Abstract: Process and facility for upgrading heavy hydrocarbonaceous materials for making coke suitable for metallurgical purposes comprises mixing the heavy hydrocarbonaceous materials with a diluent having a closely controlled boiling range and subjecting the oil diluent mixture to distillation and careful fractionation so as to maximize liquid yields in the coking step.

Abstract: Apparatus for upgrading heavy hydrocarbonaceous materials for making coke suitable for metallurgical purposes comprises mixing the heavy hydrocarbonaceous materials with a diluent having a closely controlled boiling range so as to facilitate transport, dehydration and desalting of the crude oil. In addition, the diluent aids in controlling temperature and residence time of the crude thereby avoiding premature decomposition.

Abstract: A process is disclosed for increasing the volume of lubricating oil base stocks recovered from a crude oil. A fraction having an atmospheric boiling range of about 675.degree. to 1100.degree. F. is recovered by vacuum distillation. This fraction is treated with furfural to extract a hydrocarbon mixture containing at least 50 volume % aromatic hydrocarbons. The raffinate is a lubricating oil base stock very high in paraffinic hydrocarbons and low in naphthenic hydrocarbons. The fraction extracted by the furfural contains at least about 50 volume % aromatic hydrocarbons and less than about 10 volume % paraffinic hydrocarbons. The mixture is hydrotreated to hydrogenate a substantial portion of the aromatic hydrocarbons. The hydrotreated product then is catalytically dewaxed. After removal of low boiling components, the finished lubricating oil base stock has a viscosity of at least about 200 SUS at 100.degree. F., a pour point of less than 20.degree. F.

Abstract: A delayed coking process is provided in which the fresh hydrocarbonaceous oil feed is divided into at least two streams. One stream is introduced directly into the preheating zone of the coking zone and one stream is introduced into the coker product fractionator. The fractionator bottoms fraction is recycled to the preheating zone as a separate stream from the fresh feed stream. The separate preheated fresh feed stream is introduced into the top of the coking zone and the preheated recycled fractionator bottoms fraction is introduced into the bottom of the coking zone. The given fresh feed splitting configuration permits decreasing the recycle rate of the heavy coker product and increasing liquid yield while the top and bottom feeding to the coking zone permit subjecting the given streams to different severity of coking.

Abstract: A delayed coking process is provided in which the fresh hydrocarbonaceous oil feed is divided into at least two streams. One stream is introduced directly into the preheating zone of the coking zone and one stream is introduced into the coker product fractionator. The fractionator bottoms fraction is recycled to the preheating zone. The given fresh feed splitting configuration permits decreasing the recycle rate of the heavy coker product and increasing liquid yield.

Abstract: A used lubricating oil is reclaimed by vacuum distillation. The bottoms is vacuum pyrolyzed with limestone to form a virtually insoluble coked mass containing insoluble metal carbonates and free metal. This solid coked residuum is suitable for landfilling.

Abstract: A process is set forth for the solvent extraction and hydroliquefaction of heavy hydrocarbon oils and residua having an API gravity at 60.degree. F. of less than 20.degree. in the presence of a hydrogen atmosphere and a hydrogen donor solvent at elevated temperature and pressure. Alternately, the hydrocarbon feed can be subjected to a vacuum distillation before solvent extraction or the liquefaction can be catalyzed in-situ. The process results in improved oil production and greater denitrogenation desulfurization and demetallization.

Abstract: A process for producing a pitch is disclosed. The process involves distilling a heavy petroleum oil under reduced pressure to obtain a distillate, the distillate is hydrogenated to obtain a hydrogenated oil which is subjected to catalytic cracking. The cracked oil is subjected to distillation to obtain a high boiling point fraction having a boiling point of more than 300.degree. C. The high boiling point fraction is subjected to thermal modification in order to obtain the pitch. The pitch can be utilized in order to produce carbon fibers of high quality. By utilizing the process a greater variety of starting materials can be utilized in order to produce the pitch which is utilized to produce high quality carbon fibers.

Abstract: A method and apparatus for the thermal cracking and fractionation of petroleum heavy gas oil and simultaneously heavy crude oil feedstock below atmospheric pressure. The feedstock is fed to a fractionator after heat exchange with distillate fractions withdrawn from the fractionator. A heavy gas oil fraction is withdrawn from the fractionator, fed to a heater and subsequently to the top of a thermal cracking reactor, while the reduced or heavy crude stock is fed to the mid-section of the reactor. The cracked products are quenched with the feedstock and fed to the bottom flash zone of the fractionator. The process may also be applied to existing crude oil topping still with modifications and operated above atmospheric pressure.

Abstract: Hydrogen partial pressure in the distilled vapor phase in a stripper is maintained sufficienty to allow a smooth distillation processing whereby an efficient crude oil stripping is performed. The distillate overhead thus produced is maintained at a temperature high enough for direct feeding to a subsequent hydrotreating process by means of a reflux cooler installed at the top of the stripper.

Abstract: An upgraded benzene-synthetic natural gas product is produced from hydrocarbon gas condensate feedstock by catalytically reforming a C.sub.6 -300.degree. F. B.P. fraction and hydrogasifying the remainder of the feedstock. The overall efficiency of the process is enhanced by dealkylation of certain intermediate streams in the process and by recycling certain other aromatic and hydrogen-rich streams within the process.

Abstract: Heavy high-sulfur crude oil is subjected to distillation to produce gas and liquid hydrocarbon products and a residuum. The gas and liquid products are desulfurized. Part of the residuum is coked in a delayed coker, and sulfur in the coke is removed by high temperature calcination. The remainder of the residuum is air-blown to produce an asphalt product, and sulfur recovered from the other products is added to the asphalt to produce a sulfur-enriched asphalt product.

Abstract: An economic route to transport fuels from low grade feedstocks containing organic polycyclic components and mineral and/or metallic components comprises separating the feedstock into (a) a residue containing fuel values and substantially all of the mineral and metallic components and (b) a liquid hydrocarbon fraction; hydrogenating the liquid hydrocarbon fraction; providing hydrogen for the hydrogenation by steam reforming methane-containing gas recovered from the hydrogenated material; and providing the heat for the steam reforming by immersing the reformer reactor tubes in a fluidized bed heated by combustion of residue from the separation step. If the fluidized bed is pressurized, the process can be made substantially self-contained with all the heat and power requirements for steam generation and feedstock compression for hydrogenation and steam reforming being recovered from the flue gas.

Abstract: This invention provides an improved method for manufacturing a slate of lubricant base stocks from a paraffin base or a mixed base crude. In one embodiment of this invention, the bright stock raffinate is catalytically dewaxed with a catalyst comprising ZSM-5, for example, and the neutral oil raffinates are solvent dewaxed. The combined use of solvent and catalytic dewaxing as described herein provides a highly efficient method of manufacture without loss of product quality.

Abstract: A process is disclosed for the preparation of a hydrocarbon mixture rich in aromatics from a gasoline boiling range hydrocarbon mixture low in aromatics which comprises catalytically reforming said hydrocarbon mixture followed by contacting the reformate with certain crystalline silicates at an elevated temperature.

Abstract: A process for upgrading of Fischer-Tropsch hydrocarbon synthesis product which comprises separating said product with at least one of a light boiling fraction and/or heavy boiling fractions and contacting said fraction(s) with certain crystalline silicates to obtain an aromatic gasoline and/or a fuel oil having a lowered pour point.

Abstract: A process is disclosed for the conversion of asphaltines-containing mineral hydrocarbon oil to distillate gas oil by a processing sequence comprising thermal cracking, flashing, atmospheric fractionation, vacuum fractionation, thermal cracking, catalytic cracking or hydrocracking, and atmospheric fractionation with certain recycle of intermediate streams to achieve efficient, economic operations.

Abstract: A process for the preparation of gas oil from residual oils by combination of two stages of thermal cracking, cyclone separation, vacuum distillation, deasphalting, atmospheric distillation, and recycling of certain streams.

Abstract: A process which comprises recracking a cracked naphtha feed containing up to about 60 percent, suitably from about 20 to about 40 percent olefins, over a crystalline aluminosilicate zeolite catalyst to further crack the naphtha and saturate at least about 50 percent of the olefins, preferably from about 90 percent to about 100 percent of the olefins, based on the weight of said cracked naphtha feed. In a preferred combination a gas oil is catalytically cracked in a first stage to produce a cat cracked naphtha product of high olefin content, and an intermediate boiling component thereof is recracked as a feed in a second stage over a zeolite catalyst to saturate the olefins, and hydrodenitrogenate and hydrodesulfurize said cat cracked naphtha. The recracked cat cracked naphtha is then hydrotreated at low to mild severities and then catalytically reformed (hydroformed) to produce high octane gasoline.

Abstract: Fractionated heavy reformate containing ethyltoluenes and propylbenzenes is selectively hydrodealkylated and transalkylated to produce ethylbenzene-lean xylenes, benzene and C.sub.2 -C.sub.4 paraffins in the presence of a catalyst comprising a tungsten/molybdenum component of WO.sub.3 and MoO.sub.3 and an acidic component of 60 (wt)% of mordenite and 40 (wt)% of catalytically active alumina.

Abstract: Process for treatment of tars and oil, the process being characterized by distillation of the oil to form a vacuum distillate and vacuum residue, hydrocracking of the distillate, deasphalting of the residue, and hydrodemetallizing and hydrodesulphurizing the deasphalted residue.

Abstract: A method of preparing benzene and xylenes from catalysates of reforming of gasoline fractions comprising a mixture of aromatic C.sub.6 -C.sub.10 hydrocarbons and non-aromatic hydrocarbons which involves separation of a low-boiling fraction boiling out at a temperature of 90.degree.-108.degree. C. from a reforming catalysate by rectification. The remaining high-boiling fraction is processed in the presence of a hydrogen-containing gas at a temperature within the range of from 450.degree. to 600.degree. C. under a pressure of from 10 to 60 atm on a catalyst. The catalyst consists of 1 to 85% by weight of H-mordenite, 0.1 to 10% by weight of a hydrogenating component as which use might be made of oxides of metals of Group VI of the periodic system, sulphides of these metals, metals of Group VIII of the periodic system, sulphides thereof; the balance being a binder.

Abstract: An integrated partial oxidation-thermal cracking process is disclosed for the more complete utilization of all chemical values in crude oil feedstocks employed in the concurrent production of synthesis gas and an olefin-rich stream comprising the steps of: burning, at a high temperature, streams of fuel and oxygen in the presence of superheated steam to form a reducing stream of hot combustion products; injecting a crude oil distillate fraction stream into said reducing stream of hot combustion products; passing the resulting injected stream to a reaction zone to effect thermal cracking of said crude oil distillate fraction steam and reaction products; thermally quenching said stream; removing pitch and fractionating to provide at least one stream of hydrocarbon oil and an olefin rich gas stream; separating carbon dioxide and any contained hydrogen sulfide from said olefin rich gas stream; separating streams of synthesis gas, methane and ethylene from said olefin rich gas stream; and recycling fractions of sa

Abstract: Residual hydrocarbon stocks obtained after vacuum distillation are converted into light distillates by certain sequences of processing steps including vacuum distillation, deasphalting, hydrocracking, atmospheric distillation and catalytic hydrotreating.

Abstract: A process for making naphthenic type lubricating oils from a low VI waxy crude which comprises distilling said low VI waxy crude to 500.degree. to 650.degree. F at atmospheric pressure to separate distillable fractions therefrom, subjecting the residue to a vacuum distillation at about 25 to about 125 mm Hg absolute pressure to obtain one or more gas oil fractions, optionally hydrotreating said gas oil fractions in the presence of a Ni/Mo catalyst at 550.degree. to 650.degree. F, 0.25 to 1.0 LHSV, and 700-1500 psig, and catalytically dewaxing said distillates in the presence of a H.sup.+ form mordenite catalyst containing a Group VI or Group VIII metal at 550.degree. to 750.degree. F, 500 to 1500 psig and 0.25 to 5.0 LHSV, to obtain said naphthenic type oils having pour points to from about -60.degree. to +20.degree. F.

Abstract: A process is provided for the simultaneous and continuous hydrocracking of two feed stocks for production of maximum distillate and optimum lube oil base stock. The second feed is mixed with vaporous phase from separation of effluent from conversion of first feed stock, preferably deasphalted crude resid.

Abstract: High grade, low-sulfur needle coke is produced from heavy high-sulfur aromatic mineral oil feedstocks by a sequence of (1) fractionating the feedstock into a minor heavy fraction, and a major lighter fraction, (2) subjecting the lighter fraction to mild hydrofining, (3) blending the heavy fraction separated in step (1) with the heavy fraction of hydrofined oil from step (2), (4) subjecting the resulting blend to delayed thermal coking, and preferably (5) recycling to the coking step heavy coker gas oil recovered from the coker effluent. If desired, the aromaticity of the heavy hydrofined oil from step (2) can be increased by subjecting the same to thermal cracking prior to step (3).

Abstract: A method for catalytically cracking an isolated reactant feed, 80-100 volume percent of which is a substantially mono-aromatic hydrocarbon fraction boiling in the boiling range of heavy gasoline and the remainder of which is a vaporizable hydrocarbon fraction, under effective cracking conditions of cracking temperature, catalyst composition, catalyst activity, catalyst-to-feed weight ratio, and weight hourly space velocity, to produce an isolated product having increased low molecular weight olefin and low molecular weight mono-aromatic contents and a reduced sulfur content and having a high octane rating.

Abstract: Process for the preparation of low pour point lubricating oils comprising:I. vacuum distilling a heavy naphthenic crude oil feedstock containing from about 2 to 10 weight % of sulfur based on the weight of the feedstock, said feedstock exhibiting a specific gravity ranging from about 5.degree. to 20.degree. API to obtain at least one distillate cut exhibiting a boiling range of from about 500.degree. to 1000.degree. F and a specific gravity ranging from about 10.degree. to 25.degree. APIii. hydrocracking said distillate cut in at least one hydrocracking zone in contact with a hydrocracking catalyst at a temperature from about 650.degree. to 850.degree. F, a hydrogen partial pressure of about 500 to 5000 psig. and a space velocity of from about 0.1 to 2.0 V/V/Hr;Iii. removing the low boiling light ends from the hydrocrackate; andIv. recovering a low pour point lubricating oil.

Abstract: A process for hydrodenitrogenation of shale oil comprising fractionating the shale oil into relatively light and heavy fractions, passing the relatively light fraction through a zone containing a catalyst comprising supported molybdenum and Group VIII metal and passing the relatively heavy fraction through a zone containing a catalyst comprising supported tungsten and Group VIII metal.

Abstract: Alkyl aromatic hydrocarbons useful as chemical raw material, solvents and the like are provided in high purity by hydrocracking of a fraction rich in alkyl aromatics and lean in aliphatic hydrocarbons over a particular zeolite catalyst associated with a hydrogenation/dehydrogenation component. The charge stock is characterized by substantial absence of benzene and lighter hydrocarbons. The technique is particularly well suited to production of maximum xylenes from a fraction containing higher boiling and lower boiling alkyl aromatics. Toluene derived from the hydrocracking reaction is disproportionated in the presence of hydrogen over a zeolite catalyst and the disproportionation effluent is processed through the same recovery train as the hydrocracked product.

Abstract: A process combination is described for upgrading a gasoline product of fluid cracking by treatment with a ZSM-5 catalyst wherein the cracking operation is performed under conditions to provide a depentanized gasoline product of cracking containing not more than 15 wt.% olefins before ZSM-5 treatment thereof for octane improvement.

Abstract: Alkyl aromatic hydrocarbons useful as chemical raw material, solvents and the like are provided in high purity by hydrocracking of a fraction rich in alkyl aromatics and lean in aliphatic hydrocarbons over a particular zeolite catalyst associated with a hydrogenation/dehydrogenation component. The charge stock is characterized by substantial absence of hydrocarbons lighter than benzene. The technique is particularly well suited to production of maximum xylenes from a fraction containing higher boiling and lower boiling alkyl aromatics.

Abstract: Certain acidic heterogeneous catalysts produce large yields of benzene, toluene and xylene from alkyl aromatics of at least nine carbon atoms by a mechanism different from the classical disproportionation reaction characteristic of acid catalysts. These catalysts are characterized by a zeolite of the ZSM-5 type or zeolite ZSM-12 or zeolite ZSM-21. The reaction has the unique function of providing aliphatic by-products of higher molecular weight than is to be expected by splitting side chains from benzene rings. Typically, aromatic mixtures so derived from such charge stocks have unusually low content of ethyl benzene, thus greatly simplifying separation of xylene isomers.

Abstract: A process for making naphthenic type lubricating oils from a low VI waxy crude which comprises distilling said low VI waxy crude to 500.degree. to 650.degree. F. at atmospheric pressure to separate distillable fractions therefrom, subjecting the residue to a vacuum distillation at about 25 to about 125 mm Hg absolute pressure to obtain one or more gas oil fractions, optionally hydrotreating said gas oil fractions in the presence of a Ni/Mo catalyst at 550.degree. to 650.degree. F., 0.25 to 1.0 LHSV, and 700-1500 psig, and catalytically dewaxing said distillates in the presence of a H.sup.+ form mordenite catalyst containing a Group VI or Group VIII metal at 550.degree. to 750.degree. F., 500 to 1500 psig and 0.25 to 5.0 LHSV, to obtain said naphthenic type oils having pour points of from about -60.degree. to +20.degree. F.