Abstract: A method of cementing a pipe into a wellbore filled with a drilling fluid that includes displacing the drilling fluid with the displacement fluid which includes a base fluid, a micronized weighting agent; suspending a pipe in the wellbore; and pumping cement into the wellbore to substantially fill the annulus formed between the outer surface of the pipe and the wellbore is disclosed.

Abstract: Of the many compositions and methods provided herein, an embodiment of a method comprises introducing a foamed cement composition into a subterranean formation, wherein the foamed cement composition comprises: a cementitious component; a foaming and stabilizing surfactant; an oil-swellable particle; gas; and water; and allowing the settable composition to set in the subterranean formation. Another embodiment of a method comprises introducing a foamed cement composition into an annulus between a pipe string and a subterranean formation, wherein the foamed cement composition comprises comprising: a cementitious component; a foaming and stabilizing surfactant; an oil-swellable particle; gas; and water; and allowing the settable composition to set in the annulus. An embodiment of a foamed cement composition comprises a cementitious component, a foaming and stabilizing surfactant, a swellable particle, gas, and water.

Abstract: A method of cementing an oil well with a silicate-forming gel solution and an acid-soluble cement separated by a polymeric spacer which permits solubilization and removal of the cement by HCl in the event of a fracture in subterranean formation and the need for water and/or gas shutoff.

Abstract: Methods of isolating particular zones within a subterranean formation utilizing self-degrading cement compositions are provided. An example of a method of the present invention is a method that includes: providing a self-degrading cement composition that includes a degradable material, an acid source, a base source, and a water source; placing the self-degrading cement composition in a zone within a subterranean formation; and allowing the self-degrading cement composition to set to form a solid mass that is capable of isolating the zone from a well bore penetrating the zone or from another zone.

Abstract: Of the many methods and compositions provided herein, one method includes a method comprising introducing a sealant composition into a well bore that penetrates a subterranean formation, wherein the sealant composition comprises a base fluid, a binder material, and a filler material; and allowing the sealant composition to form a cohesive sealant. One composition provided herein includes a sealant composition comprising a base fluid, a binder material, and a filler material, wherein the sealant composition will form a cohesive sealant.

Abstract: Of the many methods and compositions provided herein, one method includes a method comprising introducing a sealant composition into a well bore that penetrates a subterranean formation, wherein the sealant composition comprises a base fluid, a binder material, and a filler material; and allowing the sealant composition to form a cohesive sealant. One composition provided herein includes a sealant composition comprising a base fluid, a binder material, and a filler material, wherein the sealant composition will form a cohesive sealant.

Abstract: An embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive, wherein the extended settable composition is capable of remaining in a pumpable fluid state for at least about 1 day; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set. Another embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive; storing the extended settable composition; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set.

Abstract: In a process to design high temperature cement sluries, the temperature stable phases (anorthite, wairakite) are selected; aluminum modifiers and silica oxides are added to the dry cement so that the elemental composition of the blend corresponds to the phases selected; the control of the particle size distribution and the relative amount of those minerals allow their addition at high concentration while leaving the slurry easily mixable and pumpable; and the kinetics of the targeted phases formation is then controlled by adjusting the crystallinity and the particles sizes of the different solids.

Abstract: A delayed gelling system useful in conformance control in the production of petroleum from subterranean formations, especially low permeability formations, is disclosed. The gelling system comprises a basic silica sol, an activator comprising a hydroxyl donor, and an optional syneresis inhibitor. In the disclosed method of using the gelling system, the gelling system may be pumped into formations with excessive water and/or gas production and thermally activated in the formation at downhole conditions to form a hard gel to reduce water and/or gas production.

Abstract: A method of primary cementing well is provided utilizing a cement and cement activator cementing composition, in which one of the components is first placed in the annulus of the well. Next, the other component is placed in the annulus above the first placed component. Densities of the components have been selected such that the density of the second placed component is sufficiently higher then the density of the first placed component to facilitate gravity mixing of the two components as the second placed component moves through the first placed component and in the process activation occurs.

Abstract: Methods and compositions for cementing, especially drilling fluids that comprise zeolite and a carrier fluid, and cementing compositions made with such drilling fluids.

Abstract: Cementitious slurries capable of controlling and/or preventing strength retrogression during the cementing of a formation contain a bismuth salt or derivative thereof. Bismuth trioxide is preferred. The cementitious slurry may further contain a density modifying agent and/or strength enhancer. The cementitious slurries of the invention are suitable for use over a broad temperature range of from about 45° F. to about 500° F.

Abstract: A two part encapsulated cementing system is surface mixed and then placed downhole in a method of remediating an active well. This mixture is then placed downhole where it is allowed to degrade in the well fluid allowing for the formation of a cement plug.

Abstract: The present invention provides foamed cement compositions with improved mechanical properties and methods of cementing in subterranean formations, particularly in conjunction with subterranean well operations. The foamed cement compositions comprise carbon fibers, a hydraulic cement material, sufficient water to form a slurry, an expanding additive, and optionally other ingredients including a weighting agent, a retarding or accelerating agent, or the like.

Abstract: A method of servicing a wellbore in contact with a subterranean formation comprising viscosifying a cement composition comprising a metal oxide and a soluble salt, placing the viscosified cement composition in the wellbore, and allowing the composition to set. A method of cementing a wellbore comprising preparing a cement composition comprising magnesium oxide, a chloride or phosphate salt, and a quaternary material, placing the cementitious composition into the wellbore, and allowing the cementitious composition to set. A method of viscosifying a Sorel cement comprising contacting the cement composition with quaternary material.

Abstract: Cement compositions that include high aspect ratio materials, and methods for using such cement compositions in subterranean formations are provided herein. An example of a method is a method of cementing in a subterranean formation. An example of a composition is a cement composition for use in a subterranean formation.

Abstract: Nonionic derivatized starch of varying degrees of substitution may be used as a fluid loss additive for well bore cementing operations. A well bore cementing composition may include a cement and a nonionic derivatized starch, the nonionic derivatized starch in a concentration in the cement to provide a fluid loss of less than 200 cc/30 min. A method for cementing subterranean zones penetrated by a well bore may include: providing a cement slurry including mix water, hydraulic cement and a nonionic derivatized starch as an additive for fluid loss control in well cementing applications; pumping the cement slurry into a well; and holding the cement slurry in place until it sets.

Abstract: Methods of cementing and low density foamed cement compositions therefor are disclosed. A low density foamed cement composition of the invention comprises fly ash comprising calcium oxide or calcium hydroxide, water present in an amount sufficient to form a slurry, a foaming and foam stabilizing surfactant or a mixture of surfactants present in an amount sufficient to facilitate foam and stabilize the foamed cement composition, and sufficient gas to foam the foamed cement composition.

Abstract: A method for treating a subterranean formation penetrated by a wellbore that includes injecting an alkali silicate into the wellbore; injecting a solid micronized silicate-precipitating agent into the wellbore; and allowing the alkali silicate and the solid micronized silicate-precipitating agent to react to form a silicate gel is disclosed.

Abstract: Methods of using cement compositions comprising phosphate compounds in subterranean formations are provided. An example of a method is a method of cementing in a subterranean formation. Other examples of methods include methods of avoiding the loss of circulation in a subterranean formation. Other examples of methods include methods of drilling in a subterranean formation.

Abstract: Loss circulation fluids contain aqueous based compositions having at least one alkali metal formate and at least one thermally activated self-crosslinkable gel forming material, wherein the composition is easily transported to a loss circulation zone and yet has ability to close off the loss circulation zone once thermally activated to reduce the loss of circulation fluids into flow passages of a subterranean formation. In addition, packer fluids contain aqueous based compositions which contain at least one alkali metal formate and at least one thermally activated self-crosslinkable gel forming material, wherein the packer fluid forms a thermal insulating fully hydrated gel once thermally activated.

Abstract: A method for use within a subterranean formation penetrated by a wellbore includes introducing a thixotropic agent into the well and introducing a cement slurry into the well. The method includes forming a thixotropic cement slurry downhole, including mixing the cement slurry and the thixotropic agent downhole.

Abstract: A well cementing composition comprises an hydraulic cement and flexible, acrylonitrile-butadiene copolymer particulate material. A method of cementing a well comprises mixing the composition with sufficient water, and optionally, other additives to form a pumpable slurry, and pumping the slurry into the well and allowing it to set.

Abstract: A method of servicing a wellbore in contact with a subterranean formation comprising viscosifying a cement composition comprising a metal oxide and a soluble salt, placing the viscosified cement composition in the wellbore, and allowing the composition to set. A method of cementing a wellbore comprising preparing a cement composition comprising magnesium oxide, a chloride or phosphate salt, and a quaternary material, placing the cementitious composition into the wellbore, and allowing the cementitious composition to set. A method of viscosifying a Sorel cement comprising contacting the cement composition with quaternary material.

Abstract: The problem of fiber or particle settling in well cement slurries is addressed by providing a fluid containing two fiber components of differing properties. Such a well treatment fluid, comprising a base fluid; a first fiber component that it substantially more dense than the base fluid; and a second fiber component that has a density close to that of the base fluid and is relatively flexible.

Abstract: Methods for performing cementing operations in a subterranean zone under high temperature conditions include forming a cementing composition having a density of less than about 10.5 pounds per gallon, pumping the cementing composition into the subterranean zone by way of the well bore and allowing the cementing composition to set therein. The cementing composition includes calcium aluminate, water, and a lightweight additive having a specific gravity of less than about 0.70.

Abstract: The present invention provides settable compositions that comprise water and cement kiln dust. The settable compositions optionally may comprise an additive that comprises at least one of the following group: fly ash; shale; slag cement; zeolite; metakaolin; and combinations thereof. The settable compositions optionally may be foamed with a gas. Methods of cementing also are provided that comprise: providing the settable composition; introducing the settable composition into a location to be cemented; and allowing the settable composition to set therein. The location to be cemented may be above ground or in a subterranean formation.

Abstract: An embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive, wherein the extended settable composition is capable of remaining in a pumpable fluid state for at least about 1 day; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set. Another embodiment of the present invention includes a method of cementing in a subterranean formation comprising: providing an extended settable composition comprising hydraulic cement, cement kiln dust, water, and a set retarding additive; storing the extended settable composition; adding a cement set accelerator to the extended settable composition; introducing the extended settable composition into a well bore; and allowing the extended settable composition to set.

Abstract: Novel well cement compositions are provided. Exemplary embodiments of the well cement compositions comprise water, a cement and a fluid loss control additive comprising a graft polymer. The graft polymer comprises a backbone comprising a lignite. The graft polymer further comprises grafted monomers selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid, vinylphosphonic acid, diallyldimethylammonium chloride and salts thereof.

Abstract: Improved fluid loss control additives for use in cement compositions are provided. The improved fluid loss control additives and cement compositions are suitable for use in surface and subterranean applications. The improved fluid loss control additives and cement compositions may be particularly useful for subterranean well completion and remedial operations, such as primary cementing, e.g., cementing casings and liners in well bores, including those in production wells, which include multi-lateral subterranean wells. They also may be useful for surface cementing operations, including construction cementing operations. Examples of compositions include fluid loss control additives.

Abstract: Cement compositions comprising an improved fluid loss control additive are provided. The cement compositions are suitable for use in surface and subterranean applications. The cement compositions may be particularly useful for subterranean well completion and remedial operations, such as primary cementing, e.g., cementing casings and liners in well bores, including those in production wells, which include multi-lateral subterranean wells. They also may be useful for surface cementing operations, including construction cementing operations. Examples of compositions include cement compositions.

Abstract: Set retarders of copolymers of at least one polymerizable ethylenically unsaturated monomer and at least one alkoxylated sulfate, phosphate or ketonic salt are capable of delaying the hardening of a cementitious slurry when introduced into a subterranean formation until a downhole temperature greater than or equal to 500° F. is obtained, even in the absence of an intensifier.

Abstract: A method of servicing a wellbore in a subterranean formation, comprising preparing a cement composition comprising water, a cementitious material, and a gas hydrate inhibitor, and placing the cement composition in the wellbore. A cement composition comprising water, a cementitious material, and a gas hydrate inhibitor.

Abstract: A method of serving a wellbore comprising placing a slurry composition comprising an alkaline metal oxide, a chloride or phosphate salt, water, glass beads and a foaming agent into a wellbore and allowing the composition to set. A method of servicing a wellbore comprising foaming a slurry comprising magnesium oxide, water, a chloride or phosphate salt, and glass beads, wherein the slurry has a density of from about 4 to about 12 pounds per gallon, placing the slurry in a wellbore, and allowing the composition to set. A method of temporarily plugging a wellbore comprising placing in the wellbore a cement slurry comprising magnesium oxide, water, a chloride or phosphate salt, a foaming agent and beads, wherein the slurry has a density of from about 4 to about 12 pounds per gallon, allowing the composition to set, and removing the composition by contacting the set composition with acid.

Abstract: Methods of cementing in a subterranean formation are provided. An exemplary embodiment comprises introducing a cement composition into a subterranean formation. The cement composition comprises water, a cement and a fluid loss control additive comprising a graft polymer. The graft polymer comprises a backbone comprising a lignite. The graft polymer further comprises grafted monomers selected from the group consisting of 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, acrylic acid, vinylphosphonic acid, diallyldimethylammonium chloride and salts thereof.

Abstract: The present invention provides settable compositions that comprise water and cement kiln dust. The settable compositions optionally may comprise an additive that comprises at least one of the following group: fly ash; shale; slag cement; zeolite; metakaolin; and combinations thereof. The settable compositions optionally may be foamed with a gas. Methods of cementing also are provided that comprise: providing the settable composition; introducing the settable composition into a location to be cemented; and allowing the settable composition to set therein. The location to be cemented may be above ground or in a subterranean formation.

Abstract: The prevention of latex inversion in saltwater cement compositions for use in subterranean formations by inclusion of a combination of latex stabilizers and associated methods of cementing. Saltwater cement compositions comprising saltwater, a cement, a latex, a first latex stabilizer comprising a surfactant having the formula: R—O—(OCH2CH2)mXM wherein R is an alkyl group having in the range of from about 10 carbons to about 20 carbons, m is an integer in the range of from about 10 to about 40, X is OSO3 or SO3, and M is a compatible cation, and a second latex stabilizer comprising an alcohol ether sulfate having the formula: R1—O—(OCH2CH2)nOSO3M wherein R1 is an alkyl group having in the range of from about 4 carbons to about 12 carbons, n is an integer in the range of from about 1 to about 10, and M is a compatible cation.

Abstract: Methods of retarding the setting of a cement composition comprise including one or more secondary amines substituted with a carboxyl group or salts thereof (e.g., 3-hydroxy N,N?-iminodisuccinic acid) in the cement composition. The inclusion of such materials in cement compositions may be highly beneficial. In wellbores having BHCT's of less than or equal to about 250° F., the use of the secondary amine as the set retarder ensures that the thickening time of the cement composition is sufficient to allow the cement composition to be pumped to its desired downhole location. Further, the secondary amine may be used in combination with conventional set retarders to enhance the ability of those retarders to increase the thickening time of the cement composition at higher BHCT's, e.g., from about 250° F. to about 525° F.

Abstract: A method of servicing a wellbore in contact with a subterranean formation comprising placing in the wellbore a composition comprising a metal oxide, a soluble salt, a surfactant and an oleaginous fluid, and allowing the composition to set. A method of cementing a wellbore comprising placing a first composition comprising magnesium oxide, a chloride or phosphate salt, an organophilic surfactant and an oleaginous fluid into a wellbore, allowing the composition to set, placing a second cementitious composition into the wellbore, and allowing the second cementitious composition to set. A method of servicing a wellbore comprising placing in the wellbore a composition comprising magnesium oxide, magnesium chloride, an organophilic surfactant, water and an oleaginous fluid wherein the organophilic surfactant is present in an amount of from about 0.

Abstract: Cementitious compositions are provided that can be use in drilling oil and gas well applications. The compositions include a source of hydraulically settable cement, calcium carbonate, free lime and alkali ions, calcium sulfate and an organic component. Methods for cementing a casing and liners and for remedial operations such as plugging back and squeeze cementing are also provided.

Abstract: Settable drilling fluids that comprise an aqueous-based drilling fluid and cement kiln dust. Methods of cementing in a subterranean formation that comprise providing a settable drilling fluid comprising an aqueous-based drilling fluid and cement kiln dust, introducing the settable drilling fluid into a subterranean formation, and allowing the settable drilling fluid to set in the subterranean formation. Methods of converting an aqueous-based drilling fluid to a settable drilling fluid that comprise providing the aqueous-based drilling fluid, and adding cement kiln dust to the aqueous-based drilling fluid to form the settable drilling fluid. Methods of drilling a well bore and cementing a well bore that comprise drilling a well bore, circulating an aqueous-based drilling fluid in the well bore during the step of drilling the well bore, adding cement kiln dust to the aqueous-based drilling fluid to form a settable drilling fluid, and allowing the settable drilling fluid to set in the well bore.

Abstract: The present invention provides cement compositions that comprise water, high alumina cement, a soluble phosphate, and cement kiln dust. The cement compositions optionally may be foamed with a gas. Methods of cementing also are provided that comprise: providing the cement composition; introducing the cement composition into a location to be cemented; and allowing the cement composition to set therein. The location to be cemented may be above ground or in a subterranean formation.

Abstract: A delayed gelling system useful in conformance control in the production of petroleum from subterranean formations, especially low permeability formations, is disclosed. The gelling system comprises a basic silica sol, an activator comprising a hydroxyl donor, and an optional syneresis inhibitor. In the disclosed method of using the gelling system, the gelling system may be pumped into formations with excessive water and/or gas production and thermally activated in the formation at downhole conditions to form a hard gel to reduce water and/or gas production.

Abstract: A method of cementing a wellbore comprising preparing a cement composition comprising a water-soluble aromatic sulfonated polymer, and placing the cement composition into the wellbore, wherein the cement composition develops a compressive strength of greater than about zero in less time than a similar cement composition having a comparable thickening time and lacking a water-soluble aromatic sulfonated polymer. A cement composition comprising a water-soluble aromatic sulfonated polymer, wherein the cement composition develops a compressive strength of greater than about zero in less time than a similar cement composition having comparable thickening time and lacking a water-soluble aromatic sulfonated polymer.

Abstract: Cementitious compositions are provided that can be use in drilling oil and gas well applications. The compositions include a source of hydraulically settable cement, calcium carbonate, free lime and alkali ions, calcium sulfate and an organic component. Methods for cementing a casing and liners and for remedial operations such as plugging back and squeeze cementing are also provided.

Abstract: Embodiments of the present invention are directed to defoaming methods and compositions for well treatment fluids. An exemplary embodiment of the present invention provides a method of treating a subterranean formation, comprising introducing a treatment fluid comprising a liquid and a defoaming composition into a subterranean formation, the defoaming composition comprising an amide of carboxylic acid, a polypropylene glycol, an ethoxylated and propoxylated fatty alcohol, an ethoxylated alcohol comprising from 3 carbons to 6 carbons, and a hydrophobic silica in an amount of up to about 3% by weight of the defoaming composition.

Abstract: A polymeric fluid loss additive for hydraulic cement which includes a polymer component which exhibits delayed hydration. The fluid loss additive is suitable for use in cement slurries which may be subjected to elevated temperatures, as is common in oil and gas drilling operations. By way of the invention, cement slurries are provided which have improved fluid loss properties at high temperatures, while maintaining manageable rheologies that are conducive to mixing, pumping, and the like across a broad range of temperatures.

Abstract: A fluid loss additive for hydraulic cement which includes at least two highly hydrolyzed polyvinyl alcohol resins having different molecular weights, or a polyvinyl alcohol resin composition having a broad molecular weight distribution. The fluid loss additive is suitable for use in cement slurries which may be subjected to elevated temperatures, as is common in oil and gas drilling operations. By way of the invention, cement slurries are provided which have improved fluid loss properties at high temperatures, while maintaining manageable rheologies that are conducive to mixing, pumping, and the like across a broad range of temperatures.

Abstract: Methods and compositions for wellbore treating fluids, especially cementitious compositions that include interground cement clinker and zeolite, with and without gypsum.

Abstract: Improved casing strings, and methods of using improved casing strings in subterranean cementing operations, are provided. An example of an apparatus is a pipe string comprising at least one pipe section and a delivery system of an activator. Another example of an apparatus is a pipe string comprising at least one pipe section and a delivery system of a set retarder. An example of a method is a method of cementing in a subterranean formation. Other examples of methods are methods of cementing in a subterranean formation comprising a well bore.