Using Both Anion And Cation Selective Membranes Patents (Class 204/522)
- And using ion exchange material (e.g., suspended particles, etc.) (Class 204/524)
- With prevention of scale buildup or fouling of membrane (Class 204/525)
- Gas or vapor treated (Class 204/526)
- Biological material prepared, recovered, or treated (e.g., urine, etc.) (Class 204/527)
- Regeneration of liquid electrolyte (Class 204/528)
- Metal or metal salt recovered or removed (Class 204/529)
- Organic material prepared, recovered, or treated (Class 204/530)
- Acid prepared, recovered, or treated (Class 204/531)
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Patent number: 7901577Abstract: Desalination is carried out by a hybrid ion exchange-nanofiltration process in which ion exchange is followed by pressure-driven nanofiltration. Monovalent ions of sodium and chloride of saline water are exchanged for equivalent concentrations of poly-valent ions (for example, sodium ions for magnesium ions or chloride ions for sulfate ions) when passed through ion exchangers in the form of those poly-valent ions. The resultant solution has a lower osmotic pressure than the initial solution containing monovalent sodium and chloride ions, and requires less transmembrane pressure for membrane desalination compared to traditional reverse osmosis. The concentrated reject stream from the membrane process is used as regenerant for the exhausted ion exchanger, which has been converted to monovalent anionic or cationic form.Type: GrantFiled: February 13, 2008Date of Patent: March 8, 2011Inventors: Arup K. SenGupta, Sudipta Sarkar
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Publication number: 20100282689Abstract: A low energy water treatment system and method is provided. The system has at least one electrodialysis device that produces partially treated water and a brine byproduct, a softener, and at least one electrodeionization device. The partially treated water stream can be softened by the softener to reduce the likelihood of scale formation and to reduce energy consumption in the electrodeionization device, which produces water having target properties. At least a portion of the energy used by the electrodeionization device can be generated by concentration differences between the brine and seawater streams introduced into compartments thereof. The brine stream can also be used to regenerate the softener.Type: ApplicationFiled: September 22, 2008Publication date: November 11, 2010Inventors: Gary C. Ganzi, Li-Shiang Liang, Frederick C. Wilkins
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Publication number: 20100270158Abstract: Microbial processes and systems are provided according to the present invention for desalination of saline materials, such as aqueous mixtures including dissolved salts. Microbial desalination devices according to embodiments of the present invention create hydrogen gas in a configuration referred to as a microbial electrolysis desalination cell (MEDC), or electricity in a configuration referred to as a microbial fuel desalination cell (MFDC) in addition to desalination of saline materials.Type: ApplicationFiled: April 22, 2010Publication date: October 28, 2010Applicant: The Penn State Research FoundationInventor: Bruce Logan
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Publication number: 20100140092Abstract: An embodiment is a method and apparatus to provide de-ionization. First and second conductive porous membranes are placed between a feed channel having a feed flow and first and second concentration channels having first and second concentration flows to separate the feed channel from the concentration channels. Cathode and anode electrodes are placed on external sides of the concentration channels. A voltage supply distribution network provides independent voltages across the channels to cause movement of ions in the feed and concentration flows toward the electrodes.Type: ApplicationFiled: December 4, 2008Publication date: June 10, 2010Applicant: PALO ALTO RESEARCH CENTER INCORPORATEDInventors: Armin R. Volkel, Meng H. Lean
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Publication number: 20100126864Abstract: The invention relates to a process for the production of an amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups or its salt with less than an equivalent of alkaline metal based on the number of carboxyl groups, said process comprising reducing alkali metal ions from an aqueous solution of an alkali metal salt of an amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups and acidifying the amino carboxylate starting material by first performing a chemical acidification step using an organic or inorganic acid to get a compound in which at least one of the groups is protonated, and in a subsequent step further acidifying the amino carboxylate starting material and reducing alkali metal ions from an aqueous solution of the partially acidified alkali metal salt of the amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups by electrodialysis, wherein the electrodialysis is performedType: ApplicationFiled: November 27, 2007Publication date: May 27, 2010Applicant: Akzo Nobel N.V.Inventors: Martin Heus, Hans Lammers, Arie Volmer
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Patent number: 7722751Abstract: An apparatus for regulating salt concentration, a lab-on-a-chip including the same and a method of regulating salt concentration using the apparatus are provided. The apparatus includes: a reaction chamber that is defined by a cation exchange membrane and an anion exchange membrane and is selected from the group consisting of a biomolecule extraction chamber, an amplification chamber, a hybridization chamber, and a detection chamber; a first electrode chamber that is defined by the anion exchange membrane and a first electrode and includes an ion exchange medium; and a second electrode chamber that is defined by the cation exchange membrane and a second electrode and includes an ion exchange medium. Even without injecting solutions with different salt concentrations into the reaction chamber by operating pumps and valves for each operation stage, the salt concentration can be reversibly regulated in situ by adjusting the polarity, intensity and application time of a voltage.Type: GrantFiled: May 25, 2006Date of Patent: May 25, 2010Assignee: Samung Electronics Co., Ltd.Inventors: Jung-im Han, Young-sun Lee, Joon-ho Kim
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Patent number: 7704361Abstract: The present invention relates to a method for isolation of ionic species from a liquid and an apparatus for isolation of ionic species from a liquid. Moreover the invention relates to an electro enhanced dialysis cell and the use of the cell in the method and the apparatus.Type: GrantFiled: December 6, 2001Date of Patent: April 27, 2010Assignee: Jurag Separation A/SInventors: Arvid Garde, Jens-Ulrik Rype, Gunnar Jonsson
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Patent number: 7705061Abstract: This invention presents an ion exchange media including a plurality of cation exchange zones and anion exchange zones in flow paths that are contained in a substantially nonporous resin transport framework. During electrodeionization and other potential applications the ion exchange media of the invention prevents unfavorable water splitting at resin-membrane interfaces and encourages water splitting at resin-resin interfaces where the water splitting may be constructively used to regenerate the resin.Type: GrantFiled: December 11, 2006Date of Patent: April 27, 2010Assignee: Aquatech International CorporationInventors: Ravi Chidambaran, Pavan Raina, Devesh Sharma, Narendra Singh Bisht
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Patent number: 7699968Abstract: The present invention provides a water purifying system capable of efficiently producing treated water containing boron at a low concentration. Water to be treated is first fed to the RO membrane apparatus 1 and the passed water is fed through the boron absorptive apparatus 2. Water which was passed through the boron absorptive apparatus 2 and of which boron was thus removed is fed through the electrodeionization apparatus 3. In this manner, water treated by electrodeionization is taken out as treated water. The condensed water of the electrodeionization apparatus 3 may be discharged or returned to the upstream side of the RO membrane apparatus 1 through a return pipe 4 so that the condensed water is added to water to be treated. Suitably used as the absorptive agent accommodated in the boron absorptive apparatus 2 is a boron selective absorptive agent capable of selectively absorbing boron.Type: GrantFiled: December 6, 2005Date of Patent: April 20, 2010Assignee: Kurita Water Industries Ltd.Inventors: Masanobu Osawa, Satoshi Yamada
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Patent number: 7662266Abstract: In regenerating an electroless metal plating bath by electrodialysis, it has been found that the metal of the metal plating bath deposits in the electrolysis arrangement. To overcome this problem, an improvement to prior art regenerating devices is suggested, said improvement consisting in providing main cation exchangers for removing ions of this metal from a concentrate fluid. The main cation exchangers are coupled to the concentrate compartments of the electrolysis arrangement in such a manner that the concentrate fluid flowing through the concentrate compartments is allowed to pass through the main cation exchangers and to be recirculated back into the concentrate compartments.Type: GrantFiled: August 14, 2003Date of Patent: February 16, 2010Assignee: Atotech Deutschland GmbHInventors: Jens Heydecke, Masanori Muranushi
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Publication number: 20100006438Abstract: An efficient system for desalinization of water is described wherein multiple stages of deionization result in drinking water quality and provision is made for recycling wastewater through the system.Type: ApplicationFiled: July 10, 2009Publication date: January 14, 2010Applicant: Biological Targets, Inc.Inventors: Peter P. ANTICH, Lee A. BULLA, JR.
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Patent number: 7604724Abstract: A method for selectively removing hydrogen sulfide and carbon dioxide from sour gas by reacting the hydrogen sulfide and carbon dioxide in the sour gas with sodium hydroxide is disclosed. Also disclosed is a process for the production of a salt product from a sour gas stream. The reaction with sodium hydroxide creates a scrubber solution comprising water, hydrocarbons, contaminants and salts. The scrubber solution may be oxidized, filtered and can then be subjected to electrodialysis. Ammonia is introduced into the acid compartments of the cell. Sodium hydroxide and a salt product comprising ammonium sulfate or ammonium thiosulfate with ammonium bicarbonate, ammonium carbonate, ammonium carbamate may be produced. The regenerated sodium hydroxide may be used to sweeten further sour gas. The salt product may be used as a fertilizer.Type: GrantFiled: July 2, 2008Date of Patent: October 20, 2009Assignee: Aristos Energy Inc.Inventor: Murray Edward Arne Mortson
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Patent number: 7582198Abstract: A method and apparatus for producing purified water. An electrochemical system can be configured to pass product water through depletion compartments as well as a cathode compartment. An electrochemical apparatus may also be configured to pass concentrate through both concentrating compartments and an anode compartment.Type: GrantFiled: November 13, 2003Date of Patent: September 1, 2009Assignee: Siemens Water Technologies Holding Corp.Inventors: Frederick Wilkins, Evgeniya Freydina, Aytac Sezgi, Reshma Madhusudan, Anil D. Jha
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Patent number: 7544278Abstract: The invention includes novel anion exchange membranes formed by in situ polymerization of at least one monomer, polymer or copolymer on a woven support membrane and their methods of formation. The woven support membrane is preferably a woven PVC membrane. The invention also includes novel cation exchange membranes with or without woven support membranes and their methods of formation. The invention encompasses a process for using the membranes in electrodialysis of ionic solutions and in particular industrial effluents or brackish water or seawater. The electrodialysis process need not include a step to remove excess ions prior to electrodialysis and produces less waste by-product and/or by-products which can be recycled.Type: GrantFiled: April 19, 2004Date of Patent: June 9, 2009Assignee: Seventy-Seventh Meridian Corporation, LLCInventors: Tejraj Aminabhavi, Padmakar V. Kulkarni, Mahadevappa Y. Kariduraganavar
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Patent number: 7501064Abstract: An integrated treatment system using electrodialysis and pressure-driven membranes for deionizing and decontaminating liquids to a near-pure quality for use or reuse in industrial or municipal operations. The integrated system includes steps of pre-filtering contaminated feed liquids blending the filtered liquids in preparation for treating the mixed liquids in parallel or sequential treatment steps utilizing nanofiltration or reverse osmosis, proceeded by or followed by an integrated electrodialysis treatment. A control means selectively directs mixed liquids to each of the treatment units for treatment in parallel or in series depending on the conductivity and residual contaminants in the mixed liquids. In comparison with nanofiltration or reverse osmosis only systems, or electrodialysis only systems, the integrated system provides improved efficiencies for treatment, requires less energy to operate, and reduces maintenance and capital costs.Type: GrantFiled: January 6, 2005Date of Patent: March 10, 2009Assignee: EETInventors: Ernst Schmidt, Alois F. Sferrazza, Michael E. Williams
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Patent number: 7459088Abstract: A process and system for purifying water is disclosed. For example, in one embodiment, the process may be used to remove a divalent salt, such as calcium sulfate, from a water source in order to prevent the divalent salt from precipitating during the process. The water source, for instance, may be fed to an ion separating device, such as an electrodialysis device. In the electrodialysis device, an ion exchange takes place between the divalent salt and another salt, such as a monovalent salt to produce two concentrated salt streams that contain salts having greater solubility in water than the divalent salt. In one embodiment, the two salt streams that are produced may then be combined to precipitate the divalent salt in a controlled manner. During the process, various other components contained within the water feed stream may also be removed from the stream and converted into useful products. In one particular embodiment, the process is configured to receive a byproduct stream from a reverse osmosis process.Type: GrantFiled: September 13, 2005Date of Patent: December 2, 2008Assignee: The University of South CarolinaInventor: Thomas A. Davis
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Publication number: 20080245667Abstract: Apparatus is described for removing ionisable impurities from an electrolyte solution in an electromembrane device. The apparatus comprises means for recirculating the electrolyte solution between the cathode and the anode, and means for transferring selected ions from the electrolyte solution into a separate stream upon application of a current.Type: ApplicationFiled: March 9, 2005Publication date: October 9, 2008Inventors: Christopher Peter Jones, Peter James Mawle
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Patent number: 7291274Abstract: Deionisation and clarification process of the aqueous medium used in an electroerosion machine and product for this process, where the electroerosion machines are comprised of a purification circuit for this aqueous medium, which includes an ion exchange phase between some cationic and anionic resins with the aqueous dielectric medium, which has a conductivity of less than 40 ?S/cm, and to which a solution of oxalic acid and phosphoric acid in distilled/deionised water is added in the approximate proportion of oxalic acid between 0.18 and 0.035 moles and phosphoric acid between 1.28 and 2.5 moles per liter of solution.Type: GrantFiled: December 20, 2001Date of Patent: November 6, 2007Assignee: Ona Electro-Erosion, S.A.Inventors: Koldobika Castrillo, Fernando Martinez, Raquel Ferret, Ana Aranzabe
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Patent number: 7083730Abstract: Sodium chloride and purified water are recovered by treating salt water that contains sodium chloride with an integrated reverse osmosis and electrodialysis system, which includes an efficiency-enhancing feature that is one or more of the following: the use of univalent anion and univalent cation selective membranes in the electrodialysis unit; the addition of a nanofiltration unit to process the diluate from the electrodialysis unit; or operation of the electrodialysis unit at an elevated pressure. Magnesium and bromine can optionally be produced when the salt water contains these materials.Type: GrantFiled: August 1, 2003Date of Patent: August 1, 2006Assignee: University of South CarolinaInventor: Thomas A. Davis
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Patent number: 7049020Abstract: The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.Type: GrantFiled: October 30, 2001Date of Patent: May 23, 2006Inventors: Jochen Kerres, Thomas Haring, Rima Haring
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Patent number: 6830671Abstract: An ion-exchange membrane having excellent resistance against organic fouling by high molecular weight organic ions etc. and showing low electric resistance is provided. Said ion-exchange membrane is characterized by that a polyether compound containing polyalkylene glycol chain, such as polyethylene glycol, polypropylene glycol, their derivatives, etc., is fixed on the surface and/or inside of the membrane. As examples of the mode of the fixation there are mentioned fixation by entanglement of the molecules forming the membrane and the molecules of the polyether compound, physical fixation of both molecules by the anchor effect, and chemical fixation of both molecules by the formation of covalent bond or ionic bond. Said ion-exchange membrane can be preferably used in case of removing low molecular weight electrolytes from an aqueous solution containing low molecular weight electrolytes and high molecular weight organic ions etc. through electrodialysis.Type: GrantFiled: June 28, 2002Date of Patent: December 14, 2004Assignee: Tokuyama CorporationInventors: Toshio Aritomi, Minoru Kawashima
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Patent number: 6814865Abstract: The invention includes novel anion exchange membranes formed by in situ polymerization of at least one monomer, polymer or copolymer on a woven support membrane and their methods of formation. The woven support membrane is preferably a woven PVC membrane. The invention also includes novel cation exchange membranes with or without woven support membranes and their methods of formation. The invention encompasses a process for using the membranes in electrodialysis of ionic solutions and in particular industrial effluents or brackish water or seawater. The electrodialysis process need not include a step to remove excess ions prior to electrodialysis and produces less waste by-product and/or by-products which can be recycled.Type: GrantFiled: December 5, 2001Date of Patent: November 9, 2004Assignee: Seventy-Seventh Meridian Corporation LLCInventors: Tejraj Aminabhavi, Padmakar V. Kulkarni, Mahadevappa Y. Kariduraganavar
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Patent number: 6787021Abstract: This invention relates to a process for improving the purity of an aqueous onium hydroxide solution. In particular, the invention relates to a process for improving the purity of aqueous onium hydroxide solutions containing undesirable amounts of anions. The invention also relates to the improved high purity onium hydroxide solutions obtained by the above method.Type: GrantFiled: January 3, 2002Date of Patent: September 7, 2004Assignee: Sachem, Inc.Inventors: Robert J. Reiter, Kelly Hefner
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Patent number: 6712946Abstract: A method for electrodialysis is conducted in a multi-compartment, preferably a four compartment, electrodialysis cell configuration wherein an inexpensive source of protons, preferably from a strong inorganic acid enables the conversion of multivalent metal salts into valuable acid products, such as 2-keto-L-gluconic acid, a vitamin C precursor, and useful by-products, like calcium chloride.Type: GrantFiled: May 21, 2002Date of Patent: March 30, 2004Assignee: The Electrosynthesis Company, Inc.Inventors: J. David Genders, Dan Hartsough
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Patent number: 6541228Abstract: A process for purifying and concentrating a gluconic acid derivative, such as 2-keto-L-gulonic acid, comprising introducing a non-viable and/or acidified fermentation medium or an in-vitro reactor medium comprising at least the gluconic acid derivative and/or salt thereof to electrodialysis thereby purifying and concentrating the gluconic acid derivative.Type: GrantFiled: November 28, 2000Date of Patent: April 1, 2003Assignee: The Electrosynthesis Company, Inc.Inventors: J. David Genders, Ram Gopal, Dan M. Hartsough, Peter M. Kendall, William J. Long, Duane J. Mazur, Guillermo D. Zappi
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Patent number: 6537436Abstract: An electrodialysis treatment system utilizing a plurality of disparate layers of an electrodialysis cell stack for separation of components in liquid mixtures. The system for electrodialysis treatment for purification and deionizing liquids includes providing an operation of pretreatment by filtration for removal of inorganic and organic contaminants and generating a filtrate effluent. An adsorbing operation for adsorbing organic contaminants from the filtrate effluent of the pretreatment operation is provided by utilizing activated carbon adsorption and generating a liquid fraction. A deionizing operation for continuously purifying the liquid fraction is provided by utilizing an electrodialysis stack having a plurality of ion exchange membranes and separating gaskets for selectively removing contaminant ions from the liquid fraction of the adsorbing operation.Type: GrantFiled: May 31, 2001Date of Patent: March 25, 2003Inventors: Ernst Schmidt, Michael E. Williams, Brian M. Schmidt, James Schmidt, Erich Schmidt
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Publication number: 20020189951Abstract: An electrodeionization apparatus and method for purifying a fluid. A fluid, such as water, can be purified by removing weakly ionizable species from the fluid. Weakly ionizable species may be dissociated at different pH levels to facilitate removal from the fluid in an electrodeionization device.Type: ApplicationFiled: May 29, 2001Publication date: December 19, 2002Inventors: Li-Shiang Liang, Anil Jha, John Arba, Stephane Dupont
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Publication number: 20020094466Abstract: The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.Type: ApplicationFiled: October 30, 2001Publication date: July 18, 2002Inventors: Jochen Kerres, Thomas Haring, Rima Haring
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Publication number: 20020084187Abstract: A method of removing a biological contaminant from a mixture containing a biomolecule and the biological contaminant, the method comprising: (a) placing the biomolecule and contaminant mixture in a first solvent stream, the first solvent stream being separated from a second solvent stream by an electrophoretic membrane; (b) selecting a buffer for the first solvent stream having a required pH; (c) applying an electric potential between the two solvent streams causing movement of the biomolecule through the membrane into the second solvent stream while the biological contaminant is substantially retained in the first sample stream, or if entering the membrane, being substantially prevented from entering the second solvent stream; (d) optionally, periodically stopping and reversing the electric potential to cause movement of any biological contaminants having entered the membrane to move back into the first solvent stream, wherein substantially not causing any biomolecules that have entered the second solvent stType: ApplicationFiled: June 22, 2001Publication date: July 4, 2002Applicant: Gradipore LimitedInventors: Brendon Conlan, Tracey Ann Edgell, May Lazar, Chenicheri Haribaran Nair, Elizabeth Jean Seabrook, Thomas Norman Turton
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Publication number: 20020079233Abstract: The present invention relates to a process for improving the purity of a composition comprising a quaternary ammonium hydroxide comprising the steps of (a) providing an electrolysis cell which comprises an anolyte compartment containing an anode, a catholyte compartment containing a cathode, and at least one intermediate compartment, said at least one intermediate compartment being separated from the anolyte and catholyte compartments by cation selective membranes, (b) charging water, optionally containing a supporting electrolyte, to the anolyte compartment, charging water, optionally containing a quaternary ammonium hydroxide, to the catholyte compartment, and charging the composition comprising the quaternary ammonium hydroxide to be purified to the intermediate compartment, (c) passing a current through the electrolysis cell to produce a purified aqueous quaternary ammonium hydroxide solution in the catholyte compartment, and (d) recovering the purified aqueous quaternary ammonium hydroxide solution fromType: ApplicationFiled: October 16, 2001Publication date: June 27, 2002Inventors: Anna Giatti, Fred Korpel, Roger Keranen Rains, Gerrit Jan Boerman
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Patent number: 6379517Abstract: A method and a device for the regeneration of an electroless metal deposition bath containing hypophosphite ions by electrodialysis is described. The method according to the invention and the device differ from the prior art in that the bath solution is led simultaneously through diluate compartments in a second electrodialysis unit having cathodes and anodes, which compartments are separated from concentrate compartments in the second electrodialysis unit on the cathode side by monoselective anion-exchange membranes and on the anode side by anion-exchange membranes, the diluate compartments and the concentrate compartments in the second electrodialysis unit being disposed alternately to one another.Type: GrantFiled: December 4, 2000Date of Patent: April 30, 2002Assignee: Atotech Deutschland GmbHInventors: Jens Heydecke, Rainer Born, Werner Richtering, Manfred Blaschke, Alexander Kraft, Maja Wunsche
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Publication number: 20020020625Abstract: A process is disclosed for removing heat stable amine salts using an electrodialysis process. The process of the present invention can be used to reduce the level of heat stable salts in a lean solvent stream in an acid gas removal process. A base is added to the electrodialysis unit in order to permit the recovery of the heat stable amine salts as salts corresponding to the base added. The purified amine solution can be used again to remove acid gases from a gas stream.Type: ApplicationFiled: May 4, 2001Publication date: February 21, 2002Inventor: Carolyn H. Byszewski
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Publication number: 20020005356Abstract: Bipolar membrane electrodialysis methods for salt splitting polyvalent metal salts, where the metal cation can form substantially insoluble precipitates in the presence of hydroxyl ions can now be used in recovering acid and base values from a salt streams without precipitates fouling cell operation and causing shutdown. The introduction of an acid to the chamber where metal hydroxides would form inhibits their development or neutralizes formed solids, allowing salt splitting to continue. Salt splitting methods of the invention performed with a three compartment bipolar electrodialysis cell are useful in producing concentrated and purified acid forms, such as 2-keto-L-gluconic acid, H(KLG), a key intermediate in the production of ascorbic acid.Type: ApplicationFiled: July 9, 2001Publication date: January 17, 2002Inventors: Duane J. Mazur, J. David Genders, Dan M. Hartsough
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Patent number: 6328894Abstract: A process to purify and classify a dispersion containing stabilized particles having counterions and ions as well as free species is disclosed. The solution may comprise an aqueous media, a solvent media, or a combination of both and can include more than one type of aqueous and/or solvent solutions. The process includes at least the steps, in any order, of substantially removing the particles having sizes above about 1 micron, preferably above 0.5 micron; substantially removing the free species; and exchanging at least a portion of the counterions that are a part of the stabilized particles. The process disclosed is especially useful in purifying dispersions where the ionic stabilized colloidal particles are carbon black having attached organic groups comprising at least one ionic group, or at least one ionizable group, or mixtures thereof.Type: GrantFiled: January 29, 1999Date of Patent: December 11, 2001Assignee: Cabot CorporationInventors: Michael K. Chan, Joseph E. Johnson, John Mathew, Friedrich K. von Gottberg
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Publication number: 20010040093Abstract: An apparatus and process produces salts by an electrodialysis operation. The basic electrodialysis apparatus is a cell having a number of compartments separated by membranes. A DC source is connected to drive a current through a feed stream passing through the cell which splits the salt stream into an acid and a base. The incoming feed may be nanofiltered to remove divalent metal. The base loop may be in communication with an ion exchange column packed with a material that removes multivalent cations. Depending upon the material being processed and the desired end result either or both the nanofiltration and the ion exchanged column may be used in the apparatus.Type: ApplicationFiled: February 14, 2001Publication date: November 15, 2001Applicant: Archer Daniels Midland CompanyInventor: K. N. Mani
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Publication number: 20010030129Abstract: A method for producing deionized water by an electro-regenerating deionization method, which comprises employing a deionized water producing apparatus comprising an electrodialyzer, wherein cation exchange membranes and anion exchange membranes are arranged alternately between an anode compartment provided with an anode and a cathode compartment provided with a cathode so as to form demineralizing compartments partitioned by the anion exchange membranes on the anode side and partitioned by the cation exchange membranes on the cathode side and concentrating compartments partitioned by the cation exchange membranes on the anode side and partitioned by the anion exchange membranes on the cathode side, and ion exchangers being accommodated in the demineralizing compartments, supplying water to be treated in the demineralizing compartments and supplying a concentrated water which is an electrolyte solution to the concentrating compartments under applying a voltage to transfer and remove impurity ion contained in tType: ApplicationFiled: March 2, 2001Publication date: October 18, 2001Applicant: Asahi Glass Company, LimitedInventors: Yoshio Sugaya, Yukio Matsumura, Hiroshi Toda
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Publication number: 20010013471Abstract: An electrodialytic method and device for the simultaneous production of acids and bases of high purity and higher concentration operates by splitting corresponding salts in aqueous solution using an electrolysis cell. The electrolysis cell includes a cathode chamber in which an alkali is formed, a salt chamber for supplying a salt to be split, an acid chamber in which the acid is formed, and an anode chamber through which a mineral acid flows as a proton carrier. The anode is a hydrogen-consuming electrode. The method and device are preferably used in the production of hydrochloric acid and sodium hydroxide solution.Type: ApplicationFiled: February 5, 2001Publication date: August 16, 2001Inventors: Georg Hartel, Christian Bienhuls, Jurgen Kunzel
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Patent number: 6270672Abstract: A method for removing pathogens from biological liquids and an apparatus for performing such a method, said method comprising the steps of providing a biological liquid, wherein pathogens are potentially present, in an apparatus comprising an anode and a kathode and a separation means suitable for separating said pathogens from said pharmaceutically active molecule, said separation means being positioned between said anode and said kathode, applying current between said anode and said kathode, thereby causing one of said pathogens or said pharmaceutically active molecule to pass said separation means and recovering said pharmaceutically active molecule in a form being free of said pathogens as well as an apparatus carrying out the present method.Type: GrantFiled: August 6, 1999Date of Patent: August 7, 2001Assignee: Baxter AktiengesellschaftInventors: Peter Turecek, Erwin Mattes, Hans Peter Schwarz
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Patent number: 6241866Abstract: Electrodeionization apparatus for purifying water that includes a cathode, an anode, and a plurality of alternating anion permeable membranes and cation permeable membranes between the cathode and anode that define concentrating and diluting flow channels between adjacent pairs of membranes. The diluting channels include cation exchange materials and anion exchange materials that are fixed in close contacting position with respect to each other and provide conductive paths for cations and anions to the adjacent membranes and provide flow passages for water between the materials. The anion exchange materials and cation exchange materials each have a characteristic dimension that is smaller than the characteristic dimensions of the flow passages.Type: GrantFiled: September 13, 1999Date of Patent: June 5, 2001Inventor: Leon Mir
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Patent number: 6217743Abstract: In one embodiment, the present invention relates to a process for recovering an onium compound from waste solutions or synthetic solutions containing the onium compound and impurities including the steps: contacting the waste solution or synthetic solution with a metal ion scavenger to remove metal ion impurities, wherein the metal ion scavenger comprises at least one of a chelating compound, a nanoporous material, and a magnetically assisted (MACS) material; charging the waste solution or synthetic solution to an electrochemical cell containing at least two compartments, a cathode, an anode and a divider and passing a current through the cell whereby the onium compound is regenerated or produced; and recovering the onium compound from the cell.Type: GrantFiled: August 9, 1999Date of Patent: April 17, 2001Assignee: Sachem, Inc.Inventors: Roger D. Moulton, Weilian Lang, Allen Tanner
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Patent number: 6187570Abstract: A process for purifying and concentrating a gluconic acid derivative, such as 2-keto-L-gulonic acid, comprising introducing a non-viable and/or acidified fermentation medium or an in-vitro reactor medium comprising at least the gluconic acid derivative and/or salt thereof to electrodialysis thereby purifying and concentrating the gluconic acid derivative.Type: GrantFiled: May 25, 1999Date of Patent: February 13, 2001Assignee: The Electrosynthesis Company, Inc.Inventors: J. David Genders, Ram Gopal, Dan M. Hartsough, Peter M. Kendall, William J. Long, Duane J. Mazur, Guillermo D. Zappi
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Patent number: 6120673Abstract: The invention relates to a method and a device for regenerating exhausted tin-plating solutions which contain tin and copper ions, free complexing agent and complexing agent bound to the copper ions, as well as expended and unexpended reducing agent. By means of a suitable rinsing technique, the rinse water of the tin-plating process is concentrated to a 10 to 15 percent dilution of the process solution. The regenerating solution thus produced is fed to an electrolytic cell. The electrolytic cell comprises a cathode chamber, a middle chamber and an anode chamber. The cathode chamber is separated from the middle chamber by an anion-exchange membrane and the anode chamber is separated from the middle chamber by a cation-exchange membrane. The regenerating solution is initially provided in the cathode chamber. Here, the interfering copper component is cathodically deposited.Type: GrantFiled: May 7, 1998Date of Patent: September 19, 2000Assignee: KM Europa Metal AGInventors: Ulrich Reiter, Werner Harnischmacher, Klaus Fischwasser, Hans-Wilhelm Lieber, Ralph Blittersdorf, Annette Heuss
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Patent number: 6045684Abstract: An on-site process and apparatus for producing hydrogen peroxide at a high efficiency substantially from brine and oxygen-containing gas alone as raw materials while removing alkaline earth metals. Sea water concentrated by an electrodialytic apparatus 2 or the like as a raw material is supplied to an impurity removing apparatus 10 where caustic soda produced in an acid-alkali producing apparatus 11 at a subsequent stage and/or carbon dioxide gas is added to remove alkaline earth metals contained in sea water in the form of a hydroxide or carbonate precipitate. Separately, the acid-alkali producing apparatus 11 performs a salt separating operation to produce caustic soda which is then supplied to a hydrogen peroxide generator 28 to produce an alkaline aqueous solution of hydrogen peroxide.Type: GrantFiled: April 16, 1998Date of Patent: April 4, 2000Assignees: Permelec Electrode Ltd., Katayama Chemical, Inc.Inventors: Shuhei Wakita, Masaharu Uno, Takayuki Shimamune, Yoshinori Nishiki, Kunio Nishimura
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Patent number: 6030844Abstract: Method of pre-treating a sample for metal analysis, the sample including a volatile alkali, by permeating the volatile alkali through a gas permeable membrane, dissolving the volatile alkali in an absorbent, passing ions through a first cation exchange membrane in electrical contact with an anode, reacting the volatile alkali with the ions, and passing the reacted volatile alkali through a second cation exchange membrane in electrical contact with a cathode, whereby the volatile alkali is removed from the sample.Type: GrantFiled: August 18, 1997Date of Patent: February 29, 2000Assignee: NEC CorporationInventor: Ushio Hase
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Patent number: 6024855Abstract: In one embodiment, the present invention relates to a method of preparing a hydroxylammonium salt, involving the steps of: providing an electrochemical cell containing an anode, a cathode, and a divider positioned between the anode and the cathode, to define a catholyte compartment between the cathode and the divider and an anolyte compartment between the anode and the divider; charging the catholyte compartment with a first solution comprising a nitrogen containing compound and a mediator and the anolyte compartment with a second solution comprising an ionic compound; passing a current through the electrochemical cell to produce a hydroxylammonium salt in the catholyte compartment; and recovering the hydroxylammonium salt from the catholyte compartment.Type: GrantFiled: August 13, 1998Date of Patent: February 15, 2000Assignee: Sachem, Inc.Inventors: Hossein Sharifian, John H. Wagonknecht
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Patent number: 5968338Abstract: In one embodiment, the present invention relates to a process for recovering an onium hydroxide from a solution containing an onium compound, including contacting the solution with a cation exchange material so that at least a portion of onium cations from the onium compound are adsorbed by the cation exchange material; contacting an acid with the cation exchange material to elute an onium salt; charging the onium salt to an electrochemical cell containing at least three compartments, a cathode, an anode, and in order from the anode to the cathode, a bipolar membrane and a cation selective membrane, and passing a current through the cell whereby the onium hydroxide is regenerated; and recovering the onium hydroxide from the cell.Type: GrantFiled: January 20, 1998Date of Patent: October 19, 1999Assignee: Sachem, Inc.Inventors: David R. Hulme, Roger Moulton, Wilfred W. Wilson, Mark Hellums
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Patent number: 5951845Abstract: In one embodiment, the present invention relates to a process for recovering an organic hydroxide from waste solutions containing the organic hydroxide and impurities including the steps: contacting the waste solution with a metal ion scavenger to remove metal ion impurities; charging the waste solution to an electrochemical cell containing at least two compartments, a cathode, an anode and a divider and passing a current through the cell whereby the organic hydroxide is regenerated; and recovering the organic hydroxide from the cell.Type: GrantFiled: March 4, 1997Date of Patent: September 14, 1999Assignee: Sachem, Inc.Inventor: Roger D. Moulton
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Patent number: 5910237Abstract: In one embodiment, the present invention relates to a process for recovering organic hydroxide from contaminated solutions containing the organic hydroxide and impurities including charging the contaminated solution to a first electrochemical cell containing at least two compartments, a cathode, an anode and a size selective divider and passing a current through the first electrochemical cell whereby impurities migrate through the size selective divider; recovering a second solution containing organic ions from the first electrochemical cell and charging the second solution to a second electrochemical cell containing at least two compartments, a cathode, an anode and a divider and passing a current through the second electrochemical cell whereby the organic hydroxide is purified; and recovering the organic hydroxide from the second electrochemical cell.Type: GrantFiled: March 11, 1997Date of Patent: June 8, 1999Assignee: Sachem, Inc.Inventors: Roger D. Moulton, Mark W. Hellums
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Patent number: 5904823Abstract: In one embodiment, the present invention provides a method of preparing hydroxylamine from a hydroxylammonium salt solution, including providing an electrochemical cell containing an anode, a cathode, a cation selective membrane and an anion selective membrane, wherein the cation selective membrane is positioned between the cathode and the anion selective membrane, and the anion selective membrane is positioned between the cation selective membrane and the anode, thereby defining a feed compartment between the cation selective membrane and the anion selective membrane, a recovery compartment between the cathode and the cation selective membrane, and an acid compartment between the anion selective membrane and the anode; charging a first solution to the acid compartment and a second solution the recovery compartment; charging the hydroxylammonium salt solution to the feed compartment; passing a current through the cell to produce hydroxylamine in the recovery compartment; and recovering hydroxylamine from theType: GrantFiled: April 10, 1997Date of Patent: May 18, 1999Assignee: Sachem, Inc.Inventors: Hossein Sharifian, Christopher D. Shay
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Patent number: 5900133Abstract: Describes a method of electrochemically converting amine hydrohalide, e.g., ethyleneamine hydrochloride, into free amine, e.g., free ethyleneamine. A three compartment electrolytic cell is provided having (1) a catholyte compartment containing a cathode assembly comprising a cathode and anion exchange membrane, (2) an anolyte compartment containing an anode assembly comprising an anode and a cation exchange membrane, and (3) an intermediate compartment separated from the catholyte and anolyte compartments by the anion and cation exchange membranes respectively. An aqueous solution of amine hydrohalide is charged to the catholyte compartment, while hydrogen halide solutions are charged to the intermediate and anolyte compartments. Direct current is passed through the electrolytic cell and an aqueous solution comprising free amine is removed from the catholyte compartment.Type: GrantFiled: August 18, 1997Date of Patent: May 4, 1999Assignee: PPG Industries, Inc.Inventors: Peter C. Foller, David G. Roberts, Robert H. Tang, James R. Franks