Carboxylic Organic Compounds Containing Patents (Class 252/76)
  • Patent number: 6676848
    Abstract: Corrosion protection of magnesium and aluminum alloys in engine coolants and heat-exchange fluids is achieved by the use of a select group of aliphatic and aromatic carboxylate acids or the alkaline metal, ammonium or amine salts thereof in combination with a fluoride and/or a fluorocarboxylic acid or salt thereof. These compositions have been found to significantly improve the high temperature magnesium corrosion protection properties of coolants, and are of use in automobile engine coolant systems.
    Type: Grant
    Filed: November 15, 2001
    Date of Patent: January 13, 2004
    Assignees: Texaco Inc., Texaco Development Corporation
    Inventors: Jean-Pierre Leopold Maes, Serge Stefan Lievens
  • Publication number: 20030218150
    Abstract: A chemical composition and method of deployment into a coolant or coolant systems to provide at least one benefit to the system. The additive compositions includes a silicate component and a silicate stabilizer, the compositions being in the form of a solid, a non-flowable semi-solid or a flowable semi-solid which is dissolved into a coolant and enters the cooling system so as to provide at least one benefit to a coolant system when released, for example, to protect an engine. The method of deployment into the coolant and subsequently the cooling systems includes injecting or dissolving the additive into the coolant, forming the additive to the housing of the system or forming the coolant to the filter located in the housing of the cooling system.
    Type: Application
    Filed: February 26, 2003
    Publication date: November 27, 2003
    Applicant: Dober Chemical Corporation
    Inventors: Thomas J. Blakemore, Yu-Sen Chen, Heather Michalesko
  • Publication number: 20030071242
    Abstract: A non-aqueous, reduced toxicity polyhydric alcohol based heat transfer fluid is provided comprised of at least one polyhydric alcohol that acts as an ADH enzyme inhibitor, such as for example propylene glycol, thereby reducing the toxicity of ethylene glycol if ethylene glycol. The heat transfer fluid may also include corrosion inhibitors that are soluble in the polyhydric alcohols used for the heat transfer fluid. The heat transfer fluid may be used as a coolant in internal combustion engines such as automobile engines, a coolant for cooling electrical or electronic components, as a heat transfer fluid for solar energy heating systems, or a heat transfer fluid for maintaining temperatures in industrial processes. A low toxicity preparation fluid for absorbing water from heat exchange systems prior to installation of the heat transfer fluid is also provided that is comprised of ethylene glycol and at least one polyhydric alcohol, preferably propylene glycol, that acts as an ADH enzyme inhibitor.
    Type: Application
    Filed: August 23, 2001
    Publication date: April 17, 2003
    Inventors: John W. Evans, J. Thomas Light
  • Publication number: 20030047210
    Abstract: Fire hydrants are protected from freezing by including potassium formate, preferably at least 10% by weight, in the water enclosed in them during nonuse.
    Type: Application
    Filed: August 24, 2001
    Publication date: March 13, 2003
    Applicant: Clearwater, Inc.
    Inventors: William Hyland, John H. Hallman
  • Patent number: 6524497
    Abstract: An ice storage element (28), especially for the auxiliary air conditioning system of a motor vehicle, with a hollow body for forming at least one storage space (34) for an ice storage medium (36) which is liquid in the thawed state and which can be brought into heat-conductive connection with a refrigerant. The ice storage medium (36) contains a thickening agent to suppress sloshing of the ice storage medium (36) in the thawed state and to ensure freezing of the ice storage medium (36) in the form of a slush.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: February 25, 2003
    Assignee: Webasto Thermosysteme GmbH
    Inventors: Peter Glaser, Albrecht Otte, Andreas Ludwig
  • Patent number: 6508951
    Abstract: A glycol-based coolant composition which provides an excellent metal corrosion inhibition despite its low phosphorus content is disclosed. The glycol-based coolant composition contains: (A) 0.1-5.0% by weight of at least one ingredient selected from group A′ consisting of C6-C12 aliphatic dibasic acids and their alkali metal salts; (B) 0.1-10% by weight of at least one ingredient selected from group B′ consisting of alkyl benzoic acids and their alkali metal salts; (C) 0.001-0.1% by weight of at least one ingredient selected from group C′ consisting of strontium compounds and their alkali metal salts; and (D) 0.1-0.3% by weight of at least one ingredient selected from group D′ consisting of phosphoric acids and their alkali metal salts.
    Type: Grant
    Filed: September 1, 2000
    Date of Patent: January 21, 2003
    Assignees: CCI Kabushiki Kaisha, Honda Giken Kogyo
    Inventors: Yasuaki Mori, Michihiro Hori, Mitsuru Osawa, Takashi Nagashima
  • Patent number: 6482778
    Abstract: Transmission fluid compositions comprising a zinc detergent and at least one phosphorus-containing additive have enhanced performance capabilities. The use of the zinc detergent and the phosphorus-containing additive provide transmission fluids that exhibit high steel-on-steel coefficients of friction, particularly useful in continuously variable transmissions (CVT).
    Type: Grant
    Filed: August 11, 1999
    Date of Patent: November 19, 2002
    Assignee: Ethyl Corporation
    Inventors: Samuel H. Tersigni, Sanjay Srinivasan, David L. Strait
  • Patent number: 6447692
    Abstract: A composition for enhanced heat transfer fluid performance, comprising a base heat transfer fluid and a nanometer sized phase change material. Introduction of nanometer sized phase change material into the heat transfer fluid leads to improved, high reversible thermal transport properties at elevated temperatures while ensuring low viscosity of the fluid at sub-freezing temperatures. A method for preparing of the heat transfer fluid with enhanced heat transfer performance, comprising making nanometer sized capsules having the phase change material contained therein and dispersing the capsules into the base heat transfer fluid.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: September 10, 2002
    Assignee: HRL Laboratories, LLC
    Inventors: Leslie A. Momoda, Amanda C. Phelps
  • Publication number: 20020117648
    Abstract: Disclosed are phosphate ester base fluids and aircraft hydraulic fluids containing a novel combination of phosphate ester components. The disclosed aircraft hydraulic fluids contain from about 30 to about 45 weight percent, based on the total weight of the fluid, of tri-iso-butyl phosphate; from about 30 to about 45 weight percent, based on the total weight of the fluid, of tri-n-butyl phosphate; from about 10 to about 15 weight percent, based on the total weight of the fluid, of one or more triaryl phosphates; and an effective amount of a viscosity index improver, an acid control additive and an erosion inhibitor.
    Type: Application
    Filed: September 28, 2001
    Publication date: August 29, 2002
    Inventors: Mark E. Okazaki, Adrian D'Souza, Shlomo Antika
  • Patent number: 6413923
    Abstract: A non-corrosive cleaning composition for removing residues from a substrate. The composition comprises: (a) water; (b) at least one hydroxylammonium compound; (c) at least one basic compound, preferably selected from the group consisting of amines and quaternary ammonium hydroxides; (d) at least one organic carboxylic acid; and (e) optionally, a polyhydric compound. The pH of the composition is preferably between about 2 to about 6.
    Type: Grant
    Filed: November 15, 1999
    Date of Patent: July 2, 2002
    Assignee: Arch Specialty Chemicals, Inc.
    Inventors: Kenji Honda, Michelle Elderkin, Vincent Leon
  • Patent number: 6406643
    Abstract: Hydraulic oil including an ester of tall oil obtained with at least one polyvalent alcohol selected from the group consisting of a polyhydroxy compound of neopentane and poly(ethyleneglycol), an oxidation inhibitor, a corrosion inhibitor, an antifoam agent, and an EP lubricant.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: June 18, 2002
    Assignee: Voitelukeskus Tonitila Oy
    Inventors: Ari Lindén, Arto Tonttila, Mika Tonttila
  • Patent number: 6398984
    Abstract: Corrosion protection of magnesium and aluminum alloys in engine coolants and heat-exchange fluids is achieved by the use of a select group of aliphatic and aromatic carboxylate acids or the alkaline metal, ammonium or amine salts thereof in combination with a fluoride and/or a fluorocarboxylic acid or salt thereof. These compositions have been found to significantly improve the high temperature magnesium corrosion protection properties of coolants, and are of use in automobile engine coolant systems.
    Type: Grant
    Filed: October 13, 1999
    Date of Patent: June 4, 2002
    Assignee: Texaco Inc.
    Inventors: Jean-Pierre Leopold Maes, Serge Stefan Lievens
  • Patent number: 6391257
    Abstract: This invention relates to antifreeze compositions comprising a mixture of organic acid corrosion inhibitors. The compositions comprise (a) from about 90% to about 99.89% by weight of a liquid alcohol which functions as a freezing point depressant, or mixture thereof; (b) from about 0.1% to about 5.5% by weight of a carboxylic acid selected from the group consisting of saturated and unsaturated aliphatic, and aromatic, mono-, di- and tri-carboxylic acids, and salts and isomers thereof, and any mixture thereof, and (c) from about 0.1% to about 2% by weight of a cyclohexenoic acid, or salt, isomer or mixture thereof, having the formula: wherein each of R1, R2 and R3 is, independently, selected from the group consisting of H, OH, COOH, C1-C10 alkyl groups, glycol esters, or combinations thereof.
    Type: Grant
    Filed: August 19, 1998
    Date of Patent: May 21, 2002
    Assignee: Prestone Products Corporation
    Inventor: Peter M. Woyciesjes
  • Publication number: 20020033471
    Abstract: A coolant composition containing at least cesium formate is described as well as the use of the coolant composition in radiators and other cooling devices. The coolant composition permits a variety of benefits to the engine performance and operation of the vehicle. Other uses for the cesium formate in cooling systems and other apparatuses are described.
    Type: Application
    Filed: June 1, 2001
    Publication date: March 21, 2002
    Inventors: Thomas H. Odle, William J. Benton
  • Publication number: 20020033470
    Abstract: A non-aqueous, reduced toxicity diol based heat transfer fluid is provided comprised of at least one diol that acts as an antidote for ethylene glycol poisoning, such as for example propylene glycol. The heat transfer fluid may also include corrosion inhibitors that are soluble in the diols used for the heat transfer fluid. The heat transfer fluid may be used as a coolant in internal combustion engines such as automobile engines.
    Type: Application
    Filed: July 19, 2001
    Publication date: March 21, 2002
    Inventors: John W. Evans, J. Thomas Light
  • Patent number: 6309559
    Abstract: The invention relates to a coolant concentrate comprising a) from 0.1 to 6% by weight of at least one monocarboxylic and/or dicarboxylic acid having from 4 to 16 carbon atoms in the form of alkali metal salts, b) from 0.02 to 2% by weight of a triazinetriiminocarboxylic acid in the form of its alkali metal salt, c) from 0.02 to 2% by weight of at least one hydrocarbon triazole, d) from 0.01 to 1% by weight of at least one soluble alkaline earth metal salt, e) if desired, up to 4% by weight of water, and f) glycols to 100% by weight, in each case based on the total weight of the concentrate.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: October 30, 2001
    Assignee: Clariant GmbH
    Inventors: Peter Minks, Johann Schuster
  • Patent number: 6290870
    Abstract: The present invention relates to an acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: September 18, 2001
    Assignee: Ashland Inc.
    Inventors: David E. Turcotte, Michael A. Dituro, Arnold L. Coffey, Jr., Alden W. Olsen, Carl R. Stephens
  • Patent number: 6235217
    Abstract: A monobasic carboxylic acid is used with low levels of molybdate and a triazole compound to produce a well balanced corrosion inhibiting formulation with very low solids to minimize potential deposits and exhibit surprising long life characteristics in engine coolant applications.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: May 22, 2001
    Assignee: Ashland, Inc.
    Inventors: David E. Turcotte, Arnold L. Coffey, Jr., Alden W. Olsen, Michael A. Dituro, Carl R. Stephens
  • Patent number: 6228283
    Abstract: The present invention provides heavy duty long life corrosion inhibition formulations and compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids. The combination of a mixture of polymeric polycarboxylates, azoles, molybdenum, and a combination of nitrite and nitrate salts, phosphates, stabilized silicates and transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    Type: Grant
    Filed: October 21, 1999
    Date of Patent: May 8, 2001
    Assignee: Ashland Inc.
    Inventors: David E. Turcotte, Frances E. Lockwood
  • Patent number: 6221276
    Abstract: The invention relates to a heat transfer liquid for ventilation and air-conditioning installations to be used at low temperatures, in which installations heat is recovered from the exhaust air and conveyed to the supply air by means of a heat transfer liquid. For lowering the costs and eliminating environmental risks, the heat transfer liquid contains potassium formiate and water.
    Type: Grant
    Filed: June 11, 1999
    Date of Patent: April 24, 2001
    Assignee: ABB Installaatiot Oy
    Inventor: Dan Sarin
  • Patent number: 6203719
    Abstract: The present invention provides corrosion inhibition formulations and compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids. The combination of a mixture of polymeric polycarboxylates, azoles, nitrate salts, phosphates, stabilized silicates and transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    Type: Grant
    Filed: January 10, 1997
    Date of Patent: March 20, 2001
    Assignee: Ashland Inc.
    Inventors: David E. Turcotte, Frances E. Lockwood
  • Patent number: 6146546
    Abstract: Disclosed is a freezable coolant composition used for cold-preservation of, e.g., foods by utilizing the latent heat of fusion at the freezing point which is substantially higher than 0.degree. C. and in the range, for example, from 5.degree. C. to 26.degree. C. The composition is a ternary mixture consisting of: (A) from 98.0 to 8.0% by weight of 1,6-hexanediol; (B) from 0.5 to 3.0% by weight of sodium benzoate; and (C) from 1.5 to 89.0% by weight of water, each percentage being based on the total amount of the components (A), (B) and (C).
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: November 14, 2000
    Assignees: S*I*C Co., Ltd, Rokuro Suzuki
    Inventor: Rokuro Suzuki
  • Patent number: 6143243
    Abstract: This invention relates to a method of inhibiting the cavitation-erosion corrosion of aluminum surfaces. The method comprises the step of contacting the aluminum surface with a formulation comprising a corrosion inhibitor composition comprising one or more carboxylic acids, or salts or isomers thereof, and a polymerizable-acid graft polymer which comprises an unsaturated grafting acid and an alkylene oxide polymer, or copolymers thereof. This method has been demonstrated to be a surprisingly effective means to inhibit cavitation-erosion corrosion of aluminum surfaces found in the cooling systems of internal combustion engines.
    Type: Grant
    Filed: December 29, 1997
    Date of Patent: November 7, 2000
    Assignee: Prestone Products Corporation
    Inventors: Aleksei V. Gershun, Peter M. Woyciesjes
  • Patent number: 6126852
    Abstract: A linear monobasic aliphatic carboxylic acid is used with low levels of molybdate and a hydrocarbyl triazole to produce a well balanced corrosion inhibiting formulation with very low solids to minimize potential deposits and exhibit surprising long life characteristics in engine coolant applications.
    Type: Grant
    Filed: August 17, 1998
    Date of Patent: October 3, 2000
    Assignee: Ashland Inc.
    Inventors: David E. Turcotte, Arnold L. Coffey, Jr., Alden W. Olsen, Michael A. Dituro, Carl R. Stephens
  • Patent number: 6126851
    Abstract: A glycol-based antifreeze/coolant concentrate to be blended in coolant in a cooling system of a vehicle is disclosed, which can effectively inhibit occurrence of cavitation damage in the cooling system while suppressing production of nitrosoamine which is a known carcinogenic substance. A glycol-based antifreeze/coolant concentrate of the present invention contains a 0.05-8.0 wt. % p-toluate and a 0.01-1.0 wt. % molybdate.
    Type: Grant
    Filed: September 2, 1997
    Date of Patent: October 3, 2000
    Assignee: CCI Co., Ltd.
    Inventors: Yuji Miyake, Yasuaki Mori
  • Patent number: 6096235
    Abstract: An electrorheological fluid composition comprises dielectric particles as a disperse-phase and an electrically insulating oil as a dispersion medium, wherein the dielectric particle has a polymer portion and an electrically conductive carbon black portion and the polymer portion is grafted on the carbon black portion. The electrorheological fluid composition shows a large change in viscosity and the small current properties under an applied electric field, and excellent fluidity and dispersion stability in an absence of an applied electric field.
    Type: Grant
    Filed: May 20, 1997
    Date of Patent: August 1, 2000
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshinobu Asako, Yoshikuni Mori, Satoru Ono
  • Patent number: 6096236
    Abstract: An antifreeze/coolant composition is disclosed, which can effectively inhibit corrosion of metals, particularly cast aluminum and cast iron, and can also inhibit cavitation damage to metals in an engine cooling system. The antifreeze/coolant composition comprises a glycol as the chief ingredient, 0.1-0.5% by weight of at least one ingredient selected from among hexanoic acid heptanoic acid and their salts, and 0.1-0.5% by weight of at least one ingredient selected from among alkylbenzoic acids having C.sub.1 -C.sub.5 alkyl and their salts.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: August 1, 2000
    Assignee: CCI Co., Ltd.
    Inventors: Yuji Miyake, Yasuaki Mori
  • Patent number: 6093341
    Abstract: The invention relates to a concentrate for a heat transfer medium for solar units, comprisinga) from 45 to 98% by weight of triethylene glycol and/or tetraethylene glycol,b) from 1 to 55% by weight of 1,2-propylene glycol and/or ethylene glycol, andc) from 1 to 6% by weight of corrosion inhibitors.The concentrate is used in admixture with water for heat transport in solar units.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: July 25, 2000
    Assignee: Clariant GmbH
    Inventors: Peter Minks, Johann Schuster, Knud Pulletz
  • Patent number: 6080331
    Abstract: The present invention relates to novel silicate-, borate- and nitrate-free antifreeze concentrates based on alkylene glycols or derivatives thereof which include an inhibitor combination essentially comprising salts of carboxylic acids together with hydrocarbon-triazoles and/or -thiazoles. These antifreeze concentrates are, in particular, entirely free from any salts of inorganic acids as corrosion inhibitors. The invention also relates to ready-to-use aqueous coolant compositions comprising these antifreeze concentrates.
    Type: Grant
    Filed: June 20, 1997
    Date of Patent: June 27, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Ladislaus Meszaros, Hans Schrimpf, Klaus Pfitzner
  • Patent number: 6010639
    Abstract: A controlled-release supplement coolant additive for use in diesel engine coolant systems comprising a core containing at least one supplemental coolant additive (SCA) active component and a polymeric coating material encapsulating said core. The controlled released supplement coolant additive slowly releases the SCA active components to a diesel engine coolant system, thereby delivering an effective concentration level of SCA active components over an extended period. The controlled-release supplement coolant additive maintains a minimum concentration level of active SCA components in the coolant system. Additionally, the controlled-release supplemental coolant additive prevents overdosing the coolant system with particular SCA active components such as nitrates.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: January 4, 2000
    Assignee: BetzDearborn Inc.
    Inventors: Wayne A. Mitchell, Kurt D. Heinz, Clifford Alvin Ferrin, Jr., Narender Pal Luthra
  • Patent number: 5997763
    Abstract: An anti-freeze concentrate made by adding together at least:a) an alkylene glycol;b) an effective corrosion inhibiting amount, or more, of an unsubstituted benzoic acid; andc) an effective corrosion inhibiting amount, or more, of a C.sub.7 -C.sub.14 monocarboxylic acid.This formulation is particularly effective at inhibiting corrosion in coolants which are free of borates, primary and secondary amines, phosphates, silicates, as well as those coolants which are free of p-tertbutyl benzoic acid.
    Type: Grant
    Filed: April 27, 1998
    Date of Patent: December 7, 1999
    Assignee: Shell Oil Company
    Inventors: Raul Antonio Pabon, Jr., Nelson Eduardo Prieto
  • Patent number: 5961875
    Abstract: An antifreeze/coolant position is disclosed, which can effectively inhibit corrosion of metals, particularly cast aluminum and cast iron, and can also inhibit cavitation damage to metals in an engine cooling system. The anitifreeze/coolant composition comprises a glycol as the chief ingredient, 0.1-0.5% by weight of at least on ingredient selected from among C.sub.6 -C.sub.12 aliphatic monobasic acids and their salts, and 0.1-5.0% by weight of at least one ingredient selected from among cinnamic acid, alkylcinnamic acids, alkoxycinnanic acids and their salts.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: October 5, 1999
    Assignee: CCI Co., Ltd.
    Inventors: Yuji Miyake, Yasuaki Mori
  • Patent number: 5925173
    Abstract: This invention relates to a method of inhibiting the corrosion of flux-treated metal surfaces. The method comprises the step of contacting the flux-treated metal surface with a formulation comprising a corrosion inhibitor composition comprising one or more mono-carboxylic acids, or salts or isomers thereof, and an effective amount of a corrosion inhibiting surface active agent such as a water soluble alkali or alkaline earth metal nitrate salt. This method has been demonstrated to be a surprisingly effective means to inhibit corrosion of flux-treated metal surfaces found in the cooling systems of internal combustion engines.
    Type: Grant
    Filed: August 11, 1997
    Date of Patent: July 20, 1999
    Assignee: Prestone Products corporation
    Inventors: Richard A. Frost, Aleksei V. Gershun, William C. Mercer, Peter M. Woyciesjes
  • Patent number: 5916478
    Abstract: Heat-accumulating microcapsule dispersion includes a microcapsule provided as a small-diameter heat-accumulating material including organic compound functioning as heat accumulating material in association with a phase change thereof accommodated within a microcapsule, heat transfer fluid medium including a number of the microcapsules dispersed stably therein, and a number of thermal boundary layer stirring particles dispersed in the heat transfer fluid medium. The stirring particles has a volume average particle diameter between 0.1.times.D and 1.9.times.D relative to a layer thickness D of a thermal boundary layer formed inside a heat exchanging passage through which the dispersion is caused to flow. The particles stir the thermal boundary layer in association with movement thereof inside the heat exchanging passage.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: June 29, 1999
    Assignee: Osaka Gas Co, Ltd
    Inventors: Takatoshi Nakahira, Tetsuo Setoguchi, Masaaki Yoshikawa, Akira Kishimoto, Akio Chikazawa, Mamoru Ishiguro, Yasunori Nakanishi, Shigehiro Maeda, Yukihiko Akamatsu
  • Patent number: 5911906
    Abstract: An antifreeze/coolant composition is disclosed, which can effectively inhibit corrosion of metals, particularly cast aluminum and cast iron, and can also inhibit cavitation damage to metals in an engine cooling system. The antifreeze/coolant composition comprises a glycol as the chief ingredient, 0.1-0.5% by weight of at least one ingredient selected from among C.sub.6 -C.sub.12 aliphatic monobasic acids and their salts, and 0.1-0.5% by weight of at least one ingredient selected from among alkoxybenzoic acids having C.sub.1 -C.sub.5 alkoxy and their salts.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: June 15, 1999
    Assignee: CCI Co., Ltd.
    Inventors: Yuji Miyake, Yasuaki Mori
  • Patent number: 5885942
    Abstract: The multifunctional lubricant additive compositions of the invention preferably contain a methylene bis(dibutyldithiocarbamate) as an antiwear and extreme pressure additive, a 2,5-dimercapto-1,3,4-thiadiazole derivative as an antioxidant and antiwear additive, a tolutriazole compound as an antioxidant and corrosion inhibitor, a glycerol monooleate as a friction modifier, a calcium sulfonate as a detergent and extreme pressure additive, a zinc dialkyl dithiophosphate as an antiwear and antioxidant additive, a polymethylacrylate as a dispersant, a polyol ester as a carrier and friction modifier, a red dye for leak detection, and optionally, solvent neutral oil and a pour point depressant.
    Type: Grant
    Filed: September 23, 1997
    Date of Patent: March 23, 1999
    Assignee: NCH Corporation
    Inventors: Ruiming Zhang, Robert M. Hooks
  • Patent number: 5851419
    Abstract: An effective metal corrosion inhibitive coolant composition having an excellent pH stabilizing property is disclosed, comprising a glycol as a main ingredient, at least one C 4-C 16 alkenylsuccinic acid or its alkali metal salt in an amount of 0.5-5.0 wt. %, and at least one benzoic acid or its derivative in an amount of 0.5-5.0 wt. %. This coolant composition is further characterized in that no phosphates, amine salts, silicates, borates, or nitrites are contained to avoid their detrimental side effects.
    Type: Grant
    Filed: March 28, 1997
    Date of Patent: December 22, 1998
    Assignee: CCI Co., LTD.
    Inventors: Yuji Miyake, Yasuaki Mori
  • Patent number: 5846450
    Abstract: An absorbent for use in absorption refrigeration systems, air conditioning systems, heat pumps or dehumidifiers comprising a solution of potassium formate. The absorbent is relatively non-toxic and relatively non-corrosive towards metals. The absorbent is generally water-based but may also comprise ammonia or methanol. Additives such as corrosion inhibitors or other absorbent salts may be included.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: December 8, 1998
    Inventor: Stephen Atkinson
  • Patent number: 5840207
    Abstract: The addition of an effective amount of a liquid modified diethanolamide which is suitably a reaction product of cocoamide and phthalic anhydride to a calcium chloride composition, which can be a brine solution or a solid, reduces the amount of corrosion of metals by the resulting composition. The calcium chloride/diethanolamide composition can be used as a deicer composition.
    Type: Grant
    Filed: August 22, 1996
    Date of Patent: November 24, 1998
    Assignee: General Chemical Corporation
    Inventors: John Scott Beazley, William Edward Sadar, Douglas Robert Maynes, Mark G. Jantzen
  • Patent number: 5830380
    Abstract: An antifreeze solution for use in potable water systems is provided which has a distinct, pleasant aroma. The aroma allows the user to determine by smell the presence of the antifreeze solution in the water system. The antifreeze solution contains methyl salicylate, ethyl alcohol and propylene glycol and water in specific proportions to insure against freezing.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: November 3, 1998
    Assignee: Camco Manufacturing, Inc.
    Inventor: W. Keith Cook
  • Patent number: 5811025
    Abstract: Coolant compositions are disclosed which include only a minimum amount of metal corrosion inhibitor. The coolant compositions effectively inhibit: (1) metal corrosion; (2) precipitation of the included metal corrosion inhibitor; (3) oxidative deterioration of the included glycol; (4) lowering of the pH value of coolant fluid; and (5) chemical reaction with hard water components. A coolant composition of the invention includes an alkylbenzoic acid (or acids) or a salt (or salts) thereof, a hydrocarbon triazole and an alkali nitrate in addition to a glycol (or glycols) as a base, water and others. It is characteristic that the coolant compositions of the present invention do not include any aliphatic monobasic acids.
    Type: Grant
    Filed: October 10, 1995
    Date of Patent: September 22, 1998
    Assignee: CCI Co., Ltd.
    Inventors: Masaru Kawai, Yuji Miyake, Yasuaki Mori
  • Patent number: 5811026
    Abstract: A method of inhibiting corrosion and the formation of hydrogen and thus improving absorption in an ammonia/water absorption refrigeration, air conditioning or heat pump system by maintaining the hydroxyl ion concentration of the aqueous ammonia working fluid within a selected range under anaerobic conditions at temperatures up to 425.degree. F. This hydroxyl ion concentration is maintained by introducing to the aqueous ammonia working fluid an inhibitor in an amount effective to produce a hydroxyl ion concentration corresponding to a normality of the inhibitor relative to the water content ranging from about 0.015 N to about 0.2 N at 25.degree. C. Also, working fluids for inhibiting the corrosion of carbon steel and resulting hydrogen formation and improving absorption in an ammonia/water absorption system under anaerobic conditions at up to 425.degree. F. The working fluids may be aqueous solutions of ammonia and a strong base or aqueous solutions of ammonia, a strong base, and a specified buffer.
    Type: Grant
    Filed: August 14, 1996
    Date of Patent: September 22, 1998
    Assignee: Phillips Engineering Company
    Inventors: Benjamin A. Phillips, Eugene P. Whitlow
  • Patent number: 5800731
    Abstract: Homogeneous, electro-viscous fluids are provided which contain aluminum soaps based on products obtained by reacting one or more mono- or polycarboxylic acid(s) or the anhydrides or semi-esters thereof with reactive aluminum compounds, such as aluminum alcoholates. The aforesaid fluids manifest high electro-rheological effect and are completely homogeneous, and do not require a dispersant.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: September 1, 1998
    Assignee: RWE-DEA Aktiengesellschaft fur Mineraloel und Chemie
    Inventors: Dietrich Pirck, Hans-Dieter Grasshoff, Harald Kohnz, Peter Finmans, Tobias Carstensen, Dieter Jakubik, Wilfried Weber, Dieter Winkler
  • Patent number: 5766506
    Abstract: A heat transfer fluid is disclosed which comprises a glycol, a phosphate, and a copolymer additive which is a copolymer of an ethylenically substituted carboxylic acid and an aldehyde. A method for preparing the heat transfer fluid comprises admixing 92 to 96 weight percent of one or more glycols; 2 to 4 weight percent of a phosphate; and 0.01 to 0.25 weight percent of the copolymer additive. Precipitation of phosphate salts is inhibited in phosphate-containing glycol-based fluids by the addition of the copolymer additive before mixing the fluid with water.
    Type: Grant
    Filed: September 12, 1996
    Date of Patent: June 16, 1998
    Assignee: The Dow Chemical Company
    Inventors: Abel Mendoza, Mark E. Ogle
  • Patent number: 5741436
    Abstract: This invention relates to organic acid corrosion inhibitors for use in antifreeze coolant compositions. The corrosion inhibitors comprise a C.sub.8 mono-carboxylic acid component, or isomers and/or salts thereof, and a neo-decanoic acid, or isomers and/or salts thereof. The corrosion inhibitors of this invention provide improved corrosion protection to metal surfaces as compared to conventional inhibitors and provide surprisingly improved corrosion protection as compared to inhibitors containing only a single mono-carboxylic acid component.
    Type: Grant
    Filed: December 5, 1995
    Date of Patent: April 21, 1998
    Assignee: Prestone Products Corp.
    Inventors: Aleksei V. Gershun, William C. Mercer, Peter M. Woyciesjes
  • Patent number: 5741433
    Abstract: A controlled-release supplement coolant additive for use in diesel engine coolant systems comprising a core containing at least one supplemental coolant additive (SCA) active component and a polymeric coating material encapsulating said core. The controlled released supplement coolant additive slowly releases the SCA active components to a diesel engine coolant system, thereby delivering an effective concentration level of SCA active components over an extended period. The controlled-release supplement coolant additive maintains a minimum concentration level of active SCA components in the coolant system. Additionally, the controlled-release supplemental coolant additive prevents overdosing the coolant system with particular SCA active components such as nitrates.
    Type: Grant
    Filed: June 21, 1996
    Date of Patent: April 21, 1998
    Assignee: BetzDearborn Inc.
    Inventors: Wayne A. Mitchell, Kurt D. Heinz, Clifford Alvin Ferrin, Jr., Narender Pal Luthra
  • Patent number: 5723061
    Abstract: The present invention relates to an antifreeze composition containing a water-soluble liquid alcohol and a corrosion inhibitor system comprising (a) a mixture of at least two aromatic or aliphatic dicarboxylic acids, or of at least two salts of the said acids, (b) at least one 1,3-diazole chosen from imidazole, benzimidazole, imidazoline and hydrocarbon derivatives thereof, and (c) at least one triazole compound. The aqueous fluids containing the said composition have excellent anticorrosive properties and heat stability over long periods of time, in particular when the fluids are used as heat transfer fluids at temperatures above 150.degree. C.
    Type: Grant
    Filed: April 23, 1996
    Date of Patent: March 3, 1998
    Assignee: BP Chemicals Limited
    Inventors: Claude Ciardi, Valerie Rousselon
  • Patent number: 5718836
    Abstract: A liquid coolant composition with improved anti-corrosive property contains 85-99 weight % of an agent for lowering the melting point selected from the group consisting of alcohols and glycol, and 1-15 weight % of a rust preventive composition. The rust preventive composition contains 0.00005-0.02 weight % at elemental metal concentration of calcium compounds or a mixture of 0.00005-0.02 weight % each of calcium and magnesium compounds, and at least one kind of rust preventive selected from the group consisting of phosphates, borates, nitrates, molybdates, benzoates, silicates, triazoles, thiazoles, sebacic acid and octylic acid. Still better results are obtained if 0.001-0.02 weight % of at least one kind of polyphosphoric or polycarboxylic acids is additionally contained.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: February 17, 1998
    Assignee: Japan Chemical Industries Co., Ltd.
    Inventors: Yoshitaka Nakatani, Masamine Tanikawa, Hisaki Ito, Hideyuki Tami, Kazuhito Yaeda
  • Patent number: 5711894
    Abstract: An additive to be added to coolant or antifreeze concentrate is disclosed. The additive includes at least one ingredient selected from the group consisting of alkoxybenzoic acids and their amine salts, alkali metal salts and ammonium salts.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: January 27, 1998
    Assignee: CCI, Co., Ltd.
    Inventors: Yuji Miyake, Yasuaki Mori
  • Patent number: RE36479
    Abstract: A composition is disclosed which comprises water and at least one carboxylic salt dispersed or dissolved in said water, said salt being derived from:(A)(I) at least one derivative formed by reacting at least one C.sub.
    Type: Grant
    Filed: October 4, 1996
    Date of Patent: January 4, 2000
    Assignee: The Lubrizol Corporation
    Inventor: John Wesley Forsberg