ratio (a/b), between a longer diameter a of a crystal grain on a cross section parallel to a direction of final plastic-working, and a longer diameter b of a crystal grain on a cross section perpendicular to the direction of final-plastic working, is 1.5 or less, and wherein the alloy has a tensile strength of 800 N/mm2 or more.
    Type: Grant
    Filed: September 27, 2001
    Date of Patent: May 17, 2005
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Takayuki Usami, Takao Hirai
  • Patent number: 6881281
    Abstract: The present invention provides a Cu—Cr—Zr alloy material excellent in fatigue and intermediate temperature characteristics, which comprises 0.05 to 1.0% by mass of Cr and 0.05 to 0.25% by mass of Zr with a balance of Cu and inevitable impurities. The alloy comprises inclusion particles based on any one of Zr and a Cu—Zr alloy having a diameter of 0.1 ?m or more, and the proportion of the inclusion particles containing 10% or more of sulfur as one of the inevitable impurities is one particle/mm2.
    Type: Grant
    Filed: January 20, 2004
    Date of Patent: April 19, 2005
    Assignee: Nikko Metal Manufacturing Co., Ltd.
    Inventors: Kazuki Kanmuri, Kazuhiko Fukamachi
  • Patent number: 6863746
    Abstract: The present invention discloses a white gold composition consisting essentially of copper, silver, zinc, and manganese, and further consisting of small amounts of tin, cobalt, silicon/copper and boron/copper. More particularly, the white gold composition of the present invention discloses a white gold composition consisting essentially of about 36% to about 57% copper, about 10% silver, about 18.2% to about 24.2% zinc, about 14% to about 28.9% manganese, and the balance further consisting of about 1% tin, about 0.025% to about 0.03% cobalt, about 0.52% silicon/copper, and about 0.2% boron/copper. An objective of the present invention is to provide for methods and compositions of casting, fabricating and soldering white gold that does not incorporate nickel or palladium. The present invention also discloses no tarnish results when hydrogen is used as a catalyst to all compositions.
    Type: Grant
    Filed: August 2, 2001
    Date of Patent: March 8, 2005
    Inventor: Keith Weinstein
  • Patent number: 6858102
    Abstract: The invention includes a sputtering target containing copper of a purity of at least about 99.999 wt. %, and at least one component selected from the group consisting of Ag, Sn, Te, In, B, Bi, Sb, and P dispersed within the copper. The total of Ag, Sn, Te, In, B, Bi, Sb, and P within the copper is from at least 0.3 ppm to about 10 ppm. The sputtering target has a substantially uniform grain size of less than or equal to about 50 micrometers throughout the copper and the at least one component.
    Type: Grant
    Filed: November 15, 2000
    Date of Patent: February 22, 2005
    Assignee: Honeywell International Inc.
    Inventors: Janine K. Kardokus, Chi tse Wu, Christopher L. Parfeniuk, Jane E. Buehler
  • Patent number: 6790297
    Abstract: A brass is a base material, and a material containing Mn and Si is cast to make a ring material. Ametallic structure in the cross section of the ring material is under a condition where an intermetallic compound Mn5Si3 is uniformly and finely scattered and precipitated in the base material (brass composed of &agr;- and &bgr;-phase). A machined retainer provided by matching said material has an excellent sizing precision, sound affect resistance.
    Type: Grant
    Filed: September 7, 2000
    Date of Patent: September 14, 2004
    Assignee: NSK Ltd.
    Inventors: Kouji Ueda, Manabu Ohori, Keijiro Yamaguchi, Takashi Murai
  • Patent number: 6783611
    Abstract: A phosphorized copper anode used for electroplating, including: 20-800 ppm of phosphorus; between 0.1 and less than 2 ppm of oxygen, and the balance being high purity copper having a purity of 99.9999% by mass or higher, wherein the average grain size of the copper anode after recrystallization is in the range between about 10 and 50 &mgr;m.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: August 31, 2004
    Assignee: Mitsubishi Materials Corporation
    Inventors: Kenji Yajima, Akihiro Kakimoto, Hideyuki Ikenoya
  • Publication number: 20040159375
    Abstract: A copper-based alloy excellent in dezincing resistance comprises, in percentage by weight, Cu: 57-69%, Sn: 0.3-3%, Si: 0.02-1.5%, Bi: 0.5-3%, and Pb: not more than 0.2%, where the ratio of Si/Sn expressed in weight percentage is in the range of 0.05-1 and apparent zinc content as defined by the following formula is in the range of more than 39-50 wt. %, and the balance of unavoidable impurities: Apparent Zn content=[(Zn %+2.0×Sn %+10.0×Si %)/(Cu %+Zn %+2.0×Sn %+10.0×Si %)]×100. Despite the fact that contains no added environment-unfriendly Pb, the alloy exhibits enhanced cuttability, together with excellent forgeability, dezincing resistance and hot forgeability.
    Type: Application
    Filed: October 29, 2003
    Publication date: August 19, 2004
    Inventor: Yoshinori Yamagishi
  • Patent number: 6749699
    Abstract: A copper alloy that consists essentially of, by weight, from 0.15% to 0.7% of chromium, from 0.005% to 0.3% of silver, from 0.01% to 0.15% of titanium, from 0.01% to 0.10% of silicon, up to 0.2% of iron, up to 0.5% of tin, and the balance copper and inevitable impurities has high strength, a yield strength in excess of 80 ksi, and high electrical conductivity, in excess of 80% IACS. The alloy further has substantially isotropic bend characteristics when the processing route includes a solution heat anneal above 850° C. and subsequent cold rolling into sheet, strip or foil interspersed by bell annealing. As a result, the alloy is particularly suited for forming into box-type electrical connectors for both automotive or multimedia applications. The alloy is also suitable for forming into a rod, wire or section.
    Type: Grant
    Filed: August 6, 2001
    Date of Patent: June 15, 2004
    Assignees: Olin Corporation, Wieland-Werke AG
    Inventors: Andreas Bögel, Jörg Seeger, Hans-Achim Kuhn, John F. Breedis, Ronald N. Caron, Derek E. Tyler
  • Publication number: 20040094243
    Abstract: Disclosed is a lead-free copper alloy with superior properties as compared to currently available lead-free copper alloys which can be produced at lower costs than currently available lead-free copper alloys. The lead-free copper alloy uses a novel combination of tin, nickel and zinc along with selenium and bismuth to avoids the problems associated with leaded copper alloys, while maintaining physical properties comparable to traditional leaded copper alloys. In one embodiment, the lead-free copper alloy described contains from about 7.5 to 10.0 percent by weight zinc, from about 0.8 to 1.5 percent by weight nickel, from about 1.6 to 2.2 percent by weight bismuth, from about 0.04 to 0.35 percent by weight selenium, from about 2.2 to 3.0 percent by weight tin and up to about 0.3 percent by weight iron (maximum), the balance, apart from impurities, being copper. In an alternate embodiment, the lead-free copper alloy described contains from about 5 to 7.5 percent by weight zinc, from about 1.0 to 1.
    Type: Application
    Filed: November 15, 2002
    Publication date: May 20, 2004
    Inventors: Albert Wynne, Peter B. Kirkland
  • Patent number: 6716541
    Abstract: The material for a metal strip for manufacturing electrical contact component parts has, expressed in percent by weight, the following composition: nickel (Ni) 0.5-3.5% silicon (Si) 0.08-1.0%  tin (Sn) 0.1-1.0% zinc (Zn) 0.1-1.0% zirconium (Zr) 0.005-0.2%  silver (Ag) 0.02- 0.5%  The remainder is copper and includes impurities caused by smelting.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: April 6, 2004
    Assignee: Stolberger Metallwerke GmbH & Co. KG
    Inventors: Udo Adler, Jürgen Gebhardt, Heinz Klenen, Robert Leffers, Thomas Helmenkamp
  • Patent number: 6716292
    Abstract: An unwrought continuous cast Cu—Ni—Sn spinodal alloy and a method for producing the same is disclosed. The Cu—Ni—Sn spinodal alloy is characterized by an absence of discontinuous &ggr;′ phase precipitate at the grain boundaries, ductile fracture behavior during tensile testing, high strength, excellent wear and corrosion resistance, superior bearing properties, and contains from about 8-16 wt. % nickel, from about 5-8 wt. % tin, and a remainder copper.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: April 6, 2004
    Assignee: Castech, Inc.
    Inventors: William D. Nielsen, Jr., William D. Nielsen, Sr.
  • Publication number: 20040045640
    Abstract: A high-mechanical strength copper alloy, which comprises Ni 1.0 to 4.5% by mass, Si 0.2 to 1.0% by mass, Mg 0.01 to 0.20% by mass, Sn 0.05 to 1.5% by mass, Zn 0.2 to 1.5% by mass, and S less than 0.005% by mass (including 0% by mass), with the balance being made of Cu and inevitable impurities, wherein the alloy has a tensile strength of 800 N/mm2 or more, and wherein the alloy has a stress relaxation ratio of 10% or less.
    Type: Application
    Filed: June 25, 2003
    Publication date: March 11, 2004
    Inventors: Takayuki Usami, Takao Hirai
  • Patent number: 6699337
    Abstract: An ingot of a copper-base alloy containing a total of 0.
    Type: Grant
    Filed: December 3, 2001
    Date of Patent: March 2, 2004
    Assignee: Dowa Mining Co., Ltd.
    Inventors: Koichi Hatakeyama, Akira Sugawara
  • Patent number: 6695934
    Abstract: A copper base alloy consisting essentially of tin in an amount from about 0.1 to about 1.5% by weight, phosphorous in an amount from about 0.01 to about 0.35% by weight, iron in an amount from about 0.01 to about 0.8% by weight, zinc in an amount from about 1.0 to about 15% by weight, and the balance essentially copper, including phosphide particles uniformly distributed throughout the matrix, is described. The alloy is characterized by an excellent combination of physical properties. The process of forming the copper base alloy described herein includes casting, homogenizing, rolling, process annealing and stress relief annealing.
    Type: Grant
    Filed: March 16, 2000
    Date of Patent: February 24, 2004
    Assignee: Waterbury Rolling Mills, Inc.
    Inventor: Ashok K. Bhargava
  • Patent number: 6679955
    Abstract: In the present invention, forming is carried out by employing casting to rapidly solidify molten material comprising a copper base alloy containing 3 to 20% Ag (mass % hereinafter), 0.5 to 1.5% Cr and 0.05 to 0.5% Zr. Next, an aging treatment for precipitation is carried out at 450 to 500° C., and the formed article is obtained by precipitation strengthening. In addition, in the aforementioned copper base alloy, molten material comprising a copper base alloy containing Ag in the amount of 3 to 8.5% is solidified by casting, and the solidified article or the hot worked article thereof is subjected to an aging treatment for precipitation and a thermomechanical treatment using forging or rolling, and the casting is obtained by forming the material into a specific shape and carrying out precipitation strengthening.
    Type: Grant
    Filed: April 3, 2001
    Date of Patent: January 20, 2004
    Assignee: Ishikawajima-Harima Heavy Industries, Co., Ltd.
    Inventor: Kazuaki Mino
  • Publication number: 20040007294
    Abstract: A phosphor bronze strip having excellent bending workability and high mechanical strength for use in electronic parts such as terminal connectors wherein;
    Type: Application
    Filed: March 28, 2003
    Publication date: January 15, 2004
    Inventors: Kazuhiko Fukamachi, Toshihiro Niimi
  • Patent number: 6652675
    Abstract: Disclosed is a copper alloy sliding material having a metal structure wherein intermetallic compounds exist adjacently to Pb-phase islands and/or Bi-phase islands. Because intermetallic compounds exist between the matrix and the Pb phase and/or the Bi phase, the material can have improved anti-seizure property, since, under load or due to wear, the surface of the material has recessions at the soft Pb and/or Bi phase and the matrix with respect to the intermetallic compounds.
    Type: Grant
    Filed: December 28, 2000
    Date of Patent: November 25, 2003
    Assignee: Daido Metal Company Ltd.
    Inventors: Kenji Sakai, Naohisa Kawakami, Satoru Kurimoto, Koichi Yamamoto, Takayuki Shibayama
  • Publication number: 20030205301
    Abstract: Brass consists essentially of Cu, Sn, Bi, Fe, Ni and P in weight ratios respectively of 58.0-63.2%, 0.3-2.0%, 0.7-2.5%, 0.05-0.3%, 0.10-0.50% and 0.05-0.15% plus the balance of Zn and unavoidable impurities to exhibit excellent tolerance for dezincification, hot forgeability and machinability.
    Type: Application
    Filed: June 2, 2003
    Publication date: November 6, 2003
    Inventors: Koichi Hagiwara, Masaru Yamazaki, Yoshihiro Hirata, Mitsuhide Hirabayashi, Kozo Ito
  • Patent number: 6632300
    Abstract: A copper alloy having improved stress relaxation resistance is formed from a copper base alloy that consists, by weight, essentially of 1.8%-3.0% iron, 0.01%-1.0% zinc, 0.001 %-0.25% phosphorus, 0.1 %-0.35% magnesium and the balance is copper and unavoidable impurities. When compared to other copper base alloys that include iron, zinc and phosphorous, the disclosed alloy has improved resistance to stress relaxation. In addition, directionality of stress relaxation resistance (where stress relaxation resistance is typically poorer in a transverse strip direction relative to a longitudinal strip direction for a copper alloy that is strengthened by cold rolling) is reduced to being nearly equivalent, regardless of strip direction. The alloy is particularly useful for electronic applications, such as being formed into an electrical connectors.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: October 14, 2003
    Assignee: Olin Corporation
    Inventors: John F. Breedis, Dennis R. Brauer, Peter W. Robinson
  • Publication number: 20030188814
    Abstract: The invention aims at providing high-strength copper alloy, especially phosphor bronze, with excellent bending workability. The excellently bendable high-strength copper alloy is obtained through grain size control whereby a finally cold rolled copper alloy with a tensile strength and 0.2% yield strength different by not more than 80 MPa is allowed to have characteristics such that its mean grain size (mGS) after annealing at 425° C. for 10,000 seconds is not more than 5 &mgr;m and the standard deviation of the mean grain size (&sgr;GS) is not more than ⅓XmGS. Improvements in characteristics presumably attributable to the synergistic effect of grain-boundary strengthening and dislocation strengthening are stably achieved by the adjustments of cold rolling and annealing conditions and by the study of the correlation between pertinent characteristic values after the final rolling.
    Type: Application
    Filed: March 10, 2003
    Publication date: October 9, 2003
    Inventors: Kazuhiko Fukamachi, Masato Shigyo
  • Patent number: 6627009
    Abstract: In an extrafine or ultrafine copper alloy wire having an outer diameter of not more than 0.1 mm, the copper alloy wire is formed of a heat treated copper alloy comprising 0.05 to 0.9% by weight in total of at least one metallic element selected from the group consisting of tin, indium, silver, antimony, magnesium, aluminum, and boron and not more than 50 ppm of oxygen with the balance consisting of copper. By virtue of this constitution, the extrafine or ultrafine copper alloy wire has a combination of excellent bending fatigue lifetime based on high tensile strength and excellent torsional strength based on high elongation or a combination of excellent tensile strength, electrical conductivity, and drawability and good elongation. The invention has been described in detail with particular reference to preferred embodiments, but it will be understood that variations and modifications can be effected within the scope of the invention as set forth in the appended claims.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: September 30, 2003
    Assignee: Hitachi Cable Ltd.
    Inventors: Hakaru Matsui, Takaaki Ichikawa, Seigi Aoyama, Koichi Tamura, Osamu Seya, Hiroshi Komuro, Ryohei Okada, Shigetoshi Goto
  • Publication number: 20030173000
    Abstract: Disclosed is a sliding material containing 0.5 to 15 mass % of Sn, 0.2 to 10 mass % of Ni, 0.4 to 10 volume % of hard particles, and the balance being essentially Cu. The hard particles are of one or more selected from the group consisting of WC, W2C, Mo2C, W, and Mo. A grain size of the Cu—Sn—Ni matrix is set to be not more than 0.070 mm.
    Type: Application
    Filed: February 19, 2003
    Publication date: September 18, 2003
    Applicant: DAIDO METAL COMPANY, LTD.
    Inventors: Kenji Sakai, Hiroyuki Sugawara, Hideo Ishikawa, Masaaki Sakamoto
  • Publication number: 20030129076
    Abstract: Copper alloy having the basic composition Cu—Zn—Sn contains 23-28 wt % Zn and 0.3-1.8 wt % Sn and satisfies the relation 6.0≦0.25X+Y≦8.5 (where X is the addition of Zn in wt % and Y is the addition of Sn in wt %). The alloy is cast into an ingot by melting and cooling over the range from the liquidus line to 600° C. at a rate of at least 50° C./min; the ingot is hot rolled at a temperature not higher than 900° C. and then subjected to repeated cycles of cold rolling and annealing at 300-650° C. to control the size of crystal grains, thereby producing a rolled strip having a 0.2% yield strength of at least 600 N/mm2, a tensile strength of at least 650 N/mm2, an electrical conductivity of at least 20% IACS, a Young's modulus of no more than 120 kN/mm2 and a percent stress relaxation of no more than 20%.
    Type: Application
    Filed: September 23, 2002
    Publication date: July 10, 2003
    Applicant: DOWA MINING CO., LTD.
    Inventors: Akira Sugawara, Kazuki Hatakeyama, Le Ling
  • Publication number: 20030029528
    Abstract: A method for inhibiting metal dusting corrosion of surfaces exposed to supersaturated carbon environments comprising constructing said surfaces of, or coating said surfaces with a copper based alloy. The invention is also directed to a composition resistant to metal dusting.
    Type: Application
    Filed: December 7, 2001
    Publication date: February 13, 2003
    Inventors: Trikur Anantharaman Ramanarayanan, Changmin Chun, James Dirickson Mumford
  • Patent number: 6482276
    Abstract: A copper alloy with excellent punchability, comprising 0.2 to 0.35 wt % of Cr, 0.1 to 0.5 wt % of Sn, and 0.1 to 0.5 wt % of Zn, the balance being made of Cu and unavoidable impurities, wherein, in a Cu matrix, a precipitation phase A of Cr or a Cr compound of 0.1 to 10 &mgr;m in maximum diameter, is provided, at a density in number of 1×103 to 3×105/mm2, and a precipitation phase B of Cr or a Cr compound of 0.001 to 0.030 &mgr;m in maximum diameter, is provided, at a density in number that is 10 times or more of that of the precipitation phase A.
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: November 19, 2002
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Takao Hirai, Yoshimasa Ohyama, Takayuki Usami
  • Publication number: 20020162611
    Abstract: The casting porosity of an unwrought casting made from an alloy having a large difference between its liquidus and solidus temperatures is reduced by subjecting the casting to hot isostatic pressing.
    Type: Application
    Filed: March 1, 2001
    Publication date: November 7, 2002
    Inventor: Don H. Hashiguchi
  • Patent number: 6471792
    Abstract: An alpha brass (copper/zinc alloy with less than 39%, by weight, of zinc) stock alloy has controlled additions of nickel, tin and phosphorous. The combination of nickel and tin increase resistance of the alloy to elevated temperature stress relaxation. As a result, spring contacts formed from alloys of the invention maintain a higher percentage of initially imposed stress at elevated temperatures, in the range of 125° C. to 150° C., for significantly longer times than other brass alloys of comparable strength.
    Type: Grant
    Filed: October 29, 1999
    Date of Patent: October 29, 2002
    Assignee: Olin Corporation
    Inventors: John F. Breedis, Ronald N. Caron, Carl L. Deppisch
  • Patent number: 6458222
    Abstract: A brass for forging which has an apparent Zn content of 37 to 50 wt % and contains 0.5 to 7 wt % Sn. The brass has a microstructure of at least an &agr; phase and a &ggr; phase at a temperature of 300 to 550° C. and has crystal grain sizes which are made fine. A process for preparing brass involving making the crystal grain size of brass material fine and plastic working the brass material at 300 to 550° C.
    Type: Grant
    Filed: May 8, 2000
    Date of Patent: October 1, 2002
    Assignee: Toto Ltd.
    Inventors: Ryuji Matsubara, Nobuyuki Ashie, Katsuaki Nakamura
  • Publication number: 20020119071
    Abstract: A high-mechanical strength copper alloy, which comprises Ni 3.5 to 4.5% by mass, Si 0.7 to 1.0% by mass, Mg 0.01 to 0.20% by mass, Sn 0.05 to 1.5% by mass, Zn 0.2 to 1.5% by mass, and S less than 0.005% by mass (including 0% by mass), with the balance being made of Cu and inevitable impurities, wherein a crystal grain diameter is from more than 0.001 mm to 0.025 mm; and the ratio (a/b), between a longer diameter a of a crystal grain on a cross section parallel to a direction of final plastic-working, and a longer diameter b of a crystal grain on a cross section perpendicular to the direction of final-plastic working, is 1.5 or less, and wherein the alloy has a tensile strength of 800 N/mm2 or more.
    Type: Application
    Filed: September 27, 2001
    Publication date: August 29, 2002
    Inventors: Takayuki Usami, Takao Hirai
  • Publication number: 20020108685
    Abstract: An ingot of a copper-base alloy containing a total of 0.
    Type: Application
    Filed: December 3, 2001
    Publication date: August 15, 2002
    Applicant: DOWA MINING CO., LTD.
    Inventors: Koichi Hatakeyama, Akira Sugawara
  • Patent number: 6419766
    Abstract: A cutting-free bronze alloy which is substantially free of lead contains 1 to 13 wt. % of tin, not larger than 18 wt. % of zinc, 0.5 to 6 wt. % of bismuth, 0.05 to 3 wt. % of antimony, not larger than 1 wt. % of phosphorus, less than 0.4 wt. % of lead, and the balance being copper. The alloy may further contain 0.1 to 3 wt. % of nickel. When 3 to 8 wt. % of tin and 6 to 10 wt. % of zinc are present, the alloy is particularly suitable for use as a plumbing faucet and fixture. Likewise, when 8.5 to 13 wt. % of tin and not larger than 1 wt. % of zinc are present, the alloy is suitable for use as a sliding member.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: July 16, 2002
    Assignees: Tabuchi Corp., Chuetsu Metal Works Co., Ltd.
    Inventors: Yukinori Ikemiya, Hideki Yoshimura, Kenji Sugiyama, Kunio Nakashima, Masao Hosoda, Wataru Yago, Kazuyuki Inagaki
  • Patent number: 6395110
    Abstract: The present invention provides a copper-based alloy characterized by: having a composition of 58.0 to 63.0% by weight of Cu, 0.5 to 4.5% by weight of Pb, 0.05 to 0.25% by weight of P, 0.5 to 3.0% by weight of Sn, 0.05 to 0.30% by weight of Ni, and the balance of Zn and inevitable impurities; having a texture uniformly fragmented to acquire excellent corrosion resistance and hot working property; having undergone a given drawing work and heat treatment to acquire excellent mechanical properties including tensile strength, proof strength and elongation; and having internal stress thoroughly removed to excel in stress-corrosion cracking resistance.
    Type: Grant
    Filed: October 7, 1999
    Date of Patent: May 28, 2002
    Assignee: Kitz Corporation
    Inventors: Tadao Mizoguchi, Kozo Itoh, Kazuaki Yajima
  • Patent number: 6379478
    Abstract: A phosphor bronze alloy which contains 0.4 to 3.0 weight % Ni, 0.1 to 1.0 weight % Si, 0.01 to 0.35 weight % P, 1.0 to 11.0 weight % Sn with remainder being substantially Cu.
    Type: Grant
    Filed: May 4, 2000
    Date of Patent: April 30, 2002
    Assignee: The Miller Company
    Inventors: Daniel D. Farquharson, David H. Mandle
  • Patent number: 6348114
    Abstract: A sliding bearing having improved seizure resistance has the following structure: (a) A bearing layer (2). It comprises a copper alloy containing in a Cu matrix Ag, Sn, Sb, In, Mn, Fe, Bi, Zn, Ni and/or Cr. (b) A first sub-layer (3) of the bearing layer (2). First sub-layer (3) contains concentrated element, hexagonal compound or eutectic of said element(s). (c) A second sub-layer (2a) in which said element in essential solid-solution state. (d) Metal backing (1).
    Type: Grant
    Filed: March 24, 1999
    Date of Patent: February 19, 2002
    Assignee: Taiho Kogyo Co., Ltd.
    Inventors: Haruyuki Oshiro, Takashi Tomikawa, Soji Kamiya, Katuyuki Hashizume
  • Patent number: 6346215
    Abstract: A copper alloy contains from 4 to 20 wt. % tin and various other metals. The alloys can be used in the manufacture of structural parts which are joined together through the use of heat such as jewelry, clothing accessories and mechanically stressed structural parts in a general machine-building or automotive industry. Iron, titanium, zirconium, hafnium, manganese, zinc, phosphorus and lead can also be present in the alloy composition.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: February 12, 2002
    Assignee: Wieland-Werke AG
    Inventors: Andreas Boegel, Stephan Hansmann, Uwe Hofmann, Hilmar R. Mueller, Joachim Riedle
  • Patent number: 6344171
    Abstract: Provided is a copper alloy for electrical or electronic parts which is superior in yield strength, electric conductivity, spring limit value, resistance property of stress relaxation, bendability and Sn plating property. The copper alloy for electrical or electronic parts comprises Fe: 0.5-2.4% (“%” means “% by mass”, which is the same hereinafter.), Si: 0.02-0.1%, Mg: 0.01-0.2%, Sn: 0.01-0.7%, Zn: 0.01-0.2%, Pb: 0.0005-0.015%, P: less than 0.03%, Ni: 0.03% or less, and Mn: 0.03% or less, and further comprises Cu and inevitable impurities as the balance of the copper alloy.
    Type: Grant
    Filed: August 15, 2000
    Date of Patent: February 5, 2002
    Assignee: Kobe Steel, Ltd.
    Inventor: Koya Nomura
  • Publication number: 20020011288
    Abstract: The present invention provides a copper-based alloy characterized by: having a composition of 58.0 to 63.0% by weight of Cu, 0.5 to 4.5% by weight of Pb, 0.05 to 0.25% by weight of P, 0.5 to 3.0% by weight of Sn, 0.05 to 0.30% by weight of Ni, and the balance of Zn and inevitable impurities; having a texture uniformly fragmented to acquire excellent corrosion resistance and hot working property; having undergone a given drawing work and heat treatment to be exalted in mechanical properties including tensile strength, proof strength and elongation; and having internal stress thoroughly removed to excel in stress-corrosion cracking resistance.
    Type: Application
    Filed: October 7, 1999
    Publication date: January 31, 2002
    Inventors: TADAO MIZOGUCHI, KOZO ITOH, KAZUAKI YAJIMA
  • Publication number: 20020007879
    Abstract: An unwrought continuous cast Cu—Ni—Sn spinodal alloy and a method for producing the same is disclosed. The Cu—Ni—Sn spinodal alloy is characterized by an absence of discontinuous &ggr;′ phase precipitate at the grain boundaries, ductile fracture behavior during tensile testing, high strength, excellent wear and corrosion resistance, superior bearing properties, and contains from about 8-16 wt. % nickel, from about 5-8 wt. % tin, and a remainder copper.
    Type: Application
    Filed: November 3, 1995
    Publication date: January 24, 2002
    Inventors: WILIAM D. NIELSEN JR., WILLIAM D. NIELSEN SR.
  • Patent number: 6334914
    Abstract: Disclosed is a copper alloy sliding material comprising 0.5 to 15 mass % Sn and 0.1 to 10 vol % of hard particles consisting of one or more selected from WC, W2C and Mo2C. The hard particles have preferably an average particle size of 0.1 to 10 &mgr;m, whereby they are dispersed in the copper alloy matrix so as to make the sliding-contact surface uneven, from which the hard particles protrude partially. The sliding material comprises an amount or a total amount of not more than 40 mass % of one or more selected from Ni, Ag, Fe, Al, Zn, Mn, Co, Si and P, an amount or a total amount of not more than 10 mass % of Bi and/or Pb, and/or an amount or a total amount of not more than 10 vol % of a solid lubricant comprising BN, graphite, MoS2 and/or WS2.
    Type: Grant
    Filed: December 28, 2000
    Date of Patent: January 1, 2002
    Assignee: Daido Metal Company Ltd.
    Inventors: Kenji Sakai, Naohisa Kawakami, Satoru Kurimoto, Takashi Inaba, Koichi Yamamoto, Takayuki Shibayama
  • Patent number: 6312762
    Abstract: A process for the production of copper or a copper base alloy that provides a surface having improved characteristics suitable for the production of a connector or a charging-socket of an electric automobile by having a decreased coefficient of friction on the surface and improved resistance to abrasion. The process comprises coating copper or a copper alloy with Sn, followed by heat treating the resulting Sn-plated copper or copper base in an atmosphere having an oxygen content of no more than 5%, thereby forming on an outermost surface thereof an oxide film and beneath the surface a layer of an intermetallic compound mainly comprising Cu—Sn.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: November 6, 2001
    Assignees: Dowa Mining Co., Ltd., Yazaki Corporation
    Inventors: Akira Sugawara, Yoshitake Hana, Takayoshi Endo
  • Publication number: 20010035237
    Abstract: A physical vapor deposition target includes an alloy of copper and silver, with the silver being present in the alloy at from less than 1.0 at % to 0.001 at %. In one implementation, a physical vapor deposition target includes an alloy of copper and silver, with the silver being present in the alloy at from 50 at % to 70 at %. A physical vapor deposition target includes an alloy of copper and tin, with tin being present in the alloy at from less than 1.0 at % to 0.001 at %. In one implementation, a conductive integrated circuit metal alloy interconnection includes an alloy of copper and silver, with the silver being present in the alloy at from less than 1.0 at % to 0.001 at %. A conductive integrated circuit metal alloy interconnection includes an alloy of copper and silver, with the silver being present in the alloy at from 50 at % to 70 at %. A conductive integrated circuit metal alloy interconnection includes an alloy of copper and tin, with tin being present in the alloy at from less than 1.0 at % to 0.
    Type: Application
    Filed: February 14, 2001
    Publication date: November 1, 2001
    Inventors: Shozo Nagano, Hinrich Hargarter, Jianxing Li, Jane Buehler
  • Publication number: 20010019779
    Abstract: Disclosed is a copper alloy sliding material having a metal structure wherein intermetallic compounds exist adjacently to Pb-phase islands and/or Bi-phase islands. Because intermetallic compounds exist between the matrix and the Pb phase and/or the Bi phase, the material can have improved anti-seizure property, since, under load or due to wear, the surface of the material has recessions at the soft Pb and/or Bi phase and the matrix with respect to the intermetallic compounds.
    Type: Application
    Filed: December 28, 2000
    Publication date: September 6, 2001
    Inventors: Kenji Sakai, Naohisa Kawakami, Satoru Kurimoto, Koichi Yamamoto, Takayuki Shibayama
  • Patent number: 6264764
    Abstract: Copper alloys for electrical applications, particularly in the computer industry, and a process for making the copper alloys. The copper alloys contain 13-15% by weight of zinc, 0.7-0.9% by weight of tin, and 0.7-0.9% by weight of iron, the balance being copper. The low tin and iron content and high zinc content provide high tensile and yield strengths, a high conductivity, and a low cost for the copper alloys.
    Type: Grant
    Filed: May 9, 2000
    Date of Patent: July 24, 2001
    Assignee: Outokumpu Oyj
    Inventors: Anders Claes Kamf, M. Parker Finney
  • Patent number: 6254701
    Abstract: A sliding bearing having improved seizure resistance has the following structure. (a) A bearing layer (2). It comprises a copper alloy containing in a Cu matrix Ag, Sn, Sb, In, Mn, Fe, Bi, Zn, Ni and/or Cr. (b) A fisrst sub-layer (3) of the bearing layer (2). It (3) contains concentrated element, hexagonal compound or eutectic of said element(s). (c) A second sub-layer (2a) in which said element in essential solid-solution state. (d) Metal backing (1).
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: July 3, 2001
    Assignee: Taiho Kogyo Co., Ltd.
    Inventors: Haruyuki Oshiro, Takashi Tomikawa, Soji Kamiya, Katuyuki Hashizume
  • Patent number: 6254702
    Abstract: A copper alloy for terminals of the Cu—Ni—Sn—P system or Cu—Ni—Sn—P—Zn system and that has a tensile strength of at least 500 N/mm2, a spring limit of at least 400 N/mm2, a stress relaxation of no more than 10%, a conductivity of at least 30% IACS and a bending workability in terms of a R/t ratio of no more than 2. The spring portion or the entire part of such terminals are produced from the copper alloy, and have an initial insertion/extraction force of 1.5 N to 30 N and a resistance of no more than 3 m&OHgr; at low voltage and low current as initial performance. The terminals experience not more than 20% stress relaxation.
    Type: Grant
    Filed: August 24, 1999
    Date of Patent: July 3, 2001
    Assignees: Dowa Mining Co., Ltd., Yazaki Corporation
    Inventors: Yoshitake Hana, Akira Sugawara, Takayoshi Endo
  • Patent number: 6251199
    Abstract: A copper alloy having improved resistance to cracking due to localized plastic deformation and the process of making it. The alloy consists essentially of: from 0.7 to 3.5 weight percent nickel; from 0.2 to 1 weight percent silicon; from 0.05 to 1 weight percent tin; from 0.26 to 1 weight percent iron; and the balance copper and unavoidable impurities. The copper alloy has a local ductility index of greater than 0.7 and a tensile elongation exceeding 5%. Cobalt may be substituted for iron, in whole or in part, on a 1:1 basis by weight. The alloy is precipitation hardenable and useful for electronic applications, including without limitation, connectors.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: June 26, 2001
    Assignee: Olin Corporation
    Inventors: Frank N. Mandigo, John F. Breedis
  • Patent number: 6241831
    Abstract: The present invention relates to copper-magnesium-phosphorous alloys. In a first embodiment, copper-magnesium-phosphorous alloys in accordance with the present invention consist essentially of magnesium in an amount from about 0.01 to about 0.25% by weight, phosphorous in an amount from about 0.01 to about 0.2% by weight, silver in an amount from about 0.001 to about 0.1% by weight, iron in an amount from about 0.01 to about 0.25% by weight, and the balance copper and inevitable impurities. Preferably, the magnesium to phosphorous ratio is greater than 1.0. In a second embodiment, copper-magnesium-phosphorous alloys in accordance with the present invention consist essentially of magnesium in an amount from about 0.01 to about 0.25% by weight, phosphorous in an amount from about 0.01 to about 0.2% by weight, optionally silver in an amount from about 0.001 to about 0.1% by weight, at least one element selected from the group consisting of nickel, cobalt, and mixtures thereof in an amount from about 0.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: June 5, 2001
    Assignee: Waterbury Rolling Mills, Inc.
    Inventor: Ashok K. Bhargava
  • Publication number: 20010001400
    Abstract: There is provided a tin brass alloy having a grain structure that is refined by the addition of controlled amounts of both zinc and iron.
    Type: Application
    Filed: June 30, 1997
    Publication date: May 24, 2001
    Applicant: Dennis R. Brauer et al
    Inventors: DENNIS R. BRAUER, JOHN F. BREEDIS, RONALD N. CARON, CARL DEPPISCH
  • Patent number: 6197433
    Abstract: A rolled copper foil for flexible printed circuits contains not more than 10 ppm by weight of oxygen and has a softening-temperature rise index T defined as T=0.60[Bi]+0.55[Pb]+0.60[Sb]+0.64 [Se]+1.36[S]+0.32[As]+0.09[Fe]+0.02[Ni]+0.76[Te]+0.48[Sn]+0.16[Ag]+1.24[P] (each symbol in the brackets representing the concentration in ppm by weight of the element) in the range of 4 to 34. The concentrations of the elements are in the ranges of[Bi]<5, [Pb]<10, [Sb]<5, [Se]<5, [S]<15, [As]<5, [Fe]<20, [Ni]<20, [Te]<5, [Sn]<20, [Ag]<50, and [P]<15 (each symbol in the brackets representing the concentration in ppm by weight of the element).
    Type: Grant
    Filed: January 12, 2000
    Date of Patent: March 6, 2001
    Assignee: Nippon Mining & Metals Co., Ltd.
    Inventor: Takaaki Hatano