Derived From Iso- Or Thio-cyanate; E.g., Polyurethane, Etc. Patents (Class 156/331.7)
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Patent number: 12139647Abstract: Provided is a composition comprising one or more epoxy phosphate esters wherein the structure comprises two or more polyester linkages. Also provided is a method of making the epoxy phosphate esters that comprises reacting one or more epoxy-terminated polyesters with one or more phosphoric acids. Further provided is an adhesive composition that comprises one or more epoxy phosphate esters, one or more multifunctional isocyanate prepolymers, and one or more multifunctional isocyanate-reactive compounds.Type: GrantFiled: April 23, 2021Date of Patent: November 12, 2024Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Tuoqi Li, Joseph J. Zupancic, Yinzhong Guo, Jie Wu
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Patent number: 12122183Abstract: The present invention relates to a method for producing a polyvinyl chloride-free top layer (1) for a decking element (3), the method comprising the method steps indicated below: A) Providing a base layer (4) comprising and/or consisting of plastic; B) Printing a décor (6) on a top (5) of the base layer (4) facing a usable side (7); C) Bonding, preferably laminating, a, preferably transparent, wearing surface (8) to the printed base layer (4) to form a, preferably solid, layer composite (9); D) Embossing the layer composite (9) at least in some areas, preferably over the entire surface, with a structure (10) at least substantially synchronous with the décor (6), the structure (10) being embossed in such a way that it is visible both on the top (11) facing the usable side (7) and at least in some areas on the bottom (12) of the layer composite (9) facing away from the usable side (7); E) Application of a surface sealing layer (17), preferably a lacquer layer, to the top (11) of the layer composite (9) facinType: GrantFiled: August 24, 2021Date of Patent: October 22, 2024Assignee: Parador GmbHInventors: Dirk Nowak, Christoph Wellekötter, Frank Petersen
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Patent number: 12064396Abstract: A container for blood or a blood component is provided, the container comprising one or more container walls defining an interior chamber, the container walls comprising one or more layers, the layers comprising or consisting of a composition comprising one or more polymeric materials and at least one extractable agent selected from the group consisting of a terephthalate ester, a cyclohexane dicarboxylic acid ester, a citrate ester, and a polyol ester, wherein the container further comprises one or more additional components, wherein the container comprises less than about 3% (w/w) of di-2-ethylhexyl phthalate (DEHP), preferably wherein the container comprises less than about 3% (w/w) of phthalates. Thereby, improved blood products are provided in which the DEHP or overall phthalate content is reduced.Type: GrantFiled: October 28, 2021Date of Patent: August 20, 2024Assignee: Fresenius Kabi Deutschland GmbHInventors: Karin Platenkamp, Craig L. Sandford, Koos L. Hakvoort
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Patent number: 12054652Abstract: The present disclosure provides a two-component solvent-less adhesive composition. The two-component solvent-less adhesive composition contains the reaction product of (A) an isocyanate component and (B) a polyol component containing a poly-ester-amide polycarbonate polyol. The present disclosure also provides a method of forming a two-component solvent-less adhesive composition.Type: GrantFiled: March 4, 2020Date of Patent: August 6, 2024Assignees: Dow Global Technologies LLC, Rohm and Haas CompanyInventors: Tuoqi Li, Joseph J. Zupancic, Matthew M. Yonkey, Paul G. Clark, Thorsten Schmidt, Ken Kawamoto, Wenwen Li
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Patent number: 12030297Abstract: Provided is a glass film-resin composite, which prevents the breakage of a glass film and enables the production of an elongated glass film. The glass film-resin composite of the present invention includes: an elongated glass film; a resin tape, which is arranged on at least one surface of the elongated glass film and is linearly arranged at least near each of both ends in a widthwise direction of the elongated glass film in one surface of the elongated glass film; a protective layer, which is arranged near each of both the ends in the widthwise direction of the surface of the elongated glass film having arranged thereon the resin tape and on an outside of the resin tape in the widthwise direction; and a resin layer arranged on one surface of the elongated glass film.Type: GrantFiled: April 17, 2019Date of Patent: July 9, 2024Assignee: NITTO DENKO CORPORATIONInventors: Keisuke Sato, Takeshi Murashige, Junichi Inagaki, Atsushi Kishi
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Patent number: 12018189Abstract: Provided are an outer package material that is for electricity storage devices such as batteries and has such a sufficient anti-electrolytic solution property that the time-dependent reduction of the adhesive strength between a metal foil layer and a sealant layer by an electrolytic solution is suppressed over a long time and a composition for adhesives for giving the outer package material. In an outer package material that is for electricity storage devices and has a structure in which at least a base material layer, a first adhesive layer, a metal foil layer, a second adhesive layer, and a sealant layer are stacked in sequence, a composition containing an isocyanato group and a (meth) acryloyl group and further containing an acid-modified polyolefin (component 1), an active energy ray polymerization initiator (component 3), and a solvent (component 4) is used as a composition for adhesives to form the second adhesive layer.Type: GrantFiled: March 16, 2020Date of Patent: June 25, 2024Assignee: Resonac CorporationInventors: Kazuhiko Oga, Takeshi Kawamoto, Kai Suzuki, Ryunosuke Yamamoto
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Patent number: 11981785Abstract: A water-barrier laminated film (10) including a plastic film (A) that has an inorganic barrier layer (A1) on the surface thereof and a water-trapping layer (B), characterized in that: between the plastic film (A) and the water-trapping layer (B), an isocyanate type coating (C) is provided that contains, as a film-forming component, an isocyanate type polymer obtained by reacting an isocyanate as the reaction component; and the water-trapping layer (B) is formed on the isocyanate type coating (C) that is formed as the underlying layer.Type: GrantFiled: November 7, 2018Date of Patent: May 14, 2024Assignee: TOYO SEIKAN GROUP HOLDINGS, LTD.Inventors: Shinpei Okuyama, Keisuke Takayama, Shunya Nangou, Misato Yagisawa, Yoshihiro Ohta
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Patent number: 11965067Abstract: The present disclosure provides a process. The process includes (A) providing at least 6 film layers, each film layer being a pearlized biaxially oriented polypropylene; (B) applying a solvent-less adhesive at a coat weight of 2.0 g/m2 to 3.5 g/m2 between each film layer; and (C) forming a laminate, the laminate having a thickness of at least 300 ?m. The solvent-less adhesive contains (i) a polyol component including at least one polyol selected from a polyester polyol, a polyether polyol, and combinations thereof; and (ii) an isocyanate component including an isocyanate prepolymer that is the reaction product of at least one isocyanate monomer and at least one polyol selected from a polyester polyol, a polyether polyol, and combinations thereof. The present disclosure also provides a laminate formed by said process.Type: GrantFiled: September 20, 2019Date of Patent: April 23, 2024Assignee: Dow Global Technologies LLCInventor: Abraham Barretto
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Patent number: 11952515Abstract: The disclosed adhesive compositions comprise (A) an isocyanate component comprising (i) an isocyanate and (ii) an isocyanate-terminated silane compound. In some embodiments, the isocyanate-terminated silane compound (ii) is the reaction product of a polyisocyanate and an isocyanate-reactive compound comprising a silane group and at least one isocyanate-reactive group selected from the group consisting of —OH, —SH, and —NHR, where R stands for an alkyl remainder having from 1 to 12 C atoms or a cycloaliphatic or aromatic remainder having between 6 and 12 C atoms. In other embodiments, the isocyanate-terminated silane compound (ii) is the reaction product of a polyisocyanate selected from the group consisting of isophorone diisocyanate, m-xylylene diisocyanate, mixtures thereof, dimers thereof, trimers thereof, prepolymers thereof, and combinations thereof and an isocyanate-reactive compound comprising a silane group and at least one isocyanate-reactive group of —NH2.Type: GrantFiled: February 25, 2019Date of Patent: April 9, 2024Assignee: Dow Global Technologies LLCInventors: Rui Xie, Jie Wu, Kalyan Sehanobish
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Patent number: 11858242Abstract: Recyclable, all-polyethylene laminate film structures suitable for use in a flexible packaging are disclosed. The structures comprise a film layer consisting essentially of an ethylene-based polymer and a barrier adhesive layer disposed on a surface of the film layer, wherein the structure has an oxygen transmission rate not greater than 100 O2/m2/day, measured according to ASTM Method D3985. Recyclable, all-polyethylene laminate film structures suitable for use in a flexible packaging are disclosed comprising (A) a sealant film layer consisting essentially of an ethylene-based polymer, (B) an intermediate film layer consisting essentially of an ethylene-based polymer, (C) a structural film layer consisting essentially of an ethylene-based polymer, and (D) a barrier adhesive layer, wherein the recyclable, all-polyethylene laminate film structure has an oxygen transmission rate not greater than 100 O2/m2/day, measured according to ASTM Method D3985.Type: GrantFiled: June 29, 2022Date of Patent: January 2, 2024Assignee: Dow Global Technologies LLCInventors: Kalyan Sehanobish, Amira A. Marine, Daniele Vinci
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Patent number: 11787911Abstract: A method of activating a surface of a plastics substrate formed from: (a) polyaryletherketone such as polyether ether ketone (PEEK) polyether ketone ketone (PEKK), polyether ketone (PEK); polyether ether ketone ketone (PEEKK); or polyether ketone ether ketone ketone (PEKEKK); (b) a polymer containing a phenyl group directly attached to a carbonyl group, for example polybutadiene terephthalate (PBT) optionally wherein the carbonyl group is part of an amide group, such as polyarylamide (PARA); (c) polyphenylene sulfide (PPS); or (d) polyetherimide (PEI); for subsequent bonding, the method comprising the step of exposing the surface to actinic radiation wherein the actinic radiation: includes radiation with wavelength in the range from about 10 nm to about 1000 nm; the energy of the actinic radiation to which the surface is exposed is in the range from about 0.5 J/cm2 to about 300 J/cm2.Type: GrantFiled: February 25, 2021Date of Patent: October 17, 2023Assignee: Henkel AG & Co. KGaAInventor: Brian Deegan
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Patent number: 11764394Abstract: A battery cell includes an electrode assembly; a case comprising an accommodation portion accommodating the electrode assembly and a sealing portion formed on a periphery of the accommodation portion; and a fixing member disposed between the accommodation portion and the sealing portion to adhere each other; wherein the fixing member comprises a core layer, and an adhesive layer is stacked on both surfaces of the core layer.Type: GrantFiled: March 25, 2019Date of Patent: September 19, 2023Assignee: SK ON CO., LTD.Inventors: Jin-Go Kim, Dong-Ju Kim, Seung-Noh Lee
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Patent number: 11753526Abstract: The invention relates to a synergistically active composition which comprises a mixture of a sulfinic acid or a salt thereof and ascorbic acid or a salt thereof and the use of the composition as reducing agent. The reducing power of the composition of the invention is significantly higher than the reducing power of the single components.Type: GrantFiled: March 5, 2018Date of Patent: September 12, 2023Assignee: L. BRÜGGEMANN GMBH & CO. KGInventors: Josef Berghofer, Stefan Mark, Stefanie Enderle
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Patent number: 11717053Abstract: Debondable adhesive compositions are provided. This disclosure also provides articles of footwear and components for articles of footwear including a debondable adhesive matrix. The debondable adhesive matrix can allow for the bonding and debonding of two substrates in the article of footwear or component thereof. This disclosure also provides methods of making the debondable adhesive compositions and methods of using said compositions for bonding and debonding the substrates, e.g. for bonding and debonding of an upper and an outsole in an article of footwear.Type: GrantFiled: October 14, 2020Date of Patent: August 8, 2023Assignee: NIKE, INC.Inventors: Eduardo Alberto Gonzalez de los Santo, Kethinni Chittibabu, Debora Marcela Martino, Sofia Trakhtenberg, John C. Warner
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Patent number: 11661487Abstract: A method of activating a surface of a plastics substrate formed from: (a) polyaryletherketone such as polyether ether ketone (PEEK) polyether ketone ketone (PEKK), polyether ketone (PEK); polyether ether ketone ketone (PEEKK); or polyether ketone ether ketone ketone (PEKEKK); (b) a polymer containing a phenyl group directly attached to a carbonyl group, optionally wherein the carbonyl group is part of an amide group, such as polyarylamide (PARA); (c) polyphenylene sulfide (PPS); or (d) polyetherimide (PEI); for subsequent bonding, the method comprising the step of exposing the surface to actinic radiation wherein the actinic radiation: includes radiation with wavelength in the range from about 10 nm to about 1000 nm; the energy of the actinic radiation to which the surface is exposed is in the range from about 0.5 J/cm2 to about 300 J/cm2. Hard to bond substrates are then more easily subsequently bonded for example using acrylic, epoxy or anaerobic adhesive.Type: GrantFiled: December 13, 2019Date of Patent: May 30, 2023Assignee: Henkel AG & Co. KGaAInventor: Brian Deegan
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Patent number: 11643577Abstract: To provide an adhesive suitable to bond a component of an electronic apparatus or an optical apparatus, as well as an electronic apparatus and an optical apparatus in which the adhesive is used. An adhesive according to an embodiment of the present technology includes a flexible adhesive material and a plurality of particles. The adhesive material is flexible. The plurality of particles is dispersed in the adhesive material, the plurality of particles being deformed under a low-rate load and not being deformed under a high-rate load.Type: GrantFiled: July 20, 2018Date of Patent: May 9, 2023Assignee: SONY CORPORATIONInventors: Masahiko Mitsuboshi, Motohisa Inadu
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Patent number: 11530344Abstract: The present invention relates to a reactive hot melt adhesive composition, a polyurethane prepolymer composition, and cured reaction product thereof having a high mechanical strength and an excellent bonding strength as well as a better reworkability. In particular, the present invention relates to a reactive hot melt adhesive composition comprising: 10% to 24% by weight of a polyisocyanate, 40% to 73% by weight of a first polyol having a number average molecular weight larger than 1,500 g/mol, 1% to 25% by weight of a (meth)acrylate polymer having a number average molecular weight of 20,000 to 80,000 g/mol, and 1% to 15% by weight of a diluent, in which the weight percentages are based on the total weight of all components of the composition.Type: GrantFiled: May 7, 2019Date of Patent: December 20, 2022Assignee: Henkel AG & Co. KGaAInventors: Dan Xie, Dongmei Shen, Xiao Han, Claudia Meckel-Jonas, Xueyu Qiu
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Patent number: 11530343Abstract: A binder has at least one isocyanate and at least one biopolymer mixed with water. The biopolymer may be a biopolymer nanoparticle or cooked and chemically modified starch. Optionally, the binder may also include urea. The biopolymer and water are mixed, and the isocyanate is added to the mixture. The binder may have a viscosity that is suitable for being sprayed on a substrate to make a composite material, for example a viscosity of 700 cP or less or 500 cP or less at 40° C. The substrate may be wood, another lignocellulosic material, or synthetic or natural fibers. In particular examples, the binder is used to make no added formaldehyde wood composites including particle board and fiberboard. Alternatively, the binder may have a higher viscosity and be used to make plywood.Type: GrantFiled: November 23, 2020Date of Patent: December 20, 2022Assignee: ECOSYNTHETIX INC.Inventors: Somaieh Salehpour, J. Douglas Ireland, Niels M. B. Smeets, Steven Bloembergen, Michael Kuska
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Patent number: 11359045Abstract: The invention relates to a continuous method for producing an isocyanurate-containing isocyanate mixture, in which in a step a) a mixture of a first and a second isocyanate component and an isocyanate group trimerization catalyst is provided; in a step b) the mixture obtained in step a) is reacted in a first residence time zone at an elevated temperature; in a step c), the reaction mixture obtained in step b) is further heated in a second residence time zone, optionally after adding a stopper; and in a step d), the reaction mixture obtained in step c) is cooled down in a third residence time zone by way of lowering the temperature, thus obtaining the desired isocyanurate-containing isocyanate mixture.Type: GrantFiled: December 14, 2018Date of Patent: June 14, 2022Assignee: Covestro Deutschland AGInventors: Christian Hahn, Hans-Detlef Arntz, Stephan Schubert, Ernst Felske, Claudia Houben, Frank Behrendt
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Patent number: 10662355Abstract: The present invention is an adhesive composition that is characterized by including (A) a polymer comprising a structural unit having a hydroxy group in a side chain, (B) a compound having two or more isocyanate groups, (C) a bismuth carboxylate, and (D) a tertiary amine having a pKa of 6 or more. The polymer (A) may include further a structural unit having a urethane bond and a polymerizable unsaturated bond in a side chain.Type: GrantFiled: July 12, 2016Date of Patent: May 26, 2020Assignee: MITSUI CHEMICALS TOHCELLO, INC.Inventors: Manami Saito, Hiroyoshi Kurihara
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Patent number: 10640616Abstract: An improved process for forming polyamide dispersions in water utilizing carbon dioxide to facilitate dispersion of the polyamide is disclosed. The polyamides are generally below 30,000 or 40,000 g/mole molecular weight when dispersed, but can be chain extended with polyfunctional species such as polyisocyanates after dispersion. The dispersions are useful in coatings, adhesives, and inks. Composites and hybrids of these other polyamides with vinyl polymers are also disclosed and claimed.Type: GrantFiled: November 13, 2015Date of Patent: May 5, 2020Assignee: LUBRIZOL ADVANCED MATERIALS, INC.Inventors: Gabor Erdodi, John Ta-Yuan Lai, Naser Pourahmady
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Patent number: 10611873Abstract: A crosslinkable composition is provided including an asymmetric isocyanate, a polyether polyol, and a crosslinker. Polyurethane pressure-sensitive adhesives, articles, and solutions are also provided. The polyurethane pressure-sensitive adhesives have advantageous adhesive properties, low glass transition temperatures, and cohesion following thermal cycling.Type: GrantFiled: December 4, 2015Date of Patent: April 7, 2020Assignee: 3M Innovative Properties CompanyInventors: Yongshang Lu, Charlie Chia-Tie Ho
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Patent number: 10597532Abstract: Polyester polyols are generally disclosed, including methods of making and using them. In some embodiments, the polyester polyols are incorporated into a block copolymer, such as a polyurethane block copolymer. In some embodiments, the polyurethane block copolymers can be used as compatibilizing agents, which can be used, for example, in polymer blends, polymer alloys, solutions, emulsions, as well as in extruded and injection molded articles. In some embodiments, at least a portion of the polyurethane block copolymer is derived from a renewable source.Type: GrantFiled: June 26, 2018Date of Patent: March 24, 2020Assignee: Elevance Renewable Sciences, Inc.Inventors: Allyson Beuhler, Debra Tindall, Kamlesh Mody, Donald A. Meltzer
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Patent number: 10265932Abstract: Multi-layer protective sheets of the invention are extensible. They are useful in a range of indoor and outdoor applications in, for example, the transportation, architectural and sporting goods industries. The protective sheets can advantageously be applied to at least a portion of a surface of any article where protection is desired. Methods of the invention include those for forming protective sheets of the invention and applying them to articles.Type: GrantFiled: October 23, 2006Date of Patent: April 23, 2019Assignee: entrotech, inc.Inventor: James E. McGuire, Jr.
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Patent number: 10046363Abstract: Screening members, screening assemblies, methods for fabricating screening members and assemblies and methods for screening materials are provided for vibratory screening machines that incorporate the use of injection molded materials. Use of injection molded screen elements provide, inter alia, for: varying screening surface configurations; fast and relatively simple screen assembly fabrication; and a combination of outstanding screen assembly mechanical and electrical properties, including toughness, wear and chemical resistance. Embodiments of the present invention use a thermoplastic injection molded material.Type: GrantFiled: March 13, 2013Date of Patent: August 14, 2018Assignee: Derrick CorporationInventor: Keith F. Wojciechowski
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Patent number: 10030142Abstract: Polyester polyols are generally disclosed, including methods of making and using them. In some embodiments, the polyester polyols are incorporated into a block copolymer, such as a polyurethane block copolymer. In some embodiments, the polyurethane block copolymers can be used as compatibilizing agents, which can be used, for example, in polymer blends, polymer alloys, solutions, emulsions, as well as in extruded and injection molded articles. In some embodiments, at least a portion of the polyurethane block copolymer is derived from a renewable source.Type: GrantFiled: June 23, 2016Date of Patent: July 24, 2018Assignee: Elevance Renewable Sciences, Inc.Inventors: Allyson Beuhler, Debra Tindall, Kamlesh Mody, Donald A. Meltzer
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Patent number: 9879154Abstract: A one-part moisture-curing liquid-applied waterproofing membrane is disclosed as including a polyurethane polymer and two different aldimines as blocked amine hardeners in a specific ratio range. The membrane has a low odor, a long shelf life stability, a low viscosity at low solvent content, a sufficiently long open time to allow hand application and cures fast to a solid elastic material. The liquid-applied waterproofing membrane is particularly suitable for roofing applications, possessing high strength, high elongation and good durability under outdoor weathering conditions in a broad temperature range.Type: GrantFiled: January 21, 2014Date of Patent: January 30, 2018Assignee: SIKA TECHNOLOGY AGInventors: Michael Byrne, Mark Gatrell, Alexander Coward, Urs Burckhardt
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Patent number: 9657173Abstract: A curable resin composition which can achieve a cured product in which the generation of cracks upon curing is suppressed and which has both a low thermal expansion rate and a low water absorbability is provided. The curable resin composition comprises: at least a cyanate ester compound (A) represented by the following formula (I); a metal complex catalyst (B); and an additive (C), wherein the additive (C) contains any one or more selected from the group consisting of a compound represented by the following general formula (II), a compound represented by the following general formula (III), and a tertiary amine.Type: GrantFiled: January 31, 2012Date of Patent: May 23, 2017Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Makoto Tsubuku, Taketo Ikeno, Masayuki Katagiri, Tomoo Tsujimoto
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Patent number: 9403937Abstract: Polyester polyols are generally disclosed, including methods of making and using them. In some embodiments, the polyester polyols are incorporated into a block copolymer, such as a polyurethane block copolymer. In some embodiments, the polyurethane block copolymers can be used as compatibilizing agents, which can be used, for example, in polymer blends, polymer alloys, solutions, emulsions, as well as in extruded and injection molded articles. In some embodiments, at least a portion of the polyurethane block copolymer is derived from a renewable source.Type: GrantFiled: October 7, 2014Date of Patent: August 2, 2016Assignee: Elevance Renewable Sciences, Inc.Inventors: Allyson Beuhler, Debra Tindall, Kamlesh Mody, Donald A. Meltzer
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Patent number: 9382371Abstract: The invention relates to a process for the production of a foam composite element, comprising the steps of providing a facing, applying adhesion promoter, and applying a foam layer comprising polyurethane and/or polyisocyanurate to the adhesion promoter, characterized in that the adhesion promoter consists of at least one compound selected from the group consisting of polyether polyol (B.1), polymer polyol (B.2), polyurea dispersion (B.3), polyester polyol (B.4) and PIPA polyol (B.5). The invention relates further to the use of at least one compound selected from the group consisting of polyether polyol, polymer polyol and polyurea dispersion as adhesion promoter in the production of foam composite elements, as well as to foam composite elements produced by the process according to the invention.Type: GrantFiled: July 23, 2010Date of Patent: July 5, 2016Assignee: Covestro Deutschland AGInventors: Johannes Van De Braak, Rolf Roers, Peter Haas
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Patent number: 9102827Abstract: A transparent thermoplastic resin composition includes (A) a methylmethacrylate-styrene-acrylonitrile-butadiene copolymer (g-MABS) which is a graft resin having a core-shell structure and including butadiene with an average particle size of about 700 to about 1800 ?; (B) a methylmethacrylate-styrene-acrylonitrile-butadiene copolymer (g-MABS) which is a graft resin having a core-shell structure and including butadiene with an average particle size of about 2000 to about 4000 ?; (C) dimethyl polysiloxane; and (D) a base resin which includes (meth)acrylic acid alkyl ester in an amount of about 40 to about 100% by weight.Type: GrantFiled: April 19, 2013Date of Patent: August 11, 2015Assignee: Cheil Industries Inc.Inventors: Dong Hui Chu, Doo Han Ha, In Chol Kim
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Publication number: 20150143672Abstract: A water-proof fastener tape of an environment-conscious type fabricated using a reduced amount of an organic solvent is provided. The fastener tape includes a base fabric and a water-stop film laminated to at least one surface of the base fabric, the water-stop film includes a surface layer of a polyurethane film and an adhesive layer of a cured product of an aqueous polyurethane adhesive adjacent to the surface layer so that the fastener tape has a laminate structure.Type: ApplicationFiled: July 9, 2012Publication date: May 28, 2015Applicant: YKK CorporationInventors: Toshimasa Konaka, Shinyo Yokoyama, Jun Hamada
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Publication number: 20150136323Abstract: The invention provides anaerobic curable compositions comprising a (meth)acrylate component, at least a portion which comprises a (meth)acrylate-functionalized bio-renewable oleaginous polyurethane polymer, and methods of their production and use. These compositions provide excellent adhesion especially on oily surfaces.Type: ApplicationFiled: January 26, 2015Publication date: May 21, 2015Inventors: Andrew D. Messana, David P. Dworak, Angelica Messana, Anthony F. Jacobine, Darel Gustafson
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Patent number: 9032692Abstract: Embodiments of the invention include insulated units and methods of producing the insulating units. The insulating units include a first surface, a structural seal disposed on at least portions of the first surface, and a second surface disposed on the structural seal. The structural seal includes the reaction product of at least one first isocyanate, at least one isocyanate reactive side, and at least one adhesion promoter including a reaction product of at least one secondary aminoalkoxy silane and at least one second isocyanate.Type: GrantFiled: November 10, 2011Date of Patent: May 19, 2015Assignee: Dow Global Technologies LLCInventors: Bindushree Radhakrishnan, Laura A. Grier, Syed Z. Mahdi
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Patent number: 9034140Abstract: An adhesive sheet having high adhesion and removability, low metal corrosion, small outgas generation, and particularly suitable for adherence to an electronic part, which sheet includes an adhesive layer provided for at least one surface of a substrate sheet, in which a pressure-sensitive adhesive forming the adhesive layer includes a resin composition mainly formed of an acrylic copolymer obtained by blending a carboxyl group-free acrylic copolymer obtained by copolymerizing the following components (A) to (C) with (D) an isocyanate-based cross-linking agent: (A) 76.999 to 94.999% by mass of an alkyl(meth)acrylate; (B) 5.0 to 23.0% by mass of an ethylenically unsaturated group-containing morpholine-based compound; and (C) 0.001 to 1.5% by mass of a functional group-containing unsaturated monomer; and a ratio M2/M1 of the mole number (M2) of isocyanate groups in the component (D) to the mole number (M1) of functional groups in the component (C) is 1.5 to 15.0.Type: GrantFiled: September 23, 2013Date of Patent: May 19, 2015Assignee: LINTEC CORPORATIONInventors: Takuo Nishida, Akihito Yamada
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Patent number: 9011630Abstract: The present invention relates to curable compositions comprising at least one specific blocked amine, at least one surface-deactivated polyisocyanate that is solid at ambient temperature and optionally water or a water-producing substance. Compositions of this type are characterized by an extremely high storage stability as long as they are not heated. Hot curing compositions that cure with the action of heat can thus be produced. Heat-activated compositions can also be produced. When heat is applied the latter compositions are not cured but are activated so that they are able to cure under the influence of moisture. The curable compositions are particularly suitable for use as adhesives.Type: GrantFiled: March 31, 2010Date of Patent: April 21, 2015Assignee: Sika Technologies AGInventors: Urs Burckhardt, Peter Gimmnich
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Patent number: 9005762Abstract: The use of aqueous polyurethane dispersions is described for composite foil lamination, where at least 10% by weight of the polyurethane derives from at least one amorphous polyester polyol.Type: GrantFiled: December 5, 2012Date of Patent: April 14, 2015Assignee: BASF SEInventors: Axel Meyer, Karl-Heinz Schumacher, Christoph Kiener
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Publication number: 20150083327Abstract: Adhesive for adhering synthetic and/or metal substrates, selected from liquid or thermoplastic adhesives which have urethane groups in the polymer chain, wherein the adhesive is selected from NCO-reactive adhesives, silane-reactive adhesives or thermoplastic polyurethanes (TPU) and include as a constituent 0.01 to 10 wt. % of at least one compound (H) having a molecular weight of less than 500 g/mol, which compound has at least one sulphonamide group having an SO2—NH—C(O) structure or at least one amidosulphonate group.Type: ApplicationFiled: December 1, 2014Publication date: March 26, 2015Inventors: Dennis Bankmann, Nina Jungholt, Stefan Tomke
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Publication number: 20150083326Abstract: The present invention encompasses polyurethane adhesive compositions comprising aliphatic polycarbonate chains. In one aspect, the present invention encompasses polyurethane adhesives derived from aliphatic polycarbonate polyols and polyisocyanates wherein the polyol chains contain a primary repeating unit having a structure. In another aspect, the invention provides articles comprising the inventive polyurethane compositions as well as methods of making such compositions.Type: ApplicationFiled: April 16, 2013Publication date: March 26, 2015Inventors: Scott D. Allen, Vahid Sendijarevic, James O'Connor
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Patent number: 8987375Abstract: A moisture-curable polyurethane formulation is provided capable of curing to form a reaction product, having high green strength and being dispensable from a caulking gun. The polyurethane formulation comprises at least one isocyanate-terminated prepolymer, at least one rheology modifier or filler, optionally monomeric/polymeric isocyanate, and at least one urea-based thixotropic additive added to the formulation or formed in situ, to provide greater than 1% of urea groups in the reaction product. A method for making a moisture-curable polyurethane formulation capable of curing to form a reaction product and methods of bonding materials together using the formulation are also provided.Type: GrantFiled: August 27, 2010Date of Patent: March 24, 2015Assignee: Construction Research & Technology GmbHInventors: Paula Bushendorf, John M. Davis, Michael Porsch
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Publication number: 20150068661Abstract: The invention is an adhesive composition comprising a silyl terminated prepolymer having a number molecular weight average (Mn) of about 8,000 to about 80,000 g/mole, a filler, and a silanol condensation reaction catalyst. The silyl terminated prepolymer is comprised of a polymeric backbone of alkylene oxide and at least three urethane groups and at least two terminal groups comprised of a silicon atom having at least two alkoxy silane groups, wherein each silicon atom in the terminal groups is separated from the urethane groups in the polymeric backbone by an amount of alkylene oxide that has a molecular weight of 200 to 15,000 g/mole.Type: ApplicationFiled: August 25, 2014Publication date: March 12, 2015Inventors: Syed Z. Mahdi, Susan P. Sevidal
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Patent number: 8974906Abstract: The present invention is to provide a weather-resistant adhesive which achieves adhesive property, moist heat resistance and weather resistance in a practical level by means of aging at low temperature and for short time. There is provided a weather-resistant adhesive composition, characterized in containing (A) a polyester polyol having an acid value of 30 to 150 equivalents/106 g and (B) a polyisocyanate compound comprising an aliphatic polyisocyanate compound and/or an alicyclic polyisocyanate compound. Also, there is provided a layered product, characterized in being prepared by laminating films using said composition.Type: GrantFiled: March 26, 2012Date of Patent: March 10, 2015Assignee: Toyobo Co., Ltd.Inventors: Yuko Nakamura, Kenichi Eguchi
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Publication number: 20150060348Abstract: Provided are a hollow-fiber membrane unit in which the membranes are prevented from decreasing in permeation rate and the membrane area per unit volume has been rendered suitable and which can hence treat water in an increased rate and a hollow-fiber membrane module which is for use in such hollow-fiber membrane unit. The hollow-fiber membrane module comprises either a hollow-fiber membrane sheet composed of hollow-fiber membranes disposed in a sheet arrangement or a stack of such sheets and a box-shaped water collection member which holds the hollow-fiber membrane sheet or stack, wherein one surface of the water collection member has an opening that is filled with a fixing resin (potting resin) and is for fixing the hollow-fiber membrane sheet stack.Type: ApplicationFiled: April 2, 2013Publication date: March 5, 2015Applicant: Mitsubishi Rayon Co., Ltd.Inventors: Makoto Ideguchi, Manabu Sasakawa, Yoshihito Nakahara, Nobuyasu Ueno, Toshinori Tanaka, Kazumi Akagawa, Masato Takeuchi, Zhuoyi Zou
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Publication number: 20150052838Abstract: Magnesium oxide cement sheathing is laminated to plywood, OSB, wood, steel, other building products or other substrates to enhance fire, structural and sound performance of the substrate to meet new and more stringent fire codes while also providing water, insect, mold and rot protection. Further, the magnesium oxide cement board laminated to a foam core enhances fire performance and mold and rot protection over that of the foam core alone. The magnesium oxide laminate is used in wall, floor and roof assemblies to meet or exceed performance as specified in the building codes.Type: ApplicationFiled: August 21, 2013Publication date: February 26, 2015Applicant: MagBoard, LLCInventors: Gordon D. Ritchie, Humberto F. Hassey
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Patent number: 8962784Abstract: A novel macromer or mixture thereof is described herein, comprising isocyanatophenyl ether terminal moieties and at least two residues of a water-soluble polymer having a molecular weight ranging from 80 to 10,000 adjacent to the ether group of the isocyanatophenyl ether terminal isocyanate moieties, thereby forming at least two ether linkages in the macromer or mixture thereof. A method for making a polyisocyanate macromer is also described herein.Type: GrantFiled: December 19, 2008Date of Patent: February 24, 2015Assignee: Ethicon, Inc.Inventors: Chetan Anirudh Khatri, Benjamin D. Fitz, Joseph Zavatsky
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Patent number: 8956497Abstract: A method for producing biodisintegratable composite foils with an aqueous polyurethane dispersion adhesive. The method involves adhesive-bonding a first substrate to a second substrate with use of the aqueous polyurethane dispersion adhesive. At least one of the first substrate and the second substrate is made of a biodisintegratable polymer foil, and at least 60% by weight of the polyurethane contains diisocyanates, polyesterdiols, and bifunctional carboxylic acids. The bifunctional carboxylic acids are dihydroxycarboxylic acids or diaminocarboxylic acids.Type: GrantFiled: July 27, 2011Date of Patent: February 17, 2015Assignee: BASF SEInventors: Cornelis Petrus Beyers, Heiko Diehl, Stefan Dahmen, Volker Kriegisch, Ulrike Licht, Axel Meyer, Motonori Yamamoto
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Patent number: 8951642Abstract: An aqueous two-component aqueous dispersion adhesives, including in particular polyether-polyurethane polymers and ethylene vinyl acetate copolymers (EVA) having a glass transition temperature of greater than 0° C. The dispersion adhesives are optimally suited for use as contact adhesives, and for gluing plastic membranes. It has been demonstrated that the adhesives or the adhesive composite items produced therewith are characterized by an exceptionally low plasticizer absorption behavior, and contact adhesion. The good heat resistance and good bonding to various bases are also advantageous.Type: GrantFiled: October 12, 2010Date of Patent: February 10, 2015Assignee: Sika Technology AGInventors: Martin Demmig, Andre Buchholz, Christina Bosse, Tino Bendkowski
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Patent number: 8933188Abstract: The tendency of a two component laminating adhesive based on polyurethane chemistry to form a mist of fine droplets when applied at a high line speed may be reduced by including both a high functionality polyol and a lower functionality polymeric polyol in Component B which is combined and reacted with an isocyanate-functionalized polyurethane prepolymer in Component A.Type: GrantFiled: November 12, 2004Date of Patent: January 13, 2015Assignee: Henkel US IP LLCInventors: J. Brandon Simons, Grant B. Kenion
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Patent number: 8932721Abstract: The present invention relates to laminates of a plasticizer-containing plastic, obtained by bonding by means of a moisture-reactive hot-melt adhesive which comprises at least one aldimine and at least one polyurethane polymer which contains isocyanate groups and is solid at room temperature. The bonded assembly is notable for improved adhesive, particularly following heat/moisture storage or alternating storage. Preferred embodiments of such laminates are bonded films or film-laminated supports, the film preferably being a pPVC film.Type: GrantFiled: December 9, 2011Date of Patent: January 13, 2015Assignee: Sika Technology AGInventors: Kai Paschkowski, Doreen Janke, Urs Burckhardt, Mario Slongo
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Patent number: 8906192Abstract: Preparing a polyurethane with polyurethane-polyether and polyurethane-polyester blocks with at least 2 polyurethane-polyester end blocks joined to an alkoxysilane end group, by reaction of a polyether polyol (A) with a stoichiometric excess of an aliphatic diisocyanate (B), then reaction of the polyurethane formed with a stoichiometric excess of a polyester polyol, then reaction of the polyurethane formed with a stoichiometric amount of an isocyanatosilane (D); polyurethane formed by said method; corresponding adhesive composition, further comprising a crosslinking catalyst method of assembly of 2 substrates employing the composition.Type: GrantFiled: December 21, 2011Date of Patent: December 9, 2014Assignee: Bostik S.A.Inventors: Olivier Laferte, Stephane Fouquay, Regis Guillotte