Catalytic Patents (Class 208/143)
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Patent number: 7918992Abstract: Methods and systems for contacting of a crude feed with one or more catalysts to produce a total product that includes a crude product are described. The crude product is a liquid mixture at 25° C. and 0.101 MPa. The crude product has an MCR content of at most 90% of the MCR content of the crude feed. One or more other properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.Type: GrantFiled: April 7, 2006Date of Patent: April 5, 2011Assignee: Shell Oil CompanyInventor: Opinder Kishan Bhan
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Patent number: 7892500Abstract: A system and method for recycling plastics. The system and method recover materials such as hydrocarbon gases, liquid hydrocarbon distillates, various polymers and/or monomers used to produce the original plastics. The system and method allow about one unit of input of energy input to the plastic recycler to be used to create one or more gaseous components and one or more liquid distillate components from a plastic that is being recycled. The one or more gaseous components and one or more liquid distillate components produce about one corresponding unit of useable output energy recovered from the recycling of the plastic.Type: GrantFiled: November 18, 2009Date of Patent: February 22, 2011Inventor: William E. Carner
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MCM-22 family molecular sieve composition, its method of making, and use for hydrocarbon conversions
Patent number: 7883686Abstract: This disclosure relates to a crystalline MCM-22 family molecular sieve having a platelet aggregates morphology wherein greater than 50 wt % of the molecular sieve having a crystal diameter greater than 1 ?m as measured by the SEM. The crystalline MCM-22 family molecular sieve of this disclosure, wherein the platelet aggregates morphology is rosette habit morphology, or multiple layer plate's morphology.Type: GrantFiled: June 28, 2007Date of Patent: February 8, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Wenyih Frank Lai, Robert Ellis Kay, Mohan Kalyanaraman -
Patent number: 7879223Abstract: Contact of a crude feed with a hydrogen source in the presence of an inorganic salt catalyst produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The inorganic salt catalyst may includes one or more alkali metal salts and/or one or more alkaline-earth metal salts. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.Type: GrantFiled: December 16, 2004Date of Patent: February 1, 2011Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Thomas Fairchild Brownscombe
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Publication number: 20110000822Abstract: The present invention relates to a process for starting up a hydrotreating process using a bulk metal catalyst, said process comprising the steps of: i) providing a hydrocarbon feed stream containing less than 100 ppmw nitrogen-containing species; ii) adding a nitrogen-containing compound to said hydrocarbon feed stream; and iii) contacting the resultant feed stream with the bulk metal catalyst in the presence of hydrogen and a sulfur-containing species. The present invention also relates to a process for hydrotreating a hydrocarbon feedstock, said process comprising the steps of: i) providing a hydrocarbon feed stream containing less than 100 ppmw nitrogen-containing species; ii) adding a nitrogen-containing compound to said hydrocarbon feed stream; iii) contacting the resultant feed stream with a bulk metal catalyst in the presence of hydrogen and a sulfur-containing species; and iv) subsequently contacting the resultant bulk metal catalyst with the hydrocarbon feedstock in the presence of hydrogen.Type: ApplicationFiled: November 19, 2008Publication date: January 6, 2011Inventors: László Domokos, Hermanus Jongkind, Pieter Van Der Laan, Marcello Stefano Rigutto
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Patent number: 7854833Abstract: The present invention is directed to a method for producing a crude product from a crude feed. A crude feed is contacted with a hydrogen source and a catalyst comprising a transition metal sulfide under conditions controlled such that the crude product has a residue content of at most the 30% of the residue content of the crude feed.Type: GrantFiled: May 12, 2008Date of Patent: December 21, 2010Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Stanley Nemec Milam
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Patent number: 7854834Abstract: The invention relates to a catalyst consisting of at least: one matrix comprising at least one oxide which is selected from an amorphous oxide, an oxide with low crystallinity and a mixture of both; at least one solid microporous crystalline material which, in the calcined and anhydrous state, has the molar compositions X2O3:nYO2:mZO2, in which X is a trivalent element such as, for example, Al, B, Fe, In, Ga, Cr, Y is at least one trivalent element that is different from Ge and Z is Ge, the value (n+m) is at least equal to 5 and can be between 5 and ?, and the value of n/m is at least equal to 1; and at least one hydrogenating compound, preferably Pt, Pd, Ir, Ru, Rh, and Re or a combination of same. The invention also relates to the use of said catalyst in a process in order to improve the quality of diesel fractions.Type: GrantFiled: August 25, 2009Date of Patent: December 21, 2010Assignees: Consejo Superior de Invetigaciones Cientificas, Universidad Politenica de ValenciaInventors: Avelino Corma Canos, Agustin Martinez Feliu, Fernando Rey García, María José Díaz Cabañas, Maria de los Desamparados Arribas Viana
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Publication number: 20100314295Abstract: The catalyst comprises at least a metal component and at least a non-metallic conducting component as supplement component. The metal component generally contains one or more metals of the groups VIb, VIIb or VIIIb of the periodic table. The supplement component is e.g. a conducting carbon material like graphite, a conducting polymer or a conducting metal oxide. Preferably it is hydrophobic or made hydrophobic. The catalyst is used for hydroprocessing of bio-feedstock like vegetable oils to produce fuels, which are aliphatic hydrocarbons comparable to conventional fuel from mineral oil.Type: ApplicationFiled: June 24, 2009Publication date: December 16, 2010Inventors: Gerd Sandstede, Thomas Lehmann
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Patent number: 7842262Abstract: A reactor in which a multi-phase mixture, including gas and a catalyst slurry or liquid, is to be conducted. The reactor includes a reaction chamber having a substantially unencumbered center portion through which the multi-phase mixture is conducted upwardly. A downcomer arrangement is disposed laterally outwardly of the center portion and adjacent to an inner surface of the reaction chamber. An external pump communicates with a lower portion of the reaction chamber for circulating components of the mixture downward from an upper end of the downcomer arrangement to a lower end thereof. A collection chamber is disposed below the reaction chamber into which the components exiting the downcomer arrangement are introduced and where the gas is separated from the remainder of the components. The separated gas can be reintroduced into the reaction chamber.Type: GrantFiled: December 19, 2007Date of Patent: November 30, 2010Assignee: Chevron U.S.A. Inc.Inventor: Abdenour Kemoun
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Publication number: 20100276338Abstract: A process for preparing a bulk multi-metallic catalyst for hydrotreating heavy oil feeds is provided. The catalyst is particularly suitable for hydrotreating heavy oil feeds having a boiling point in the range of 343° C. (650° F.)- to 454° C. (850° F.), an average molecular weight Mn ranging from 300 to 400, and an average molecular diameter ranging from 0.9 nm to 1.7 nm. The bulk multi-metallic catalyst is prepared by sulfiding a catalyst precursor that has an essentially monomodal pore volume distribution with at least 95% of the pores being macropores, and having a total pore volume of at least 0.08 g/cc.Type: ApplicationFiled: April 29, 2009Publication date: November 4, 2010Inventors: Dennis Dykstra, Alexander E. Kuperman, Theodorus Maesen, Soy Uckung, Darren Fong
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Publication number: 20100236986Abstract: The invention concerns a catalyst comprising a porous support, palladium, at least one metal selected from the group constituted by alkalis and alkaline-earths, in which: the specific surface area of the porous support is in the range 50 to 210 m2/g; the palladium content in the catalyst is in the range 0.05% to 2% by weight; at least 80% by weight of the palladium is distributed in a crust at the periphery of the support, the thickness of said crust being in the range 20 to 200 ?m; the metallic dispersion D is in the range 25% to 70%; the density of the palladium particles in the crust is in the range 1500 to 4100 particles of palladium per ?m2; and said alkali and/or alkaline-earth metal is distributed homogeneously across the support. The invention also concerns the preparation of the catalyst and its use in selective hydrogenation.Type: ApplicationFiled: October 24, 2008Publication date: September 23, 2010Applicant: IFPInventors: Lars Fischer, Carine Petit-Clair, Cecile Thomazeau, Lois Sorbier, Catherine Verdon
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Patent number: 7794588Abstract: A process is provided for producing low sulfur diesel having a reduced poly-aromatic level where at least a portion of the poly-aromatics are converted to mono-aromatics. In one aspect, the process separates the temperature and pressure requirements for obtaining low levels of sulfur from the temperature and pressure requirements to saturate poly-aromatics to mono-aromatics. By one approach, the process first converts a diesel boiling range hydrocarbon stream in a hydrotreating zone at conditions effective to produce a hydrotreating zone effluent having a reduced concentration of sulfur with minimal saturation of poly-aromatics. Hydrogen is then admixed in the hydrotreating zone effluent or at least a portion thereof, which is then reacted in a substantially liquid-phase continuous reaction zone to effect saturation of poly-aromatics to provide a liquid-phase continuous reaction zone effluent having a reduced level of poly-aromatics relative to the diesel feed.Type: GrantFiled: October 15, 2007Date of Patent: September 14, 2010Assignee: UOP LLCInventors: Peter Kokayeff, Laura Elise Leonard, Michael Roy Smith
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Publication number: 20100224535Abstract: A supported carbon having high surface area, high pore volume containing (i) molybdenum (ii) a metal of non noble Group VIII, (iii) phosphorous, is used for hydrometallization of heavy crude oil and residue. The catalyst contains about 6 to 15 wt % molybdenum as MoO3, about 1 to 6 wt % cobalt or nickel as CoO or NiO and phosphorus as phosphorous oxide. One characteristic of the catalyst is the portion of pores having pore diameter in the range of 200 to 2000 Angstrom of 20 percent or more. The catalyst prepared by chelating agent has higher hydrodesulfurization activity assuming that more dispersed active metals are present on this catalyst. Long run activity studies show that catalyst having only molybdenum supported on activated carbon has good stability with time-on-stream and very high metal retention capacity.Type: ApplicationFiled: March 3, 2010Publication date: September 9, 2010Applicants: INSTITUTO MEXICANO DEL PETROLEO, TOYO ENGINEERING CORPORATIONInventors: Samir Kumar Maity, Jorge Ancheyta Juárez, Fernando Alonso Martínez, Hidetsugu Fukuyama, Satoshi Terai, Masayuki Uchida
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Patent number: 7790020Abstract: A process is provided for producing low sulfur diesel having a high cetane number where the temperature and pressure requirements for obtaining low levels of sulfur is separated from the temperature and pressure requirements for improving cetane. In one aspect, a low pressure hydrodesulfurization zone and a high pressure aromatic saturation zone are employed to sequentially achieve the desired sulfur and cetane levels. In another aspect, the process first converts a diesel boiling range hydrocarbonaceous stream in a hydrotreating zone at conditions effective to produce a hydrotreating zone effluent having a reduced concentration of sulfur with minimal saturation of aromatics. Hydrogen is then admixed with the hydrotreating zone effluent, which is then reacted in a substantially liquid-phase continuous reaction zone substantially undiluted with other streams to effect saturation of aromatics to provide a liquid-phase continuous reaction zone effluent having an improved cetane number.Type: GrantFiled: October 15, 2007Date of Patent: September 7, 2010Assignee: UOP LLCInventors: Peter Kokayeff, Laura Elise Leonard, Michael Roy Smith
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Publication number: 20100213103Abstract: System and relative process for the complete and high productivity hydroconversion of heavy oils essentially consisting of a solid accumulation reactor and a stripping section of the conversion products outside or inside the reactor itself. In particular, the system proposed consists of a solid accumulation hydroconversion reactor in which the solids deriving from and generated by the feedstock treated (metals in the form of sulphides and coke) are accumulated, up to very high levels, and a hot gas stripping section of the reaction liquid, designed in relation to the type of reactor adopted, for the direct and continuous removal of the conversion products, including high-boiling products.Type: ApplicationFiled: May 19, 2008Publication date: August 26, 2010Applicant: ENI S.P.A.Inventors: Luigi Patron, Giuseppe Bellussi, Lorenzo Tagliabue, Vincenzo Piccolo
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Publication number: 20100200462Abstract: An aromatics hydrogenation catalyst composition which comprises a noble metal component and a support comprising zirconia, silica, and, optionally, alumina. The catalyst composition is manufactured by co-mulling silica, a zirconium compound, and, optionally, alumina to form a mixture that is formed into a shape, such as by extrusion to form an extrudate, with the shape being calcined and noble metal being incorporated into the shape. The catalyst composition may be used in the saturation of aromatic compounds.Type: ApplicationFiled: April 21, 2010Publication date: August 12, 2010Inventors: John Anthony SMEGAL, Johannes Anthonius Robert Van Veen
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Patent number: 7763164Abstract: This invention focuses on the specialized catalyst and/or additive for lower FCCU gasoline and diesel blendstock component sulfur content. This invention utilizes a specified ratio of the transition metal oxides of cobalt and molybdenum to accomplish gasoline and diesel blendstock sulfur reduction. This is accomplished by minimizing sulfur compound formation in the FCCU riser. The cobalt and molybdenum oxides in the presence of H2S from cracked organic sulfur compounds are converted to metal sulfides. A portion of the overall sulfur reduction in the gasoline and diesel blendstock occurs emitted NOx also is reduced.Type: GrantFiled: May 3, 2007Date of Patent: July 27, 2010Assignee: Marathon Petroleum Company LLCInventors: William Jay Turner, Ronald Lee Cordle, David J. Zalewski, Jeffrey A. Sexton
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Patent number: 7763160Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The one or more catalysts include a transition metal sulfide catalyst. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.Type: GrantFiled: December 16, 2004Date of Patent: July 27, 2010Inventors: Scott Lee Wellington, Stanley Nemec Milam
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Publication number: 20100176030Abstract: The present invention discloses an alumina support having multiple pore structure, wherein the alumina support has a specific surface area of from 40 to 160 m2/g and a total pore volume of from 0.3 to 1.2 cm3/g; a pore volume of pores having a pore diameter of less than 30 nm comprises 5 to 60% of the total pore volume; a pore volume of pores having a pore diameter of from 30 to 60 nm comprises 20 to 75% of the total pore volume; and a pore volume of pores having a pore diameter of larger than 60 nm comprises 20 to 60% of the total pore volume. The present invention further discloses a catalyst used for selective hydrogenation of a pyrolysis gasoline, comprising: (a) the alumina support according to the invention; and (b) 0.01 to 1.2 wt. % of metal palladium or palladium oxides, based on the weight of the alumina support.Type: ApplicationFiled: August 2, 2007Publication date: July 15, 2010Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, SHANGHAN RESEARCH INSTITUTE OF PETROCHEMICAL TECHNOLOGYInventors: Zhongneng Liu, Zaiku Xie, Xinghua Jiang, Xiaoling Wu, Minbo Hou, Hongyuan Zong
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Publication number: 20100147740Abstract: A process comprising regenerating a used ionic liquid catalyst, recovering conjunct polymer from the regenerated catalyst and using at least a portion of the conjunct polymer is disclosed.Type: ApplicationFiled: December 16, 2008Publication date: June 17, 2010Inventors: Saleh A. Elomari, Hye-Kyung C. Timken
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Patent number: 7736492Abstract: A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into monounsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds, said process employing a supported catalyst comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form, deposited on a specific support comprising a metal aluminate of the MAl2O4 type with a metal M selected from the group constituted by nickel and cobalt, and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h?1 to 10 h?1 and at a pressure in the range of 0.5 to 5 MPa.Type: GrantFiled: December 21, 2006Date of Patent: June 15, 2010Assignee: Institut Francais du PetroleInventors: Christophe Bouchy, Florent Picard, Nathalie Marchal
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Publication number: 20100133147Abstract: A supported and sulphur-containing catalyst is described, comprising; a porous support constituted by an organic-inorganic hybrid material for which the covalent bond between the organic and inorganic phases conforms to the formula M-O—Z—R where M represents at least one metal constituting the inorganic phase, Z at least one heteroelement from among phosphorus and silicon and R an organic fragment, at least one metal of group VIB and/or of group VB and/or of group VIII. The invention also relates to the use of this catalyst for the hydrorefining and the hydroconversion of hydrocarbon-containing feedstocks such as petroleum fractions, fractions from coal or biomass or hydrocarbons produced from natural gas.Type: ApplicationFiled: July 6, 2007Publication date: June 3, 2010Inventors: Alexandra Chaumonnot, Denis Guillaume, Benoit Fremon, Karin Marchand, Renaud Revel
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Patent number: 7727378Abstract: A process to prepare a waxy raffinate product by performing the following steps: (a) subjecting a Fischer-Tropsch derived product having a weight ratio of compounds boiling above 540° C. and compounds boiling between 370 and 540° C. of greater than 2 to a hydroconversion step and (b) fractionating the effluent of step (a) to obtain products boiling in the fuels range and a waxy raffinate product boiling between 350 and 600° C.Type: GrantFiled: July 2, 2004Date of Patent: June 1, 2010Assignee: Shell Oil CompanyInventors: Jan Lodewijk Maria Dierickx, Arend Hoek, Lip Piang Kueh
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Patent number: 7718053Abstract: A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into monounsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds employing a supported catalyst, comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form deposited on a support and having a controlled porosity, and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h?1 to 10 h?1 and at a pressure in the range of 0.5 to 5 MPa.Type: GrantFiled: December 21, 2006Date of Patent: May 18, 2010Assignee: Institut Francais du PetroleInventors: Christophe Bouchy, Florent Picard, Nathalie Marchal
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Patent number: 7691256Abstract: Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/H2S, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and H2S, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from theType: GrantFiled: December 20, 2005Date of Patent: April 6, 2010Assignees: ENI S.p.A., SNAMPROGETTI S.p.A., ENITECNOLOGIE S.p.A.Inventors: Romolo Montanari, Mario Marchionna, Sergio Rosi, Nicoletta Panariti, Alberto Delbianco
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Patent number: 7682502Abstract: An improved hydrogenation process for lube oil boiling range feedstreams utilizing a catalyst comprising at least one Group VIII noble metal selected from Pt, Pd, and mixtures thereof having an average pore diameter of about 15 to less than about 40 ?.Type: GrantFiled: August 17, 2005Date of Patent: March 23, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Stephen J. McCarthy, Wenylh F. Lai, Jean W. Beeckman, Sylvain S. Hantzer
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Publication number: 20100038285Abstract: The present invention relates to the novel catalytic composition having a high specific activity in reactions involving hydroprocessing of light and intermediate petroleum fractions, and preferably in hydrodesulphurization and hydrodenitrogenation reactions. The inventive catalyst contains at least one element of a non-noble metal from group VIII, at least one element from group VIB and, optionally, a group one element of the VA group, which are deposited on a novel catalytic support comprising of an inorganic metal oxide from group IVB, consisting of an (ID) one-dimensional nanostructured material having nanofibers and/or nanotube morphology with high specific surface area of between 10 and 500 m2/g.Type: ApplicationFiled: October 10, 2003Publication date: February 18, 2010Inventors: José Antonio Toledo Antonio, José Escobar Aguilar, Maria Antonia Cortés Jacome, Maria de Lourdes Mosqueira Mondragon, Vitor Pérez Moreno, Calos Angeles Chávez, Esteban López Salinas, Marcelo Lozada y Cassou
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Patent number: 7663008Abstract: A method of catalytic reaction uses a micro-reactor (1) with a metal catalyst (5) or a metal complex catalyst (5) as a solid phase supported on the inner wall (4c) of a channel (4), a solution (7) dissolving a reactant as a liquid phase and hydrogen (9) as a gas phase are flown through the channel (4) in pipe flow state, and the reaction of the solution (7) and the gas (9) accelerated by the metal catalyst (5) or the metal complex catalyst (5) is conducted by three phase catalytic reaction of solid-liquid-gas phases. The metal catalyst (5) or the metal complex catalyst (5) is incorporated in a polymer, and hydrogenation reaction by three phase catalytic reductive reaction of a substance to be reduced can be conducted in short time at good yield. For hydrogenation reaction of unsaturated organics, the rate of reaction and yield are high when palladium catalyst is used, and carbonylation reaction can be conducted if carbon monoxide is used instead of hydrogen.Type: GrantFiled: January 26, 2005Date of Patent: February 16, 2010Assignee: Japan Science and Technology AgencyInventors: Shu Kobayashi, Yuichiro Mori, Takehiko Kitamori, Masaharu Ueno, Kuniaki Okamoto
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Patent number: 7663011Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of refractory oxide containing at least 97% by volume of pores having a pore size ranging from about 15 ? to about 30 ? and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2 theta (?). The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.Type: GrantFiled: August 5, 2005Date of Patent: February 16, 2010Assignee: Lummus Technology Inc.Inventors: Zhiping Shan, Jacobus Cornelis Jansen, Chuen Y. Yeh, Philip J. Angevine, Thomas Maschmeyer, Mohamed S. Hamdy
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Patent number: 7645376Abstract: A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into mono unsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds, said process employing a supported catalyst comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form deposited on a support and having a specific composition and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h?1 to 10 h?1 and at a pressure in the range of 0.5 to 5 MPa.Type: GrantFiled: December 21, 2006Date of Patent: January 12, 2010Assignee: Institute Francais du PetroleInventors: Christophe Bouchy, Florent Picard, Nathalie Marchal
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Patent number: 7638040Abstract: A process for the recovery and purification of a contaminated hydrocarbons, wherein the contamination includes metals, finely divided solids and non-distillable components. The process further includes hydroprocessing the oil to remove deleterious compounds, to produce high quality reusable lubricants, solvents and fuels and to improve the quality of water byproduct.Type: GrantFiled: June 29, 2007Date of Patent: December 29, 2009Assignee: UOP LLCInventors: Mark Van Wees, Robert B. James, Jr., Tom N. Kalnes, Gavin P. Towler
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Publication number: 20090308790Abstract: The present invention relates to a hydrogenation catalyst composition, process for preparing the same and use thereof. The composition comprises a hydrogenation catalyst, an organonitrogen compound in an amount of 0.01%-20% by weight of the catalyst, a sulfiding agent in an amount of 30%-150% by weight of the sulfur-requiring amount calculated theoretically of the hydrogenation catalyst, and an organic solvent in an amount of 0.1%-50% by weight of the catalyst. The preparation process comprises introducing the required substances onto the hydrogenation catalyst in oxidation state. By introduction of the organonitrogen compound, sulfur and organic solvent, the hydrogenation catalyst composition of the present invention may further increase the sulfur-maintaining ratio of the catalyst during the activation, slow down the concentrative exothermic phenomenon, decrease the rate of temperature rise of the catalyst bed layer, and improve the activity of the catalyst.Type: ApplicationFiled: November 14, 2006Publication date: December 17, 2009Applicant: CHINA PETROLEUM & CHEMICAL CORPORATIONInventors: Yulan Gao, Xiangchen Fang, Gang Wang, Fenglan Cao, Chonghui Li, Guang Chen
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Patent number: 7626062Abstract: A system and method for recycling plastics. The system and method recover materials such as hydrocarbon gases, liquid hydrocarbon distillates, various polymers and/or monomers used to produce the original plastics. The system and method allow about one unit of input of energy input to the plastic recycler to be used to create one or more gaseous components and one or more liquid distillate components from a plastic that is being recycled. The one or more gaseous components and one or more liquid distillate components produce about one corresponding unit of useable output energy recovered from the recycling of the plastic.Type: GrantFiled: July 31, 2007Date of Patent: December 1, 2009Inventor: William E. Carner
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Publication number: 20090266743Abstract: A triglyceride or a triglyceride/hydrocarbon combination can be heated to produce thermally treated feeds. The thermally treated feeds can then be contacted with a hydrotreating catalyst in a reaction zone.Type: ApplicationFiled: April 25, 2008Publication date: October 29, 2009Inventors: Jianhua Yao, Edward L. Sughrue, II, Dhananjay B. Ghonasgi, Xiaochun Xu
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Patent number: 7601881Abstract: A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a tungstated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a phosphorus component, and at least one platinum-group metal component which is preferably platinum. The catalyst has a structure other than a heteropoly anion structure.Type: GrantFiled: January 30, 2008Date of Patent: October 13, 2009Assignee: UOP LLCInventors: Ralph D. Gillespie, Feng Xu
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Patent number: 7598202Abstract: Novel compositions of matter comprising a cationic layered material and a second compound. The second compound has a reflection in its XRD pattern at 18.5 degrees two-theta, and s second reflection at 29 degrees two-theta. The composition of matter may be used in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking and hydroprocessing. The materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel.Type: GrantFiled: December 20, 2005Date of Patent: October 6, 2009Assignee: Albemarle Netherlands B.V.Inventors: Paul O'Connor, William Jones, Dennis Stamires
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Patent number: 7591942Abstract: Bulk bi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor containing an organic agent.Type: GrantFiled: September 14, 2005Date of Patent: September 22, 2009Assignee: ExxonMobil Research and Engineering CompanyInventors: Stuart L. Soled, Sabato Miseo, Zhiguo Hou
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Patent number: 7591940Abstract: A catalytic hydrocracking process for the production of ultra low sulfur diesel wherein a hydrocarbonaceous feedstock is hydrocracked at elevated temperature and pressure to obtain conversion to diesel boiling range hydrocarbons. The resulting hydrocracking zone effluent is hydrogen stripped in a stripping zone maintained at essentially the same pressure as the hydrocracking zone to produce a first gaseous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. The first gaseous hydrocarbonaceous stream containing diesel boiling range hydrocarbons is introduced into a desulfurization zone and subsequently partially condensed to produce a hydrogen-rich gaseous stream and a second liquid hydrocarbonaceous stream containing diesel boiling range hydrocarbons. At least a portion of the first liquid stream is thermal cracked to produce diesel boiling range hydrocarbons. An ultra low sulfur diesel product stream is recovered.Type: GrantFiled: April 3, 2006Date of Patent: September 22, 2009Assignee: UOP LLCInventor: Tom N. Kalnes
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Patent number: 7588680Abstract: In some embodiments, the invention is a method of removing sulfur from a hydrocarbon feed using the steps of dissolving metallic sodium in a first solvent, combining the sodium/first solvent solution with a sulfur-free alkane or cycloalkane second solvent, vaporizing the first solvent from sodium/first solvent/second solvent combination to transfer the dissolved metallic sodium into the second solvent, and then combine the resultant liquid with a liquid hydrocarbon feed containing an organosulfur species. The resulting stream is combined with a hydrogen donor. The combination is heated and pressurized to form a liquid hydrocarbon product containing sodium sulfide. The liquid hydrocarbon product containing sodium sulfide is then cooled, and the sodium sulfide is extracted.Type: GrantFiled: February 26, 2007Date of Patent: September 15, 2009Assignee: Trans Ionics CorporationInventor: Robert C. Schucker
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Patent number: 7585406Abstract: A Process for hydroconverting of a heavy hydrocarbonaceous feedstock comprising a catalyst to produce lower boiling hydrocarbon products. The method can be used for the high- boiling point residues of oil refining (asphaltene, the residues of vacuum and under pressure distillation of oil, and the useless and heavy materials of thermo catalytic processes), heavy oil, natural bitumen, and bitumen-containing sands. It can also be used in oil refinery industries for the production of gas, gasoline fractions, distillation gas oil, concentrate of ash containing metals and chemical fertilizers.Type: GrantFiled: August 16, 2006Date of Patent: September 8, 2009Assignees: Research Institute of Petroleum Industry (RIPI), NTI CompanyInventors: Salambek Naibovich Khadzhiev, Khusain Magamedovich Kadiev, Vahid Khumaidovich Mezhidov, Jamshid Zarkesh, Reza Hashemi, Seyed Kamal Masoudian Targhi
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Publication number: 20090211945Abstract: The invention relates to a bulk catalyst having improved activity in hydrodesulphurisation, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock.Type: ApplicationFiled: October 25, 2006Publication date: August 27, 2009Applicant: ALBEMARLE NETHERLANDS B.V.Inventors: Sona Eijsbouts-Spickova, Robertus Gerardus Leliveld, Stuart Leon Soled, Sabato Miseo
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Publication number: 20090206004Abstract: An MCM-41 catalyst having a crystalline framework containing SiO2 and a Group IV metal oxide, such as TiO2 or ZrO2 is provided. The catalyst is low in acidity and is suitable for use in processes involving aromatic saturation of hydrocarbon feedstocks.Type: ApplicationFiled: December 16, 2008Publication date: August 20, 2009Inventors: Stephen J. McCarthy, Wenyih Frank Lai, Michel A. Daage
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Publication number: 20090200204Abstract: A hydroprocessing catalyst is provided. The hydroprocessing catalyst has the formula (Mt)a(Xu)b(Sv)d(Cw)e(Hx)f(Oy)g(Nz)h, wherein M is at least one group VIB metal; X is at least one Group VIII non-noble metal; t, u, v, w, x, y, z representing the total charge for each of the components (M, X, S, C, H, O and N, respectively); ta+ub+vd+we+xf+yg+zh=0; and 0=<b/a=<5, (a+0.5b)<=d<=(5a+2b), 0<=e<=11(a+b), 0<=f<=7(a+b), 0<=g<=5(a+b), 0<=h<=0.5(a+b). The catalyst has an X-ray powder diffraction pattern with at least one broad diffraction peak at any of Bragg angles: 8 to 18°, 32 to 40°, and 55 to 65° (from 0 to 70° 2-? scale). In one embodiment, the at least one diffraction peak is greater than 2 degrees wide at ½ height.Type: ApplicationFiled: October 31, 2007Publication date: August 13, 2009Inventors: Oleg Mironov, Alexander E. Kuperman, Jaime Lopez, Axel Brait, Bruce Reynolds, Kaidong Chen
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Patent number: 7563359Abstract: An aromatics/naphthalene rich stream obtained by processing heavy gas oil derived from tar sands and cycle oils derived from cracking heavy gas oil may optionally be blended and subjected to a hydrogenation process and a ring opening reaction typically in the presence of a zeolite, alumina, or silica alumina based catalyst which may contain noble metals and or copper or molybdenum to produce paraffinic feedstocks for further chemical processing.Type: GrantFiled: May 17, 2005Date of Patent: July 21, 2009Assignee: Nova Chemical (International) S.A.Inventors: Michael C. Oballa, Andrzej Krzywicki, Sunny Ying-Shing Wong, Anthony Tse, Abdul Alim Fakih
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Publication number: 20090178953Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude product is a liquid mixture at 25° C. and 0.101 MPa. The one or more catalysts may include a catalyst that has a median pore diameter of at least 90 ?. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.Type: ApplicationFiled: March 25, 2009Publication date: July 16, 2009Inventors: Opinder Kishan BHAN, Scott Lee Wellington
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Publication number: 20090166260Abstract: The present invention concerns a catalyst for hydrotreating and/or hydroconverting heavy metal-containing hydrocarbon feeds, said catalyst comprising a support in the form of mainly irregular and non-spherical alumina-based agglomerates the specific shape of which results from a crushing step, and containing at least one catalytic metal or a compound of a catalytic metal from group VIB and/or group VIII (groups 8, 9 and 10 of the new periodic table notation), optionally at least one doping element selected from the group constituted by phosphorus, boron and silicon (or silica which does not form part of that which may be contained in the selected support) and halogens, said catalyst essentially being constituted by a plurality of juxtaposed agglomerates each formed by a plurality of acicular platelets, the platelets of each agglomerate generally being oriented radially with respect to each other and with respect to the centre of the agglomerate.Type: ApplicationFiled: December 14, 2006Publication date: July 2, 2009Inventors: Stephane Kressmann, Magalie Roy-Auberger, Jean Luc Le Loarer, Denis Guillaume, Jean Francois Chapat
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Publication number: 20090159499Abstract: A reactor in which a multi-phase mixture, including gas and a catalyst slurry or liquid, is to be conducted. The reactor includes a reaction chamber having a substantially unencumbered center portion through which the multi-phase mixture is conducted upwardly. A downcomer arrangement is disposed laterally outwardly of the center portion and adjacent to an inner surface of the reaction chamber. An external pump communicates with a lower portion of the reaction chamber for circulating components of the mixture downward from an upper end of the downcomer arrangement to a lower end thereof. A collection chamber is disposed below the reaction chamber into which the components exiting the downcomer arrangement are introduced and where the gas is separated from the remainder of the components. The separated gas can be reintroduced into the reaction chamber.Type: ApplicationFiled: December 19, 2007Publication date: June 25, 2009Applicant: Chevron U.S.A. Inc.Inventor: Abdenour Kemoun
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Patent number: 7550073Abstract: The present invention relates to new crystalline molecular sieve SSZ-70 prepared using a N,N?-diisopropyl imidazolium cation as a structure-directing agent, methods for synthesizing SSZ-70 and processes employing SSZ-70 in a catalyst.Type: GrantFiled: November 2, 2005Date of Patent: June 23, 2009Assignee: Chevron U.S.A., Inc.Inventors: Stacey I. Zones, Allen W. Burton, Jr.
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Publication number: 20090134060Abstract: Contact of a crude feed with one or more catalysts containing a transition metal sulfide produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. In some embodiments, gas is produced during contact with one or more catalysts and the crude feed.Type: ApplicationFiled: January 27, 2009Publication date: May 28, 2009Inventors: Scott Lee Wellington, Thomas Fairechild Brownscombe, Stanley Nemec Milam
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Patent number: 7537685Abstract: The present invention relates to new molecular sieve SSZ-71 prepared using a N-benzyl-1,4-diazabicyclo[2.2.2]octane cation as a structure-directing agent, methods for synthesizing SSZ-71 and processes employing SSZ-71 in a catalyst.Type: GrantFiled: November 2, 2005Date of Patent: May 26, 2009Assignee: Chevron U.S.A. Inc.Inventors: Cong-Yan Chen, Allen W. Burton, Jr., Ann J. Liang