Abstract: A steam-cracking unit and a steam-cracking process with controlled injection of solid particles in a quenching exchanger (3) is described. The particles are injected through a single axial injection pipe that is arranged on the axis of input cone (2) of the quenching exchanger, just upstream from an impact separator-diffuser (6) that comprises solid surfaces that are arranged opposite the transfer pipe of the cracked gases toward the exchanger; this impact separator-distributor is located in input cone (2) of the exchanger and is gas-permeable along a number of passages and at least 70% opaque when viewed from the transfer pipe.

Abstract: A process is provided by the invention which comprises: (a) providing a tubular reactor having an inlet and an outlet, a furnace for heating the reactor, and a cooler having an inlet in communication with the reactor outlet and also having an outlet; (b) introducing a substantially constant flow of feed gas comprising steam to the reactor inlet while the reactor is heated by the furnace to produce a predetermined and substantially constant reactor outlet temperature; and (c) controlling, during at least a portion of (b), the concentration of an antifoulant in the feed gas based on cooler outlet temperature.

Abstract: A process to provide a multiplicity of hydrocracking reaction zones containing hydrocracking catalyst wherein the catalyst is rejuvenated or reactivated while the process unit remains on-stream by the periodic exposure of partially spent catalyst to hot recycle gas containing hydrogen. The hydrocracking catalyst always operates at "near" fresh activity and selectivity thereby resulting in more stable temperature, yield and product quality performance.

Abstract: The invention is directed to a process of reducing the chlorine content of oil as well as its propensity to foul during subsequent distillation processes. The process heats the oil to a temperature in the range of 400 to 700 F and contacts the oil with a non-oxidizing gas, such as steam, for a residence time of at least several minutes. Thereafter the oil may be distilled and/or finished to a base lubricating oil or other distillate product. The oil subject to the process may be used oil, and can be subject to a dewatering or removal of light contaminants treatment prior to being subject to the process.

Abstract: Process flow sequences for the reduction of equipment fouling in the fractional distillation of light end hydrocarbon components, such as those produced by pyrolysis or steam cracking, wherein conventional multiple hydrogenation unit configurations are replaced with upstream hydrogenation unit configurations. The upstream hydrogenation units of the invention are located at either side draws or in the reboiler circuit of deethanizers, in front-end demethanizer and front-end deethanizer sequences, or depropanizers, in front-end depropanizer sequences and obviate the need for most of the conventionally used hydrogenation units downstream.

Abstract: Method for improving the yield of lighter components in heat-refining process of petroleum heavy oil, and additive used in the method. The heat-treatment in a heating unit is effected in the presence of at least one compound (I) having at least one mercapto alkylthio group: HS--C.sub.m H.sub.2m --S--, in which "m" is an integer of 2 to 4.

Abstract: For a given percentage decomposition, the decomposition temperature of an organosilicon compound is reduced by admixing with the organosilicon compound a decomposition promoting organotin compound. The amount of decomposition promoting organotin compound admixed with the organosilicon compound is sufficient to effectively lower the decomposition temperature of the organosilicon required for a given percentage decomposition.

Abstract: A process for the pyrolysis of hydrocarbons in a reactor with at least two rows which are parallel to each other in which at least one row is supplied with a non hydrocarbon fluid containing steam to decoke the reaction zone at least in part. At least one other row is supplied with a gaseous mixture containing at least one hydrocarbon and water, to pyrolyze said mixture.

Abstract: A process for hydrocracking a heavy hydrocarbon oil feedstock, a substantial portion of which boils above 524.degree. C. is described which includes the steps of: (a) passing a slurry feed of a mixture of heavy hydrocarbon oil feedstock and from about 0.01-4.0% by weight (based on fresh feedstock) of coke-inhibiting additive particles upwardly through a confined vertical hydrocracking zone, the hydrocracking zone being maintained at a temperature between about 350.degree. and 600.degree. C. a pressure of at least 3.

Abstract: The present invention includes a process for blending two or more petroleum oils, any component of which may be an unprocessed crude oil or a processed oil derived from petroleum, in a manner to minimize fouling and coking of refinery process equipment. The blending method includes the steps of determining the insolubility number, I, for each oil, determining the solubility blending number, S, for each oil, and combining the petroleum oils in the proportions in order to keep the solubility blending number of the mixture higher than 1.4 times the insolubility number of any oil in the mixture. The present invention also includes selecting petroleum oils to minimize fouling.

Abstract: A continuous pyrolysis and decoking process and apparatus is described for the production of acetylenic compounds, in which hydrocarbons and steam are circulated in at least one tube (31) of a steam cracking reactor (30) and steam is circulated in at least one tube (32) of that reactor. The hydrocarbon effluent and steam then circulate in at least one row (1) of a pyrolysis reactor (40) and the decoking effluent comprising steam circulate in at least one other row (2) of that reactor (4) to effect decoking. A set of valves V1, V2, V11, V12 is used to alternate the pyrolysis step path and the decoking step path. The temperature in the steam cracking furnaces is lower than that in the pyrolysis reactor.

Abstract: Disclosed is a method for reducing the concentration of amines in hydrocarbon fluids and process streams by generating therein a nitrosating agent. The nitrosating agent will react with the amines to form innocuous by-products under refinery process conditions.

Abstract: A process is described for controlling the size of additive or catalyst particles mixed with heavy hydrocarbon oil feedstock containing asphaltenes and metals and being subjected to hydrotreating. A slurry feed of a mixture of the heavy hydrocarbon oil feedstock and coke-inhibiting additive particles or catalyst particles is passed upwardly through a confined vertical hydrotreating zone in the presence of hydrogen gas, while removing from the top of the hydrotreating zone a mixed effluent containing a gaseous phase comprising hydrogen and vaporous hydrocarbon and a liquid phase comprising heavy hydrocarbon. The mixed effluent is passed through a separation vessel, while withdrawing from the top of the separator a gaseous stream comprising hydrogen and vaporous hydrocarbons and withdrawing from the bottom of the separator a liquid stream comprising heavy hydrocarbons and particles of coke-inhibiting additive or catalyst.

Abstract: A flexible steam cracking process for hydrocarbon feeds comprises injection of particles with an average size of between 0.02 mm and 4 mm, at a circulation rate in indirect transfer line exchangers (4) of 20 to 180 m/s, and in a sufficient quantity to limit the increase in temperature at the outlet to the exchangers (4) to a value of less than 100.degree. C. per month, into at least one point upstream of an indirect transfer line exchanger (4), cracking zone (2) remaining in communication with downstream means (6) for the treatment of cooled effluents. At least 70% by weight of the quantity of injected particles is introduced between the outlet to the cracking zone (2) and the tubes of the indirect transfer line exchanger (4). Chemical decoking is carried out in the tubes of the cracking zone at time intervals of less than 4 months by establishing accelerated coke gasification conditions, for example by injecting compounds which catalyse gasification by steam, or by decoking in air and/or steam.

Abstract: Method for reducing deposition of cokes in heat-refining process of petroleum high-molecular hydrocarbons, characterized in that heat-treatment in a heating unit is effected in the presence of at least one compound (I) having at least one mercaprtoalkylthio group:HS--C.sub.m H.sub.2m --S--in which "m" is an integer of 2 to 4.

Abstract: A facility and a process for steam cracking include controlled injection of solid particles into a transfer line exchanger (3). The particles are injected via injection lines, numbering between 1 and 8, just upstream of an impact-diffuser (6) comprising solid surfaces disposed on either side of the line for transfer of the cracked gases to the exchanger; this impact-diffuser is located in the inlet cone (2) of the exchanger, is permeable to the gases via a plurality of passages and at least 70% opaque viewed from the transfer line.

Abstract: A method is disclosed for reducing coke deposition in a pyrolysis furnace which comprises treating the pyrolysis furnace with a combination of sulfur- and phosphorus-containing compounds having a total sulfur to phosphorus atomic ratio of at least 5.

Abstract: A process for thermally and catalytically upgrading a heavy feed in a single riser reactor FCC unit is disclosed. A heavy feed is cracked in the base of the riser at higher than normal cracking temperatures for at least 1.0 seconds of vapor residence time, then quenched. Quenching with large amounts of quench, preferably downstream of the mid point of the riser, increases conversion as compared to use of the same amount of quench within one second. Small amounts of quench, near the riser outlet, crack heavy feed roughly as well as large amounts of quench, near the base of the riser. High velocity, atomizing quench nozzles reduce riser pressure and/or catalyst slip in downstream portions of the riser, further increasing gasoline selectivity and reducing coke yields.

Abstract: Apparatus for injecting antifoulant solution into a hot gaseous process stream in a thermal cracking furnace tube to inhibit coke deposition includes an inner antifoulant supply tube having one end connected to a pressurized supply of antifoulant solution and an access port along the furnace tube and the other end connected to an inlet of a centrifugal, atomizing nozzle having an outlet for discharging the antifoulant solution as a spray of small drops. An outer tube extends in concentric, insulating relation along the antifoulant supply tube between the access port and the nozzle, A flow deflector has an apertured peripheral wall with a portion defining a tubular mixing and vaporizing chamber extends coaxially along the furnace tube and an axial inlet end mounted in registration with the nozzle outlet to receive all spray therefrom. An axial outlet end is radially enlarged so as to deflect the gaseous process stream through wall apertures into the chamber.

Abstract: An improved method for cracking a hydrocarbon feedstock comprising passing the feedstock through furnace tubes at high temperatures. The improvement comprises tubes comprised of a nickel-cobalt alloy containing: nickel; 27.0-33.0 weight percent cobalt; 26.0-30.0 weight percent chromium; 2.4-3.0 weight percent silicon; 0.20-0.80 weight percent titanium; not more than 3.5 weight percent iron; not more than 1.5 weight percent manganese; not more than 1.0 weight percent columbium; not more than 1.0 weight percent molybdenum; not more than 1.0 weight percent tungsten; not more than 0.15 weight percent carbon; not more than 0.030 weight percent phosphorus; and not more than 0.015 weight percent sulfur. The improvement results in lower coking rates inside the furnace tubes, thus enhancing furnace efficiency and tube life.

Abstract: A method is provided for cooling prior to decoking a petroleum coke drum having a substantially solidified mass of petroleum coke by initiating the injection of water into the coke drum while the average temperature of the coke within the coke drum is greater than about 500.degree. F., wherein the average flow rate of water injected into the coke drum over the initial 10 minute period of water injection is from about 0.0033 to about 0.01 gpm per cubic foot of coke in the coke drum; and thereafter continuing the injection of water into the drum for a total injection time of at least about 60 minutes, at a flow rate during the 50 minute period immediately following the initial 10 minute period less than about 0.0036 to about 0.011 gpm per cubic foot of coke in the coke drum.

Abstract: The rate of coke formation during the aromatization of gasoline boiling range hydrocarbons in which the hydrocarbons are contacted with a zeolite catalyst is significantly reduced by providing a concentration of a silyating agent in the hydrocarbon feed.

Abstract: A heat exchange surface in reactors and/or heat exchangers of installations for the conversion of hydrocarbons and other organic compounds at high temperatures in the gaseous phase. According to the invention, the metallic surfaces coming into contact with the organic substances are treated at a temperature of 300 to 1000.degree. C. over a period of 0.5 to 12 hours with a mixture of a silicon- and sulfur-containing product and a dry gas flow which is inert with respect to the silicon- and sulfur-containing product. The invention is further directed to a process for producing a catalytically inactivated metallic surface in chemical reactors and/or heat exchangers.

Abstract: A fluid containment article that exhibits a reduced tendency for thermal decomposition products to deposit and adhere to its surface in contact with a hydrocarbon fluid, such as a hydrocarbon fuel, at elevated temperatures. Deposition and adhesion of thermal decomposition products are avoided by tailoring both the composition and surface finish of the surface contacting the hydrocarbon fluid. Preferred characteristics are achieved by appropriately preparing the surface of the article to have a surface roughness characterized by an R.sub.max of up to about 0.4 micrometer, and then depositing an oxide coating on the surface using a deposition process that yields a coating consisting essentially of a metal oxide and the vapors of an organometallic compound used in the deposition process.

Abstract: The corrosion of metals in contact with aqueous alkanolamine solution in acid gas removal units is inhibited by maintaining in the alkanolamine solution a corrosion inhibiting amount of a thiodialkanol. The thiodialkanol is useful for inhibiting the corrosion of metals in both the acid gas rich and lean portions of the acid gas removal unit.

Abstract: Articles for hot hydrocarbon fluid wherein the surface for contacting the fluid is a diffusion barrier material or a catalytic material coated on a metal substrate. The material is either catalytically-inactive tantalum oxide which inhibits the formation of coke in the fluid or catalytically-active zirconium oxide which promotes the formation of a loosely adherent coke in the fluid while inhibiting the formation of gum in the fluid. The coating materials, i.e., the diffusion barrier coating material and the catalytic coating material, are deposited by chemical vapor deposition (CVD), e.g., by effusive chemical vapor deposition of an organometallic compound on the surface without the use of carrier gas, without pre-oxidation of the surface and without thermal decomposition of the diffusion barrier material or the catalytic coating material.

Abstract: The polymerization of an ethylenically unsaturated monomer such as isoprene, butadiene and acrylonitrile is inhibited during storage or handling thereof by the addition of a dihydroxycinnamic acid or derivative thereof.

Abstract: A method of inhibiting the formation of fouling deposits occurring in spent caustic wash systems used for ethylene dichloride (EDC) manufacturing processes. Fouling occurs in these systems when they are in contact with EDC processing streams contaminated with oxygen-containing compounds, such as aldehydes. These deposits are formed in EDC processing streams contaminated with oxygen-containing compounds while in contact with a caustic solution having a pH>7. The invention comprises adding an effective deposit-inhibiting amount of a non-enolizable carbonyl compound to the caustic solution. Preferred non-enolizable carbonyl compounds are formaldehyde, glyoxal, benzaldehyde, p-anisaldehyde, formic acid, glyoxalic acid and paraformaldehyde.

Abstract: A paraffinic solvent is mixed with bitumen froth containing water and solids. Sufficient solvent is added to induce inversion when the mixture is subjected to gravity or centrifugal forces. The emulsion reports to the water phase and a dry bitumen product is obtained.

Abstract: The present invention includes a method for blending two or more petroleum feedstreams, petroleum process streams, or combination thereof, at least one of which includes the solute asphaltenes so that the asphaltenes remains a solute. The blending method includes the steps of determining the insolubility number, I.sub.N, for each feedstream, determining the solubility blending number, S.sub.BN, for each feedstream, and combining the feedstreams in order of decreasing S.sub.BN number of each feedstream such that the solubility blending number of the mixture is greater than the insolubility number of any component of the mix, when the solubility blending number of any of the feedstreams or streams is equal or less than the insolubility number of any of the streams.

Abstract: The present invention is a method of preventing fouling and coke formation on the high temperature sections of hydrocarbon processing equipment which comes into contact with a hydrocarbon fluid. The method comprises adding to a carrier prior to the carrier coming into contact with the high temperature sections of such equipment, an effective amount of an antifoulant in its vapor phase selected from the group consisting of tri-tertiary-butylphenol phosphate esters and compounds having the formula I: ##STR1## wherein Q is Z, or R with the proviso that two occurrences of Q are Z, R is hydrogen, or a straight or branched alkyl group having from 1 to 7 carbon atoms, and only one or two occurrences of R may be alkyl. Z is represented by the formula II: ##STR2## wherein R.sub.2 and R.sub.3 are the same as R and only one or two occurrences of each of R.sub.2 and R.sub.3 may be alkyl, and "n" is a whole number of from 1 to 9, and mixtures thereof.

Abstract: Disclosed is a method for reforming hydrocarbons comprising contacting the hydrocarbons with a catalyst in a reactor system of improved resistance to carburization and metal dusting under conditions of low sulfur.

Abstract: Wash water is used to remove impurities such as hydrogen sulfide, ammonia, and hydrogen cyanide from light hydrocarbons and gases derived from refinery fluid catalytic cracking operations. The present invention is a process of low pressure recirculation of wash water combined with low pressure removal of waste water which results in the efficient removal of the above impurities at significantly reduced wash water rates.

Abstract: A device for drilling a layer of coke within a reactor to effect the decoking of the reactor includes a decoking tool arranged at one end of a hose for conveying a decoking fluid to the tool. The decoking tool has a first part and a second part coaxial with the first part. The second part has means for ejecting the decoking fluid against the coke layer, including a first ejection means for ejecting the fluid in a substantially axial direction downwardly to penetrate the coke layer, a second ejection means ejecting the fluid in a substantially lateral direction and a third ejection means for ejecting the fluid in a substantially upward direction to remove any coke accumulated above the tool.

Abstract: Fouling in a hydrocarbon process stream is reduced by adding to the stream a composition prepared by first reacting an olefinic compound containing at least one group of the formula ##STR1## and a carboxylic reactant having the formula ##STR2## then reacting the product formed thereby with about 0.5 equivalents to about 2 moles, per mole of the carboxylic reactant, of ammonia or a hydrazine or an amine having at least one H--N group.

Abstract: The invention relates to the protection of tubular reactors or heat exchangers against coke formation in plants for converting hydrocarbons and other organic compounds at high temperatures in the gaseous phase. The problem in such plants is that the usual steam/air cleaning processes for removing coke deposits lead to an increase in the catalytic activity of the material surfaces, which in turn shortens the service life of the plants. The object of the invention is to substantially reduce coking and to maintain the long-term passivity of steels for long operational periods.

Abstract: Carburization and metal-dusting while hydrodealkylating a hydrodealkylatable hydrocarbon are reduced even in the substantial absence of sulfur.

Abstract: The present invention relates to a method of manufacturing one or more chemical products in which a chemical reaction is performed by causing one or more reagents to flow along the inside of a tube disposed in a radiation zone of a furnace. In the method, at least a portion of the tube is caused to vibrate so as to limit the deposition of reaction by-products on the inside wall of the tube. More particularly, the tube can be vibrated at a frequency lying in the range 50 Hz to 2000 Hz. The invention also provides apparatus for performing the method of the invention, which apparatus comprises a furnace including a radiation thermal enclosure through which at least one tube passes, which tube is provided with at least one excitation means suitable for generating tube vibration.

Abstract: Methods for cracking hydrocarbons in reactor systems having improved resistances to carburization and coking. The reactor system comprises a steel portion having provided thereon a Group VIB metal protective layer to isolate the steel portion from hydrocarbons, applied to a thickness effective for isolating the steel portion from the hydrocarbon environment. The protective layer is anchored to the steel substrate through an intermediate carbide-rich, bonding layer.

Abstract: A steam cracking process and facility is described which comprises injection of erosive powder to effect at least partial decoking of transfer line exchangers without interrupting the steam cracking stream. The powder, preferably injected just upstream of the transfer line exchangers (TLE) (4), is separated from the cracked gases in primary gas/solid separators (5), temporarily stored in receiving drums at a controlled temperature and evacuated to a common powder storage and/or treatment module by pneumatic transfer by means of a relatively low flow of uncondensable gas. The process and facility can be used to collect solid fragments generated by injection of chemical compounds which are catalysts for the gasification of coke by steam.

Abstract: A hydrocarbon conversion process wherein austenitic stainless steel portions that are subject to halide stress-corrosion cracking conditions, such as the colder portions of the process equipment including effluent coolers, knockout drums, accumulation drums, and piping low points, are provided with a protective layer having improved halide stress-corrosion cracking resistance. The method comprises applying a metal cladding, plating, paint or other coating to a stressed portion of austenitic stainless steel hydrocarbon conversion process equipment, optionally curing the coated steel to form intermetallic compounds to protect the steel portions; converting hydrocarbons utilizing a halided catalyst or under conditions where a halogen-containing compound is added or evolved or both; and subjecting the protected steel portion to halide stress-corrosion cracking conditions.

Abstract: Articles for hot hydrocarbon fluid wherein the surface for contacting the fluid is a metal oxide, amorphous glass or metal fluoride diffusion barrier material coated on a metal substrate. The metal oxide, amorphous glass or metal fluoride is deposited by chemical vapor deposition (CVD), e.g., by effusive CVD of an organometallic compound on the surface without the use of carrier gas, without pre-oxidation of the surface and without thermal decomposition of the diffusion barrier coating material. Examples of coating materials deposited by effusive CVD are SiO.sub.2, TiO.sub.2, spinel and Al.sub.2 O.sub.3. The articles having the coated surfaces find utility in components subjected to high temperatures wherein the components are in contact with hydrocarbon fluids without additives, without special attention to quality control and without the need for special processing.

Abstract: The rate of coke formation during the aromatization of gasoline boiling range hydrocarbons in which the hydrocarbons are contacted with a zeolite catalyst is significantly reduced by providing a concentration of a silylating agent in the hydrocarbon feed.

Abstract: A method to inhibit coke formation on heat transfer surfaces used to heat or cool a petroleum feedstock at coke-forming conditions is disclosed. The heat transfer surfaces are treated with an effective amount of phosphonate to inhibit coke formation on the heat transfer surfaces. The phosphonate is essentially free from contributing to corrosion and from producing detrimental by-products.

Abstract: A thermal cracking process is provided which comprises contacting a thermal cracking furnace with a fluid stream which comprises steam and a polysulfide such as di-t-nonylpolysulfide under a condition sufficient to effect the suppression of the formation of carbon monoxide and thereafter introducing a steam fluid containing a saturated hydrocarbon such as ethane and a polysulfide such as di-t-nonylpolysulfide under a condition sufficient to convert the saturated hydrocarbon to an olefinic compound such as ethylene.

Abstract: The invention is a method of inhibiting the formation of fouling deposits occurring on the surface of an alkaline scrubber used to remove acid gases, such as hydrogen sulfide, carbon dioxide and mercaptans, from hydrocarbon streams. These deposits are formed during the scrubbing of pyrolytically produced hydrocarbons contaminated with oxygen-containing compounds with a caustic solution having a pH>7 which comprises adding an effective deposit-inhibiting amount of a non-enolizable carbonyl compound to the caustic solution. The invention is also a method of inhibiting the formation of fouling deposits occurring in spent caustic wash/stripper systems used for hydrocarbon manufacturing processes. Fouling occurs in these systems when they are in contact with hydrocarbon processing streams contaminated with oxygen-containing compounds, such as aldehydes.

Abstract: A process for hydrocracking a heavy hydrocarbon oil feedstock, a substantial portion of which boils above 524.degree. C. is described which includes the steps of: (a) passing a slurry feed of a mixture of heavy hydrocarbon oil feedstock and from about 0.01-4.0% by weight (based on fresh feedstock) of coke-inhibiting additive particles upwardly through a confined vertical hydrocracking zone, the hydrocracking zone being maintained at a temperature between about 350.degree. and 600.degree. C. a pressure of at least 3.

Abstract: A method for controlling the formation of gas hydrate crystals in a fluid mixture by admixing with said fluid mixture a polyoxyalkylenediamine in an amount effective to prevent and/or inhibit crystal growth.

Abstract: Aromatic compounds in small amounts function as antifoulant additives in pyrolysis furnaces which are subjected to elevated temperatures from about 500.degree. C. to about 1200.degree. C. when thermally convening hydrocarbons to ethylene as well as other useful products. These furnaces produce material that deposits and accumulates upon furnace surfaces including furnace radiant coils and transfer line exchangers. The present antifoulant additives inhibit and suppress the formation and deposition of material on furnace surfaces. The present invention is a method for inhibiting the formation of coke on the surfaces of a radiant heating section of a pyrolysis furnace and the surfaces immediately downstream of such section in contact with a hydrocarbon feedstock which comprises decoking the pyrolysis furnace, and prior to processing the hydrocarbon feedstock, adding an inhibiting compound to the pyrolysis furnace.

Abstract: A method to minimize catalyst deactivation rate and coke laydown, and maximize desired reaction rate in processing of industrially significant reactions under supercritical conditions to generate a reaction mixture stream including formed reaction products and reactants, said contacting at a desired catalyst temperature of about 1-1.2 critical temperature of the resulting reaction mixture and at a pressure between the critical pressure of the reaction mixture and a pressure necessary to establish said reaction mixture fluid density of greater than 0.65 gm/cc.