Abstract: An absorbent paper sheet is treated with an aqueous wax dispersion such that the sheet includes a fused wax and emulsifier residue in an amount of from about 1 to about 20 weight percent of the sheet based on the combined weight of the fiber, wax residue and an emulsifier residue in the sheet. The fused wax emulsion operates to make at least one surface of the sheet laterally hydrophobic, exhibiting a moisture penetration delay of at least about 2 seconds and less than about 40 seconds as well as a typical contact angle with water at one minute of at least about 50 degrees. There is thus provided absorbent products which exhibit both absorbency and resistance to moisture penetration. The treated sheet further exhibits microbial barrier properties, impeding transfer of bacteria, for example, through the sheet. There are produced tissue products which resist moisture penetration from propelled liquids as well as sequester sorbed liquids in the interior of the tissue.

Abstract: It is intended to provide sanitary paper which is excellent in texture such as moistness and softness and scarcely causes skin irritation or blushing even if it is brought into contact with the skin frequently. Namely, sanitary paper having an oil absorbance specified in JIS P8141 of 7 mm or less and a moisture content of from 9.50 to 15.00% (measured in accordance with JIS P8127 after conditioning in accordance with JIS P8111); carrying a solution, which contains a moistening agent, a softener, an antioxidant and so on, coated in a dose of 46.0 to 160.0 mg/cm3 of the paper base; and having a bending hardness B measured with the use of a pure bending machine of from 0.0040 to 0.0060 g·cm2/cm.

Abstract: A process for manufacturing a cellulosic paper product (e.g., paper hand towels) exhibiting reduced malodor upon wetting. The process comprises forming an aqueous suspension of papermaking fibers, depositing the aqueous suspension onto a sheet-forming fabric to form a wet web, drying the web at high temperature in an oxidative environment and topically applying a liquid glycol composition comprising a glycol compound selected from the group consisting of polyethylene glycol, triethylene glycol, glycerol and mixtures thereof to the web having a dry weight consistency of at least about 80%. The process of the present invention is particularly suited for reducing malodor released from cellulosic paper products made from through-air dried base sheet material.

Abstract: The invention provides a method for preparing cross-linked cellulosic fibers. A sheet of mercerized cellulosic fibers with a purity of at least 95% is treated with a solution containing a carboxylic acid cross-linking agent. The treated cellulosic fibrous material is dried and cured in sheet form to promote intrafiber cross-linking. Cross-linked fiber products produced are economic and possess good porosity, bulking characteristics, wet resiliency, absorption characteristics, low fines, low nits and low knots. The invention also includes blended cellulose compositions comprising a minor proportion of cross-linked mercerized cellulosic fibers and a major proportion of other cellulosic fibers. The invention further provides individualized, chemically cross-linked mercerized cellulosic fibers of high purity.

Abstract: Sized paper containing an amphoteric promoter resin that is a polymerization reaction product of a quaternary diallylammonium monomer, optionally a diallylammonium monomer, and an unsaturated organic acid is described. The method of sizing paper with such amphoteric promoter resin compound and a sizing agent provides sized paper with significantly improved sizing property characteristics, and the sized paper exhibits superior retention of brightness due to added optical brighteners.

Abstract: A process for manufacturing a cellulosic paper product is provided. The process comprises forming an aqueous suspension of papermaking fibers; depositing the aqueous suspension onto a sheet-forming fabric to form a wet web; dewatering the wet web to form a partially dewatered web; topically applying a glycol compound selected from the group consisting of polyethylene glycol, triethylene glycol, glycerol and mixtures thereof to the partially dewatered web; and drying said wet web. The present invention also provides for cellulosic paper products exhibiting a reduced malodor upon wetting.

Abstract: The invention relates to a starch and fiber mixture, and the application of a starch and fiber mixture in paper manufacturing. The starch and fiber mixture is applied to a paper mat, after the paper mat is formed. The starch and fiber mixture may be obtained by the selective filtering of white water from the papermaking process, particularly by use of a pressure screen.

Abstract: The invention provides a method for preparing cross-linked cellulosic fibers. A sheet of cellulosic fibers treated with a caustic solution under non-mercerizing conditions is cross-linked with a solution containing polymeric polycarboxylic acid cross-linking agents. The treated cellulosic fibrous material is dried and cured in sheet form to promote intrafiber cross-linking. Cross-linked fiber products of this method, which is economic, that possess good absorption and wet resiliency properties are also disclosed.

Abstract: Methods for forming an absorbent fibrous composite containing absorbent material dispersed in bands through the composite and along the composite's length are disclosed. The methods generally include depositing a fibrous slurry on a foraminous support to form a web and depositing or injecting absorbent material into the web across its width to provide a web having absorbent material in bands along the composite's length. Drying the web provides a fluted absorbent composite. In one embodiment, the method is a wetlaid method and in another embodiment, the method is a foam-forming method. Preferably, the methods are twin-wire forming methods.

Abstract: Fiber treated with an organic nonpolymeric binder is combined with superabsorbent particles in order to bind the particles to the fiber. The nonpolymeric organic binder comprises binder molecules that include at least one functional group capable of forming a hydrogen bond or a coordinate covalent bond with the particles and at least one functional group capable of forming a hydrogen bond with the fiber. The superabsorbent particles have a hydrogen or coordinate covalent bonding functional site. The binder serves to bind the particles to the fiber through formation of hydrogen and/or coordinate covalent bonds.

Abstract: Aqueous compositions of (per)fluoropolyether phosphates of formula: T—O—[Rf—CFY—L—O]P(O)(O?Z+)(OH); ??(A) and/or (OH)m(O?Z+)2-mP(O)[O—L—YFC—O—Rf—CFY—L—O—P(O)(O?Z+)]m?——[O—L—YFC—O—Rf—CFY—L—O]P(O)(O?Z+)2-m(OH)m ??(B) and use thereof to confer oleo-repellence to the paper by means of the size-press method.

Abstract: A method is disclosed for topical application of compositions containing a chemical additive onto a paper web. The present invention is also directed to paper products formed from the method. In general, the method includes the steps of extruding a composition containing a chemical additive through a melt blown die and then applying the composition to a moving paper web. In particular, the method provides for the application of tacky compositions to a web through a melt blown die while avoiding die tip clogging. In one embodiment, the chemical composition is extruded into fibers and applied to the paper web. The chemical composition may contain, for instance, various additives, such as a polysiloxane softener and one or more beneficial agents.

Abstract: A method for target application of a Performance Enhancing Material to a creping cylinder in order to improve a tissue making operation is described and claimed. The method involves dividing the creping cylinder into Zones and then applying the desired Performance Enhancing Material on a Zone by Zone basis such that each Zone has the optimal Performance Enhancing Material present. Furthermore, a method to ascertain the amount and pattern of application of the Performance Enhancing Material used on the creping cylinder is described and claimed. This method involves adding an inert fluorescent tracer to said Performance Enhancing Material and then to use a fluorometer to look for the tracer on the creping cylinder, and/or on the creped tissue product and/or in the water removed from the felt.

Abstract: A method and assembly is disclosed for manufacturing a sized web of paper or paperboard, the method comprising the steps of first forming the web at a headbox (1) from a stock comprising at least water and fiber, then pressing the web for water drainage, and finally drying the web by heating. Size furnish is added to the web so that at least a portion of the overall amount of size is added to the web prior to initiating the drying of the web by heating, and at least a portion of the overall amount of size is applied to the web after initiating the drying of the web.

Abstract: The invention provides a method for preparing cross-linked cellulosic fibers. A sheet of mercerized cellulosic fibers with a purity of at least 95% is treated with a solution containing a carboxylic acid cross-linking agent. The treated cellulosic fibrous material is dried and cured in sheet form to promote intrafiber cross-linking. Cross-linked fiber products produced are economic and possess good porosity, bulking characteristics, wet resiliency, absorption characteristics, low fines, low nits and low knots. The invention also includes blended cellulose compositions comprising a minor proportion of cross-linked mercerized cellulosic fibers and a major proportion of other cellulosic fibers. The invention further provides individualized, chemically cross-linked mercerized cellulosic fibers of high purity.

Abstract: The invention relates to a starch and fiber mixture, and the application of a starch and fiber mixture in paper manufacturing. The starch and fiber mixture is applied to a paper mat, after the paper mat is formed. The starch and fiber mixture may be obtained by the selective filtering of white water from the papermaking process, particularly by use of a pressure screen.

Abstract: A method is disclosed for topical application of compositions containing a chemical additive onto a paper web. The present invention is also directed to paper products formed from the method. In general, the method includes the steps of extruding a composition containing a chemical additive through a melt blown die and then applying the composition to a moving paper web. In particular, the method provides for the application of tacky compositions to a web through a melt blown die while avoiding die tip clogging. In one embodiment, the chemical composition is extruded into fibers and applied to the paper web. The chemical composition may contain, for instance, various additives, such as a polysiloxane softener and one or more beneficial agents.

Abstract: The invention relates to a process for producing a coated paper web, According to the process, a paper web is formed from a fibrous raw material in a paper machine, the paper web is coated with a pigment-containing coating mix, and the coated paper web is calendered. According to the invention, the paper web is coated with a coating composition that contains as the mineral pigment mainly a mixture of gypsum and calcium carbonate, the amount of gypsum being at minimum 10% by weight of the total amount of gypsum and calcium carbonate. With mixtures of calcium carbonate and gypsum, such as mixtures of PCC and gypsum and mixtures of PCC, ground carbonate and gypsum, there are obtained simultaneously a sufficient gloss and smoothness as well as a brightness and opacity better than with PCC-kaolin pastes.

Abstract: A method of producing core raw paper is provided that prevents corrugation cracking, corrugation cutting or breakage from occurring during corrugating operation using a corrugating roll, prevents the wearing of the corrugating roll, reduces the consumption of driving power and noise, is capable of uniformly and efficiently coating the core raw paper with wax, and does not pollute facilities such as a paper machine.

Abstract: A tissue product comprising cellulosic fibers and having at least 10% of fugitive wet strength and at least about 3% of a fiber-flexibilizing composition. The fugitive wet strength can be generated by adding a binder that promotes acid-catalyzed formation of hemiacetal functional inter-fiber cross-links. The fiber-flexibilizing composition can comprise either a humectant or a plasticizer. The humectant can be selected from the group consisting of calcium chloride; lactic acid and its salts, high fructose corn syrup, glycerol, triacetin, sorbitol, maltitol, mannitol, propylene glycol, and any combination thereof. The plasticizer can be selected from the group consisting of urea, alkyloxylated glycols, dextrose, sucrose, ethylene carbonate, propylene carbonate, and any combination thereof.

Abstract: A method of making a multilayer paper web, wherein at least two paper sheets are formed and dried separately to a dry content of no more than 80% by weight, imparting a three-dimensional pattern of alternating raised and recessed portions in the paper sheets during drying, combining the paper sheets into a multilayer web, in which void volumes are created between the raised and recessed portions of the combined sheets and drying the multilayer web.

Abstract: A method for forming a tissue product that is soft and produces relatively low levels of slough is provided. The method includes providing a liquid furnish of cellulosic fibers and forming a multi-layered wet web therefrom. The web is dried (e.g., through-dried) to a solids consistency of 90% or greater. A latex having a glass transition temperature less than about 30° C. is applied to the dried web (e.g., foamed, printed, sprayed, etc.) such that the latex comprises less than about 3% by weight of the dry weight of the web. The latex remains substantially uncured after being applied to the dried web.

Abstract: A method for obtaining a chemical composition for de-acidification of cellulose-type material comprises preparing a solution of 30 to 70% carbonated magnesium di-n-propylate in n-propanol and diluting the solution by addition of a hydrofluorocarbon diluent selected from the group consisting of 1,1,1,2-tetrafluoroethane and 1,1,1,2,3,3,3-heptafluoropropane.

Abstract: A method for applying a foam composition to a paper web is provided. Specifically, a paper web is initially formed from papermaking fibers and is carried by a first moving papermaking surface so that a first surface of the paper web faces the first moving papermaking surface (e.g., fabric). A foam composition is deposited onto a second moving papermaking surface (e.g., fabric). The second moving papermaking surface is positioned adjacent to the first moving papermaking surface so that a second surface of the paper web faces the second moving papermaking surface. As a result, at least a portion of the foam composition is transferred to the paper web.

Abstract: A method and assembly is disclosed for manufacturing a sized web of paper or paperboard, the method comprising the steps of first forming the web at a headbox (1) from a stock comprising at least water and fiber, then pressing the web for water drainage, and finally drying the web by heating. Size furnish is added to the web so that at least a portion of the overall amount of size is added to the web prior to initiating the drying of the web by heating, and at least a portion of the overall amount of size is applied to the web after initiating the drying of the web.

Abstract: A method is disclosed for topical application of compositions containing a chemical additive onto a paper web. The present invention is also directed to paper products formed from the method. In general, the method includes the steps of applying a composition containing a chemical additive onto a first side of a paper web. The paper web is then wound into a roll. During winding, a portion of the composition transfers from the first side of the web to the second side of the web. Thus, both sides of the web become treated with the composition through a single application of the composition to the web.

Abstract: Paper products treated on two surfaces with a liquid resistant composition are disclosed. The paper products can be, for instance, bath tissues, facial tissues, paper towels, and industrial wipers. The liquid resistant compositions can include any additive that provides benefits to the product. For instance, the liquid resistant composition can be a softener containing a hydrophobic additive. In one embodiment, the hydrophobic additive is a polysiloxane. In accordance with the present invention, the water resistant composition is applied to each surface according to a pattern. Each of the patterns includes treated and untreated areas. The patterns are positioned on the paper product such that untreated areas on one surface are in correspondence with the treated areas on the other surface of the sheet.

Abstract: Articles containing cellulose materials and treated with a chemical additive are disclosed. In accordance with the present invention, at least a portion of the cellulose containing the article is modified to include a first moiety. A chemical additive, such as softener or a humectant, is then chosen that includes a second moiety. When the chemical additive is applied to the article, the second moiety on the chemical additive forms a chemical linkage with the first moiety on the cellulose material. In this manner, the chemical additive becomes bonded to the cellulose material alleviating problems associated with retention. In one embodiment, the present invention is directed to the formation of tissue products, such as facial tissue, bath tissue and paper towels.

Abstract: A creping composition including a crosslinkable polymer that releases formaldehyde during crosslinking, a filler material and a water-soluble glycol compound is disclosed. Also disclosed is a creped material including the creping composition and a process for making the same.

Abstract: The product is presented in the form of a solution and is composed of carbonated magnesium di-n-propylate, n-propanol, and a hydrofluorocarbon (HFC) diluent selected from 1,1,1,2-tetrafluoroethane (HFC 134a) and 1,1,1,2,3,3,3-heptafluoropropane (HFC 227). The product may be obtained by a procedure which comprises preparing a solution of carbonated magnesium di-n-propylate in n-propanol and diluting said solution by addition of the HFC diluent. The product is suitable for de-acidifying cellulose-type material and preserving objects based on cellulose-type material.

Abstract: A method is disclosed for topical application of compositions containing a chemical additive onto a paper web. The present invention is also directed to paper products formed from the method. In general, the method includes the steps of extruding a composition containing a chemical additive through a melt blown die and then applying the composition to a moving paper web. In particular, the method provides for the application of tacky compositions to a web through a melt blown die while avoiding die tip clogging. In one embodiment, the chemical composition is extruded into fibers and applied to the paper web. The chemical composition may contain, for instance, various additives, such as a polysiloxane softener and one or more beneficial agents.

Abstract: A coating color composition comprising an aqueous dispersion of (a) a pigment, (b) a binder, (c) a fluorescent whitener and (d) a water-soluble polymer formed from a water-soluble ethylenically unsaturated monomer or monomer blend, characterised in that the water-soluble polymer consists essentially of, (i) 90 to 100 mole % hydrophilic essentially nonionic repeating units and, (ii) 0 to 10 mole % anionic repeating units and has an average molecular weight of between 50,000 and 500,000.

Abstract: Method and assembly for supporting a web (1) during the postprocessing of a web of paper or board, in which method the web is passed from a preceding device to at least one next downstream located web treatment device (4) wherein to at least one side of the web (1) is applied a treatment agent causing wetting of said side of said web, and the web (1) exiting said web treatment device is passed to at least one dryer means (8). The web (1) is contactingly supported in a continuous and unbroken manner at least from said web treatment device (4) to said dryer means (8). Advantageously, the web (1) is dried by means of at least one dryer (3) before taking the web to the web treatment device (4), and the web is contactingly supported in a continuous and unbroken manner at least from said dryer means (3) preceding said web treatment device (4) to said dryer means (8) located downstream next to said web treatment device.

Abstract: Method and assembly for forming a paper or board web and a product made using the method. According to the method, the web (11) is made from fibers and then the web (11) is treated with pigment particles. The web is treated with microscopic pigment particles whose average size is so small as to permit the particles to adhere to each other by van der Waals forces. The particles are transferred to the web and adhered thereto advantageously using an ion-blast technique.

Abstract: A highly densifiable wood pulp product is disclosed. In one embodiment, the densifiable product includes fibers having low coarseness, preferably having a fiber coarseness less than about 22 mg/100 m, and a densifying agent. In another embodiment, the densifiable product further includes fibers having coarseness greater than about 22 mg/100 m. Juvenile wood fibers are the preferred source of fibers having low coarseness. A densified pulp product formed by compacting a fibrous composite that includes fibers having a fiber coarseness less than about 22 mg/100 m, a densifying agent, and optionally, fibers having coarseness greater than about 22 mg/100 m is also disclosed. The pulp products can be advantageously incorporated into absorbent articles and can optionally further include superabsorbent material. Methods for forming the densifiable and densified fibrous products are also disclosed.

Abstract: A method for forming a tissue product that is soft and produces relatively low levels of slough is provided. The method includes providing a liquid furnish of cellulosic fibers and forming a multi-layered wet web therefrom. The web is dried (e.g., through-dried) to a solids consistency of 90% or greater. A latex having a glass transition temperature less than about 30° C. is applied to the dried web (e.g., foamed, printed, sprayed, etc.) such that the latex comprises less than about 3% by weight of the dry weight of the web. The latex remains substantially uncured after being applied to the dried web.

Abstract: A method of compressively modifying, such as by calendering, an uncreped throughdried tissue sheet is disclosed. The dried tissue sheet, initially supported by the throughdrying fabric, is removed from the throughdrying fabric and compressively modified. Thereafter, the compressively modified sheet is recombined with a papermaking fabric and carried to a reel section while supported by the fabric. The sheet is always, or substantially always, supported by a fabric or a roll surface to minimize opportunities for sheet breaks or otherwise adversely affecting sheet properties.

Abstract: A paper tissue such as a facial tissue or a disposable handkerchief and a method of making the tissue. The method includes passing the tissue paper web through an embossing nip formed between a first and a second embossing roll, wherein at least one of the embossing rolls comprises at least 30 embossing elements per square centimeter and applying a transferable lotion to at least portions of the tissue paper web.

Abstract: The invention relates to a coated fiber mat of improved tear strength upon dividing pieces of the coated mat and the coating which comprises a cured, non-woven, fiber glass mat containing a polysiloxane wherein the fibers are fixedly distributed in a formaldehyde type binder containing a binder modifier which is a crosslinked styrene/acrylic polymer, and to a process for the preparation of the mat.

Abstract: A process for forming an abrasion resistant, decorative sheet which comprises forming a web of cellulosic fibers on a papermaking machine and applying a coating suspension including an abrasion-resistant grit and decorative inclusion particles to the upper surface of the web on the papermaking machine.

Abstract: A polyamide, the enzymatic reaction product of at least one polyamine and diester, and processes for preparing and using the same. In addition, processes for preparing and using the enzymatic reaction product as creping adhesives and wet strength resins to make cellulose products.

Abstract: A highly densifiable wood pulp product is disclosed. In one embodiment, the densifiable product includes fibers having low coarseness, preferably having a fiber coarseness less than about 22 mg/100 m, and a densifying agent. In another embodiment, the densifiable product further includes fibers having coarseness greater than about 22 mg/100 m. Juvenile wood fibers are the preferred source of fibers having low coarseness. A densified pulp product formed by compacting a fibrous composite that includes fibers having a fiber coarseness less than about 22 mg/100 m, a densifying agent, and optionally, fibers having coarseness greater than about 22 mg/100 m is also disclosed. The pulp products can be advantageously incorporated into absorbent articles and can optionally further include superabsorbent material. Methods for forming the densifiable and densified fibrous products are also disclosed.

Abstract: Modified polysaccharides (such as starches, gums, chitosans, celluloses, alginates, sugars, etc.), which are commonly used in the paper industry as strengthening agents, surface sizes, coating binders, emulsifiers and adhesives, can be combined into a single molecule with modified aliphatic hydrocarbons, which are commonly utilized, in conjunction with cationic moieties, as softeners, debonders, lubricants and sizing agents. The resulting molecule is a modified polysaccharide having an aliphatic moiety which can provide several potential benefits, depending on the specific combination employed, including: (a) strength aids that do not impart stiffness; (b) softeners that do not reduce strength; (c) wet strength with improved wet/dry strength ratio; (d) debonders with reduced linting and sloughing; (e) strength aids with controlled absorbency; and (f) surface sizing agents with improved tactile properties.

Abstract: Textile materials, including paper webs, treated with a polyvinylamine polymer and a second agent that interacts with the polyvinylamine polymer is disclosed. The second agent added with the polyvinylamine polymer can be, for instance, a polymeric anionic reactive compound or a polymeric aldehyde-functional compound. When incorporated into a paper web, the combination of the polyvinylamine polymer and the second agent provide improved strength properties, such as wet strength properties. In an alternative embodiment, the polyvinylamine polymer and the second polymer can be applied to a textile material for increasing the affinity of the textile material for acid dyes.

Abstract: This invention pertains to security paper and methods of making such security paper. The invention comprises a light-colored base paper having a non-protection area of a first thickness, and a protection area of a second thickness on at least one major surface of the base paper wherein the first thickness is greater than the second thickness. The base paper comprises colorant whereby the protection area exhibits a translucence when viewed using transmitted light, and exhibits the colorant as a darker color indication, relative to the non-protection area, when viewed using reflected light. Transmission of light through a combination of paper fibers and the colorant of the invention, both being disposed at the protection area, is discernibly different from transmission of light through the non-protection areas of the base paper, when viewed with a human eye.

Abstract: The invention relates to a process for producing a coated paper web. According to the process, a paper web is formed from a fibrous raw material in a paper machine, the paper web is coated with a pigment-containing coating mix, and the coated paper web is calendered. According to the invention, the paper web is coated with a coating composition that contains as the mineral pigment mainly a mixture of gypsum and calcium carbonate, the amount of gypsum being at minimum 10% by weight of the total amount of gypsum and calcium carbonate. With mixtures of calcium carbonate and gypsum, such as mixtures of PCC and gypsum and mixtures of PCC, ground carbonate and gypsum, there are obtained simultaneously a sufficient gloss and smoothness as well as a brightness and opacity better than with PCC-kaolin pastes.

Abstract: The present invention is a method for uniformly applying a foam to a wet tissue web is provided. Specifically, a foam is first formed from a liquid-based composition and a gas, such as air. Once formed, the foam is applied by a foam applicator to the wet tissue web. In one embodiment, for example, the foam applicator applies the foam with a flexible scraper contacting the wet tissue web during the application of the foam. When applied with the foam, the wet tissue web typically has a solids consistency less than about 95% by dry weight of the tissue web. In some embodiments, one or more vacuum slots may be utilized in conjunction with the foam applicator to facilitate uniform application of the foam to the wet tissue web.

Abstract: In the manufacture of tissue products from cellulose fibers, it is often desirable to enhance physical properties by the addition of chemical additives, including for example debonding agents. These additives serve to prevent or disrupt interfiber or intrafiber hydrogen bonding. Depending upon the nature of the chemical additive, debonding agents may also act as softening agents. During the papermaking process, chemical additives of this type can be added to fiber slurries in the wet end of a papermaking machine. Alternately, such additives may be sprayed upon tissue layers during manufacture, prior to assembly into multi-ply tissue structures. The chemical additives may include quaternary ammonium salts or organofunctional polysiloxanes. The chemical additives may include quaternary ammonium salts or organofunctional polysiloxanes or polysiloxanes. Some of the quaternary salts which may be used include salts comprised in part of imidazoline heterocyclic nitrogen ring structures.

Abstract: A method of forming a finished paper having high gloss while maintaining high bulk, comprising applying on a surface of a base stock at least one layer of a coating formulation comprising a particulate plastic pigment; and passing the base stock through a multi-nip calender device maintained at relatively low roll temperature and nip pressure. The product formed using this coating formulation and process is of high gloss quality, yet maintains a relatively high bulk, in comparison to high gloss papers produced by conventional methods.

Abstract: The present invention is a method of applying a chemical treating agent to a cellulose web. The invention is further a means of increasing the bulk, absorbency and pattern definition in an embossed cellulose web without losing softness in the web. Finally, the invention includes products produced by the foregoing processes.