With Group Viii Metal Or Metal Oxide Patents (Class 208/137)
-
Patent number: 11673845Abstract: Embodiments of the present disclosure are directed to processes for aromatizing hydrocarbons includes contacting the hydrocarbons with a catalyst including at least two different metal modifiers dispersed on surfaces of a hydrogen-form medium-pore zeolite support. Each of the at least two different metal modifiers comprises a metal selected from the group consisting of IUPAC Groups 3-12, and lanthanide metals, and the catalyst is substantially free of gallium. Contacting the hydrocarbons with the catalyst causes a least a portion of the hydrocarbons to undergo a chemical reaction to form aromatic hydrocarbons.Type: GrantFiled: September 3, 2020Date of Patent: June 13, 2023Assignees: Saudi Arabian Oil Company, King Fahd University of Petroleum and MineralsInventors: Ziyauddin S. Qureshi, Yaming Jin, Abdullah M. Aitani, Omer Refa Koseoglu, Mohammad Naseem Akhtar, Hassan Saeed Al-Awad Alasiri
-
Patent number: 11439991Abstract: Processes for aromatizing hydrocarbons include contacting the hydrocarbons with a catalyst composition comprising a metal oxide dispersed on a surface of a zeolite support, where contacting the hydrocarbons with the catalyst composition causes at least a portion of the hydrocarbons to undergo a chemical reaction to form aromatic hydrocarbons. The catalyst composition is prepared by a synthesis process that includes combining the zeolite support with a hydrocarbon solvent to form a zeolite mixture, where the hydrocarbon solvent pre-wets the pores of the zeolite support. The synthesis process further includes combining a polar solvent comprising a metal salt with the zeolite mixture to form an impregnated zeolite support. The synthesis process also includes drying the impregnated zeolite support and calcining the impregnated zeolite support to convert the metal salt to the metal oxide, thereby forming the catalyst composition.Type: GrantFiled: December 19, 2019Date of Patent: September 13, 2022Assignees: King Fahd University of Petroleum & Minerals, Saudi Arabian Oil CompanyInventors: Palani Arudra, Abdullah M. Aitani, Yaming Jin, Omer Refa Koseoglu, Muhammad Naseem Akhtar
-
Patent number: 11040926Abstract: An integrated process for maximizing recovery of aromatics is provided. The process comprises passing at least a portion of a xylene column bottoms stream to a heavy aromatics column to provide a heavy aromatics column bottoms stream comprising C9+ aromatics and a heavy aromatics column overhead stream. The heavy aromatics column bottoms stream is passed to a second stage hydrocracking reactor of a two-stage hydrocracking reactor. In the second stage hydrocracking reactor, the heavy aromatics column bottoms stream is hydrocracked in the presence of a hydrocracking catalyst and hydrogen to provide a hydrocracked effluent stream.Type: GrantFiled: July 22, 2019Date of Patent: June 22, 2021Assignee: UOP LLCInventors: Gautam Pandey, Krishna Mani, Deepak Bisht, Priyesh Jayendrakumar Jani, Vikrant Vilasrao Dalal, Ram Ganesh Rokkam
-
Patent number: 10933406Abstract: A method of preparing large-size high-porosity Fe-doped photocatalytic porous magnetic microspheres, including: dissolving a soluble macromolecule in a distilled water to obtain a solution A having a concentration of 0.5-1.5 wt %; adding a photocatalyst to the solution A, and uniformly stirring the solution A to obtain a suspension B; mixing a saturated soluble ferric salt solution with the suspension B, and uniformly stirring the mixture to obtain a suspension C; dropwise adding the suspension C to a high-concentration alkali solution by a syringe equipped with a suitable needle size to form microspheres; ageing the reaction system and drying the formed microspheres after adding; calcining the dried microspheres at 600-1100° C.; cooling the calcined microspheres to obtain the large-size high-porosity Fe-doped photocatalytic porous magnetic microspheres.Type: GrantFiled: April 25, 2019Date of Patent: March 2, 2021Assignee: JIANGXI UNIVERSITY OF SCIENCE & TECHNOLOGYInventors: Honghui Jiang, Yiqun Deng, Hui Yang, Tongxiang Liang, Xiaopeng Qi, Zhuowu Zhen, Rigang Nie, Yucheng Lv, Wenyu Shen
-
Patent number: 10472577Abstract: A catalyst composition comprising a support comprising a mixture of amorphous silica-alumina and non-zeolitic alumina comprising no more than 75 wt % amorphous silica-alumina and having a ratio of moles of silicon to moles of aluminum in the range of about 0.05 to about 0.50. A first hydrogenation metal comprising platinum, a second hydrogenation metal from Group VIIB or Group VIII of the Periodic Table other than platinum and an optional third metal from Group IA of the Periodic Table may be deposited on the support. The ratio of moles of silicon to the moles of the first hydrogenation metal, the second hydrogenation metal and the optional third metal on the support may be between about 15 and about 75.Type: GrantFiled: June 22, 2017Date of Patent: November 12, 2019Assignee: UOP LLCInventors: Antoine Negiz, Shurong Yang, Richard R. Willis, Gregory J. Gajda, Suheil F. Abdo, Lisa M. Knight, Hayim Abrevaya, John A. Petri
-
Patent number: 9758734Abstract: The hydroisomerization of a paraffinic hydrocarbon feedstock obtained from renewable sources is effectively achieved by passing the feedstock in the presence of hydrogen over a hydroisomerization catalyst comprising a crystalline metal silicate molecular sieve, in which a portion of the crystalline framework contains iron.Type: GrantFiled: March 10, 2014Date of Patent: September 12, 2017Assignee: BASF CorporationInventors: Ivan Petrovic, Ahmad Moini, Scott Hedrick, Martin Kraus
-
Patent number: 9687824Abstract: To provide a heterogeneous catalyst that exhibits high activity and high selectivity, specifically a catalyst suitable for oxychlorination to produce 1,2-dichloroethane from ethylene, and a catalyst system. Provided are: a heterogeneous catalyst supported on a porous carrier, characterized in that the integral value of the hysteresis occurring between an adsorption isotherm and a desorption isotherm by a gas adsorption method, is at most 19% to the total integral value of the adsorption isotherm; and a catalyst system for producing 1,2-dichloroethane, which comprises this catalyst and a diluent having a spherical shape, circular cylindrical shape or hollow cylindrical shape.Type: GrantFiled: July 17, 2014Date of Patent: June 27, 2017Assignee: TOSOH CORPORATIONInventors: Tetsuo Asakawa, Sae Someya, Tomokazu Ohashi, Shinya Imatomi, Hideyuki Hamaji, Yoshihiko Mori, Motohiro Oguri
-
Patent number: 9005380Abstract: Disclosed is a high performance hydrocarbon fuel characterized by a hydrogen content greater than 14.3% by weight, a hydrogen to carbon atomic ratio greater than 2.0 and/or a heat of combustion greater than 18.7 KBtu/lb. The disclosed fuels generally have a paraffin content that is at least 90% by mass and a C12-C20 isoparaffin content of at least 40% by mass.Type: GrantFiled: November 7, 2012Date of Patent: April 14, 2015Assignee: Johann Haltermann LimitedInventor: Indresh Mathur
-
Patent number: 8933283Abstract: This invention relates to a petroleum refining method for producing high value-added clean petroleum products and aromatics (Benzene/Toluene/Xylene) together, by which low pollution petroleum products including liquefied petroleum gas or low-sulfur gas oil and aromatics can be efficiently produced together from a fluid catalytic cracked oil fraction.Type: GrantFiled: November 26, 2008Date of Patent: January 13, 2015Assignee: SK Innovation Co., Ltd.Inventors: Cheol Joong Kim, Jae Wook Ryu, Kyeong Hak Seong, Byoung Mu Chang, Byeung Soo Lim, Jong Hyung Lee, Kyung Seok Noh, Hyuck Jae Lee, Sam Ryong Park, Sun Choi, Seung Hoon Oh, Yong Seung Kim, Gyung Rok Kim
-
Patent number: 8926829Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.Type: GrantFiled: March 9, 2012Date of Patent: January 6, 2015Assignee: UOP LLCInventors: Manuela Serban, Antoine Negiz, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer, Gregory J. Gajda
-
Patent number: 8926830Abstract: Processes for producing aromatics from a naphtha feedstream are provided. An exemplary process includes passing the feedstream to a fractionation unit, thereby generating a first stream including hydrocarbons having less than 8 carbon atoms and a second stream including hydrocarbons having at least 8 carbon atoms. The first stream is passed to a first reformer operated at a first set of reaction conditions to generate a first product stream. The first set of reaction conditions includes a first temperature and a first pressure. The second stream is passed to a second reformer operated at a second set of reaction conditions to generate a second product stream. The second set of reaction conditions includes a second temperature and a second pressure. The first pressure is lower than the second pressure.Type: GrantFiled: April 3, 2013Date of Patent: January 6, 2015Assignee: UOP LLCInventors: Gregory J. Gajda, Mary J. Wier, Clayton Colin Sadler
-
Patent number: 8894842Abstract: The present invention concerns an optimized reforming catalyst comprising at least platinum, at least one promoter metal selected from the group formed by rhenium and iridium, at least one halogen, and at least one alumina support with a low sulphur and phosphorus content.Type: GrantFiled: October 17, 2011Date of Patent: November 25, 2014Assignee: IFP Energies NouvellesInventors: Sylvie Lacombe, Malika Boualleg, Eric Sanchez
-
Patent number: 8852428Abstract: The hydrorefining method of the invention is characterized by contacting, in the presence of hydrogen, a fuel stock comprising normal paraffins and oxygen-containing compounds, with a hydrorefining catalyst comprising a support containing USY zeolite and at least one solid acid selected from among silica-alumina, alumina-boria, silica-zirconia, silica-magnesia and silica-titania, and at least one metal selected from among metals of Group VIb and metals of Group VIII of the Periodic Table supported on the support.Type: GrantFiled: December 7, 2006Date of Patent: October 7, 2014Assignee: Nippon Oil CorporationInventors: Hiroyuki Seki, Masahiro Higashi
-
Patent number: 8845883Abstract: A process for reforming a hydrocarbon stream is presented. The process involves splitting a naphtha feedstream to at least two feedstreams and passing each feedstream to separation reformers. The reformers are operated under different conditions to utilize the differences in the reaction properties of the different hydrocarbon components. The process utilizes a common catalyst, and common downstream processes for recovering the desired aromatic compounds generated.Type: GrantFiled: March 9, 2012Date of Patent: September 30, 2014Assignee: UOP LLCInventors: Gregory J. Gajda, Kurt M. VandenBussche, Mark D. Moser, David A. Wegerer
-
Patent number: 8840779Abstract: A supported catalyst comprises a zeolite having a silica to alumina molar ratio of 500 or less, a first metal oxide binder having a crystallite size greater than 200 ? and a second metal oxide binder having a crystallite size less than 100 ?, wherein the second metal oxide binder is present in an amount less than 15 wt % of the total weight of the catalyst.Type: GrantFiled: February 7, 2011Date of Patent: September 23, 2014Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen J. McCarthy, Wenyih F. Lai, Darryl Donald Lacy, Robert Ellis Kay
-
Patent number: 8790507Abstract: Processes and catalyst systems are provided for dewaxing a hydrocarbon feedstock to form a lubricant base oil. A layered catalyst system of the present invention may comprise a first hydroisomerization dewaxing catalyst disposed upstream from a second hydroisomerization dewaxing catalyst. Each of the first and second hydroisomerization dewaxing catalysts may be selective for the isomerization of n-paraffins. The first hydroisomerization catalyst may have a higher level of selectivity for the isomerization of n-paraffins than the second hydroisomerization dewaxing catalyst. At least one of the first and second hydroisomerization dewaxing catalysts comprises small crystallite zeolite SSZ-32x.Type: GrantFiled: June 14, 2011Date of Patent: July 29, 2014Assignee: Chevron U.S.A. Inc.Inventors: Kamala Krishna, Guan-Dao Lei
-
Patent number: 8753503Abstract: One exemplary embodiment can be a process for producing a reformate by combining a stream having an effective amount of isopentane and a stream having an effective amount of naphtha for reforming. Generally, the naphtha has not less than about 95%, by weight, of one or more compounds having a boiling point of about 38-about 260° C. as determined by ASTM D86-07. The process may include introducing the combined stream to a reforming reaction zone. The combined stream can have an isopentane:naphtha mass ratio of about 0.10:1.00-about 1.00:1.00.Type: GrantFiled: July 24, 2008Date of Patent: June 17, 2014Assignee: UOP LLCInventors: Steven L. Krupa, Mark P. Lapinski, Clayton C. Sadler
-
Patent number: 8642496Abstract: The present invention relates to a method for forming a catalyst comprising catalytic nanoparticles and a catalyst support, wherein the catalytic nanoparticles are embedded in the catalyst support, comprising forming the catalytic nanoparticles on carbon particle, dispersing the carbon particle in a solution comprising precursors of the catalyst support to form a suspension, heating the suspension to form a gel, subjecting the gel to incineration to form a powder, and sintering the powder to form the catalyst.Type: GrantFiled: July 13, 2011Date of Patent: February 4, 2014Assignee: Agency for Science, Technology and ResearchInventors: Zetao Xia, Liang Hong, Wei Wang, Zhao Lin Liu
-
Publication number: 20130299388Abstract: The invention relates to a method for preparing a hydroconversion catalyst based on mesoporous silica or silica-alumina, comprising the following steps: (A) deposition of alumina on a mesoporous material having interconnected pores by treatment with at least one aluminium-based reactant, so as to obtain a compound having a Si/Al ratio of between 0.1 and 1000; (B) addition of at least one catalytically active species chosen from the group formed by the metals of group VIII and/or of group VIB; and (C) drying followed by thermal and/or chemical treatment according to the invention. The invention also relates to the catalyst thus obtained as well as a method of hydroconverting (hydrocracking, hydroisomerizing) a hydrocarbon feedstock, which comprises bringing the feedstock to be treated into contact with the hydroconversion catalyst according to the invention.Type: ApplicationFiled: December 23, 2011Publication date: November 14, 2013Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, TOTAL RAFFINAGE MARKETINGInventors: Metin Bulut, Régine Kenmogne-Gatchuissi, François Fajula, Jean-Pierre Dath, Sander Van Donk, Annie Finiels, Vasile Hulea
-
Patent number: 8569197Abstract: For preparing a reforming catalyst comprising a support, a group VIIIB metal and a group VIIB metal, comprises the following steps in the order a) then b) or b) then a): a step a) impregnating the support with an aqueous solution of hydrochloric acid comprising a group VIIIB metal; a step b) impregnating the support with an aqueous solution comprising a group VIIB metal and a sulphur-containing complexing agent in a reducing environment, or a step b) impregnation with an aqueous solution comprising a group VIIB metal, then with a solution comprising a sulphur-containing complexing agent in a reducing environment. The reducing environment is any reducing atmosphere comprising more than 0.1% by weight of a reducing gas or a mixture of reducing gases; or reducing solutions comprising, with respect to the group VIIB metal, in the range 0.1 to 20 equivalents of reducing metals, reducing organic compounds or inorganic reducing compounds.Type: GrantFiled: November 24, 2008Date of Patent: October 29, 2013Assignee: IFP Energies NouvellesInventor: Yohan Oudart
-
Patent number: 8569555Abstract: A hydrocarbon aromatization process comprising adding a nitrogenate, an oxygenate, or both to a hydrocarbon stream to produce an enhanced hydrocarbon stream, and contacting the enhanced hydrocarbon stream with an aromatization catalyst, thereby producing an aromatization reactor effluent comprising aromatic hydrocarbons, wherein the catalyst comprises a non-acidic zeolite support, a group VIII metal, and one or more halides. Also disclosed is a hydrocarbon aromatization process comprising monitoring the presence of an oxygenate, a nitrogenate, or both in an aromatization reactor, monitoring at least one process parameter that indicates the activity of the aromatization catalyst, modifying the amount of the oxygenate, the nitrogenate, or both in the aromatization reactor, thereby affecting the parameter.Type: GrantFiled: April 1, 2011Date of Patent: October 29, 2013Assignee: Chevron Phillips Chemical Company LPInventors: Christopher D. Blessing, Scott H. Brown, Tin-Tack Peter Cheung, David J. Glova, Daniel M. Hasenberg, Dennis L. Holtermann, Gyanesh P. Khare, Daniel B. Knorr, Jr.
-
Patent number: 8470165Abstract: Process for the production of high-quality kerosene and diesel fuels and for the coproduction of hydrogen from a so-called light naphtha cut to which any quantity of LPG cut can be added where the steps of the process include: separating normal and iso-paraffins, dehydrogenation of the paraffins, oligomerization of the olefins and hydrogenation of the oligomerized olefins, the process permitting the production of kerosene and diesel fuels meeting market specifications, or even improved relative to the latter.Type: GrantFiled: November 12, 2010Date of Patent: June 25, 2013Assignee: IFP Energies NouvellesInventors: Jean Cosyns, Annick Pucci, Quentin Debuisschert, Fabienne Le Peltier
-
Patent number: 8471083Abstract: A reforming process using a medium pore zeolite under conditions to facilitate the conversion of C8 paraffinic compounds to para-xylene is provided. Para-xylene is produced at greater than thermodynamic equilibrium concentrations using the process.Type: GrantFiled: January 11, 2013Date of Patent: June 25, 2013Assignee: Chevron U.S.A. Inc.Inventors: Cong-Yan Chen, Ann Jia-Bao Liang, Stephen Joseph Miller, James Nathan Ziemer
-
Patent number: 8425760Abstract: The invention concerns a process for converting a stream of natural or associated gas into liquid fractions, comprising: a) a step for converting said stream of gas into a synthesis gas SG; b) a step FT for Fischer-Tropsch synthesis to convert the SG into liquid fractions; c) a step for fractionating the effluents from the Fischer-Tropsch synthesis into at least one relatively heavy fraction comprising waxes with a boiling point of 565° C. or more and at least one relatively light fraction; d) a step HCKI for isomerization hydrocracking of the relatively heavy fraction, in which at least 75% by weight of the fraction of the feed with a boiling point of more than 565° C. is converted into compounds boiling below 565° C.; e) at least one step for mixing at least the effluents from step HCKI (step d)), the light fraction from step c) and a crude oil P, to thereby produce an oil P*.Type: GrantFiled: November 12, 2007Date of Patent: April 23, 2013Assignee: IFP Energies NouvellesInventors: Eric Lenglet, Patrick Chaumette
-
Patent number: 8404105Abstract: One exemplary embodiment can be a process for facilitating a transfer of a metal catalyst component from at least one donor particle to at least one recipient particle in a catalytic naphtha reforming unit. The process can include transferring an effective amount of the metal catalyst component from the at least one donor particle to the at least one recipient particle under conditions to effect such transfer to improve a conversion of a hydrocarbon feed.Type: GrantFiled: February 11, 2011Date of Patent: March 26, 2013Assignee: UOP LLCInventors: Mark P. Lapinski, Gregory J. Gajda, Jeffry T. Donner, Richard R. Rosin, Marc R. Scheier, Simon R. Bare
-
Patent number: 8404104Abstract: A method for obtaining an olefin is disclosed, the method comprising subjecting a paraffin to dehydrogenation in the absence of oxygen and in the presence of a catalyst comprising a crystalline substrate, to obtain an olefin. The catalyst includes an inert stabilizing agent for maintaining the catalyst crystal structure. The catalyst may be regenerated by being subjected, in air, to a temperature between about 550° C. and about 750° C., for a period of time between about 15 minutes and about 4 hours.Type: GrantFiled: June 22, 2009Date of Patent: March 26, 2013Assignee: UOP LLCInventors: Wei Pan, Stephen M. Casey, Bryan K. Glover, Feng Xu
-
Publication number: 20130066125Abstract: A method of extending the life of an aromatization catalyst comprising identifying a rapid deactivation threshold (RDT) of the catalyst, and oxidizing the catalyst prior to reaching the RDT. A method of aromatizing a hydrocarbon comprising identifying a rapid deactivation threshold (RDT) for an aromatization catalyst, and operating an aromatization reactor comprising the catalyst to extend the Time on Stream of the reactor prior to reaching the RDT. A method of extending the life of an aromatization catalyst comprising predicting a rapid deactivation threshold (RDT) for an aromatization reactor by employing the catalyst in a reactor system under an accelerated fouling condition to identify a test rapid deactivation threshold (t-RDT), predicting the RDT for the aromatization reactor based upon the t-RDT, and oxidizing the catalyst prior to the predicted RDT to extend the Time on Stream of the aromatization catalyst.Type: ApplicationFiled: September 13, 2012Publication date: March 14, 2013Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventors: Scott H. BROWN, Tin-Tack Peter CHEUNG, Daniel P. HAGEWIESCHE, Baiyi ZHAO
-
Patent number: 8362310Abstract: A hydrocarbon aromatization process comprising adding a nitrogenate, an oxygenate, or both to a hydrocarbon stream to produce an enhanced hydrocarbon stream, and contacting the enhanced hydrocarbon stream with an aromatization catalyst, thereby producing an aromatization reactor effluent comprising aromatic hydrocarbons, wherein the catalyst comprises a non-acidic zeolite support, a group VIII metal, and one or more halides. Also disclosed is a hydrocarbon aromatization process comprising monitoring the presence of an oxygenate, a nitrogenate, or both in an aromatization reactor, monitoring at least one process parameter that indicates the activity of the aromatization catalyst, modifying the amount of the oxygenate, the nitrogenate, or both in the aromatization reactor, thereby affecting the parameter.Type: GrantFiled: April 1, 2011Date of Patent: January 29, 2013Assignee: Chevron Phillips Chemical Company LPInventors: Christopher D. Blessing, Scott H. Brown, Tin-Tack Peter Cheung, David J. Glova, Daniel M. Hasenberg, Dennis L. Holtermann, Gyanesh P. Khare, Daniel B. Knorr, Jr.
-
Patent number: 8318000Abstract: A method of producing a crude product from a hydrocarbon feed is provided. A hydrocarbon feed is contacted with a catalyst containing a Col. 6-10 metal or compound thereof to produce the crude product, where the catalyst has a pore size distribution with a median pore diameter ranging from 105 ? to 150 ?, with 60% of the total number of pores in the pore size distribution having a pore diameter within 60 ? of the median pore diameter, with at least 50% of its pore volume in pores having a pore diameter of at most 600 ?, and between 5% and 25% of its pore volume in pores having a pore diameter between 1000 ? and 5000 ?.Type: GrantFiled: January 11, 2012Date of Patent: November 27, 2012Assignee: Shell Oil CompanyInventors: Opinder Kishan Bhan, Scott Lee Wellington
-
Patent number: 8309778Abstract: The present invention provides a catalyst comprising metallic Pt and/or Pd supported on a binder-free zeolite for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock, wherein the amount of metallic Pt and/or Pd is of 0.01-0.8 wt %, preferably 0.01-0.5 wt % on the basis of the total weight of the catalyst, and the binder-free zeolite is selected from the group consisting of mordenite, beta zeolite, Y zeolite, ZSM-5, ZSM-11 and composite or cocrystal zeolite thereof. The present invention also provides a process for producing light aromatic hydrocarbons and light alkanes from hydrocarbonaceous feedstock using said catalyst.Type: GrantFiled: November 7, 2011Date of Patent: November 13, 2012Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical Technology SinopecInventors: Deju Wang, Zhongneng Liu, Xueli Li, Minbo Hou, Zheming Wang, Jianqiang Wang
-
Patent number: 8282815Abstract: The invention relates to a method of treating feedstocks from renewable sources without intermediate gas-liquid separation in order to produce diesel fuel bases of excellent quality. The feedstocks used can be raw vegetable oils or such oils that have been previously subjected to a prerefining stage, animal fats, or mixtures of such feedstocks. The invention relates to a method allowing high diesel fuel base yields to be obtained from such feedstocks.Type: GrantFiled: June 24, 2009Date of Patent: October 9, 2012Assignee: IFP Energies nouvellesInventors: Christophe Bouchy, Antoíne Daudin, Emmanuelle Guillon, Nathalie Dupassieux, Thierry Chapus
-
Patent number: 8206576Abstract: The present invention relates to a nickel-based catalyst using hydrotalcite-like precursor and a steam reforming reaction by using the catalyst, and particularly to a nickel-based catalyst prepared by dispersing nickel uniformly onto the inner part and the surface of the support through a substitution between the magnesium and the active nickel metal and optimizing the molar ratios of nickel, magnesium and aluminum in order to utilize nickel as an active metal and a hydrotalcite-like precursor consisting of aluminum and magnesium, which shows an increased specific surface area of the catalyst and surface area of the active nickel, and thus enables the production of hydrogen-rich gas in high yield during the steam reforming reaction of LPG with superior maintenance of catalytic activity for a long period of time due to the inhibition of carbon deposition.Type: GrantFiled: October 9, 2006Date of Patent: June 26, 2012Assignee: SK Innovation Co., Ltd.Inventors: Dong Ju Moon, Dae Hyun Kim, Jung Shik Kang, Jong Woo Ryu, Byung Gwon Lee, Young-Seek Yoon, Byong-Sung Kwak
-
Patent number: 8202815Abstract: In one embodiment, a catalyst composition comprises from about 5 weight percent to about 70 weight percent of silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal. In another embodiment, a method for processing hydrocarbons comprises hydro-treating the hydrocarbons in the presence of a catalyst composition, wherein the catalyst comprises from about 5 weight percent to about 70 weight percent silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal.Type: GrantFiled: December 26, 2008Date of Patent: June 19, 2012Assignee: General Electric CompanyInventors: Gregg Anthony Deluga, Daniel Lawrence Derr
-
Patent number: 7981274Abstract: A catalytic element useful for promoting catalytic gas phase reactions is provided, comprising a porous ceramic body comprising a multiplicity of open pores having a coating comprising a basic oxide material and a catalyst material selected from transition metal and noble metal compounds.Type: GrantFiled: July 21, 2008Date of Patent: July 19, 2011Assignee: Pall CorporationInventors: Manfred Nacken, Steffen Heidenreich
-
Patent number: 7976698Abstract: Process for catalytic conversion in the presence of hydrogen with regeneration of the catalyst that comprises a stage for reduction of said catalyst by the hydrogen that is obtained from the catalytic conversion stage, whereby this hydrogen is purified in advance of impurities that it contains by running it over adsorbent masses, whereby said adsorbent masses are regenerated by an increase in temperature that is provided by the effluent from the reduction stage of the catalyst. Application to the processes for regenerative reforming or dehydrogenation of paraffins and naphthenes and most generally to any moving-bed process that operates in the presence of hydrogen.Type: GrantFiled: January 24, 2003Date of Patent: July 12, 2011Assignee: IFP Energies nouvellesInventors: Béatrice Fischer, Frédéric Hoffmann, Michel Thomas
-
Patent number: 7959796Abstract: Contact of a crude feed with one or more catalysts produces a total product that include a crude product. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more other properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.Type: GrantFiled: December 16, 2004Date of Patent: June 14, 2011Assignee: Shell Oil CompanyInventors: Opinder Kishan Bhan, Scott Lee Wellington
-
Patent number: 7909988Abstract: One exemplary embodiment can be a process for facilitating a transfer of a metal catalyst component from at least one donor particle to at least one recipient particle in a catalytic naphtha reforming unit. The process can include transferring an effective amount of the metal catalyst component from the at least one donor particle to the at least one recipient particle under conditions to effect such transfer to improve a conversion of a hydrocarbon feed.Type: GrantFiled: April 17, 2008Date of Patent: March 22, 2011Assignee: UOP LLCInventors: Mark P. Lapinski, Gregory J. Gajda, Jeffry T. Donner, Richard R. Rosin, Marc R. Schreier, Simon R. Bare
-
Patent number: 7901565Abstract: A method of reforming a sulfur containing hydrocarbon involves contacting the sulfur containing hydrocarbon with a sulfur tolerant catalyst containing a sulfur tolerant precious metal and a non-sulfating carrier so that the sulfur tolerant catalyst adsorbs at least a portion of sulfur in the sulfur containing hydrocarbon and a low sulfur reformate is collected, and contacting the sulfur tolerant catalyst with an oxygen containing gas to convert at least a portion of adsorbed sulfur to a sulfur oxide that is desorbed from the sulfur tolerant catalyst.Type: GrantFiled: July 11, 2006Date of Patent: March 8, 2011Assignee: BASF CorporationInventors: Thomas Giroux, Earl Waterman, Robert Joseph Farrauto
-
Patent number: 7901566Abstract: A method of reforming a sulfur containing hydrocarbon involves contacting the sulfur containing hydrocarbon with a sulfur tolerant catalyst containing a non-sulfating carrier and one or more of a sulfur tolerant precious metal and a non-precious metal compound so that the sulfur tolerant catalyst adsorbs at least a portion of sulfur in the sulfur containing hydrocarbon and a low sulfur reformate is collected, and contacting the sulfur tolerant catalyst with an oxygen containing gas to convert at least a portion of adsorbed sulfur to a sulfur oxide that is desorbed from the sulfur tolerant catalyst.Type: GrantFiled: July 11, 2007Date of Patent: March 8, 2011Assignee: BASF CorporationInventors: Thomas Giroux, Earl Waterman, Robert Joseph Farrauto
-
Patent number: 7892500Abstract: A system and method for recycling plastics. The system and method recover materials such as hydrocarbon gases, liquid hydrocarbon distillates, various polymers and/or monomers used to produce the original plastics. The system and method allow about one unit of input of energy input to the plastic recycler to be used to create one or more gaseous components and one or more liquid distillate components from a plastic that is being recycled. The one or more gaseous components and one or more liquid distillate components produce about one corresponding unit of useable output energy recovered from the recycling of the plastic.Type: GrantFiled: November 18, 2009Date of Patent: February 22, 2011Inventor: William E. Carner
-
Patent number: 7892417Abstract: The present invention relates to a catalyst for reforming a hydrocarbon comprising a carrier containing manganese oxide and carried thereon (a) at least one component selected from a ruthenium component, a platinum component, a rhodium component, a palladium component, an iridium component and a nickel component and a process for producing the same and to a process for reforming a hydrocarbon (steam reforming, self thermal reforming, partial oxidation reforming and carbon dioxide reforming) using the above catalyst. Provided are a catalyst for reforming a hydrocarbon which comprises ruthenium, platinum, rhodium, palladium, iridium or nickel as an active component and in which a reforming activity is elevated, a process for producing the same, and a steam reforming process, a self thermal reforming process, a partial oxidation reforming process and a carbon dioxide reforming process for a hydrocarbon using the above catalyst.Type: GrantFiled: April 17, 2008Date of Patent: February 22, 2011Assignee: Idemitsu Kosan, Co., Ltd.Inventors: Tetsuya Fukunaga, Tomoki Yanagino, Kozo Takatsu, Takashi Umeki
-
Patent number: 7850842Abstract: The invention relates to a process for preparing a catalyst support, in which zirconium dioxide powder is mixed with a binder, if desired a pore former, if desired an acid, water and, if desired, further additives to give a kneadable composition and the composition is homogenized, shaped to produce shaped bodies, dried and calcined, wherein the binder is a monomeric, oligomeric or polymeric organosilicon compound. Suitable binders are monomeric, oligomeric or polymeric silanes, alkoxysilanes, aryloxysilanes, acryloxysilanes, oximinosilanes, halosilanes, aminoxysilanes, aminosilanes, amidosilanes, silazanes or silicones. The invention also provides the catalyst support which has been prepared in this way, a catalyst comprising the support and its use as dehydrogenation catalyst.Type: GrantFiled: May 2, 2003Date of Patent: December 14, 2010Assignee: BASF AktiengesellschaftInventors: Otto Hofstadt, Michael Hesse, Götz-Peter Schindler, Klaus Harth, Falk Simon
-
Patent number: 7837863Abstract: Contact of a crude feed with one or more catalysts produces a total product that include a crude product. The crude feed has a total content of alkali metal, and alkaline-earth metal, in metal salts of organic acids of at least 0.00001 grams per gram of crude feed. At least one of the catalysts includes vanadium. The crude product is a liquid mixture at 25° C. and 0.101 MPa and has a total content of alkali metal, and alkaline-earth metal, in metal salts of organic acids of at most 90% of the total content of alkali metal, and alkaline-earth metal, in metal salts of organic acids of the crude feed. One or more other properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.Type: GrantFiled: December 16, 2004Date of Patent: November 23, 2010Assignee: Shell Oil CompanyInventors: Opinder Kishan Bhan, Scott Lee Wellington
-
Patent number: 7780845Abstract: The instant invention relates to a process to produce low sulfur distillate products through the hydrotreating of distillate boiling range feedstreams in the presence of a bulk metal hydrotreating catalyst.Type: GrantFiled: April 1, 2005Date of Patent: August 24, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Stuart L. Soled, Sabato Miseo, Sonja Eijsbouts
-
Patent number: 7776205Abstract: The instant invention relates to a process to produce liquid products through the hydroprocessing of hydrocarbonaceous feedstreams in the presence of a bulk metal hydroprocessing catalyst.Type: GrantFiled: April 1, 2005Date of Patent: August 17, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Stuart L. Soled, Sabato Miseo, Sonja Eijsbouts
-
Patent number: 7771586Abstract: A strontium-doped, calcium-alumina nickel supported reforming catalyst is useful for reforming reactions when it is desired to generate a low H2/CO ratio synthesis gas and to reduce coking. The catalyst can generate a synthesis gas having a H2/CO ratio of less than about 2.3. The catalyst includes alumina, from about 0.3 wt. % to about 35 wt. % of calcium oxide, from about 0.1 wl % to about 35 wt. % of a strontium promoter, and about 0.5 wt. % to about 30 wt. % nickel. The support is prepared by a method wherein the calcium oxide is combined with the alumina to form aluminum-rich calcium aluminates.Type: GrantFiled: June 11, 2007Date of Patent: August 10, 2010Assignee: Sud-Chemie Inc.Inventors: Chandra Ratnasamy, Yeping Cai, William M. Faris, Jürgen R. Ladebeck
-
Patent number: 7704379Abstract: The present invention relates to a process for converting Fischer-Tropsch wax to high quality lube basestocks using a molecular sieve Beta catalyst followed by a unidimensional intermediate pore molecular sieve with near circular pore structures having an average diameter of 0.50 nm to 0.65 nm wherein the difference between the maximum diameter and the minimum is ?0.05 nm. Both catalysts comprise one or more Group VIII metals. For example, a cascaded two-bed catalyst system consisting of a first bed Pt/Beta catalyst followed by a second bed Pt/ZSM-48 catalyst is highly selective for wax isomerization and lube hydrodewaxing with minimal gas formation.Type: GrantFiled: October 8, 2002Date of Patent: April 27, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Zhaozhong Jiang, Terry Eugene Helton, Randall David Partridge, Larry E. Hoglen
-
Patent number: 7686946Abstract: One exemplary embodiment can include a method of altering a feed to a transalkylation zone by changing a destination of a stream rich in an aromatic C9 for increasing production of at least one of benzene, toluene, para-xylene, and an aromatic gasoline blend. The method can include providing the stream rich in an aromatic C9 from a first fractionation zone that receives an effluent from a second fractionation zone. The second fractionation zone may produce a stream rich in at least one of benzene and toluene. The stream rich in the aromatic C9 can be at least partially comprised in at least one of the feed to the transalkylation zone and the aromatic gasoline blend.Type: GrantFiled: August 17, 2007Date of Patent: March 30, 2010Assignee: UOP LLCInventor: Lubo Zhou
-
Patent number: 7670476Abstract: Process to optimize the yield of gas oils from a Fischer-Tropsch derived feed by performing the following steps: (a) performing a hydroconversion/hydroisomerisation step on part of the Fischer-Tropsch derived feed; (b) performing a hydroconversion/hydroisomerisation step on another part of the Fischer-Tropsch feed at a conversion greater than the conversion in step (a); and (c) isolating by means of distillation a gas oil fraction from the two reaction products obtained in steps (a) and (b).Type: GrantFiled: November 18, 2005Date of Patent: March 2, 2010Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Arend Hoek, Lip Piang Kueh
-
Patent number: H2244Abstract: A reforming process in which a hydrocarbon feed containing aliphatic hydrocarbons is converted to a hydrocarbon product comprising an increased proportion of aromatics by passage over a reforming catalyst in a sequence of moving bed reactors operating under reforming conditions including moderate hydrogen pressure. The process is applicable when a former fixed moving bed reformer has been converted to moving bed reactor operation with the recycle and other ancillary equipment retained so that moderate pressure (hydrogen partial pressure at least 11 barg) is required, usually with a catalysts such as Pt/Re which tend to exhibit excessive hydrogenolysis activity in moving bed service. The recycle hydrogen stream is split with a portion going to at least one reactor subsequent to the first reactor.Type: GrantFiled: March 22, 2005Date of Patent: August 3, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Russell T. Clay, Stuart S. Goldstein