Abstract: A process for producing alkali metal chlorate that includes introducing an electrolyte solution containing alkali metal halide and alkali metal chlorate to an electrolytic cell, electrolyzing the electrolyte solution to produce an electrolyzed chlorate solution, transferring the electrolyzed chlorate solution to a chlorate reactor to produce a more concentrated alkali metal chlorate, wherein the electrolytic cell is a non-divided electrolytic cell that includes: at least one anode or at least one cathode that includes an electrode substrate comprising M(n+1)AXn, where M is a metal of group IIIB, IVB, VB, VIB or VIII of the periodic table of elements or a combination thereof, A is an element of group IIIA, IVA, VA or VIA of the periodic table of elements or a combination thereof, X is carbon, nitrogen or a combination thereof, where n is 1, 2, or 3; and an outlet for transferring electrolyzed solution to the chlorate reactor.

Abstract: The invention relates to a process for producing alkali metal chlorate in an electrolytic cell that is divided by a cation selective separator into an anode compartment in which an anode is arranged and a cathode compartment in which a gas diffusion electrode is arranged. The process comprises introducing an electrolyte solution containing alkali metal chloride into the anode compartment and an oxygen-containing gas into the cathode compartment. The invention also relates to an electrolytic cell for the production of alkali metal chlorate comprising a cation selective separator dividing the cell into an anode compartment in which an anode is arranged and a cathode compartment in which a gas diffusion electrode is arranged. An inlet for electrolyte solution and an outlet for electrolysed solution are provided in the anode compartment and an inlet for introducing oxygen-containing gas is provided in the gas chamber.

Abstract: A method to prevent corrosion of a stainless steel cathode in a copper electrowinning system uses compounds added to the electrowinning solution which reduce the level of free chlorine. Examples of such compounds are thiourea, alkyl sulphonate surfactants and protein glues.