Abstract: The present invention is a process for reducing the smoke emissions from a jet fuel engine by combusting a jet fuel range hydrocarbon in a jet engine wherein prior to combusting the jet fuel in the engine the jet fuel is treated by the following process: (a) contacting the jet fuel with at least one adsorbent in at least one adsorbent bed under suitable process conditions such that the smoke point of the jet fuel is increased and (b) recovering the jet fuel.

Abstract: This invention relates to a process for upgrading a hydrocarbonaceous material to a product having a lower boiling point than the initial boiling point of said hydrocarbonaceous material and/or a higher boiling point than the final boiling point of said hydrocarbonaceous material, the process comprising heating a feed composition comprising said hydrocarbonaceous material in an enclosed space in the absence of externally supplied water or hydrogen at a temperature in the range of about 750.degree. F. to about 1300.degree. F. and a pressure sufficient to maintain the specific gravity of the contents of said enclosed space in the range of about 0.05 to about 1.5 for an effective period of time to yield said product, said feed composition being characterized by the absence of aromatic compounds with boiling points at atmospheric pressure below about 350.degree. F.

Abstract: This invention is a method for reducing the particulate emissions tendency of diesel fuel. Also the piston ring sticking, and deposit formation tendency of diesel fuel on the injector and combustion chamber of an internal combustion diesel fuel are reduced. The diesel fuel under the method of this invention is fed to at least one adsorbent bed in which the diesel fuel is contacted with one or more adsorbents under suitable process conditions such that there is a reduction in content of impurities in the fuel which cause the particulate emission causing tendency, piston ring sticking, and deposit formation tendency of the diesel fuel on the injector and/or combustion chamber.

Abstract: A hydrocarbon feedstock is catalytically reformed to effect dehydrocyclization of paraffins in a process combination comprising a first reforming zone and a sulfur-removal zone utilizing a manganese component to preclude sulfur from the feed to a second reforming zone. The process combination shows substantial benefits over prior art processes in the stability of the extremely sulfur-sensitive catalyst utilized in the second reforming zone.

Abstract: Lube oil basestocks having an oil/water interfacial tension (.gamma. o/w) of less than 41 mN/m, preferably less than about 35 mN/m which exhibit unacceptable demulsibility can have their demulsibility performance improved by contacting said lube oil basestock with an acidic ion exchange resin, such as Amberlyst AR-15, or with silica. The treated lube oil base stock exhibits an oil/water interfacial tension (.gamma. o/w) of at least about 41 mN/m, preferably at least about 42 mN/m.

Abstract: The present invention relates to a process for obtaining the hydrocarbon from a hydrocarbon-rich gel based on an ionic surfactant by treatment of the gel with a laminar mineral.

Abstract: A method for removing arsenic and/or phosphorus from a petroleum charge with a retaining material comprising:(a) from 60 to 97% of a carrier containing, by weight, from 1.5 to 60% of oxide of at least one metal A selected from the group consisting of Mg, Ca, Sr, Ba, Mn, Fe, Co, Ni, Cu and Zn, dissolved in alumina in the form of aluminate, and from 40 to 98.5% of at least one alumina,(b) from 3 to 40% of nickel oxide, with which the carrier is impregnated by exchange or depositing, and(c) possibly from 0 to 1% of platinum and/or palladium oxide with which the carrier is impregnated.

Abstract: A process is described for producing a catalyst composition for hydrodesulfurization of hydrocarbon oil, which comprises:drying and calcining a carrier comprising alumina or an alumina-containing material impregnated with a solution mixture of(A) at least one of an alkoxide, a chelate compound, or a glycoxide of molybdenum or chromium;(B) at least one of an alkoxide, a chelate compound, or a glycoxide of cobalt or nickel; andan organic solvent capable of dissolving (A) and (B).Also described is a process for hydrodesulfurizing hydrocarbon oil using the same catalyst composition.

Abstract: A process for the production of an ether-rich additive for gasoline, and more particularly, the production of MTBE, TAME and mixtures thereof from light hydrocarbon streams comprising passing the light hydrocarbon stream, preferably from an FCC feedstock, through a superactivated alumina medium so as to remove nitrogen compounds, mercaptan and water prior to contacting the feedstock with a catalyst under etherification process conditions. The present invention further includes a process for regenerating the spent superactivated alumina mediums used for purifying the feedstock employed in the process for the production of ether-rich additives for gasoline.

Abstract: This invention provides a process to remove aromatic color bodies, particularly oxygen or sulfur containing aromatics from a C.sub.8-11 aromatic hydrocarbon stream having a boiling range between about 160.degree.-460.degree. F. The process involves contacting the hydrocarbon stream with a neutral attapulgite clay for a time sufficient to adsorb the aromatic color bodies. The process is effective in reducing the APHA color value of the subject hydrocarbon stream from an initial 850-1100 value to about 400 or less.

Abstract: A process for removing heteroatoms from a hydrocarbonaceous feedstock using a catalyst composition comprised of: about 0.005 to 5.0 wt. % noble metal, about 0.5 to 5 wt. % of at least one Group VIII metal, and about 3 to 18 wt. % of a Group VI metal, and a refractory support, wherein the noble metal is incorporated into the refractory support by use of a precursor represented by ML.sub.2 when the noble metal is Pt or Pd, and ML.sub.3, when the noble metal is Rh or Ir, where M is the noble metal and L is a ligand selected from the dithiocarbamates, dithiophosphates, dithiophosphinates, xanthates, thioxanthates, and further wherein L has organo groups having a sufficient number of carbon atoms to render the noble metal complex soluble in oil.

Abstract: The present invention is directed to a process for treating hydrotreated naphtha which involves treating the naphtha over massive nickel catalyst followed by treating the naphtha over a metal oxide under conditions effective for removing impurities from said naphtha to result in substantially purified naphtha, wherein the metal oxide is selected from the group of metal oxides having a free energy of formation of sulfide which exceeds said free energy of formation of platinum sulfide, such as manganous oxide. In so doing, naphtha in the gas phase in the presence of hydrogen is passed over the manganous oxide at a temperature within the range of about 800.degree. F. and 1100.degree. F., a hydrogen to oil molar ratio between about 1:1 and 6:1, a whsv between about 2 and 8, and pressure between about 50 and 300 psig; and the naphtha in the liquid phase at a temperature between about 300.degree. F. and about 350.degree. F., and whsv less than about 5 is passed over the massive nickel.

Abstract: The invention relates to a method for removing RCS from off-spec white mineral oil prepared by catalytic hydrogenation by filtering the off-spec white mineral oil through a bleaching clay, such as a smectite clay, particularly an acid treated montmorillonite clay, such as bentonite or attapulgite.

Abstract: The invention provides a method for removing mercury from a liquid hydrocarbon feed material by (a) removing those components having a higher molecular weight than the desired hydrocarbon from the feed material, (b) removing water from the feed material, and thereafter (c) removing mercury from the feed material. Mercury can be removed to an extremely low concentration of 0.001 ppm or lower from a wide variety of liquid hydrocarbon feed materials containing either a relatively large amount or a trace amount of mercury.

Abstract: Trace amounts of mercury and its compounds present in hydrocarbon oil can be removed selectively and efficiently by bringing the hydrocarbon oils containing mercury and its compounds into contact with a certain treating agent after having heated such oils. Since the hydrocarbon oil from which mercury and its compounds have been removed does not contain catalyst poisons, such a hydrocarbon oil can be used extensively for catalytic reaction processes such as hydrogenation.

Abstract: A process is provided for the pretreatment of heavy oil feeds to demetalate and remove coke precursors. Inert, sorbent material is utilized in a reaction zone to effect the contaminant removal and is cycled to a regeneration zone. The sorbent also adsorbs sulfur oxides produced in a regeneration zone which are then cycled back to the reaction zone, converted to hydrogen sulfide, and removed from the system. The preferred sorbent material is high surface area alumina, having an average surface area in the circulating inventory of greater than 100 m.sup.2 /g.

Abstract: A method of selective and efficient removal of mercury from a hydrocarbon oil comprising contacting said oil with a cupric and/or stannous compound forming a reaction system. The purified hydrocarbon oil can be readily separated from the reaction system. The purified hydrocarbon oil does not contain mercury or any other catalyst poisoning component and can, therefore, be used extensively in catalytic reactions typified by hydrogenation reaction.

Abstract: A process is disclosed for removing hydrocarbons from oily wastes. According to the process, the oily wastes are mixed with solids and a binder and then granulated. The granules thus formed are contacted with solvent to extract hydrocarbons from the granules. Preferred solids include limestone and preferred binders include portland cement calcium sulfate and/or calcium sulfate hydrate such as plaster of Paris.

Abstract: Treatment of diesel or jet fuel with a non-ionic, macroreticular, cross-linked, acrylic aliphatic ester resin reduces polar impurities and (diesel) color.

Abstract: A method is provided for removing mercury from hydrocarbon fluids by high temperature reactive adsorption. A hydrocarbon feed passed through an adsorbent mass including a reactive adsorbent such as silver or copper sulfide on an alumina support. The optimum temperature of the feed to be treated depends upon the 90% boiling points corresponding to heavier feeds. A hydrocarbon condensate feed may be drawn from a stabilizer column in a natural gas processing plant at a temperature in excess of 400.degree. F. If a metallic silver/alumina adsorbent is employed, the adsorbent may be regenerated through high temperature oxidation. Once oxidation is complete, the temperature is lowered in a reducing or inert atmosphere.

Abstract: Disclosed is a process for removing accumulated metals, particularly vanadium and nickel, from particulate aluminosilicate materials and aluminosilicate materials that are obtained by the process. The process may advantageously be used to remove accumulated metals from spent aluminosilicate contact materials used in selective vaporization processes of the type described in U.S. Pat. No. 4,263,128. The process of this invention yields materials suitable for effective recycling to a selective vaporization unit or for ecologically-acceptable disposal, as well as, optionally, recovery of metals in saleable form.

Abstract: The present invention relates to a process for removing arsine from a light olefin to containing hydrocarbon feedstock, said process comprising the steps of (a) passing said feedstock over an absorbent material comprising nickel deposited on a support material wherein nickel is present as both nickel oxide and metallic nickel; and (b) recovering a stream having a substantially reduced arsine content.

Abstract: Basic nitrogen compounds (BNC) are selectively removed from solvent extracted oils by adsorption of said BNC's by solid acidic polar adsorbents. The oils are extracted using any of the common extraction solvents, such as furfural, phenol, SO.sub.2, N-methyl-2-pyrrolidone (NMP), preferably NMP. The resulting raffinate, which contains the desirable oil fraction, has the BNC's present therein removed by adsorption thereof onto an adsorbent, characterized as being a solid, polar acidic adsorbent, exemplified by silica-alumina, a high alumina base amorphous cracking catalyst (such as manufactured by Ketjen/Akzo) and crystalline zeolite (such as H-Y zeolites) are effective adsorbents. The adsorbents may additionally contain fluorine or may contain up to 30 weight percent water. The adsorbents are regenerated by either purging with hydrogen at elevated temperature and pressure, or by washing the BNC saturated adsorbent with extraction process extraction solvent, such as NMP.

Abstract: In the present invention, a petroleum fraction containing arsenic is brought into contact with an adsorbent comprising a substrate such as an active carbon, bituminous coal or organic polymeric compound having introduced therein a sulfur element, particularly represented by mercapto moiety, and therefore arsenic in the petroleum fraction can be removed at a high percent removal by means of simple equipment, and, even if highly reactive olefins are contained in the petroleum fraction, these olefins do not polymerize, thus troubles do not occur.

Abstract: This invention relates to a method of preparing a metal-containing amorphous magnesia-alumina-aluminum phosphate catalyst support involving the admixture of an organic cation having a size equal to or greater than 2 Angstroms, the organic cation preferably being a tertiary or a tetraalkylammonium or phosphonium cation. The method permits recovery of a catalyst support having a controlled pore size distribution. The invention also relates to an improved catalytic support as well as an improved petroleum residua upgrading process comprising hydrotreating residua in the presence of the improved catalyst support.

Abstract: The present invention relates to a chemical process involving a processing step which is sensitive to the presence of at least one component contained within the stream to be processed and to an economical and efficient method of temporarily removing such deleterious component from the stream so as to have the deleterious component by-pass the step which is sensitive to this component using an adsorbent for such removal wherein the adsorbent is regenerated by the product effluent stream leaving the sensitive processing step.

Abstract: The present invention relates to a process for removing carbonyl sulfide from a liquid hydrocarbon feedstock, said process comprising the steps of (a) passing said hydrocarbon feedstock over an absorbent material comprising nickel deposited on a support material wherein nickel is present as both nickel oxide and metallic nickel and wherein the absorbent material has been conditioned by passing an inert gas flow containing a minor amount of propylene; and (b) recovering a liquid hydrocarbon stream having a substantially reduced carbonyl sulfide content.

Abstract: The present invention relates to a new and integrated process involving the utilization of a primary adsorption bed containing a regenerable, physical adsorbent and an auxiliary sorption bed containing a chemisorbent for the removal of sulfur compounds from a fluid stream, which process provides for higher yields, higher purity and lower costs. A system for removing sulfur compounds in accordance with the above process is also disclosed.

Abstract: The present invention relates to a chemical process involving a processing step which is sensitive to the presence of at least one component contained within the stream to be processed. In particular, the present invention relates to an economical and efficient method of integrating the means for removing the deleterious component with the sensitive processing step by the use of a sorbent which is capable of removing the at least one deleterious component at sorption conditions which enables the stream to be in the vapor phase for subsequent introduction to the sensitive processing step which is also carried out in the vapor phase. Most preferably, the sorption conditions are substantially the same as the conditions within the sensitive processing step.

Abstract: The present invention relates to a new and integrated process involving the utilization of a primary adsorption bed containing a regenerable, physical absorbent and an auxiliary sorption bed containing a chemisorbent and an optional physical absorbent for the removal of sulfur compounds and water from a fluid stream, which process provides for higher yields, higher purity and lower costs.

Abstract: A method for updating a concentrate of tar sands bitumen containing fine mineral matter and optionally coarse mineral matter in which solvent-diluted bitumen is contacted for a short time in a riser with hot attrition-resistant substantially catalytically inert acid-resistant fluidizable particles, causing a selective vaporization of the lighter high hydrogen content components of the bitumen. The preferred particles are composed of silica-alumina, most preferably a mixture of mullite and crystalline silica or mullite, crystalline silica and an acid-resistant form of alumina. A portion of the heavier asphaltenes and most of the components which contain metals, sulfur and nitrogen remain on the attrition-resistant fluidizable particles. Fine mineral matter in the bitumen feed also deposits on the fluidized particles instead of being carried over with the vaporized hydrocarbon product.

Abstract: This invention presents a novel treating process for the removal of trace quantities of olefinic impurities from a hydrocarbon process stream. Specifically, this process operates at liquid phase conditions treating hydrocarbon streams comprising substantially aromatics and naphthenes having Bromine Index values of about 50 to 2,000. A solid medium comprising a crystalline aluminosilicate zeolite and a refractory oxide is used to reduce the level of olefin impurities to Bromine Index values of 0.1 to 50.

Abstract: Improved noncatalytic nonreactive alumina-silica solid for removing carbonaceous and metallic contaminants including nickel and vanadium from hydrocarbon feedstock by short term, high temperature contact comprises mullite and crystalline silica. In the decarbonizing and demetallizing process, impurities are deposited on the particles of the solid and the major portion of the feedstock is vaporized. After burning carbonaceous deposit from the particles, the hot particles containing nickel and vanadium are recycled into contact with incoming charges of contaminated feedstock. Periodically metals are removed from coke-depleted particles by extraction with a mineral acid at elevated temperature without dissolving or otherwise destroying the alumina-silica particles. The particles are then reintroduced into the system.

Abstract: Crude oil sludges and other relatively heavy hydrocarbon liquid sludges are mixed with diatomaceous earth or perlite to form a friable and flowable solids mixture which is conveyed to a combustion unit, such as rotary kiln, calciner or lift pipe type combustor, wherein combustion of the hydrocarbons is carried out to provide gaseous combustion products and a substantially hydrocarbon free solids mixture. The solids discharged from the combustion unit may be recycled for use in the mixing process to reduce the sludge to a friable material for introduction to the combustion unit and excess solids may be discharged for disposal.

Abstract: A process for the removal of hydrogenatable hydrocarbonaceous compounds from a hydrocarbonaceous stream which comprises the steps of: (a) contacting the hydrocarbonaceous stream with an adsorbent to remove at least a portion of the hydrogenatable hydrocarbonaceous compounds from the hydrocarbonaceous stream to provide a hydrocarbonaceous stream having a reduced concentration of hydrogenatable hydrocarbonaceous compounds; (b) contacting spent adsorbent which has accumulated the hydrogenatable hydrocarbonaceous compounds from the hydrocarbonaceous stream with an elution solvent to remove the hydrogenatable hydrocarbonaceous compounds from the spent adsorbent thereby regenerating the adsorbent; (c) recovering at least a portion of the elution solvent from a resulting admixture of elution solvent and hydrogenatable hydrocarbonaceous compounds recovered from step (b) in an elution solvent recovery zone; (d) contacting the hydrogenatable hydrocarbonaceous compounds which were recovered from step (c) in the presence

Abstract: We disclose a catalyst system which is capable of removing sodium from a hydrocarbon feed having at least 1 ppm oil-soluble sodium. It comprises a catalyst layer characterized as a fixed bed of catalyst particles having a low volume percent of their pore volume percent in the form of macropores above 1000 .ANG. in diameter, high surface area, and high hydrogenation activity. We also disclose a process of using the system.

Abstract: Hydrocarbon feedstocks containing relatively high levels of nitrogen contaminants are converted to products of lower average molecular weight by first mixing the feedstock with a dicarboxylic acid such as oxalic acid and then contacting the resultant mixture with a cracking catalyst in a cracking zone under cracking conditions in the substantial absence of added molecular hydrogen. The use of a dicarboxylic acid in lieu of a mineral acid such as sulfuric acid or nitric acid results in less corrosion to FCC unit internals and less emissions of sulfur and nitrogen oxides from the FCC unit regenerator.

Abstract: A process is disclosed for removing color or color inducing impurities to petroleum derived wax by means of an adsorbent comprising a refined inorganic oxide having a pore distribution such that at least 60% of the pores possess a size of less than 350 Angstroms. Preferably, at least 90% of the pores possess a size of less than 350 Angstroms. The preferred inorganic oxide is an aluminum oxide and preferably has a surface area between 200 square meters per gram and 500 square meters per gram. A process is also disclosed for wax finishing utilizing multiple beds of refined alumina which may be operated in a swing bed fashion to intimately regenerate the refined alumina absorbent by such procedural steps as naphtha soaking, steam treating and heating in air.

Abstract: Silicon components are removed from a hydrocarbon stream by contacting the stream with a sorbent comprising a mixture of a copper component and a porous, inorganic refractory oxide containing alumina. Preferably, the porous, inorganic refractory oxide will contain greater than about 10 weight percent alumina and most preferably consists essentially of alumina. It is normally desired to contact the hydrocarbon stream with the sorbent in the presence of molecular hydrogen in order to prevent coking of the sorbent. The sorbent may be a fresh mixture of the copper component and the porous, inorganic refractory oxide or it may be a spent sorbent prepared by using the fresh sorbent to remove sulfur components from a hydrocarbon stream. Alternatively, the sorbent may be a regenerated sorbent prepared by burning carbonaceous residues off a sorbent that was previously used to remove sulfur components from a hydrocarbon stream.

Abstract: Phenolic compounds are removed from a hydrocarbon oil by contacting the oil with manganese nodules at suitable conditions of contact time, temperature, and pressure.

Abstract: Metals contained in a hydrocarbon containing feed stream are removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising zirconium phosphate, cobalt phosphate and a metal phosphate where the metal is selected from the group consisting of nickel and vanadium. Molybdenum phosphate may also be added to the catalyst composition if desired. The life and activity of the catalyst composition may be increased by introducing a decomposable metal compound selected from the group consisting of the metals of Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream prior to contacting the hydrocarbon containing feed stream with the catalyst composition.

Abstract: In a hydrogenation operation employing an ebullated catalytic bed, recycle is recovered from the hydrogenated product with at least 25%, by volume, of the recycle boiling above 950.degree. F. The recycle is cooled to a temperature of from 350.degree. to 600.degree. F. to separate coke precursors, prior to recycle to the hydrogenation. Higher conversion levels can be achieved by effecting recycle in such manner.

Abstract: A process for treating liquid hydrocarbons to remove toxic, mutagenic and/or carcinogenic aromatic hydrocarbons comprises feeding the hydrocarbons into a reactor where vapors are thermally treated in contact with a catalyst consisting essentially of calcium oxide or a calcium oxide containing mineral. Thermally treating liquid hydrocarbons in contact with calcium oxide preferentially increases the cracking of aromatics thus producing a product having a reduced amount of aromatic compounds.

Abstract: Whole crude and residual fractions from distillation of petroleum and like feed stocks are subjected to selective vaporization to prepare heavy fractions of reduced Conradson Carbon and/or metals content by short-term, high temperature riser contact with a substantially inert solid contact material of low surface area in a selective vaporization zone. High boiling point components of the charge which are of high Conradson Carbon number and/or high metal content remain on the contact material as a combustible deposit which is then burned off in a combustion zone whereby the contact material is heated to a high temperature for return to the selective vaporization zone to supply the heat required therein. Equilibrium FCC catalyst, previously treated to reduce catalytic cracking activity and surface area, is used as the substantially inert solid.

Abstract: An improved process is provided for decarbonizing, demetallizing and/or desalting a hydrocarbon feed stock by: contacting, in a selective vaporization step, for a short hydrocarbon residence time at an elevated contact temperature, the feed stock with an inert solid contact material in a confined rising vertical column to vaporize a major portion of the feed stock and to provide, as combustible deposits on the contact material, an unvaporized minor portion of the feed stock which includes high Conradson Carbon components and/or metal-containing components of the feed stock; separating the vaporized major portion of the feed stock from the contact material bearing the combustible deposits; contacting in a combustion step the contact material, bearing the combustible deposits, with an oxidizing gas to oxidize the combustible deposits and generate heat, whereby the contact material is heated by combustion of the combustible deposits; and recycling the so-heated contact material to contact further feed stock in t

Abstract: An improvement is disclosed on selective vaporization for decarbonizing and demetallizing heavy petroleum stocks by short time riser contact with hot inert solid contact material. Flexibility is imparted to that process by suspending the contact material in steam or other carrier gas and adding the heavy petroleum stock at variable levels in the riser.

Abstract: Contaminants such as petroleum sulfonates, anticorrosion amines, and silicone oils are removed from a contaminated feedstock stream by contacting said feedstock stream with an adsorbent comprising bauxite. In a further aspect, a thus purified petroleum feedstock stream is hydrodesulfurized.

Abstract: Whole crude and bottoms fractions from distillation of petroleum are upgraded by high temperature, short time contact with a fluidizable solid of essentially inert character to deposit high boiling components of the charge on the solid whereby Conradson Carbon values, salt content and metal content are reduced. The upgraded hydrocarbon fraction may be supplied to fractionator, in which case the high temperatue contactor serves as a heater, e.g. crude heater for crude distillation, in addition to improving quality of the fractions derived by distillation. For charge stocks boiling above about 500.degree.-650.degree. F., the upgrading process yields a product suitable for charge to catalytic cracking in that Conradson Carbon, salts and metals are reduced to levels tolerable in catalytic cracking.

Abstract: Residual fractions from distillation of petroleum are rendered suitable for charge to catalytic cracking by high temperature, short time contact in a decarbonizing zone with a fluidizable solid particles of essentially inert character and low surface area to deposit high boiling components of the crude and metals on the fluidizable solid particles whereby Conradson Carbon values and metal content of the hydrocarbon feedstock are reduced to levels tolerable in catalytic cracking and carbon laid down on the inert fluidizable particles is burned in a burning zone separate from the decarbonizing zone. Heated inert particles are recycled at least in part to the decarbonizing zone and then to the burning zone.

Abstract: A method for supressing carburetor deposit formation of motor fuels containing untreated cat cracked gasoline by blending adsorbent-treated cat cracked gasoline into the motor fuel. Up to about 50 percent by weight of the total composition is adsorbent-treated cat cracked gasoline, but preferably from about 5 to about 25 percent by weight of the total composition is adsorbent-treated cat cracked gasoline. In a preferred embodiment a standard reference fuel capable of providing a predetermined level of carburetor deposit formation is provided by the addition of either adsorbent-treated cat cracked gasoline, untreated cat cracked gasoline, or aromatic amines to a base fuel.