Abstract: The invention provides: 1) a composition comprising a hydrophilic graft polymer of 60 to 98 wt %, a polyether compound of 20 to 40 wt %, and an unsaturated carboxylic acid type polymer of 0 to 5 wt %; 2) a polymer which is obtained by graft-polymerizing a monoethylenically unsaturated monomer onto a polyether compound having a repeating unit of --RCH--CH.sub.2 --O-- of 30 mol % or more of the polyether compound, and has a purity of at least 75%; and 3) a scale inhibitor comprising a polymer which is obtained by graft-polymerizing a monoethylenically unsaturated monomer onto a polyether compound having ethylene oxide of 80 mol % or more as a structural unit, and has a hydroxyl group value of 30 mgKOH/g or more and an acid value of 200 mgKOH/g or more.

Abstract: The present invention relates to a method for inhibiting the formation and deposition of silica scale in water systems. The method includes treating the water in such water systems with an effective amount of a polyamide that exhibits secondary amine and/or ether and amide functional groups.

Abstract: An improved process for inhibiting calcium carbonate scaling in aqueous systems such as that employed in the kraft process for the production of wood pulp. Such an improved process is achieved by the addition to the system of at least one antiscalant comprising at least one monomer unit derived from the group consisting of 1,2-dihydroxy-3-butene, N-(hydroxymethyl) acrylamide, and N-(sulfomethyl) acrylamide, and at least one monomer unit derived from the group consisting of maleic acid, acrylic acid, acrylamide, methacrylic acid, itaconic acid, vinyl sulfonic acid, styrene sulfonic acid, N-tertbutylacrylamide, butoxymethylacrylamide, N,N-dimethylacrylamide, sodium acrylamidomethyl propane sulfonic acid, and salts thereof, with the proviso that said polymers do not contain the monomer unit --(CH.sub.2 --CH.dbd.CH--CH.sub.2 --O)--.

Abstract: A carboxylic acid polymer containing a carboxylic group and having at least one kind of bond selected from the group consisting of an amino bond, an ether bond, and a thioether bond in a side chain is prepared by polymerizing a monomer component containing a carboxylic acid monomer represented by General Formula (3): ##STR1## where Y.sub.4 is a hydrogen atom, an allyl group, or a --(CHR.sub.4).sub.c --W.sub.2 --(CHR.sub.5).sub.d --COOR.sub.6 group, each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6, independent of the others, is either a hydrogen atom or an alkyl group of a carbon number from 1 to 6, each of W.sub.1 and W.sub.2, independent of the other, is either an --NH-- group, an --S-- group, or an --O-- group, and each of a, b, c, and d, independent of the others, is an integer from 0 to 6. The carboxylic acid polymer has a superior metal-scavenging ability (chelating ability) and can be suitably used, for example, as a chelating agent.

Abstract: Solid, slowly dispersible well treatment composites are provided which have a sufficiently high melting point to prevent melting of the composite in hot weather. The composites have a low solubility and high specific gravity compared to prior art treatment agents; thus the composites readily sink in well fluids and slowly release treatment ingredients over time, depending on the downhole conditions. The composites include a nonylphenol ethoxylate having at least about 50 moles of ethylene oxide per mole of nonylphenol and a fatty acid amide having from 16-20 carbon atoms. Preferably, the composites further include a weighting agent and active ingredients selected from the group consisting of corrosion inhibitors, scale inhibitors, bactericides, scale converters, foaming agents, and mixtures thereof.

Abstract: Methods and compositions for detackifying and dispersing, and coagulating/flocculating and dispersing solventborne and waterborne paints, respectively, in paint spray booth waters are disclosed. An aqueous composition of water soluble cationic polymer, nonionic surfactant and amphoteric surfactant is used in conjunction with a silicate compound to treat the paint spray booth waters.

Abstract: The composition for clarifying a body of water comprises at least an anionic polyacrylamide, aluminum chloral hydrate or aluminum oxide and citric acid combined in amounts sufficient to produce a clarification of a body of water. If necessary, calcium carbonate or calcium sulfate may be included in the composition to neutralize pH in acidic environments for increased effectivity.

Abstract: This invention provides a process for clarifying waters and wastewaters by using aluminum salts and/or aluminum polymers and newly formulated high molecular weight quaternized polymers. The aluminum polymers and the high molecular weight quaternized polymers are blended in the water or wastewater to form a flocculated suspension, causing liquid-solid separation. The quaternized polymers have a molecular weight of greater than approximately 1,000,000 and have a viscosity greater than about 1,000 cps at a concentration of approximately 20% in water. Preferably, poly-aluminum hydroxychloride, poly-aluminum chloride and poly-aluminum siloxane sulfate are used as aluminum polymers along with high molecular weight quaternized polymers such as di-allyl di-methyl ammonium chloride (DADMAC), to significantly improve liquid-solid separation in waters and wastewaters. Aluminum salts, such as alums and aluminum chloride, can also be used along with the quaternized polymers to clarify water.

Abstract: The invention relates to the inhibition of tripolyphosphate and pyrophosphate scales in aqueous systems involving adding to said aqueous system at least one copolymer comprising the following monomers in polymerized form:(I) 50-80% by weight of one or more weak acids; (II) 2-50% by weight of one or more strong acids;(III) 0-30% by weight of one or more monoethylenically unsaturated C.sub.4 -C.sub.8 dicarboxylic acids; and(IV) 0-30% by weight of one or more monomethylenically unsaturated monomers polymerisable with (I), (II) and (III);wherein the total of monomers (I), (II), (III), and (IV) equals 100% by weight of copolymer.The invention is particularly suited to the inhibition of tripolyphosphate and pyrophosphate scales which occur as a result of using low phosphate (STPP) containing detergent formulations.

Abstract: This invention relates to novel organic phosphonate compounds which can be used as water treatment agents. More specifically, this invention relates to 1,1 -diphosphonic acid N-oxides and water-soluble salts thereof for control of corrosion and scale in aqueous systems. Preferred N-oxides are morpholinomethane-1,1-diphosphonic acid N-oxide and N,N-dimethylaminomethane-1,1-diphosphonic acid N-oxide.

Abstract: A method of controlling the deposition of silica-containing scales and their adhesion to surfaces in contact with an aqueous system is disclosed which comprises adding to the aqueous system a synergistic combination of:(a) diethylenetriamine penta methylene phosphonic acid; and(b) a material selected from the group consisting of 2 phosphonobutane-1,2,4-tricarboxylic acid; high molecular weight, 3:1, acrylic acid/allylhydroxypropylsulfonate ether copolymer; ethylene oxide-propylene oxide block copolymers; and polyepoxysuccinic acid and salts thereof.

Abstract: The present invention is a process of treating aqueous systems to prevent precipitation of dissolved metal ion species, for example, Ca, Mg, Ba, Cu, Fe, Mn and Zn. This has the effect of preventing scale and/or stain formation. The process involves introducing 0.5 to 15000 ppm (or mg/liter) of a synergistic mixture of HEDP and DETPMP into the aqueous system to be treated.

Abstract: The present invention is a process of treating aqueous systems to prevent precipitation of dissolved metal ion species, for example, Ca, Mg, Ba, Cu, Fe, Mn and Zn. This has the effect of preventing scale and/or stain formation. The process involves introducing 0.5 to 100 ppm of a synergistic mixture of HEDP and DETPMP into the water system to be treated.

Abstract: A method of controlling the deposition of silica-containing scales and their adhesion to surfaces in contact with an aqueous system is disclosed which comprises adding to the aqueous system an ethylene oxide-propylene oxide copolymer.

Abstract: This invention relates to a liquid composition for the control of pitch deposition in pulp and paper making comprising an aqueous solution of (1) a derivatized cationic guar, and (2) styrene maleic anhydride copolymer. The invention also relates to a process for inhibiting pitch deposition in pulp and papermaking systems and on papermaking equipment.

Abstract: The present invention relates to a composition and method for inhibiting chloride-induced corrosion of and limescale formation on ferrous metals and alloys which contact aqueous solutions, the composition containing a corrosion inhibiting amount of at least one polycarboxylic acid and/or its alkali metal or alkaline earth metal salts and a sufficient amount of a base to bring the aqueous solution to a pH effective to inhibit both chloride-induced corrosion and limescale formation.

Abstract: A method of processing peat for use in treating a contaminated aqueous solution, especially storm water runoff entering a sewer system. The method includes mixing raw peat with heated sulfuric acid to produce a slurry. The slurry is dried and then mixed with a binder medium to produce an aggregate material. The aggregate material is extruded to form a plurality of pellets. The plurality of pellets are then baked in an oven at a temperature in the range of approximately 900-1000 degree F. Peat processed in accordance with the present invention serves as both an ion exchange material as well as an organic retention material. A filter canister for maintaining pelletized peat is also disclosed.

Abstract: Water-treatment compositions are provided which contain a water-soluble, water-treatment polymer and, optionally, additional water-treatment chemicals. The polymers are prepared from water-treatment monomers and a photo-inert, latently-detectable moiety which is covalently bonded to the polymer backbone. When the residue of the photo-inert moiety is contacted with an amount of a photoactivator which is effective to cause the residue of the photo-inert moiety to absorb within a wavelength ranging from 300 to 800 nanometers, the residue of the photo-inert moiety is detectable at concentrations of less than 100 parts per million. Methods are also provided which allow for the determination of the concentration of low levels, i.e., less than 100 ppm, of the water-treatment polymer present in an aqueous system.

Abstract: Several copolymers of aspartic acid and another monomer provide effective mild steel corrosion inhibitors and scale formation inhibitors under oil field conditions. The copolymers are polymers of modified polyaspartic acid mer units and polyaspartic acid mer units. The resulting polymers are biodegradable.

Abstract: A water-treating agent comprising a ternary copolymer of conjugated dienesulfonic acid/(meth)acrylic acid/2-hydroxyethyl (meth)acrylate, or a ternary copolymer of conjugated dienesulfonic acid/(meth)acrylic acid/(meth)acrylamido-2-methylalkanesulfonic acid ternary copolymer, is effective against scaling and fouling in water systems and a method for treating water with the water-treating agent. When combined with a corrosion inhibitor, the water-treating agent exhibits an excellent anti corrosion effect.

Abstract: A maleic acid-based copolymer is provided which has a weight-average molecular weight of 1,000 to 100,000, a calcium ion-capturability of 300 mgCaCO.sub.3 /g or higher calculated as calcium carbonate, and a clay-dispersibility of 1.2 or higher. Another maleic acid-based copolymer is also provided which has a level of adsorption to clay within the range of 20 to 90% and a calcium ion-stabilization degree constant of 4.0 or larger.

Abstract: The present invention provides a composition and method of administering same for inhibiting the growth of microorganisms. The composition of the present invention includes sufficient amounts of peracetic and a non-oxidizing biocide. The method of the present invention includes the step of adding sufficient amounts of peracetic acid and the non-oxidizing biocide to industrial process waters.

Abstract: Phosphonic acid polymers are prepared from di- or polyphosphonic acids having one or more unsaturated C.dbd.C bonds (e.g. vinylidene-1,1-diphosphonic acid), either as homopolymers or as higher polymers with at least one further compound having unsaturated C.dbd.C bonds (e.g. acrylic acid). The polymers can be used as, or in connection with, flame-retardants, corrosion inhibitors, coatings, cements and ion exchange resins.

Abstract: The use of halo-benzotriazoles as corrosion inhibitors in aqueous systems is disclosed. Specific isomers of chloro-methylbenzotriazole were found to be more effective corrosion inhibitors than tolyltriazole in the presence of chlorine.

Abstract: An agent for water treatment comprises a water-soluble polymer obtained by polymerizing a monomer component containing a water-soluble monomer capable of dissolving in water of 50.degree. C. in the amount of 1 weight % or more, having an ethylenically unsaturated group, and exhibiting fluorescence. The water-soluble polymer has a ratio of fluorescence intensity FL.sub.1 /FL.sub.2 larger than 1, wherein FL.sub.1 is an intensity of fluorescence obtained in dissolving a water-soluble polymer in a concentration of 10 ppm in pure water, and FL.sub.2 is an intensity of fluorescence obtained in dissolving phenol in a concentration of 0.1 ppm in pure water.

Abstract: Polynucleate metal hydroxide anionic compounds and method for their production. The compounds have the formula:M.sub.a N.sub.b (OH).sub.c X.sub.d Y.sub.e Z.sub.f.(H.sub.2 O).sub.gwhereinM is a tri- or more valent metal ion;N is a divalent metal ion that forms a soluble salt with anions X, Y or Z;OH represents the level of basicity;X is a monovalent anion;Y is a divalent anion;Z is a trivalent anion;a is 1;b is from 0.15 to 2.0;c is from 0.3 to 5;d is from 0 to 3;e is from 0.1 to 2.25;f is from 0 to 1; andg is greater than 4 where the compound is in the form of an aqueous solution, or from 0 to 20 where the compound is not in the form of an aqueous solution. The compounds are useful for water treatment for removal of suspended solids and for various applications in the paper industry.

Abstract: The present invention relates to a composition and process for stabilizing inorganic salts. The composition generally includes a carboxylated polymer that has been neutralized with an alphahydroxy amine. The composition can be used, for example, to disperse and suspend inorganic salts, such as silicates and sulfates, in fluids for inhibiting the insoluble inorganic matter from agglomerating and forming deposits on surfaces in contact with the fluid. The present invention is particularly suitable for use in industrial water handling systems such as boilers, coolers, and the like in other various industrial applications where inorganic salts form scale in a vessel in which an aqueous liquid is handled.

Abstract: A first media provides an oxygen inducer such as catalase, bound and stabilized in pellet form so as to dissipate slowly into aqueous surroundings. A second media provides an oxygen supplier such as a peroxide, stabilized by combination with a proteinaceous compound such as urea and bound in a matrix that limits oxygen release. The two media are combined in aqueous environment to generate nascent oxygen at a modulated rate such that the oxygen is efficiently absorbed into the surrounding aqueous environment, promoting growth of aerobic species and reducing biological pollution. Specific adaptations demonstrate benefits of use in shrimp or fish ponds, raw milk, fruit juice, fresh food, silage and animal feed, fertilizer, plumbing systems, and grease traps. When used in ponds, further adaptations reduce algae and phytoplankton populations.

Abstract: A biodegradable anti-scalant for steam generators, boilers and other heat transfer equipment is provided. Anti-scalants prepared in accordance with the present invention include aspartic acid, poly(aspartic acid) and copolymers of aspartic acid and functionalized aspartic acid. Anti-scalants provided in accordance with the present invention are biodegradable and therefore more environmentally friendly than currently available anti-scalant for use with hard water. Methods and use of making anti-scalants are also provided.

Abstract: A method of treating water to inhibit the formation of salt scale is disclosed. The method is particularly effective at inhibiting the formation and deposition of mineral salts in brine concentration and evaporation systems. The method comprises introducing into the system a polyepoxysuccinic acid of the general formula: ##STR1## where n ranges from about 2 to about 50, M is hydrogen or a water soluble cation such as Na.sup.+, NH.sub.4.sup.+ or K.sup.+ and R is hydrogen, C.sub.1-4 alkyl or C.sub.1-4 substituted alkyl.

Abstract: The present invention provides for methods and compositions for inhibiting the corrosion of iron-containing metals in contact with aqueous systems. The present invention further provides for compositions and methods for inhibiting pitting of iron-containing metals in contact with aqueous systems. The methods include the use of a copolymer of acrylic or methacrylic acid and 2-acetoacetoxyethylmethacrylate with or without a polyvalent metal salt or a polyhydroxy-polycarboxylic acid.

Abstract: A composition for of controlling scale formation and deposition and corrosion in aqueous systems is described wherein a treatment solution of a substoichiometric amount of a composition comprising a scale/corrosion inhibitor in combination with a substituted alkylpolycarboxylate is employed. The scale/corrosion inhibitor can be a phosphonate such as hydroxyethylidene diphosphonic acid, 2-phosphonobutane-1,2,4-tricarboxylic acid, hydroxyphosphonoacetic acids, amino phosphonates; terpolymers, copolymers and homopolymers of acrylic acid, maleic acid, epoxysuccinic acids such as polyepoxysuccinic acid or mixtures thereof. The substituted alkylpolycarboxylates are compounds of the general structure: R--X.sub.m --Y.sub.n wherein R is a hydrocarbon functionality having 4 to 18 carbons; X, when present, is --NH--, --NY.sup.1 --, --N-->O, --N--OC--Y.sup.1, --O-- or --S--; n is greater than or equal to 1; m=O or 1; and Y and Y.sup.

Abstract: A method and composition for simultaneously controlling the deposition of scale and the formation of corrosion in a cooling water system comprising adding to the system a combination of (a) a water soluble copolymer having the structure: ##STR1## wherein R.sub.1 is H or lower (C.sub.1 -C.sub.4) alkyl, F is H.sub.2 or O, M is a water soluble cation, R.sub.2 is (CH.sub.2 --CH.sub.2 --O).sub.n, ##STR2## or mixture of both, n is an integer of from 1 to about 40, R.sub.3 is H, lower (C.sub.1 -C.sub.4) alkyl or an acetate, and (b) a water soluble polymer characterized by the structural formula: ##STR3## wherein R.sub.1 is H or lower alkyl (C.sub.1 -C.sub.3); R.sub.2 is OH, OM, or NH.sub.2 ; M is a water soluble cation; R.sub.

Abstract: The water-treatment processes of this invention utilize maleate copolymers to sequester water hardness ions, modify crystal formation in water and inhibit scale formation (e.g., in circulating water systems and oil field production systems), which polymers contain from about 40 to 70 mole percent of dicarboxylic functionality provided by a maleate monomer upon polymerization, from about 1 to about 15 mole percent of the polymerized residue of a non-ionic monomer, and from about 20 to about 50 mole percent of monocarboxylic functionality.

Abstract: A biodegradable scale inhibitor and dispersant is provided. The scale inhibitor includes a copolymer comprising at least one of N-oxygenatedhydrocarbonamide monomers and at least one of amino acid monomers. A method of reducing scale build-up on heating exchanger surfaces that come in contact with an industrial water is provided by adding a copolymer comprising at least one of N-oxygenatedhydrocarbonamide monomers and at least one of amino acid monomers to the water system such as cooling towers.

Abstract: A new block copolymer, which is excellent with regard to abilities such as dispersibility, chelatability, and scale inhibitability, includes a polyalkylene glycol structural unit and a polyglyoxylate structural unit. This block copolymer, for example, can be produced by carrying out a polymerization reaction between a polyalkylene glycol and a glyoxylic acid-based monomer in the presence of a catalyst in a polymerization reaction system having a water content of about 30 mol % or less relative to the polyalkylene glycol, and used as a cement dispersant, pigment dispersant, water-treating agent, or detergent builder.

Abstract: A method to prevent the degradation of water soluble film placed in contact with halogenated hydantoin or chlorinated cyanuric acid and an apparatus for disinfecting water systems. Halogenated 5,5-dialkyl hydantoin or chlorinated cyanuric acid is combined with a stabilizing agent to prevent the halogenated hydantoin or chlorinated cyanuric acid from discoloring or degrading a polymeric film which it may contact. The oxidizing agent includes alkaline hydroxide, alkaline carbonates, alkaline bicarbonates, alkaline phosphates, alkaline silicates, and alkaline borates. Polymeric films for which this is suitable include 2-hydroxy propyl cellulose and poly(vinyl alcohol).

Abstract: Aqueous, homogeneous 20 to 60% solutions (L) of mixtures of(A) copolymers of(x) (meth)acrylic acidwith (y) maleic acid or maleic acid anhydride in the molar ratio (x)/(y)=0.7/1 to 7/1, with an average molecular weight M.sub.w in the range of from 500 to 500'000, as free acids and/or sodium saltsand (B) Nitrilotriacetic acid as free acid and/or sodium salt,in which the weight ratio (A)/(B) is in the range of from 1/1 to 1/10 at least 25% of the total carboxy groups are present as sodium salt and the pH of (L) is in the range of from 5 to 11, are suitable as adjuvants for the treatment of fibrous material, in particular as scouring agents for dyeings of hydrophilic fibrous material.

Abstract: A method of remediating methyl amine and/or methyl amine derivative odors in aqueous systems by contacting the methyl amine or methyl amine derivative with a compound having amide or imide functionality, such as a hydantoin composition, in the presence of hydrogen peroxide. The amide/imide composition is preferably a non-halogenated, singe-ring hydantoin that binds methyl amines to the amide or imide functional group of the hydantoin.

Abstract: Compositions comprising polyamine and melamine polymers in certain ratios are provided for coagulating suspended solids in wastewaters such as deinking process waters and raw waters.

Abstract: An all-in-one cooling water treatment composition includes a high concentration of peroxide, preferably hydrogen peroxide, in combination with a polyhydric alcohol and a phosphonate to stabilize the peroxide in a concentrated solution. The composition further includes a yellow metal corrosion inhibitor such as aromatic triazole and optionally polymeric dispersants and ferrous metal corrosion inhibitors and/or molybdate metal corrosion inhibitors. In this composition the phosphonate, preferably HEDP, acts both to stabilize the peroxide and, at the same time, provides anti-scalant treatment for the cooling tower. Due to the stability provided by the HEDP and its anti-scalant properties, this can be formulated as an all-in-one treatment composition which is stable at high concentrations and can be added to effectively control biocidal activity, scale and corrosion.

Abstract: This invention relates to the use of iminoalkylenephosphonic acids to prevent corrosion, including both localized corrosion and general corrosion on iron based metal surfaces in contact with a corrosive system water in an aqueous system. The invention also relates to the use of the iminoalkylenephosphonic acids to control formation, deposition and adherence of scale at the surfaces of metals in contact with a scale-forming system water in an aqueous system.

Abstract: The present invention provides a composition and method of administering same for inhibiting the growth of microorganisms. The composition of the present invention includes sufficient amounts of a peracetic acid or peracetic acid/peracid blend and a non-oxidizing biocide. The method of the present invention includes the step of adding sufficient amounts of the peracetic acid or peracetic acid/peracid blend and the non-oxidizing biocide to industrial process waters.

Abstract: The invention relates to a process for the treatment of water and of surfaces in contact with the said water in order to prevent the attachment and/or to, remove and/or to control macroorganisms, in particular molluscs, on the said surfaces in contact with the water, in which process at least one biocidal and/or biostatic active product is employed which is injected into the water and/or applied to the said surfaces, according to which process the active product(s) used comprise(s) at least one polyamine of formula I:R.sub.1 --NH?(CH.sub.2).sub.3 --NH!.sub.n --(CH.sub.2).sub.3 NH.sub.2(I)in which formula R.sub.1 is a C.sub.8 -C.sub.22 alkyl or alkenyl radical and/or at least one monoamine of formula II:R.sub.2 NH.sub.2 (II)in which formula R.sub.2 is a C.sub.8 -C.sub.22 alkyl or alkenyl radical, and n is an integer between 0 and 3 (inclusive).The invention also relates to a composition to be injected into the water and to a paint for covering the surfaces in contact with the water.

Abstract: An aqueous system containing scale forming salts including both calcium carbonate and calcium phosphate and characterized by high pH and high calcite concentrations which further contains a synergistic effective amount of a combination comprising (A) a polyether polyamino methylene phosphonate, (B) a terpolymer comprising the monomers of acrylic acid, sulfophenoxymethallyl ether and maleic acid, (C) a hydroxyphosphonoacetic acid, and (D) a phosphonocarboxylic acid copolymer comprising the monomers of acrylic acid, telomer with (1-hydroxy-1-methylethyl) phosphinic acid monosodium salt, and 2-acrylamido 2 methylpropane sulfonic acid, is disclosed. A method for inhibiting the formation, deposition and adherence of such scale forming salts in the aqueous system employing the synergistic combination is also provided.

Abstract: The invention is a method for the prevention of scale formation on metal or other surfaces in contact with scale-forming industrial water with an effective scale-inhibiting amount of an ether 1,1-diphosphonate of the general formula: ##STR1## The invention is also a method for the prevention of corrosion on metal surfaces in contact with corrosive industrial water with an effective corrosion-inhibiting amount of an ether 1,1-diphosphonate of the same general formula. A preferred ether 1, 1-diphosphonate is 1,1, diphosphono-4,7-dioxaoctane for both methods.

Abstract: The use of polyaspartic acid prepared by polycondensation of aspartic acid in the presence of phosphoric acid in a molar ratio of from 1:0.05 to 1:10 at temperatures of at least 120.degree. C. to give polysuccinimide, and subsequent hydrolysis of the polysuccinimide with bases to give at least partially neutralized polyaspartic acid, as additive to detergents and cleaners in amounts of from 0.1 to 10% by weight, and detergents and cleaners which contain polyaspartic acids prepared in the presence of phosphoric acid.

Abstract: A heat transfer fluid is disclosed which comprises a glycol, a phosphate, and a copolymer additive which is a copolymer of an ethylenically substituted carboxylic acid and an aldehyde. A method for preparing the heat transfer fluid comprises admixing 92 to 96 weight percent of one or more glycols; 2 to 4 weight percent of a phosphate; and 0.01 to 0.25 weight percent of the copolymer additive. Precipitation of phosphate salts is inhibited in phosphate-containing glycol-based fluids by the addition of the copolymer additive before mixing the fluid with water.

Abstract: Alkaline earth metal scales, particularly barium sulfate and strontium sulfate, and silica-based scales, particularly potassium fluorosilicate, are removed from industrial processing equipment, tubular goods, and other scaled materials with a composition comprising sufficient potassium base to provide an overall system pH of between about 12.0 to about 14.0, a polyaminocarboxylic acid, preferably EDTA, a hydroxycarboxylic acid synergist, a pH buffering agent, a wetting agent, and optionally a sodium base.

Abstract: A method for inhibiting barium sulfate precipitation in low pH aqueous fluids of underground petroleum-bearing formations by adding to such systems an effective amount of low molecular weight water-soluble polymer containing 5-35 weight percent sulfonic acid monomer units and 65-95 weight percent carboxylic acid monomer units, is provided. Polymer compositions based on 10-15 weight percent 2-acrylamido-2-methyl-1-propanesulfonic acid, 15-65 weight percent acrylic acid and 25-70 weight percent maleic acid are particularly preferred for use at very low pH conditions, e.g., 5.5 or less in the presence of high sulfate ion and barium ion concentrations.