Water-softening Or Purifying Or Scale-inhibiting Agents Patents (Class 252/175)
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Publication number: 20120241385Abstract: In one embodiment the invention relates to a filter media for removal of contaminants from water comprising aluminium coated granular activated carbon and granular zeolite. Another embodiment relates to a method of producing aluminium coated granular activated carbon comprising exposing granular activated carbon to an aqueous solution comprising one or more aluminium salts which is acidified to a pH of between about 5 and about 6.8, removing the aqueous solution and washing and drying the aluminium coated granular activated carbon that is produced. Further embodiments relate to: a filter system for removal of contaminants from water comprising (i) a middle zone comprising granular activated carbon and granular zeolite and (ii) a lower barrier zone comprising screening material, wherein the system allows a flow rate of water there through of from about 0.5 Lsec-1 m?2 to about 10 Lsec?1m31 2; a cartridge containing the filter system and related methods of removing contaminants from water.Type: ApplicationFiled: August 13, 2010Publication date: September 27, 2012Applicant: WATER HARVESTING TECHNOLOGIES PTY LTDInventors: David Thomas McCarthy, Ana Deletic, Timothy David Fletcher
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Publication number: 20120241382Abstract: Novel water softening products and methods of treating hard water are provided. The products comprise a chloride-free, organic salt and a chelating agent. The products are useful for regenerating ion exchange material in a water softening system and providing softened water containing both sodium and potassium ions, while avoiding the formation of undesirable precipitates (e.g., low Ksp byproducts).Type: ApplicationFiled: March 26, 2012Publication date: September 27, 2012Applicant: NORTH AMERICAN SALT COMPANYInventors: Geoffrey A. Brown, Kristopher Shelite, Jerry Poe
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Publication number: 20120223022Abstract: The present disclosure is directed to the use of rare earth-containing additives, particularly rare earth-containing additives comprising rare earths of plural oxidation states, to remove, particularly from recreational waters, various target materials, such as disinfectant by-products and precursors thereof, phosphates, and organophosphates.Type: ApplicationFiled: March 1, 2012Publication date: September 6, 2012Applicant: MOLYCORP MINERALS, LLCInventors: Carl Hassler, John Burba, Robert Cable
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Patent number: 8257748Abstract: Described are compositions containing a mixture of (a) particulate calcium hypochlorite and (b) an amount of aluminum hydroxide that is sufficient to increase the UN-burn time of the composition by a factor of at least 2.5 compared to that of the calcium hypochlorite, the composition having an available chlorine content of at least 35 weight percent. Further described are solid compositions of (a) granular calcium hypochlorite having a UN Packing Group oxidizer classification of II, and (b) an amount of aluminum hydroxide such that the composition is classified as a Packing Group III Division 5.1 oxidizer or as a non-Division 5.1 oxidizer, the composition having an available chlorine content of at least 40 weight percent. Further described are formed articles prepared from the above-described compositions.Type: GrantFiled: September 1, 2009Date of Patent: September 4, 2012Assignee: PPG Industries Ohio, Inc.Inventors: Stanley R. Pickens, Robert B. Simmons
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Publication number: 20120211427Abstract: It is disclosed a process for removing at least a portion of the furfural and acetic acid in a first stream comprised of water, at least one compound selected from the group consisting of furfural and acetic acid, C5's and C6's. Such process comprises the steps of contacting the stream with an adsorption media which has been previously contacted with a second stream comprised of the same components and the adsorption media has been regenerated by exposing it to conditions, without being in contact with the second stream, such that at least 70% of the adsorbed furfural and acetic acid have each been desorbed and at least 60% of the C5's and C6's remain adsorbed on the media.Type: ApplicationFiled: December 11, 2009Publication date: August 23, 2012Applicant: Beta Renewables S.p.A.Inventors: Andrea Bonanni, Mariella Mule'
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Publication number: 20120187047Abstract: This disclosure relates generally to methods and rare earth-containing additives for removing target materials in the form of hydroxides, carbonates, hydrates, or oxyhydroxyls from, a typically aqueous, liquid medium.Type: ApplicationFiled: January 23, 2012Publication date: July 26, 2012Applicant: MOLYCORP MINERALS, LLCInventors: Robert Cable, Carl Hassler, John Burba
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Patent number: 8222455Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In one aspect, the present technology provides polycationic quaternary ammonium compounds that comprise bis-quaternary compound. The bis-quaternary compounds of the present technology can be symmetric or dissymmetric. In another aspect, the present technology provides viscoelastic well bore treatment fluids comprising water, and at least one polycationic quaternary ammonium compound that comprises a bis-quaternary compound. In another aspect, the present technology provides polycationic carboxylates. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or 110° C.Type: GrantFiled: January 31, 2011Date of Patent: July 17, 2012Assignee: Stepan CompanyInventor: Paul Knox
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Patent number: 8215398Abstract: A depolymerized-carboxyalkyl polysaccharide formed by de polymerizing a polysaccharide having from 0.5 to 3.0 degrees of substitution and reducing the molecular weight of said polysaccharide before or after said depolymerizing provides a biodegradable scale inhibitor useful to prevent deposition of scale comprising, for example, calcium, barium, sulfate and salts thereof. The depolymerized carboxyalkyl polysaccharide is particularly useful in off shore oil production squeeze treatments and in the treatment of scale formed in industrial water treatment.Type: GrantFiled: July 7, 2008Date of Patent: July 10, 2012Assignee: Rhodia OperationsInventors: Subramanian Kesavan, Gary Woodward, Floryan Decampo
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Publication number: 20120168674Abstract: An aspect of the present disclosure relates to a functional defoaming agent composition, and more particularly to an environmentally-friendly defoaming agent composition containing loess. In an aspect, a loess-based, environmentally-friendly functional defoaming agent includes: 1-20 wt % loess; 10-30 wt % silicone resin having a kinematic viscosity of 10-50,000 cst; 1-5 wt % thickening agent; 1-10 wt % natural surfactant; 1-10 wt % water-purifying agent; and 60-80 wt % water. In another aspect, a loess-based, environmentally friendly functional defoaming agent includes: 1-20 wt % inorganic mixture of loess with at least one selected from among elvan, tourmaline and germanium; 10-30 wt % silicone resin having a kinematic viscosity of 10-50,000 cst; 1-5 wt % thickening agent; 1-10 wt % natural surfactant; 1-10 wt % water-purifying agent; and 60-80 wt % water.Type: ApplicationFiled: June 29, 2010Publication date: July 5, 2012Applicant: GREEN CHEMICAL CO., LTD.Inventors: Gyunghee Park, Haekap Jeong
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Publication number: 20120171447Abstract: A molecular sieve including a basic skeleton of a molecular sieve and magnesium and phosphorus compounds as functional materials supported on the inner surface of the basic skeleton. A method of preparation of a modified molecular sieve including (1) dissolving a magnesium salt in water to obtain a magnesium salt solution; (2) dissolving phosphoric acid in water to obtain a phosphoric acid solution; (3) adding a molecular sieve to the magnesium salt solution, stirring, standing, drying for dehydration, and baking; and (4) adding a modified molecular sieve with supported magnesium compounds obtained from the step (3) to the phosphoric acid solution, stirring, standing, drying for dehydration, and baking to obtain a modified molecular sieve. The modified molecular sieve has high selectivity for ammonia nitrogen in wastewater.Type: ApplicationFiled: March 14, 2012Publication date: July 5, 2012Inventors: Hongqiang REN, Tao ZHANG, Lili DING
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Patent number: 8211842Abstract: The present invention relates to an agent for the preventive and/or curative cleaning of materials in contact with water, characterized in that it includes sodium chloride and at least one dispersant detergent and/or a non-ionic surfactant having at least one detergent action and at least one oxidizing agent, characterized in that the oxidizing agent is selected from solid-form precursors of hydrogen peroxide and in that the cleaning agent is in solid form, such as pellets, granules, bars tablets, large pellets or powder, the salt(s) being used as binders between the various components. Another objective of the present invention is to provide a method for agglomerating the various ingredients according to the present invention, even when they are present in a liquid form. The present invention also relates to the use of the cleaning agent for the preventive and/or curative cleaning of materials in contact with water.Type: GrantFiled: September 14, 2007Date of Patent: July 3, 2012Inventors: Roman Gerusz, Antoine Vanlaer
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Publication number: 20120128608Abstract: Hybrid copolymer compositions include a hybrid copolymer including at least one ethylenically unsaturated monomer and a naturally derived hydroxyl containing chain transfer agent as an end group; and a hybrid synthetic copolymer including one or more synthetic polymers derived from the at least one ethylenically unsaturated monomer with at least one initiator fragment as an end group. The hybrid copolymer composition may be prepared as a scale inhibiting composition. Methods of preparing a hybrid copolymer are also included.Type: ApplicationFiled: July 30, 2010Publication date: May 24, 2012Applicant: AKZO NOBEL N.V.Inventors: Klin A. Rodrigues, Matthew M. Vanderhoof, Allen M. Carrier, Jannifer Sanders
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Patent number: 8173067Abstract: A new, novel and useful disinfection and purification system comprised of organic compounds in synergistic action with selected metal ions and method of manufacture and use. One of the benefits that is derived from this system is the ability to quickly and easily treat a surface, fluid or medium for disinfection of bacteria, fungi, viruses, algae and protozoans, with a non-toxic, non-chlorinated mixture that effectively kills all such organisms in minutes or hours. The disinfection and purification system remains effective for long periods of time maintaining its disinfection capacity making it highly effective for stored or transported mediums such as potable drinking water. The disinfection and purification system may be incorporated with carbon block or membrane filters to disinfect filtered liquids such as water to render it potable.Type: GrantFiled: January 5, 2011Date of Patent: May 8, 2012Inventor: Bradley J. Eldred
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Patent number: 8163972Abstract: PCBs are removed from contaminated media using a treatment system including zero-valent metal particles and an organic hydrogen donating solvent. The treatment system may include a weak acid in order to eliminate the need for a coating of catalytic noble metal on the zero-valent metal particles. If catalyzed zero-valent metal particles are used, the treatment system may include an organic hydrogen donating solvent that is a non-water solvent. The treatment system may be provided as a “paste-like” system that is preferably applied to natural media and ex-situ structures to eliminate PCBs.Type: GrantFiled: May 13, 2009Date of Patent: April 24, 2012Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Jacqueline W. Quinn, Christian A. Clausen, Cherie L. Geiger, Kathleen B. Brooks
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Publication number: 20120095112Abstract: The present invention relates to the use of a branched addition copolymer as a dispersant in a gaseous, liquid or solid formulation in a range of applications and to the copolymers per se wherein the copolymer is obtainable by an addition polymerisation process, wherein said copolymer comprises: at least two chains which are covalently linked by a bridge other than at their ends; and wherein the at least two chains comprise at least one ethyleneically monounsaturated monomer, and wherein the bridge comprises at least one ethyleneically polyunsaturated monomer; and wherein the polymer comprises a residue of a chain transfer agent and wherein the mole ratio of polyunsaturated monomer(s) to monounsaturated monomer(s) is in a range of from 1:100 to 1:4; and wherein the branched copolymer dispersant contains anchoring, solubilising or stabilising moieties and wherein the resulting copolymer has a weight average molecular weight of greater than 100,000 Da.Type: ApplicationFiled: June 22, 2010Publication date: April 19, 2012Applicant: Unilever HouseInventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Roselyne Marie Andree Baudry, Neil John Simpson, Sharon Todd, Steven Paul Rannard
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Patent number: 8158561Abstract: The present invention relates to a method for inhibiting scale and corrosion in aqueous systems, for example, under high temperature and pressure conditions such as temperatures up to 250° C. and/or pressures up to 10000 psi (i.e., about 68.9 MPa). The method involves providing polymer compositions comprising 1% to 100% by weight of a phosphorus-containing amide monomer to such aqueous systems, which arise, for example, in connection with oilfield operations and some water treatment applications.Type: GrantFiled: August 13, 2010Date of Patent: April 17, 2012Assignee: Rohm and Haas CompanyInventors: Eric Greyson, Joseph Manna, Somil Chandrakant Mehta
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Publication number: 20120085966Abstract: The present invention is directed, in part, to a composition of about 60 parts by weight calcium oxide and about 40 parts by weight magnesium oxide that is administered as a buffering agent to a pool or spa in a ratio of approximately 1 cup of composition to 500 gallons of pool or spa water. The composition is produced in either a granular powder form or into a tablet form, the tablet form being capable of being fitted into a manufactured device that occupies a position upstream of the pool or spa water filter and in doing so, stabilizes and buffers the pH of the water entering the filter to about a range of between 7.2 and 7.8. The invention is also directed to enhancing the effectiveness of chlorine in sanitizing pool or spa water by removing the negative effects of phosphate compounds in the pool or spa water.Type: ApplicationFiled: October 6, 2010Publication date: April 12, 2012Inventor: Abraham Ziegler
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Patent number: 8147713Abstract: A method and composition for scale removal and leak detection is disclosed. The composition comprises a scale-removal agent and a fluorescing agent.Type: GrantFiled: June 30, 2006Date of Patent: April 3, 2012Assignee: PPG Industries Ohio, Inc.Inventors: Jeffrey A. Greene, Ronald A. Koehler
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Patent number: 8119011Abstract: Substitution of a single Ga-atom or single Ge-atom (GaAl12 and GeAl12 respectively) into the center of an aluminum Keggin polycation (Al13) produces an optimal water-treatment product for neutralization and coagulation of anionic contaminants in water. GaAl12 consistently shows ˜1 order of magnitude increase in pathogen reduction, compared to Al13. At a concentration of 2 ppm, GaAl12 performs equivalently to 40 ppm alum, removing ˜90% of the dissolved organic material. The substituted GaAl12 product also offers extended shelf-life and consistent performance. We also synthesized a related polyaluminum chloride compound made of pre-hydrolyzed dissolved alumina clusters of [GaO4Al12(OH)24(H2O)12]7+.Type: GrantFiled: February 11, 2009Date of Patent: February 21, 2012Assignee: Sandia CorporationInventors: May D. Nyman, Thomas A. Stewart
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Publication number: 20120024027Abstract: There is provided a water purification material including: a composite metal hydroxide exhibiting a layered structure and including iron ions, calcium ions, and at least one of nitrogen ions and sulfur ions; and at least one of calcium hydroxide and ferric hydroxide, in which a main peak intensity due to at least one of the calcium hydroxide and the ferric hydroxide measured by x-ray crystal structure analysis is equal to or less than half a main peak intensity due to the layered structure of the composite metal hydroxide.Type: ApplicationFiled: August 15, 2011Publication date: February 2, 2012Inventors: Hideyuki TSUJI, Tatsuoki Kohno, Akiko Suzuki, Shinji Murai, Katsuya Yamamoto, Nobuyuki Ashikaga
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Publication number: 20120004147Abstract: The present invention relates to a coated particle including a particle including at least one chelating agent of the formula COOH—CHX—N—(CH2—COOH)2, wherein X stands for carboxyalkyl, alkyl, hydroxyalkyl or aminoalkyl, and alkyl is a C1-C4 alkyl group, and the coating on the particle includes at least one scale-inhibiting additive, a process to prepare such particle, and to the use thereof in detergents, in oil field applications, in agriculture and in water treatment.Type: ApplicationFiled: December 24, 2009Publication date: January 5, 2012Applicant: AKZO NOBEL N.V.Inventors: Johannes Wilhelmus Franciscus Lucas Seetz, Jéróme Mercanton, Paul Michael Ferm, Martin Heus, Zoltán Szilágyi, Cornelis Elizabeth Johannus van Lare
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Publication number: 20110297874Abstract: The present invention relates to a composition for decreasing the hardness of water, which includes water soluble silica. The composition for decreasing the hardness of water of the present invention can decrease the hardness of hard water to a level capable of drinking on a simple and small scale level in an area without a large scale water-purifying facility.Type: ApplicationFiled: February 3, 2010Publication date: December 8, 2011Inventor: Aisam Han
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Publication number: 20110288049Abstract: Certain exemplary embodiments can provide a composition of matter comprising a solid form of chlorine dioxide complexed with a cyclodextrin. The concentration of chlorine dioxide in said solid form is greater than approximately 5.8 percent by weight. Certain exemplary embodiments can provide a method comprising forming a solid complex comprising chlorine dioxide and cyclodextrin, wherein a concentration of chlorine dioxide in the solid complex is greater than 5.8 percent by weight.Type: ApplicationFiled: May 19, 2011Publication date: November 24, 2011Inventors: Nick Blandford, Ken Harrison
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Publication number: 20110260098Abstract: A water treatment agent for removing pollutant by reinforcing potassium permanganate with intermediate manganese consists of a potassium permanganate and a chelating agent, or, alternatively, consists of a potassium permanganate, a chelating agent and an inducer. The chelating agent is capable of forming a coordination complex with the intermediate manganese which is produced during the reaction of potassium permanganate and organic substance. Thus self decomposition of intermediate manganese is reduced so that the effective utilization rate is increased and the capability for potassium permanganate to degrade organic pollutants is enhanced. The inducer accelerates the production of the intermediate manganese and increases the utilization rate so that the capability of potassium permanganate for degrading the organic pollutants is further enhanced.Type: ApplicationFiled: June 8, 2009Publication date: October 27, 2011Inventors: Jun Ma, Jin Jiang, Pang Suyan, Liuz Zenghe
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Patent number: 8039428Abstract: Modified polysaccharide polymers for use as anti-sealant and dispersant. The polymers are useful in compositions used in aqueous systems. The modified polysaccharides are also useful in detergent formulations, water treatment, dispersants and oilfield applications and as fiberglass binders. Such applications include a modified polysaccharide having up to about 70 mole % carboxyl groups per mole of polysaccharide ASU and up to about 20 mole % aldehyde groups per mole of polysaccharide ASU. The applications can also include a blend of modified polysaccharides and other synthetic polymers.Type: GrantFiled: April 14, 2010Date of Patent: October 18, 2011Assignee: Akzo Nobel, N.V.Inventors: Klin A. Rodrigues, John S. Thomaides, A. Levent Cimecioglu, Martin Crossman
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Publication number: 20110226702Abstract: A solubilized reagent for treating and binding heavy metals and method of producing and process of using the same. The solubilized reagent includes an isolated supernatant of a slurry or a saturated or supersaturated solution of alkali metal/alkaline earth metal carbonate, alkali metal/alkaline earth metal sulfide, and triple super phosphate.Type: ApplicationFiled: June 30, 2009Publication date: September 22, 2011Inventor: Theodore Sall
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Publication number: 20110193011Abstract: The present invention relates to a process for the purification of water by adding surface-reacted calcium carbonate or an aqueous suspension comprising surface-reacted calcium carbonate and having a pH greater than 6.0 measured at 20° C., to the medium, wherein the surface-reacted calcium carbonate is a reaction product of natural calcium carbonate with carbon dioxide and one or more acids and the use of the surface-reacted natural calcium carbonate for this process.Type: ApplicationFiled: April 14, 2011Publication date: August 11, 2011Inventors: Patrick A.C. Gane, Joachim Schölkopf, Daniel Gantenbein
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Publication number: 20110183883Abstract: The present invention provides the use of a composition comprising a polyalkyleneimine and/or salts or derivative thereof for the prevention of corrosion of non-metallic in organic items during a washing or rinsing process, in particular during an automatic dishwashing process.Type: ApplicationFiled: August 14, 2009Publication date: July 28, 2011Applicant: Reckitt Benckiser N.V.Inventors: Karlheinz Ulrich Hahn, Karin Werner
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Publication number: 20110174334Abstract: A method of treatment for inhibiting sulfur-based corrosion or scaling or for removing scaling from a surface including inhibiting corrosion caused by sulfur-containing materials, reducing corrosion caused by sulfur-containing materials, inhibiting scaling caused by sulfur-containing and sulfur-containing materials in gas, liquid or solid phase or any combination of multiple phases of materials, reducing scaling caused by sulfur-containing and sulfur-containing materials, and removing scaling caused by sulfur-containing and sulfur-containing materials. The method involves contacting sulfur-containing materials with a composition containing a turpentine liquid. The method also involves contacting corrodible surfaces or surfaces prone to scaling with a composition containing a turpentine liquid.Type: ApplicationFiled: March 10, 2010Publication date: July 21, 2011Applicant: Green Source Energy LLCInventors: Liang-tseng Fan, Mohammad Reza Shafie, Julius Michael Tollas, William Arthur Fitzhugh Lee
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Patent number: 7976725Abstract: An efficient cyclic process and related compositions for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH. The cyclic process provides a means of safe and effective use of chlorine dioxide with reduced concern of chlorite accumulation in the aqueous system. The disclosed chemistry used to support the cyclic process can be applied independently or in various combinations that are effectively inert. This dramatically reduces safety concerns since the chlorine dioxide is produced in-situ to the application and in dilute concentrations. Also, the process allows for regeneration of inert anions such as bromide and chlorite thereby reducing operating cost.Type: GrantFiled: January 9, 2009Date of Patent: July 12, 2011Assignee: Truox, Inc.Inventor: Roy William Martin
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Patent number: 7972532Abstract: A synergistic composition is provided for controlling odor from waste products. The composition comprises a combination of nitrate salt, sulfide-consuming compound, pH-elevating compound, sulfide-oxidizing, nitrate-reducing bacteria, and sulfide-oxidizing enzyme. The method includes adding a sufficient amount of the composition to a waste stream to provide sufficient sulfide-consuming compound to effect immediate removal of sulfide. The composition incorporates a pH elevating compound, which both decreases the amount of gaseous H2S and puts the aqueous phase into a pH range where naturally occurring bacteria can more easily metabolize the sulfide. The composition also includes one or more nitrate salts which will accomplish longer term prevention of odors. Specific bacteria are incorporated into the formulation to insure that the nitrate has the right type and amount of bacteria present to prevent formation of and/or consume sulfide.Type: GrantFiled: May 15, 2009Date of Patent: July 5, 2011Assignee: Siemens Industry, Inc.Inventors: Gregory D. Simpson, Glenn W. Holden
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Publication number: 20110139724Abstract: A composition and method for reducing a concentration of chlorite in water. The composition comprises a mixture of ferrous iron and a polyaluminum chloride. The mixture is contacted with a water containing chlorite.Type: ApplicationFiled: August 28, 2009Publication date: June 16, 2011Applicant: Siemens Water Technologies Corp.Inventor: Glenn W. Holden
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Patent number: 7960455Abstract: Use of copolymers comprising alkylene oxide units, which copolymers comprise incorporated randomly or blockwise by polymerization (a) 50 to 93 mol % of acrylic acid and/or a water-soluble salt of acrylic acid, (b) 5 to 30 mol % of methacrylic acid and/or a water-soluble salt of methacrylic acid and (c) 2 to 20 mol % of at least one nonionic monomer of the formula I where the variables have the following meaning: R1 hydrogen or methyl; R2 a chemical bond or unbranched or branched C1-C6-alkylene; R3 identical or different unbranched or branched C2-C4-alkylene radicals; R4 unbranched or branched C1-C6-alkyl; n 3 to 50, as additive to phosphate- and/or phosphonate-comprising aqueous systems in industrial technical plants.Type: GrantFiled: June 14, 2006Date of Patent: June 14, 2011Assignee: BASF AktiengesellschaftInventors: Stephan Nied, Karl-Heinz Buechner, Marcus Guzmann
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Publication number: 20110133116Abstract: A method for securing the use of an aqueous medium under any substantial exclusion of metal ion interference is disclosed. A phosphonic acid compound containing: a selected phosphonate moiety and a moiety selected from a limited number of species; or hydrocarbon chains containing aminoalkylene phosphonic acid substituents; or alkylamino alkylene phosphonic acids containing an active moiety embodying N, O, and S. The technology can, by way of illustration, be used in numerous applications including secondary oil recovery, scale inhibition, industrial water treatment, paper pulp bleaching, dispersant treatment, sequestering application, brightness reversion avoidance and paper pulp treatment.Type: ApplicationFiled: January 21, 2009Publication date: June 9, 2011Applicant: DEQUEST AGInventors: Patrick Notte, Tessa Johnson, Albert Devaux
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Patent number: 7947633Abstract: Viscoelastic compositions are disclosed herein containing an effective amount of one or more random or structurally defined polycationic quaternary ammonium compounds for controlling the viscoelasticity of the composition. In at least one aspect, the present technology provides polycationic quaternary ammonium compounds comprising dissymmetric bis-quaternary compounds. In another aspect, the present technology provides viscoelastic compositions comprising polycationic quaternary ammonium compounds that comprise dissymmetric bis-quaternary compounds. In yet another aspect, the present technology provides polycationic quaternary ammonium compounds comprising a carboxylate functional polycationic quaternary ammonium compound. Preferred viscoelastic compositions of the present technology maintain viscoelasticity at a temperature greater than about 80° C., preferably greater than about 100° C. or about 110° C.Type: GrantFiled: July 29, 2010Date of Patent: May 24, 2011Assignee: Stepan CompanyInventor: Paul Knox
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Patent number: 7943058Abstract: Tagged scale-inhibiting polymers, compositions comprised thereof and preventing or controlling scale formation therewith, the tagging units being units deriving from a monomer having the formula X2C?CYY? wherein X is a hydrogen atom, or a C1-C4 alkyl radical, Y is a hydrogen atom or a C1-C4 alkyl radical, Y? is a radical having formula -L-Arom, wherein L is a covalent bond or a divalent organic linking group optionally comprising heteroatoms, and Arom is a group comprising at least two conjugated aromatic rings, said rings comprising conjugated carbon atoms, and, linked to said carbon atoms, hydrogen atoms or other substituents.Type: GrantFiled: June 25, 2004Date of Patent: May 17, 2011Assignee: Rhodia ChimieInventors: Emma Hills, Pascal Chapon
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Publication number: 20110094969Abstract: A method of removing arsenic and heavy metals from water using metal salt hydroxide-gels is provided. The arsenic present in water is adsorbed onto the hydroxide-gels which can effectively be filtered through a diatomaceous earth (DE) filtration bed. The combination of DE mixed hydroxide-gels is also effective in removing arsenic from water and heavy metals from water.Type: ApplicationFiled: March 16, 2010Publication date: April 28, 2011Inventors: Manoranjan Misra, Peter Lenz
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Patent number: 7931822Abstract: Methods and compositions utilizing aluminum, magnesium, and calcium-based additives for the treatment and neutralization of wastewater are described for removing contaminants from wastewater, including reducing phosphorous-containing compounds, total suspended solids (TSS), biological oxygen demand (BOD), fats, oils, and greases (FOG), and total Kjedahl nitrogen (TKN) are described. Methods and compositions to control pH, sulfur and sodium loads present in wastewater and precipitatable solids are described. Concentrations of aluminum, magnesium, and calcium-based additives are maintained at mass action concentrations to the wastewater component levels present in the wastewater and bracketed approximately +/?0.5 pH units about the pK value of the soluble, buffering species.Type: GrantFiled: March 1, 2007Date of Patent: April 26, 2011Assignee: Inland Environmental Resources, Inc.Inventors: Douglas G. Kelley, Richard A. Handley
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Patent number: 7927510Abstract: The present invention is directed to a granular water treatment composition, comprising: 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 55 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition. The present invention is also directed to a water treatment tablet, comprising 35-95 wt % calcium hypochlorite; 1 to 50 wt % magnesium sulfate or a hydrate thereof; 0.1 to 10 wt % lime; and 0.1 to 10 wt % of a water soluble zinc salt or a hydrate thereof; wherein the weight percents are based on the total weight of the composition.Type: GrantFiled: April 20, 2007Date of Patent: April 19, 2011Assignee: Arch Chemicals, Inc.Inventors: Richard M. Mullins, Michael J. Unhoch
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Patent number: 7927509Abstract: An efficient cyclic process and related compositions for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH. The cyclic process provides a means of safe and effective use of chlorine dioxide with reduced concern of chlorite accumulation in the aqueous system. The disclosed chemistry used to support the cyclic process can be applied independently or in various combinations that are effectively inert. This dramatically reduces safety concerns since the chlorine dioxide is produced in-situ to the application and in dilute concentrations. Also, the process allows for regeneration of inert anions such as bromide and chlorite thereby reducing operating cost.Type: GrantFiled: January 23, 2009Date of Patent: April 19, 2011Assignee: Truox, Inc.Inventor: Roy William Martin
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Patent number: 7927508Abstract: An efficient cyclic process and related compositions for the in-situ generation of oxyhalogens from anions of chloride, bromide and chlorite in an aqueous system using in-situ generated sulfate free radicals. The cyclic process and compositions enhance the rate of inactivation of microbiological organisms especially those resistant to inactivation from free halogen based sanitizers, and oxidation of oxidation resistant organic based compounds in aqueous solution. Aquatic facilities susceptible to accumulation of organic N-chloramines and other oxidation resistant compounds, as well as oxidation resistant parasitic organisms such as cryptosporidium and Giardia, obtain dramatic improvements in the rate of oxidation and subsequent inactivation of these undesirable contaminants.Type: GrantFiled: December 18, 2008Date of Patent: April 19, 2011Assignee: Truox, Inc.Inventor: Roy W. Martin
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Patent number: 7922933Abstract: This invention relates to a method for enhanced sanitation and oxidation of aqueous solutions at aquatic facilities. The method provides a means for the in-situ generation of chlorine dioxide from dilute solutions of chlorite anions at near neutral pH, and enhanced inactivation rates of microbiological organisms including cryptosporidium.Type: GrantFiled: July 23, 2009Date of Patent: April 12, 2011Assignee: Truox, IncInventor: Roy W. Martin
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Publication number: 20110073802Abstract: The present invention provides for a slow release composition, preferably as a tablet, for industrial water systems, under an alkaline pH or high water hardness, using as an active ingredient a multifunctional amine of Formula (I) and a hydrophilic polymer, and other components such as a compression agent, in one composition as a biocide, biostat, biodispersant, deposit penetrant aid, organic deposit remover, detergent, surfactant, antifoam, scale inhibitor, scale remover, and a corosion inhibitor. The composition is used in multiple water cycles, can remove, disperse or inhibit fouling. The active ingredient(s) of the composition is released over a long time, up to 6 months.Type: ApplicationFiled: March 12, 2010Publication date: March 31, 2011Inventors: Anthony P Haag, Attila G Relenyi
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Publication number: 20110046239Abstract: The present invention relates to a method for forming a calcium-based carrier particle consisting of the calcium-based material, an active, with or without a surface modification, a stabilizing agent, and the related composition. The calcium-based particle is illustrated by the general formula Cax(PO4)y(OH)zR and may also include a silica or silica oxide substituent. R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, sulfates, and water soluble agents and, as needed, a surface modification, S, which may be either organic or inorganic. A stabilizing agent may be necessary to maintain dispersion of the particles in aqueous media. Examples of a surface modifying material and stabilizing agents are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers.Type: ApplicationFiled: August 24, 2009Publication date: February 24, 2011Inventors: Bruce A. Keiser, Timothy S. Keizer, Brett M. Showalter, Tiffany Bohnsack, James H. Adair, Mylisa Parette, Amy Knupp, Andrei S. Zelenev, Jason R. Burney
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Publication number: 20110046023Abstract: The present invention relates to a method for inhibiting scale and corrosion in aqueous systems, for example, under high temperature and pressure conditions such as temperatures up to 250° C. and/or pressures up to 10000 psi (i.e., about 68.9 MPa). The method involves providing polymer compositions comprising 1% to 100% by weight of a phosphorus-containing amide monomer to such aqueous systems, which arise, for example, in connection with oilfield operations and some water treatment applications.Type: ApplicationFiled: August 13, 2010Publication date: February 24, 2011Inventors: Eric Greyson, Joseph Manna, Somil Chandrakant Mehta
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Publication number: 20110046241Abstract: The present invention relates to a method for forming a calcium-based carrier particle consisting of the calcium-based material, an active, with or without a surface modification, a stabilizing agent, and the related composition. The calcium-based particle is illustrated by the general formula Cax(PO4)y(OH)zR and may also include a silica or silica oxide substituent. R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, sulfates, and water soluble agents and, as needed, a surface modification, S, which may be either organic or inorganic. A stabilizing agent may be necessary to maintain dispersion of the particles in aqueous media. Examples of a surface modifying material and stabilizing agents are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers.Type: ApplicationFiled: August 24, 2009Publication date: February 24, 2011Inventors: Timothy S. Keizer, Brett M. Showalter, Bruce A. Keiser, James H. Adair
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Publication number: 20110046240Abstract: The present invention relates to a method for forming a calcium-based carrier particle consisting of the calcium-based material, an active, with or without a surface modification, a stabilizing agent, and the related composition. The calcium-based particle is illustrated by the general formula Cax(PO4)y(OH)zR and may also include a silica or silica oxide substituent. R is an active or actives such as an organic or inorganic molecule that includes markers, amines, thiols, epoxies, organosilicones, organosilanes, sulfates, and water soluble agents and, as needed, a surface modification, S, which may be either organic or inorganic. A stabilizing agent may be necessary to maintain dispersion of the particles in aqueous media. Examples of a surface modifying material and stabilizing agents are inorganic salts of aluminum and boron or organic materials such as organosilanes or low molecular weight polymers.Type: ApplicationFiled: August 24, 2009Publication date: February 24, 2011Inventors: Timothy S. Keizer, Brett M. Showalter, Bruce A. Keiser, James H. Adair
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Patent number: 7887749Abstract: A new, novel and useful disinfection and purification system comprised of organic compounds in synergistic action with selected metal ions and method of manufacture and use. One of the benefits that is derived from this system is the ability to quickly and easily treat a surface, fluid or medium for disinfection of bacteria, fungi, viruses, algae and protozoans, with a non-toxic, non-chlorinated mixture that effectively kills all such organisms in minutes or hours. The disinfection and purification system remains effective for long periods of time maintaining its disinfection capacity making it highly effective for stored or transported mediums such as potable drinking water. The disinfection and purification system may be incorporated with carbon block or membrane filters to disinfect filtered liquids such as water to render it potable.Type: GrantFiled: November 29, 2007Date of Patent: February 15, 2011Inventor: Bradley J. Eldred
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Publication number: 20110033558Abstract: The invention concerns the polymers obtained by the use of sulphur compounds in a process for controlled radical polymerisation in water of acrylic acid and/or acrylic acid with hydrosoluble monomers. It concerns also their uses as dispersant agents or agents to aid grinding and/or co-grinding of mineral matters in aqueous suspensions, and as dispersant agents incorporated directly in aqueous formulations containing mineral matters. Finally, the invention concerns the formulations of mineral matters obtained in this manner.Type: ApplicationFiled: October 21, 2010Publication date: February 10, 2011Applicant: COATEX S.A.S.Inventors: Jean-Marc Suau, Christian Jacquemet
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Patent number: RE42907Abstract: Device for conditioning water produced by environmental conditioning or dehumidification apparatuses or plants, comprising a device (2) for measuring the quantity of water produced by a condenser (1) which transforms atmospheric humidity into water, a feeder (4) of a corrective composition of salts and mineral substances, preferably in the form of tablets (P), for dispensing at least one of them in proportion to the quantity of water measured, a mixing vessel (5) receiving the measured water and at least a tablet (P) provided by the feeder (4), a control and command unit (6) that activates the feeder (4) in proportion to the quantity of water measured and received, and a tank (7) for collecting and filtering the water provided with means (70) for filtering micro-organisms and bacteria and a valve (81) for the exit of potable water.Type: GrantFiled: December 12, 2002Date of Patent: November 15, 2011Inventor: Osman Akkad