Abstract: Disclosed are devices, systems, and methods for producing broad spectrum disinfectants, sanitizers, cleaner and deodorizers using chlorine dioxide compositions, and more particularly, to methods for producing chlorine dioxide compositions having improved long term stability by the proper choice of pH and through the careful choice of other product formula ingredients.

Abstract: Redox flow devices are described including a positive electrode current collector, a negative electrode current collector, and an ion-permeable membrane separating said positive and negative current collectors, positioned and arranged to define a positive electroactive zone and a negative electroactive zone; wherein at least one of said positive and negative electroactive zone comprises a flowable semi-solid composition comprising ion storage compound particles capable of taking up or releasing said ions during operation of the cell, and wherein the ion storage compound particles have a polydisperse size distribution in which the finest particles present in at least 5 vol % of the total volume, is at least a factor of 5 smaller than the largest particles present in at least 5 vol % of the total volume.

Abstract: A process according to the invention is a process to separate an initial fluid stream comprising phosgene and hydrogen chloride in at least a first and a second fluid stream, said first fluid stream being a hydrogen chloride enriched and phosgene depleted gaseous stream, said second fluid stream being a hydrogen chloride depleted and phosgene enriched stream. The separation is performed by feeding said initial fluid stream to a membrane separation unit, said membrane separation unit separating said initial fluid stream in a first and a second fluid stream.

Abstract: The method for reducing carbon dioxide of the present invention includes a step (a) and a step (b) as follows. A step (a) of preparing an electrochemical cell. The electrochemical cell comprises a working electrode (21), a counter electrode (23) and a vessel (28). The vessel (28) stores an electrolytic solution (27). The working electrode (21) contains boron carbide. The electrolytic solution (27) contains carbon dioxide. The working electrode (21) and the counter electrode (23) are in contact with the electrolytic solution (27). A step (b) of applying a negative voltage and a positive voltage to the working electrode and the counter electrode, respectively, to reduce the carbon dioxide.

Abstract: Method to prepare fluids (liquids and gases) containing pure chlorine dioxide which is not contaminated by the starting materials or the byproducts of the chlorine dioxide synthesis or to deliver pure chlorine dioxide into any medium capable of dissolving chlorine dioxide, wherein the chlorine dioxide generated in the process is transported across a pore free polymeric membrane via selective permeation into the target medium.

Abstract: A method for electrolytically generating a biocide having an electron deficient carrier fluid and chlorine dioxide, including providing a carrier fluid; providing a pair of electrodes interposed by a semi-permeable membrane within a vessel for creating a first passageway and a second passageway, an anode electrode of the pair of electrodes disposed in the first passageway, cathode electrode of the pair of electrodes disposed in the second passageway; flowing the carrier fluid through the vessel; applying an electric potential to the pair of electrodes to produce an oxidative acidic fluid, a reductive alkaline fluid, and anodic gases in the container; removing the fluids and gases from the vessel; mixing a portion of the anodic gases with the reductive alkaline fluid to produce a hypochlorite solution; and mixing a chlorite brine with the hypochlorite solution, followed by the introduction of additional oxidative acidic fluid to release the biocide.

Abstract: The present invention relates to a process for the preparation of stable iodate-exchanged hydrotalcite with zero effluent discharge. The iodate-exchanged hydrotalcite produced is useful as iodizing agent. The invention further relates to utilization of alkaline effluent generated in the process of ion exchange of iodate into SHT so as to fully recycle the residual iodate anion and also utilize the alkali generated in the process for production of additional quantities of iodate through reaction with iodine crystals followed by electrochemical oxidation to obtain pure aqueous solution of iodate salt which can be reused for preparation of the stable iodizing agent. The process gives zero effluent discharge hence economical.

Abstract: Method and apparatus for controlling two phase flow in electrolytic cells. The present invention is directed to any electrolytic cell, including but not limited to upflow electrolytic cells that comprise parallel electrodes in a vertical orientation. Fluid control strips are preferably added between the anode and cathode electrodes to control flow of fluid and gas bubbles generated between the electrodes in order to avoid the detrimental effects of gas bubbles on the conductivity of the fluid solution, and thereby increase production and operational efficiency of the electrolytic cell.

Abstract: The present invention provides an oxygen-reduction gas diffusion cathode having: a porous conductive substrate; diamond particle having a hydrophobic surface; and catalyst particle, the diamond particle and the catalyst particle being disposed on the porous conductive substrate, and a method of sodium chloride electrolysis using the cathode.

Abstract: A chlorine dioxide solution generator includes a chlorine dioxide gas source and an absorption loop for effecting the dissolution of chlorine dioxide into a liquid stream. A gas transfer assembly is interposed between the chlorine dioxide gas source and the absorption loop. The gas transfer assembly includes a gas transfer pump and an exhaust manifold assembly. The exhaust manifold assembly includes a manifold conduit defining an interior volume for directing the pressurized chlorine dioxide gas stream from the pump outlet to the absorption loop. The manifold conduit interior volume is sufficiently large to inhibit chlorine dioxide decomposition in the pressurized chlorine dioxide gas stream by induce a pressurized chlorine dioxide gas stream temperature within the manifold conduit of less than about 163° F. (73° C.).

Abstract: A chlorine dioxide solution generator, which injects a chlorine dioxide solution into a pressurized fluid system, including an absorption loop for effecting the dissolution of chlorine dioxide into a liquid stream. The chlorine dioxide gas source can include an anolyte loop and a catholyte loop. The generator avoids or eliminates the introduction of air or other gases that can cause corrosion in the process distribution system.

Abstract: A method of enhancing the concentration of a first inorganic compound in a first aqueous solution of a first process of a heavy chemical plant, the method comprising (a) feeding the first solution having the first compound at a first concentration and a first water vapor pressure to an osmotic membrane distillation means comprising a hydrophobic, gas and water vapor permeable membrane separating (i) a first chamber for receiving the first solution, from (ii) a second chamber for receiving a receiver feed aqueous solution having a second water vapor pressure lower than the first water vapor pressure; (b) feeding the receiver aqueous feed solution to the second chamber as to effect transfer of water vapor through the membrane from the first chamber to the second chamber, and to produce (i) a resultant first solution having a second concentration of the first compound greater than the first concentration and (ii) a diluted receiver feed aqueous solution; and (c) collecting the resultant first solution.

Abstract: A method for making chlorine dioxide, by passing an aqueous feed solution comprising sodium chlorite into a non-membrane electrolysis cell comprising an anode and a cathode, adjacent to the anode, while flowing electrical current between the anode and the cathode to electrolyze the aqueous feed solution and convert the halogen dioxide salt to halogen dioxide. The anode is preferably a porous anode through which the aqueous feed solution passes to maximize the conversion of chlorite to chlorine dioxide.

Abstract: An electrolytic process and apparatus for oxidizing inorganic or organic species is disclosed. The process and apparatus includes contacting a solution containing the inorganic or organic species with an electrocatalytic material disposed in an electrolytic reactor. Also disclosed are processes for fabricating a catalyst material for use in the electrolytic reactors and processes.

Abstract: Chlorine dioxide is produced at high conversion rates from aqueous sodium chlorite solution by electrochemical oxidation in an undivided electrochemical cell. The cell utilizes an anode of high surface area through which the aqueous sodium chlorite solution flows into an interelectrode gap between the anode and a cathode. Water or acidified water is fed into the interelectrode gap to function as catholyte and also to dilute the electrolyzed sodium chlorite solution to provide an aqueous solution of chlorine dioxide exiting from the electrochemical cell.

Abstract: An electrolytic cell is provided that can include: a first electrode plate including a first surface that can include a graphite material; a second electrode plate including a second surface that can include a graphite material opposing the first surface; an electrolytic reaction zone between the first surface and the second surface; and an inlet to and an outlet from the electrolytic reaction zone. The first electrode plate and the second electrode plate can include impregnated graphite. The first electrode plate and the second electrode plate can essentially form a chamber for the electrolytic reaction. Methods are provided for using the electrolytic cells, a sodium chloride solution, and a sodium bromide solution, for on-site electrolytic production of hypobromite solution for use as a biocide in water systems.

Abstract: Disclosed are a resin dispersion and a cationic electrodeposition coating composition including the same, in which the dried coating film of the electrodeposition paint is lead-free and has an epoxy-acrylic double-layered structure for displaying excellent properties, and in which an organic solvent content can be minimized. A resin dispersion of a cationic electrodeposition includes an aqueous dispersion prepared by the following processes. The resin dispersion includes a cationic electrodeposition resin, deionized water, an acid for neutralization, a reaction product of manganese phosphate and an acid diluted in an deionized water to 10%, and a cationic surfactant.

Abstract: It is an object of the present invention to provide a cationic electrocoating method capable of producing a coating film with high filiform-rust resistance, corrosion resistance, and rust prevention and a coated article obtainable by the method.

Abstract: A chlorination system in which brine is converted to sodium hypochlorite by an electrolyser. Brine (1) fed to the electrolyser (3) is passed through a filter (2) which is capable of adsorbing bromine or hypobromous acid. Some of the sodium hypochlorite produced in an electrolyser (3) is fed back to a point in the brine feed upstream of the filter (2) such that any bromide in the brine is oxidized to bromine or hypobromous acid and therefore adsorbed by the filter (2).

Abstract: Chlorine dioxide dissolved in water is produced by passing a solution of stabilized chlorine dioxide or sodium chlorite solution, with or without added sodium chloride, through an electrolytic cell having an anode and cathode, in the absence of a semi-permeable membrane but in the presence of a buffer, an anolyte with a pH below 10 is produced so that disproportination of the ClO2 is not appreciable.

Abstract: In a medical instrument sterilizing and washing method and apparatus for sterilizing and washing a medical instrument in a short time without corroding the metal forming the medical instrument to be washed. The sterilizing and washing method comprises the steps of preparing an electrolytic aqueous solution by adding and dissolving a halide composed of a bromide compound as a simple substance or a bromide compound and other halogenated compound to and in tap water; directly subjecting the electrolytic aqueous solution to electrolysis through electrode plates composed of an anode and a cathode and generating electrolytically-generated water containing hypohalogenous acid; and sterilizing and washing the medical instrument with the electrolytically-generated water while maintaining the hydrogen ion concentration (pH) in the electrolytic water to at least 6 at all times.

Abstract: Chlorine dioxide is generated by electrochemical oxidation of sodium chlorite in an anode compartment of a cation-exchange membrane-divided cell in the presence of significant quantities of sodium chlorate and is recovered in a suitable recipient medium by passing the chlorine dioxide through a hydrophobic microporous membrane. Water balance in a continuous operation is maintained by removing water from the anolyte by transporting the same partly across the hydrophobic microporous membrane in vapor form and partly across the cation-exchange membrane.

Abstract: Chlorine dioxide is generated by electrochemical oxidation of sodium chlorite in an anode compartment of a cation-exchange membrane-divided cell and is recovered in a suitable recipient medium by passing the chlorine dioxide through a hydrophobic microporous membrane. Water balance in a continuous operation is maintained by removing water from the anolyte by transporting the same partly across the hydrophobic microporous membrane in vapor form and partly across the cation-exchange membrane.

Abstract: Carbonyl halide is produced from carbon monoxide and halogen produced from the electrochemical conversion of anhydrous hydrogen halide. Both the oxidation of anhydrous hydrogen halide and the formation of carbonyl halide are carried out in the anode-compartment of an electrochemical cell. This reduces the equipment and thus the capital investment necessary for carrying out these reactions. Moreover, no catalyst is needed to form halogen and subsequently make carbonyl halide, as in the prior art. In addition, the health hazards associated with making a carbonyl halide, such as phosgene, at high temperatures from chlorinated hydrocarbons with atmospheric oxygen are virtually eliminated. Furthermore, the halogen produced as a result of the oxidation of anhydrous hydrogen halide are dry, thereby eliminating the need for a preheater before the halogen is reacted with carbon monoxide.

Abstract: A process for converting ammonia in a gas stream to nitrogen comprises contacting the gas stream with an electrolyte containing bromide and hypobromite ions. The ammonia is dissolved and oxidized by the hypobromite ions to nitrogen. Thereafter the electrolyte is passed through an electrochemical cell containing an anode and a cathode to regenerate the hyperbromite ions by the action of an electric current flowing across the cell. The conversion of ammonia to nitrogen in accordance with the invention is adventageous as nitrogen may be disposed of without harm to the environment whilst ammonia has toxic effects.