With Solid Catalyst Or Absorbent Patents (Class 208/299)
  • Patent number: 4176047
    Abstract: A gasoline boiling range hydrocarbon stream obtained by fractionation of overhead vapors from a delayed coker is treated for removal of organic silicon compounds prior to being processed in a desulfurizer and catalytic reformer. The stream is treated by a bed of material such as alumina, activated alumina or spent alumina-based desulfurizer catalyst at elevated temperature to reduce the level of organic silicon compounds. The organic silicon compounds, if not removed, are detrimental to desulfurizer and reformer catalysts. The organic silicon compounds are conventionally added to a delayed coker to control foaming.
    Type: Grant
    Filed: April 10, 1978
    Date of Patent: November 27, 1979
    Assignee: Continental Oil Company
    Inventors: Derrell D. Orrell, Melvin M. McFeeters
  • Patent number: 4152249
    Abstract: A hydrocarbon cut is purified by contact with a solid adsorption resin consisting of a porous polycondensate or cross-linked copolymer comprising pyridyl or hydroxy groups and having pores essentially in the range of 6 to 300 Angstroms.
    Type: Grant
    Filed: January 26, 1978
    Date of Patent: May 1, 1979
    Assignee: Institut Francais du Petrole
    Inventors: Rene Avrillon, Daniel Defives
  • Patent number: 4125457
    Abstract: Hydrocarbon lubricating oils are upgraded by removing polar compounds contained therein and improving the oxidation stability thereof using an acidified sorbent, such as alumina, silica-alumina or bauxite treated with anhydrous HCl, anhydrous HBr, aqueous (NH.sub.4).sub.2 SO.sub.4 or H.sub.2 SO.sub.4. The acidified sorbent contains at least 3%, by weight of the acidified sorbent, of Cl.sup.-, Br.sup.- or SO.sub.4 .sup.= ions. The process of upgrading the lube oils is carried out at a temperature ranging from ambient to about 250.degree. F and LHSV of 0.1 - 10.
    Type: Grant
    Filed: September 2, 1977
    Date of Patent: November 14, 1978
    Assignee: Mobil Oil Corporation
    Inventors: James A. Brennan, Stanley J. Lucki
  • Patent number: 4090953
    Abstract: An improved process for preparing a stabilized lubricating oil resistant to oxidation and sludge formation upon exposure to a highly oxidative environment, such as when metals are present and an overbased component is present in the lubricating oil, is provided. In the present process wherein a lubricating oil stock to be upgraded is contacted with elemental sulfur in the presence of a catalyst material selected from the group consisting of alumina, aluminosilicate, a metal of Groups II-A, II-B, VI-B or VIII of the Periodic Table of Elements, an oxide of a metal of Groups II-A, II-B, VI-B or VIII, a sulfide of a metal of Groups II-A, II-B, VI-B or VIII, clay, silica, silica combined with an oxide of a metal of Groups II-A, III-A, IV-B or V-B, and combinations thereof, at relatively low temperatures of from about 150.degree. to about 225.degree.
    Type: Grant
    Filed: June 8, 1976
    Date of Patent: May 23, 1978
    Assignee: Mobil Oil Corporation
    Inventors: Robert F. Bridger, Costandi A. Audeh, El-Ahmadi I. Heiba
  • Patent number: 4054419
    Abstract: An improved reactor for chemical reaction includes a wetproofed catalyst therein for increasing the rate of reaction between the reactants and/or controlling selectivity of the products, if there is more than one reaction product. The wetproofed catalyst may be used in addition to the other catalytic systems already known in the art. The reaction occurs in the presence of two or more fluid phases. The types of reaction may be reduction-oxidation, hydration and the like. The wetproofed catalyst is a solid, particulate catalyst including surface portions which are wetproofed so that the catalyst is not flooded by any of the reactants, reaction products or other fluids in the reaction chamber. Wetproofing of the surface portions of the catalyst may be accomplished in various ways, as described, and various materials may be used for the catalyst.
    Type: Grant
    Filed: October 23, 1974
    Date of Patent: October 18, 1977
    Assignee: The Mead Corporation
    Inventors: Glen C. Smith, Frederick W. Sanders
  • Patent number: 3930988
    Abstract: A process for reducing the ash content and the content of metals present in used motor oils by contacting the used motor oil with an aqueous solution of ammonium sulfate and/or ammonium bisulfate under conditions to react with the metal compounds present to form separable solids. In another embodiment of the invention, the used motor oil after reaction with an aqueous solution of ammonium sulfate and/or ammonium bisulfate can be further treated with an adsorbent and then optionally hydrotreated to produce an oil product suitable as a fuel or as a feedstock for lubricating oil compositions.
    Type: Grant
    Filed: February 24, 1975
    Date of Patent: January 6, 1976
    Assignee: Phillips Petroleum Company
    Inventor: Marvin M. Johnson