Piezoelectric Patents (Class 204/192.18)
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Patent number: 12217949Abstract: A method of sputtering a layer on a substrate includes positioning an HEDP magnetron in a vacuum with an anode, cathode target, magnet assembly, substrate, and feed gas; applying a plurality of unipolar negative direct current (DC) voltage pulses from a pulse power supply to a pulse converting network (PCN), wherein the PCN comprises at least one inductor and at least one capacitor; and adjusting an amplitude, pulse duration, and frequency associated with the plurality of unipolar negative DC voltage pulses and adjusting a value of at least one of the at least one inductor and the at least one capacitor, thereby causing a resonance mode associated with the PCN. The substrate is operatively coupled to ground by a first diode, thereby attracting positively charged ions sputtered from the cathode target and plasma to the substrate. A corresponding apparatus and computer-readable medium are also disclosed.Type: GrantFiled: October 6, 2021Date of Patent: February 4, 2025Assignee: IonQuest Corp.Inventor: Bassam Hanna Abraham
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Patent number: 12119225Abstract: An oxide semiconductor sputtering target used in a sputtering process to deposit an active layer of a TFT. The oxide semiconductor sputtering target is formed from a material based on a composition of In, Sn, Ga, Zn, and O. The material contains gallium oxide, tin oxide, zinc oxide, and indium oxide. The In, Sn, Ga, and Zn contents are in ranges of 60% to 80%, 0.5% to 8%, 5% to 15%, and 10% to 30% by weight with respect to the weight of In+Sn+Ga+Zn, respectively. A method of fabricating a TFT includes depositing an active layer using the oxide semiconductor sputtering target. Such a TFT is used in a liquid crystal display (LCD), an organic light-emitting display, an electroluminescence display, and the like.Type: GrantFiled: June 15, 2022Date of Patent: October 15, 2024Assignee: KV Materials Co., Ltd.Inventors: Shinhyuk Kang, Jeonghyun Moon, Kangmin Ok
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Patent number: 11990890Abstract: A resonator includes a base; and at least three vibrating arms having first ends connected to a front end of the base and second ends that are open ends spaced away from the front end. Each vibrating arm includes an arm portion having a part that extends from the fixed end in a direction toward the open end with a constant width and a mass-adding portion that is connected to a tip of the arm portion and has a larger width than the arm portion. An interval between the mass-adding portions is larger than an interval between the arm portions for any two vibrating arms that are adjacent to each other.Type: GrantFiled: February 22, 2021Date of Patent: May 21, 2024Assignee: MURATA MANUFACTURING CO., LTD.Inventors: Yoshihisa Inoue, Ryota Kawai, Yuichi Goto
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Patent number: 11930714Abstract: Provided is a piezoelectric film capable of realizing an electroacoustic conversion film or the like in which the durability is high and a sufficient sound pressure with respect to an input operating voltage is obtained. The piezoelectric film is a piezoelectric film including a polymer-based piezoelectric composite material which contains piezoelectric particles in a matrix containing a polymer material, and electrode layers which are provided on both surfaces of the polymer-based piezoelectric composite material, in which in a case where a cross section of the piezoelectric film in a thickness direction is observed with a scanning electron microscope, the polymer-based piezoelectric composite material is divided into two equal regions in the thickness direction, and void volumes of the two regions are measured, a ratio of the void volume obtained by dividing the void volume of the region with a larger void volume by the void volume of the region with a smaller void volume is 1.2 or greater.Type: GrantFiled: December 15, 2021Date of Patent: March 12, 2024Assignee: FUJIFILM CorporationInventor: Yoshinori Tamada
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Patent number: 11882767Abstract: A method for producing an ultrasonic transducer or ultrasonic transducer array, the method comprising providing or depositing a layer of piezoelectric material on a substrate. The piezoelectric material is a doped, co-deposited or alloyed piezoelectric material. The piezoelectric material comprises: a doped, co-deposited or alloyed metal oxide or metal nitride, the metal oxide or metal nitride being doped, co-deposited or alloyed with vanadium or a compound thereof; or zinc oxide doped, co-deposited or alloyed with a transition metal or a compound thereof. Optionally, the deposition of the layer of piezoelectric material is by sputter coating, e.g. using a sputtering target that comprises a doped or alloyed piezoelectric material. In examples, the layer of piezoelectric material is deposited onto the substrate using high power impulse magnetron sputtering (HIPIMS). Further enhancement may be obtained using substrate biasing (e.g. DC and/or RF) during deposition of the layer of piezoelectric material.Type: GrantFiled: February 27, 2019Date of Patent: January 23, 2024Assignee: Novosound Ltd.Inventors: David Hughes, Desmond Gibson, Daniel Irving
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Patent number: 11801676Abstract: A piezoelectric element includes an upper electrode, a lower electrode, and a piezoelectric body disposed between the upper electrode and the lower electrode. The piezoelectic body contains lead zirconate titanate. The piezoelectric element also includes a seed layer containing lead disposed between the lower electrode and the piezoelectric body. The seed layer has an amorphous structure at least over an entire surface layer portion on the piezoelectric body side.Type: GrantFiled: July 24, 2020Date of Patent: October 31, 2023Assignee: RICOH COMPANY, LTD.Inventors: Satoshi Mizukami, Masahiro Hayashi, Toshiaki Masuda
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Patent number: 11605775Abstract: In a piezoelectric device, electrode layers are spaced apart from each other in the direction of the normal thereto. A first piezoelectric layer is interposed between two electrode layers of electrode layers in the direction of the normal. A second piezoelectric layer is provided on an opposite side of the first piezoelectric layer from a base portion. The second piezoelectric layer is interposed between two electrode layers of the electrode layers in the direction of the normal. The half-width of a rocking curve measured by X-ray diffraction for a lattice plane of the first piezoelectric layer substantially parallel to a first main surface is smaller than a half-width for the second piezoelectric layer. The piezoelectric constant of a material defining the first piezoelectric layer is smaller than the piezoelectric constant of a material defining the second piezoelectric layer.Type: GrantFiled: June 22, 2020Date of Patent: March 14, 2023Assignee: MURATA MANUFACTURING CO., LTD.Inventors: Yutaka Kishimoto, Shinsuke Ikeuchi, Masayuki Suzuki, Fumiya Kurokawa
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Patent number: 11600766Abstract: A method for manufacturing a monocrystalline piezoelectric material layer includes providing a donor substrate made of the piezoelectric material, providing a receiving substrate, transferring a so-called “seed layer” of the donor substrate onto the receiving substrate, and using epitaxy of the piezoelectric material on the seed layer until the desired thickness for the monocrystalline piezoelectric layer is obtained.Type: GrantFiled: December 21, 2016Date of Patent: March 7, 2023Assignee: SoitecInventors: Bruno Ghyselen, Ionut Radu, Jean-Marc Bethoux
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Patent number: 11381212Abstract: Bulk acoustic wave resonator structures include a bulk layer with inclined c-axis hexagonal crystal structure piezoelectric material supported by a substrate. The bulk layer may be prepared without first depositing a seed layer on the substrate. The bulk material layer has a c-axis tilt of about 32 degrees or greater. The bulk material layer may exhibit a ratio of shear coupling to longitudinal coupling of 1.25 or greater during excitation. A method for preparing a crystalline bulk layer having a c-axis tilt includes depositing a bulk material layer directly onto a substrate at an off-normal incidence. The deposition conditions may include a pressure of less than 5 mTorr and a deposition angle of about 35 degrees to about 85 degrees.Type: GrantFiled: March 20, 2019Date of Patent: July 5, 2022Assignee: Qorvo US, Inc.Inventors: Derya Deniz, Robert Kraft, John Belsick
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Patent number: 11367650Abstract: Substrates for microelectronic radiofrequency devices may include a substrate comprising a semiconductor material. Trenches may be located in an upper surface of the substrate, at least some of the trenches including a filler material located within the respective trench. A resistivity of the filler material may be 10 kOhms·cm or greater. A piezoelectric material may be located on or above the upper surface of the substrate. Methods of making substrates for microelectronic radiofrequency devices may involve forming trenches in an upper surface of a substrate including a semiconductor material. A filler material may be placed in at least some of the trenches, and a piezoelectric material may be placed on or above the upper surface of the substrate.Type: GrantFiled: December 2, 2020Date of Patent: June 21, 2022Assignee: SoitecInventors: Eric Desbonnets, Ionut Radu, Oleg Kononchuk, Jean-Pierre Raskin
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Patent number: 11056532Abstract: Techniques are disclosed for monolithic co-integration of thin-film bulk acoustic resonator (TFBAR, also called FBAR) devices and III-N semiconductor transistor devices. In accordance with some embodiments, one or more TFBAR devices including a polycrystalline layer of a piezoelectric III-N semiconductor material may be formed alongside one or more III-N semiconductor transistor devices including a monocrystalline layer of III-N semiconductor material, over a commonly shared semiconductor substrate. In some embodiments, either (or both) the monocrystalline and the polycrystalline layers may include gallium nitride (GaN), for example. In accordance with some embodiments, the monocrystalline and polycrystalline layers may be formed simultaneously over the shared substrate, for instance, via an epitaxial or other suitable process. This simultaneous formation may simplify the overall fabrication process, realizing cost and time savings, at least in some instances.Type: GrantFiled: July 1, 2016Date of Patent: July 6, 2021Assignee: Intel CorporationInventors: Han Wui Then, Marko Radosavljevic, Sansaptak Dasgupta, Paul B. Fischer, Sanaz K. Gardner, Bruce A. Block
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Patent number: 10924086Abstract: A device including a piezoelectric substrate, an interdigital transducer (IDT), and an antireflective structure is disclosed herein. The piezoelectric substrate has a front-side surface and a smoothed back-side surface. The IDT is on the front-side surface of the piezoelectric substrate. The antireflective structure is over at least a portion of the smoothed back-side surface of the piezoelectric substrate. By having the antireflective structure on at least a portion of the smoothed back-side surface of the piezoelectric substrate, reflection of spurious bulk acoustic waves toward the front-side surface of the piezoelectric substrate can be reduced and/or eliminated to lessen interference with surface acoustic waves.Type: GrantFiled: October 16, 2017Date of Patent: February 16, 2021Assignee: Qorvo US, Inc.Inventors: Marc Solal, Charles E. Carpenter, Timothy Daniel, Shogo Inoue, Tom Moonlight
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Patent number: 10525265Abstract: A microphone system including a first sensor configured to output a first signal based on an ambient sound relative to a recipient of the system, a second sensor configured to output a second signal corresponding to a noise reference, and first signal processing circuitry configured to process the first signal based on the second signal and output a third signal based on the processed first signal, wherein the system is configured to limit a gain of the third signal based on the presence of impulsive energy in the second signal.Type: GrantFiled: December 8, 2015Date of Patent: January 7, 2020Assignee: Cochlear LimitedInventors: Florent Maxime Hubert-Brierre, Thomas Leroux
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Patent number: 10476463Abstract: A bulk acoustic wave resonator includes a substrate, a lower electrode connection member, a lower electrode, a piezoelectric layer, an upper electrode, an upper electrode connection member, and a dielectric layer in which the lower electrode, the piezoelectric layer, and the upper electrode are embedded. The lower electrode, the piezoelectric layer, and the upper electrode constitute a resonant portion. An extension portion extends away from either the lower electrode or the upper electrode to protrude outwardly from the resonant portion. A capacitor portion is constituted by the extension portion, a portion of the upper electrode connection member disposed above the extension portion, and a portion of the dielectric layer disposed between the extension portion and the portion of the upper electrode connection member disposed above the extension portion.Type: GrantFiled: November 17, 2017Date of Patent: November 12, 2019Assignee: Samsung Electro-Mechanics Co., Ltd.Inventors: Tae Hun Lee, Chang Hyun Lim, Tae Yoon Kim, Moon Chul Lee
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Patent number: 10330642Abstract: Lateral boundaries of a fluidic passage of a fluidic device incorporating at least one BAW resonator structure are fabricated with photosensitive materials (e.g., photo definable epoxy, solder mask resist, or other photoresist), allowing for high aspect ratio, precisely dimensioned walls. Resistance to delamination and peeling between a wall structure and a base structure is enhanced by providing a wall structure that includes a thin footer portion having a width that exceeds a width of an upper wall portion extending upward from the footer portion, and/or by providing a wall structure arranged over at least one anchoring region of a base structure. Anchoring features may include recesses and/or protrusions.Type: GrantFiled: December 13, 2016Date of Patent: June 25, 2019Assignee: QORVO US, INC.Inventors: Rio Rivas, Vincent K. Gustafson
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Patent number: 10291203Abstract: A MEMS resonator is provided with a high quality factor and lower motional impedance. The MEMS resonator includes a silicon layer having opposing surfaces, a piezoelectric layer above one of the surfaces of the silicon layer, and a pair of electrodes disposed on opposing surfaces of the piezoelectric layer, respectively. Moreover, the piezoelectric layer has a crystallographic axis that extends at an angle relative to the vertical axis of the MEMS resonator.Type: GrantFiled: July 12, 2016Date of Patent: May 14, 2019Assignee: MURATA MANUFACTURING CO., LTD.Inventor: Ville Kaajakari
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Patent number: 10084425Abstract: An acoustic resonator comprises a first electrode and second electrode comprising a plurality of sides. At least one of the sides of the second electrode comprises a cantilevered portion. A piezoelectric layer is disposed between the first and second electrodes. A bridge is disposed adjacent to one of the sides of the second electrode.Type: GrantFiled: May 29, 2015Date of Patent: September 25, 2018Assignee: Avago Technologies General IP (Singapore) Pte. Ltd.Inventors: Paul Bradley, Robert Thalhammer, Thomas Faust
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Patent number: 10063210Abstract: Systems and methods for growing hexagonal crystal structure piezoelectric material with a c-axis that is tilted (e.g., 25 to 50 degrees) relative to normal of a face of a substrate are provided. A deposition system includes a linear sputtering apparatus, a translatable multi-aperture collimator, and a translatable substrate table arranged to hold multiple substrates, with the substrate table and/or the collimator being electrically biased to a nonzero potential. An enclosure includes first and second deposition stations each including a linear sputtering apparatus, a collimator, and a deposition aperture.Type: GrantFiled: October 13, 2016Date of Patent: August 28, 2018Assignee: QORVO US, INC.Inventors: Kevin McCarron, John Belsick
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Patent number: 9995674Abstract: A laser vibrometer for measurement of ambient chemical species includes a laser that produces a beam that is split into a reference readout beam and a signal readout beam. A probe laser beam is tuned to an absorption feature of a molecular transition, and generates acoustic signals when incident on a gaseous species via the photo acoustic effect. The scattered acoustic signals are incident on a thin membrane that vibrates. The readout laser beam reflected from the vibrating membrane is mixed with the reference beam at the surface of a photo-EMF detector. Interferrometric fringes are generated at the surface of the photo-EMF detector. Electric current is generated in the photo-EMF detector when the fringes are in motion due to undulations in the signal readout beam imparted by the vibrating membrane. A highly sensitive photo-EMF detector is capable of detecting picoJoules or less laser energy generated by vibrating processes.Type: GrantFiled: December 29, 2014Date of Patent: June 12, 2018Assignee: THE UNITED STATES OF AMERICA AS REPRESENTED BY THE ADMINISTRATOR OF NASA.Inventor: Narasimha S. Prasad
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Patent number: 9994950Abstract: A method for depositing a piezoelectric film may be provided containing AlN on a substrate by means of magnetron sputtering of at least two targets—of which at least one target contains aluminum—within a vacuum chamber, into which a mixture of gases containing at least reactive nitrogen gas and an inert gas is introduced, and during which magnetron sputtering the unipolar pulse mode and the bipolar pulse mode are alternately used. A film may be provided containing AlN of formula AlXNYOZ, where (0.1?X?1.2); (0.1?Y?1.2) and (0.001?Z?0.1).Type: GrantFiled: June 24, 2014Date of Patent: June 12, 2018Assignees: FRAUNHOFER-GESELLSCHAFT ZUR FÖRDERUNG DER ANGEWANDTEN FORSCHUNG E.V., TU DRESDENInventors: Hagen Bartzsch, Daniel Glöß, Peter Frach, Stephan Barth
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Patent number: 9998087Abstract: An integrated structure of power amplifier and acoustic wave device comprises: a compound semiconductor epitaxial substrate including an epitaxial structure formed on a compound semiconductor substrate, a power amplifier upper structure formed on a top-side of a left part of the compound semiconductor epitaxial substrate, and a film bulk acoustic resonator formed on the top-side of a right part of the compound semiconductor epitaxial substrate; wherein the left part of the compound semiconductor epitaxial substrate and the power amplifier upper structure form a power amplifier; the right part of the compound semiconductor epitaxial substrate and the film bulk acoustic resonator form an acoustic wave device; the integrated structure of power amplifier and acoustic wave device on the same compound semiconductor epitaxial substrate is capable of reducing the component size, optimizing the impedance matching, and reducing the signal loss between power amplifier and acoustic wave device.Type: GrantFiled: January 25, 2017Date of Patent: June 12, 2018Assignee: WIN SEMICONDUCTORS CORP.Inventors: Shu-Hsiao Tsai, Re Ching Lin, Pei-Chun Liao, Cheng-Kuo Lin, Yung-Chung Chin
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Patent number: 9922809Abstract: Systems and methods for growing hexagonal crystal structure piezoelectric material with a c-axis that is tilted (e.g., 25 to 50 degrees) relative to normal of a face of a substrate are provided. A deposition system includes a linear sputtering apparatus, a translatable multi-aperture collimator, and a translatable substrate table arranged to hold multiple substrates, with the substrate table and/or the collimator being electrically biased to a nonzero potential. An enclosure includes first and second deposition stations each including a linear sputtering apparatus, a collimator, and a deposition aperture.Type: GrantFiled: October 13, 2016Date of Patent: March 20, 2018Assignee: QORVO US, INC.Inventors: Kevin McCarron, John Belsick
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Patent number: 9902153Abstract: A method of making a piezoelectric film includes forming a PbTO3 (PTO) coating film by applying a precursor liquid of a coating film containing PTO as a main ingredient, forming a PTO amorphous layer containing lead titanate as a main ingredient by heating the PTO coating film at a heating temperature lower than a crystallization temperature at which the PTO coating film is crystalized, and forming, on the PTO amorphous layer, a piezoelectric thin-film layer having a main (100) orientation measured by X-ray analysis and containing lead zirconate titanate (PZT) as a main ingredient. The heating temperature is 300° C. or lower.Type: GrantFiled: July 22, 2015Date of Patent: February 27, 2018Assignee: RICOH COMPANY, LTD.Inventor: Xianfeng Chen
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Patent number: 9793129Abstract: A segmented edge protection shield for plasma dicing a wafer. The segmented edge protection shield includes an outer structure and a plurality of plasma shield edge segments. The outer structure defines an interior annular edge configured to correspond to the circumferential edge of the wafer. Each one of the plurality of plasma shield edge segments is defined by an inner edge and side edges. The inner edge is interior to and concentric to the annular edge of the outer structure. The side edges extend between the inner edge and the annular edge.Type: GrantFiled: May 20, 2015Date of Patent: October 17, 2017Assignee: Infineon Technologies AGInventors: Manfred Engelhardt, Michael Roesner, Georg Ehrentraut
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Patent number: 9758868Abstract: A substrate processing system includes a showerhead including a stem portion and a head portion. The stem portion is in fluid communication with a process gas source, and the head portion is arranged to provide process gases from the process gas source to a reaction volume of a processing chamber below the showerhead to generate plasma in the reaction volume. A suppressor is arranged above the head portion of the showerhead, extends from the stem portion toward sidewalls of the processing chamber, and is sealed against the sidewalls of the processing chamber or sealed against an enclosure surrounding the suppressor. The suppressor, the sidewalls, and a top surface of the processing chamber, the suppressor and the enclosure, or the suppressor, the enclosure, and the top surface define a partitioned volume of the processing chamber above the showerhead. The partitioned volume is in fluid communication with a purge gas source.Type: GrantFiled: March 10, 2016Date of Patent: September 12, 2017Assignee: LAM RESEARCH CORPORATIONInventors: Patrick Girard Breiling, Ramesh Chandrasekharan, Edmund Minshall, Colin Smith, Andrew Duvall, Karl Leeser
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Patent number: 9347128Abstract: A method for forming a dielectric thin film that forms a PZT thin film having a (100)/(001) orientation. After a seed layer is formed by adhering PbO gas to a surface of a substrate, a voltage is applied to a target of lead zirconate titanate (PZT) and perform sputtering, while the substrate is heated inside of an evacuated vacuum chamber. Then, a PZT thin film is formed on the surface of the substrate. Because Pb and O are supplied from the seed layer, a PZT film having a (001)/(100) orientation can be formed without lack of Pb.Type: GrantFiled: April 5, 2013Date of Patent: May 24, 2016Assignee: ULVAC, INC.Inventors: Isao Kimura, Takehito Jinbo, Hiroki Kobayashi, Youhei Endou, Youhei Oonishi
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Publication number: 20150136586Abstract: The invention relates to a method for producing a polycrystalline ceramic film on a surface (12) of a substrate (10), in which a particle stream is directed onto the surface (12) and the ceramic film is formed by deposition of the particles onto the surface (12), wherein the particle stream is directed by means of a diaphragm onto the surface (12) along a preferred direction until a first specified layer thickness is reached, the preferred direction and a surface normal of the surface (12) enclosing a specified angle of incidence. According to the invention, the diaphragm is removed from the particle stream after the specified layer thickness has been reached, and additional particles are directed onto the surface (12) until a specified second layer thickness has been reached.Type: ApplicationFiled: June 18, 2013Publication date: May 21, 2015Inventors: Matthias Schreiter, Wolfram Wersing
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Patent number: 9017525Abstract: In a method for forming a metal fluoride film, a metal fluoride film is formed on a substrate by sputtering using a metal target and a mixed gas containing O2 gas and a reactive gas being a fluorocarbon gas.Type: GrantFiled: June 14, 2012Date of Patent: April 28, 2015Assignee: Canon Kabushiki KaishaInventor: Hideo Akiba
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Patent number: 8992744Abstract: A method of fabricating by co-sputtering deposition a lanthanoid aluminate film with enhanced electrical insulativity owing to suppression of deviation in composition of the film is disclosed. Firstly within a vacuum chamber, hold two separate targets, one of which is made of lanthanoid aluminate (LnAlO3) and the other of which is made of aluminum oxide (Al2O3). Then, transport and load a substrate into the vacuum chamber. Next, introduce a chosen sputtering gas into this chamber. Thereafter, perform sputtering of both the targets at a time to thereby form a lanthanoid aluminate film on the substrate surface. This film is well adaptable for use as ultra-thin high dielectric constant (high-k) gate dielectrics in highly miniaturized metal oxide semiconductor (MOS) transistors.Type: GrantFiled: July 28, 2011Date of Patent: March 31, 2015Assignee: Kabushiki Kaisha ToshibaInventors: Tsunehiro Ino, Akira Takashima
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Publication number: 20150022274Abstract: A piezoelectric film producing process includes depositing a piezoelectric body in a mixed atmosphere of N2 gas and Ar gas by using a sputtering method, using an Al—Cu alloy as deposition material.Type: ApplicationFiled: July 14, 2014Publication date: January 22, 2015Inventors: Takashi YAMAZAKI, Osamu IWAMOTO
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Patent number: 8845867Abstract: A method of manufacturing a magnetoresistive (MR) effective element having a pair of magnetic layers and a nonmagnetic intermediate layer including a ZnO film, wherein a relative angle of magnetization directions of the pair of magnetic layers varies according to an external magnetic field. The method includes a step for introducing a mix gas of oxygen gas and argon gas into a depressurized chamber, wherein a first target of ZnO, a second target of Zn and a substrate having a right-below layer are disposed in the chamber, and a step for depositing the ZnO film on the right-below layer by applying each of a first and second direct current (DC) application power to spaces between the first and second targets and the substrate respectively after the mix gas introducing step, wherein the first and second targets are set at negative potential, and the substrate is set at positive potential.Type: GrantFiled: December 9, 2008Date of Patent: September 30, 2014Assignee: TDK CorporationInventors: Shinji Hara, Yoshihiro Tsuchiya, Tsutomu Chou, Tomihito Mizuno
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Publication number: 20140265734Abstract: A ferroelectric device comprising a substrate; a textured layer; a first electrode comprising a thin layer of metallic material having a crystal lattice structure divided into granular regions; a seed layer; the seed layer being epitaxially deposited so as to form a column-like structure on top of the granular regions of the first electrode; at least one ferroelectric material layer exhibiting spontaneous polarization epitaxially deposited on the seed layer; the ferroelectric material layer, the seed layer, and first electrode each having granular regions in which column-like structures produce a high degree of polarization normal to the growth plane and a method of making.Type: ApplicationFiled: March 19, 2014Publication date: September 18, 2014Applicant: U.S. Army Research Laboratory ATTN: RDRL-LOC-IInventors: Glen R. Fox, Ronald G. Polcawich, Daniel M. Potrepka, Luz M. Sanchez
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Publication number: 20140246305Abstract: A method of fabricating a rare-earth element doped piezoelectric material having a first component, a second component and the rare-earth element. The method includes: providing a substrate; initially flowing hydrogen over the substrate; after the initially flowing of the hydrogen over the substrate, flowing the first component to form the rare-earth element doped piezoelectric material over a surface of a single target, the target comprising the rare-earth metal in a certain atomic percentage; and sputtering the rare-earth element doped piezoelectric material from the target on the substrate.Type: ApplicationFiled: May 15, 2014Publication date: September 4, 2014Applicant: Avago Technologies General IP (Singapore) Pte. Ltd.Inventor: John D. Larson, III
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Patent number: 8673121Abstract: In accordance with a representative embodiment, a method, comprises: providing a substrate; forming a first piezoelectric layer having a compression-negative (CN) polarity over the substrate; and forming a second piezoelectric layer having a compression-positive (CP) over the substrate and adjacent to the first piezoelectric layer.Type: GrantFiled: March 23, 2012Date of Patent: March 18, 2014Assignee: Avago Technologies General IP (Singapore) Pte. Ltd.Inventors: John D. Larson, III, Jyrki Kaitila, Stefan Bader
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Patent number: 8597722Abstract: A method for using an integrated battery and device structure includes using two or more stacked electrochemical cells integrated with each other formed overlying a surface of a substrate. The two or more stacked electrochemical cells include related two or more different electrochemistries with one or more devices formed using one or more sequential deposition processes. The one or more devices are integrated with the two or more stacked electrochemical cells to form the integrated battery and device structure as a unified structure overlying the surface of the substrate. The one or more stacked electrochemical cells and the one or more devices are integrated as the unified structure using the one or more sequential deposition processes. The integrated battery and device structure is configured such that the two or more stacked electrochemical cells and one or more devices are in electrical, chemical, and thermal conduction with each other.Type: GrantFiled: May 7, 2012Date of Patent: December 3, 2013Assignee: Sakti3, Inc.Inventors: Fabio Albano, Chia Wei Wang, Ann Marie Sastry
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Publication number: 20130228454Abstract: In order to obtain a ferroelectric thin film that is formed to have a predetermined thickness on a substrate, that have satisfactory crystallization and that achieves a high piezoelectric property, a method of manufacturing such a ferroelectric thin film and a method of manufacturing a piezoelectric element having such a ferroelectric thin film, when a dielectric material of a perovskite structure is formed into a film on the substrate, a predetermined amount of additive is mixed with PZT, and the concentration of the additive mixed is varied in the thickness direction of the thin film.Type: ApplicationFiled: October 26, 2011Publication date: September 5, 2013Inventor: Kenji Mawatari
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Publication number: 20130220799Abstract: A method for forming a dielectric thin film that forms a PZT thin film having a (100)/(001) orientation. After a seed layer is formed by adhering PbO gas to a surface of a substrate, a voltage is applied to a target of lead zirconate titanate (PZT) and perform sputtering, while the substrate is heated inside of an evacuated vacuum chamber. Then, a PZT thin film is formed on the surface of the substrate. Because Pb and O are supplied from the seed layer, a PZT film having a (001)/(100) orientation can be formed without lack of Pb.Type: ApplicationFiled: April 5, 2013Publication date: August 29, 2013Applicant: ULVAC, Inc.Inventor: ULVAC, Inc.
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Patent number: 8460519Abstract: Sputtering in a physical vapor deposition (PVD) chamber may, in one embodiment, utilize a target laterally offset from and tilted with respect to the substrate. In another aspect, target power may be reduced to enhance film protection. In yet another aspect, magnetron magnets may be relatively strong and well balanced to enhance film protection. In another aspect, a shutter may be provided to protect the substrate in start up conditions. Other embodiments are described and claimed.Type: GrantFiled: March 23, 2006Date of Patent: June 11, 2013Assignee: Applied Materials Inc.Inventors: Mengqi Ye, Zhendong Liu, Peijun Ding
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Patent number: 8330556Abstract: An acoustic resonator, comprises a substrate and a first passivation layer disposed over the substrate. The first passivation layer comprises a first layer of silicon carbide (SiC). The acoustic resonator further comprises a first electrode disposed over the passivation layer, a second electrode, and a piezoelectric layer disposed between the first and second electrodes. The acoustic resonator comprises a second passivation layer disposed over the second electrode. The second passivation layer comprises a second layer of silicon carbide (SiC).Type: GrantFiled: November 23, 2009Date of Patent: December 11, 2012Assignee: Avago Technologies Wireless IP (Singapore) Pte. Ltd.Inventors: Daniel J. Miller, Martha Johnson
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Patent number: 8288020Abstract: Provided are a piezoelectric thin film including a lead-free ferroelectric material and exhibiting high piezoelectric performance comparable to that of lead zirconate titanate (PZT), and a method of manufacturing the piezoelectric thin film. The piezoelectric thin film of the present invention comprises: a LaNiO3 film having a (001) orientation; a NaNbO3 film having a (001) orientation; and a (Bi, Na, Ba) TiO3 film having a (001) orientation. The LaNiO3 film, the NaNbO3 film, and the (Bi, Na, Ba)TiO3 film are laminated in this order.Type: GrantFiled: November 30, 2010Date of Patent: October 16, 2012Assignee: Panasonic CorporationInventors: Takakiyo Harigai, Hideaki Adachi, Eiji Fujii
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Patent number: 8192789Abstract: The present invention provides a method to design, manufacture and structure a multi-component energy device having a unified structure, wherein the individual components are chosen from the list consisting of electrochemical cells, photovoltaic cells, fuel-cells, capacitors, ultracapacitors, thermoelectric, piezoelectric, microelectromechanical turbines and energy scavengers. Said components are organized into a structure to achieve an energy density, power density, voltage range, current range and lifetime range that the single components could not achieve individually, i.e. to say the individual components complement each other. The individual components form a hybrid structure, wherein the elements are in electrical, chemical and thermal conduction with each other.Type: GrantFiled: November 6, 2009Date of Patent: June 5, 2012Assignee: Sakti3, Inc.Inventors: Fabio Albano, Chia Wei Wang, Ann Marie Sastry
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Publication number: 20120107557Abstract: A method for manufacturing a piezoelectric thin film including an aluminum nitride thin film containing scandium on a substrate, the method includes: sputtering step for sputtering aluminum and scandium under an atmosphere containing at least a nitrogen gas. In the sputtering step in the method according to the present invention, a scandium content rate falls within the range from 0.5% by atom to 50% by atom when a temperature of the substrate falls within the range from 5° C. to 450° C. during the sputtering step.Type: ApplicationFiled: June 30, 2010Publication date: May 3, 2012Applicants: DENSO CORPORATION, NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGYInventors: Morito Akiyama, Kazuhiko Kano, Akihiko Teshigahara
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Patent number: 8133362Abstract: A physical vapor deposition apparatus includes a vacuum chamber having side walls, a cathode inside the vacuum chamber, wherein the cathode is configured to include a sputtering target, a radio frequency power supply configured to apply power to the cathode, an anode inside and electrically connected to the side walls of the vacuum chamber, a chuck inside and electrically isolated from the side walls of the vacuum chamber, the chuck configured to support a substrate, a clamp configured to hold the substrate to the chuck, wherein the clamp is electrically conductive, and a plurality of conductive electrodes attached to the clamp, each electrode configured to compress when contacted by the substrate.Type: GrantFiled: February 26, 2010Date of Patent: March 13, 2012Assignee: FUJIFILM CorporationInventors: Jeffrey Birkmeyer, Youming Li, Steve Deming, Mats G. Ottosson
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Patent number: 8100513Abstract: A ferroelectric film having a columnar structure constituted by a plurality of columnar grains, and containing as a main component a perovskite oxide which has a composition expressed by a compositional formula A1+?[(ZrxTi1?x)1?yMy]Oz, where A represents one or more A-site elements including lead (Pb) as a main component, M represents one or more of vanadium (V), niobium (Nb), tantalum (Ta), and antimony (Sb) as one or more B-site elements, zirconium (Zr) and titanium (Ti) are also B-site elements, 0<x?0.7, 0.1?y?0.4, ? is approximately zero, z is approximately 3, and ? and z may deviate from 0 and 3, respectively, within ranges of ? and z in which the composition expressed by the compositional formula A1+?[(ZrxTi1?x)1?yMy]Oz can substantially form a perovskite structure.Type: GrantFiled: March 20, 2008Date of Patent: January 24, 2012Assignee: Fujifilm CorporationInventors: Takami Arakawa, Takamichi Fujii
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Patent number: 8012315Abstract: A method of fabricating by co-sputtering deposition a lanthanoid aluminate film with enhanced electrical insulativity owing to suppression of deviation in composition of the film is disclosed. Firstly within a vacuum chamber, hold two separate targets, one of which is made of lanthanoid aluminate (LnAlO3) and the other of which is made of aluminum oxide (Al2O3). Then, transport and load a substrate into the vacuum chamber. Next, introduce a chosen sputtering gas into this chamber. Thereafter, perform sputtering of both the targets at a time to thereby form a lanthanoid aluminate film on the substrate surface. This film is well adaptable for use as ultra-thin high dielectric constant (high-k) gate dielectrics in highly miniaturized metal oxide semiconductor (MOS) transistors.Type: GrantFiled: December 28, 2007Date of Patent: September 6, 2011Assignee: Kabushiki Kaisha ToshibaInventors: Tsunehiro Ino, Akira Takashima
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Patent number: 7997692Abstract: A process for producing a perovskite oxide having a composition expressed by the compositional formulas A(B, C)O3, and determined so as to satisfy the conditions (1), (2), and (3), 0.98<TF(PX)<1.01, (1) TF(ABO3)>1.0, and (2) TF(ACO3)<1.0, (3) where each of A, B, and C represents one or more metal elements, the main component of one or more A-site elements is bismuth, the composition of one or more B-site element represented by B is different from the composition of one or more B-site element represented by C, TF(PX) is the tolerance factor of the oxide expressed by the compositional formula A(B, C)O3, and TF(ABO3) and TF(ACO3) are respectively the tolerance factors of the oxides expressed by the compositional formulas ABO3 and ACO3.Type: GrantFiled: January 18, 2008Date of Patent: August 16, 2011Assignee: Fujifilm CorporationInventors: Yukio Sakashita, Tsutomu Sasaki
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Publication number: 20110180391Abstract: In accordance with a representative embodiment, a method of fabricating a piezoelectric material comprising a first component and a second component comprises: providing a substrate; flowing hydrogen over the substrate; flowing the first component to form the piezoelectric material over a target; and sputtering the piezoelectric material from the target on the substrate. In accordance with another representative embodiment, a method of fabricating a bulk acoustic wave (BAW) resonator comprises: forming a first electrode over a substrate; forming a seed layer over the substrate; and depositing a piezoelectric material having a compression-negative (CN) polarity. The depositing of the piezoelectric material comprises: flowing a first component of the piezoelectric material to form the piezoelectric material over a target comprising a second component of the piezoelectric material; and sputtering the piezoelectric material from the target to the substrate.Type: ApplicationFiled: January 22, 2010Publication date: July 28, 2011Applicant: Avago Technologies Wireless IP (Singapore) Pte. Ltd.Inventors: John Larson, III, Sergey Mishin
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Publication number: 20110143146Abstract: Provided are a piezoelectric thin film including a lead-free ferroelectric material and exhibiting high piezoelectric performance comparable to that of lead zirconate titanate (PZT), and a method of manufacturing the piezoelectric thin film. The piezoelectric thin film of the present invention comprises: a LaNiO3 film having a (001) orientation; a NaNbO3 film having a (001) orientation; and a (Bi, Na, Ba) TiO3 film having a (001) orientation. The LaNiO3 film, the NaNbO3 film, and the (Bi, Na, Ba)TiO3 film are laminated in this order.Type: ApplicationFiled: November 30, 2010Publication date: June 16, 2011Applicant: PANASONIC CORPORATIONInventors: Takakiyo HARIGAI, Hideaki Adachi, Eiji Fujii
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Patent number: 7923906Abstract: A ferroelectric film containing a perovskite type oxide represented by Formula (P) is formed on a substrate, which stands facing a target, by a sputtering technique under conditions of a height of a shield, which surrounds an outer periphery of the target on the substrate side in a non-contact state and comprises shielding layers superposed one upon another at intervals, such that a difference between a plasma potential and a floating potential is at most 35V, and under conditions such that a temperature of the substrate is at least 400° C.: (Pb1?x+?Mx) (ZryTi1?y)O—??(P) wherein M represents at least one kind of element selected from Bi and lanthanide elements, 0.05?x?0.4, and 0<y?0.7, the standard composition being such that ?=0, and z=3.Type: GrantFiled: September 3, 2008Date of Patent: April 12, 2011Assignee: FUJIFILM CorporationInventors: Takami Arakawa, Takamichi Fujii
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Publication number: 20110034336Abstract: A superconducting article includes a substrate having a biaxially textured surface, and an epitaxial biaxially textured superconducting film supported by the substrate. The epitaxial superconducting film includes particles of Ba2RENbO6 and is characterized by a critical current density higher than 1 MA/cm2 at 77K, self-field. In one embodiment the particles are assembled into columns. The particles and nanocolumns of Ba2RENbO6 defects enhance flux pinning which results in improved critical current densities of the superconducting films. Methods of making superconducting films with Ba2RENbO6 defects are also disclosed.Type: ApplicationFiled: August 4, 2010Publication date: February 10, 2011Inventors: Amit Goyal, Sung-Hun Wee, Eliot Specht, Claudia Cantoni