Abstract: The present invention is directed to a method of manufacturing of sintered bonded adhesive plates. The present invention comprises the steps of clearing the metal cores, applying thermosetting adhesives, such as phenolic or epoxy adhesives, to the core layer, then applying sintered layers on top of the adhesive layers and bonding said layers at a temperature in the range of 375-475 F, pressure in the range of 25-1000 psi and bonding such structure for at least 30 seconds. The metal core may be fabricated from metals whose melting point is at least 450 F, such as aluminum. The present invention presents a relatively inexpensive way of manufacturing sintered bonded adhesive plates.

Abstract: A laminating and coating system is employed with a gravure or flexographic set up using an enclosed doctor blade system with recirculation to coat adhesive onto a film and then laminate it to another film. The preferred adhesive is a two-stage epoxy consisting of a zero VOC 100% solids laminating adhesive having a mixed viscosity of 200-400 cps with the viscosity remaining within a desired range of 50-110 degrees F for up to 3 hours that will cure at ambient temperature. The adhesive is solventless and is unaffected by moisture. The adhesive consists of ingredients which make it permissible for use as an adhesive for laminations of films designed for food packaging pursuant to F.D.A. Regulation 175.105.

Abstract: A finished product from lignocellulose, such as a length of wood or chipboard, is impregnated with a composition containing a thermosetting resin in a nonaqueous solvent, and a styrene polymer in a nonaqueous solvent. Excess impregnating composition is removed from the impregrnated material. The solvent or solvents are also removed. The thermosetting resin may thereafter be subjected to temperature conditions for polymerization to form a finished product.

Abstract: A process is provided for producing fast curing bonded with phenolic resin, which comprises pulverulent phenolic resins mixed with or applied to the substrate to be adhered together with pulverulent addition polymers selected from the group consisting of polyvinyl alcohols and addition polymers, stabilized by hydroxyl-containing protective colloids of at least one monomer selected from the group consisting of the vinyl esters of branched or unbranched carboxylic acids of 1 to 12 carbon atoms, the esters of acrylic acid and methacrylic acid with branched or unbranched alcohols of 1 to 12 carbon atoms, vinylaromatics, vinyl halides, olefins and dienes, and subsequently, by the employment of elevated temperature and optionally elevated pressure, cured and processed into a shaped article.

Abstract: The disclosed invention is a dimensionally stable laminate prepared by layering resin saturable sheets, treating the layered sheets with a polymeric resin, pressing the treated layered sheets together under high pressure and high temperature to form a laminate and then subjecting the newly manufactured laminate to high humidity (greater than 65%) at relatively low temperatures (32°-45° C.) before exposure to ambient conditions.

Abstract: A method for making a consolidated wood product comprising coating wood components with a B-stageable, phenol-formaldehyde resole resin; heating the coated wood components to about 80 to 140° C. for a time sufficient to advance the resin to a B-stage; forming a mat or stack of the wood components coated with the B-stage resin; exposing the mat or stack of coated wood components to a saturated or superheated steam atmosphere in a hot press; and compressing the layup to form the consolidated wood product. The phenol-formaldehyde resole resin used in the method has a number average molecular weight of between about 200 and 600, has a F:P mole ratio of about 1.3:1 to 2.0:1, and has been modified with 0 to about 5.5 wt % of caustic based on resin solids.

Abstract: The invention relates to a method of gluing veneers to form LVL and plywood boards from veneers laid one over the other in several layers by curing the adhesive placed between the single layers in a heated press. The invention consists in the fact that the gluing and pressing of the outer layers of a veneer pack to form LVL and plywood boards is performed by high-temperature adhesive and the inner layers by low-temperature adhesive, so that the amount of heat to be put into the veneer pack decreases from the outside in.

Abstract: A flame retardant article produced by forming a thermoplastic material around at least a portion of a core of partially cured phenolic resin is disclosed. The article has reduced flammability and improved dimensional stability when exposed to flame compared to an article consisting solely of the thermoplastic material. By positioning the thermoplastic between the core and at least all surfaces of the article which may become directly exposed to fire or heat when the article is in use, it is possible to impart the flexibility, colorability and impact resistance characteristics of thermoplastic materials to the article. At the same time, the inner core of the phenolic resin reduces the flammability and improves the dimensional stability of the article when the article is exposed to flame.

Abstract: There is provided a method for producing lignocellulosic composites. This method is useful in reducing the thickness swell of these composites on their exposure to water. This method also is useful in reducing the hot-press times required to make lignocellulosic composites. Furthermore, there is provided a method by which wax sizing may be used without the previously expected reduction in physical properties. Also, there is provided a method by which caul plate sticking may be reduced when hydrogen peroxide is used as a furnish add-on.

Abstract: Discloses compositions of urea dissolved in aqueous, polymerizable phenolic resole resins, wood-product laminated composite products produced with such resins, with or without the urea, and methods for the production of wood-product laminated composites with such resins. The resins contain the alkaline polymerization product of (a) formaldehyde polymerized with phenol and aliphatic hydrocarbylphenol or (b) aliphatic hydrocarbylphenol dissolved in the resin containing the polymerization product of phenol and formaldehyde, wherein the hydrocarbylphenol has from 9 to 17 carbon atoms in the hydrocarbyl group and the quantity of hydrocarbylphenol is from about 0.2% to 5% based on the weight of the aqueous resole resin. Wood-product laminate composites bound with the above resole resin, after curing, exhibit unexpectedly low water absorption, good internal bond strength and reduced thickness swell properties.

Abstract: A single package, ready-to-use (RTU) resin/wax emulsion adhesive and a method of preparing the same by heating a thermosetting resin and adjusting the pH of the wax emulsion prior to combining the resin and wax emulsion. The use of the adhesive in making bonded composites such as wood products, including oriented strand board (OSB), parallel strand lumber, wafer board and particle board composites.

Abstract: There is provided a method for producing lignocellulosic composites. This method is useful in reducing the thickness swell of these composites on their exposure to water. This method also is useful in reducing the hot-press times required to make lignocellulosic composites. Furthermore, there is provided a method by which wax sizing may be used without the previously expected reduction in physical properties. Also, there is provided a method by which caul plate sticking may be reduced when hydrogen peroxide is used as a furnish add-on.

Abstract: Disclosed is a friction element designed for frictional contact with a body and for use, in particular, in brakes or clutches. The friction element has at least one freely accessible surface formed by a carbon-fiber-reinforced porous carbon block, at least some pores of which are filled with silicon and silicon carbide. In order to provide a friction element of this kind, as well as a method of manufacturing the friction element, which gives the advantages associated with C/C--SiC materials and which can be manufactured inexpensively, thus making it suitable, from the cost point of view, for general use particularly in the automobile-construction industry, the friction element is made up of at least one core element and at least one friction block securely bonded to it, the friction block being bonded to the core element on the side remote from its friction surface and the two elements being joined to each other by a high-temperature-resistant bonding layer.

Abstract: Light-colored phenolic-modified rosin esters, suitable for use as, for example, tackifiers in adhesive compositions, are prepared by reacting together rosin, a phenolic compound, formaldehyde or a reactive equivalent thereof, and a non-phenolic hydroxyl-containing organic compound in the presence of at least one lightening agent selected from phenol sulfide compounds, phosphorous acid, esters of phosphorous acid, and hypophosphite salts. The formaldehyde or reactive equivalent is present in an amount ranging from about 1.1 to about 3.5 equivalents of --CHO moieties per 1 equivalent of Ar--OH moiety of the phenolic compound, in order to obtain rosin esters having desirably low color, and adequately low molecular weight to effectively function as tackifiers.

Abstract: Mixed glycols, as exist in the waste stream from a glycol production unit, are utilized for production of a liquid resole resin in an aqueous alcoholic solvent. The solvated resole resin is employed as a binder for production of laminates.

Abstract: A process and a binder for producing fibrous webs and fibrous web moldings, preferably in molding tools, in which fibrous webs are chemically bonded with powdered binders which consist wholly or partly of powder coating material, preferably recycled powder coating material.

Abstract: The invention provides an adhesive system comprising a blend of resin and a co-adhesive conjugated triglyceride drying oil acting as a internal release agent which is mixed with fibers for bonding composite panels such as oriented strand board, particle board, plywood, MDF, hardboard, and similar panels. The resin is a fast acting bonding material which forms a mat of fibers into a self sustaining panel within a time limit during which a press may be economically utilized. The triglyceride acts slower so that, after the panel is formed, there is enough time to penetrate the fibers to a depth that results in a superior bonding. The conjugated drying oil is a release agent that provides an internal release agent that prevents the composite panel from sticking to the press that bonds it.

Abstract: The present invention provides compositions and processes wherein recycling of waste carpets and textiles is achieved by coating the individual yarn fibers with a low viscosity adhesive that is dispersed or dissolved in a suitable solvent to affect coverage of the fine fibers, and arranging the coated fibers in layers to affect the most desirable physical properties and then cured to provide a high modulus matrix for the coated fibers in the laminate structure. The fibers may be from unshredded or shredded waste carpets, shredded waste woven or non woven fabrics, fabric bits, and knitted fabrics. When the carpet is used in an as received condition, the face yarns, which may contain one or more components yarns, are coated and the carpets are arranged in a sandwich construction wherein the backings of the two carpets are placed back-to-back, e.g., (F-B-(B-F).sub.

Abstract: This invention relates to an ink jet print head having ink passage ways formed in a radiation cured resin layer which is attached to a substrate. The passageways are connected in fluid flow communication to an ink discharging outlet provided by an orifice plate. In order to form the passage ways in the resin layer, a resin composition is exposed to a radiation source in a predetermined pattern to cure certain regions of resin layer while other regions which provide the passage ways remain uncured. The uncured regions are removed from the resin layer leaving the desired passage ways. The resin composition to be used for forming the radiation curable layers is a resin composition comprising: a first multifunctional epoxy compound; a second multifunctional compound; a photoinitiator; and a non-photoreactive solvent.

Abstract: Subjecting lignocellulosic components coated with an aqueous alkaline phenolic resole resin solution to carbon dioxide inhibits overpenetration of resin and improves bond strength when the coated components are heated to cure the resin by application of steam and pressure in the preparation of structural panels. Also, contact with carbon dioxide of high moisture resin coated lignocellulosic components accelerates the speed of cure and improves bond strength of panels cured under heat and pressure.

Abstract: A process for the preparation of composition board, particleboard, fiberboard, waferboard and oriented strandboard as well as new and useful products thereof are provided for by the separation of one portion of the solid constituents of the composition board and the separate blending of that portion with adhesive before combining and mixing that portion with the remaining solid constituents of the composition board product. The method and product is particularly adapted to the use of fines as the one portion of the solid component of composition board and utilizing the precoated fines as an adhesive carrier in the final step of mixing or blending of the fines with the remaining composition board components.

Abstract: A guanidine-modified phenol-formaldehyde resole resin by reacting formaldehyde and phenol at a formaldehyde to phenol mole ratio above about 1.5:1 in the presence of an effective amount of an alkaline catalyst and in the presence of a catalytic amount of a guanidine salt. The resin is suitable for use in adhesives for high moisture content substrates.

Abstract: There is provided a co-condensation product obtainable by subjecting a p-alkylphenol to reaction with formaldehyde in the presence of an alkali catalyst to prepare a resol type condensate, and subjecting the resulting resol type condensate to reaction with a m-substituted phenol such as resorcin in the presence of an acid catalyst, wherein the content of the m-substituted phenol is not higher than 4% by weight, and the content of a component having a molecular weight not higher than 1,000 excluding both the p-alkylphenol and the m-substituted phenolis at least 25% by weight based on the total weight of the co-condensation product. This co-condensation product is low in fuming and in hygroscopic properties, exhibits excellent adhesiveness in vulcanizing adhesion between rubber and a reinforcing material, and further provides a vulcanized rubber article of high hardness.

Abstract: A plastisol type adhesive composition used to bond a filer paper and end caps of an filter element of a fuel filter for filtering a mixture fuel of gasoline and methanol. The adhesive composition comprises a polymer (vinyl chloride polymer and/or copolymer) in an amount of 100 parts by weight, a filler in an amount ranging from 50 to 250 parts by weight, a plasticizer in an amount ranging from 50 to 250 parts by weight, and phenolic resin as an adhesiveness providing agent, in an amount ranging from 0.5 to 20 parts by weight.

Abstract: The invention relates to the use of a resorcinol-glutaraldehyde reaction product as an accelerator for thermosetting phenolic resin and to a method of making the accelerator. Further, the invention relates to a resin blend comprising phenol-formaldehyde and the accelerator and a process for making cellulosic board, oriented strandboard and plywood wherein the binder for the cellulosic board, oriented strandboard and plywood in its uncured form comprises the resin blend of the invention. In another embodiment the accelerator for thermosetting resin comprises resorcinol and glutaraldehyde.

Abstract: The invention comprises a method for joining pieces of unseasoned or undr wood, by finger jointing or other joining technique. The wood may have a moisture content above the fibre saturation point of the wood, and as high as 50% to 100% or higher moisture content. An adhesive having a sufficiently high molecular weight or viscosity to avoid adhesive degradation or migration due to moisture in the wood during forming and curing of the joint, or which will cure to achieve such a sufficiently high molecular weight or viscosity during forming and curing of the joint is employed. Optionally a cure promotor or chemical which increases the rate of cure of the adhesive may be used. Preferred adhesives are formaldehyde based adhesives. Preferred cure promotor or chemicals are ammonia or amine compounds, organic acids including low molecular weight carboxylic acids, and Lewis or Bronsted class acids.

Abstract: A method for improving the adhesion of alkylated chlorosulfonated polyethylene (ACSM) and chlorosulfonated polyethylene (CSM) rubber compounds to a resorcinol-formaldehyde latex (RFL) treated polyester reinforcing element using lower than conventional heat set temperatures comprising dipping the element into a RFL dip comprising chlorosulfonated polyethylene; drying the element; heat setting the element at a temperature in the range from about 300.degree. F. to about 425.degree. F. under tension; incorporating the element into the rubber compounds; and curing the element and the rubber compounds. Further, adding an amine functional polyacrylate to the RFL dip prevents failure of the adhesion of the cord at start up temperatures of about -40.degree. F.

Abstract: A liquid binding agent comprised of a phenolic resin, thinning agents and a curing agent, characterized in that the phenolic resin is produced by condensation catalyzed under alkaline conditions of a phenol and formaldehyde in a molar ratio of phenolic compound to formaldehyde in the range of 1:0.05 to 1.

Abstract: A process for the preparation of composition board, particleboard, fiberboard, waferboard and oriented strandboard as well as new and useful products thereof are provided for by the separation of one portion of the solid constituents of the composition board and the separate blending of that portion with adhesive before combining and mixing that portion with the remaining solid constituents of the composition board product. The method and product is particularly adapted to the use of fines as the one portion of the solid component of composition board and utilizing the precoated fines as an adhesive carrier in the final step of mixing or blending of the fines with the remaining composition board components.

Abstract: A rapid curing adhesive for wood finger jointing and laminating and a method of its use are disclosed. The adhesive consists of two parts that are used as a honeymoon system. One part is used on one side of the joint being formed and the other part on the other side. When the parts are joined under pressure a very rapid reaction occurs resulting in a durable weather resistant joint. Wood finger joints bonded with the adhesive can be handled for further processing within as little time as 15 seconds. The first part of the adhesive is a conventional resorcinol-formaldehyde or phenol-resorcinol formaldehyde resin containing a hardener such as an alkylene group donor. The second part is a similar resin lacking any hardener but containing a modifier which is a heterocyclic oxygen and nitrogen containing compound. Morpholine has proved to serve well as the modifier. The hardener in the first part is used in a sufficient amount to effect a thermosetting cure for the resin used in both parts.

Abstract: A liquid composition which on exposure to actinic radiation polymerizes to form a heat-curable solid film adhesive, said composition comprising (A) a heat-curable phenol-aldehyde resol resin, (B) a photopolymerizable polyurethane or polyester having, on average, more than one polymerizable acrylic group per molecule, or a mixture of said polyurethane and said polyester, (C) a photopolymerization initiator for (B) and (D) a polyvinylacetal. The heat-curable solid film adhesive is used for bonding friction materials, such as brake linings, to metal.

Abstract: Adhesive compositions comprising an aqueous based adhesive and one or more hydrophilic hydrocarbon surfactant(s) or fluorochemical surfactants and methods for bonding porous materials are described which are particularly suitable for bonding high density and/or high moisture content woods. Methods for bonding timber veneer and improving bond cure rates are also disclosed.

Abstract: Bonding of polystyrene foam details together to produce lost foam molds suitable for casting metallic details is accomplished by coating one of the two mating surfaces of the parts with a phenol-formaldehyde adhesive. The two parts are joined together and the mated assembly is placed in a microwave oven. Exposure of the assembly to microwave energy for a pre-selected period of time effects the bonding.

Abstract: Water resistant emulsions for woodworking adhesives may be prepared using an emulsion polymer, the polymer being prepared in the presence of 1 to 2.5% by weight of 88% hydrolyzed polyvinyl alcohol and 1 to 4% by weight of 95-99.5% (or above) hydrolyzed polyvinyl alcohol.

Abstract: Tightly integrated composite products are obtained by treating a fluoropolymer member on its surface with atmospheric pressure glow discharge plasma in a helium gas atmosphere containing 97% by volume or more of helium gas, and joining another member of rubber compositions, resins, metals, ceramics, or semiconductors to the surface treated fluoropolymer member. By using a fluoropolymer sheet as the fluoropolymer member and a metal or synthetic resin layer as the other member, there are obtained weather-resistant composite sheets in which the layer is firmly bonded to the fluoropolymer sheet.

Abstract: A method for producing a relatively low viscosity tannin extract from bark and/or wood and suitable for use in formaldehyde-condensation adhesives comprises providing tannin extract obtained from bark and/or wood, separating from the tannin extract the high molecular weight material, subjecting the high molecular weight material to treatment with one or more sulphite compounds to reduce the molecular weight and recombining the sulphited material with the tannin extract. The tannin extract may be recovered by subjecting bark and/or wood to a first stage hot aqueous tannin extraction process, thereby obtaining a first stage tannin extract, subjecting the extracted bark and/or wood to a second stage hot aqueous extraction process at a higher pH than the first stage, thereby obtaining a second stage tannin extract, and optionally recombining the first and second stage tannin extracts.

Abstract: This invention relates to a process for modifying lignocellulosic materials by a chemical treatment comprising treating the material sequentially or simultaneously with phthalic anhydride and a thermosetting resin at elevated temperature, and finally heat lignocellulosic material so produced can be formed into shapes or molds having excellent dimensional stability.

Abstract: A composite wood product made from discrete wood particles secured together by a cured bisphenol A formaldehyde resin cured from an A-stage bisphenol A formaldehyde resin having an A-stage bisphenol A to formaldehyde mole ratio of 1 to between 2.5 and 4 and between 3 and 11% of caustic measured as sodium hydroxide based on the weight of resin solids. Preferably the resin will include 2 to 10% urea based on the resin solids. The cured bisphenol A formaldehyde resin secures the wood particles together to form a composite wood product having light colored glue lines that substantially corresponds in color with the wood so that the glue lines tend to be unnoticeable.

Abstract: The present invention is directed to improving the peel strength of copper foil laminated to polyetherimide substrates which optionally are reinforced. The improvement in process comprises coating one side of the copper foil with an adhesive composition, placing the coated side of the copper foil in contact with pre-formed polyetherimide substrate, and heat-pressing the resulting build-up to form a cured laminate of improved peel strength. The adhesive composition utilized comprises a blend of a polyvinyl butyral resin; one or more resole resins, and an organic solvent. Heat-pressing conditions comprise a temperature ranging from about 450.degree. to 550.degree. F. and pressing conditions ranging from about 100 to 700 psi. Within this temperature/pressure range, the adhesive-coated copper foil mated with the pre-formed polyetherimide substrate yields desired peel strengths without inducing excessive flow of the polyetherimide substrate, i.e. maintaining a pre-desired thickness .+-.7.5%.

Abstract: A golf grip assembly process which includes coating a sleeve with a layer of soluble phenol-acetaldehyde resin over the inner surface thereof, and spraying a solvent over the layer of soluble phenol-acetaldehyde resin with before the insertion of a rod for the grip. The soluble phenol-acetaldehyde resin is dissolved by the solvent into a glue to fixedly secure the rod inside the sleeve, after the insertion of the rod into the sleeve and after the setting of the glue, so that the rod and the sleeve are incorporated into a unitary golf grip assembly.

Abstract: An adhesion promoting composition for enhancing adhesion between an elastomeric substrate and a metal surface which, when applied at least in substantial contact with the metal surface, produces an elastomer-metal adhesive bond that withstands high temperature fluid and corrosive material environments and that can be applied without extensive pretreatment of the metal surface. The adhesion promoting composition comprises a phenolic resin derived from a first phenolic component, a second phenolic component, and a formaldehyde source, wherein the first phenolic component is a monohydroxy aromatic compound, a dihydroxy aromatic compound or a combination thereof, and the second phenolic component is a trihydroxy aromatic compound. A two-part adhesive composition containing a primer component and an overcoat component is also disclosed.

Abstract: In the process for the production of a molded body having a pressed core of solid inert particles which are coated with a thermoset phenolic resin, phenolic compounds on a basis of bisphenol, in particular a bis(hydroxyphenyl)alkane, and at least one compound which produces formaldehyde, and also a catalyst and optionally further additives customarily employed in the preparation of phenolic resins are mixed together with the inert particles. The mixture of particles obtained, preferably after precompressing and preforming, is pressed to form the molded body. During pressing under the action of heat formaldehyde is set free and the phenolic resin is completely cross-linked.

Abstract: A phenol-formaldehyde resole resin solution useful in adhesives for preparing wood laminates from a plurality of wood veneers, prepared by reacting at least an equal molar amount of formaldehyde with phenol in the presence of sodium hydroxide and a water-soluble potassium salt selected from the group consisting of potassium choloride, potassium sulfate and mixtures thereof.

Abstract: An electrically conductive epoxy-based adhesive. The epoxy is selected from the amine curing modified epoxy family consisting of a resin that is a combination of polyglycidylaminophenyl resin and polygylcidylether of phenylformaldehyde novalac resin family, and a catalyst that is a combination of one member from the aliphatic amide family plus one member from the aliphatic polyamine family. In one embodiment includes 17 parts by weight of the resin and 10 parts by weight of the catalyst. 73 parts by weight of a mixture of properly shaped silver flake particles are added. The resulting adhesive is curable at room temperature to provide a high-temperature, high-strength, electrically conductive adhesive.

Abstract: It has now been found that when there is a partial or complete replacement of the sodium hydroxide that is used to make a sodium phenolate resole resin by a molar equivalent of potassium hydroxide, a far faster curing resin is obtained. Such potassium-modified phenolic resins exhibit significant improvement in cure speed without loss of flowability. To the contrary, these resins act as though they were lower molecular weight condensation products. Reduced application rates are possible. The combination of faster cure and lower application rates has allowed such resins to be used as effective adhesives for plywood, for example, with veneer and interior plies having a higher moisture content than was previously possible. Generally, resins according to the invention may contain from about 1% to about 14%, and preferably from about 1% to about 7% by weight, of potassium hydroxide, or more.

Abstract: The disclosure relates to a medium density overlay plywood panel used as an exterior trim product for a residential building having a relatively high number of plies to total board thickness, and exposed edges with void free sanded surfaces having a predetermined pattern coarseness, and in which said overlay and edge surfaces are covered with an acrylic paint, whereby the trim product is characterized with the appearance of a solid wood product and the painted surfaces as highly weather resistant.

Abstract: The invention is a solution of highly advanced phenolic resin with improved inherent foamability that is made from the reaction of phenol, aldehyde, water and alkali the improved foamability being brought about by the incorporation of up to 1.0% by weight, anhydrous basis, lime (calcium hydroxide) into the early stages of the reaction mix. In another embodiment, the invention is a plywood glue composition comprising a solution of lime-containing highly advanced phenolic resin, dried animal blood and preferably an aldehyde glue viscosity-lowering agent.

Abstract: A pre-cure resistant powder resin binder for waferboard/oriented strandboard manufacture is manufactured from spray drying a liquid resin composition containing a low advanced phenol-formaldehyde resin and a water soluble oxo compound of boron. The spray dryability of the low molecular weight phenol-formaldehyde resin is enhanced by the addition of the oxo boron compound.

Abstract: Disclosed is a method of making a dimensionally stable composite board product made from a mixture of particles of a cellulose material and binder and a composite board so produced by such method. Dimensional stability is in reference to the resistance to thickness swelling when the board is subjected to high humidity or moisture conditions. The method and composite board displaying the attribute of improved dimensional stability involves subjecting the particles of cellulosic material to a pressurized steam treatment and then making the composite board under heat and pressure. When compared to conventional composite board that has not been subjected to the pretreatment, the difference in thickness swelling is significant.

Abstract: A vulcanized rubber-synthetic resin composite structure is produced by injecting a molten synthetic resin into a mold in which a vulcanized rubber molding has been disposed. For improvement the surface of the vulcanized rubber molding which comes into contact with the synthetic resin is chrominated, and on the chlorinated surface a curable adhesive layer composed mainly of resol-type phenolic resin and aldehyde-modified polyvinyl alcohol is formed. Alternatively a curable adhesive layer composed mainly of chlorosulfonated polyethylene is formed the surface of the vulcanized rubber molding which comes into contact with the synthetic resin, to which the molten synthetic resin is injected while keeping the vulcanized rubber molding heated.