Carboxylic Organic Compounds Containing Patents (Class 252/76)
  • Patent number: 4414125
    Abstract: A corrosion inhibited composition comprises an aqueous drilling, cutting, or polishing agent, an aqueous hydraulic fluid or an aqueous antifreeze compound; and an alkali metal salt, or an aliphatic amine salt of a mixture of 2- and 3-C.sub.6-12 -alkyladipic acids, the amount of this acid component being effective as a corrosion inhibitor.
    Type: Grant
    Filed: December 1, 1980
    Date of Patent: November 8, 1983
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventors: Hans S. H. Keil, deceased, Helmut Alfs, Klaus Schulze
  • Patent number: 4411808
    Abstract: There are disclosed power shaft transmission fluids such as automatic transmission fluids containing a multifunctional anti-oxidant, anti-corrosion and friction modification additive being an oil soluble aliphatic succinate ester of alkoxylated mercaptan.
    Type: Grant
    Filed: August 4, 1982
    Date of Patent: October 25, 1983
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Stanley J. Brois, Jack Ryer, Harold E. Deen
  • Patent number: 4402847
    Abstract: Compositions and method of using said compositions for inhibiting mineral scale and the corrosion of high lead solder and the cavitation-erosion corrosion of aluminum in aqueous systems are disclosed. Unexpectedly, a mixture of a siloxane-silicate copolymer with an azole is effective in reducing the corrosion of high lead solder and aluminum, particularly the cavitation-erosion corrosion of aluminum in contact with aqueous liquids, such as aqueous alcohol solutions used as heat transfer media. Antifreeze concentrates and a process for inhibiting corrosion are also disclosed.
    Type: Grant
    Filed: May 19, 1982
    Date of Patent: September 6, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Stanley T. Hirozawa
  • Patent number: 4391722
    Abstract: In accordance with the instant invention, a water-based hydraulic fluid, having improved low foaming properties can be obtained by blending 2-ethylhexanol with a conventional water-based hydraulic fluid composition.
    Type: Grant
    Filed: April 13, 1981
    Date of Patent: July 5, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Ellen S. Schwartz, Cline A. Tincher, Jerrold F. Maxwell
  • Patent number: 4390440
    Abstract: In accordance with the instant invention, a water-based hydraulic fluid, having improved viscosity can be obtained by blending a carboxylic acid with a thickened hydraulic fluid composition employing a thickener obtained by modifying a conventional polyether polyol thickening agent with an alpha-olefin epoxide or glycidyl ether having about 10 to 24 carbon atoms or mixtures thereof. Small amounts of higher molecular weight glycols may also be incorporated into the chain.
    Type: Grant
    Filed: June 8, 1981
    Date of Patent: June 28, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Ellen S. Schwartz, Cline A. Tichner
  • Patent number: 4390439
    Abstract: In accordance with the instant invention, a water-based hydraulic fluid, having improved anti-wear and corrosion inhibition properties can be obtained by blending neodecanoic acid with a conventional water-based hydraulic fluid composition.
    Type: Grant
    Filed: March 30, 1981
    Date of Patent: June 28, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Ellen S. Schwartz, Cline A. Tincher
  • Patent number: 4389371
    Abstract: Corrosion inhibited alcohol compositions can be prepared which are suitable for use as anti-freeze compositions in the cooling systems of internal combustion engines. The alcohol is selected from at least one of the group consisting of methanol, ethanol, propanol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol and glycerol. The corrosion inhibitor comprises an effective amount of a conventional corrosion inhibitor selected from the group consisting of the alkali metal carbonates, borax, the alkali metal dichromates, the alkali metal silicates, phosphorous acid, phosphoric acid, an alkali metal tungstate, benzotriazole, tolyltriazole, an alkali metal salt of benzoic or toluic acid, an alkali metal salt of a phenol, an alkanolamine and an organo-silicone compound in addition to an alkanolamine phosphate and a heterocyclic nitrogen-containing compound. The phosphate is the reaction product of an alkanolamine and phosphoric acid.
    Type: Grant
    Filed: July 8, 1981
    Date of Patent: June 21, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Stephen E. Eisenstein, Jerrold F. Maxwell, Stanley T. Hirozawa
  • Patent number: 4382008
    Abstract: Corrosion inhibitors for aqueous media comprise a triazole, an alkali metal borate, benzoate, and silicate and an alkali metal salt of a C.sub.7 to C.sub.13 dibasic acid. They may be used in antifreeze compositions for motor vehicles. Since neither nitrites and amines are required the danger of forming toxic nitrosamines by the reaction of these materials is overcome.
    Type: Grant
    Filed: February 20, 1981
    Date of Patent: May 3, 1983
    Assignee: Imperial Chemical Industries Limited
    Inventors: William Boreland, John M. Dossor, Geoffrey S. Jaques
  • Patent number: 4371448
    Abstract: A hydraulic fluid which substantially fulfils the specification DOT 5 is described. This hydraulic fluid essentially consists of (A) about 20 to 40% by weight of at least one boric acid ester obtained from orthoboric acid, diethylene glycol and an ethylene glycol monoalkyl ether; (B) 30 to 60% by weight of at least one ethylene glycol monoalkyl ether; (C) 10 to 40% by weight of at least one bis-(ethylene glycol monoalkyl ether)-formal; (D) 0.1 to 5% by weight of at least one alkylamine; and (E) 0.05 to 5% by weight of at least one stabilizer and/or inhibitor; the percentages by weight in each case being relative to the total weight of the fluid.
    Type: Grant
    Filed: November 5, 1980
    Date of Patent: February 1, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Knoblauch, Konrad von Werner
  • Patent number: 4366076
    Abstract: Corrosion-inhibited compositions are described comprising a functional fluid in contact with a ferrous metal and, as corrosion inhibitor, a compound having the formula: ##STR1## wherein X is H, an alkali- or alkaline earth metal, NH.sub.4, the residue of a protonated amine, or the group --OX is the residue of an alkanol having from 1 to 20 carbon atoms or of di-, tri- or tetra-ol having from 2 to 12 carbon atoms; R.sup.1, R.sup.2 and R.sup.4 are the same or different and each is H or --CH.sub.2 CH.sub.2 COOX wherein X has its previous meaning; R.sup.3 and R.sup.5 are the same or different and each is H, --CH.sub.2 CH.sub.2 COOX wherein X has its previous meaning, or R.sup.3 or R.sup.5 is a straight- or branched chain alkyl group having from 3 to 16 carbon atoms; or R.sup.3 and R.sup.5, together with the carbon atom to which they are each attached, may form a cycloalkanone ring containing from 5 to 15 carbon atoms.
    Type: Grant
    Filed: May 28, 1981
    Date of Patent: December 28, 1982
    Assignee: Ciba-Geigy Corporation
    Inventor: David R. Clark
  • Patent number: 4360443
    Abstract: A static storage stable fire resistant hydraulic fluid composition is provided which comprises(a) from about 40 to about 50 volume percent water together with(b) from about 50 to about 60 volume percent of a combination of(1) a lubricating oil(2) an emulsifier system containing succinic esters of hydrocarbon substituted succinic acid, polyhydric alcohols and alkaline earth salts of a fatty acid, and(3) at least one material selected from the group consisting of polyoxyethylene derivatives of alcohols and acids.Most preferred materials are the ether derivatives of polyoxyethylene containing from 10 to 20 oxyethylene units formed from 10 to 20 saturated carbon atom normal alcohols. The most preferred material is the ether derivative of a polyoxyethylene containing 10 oxyethylene units formed from stearyl alcohol.
    Type: Grant
    Filed: May 11, 1981
    Date of Patent: November 23, 1982
    Assignee: Conoco Inc.
    Inventor: Albert M. Durr, Jr.
  • Patent number: 4354949
    Abstract: Hydraulic fluids consisting of oil in water emulsion comprising 90-99%w of water, non-ionic emulsifier and 0.5-5%w of a high viscosity lubricating oil having a kinematic viscosity of 40.degree. C. of at least 160 cS.
    Type: Grant
    Filed: January 21, 1981
    Date of Patent: October 19, 1982
    Assignee: Shell Oil Company
    Inventors: Carl A. Eggers, Gerald D. Galvin
  • Patent number: 4352742
    Abstract: Hydroxy-substituted aliphatic silicone sulfonate-silicate copolymers are useful metal corrosion inhibitors for metals that come in contact with aqueous liquids. Antifreeze concentrates and a process for inhibiting the corrosion of metals below sodium in the electromotive series which come in contact with aqueous liquids are disclosed.
    Type: Grant
    Filed: April 1, 1981
    Date of Patent: October 5, 1982
    Assignee: BASF Wyandotte Corporation
    Inventors: Pauls Davis, Joe C. Wilson
  • Patent number: 4338209
    Abstract: Metal corrosion inhibitor comprising (a) benzoic acid and/or a benzoate, (b) nitrous acid and/or a nitrite, (c) phosphoric acid and/or a phosphate, and (d) at least one selected from mercaptobenzothiazole, its salts, benzotriazole and tolyltriazole, which can exhibit excellent anti-corrosive property to various metals for a long term and can be diluted with an aqueous liquor and can be employed in combination with usual anti-freezing agents.
    Type: Grant
    Filed: March 31, 1980
    Date of Patent: July 6, 1982
    Assignee: Otsuka Chemical Co., Ltd.
    Inventors: Isao Manabe, Akiyoshi Inubushi
  • Patent number: 4333850
    Abstract: A filled insoluble polymer containing one or more corrosion inhibitors and a slightly water soluble polymer is utilized to automatically and continuously add a corrosion inhibitor to a coolant solution passing through a heat exchanger. The corrosion inhibitor is gradually leached from the filled polymer supplying inhibitor to the coolant to protect the metallic parts of the coolant system that are subject to corrosive conditions.
    Type: Grant
    Filed: June 15, 1979
    Date of Patent: June 8, 1982
    Assignee: Borg-Warner Corporation
    Inventor: Robert H. Krueger
  • Patent number: 4329243
    Abstract: A Cavitation-inhibiting, nonfreezing, cooling and/or heat-transfer liquid, comprising a glycol and a cavitation inhibiting effective amount of at least one phosphonic acid of the formulaH.sub.2 O.sub.3 P--R--PO.sub.3 H.sub.2whereinR is phenylene or C.sub.1--6 -alkylene each optionally substituted by hydroxy, amino or PO.sub.3 H.sub.2 groups, or of the formula ##STR1## wherein R.sub.1, R.sub.2, and R.sub.3 each independently is a C.sub.1--4 -alkylene group or such a group whose carbon atom chain contains one or more N atoms each of which is attached to one or two groups of the formulae R.sub.1 --PO.sub.3 H.sub.2, R.sub.2 --PO.sub.3 H.sub.2 or R.sub.3 --PO.sub.3 H.sub.2 as defined above.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: May 11, 1982
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventor: Klaus Diebel
  • Patent number: 4324675
    Abstract: Alkylene glycol-based coolants free of nitrites, amines, and phosphates are metal corrosion inhibited with at least one nucleus-substituted benzoic acid and at least one conventional corrosion inhibitor for metals.
    Type: Grant
    Filed: December 29, 1980
    Date of Patent: April 13, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Barthold, Gert Liebold
  • Patent number: 4324676
    Abstract: Aqueous glycol compositions containing conventional corrosion inhibitors are improved by the addition of a .beta.-dicarbonyl compounds having the formulaR.sub.1 -C(O)-C(R.sub.2)(R.sub.3)-C(O)-R.sup.4whereR.sub.1 and R.sub.4 are independently alkyl groups of 1-4 carbons, and alkoxy groups, of 1-4 carbons,R.sub.2 and R.sub.3 are hydrogen, hydroxyl, alkyl groups of 1-4 carbons, or acetyl groups, with the proviso that R.sub.1 and R.sub.2 can be joined to form a 5 or 6 membered ring when R.sub.3 is hydrogen and R.sub.4 is an alkyl group of 1-4 carbons,with the proviso that R.sub.1 and R.sub.4 can be joined to form a 5 membered ring when R.sub.2 is hydrogen and R.sub.3 is an alkyl group of 1-4 carbons, with the proviso that R.sub.1 and R.sub.4 can be joined to form the 1,2-phenylene group when R.sub.2 and R.sub.3 are hydrogen, andwith the proviso that R.sub.1 and R.sub.4 can be joined to form the 1,2 phenylene group when R.sub.2 is hydroxyl and R.sub.3 is the 2-hydroxy 1,3-dione-indanyl-2 group.
    Type: Grant
    Filed: January 21, 1980
    Date of Patent: April 13, 1982
    Assignee: The Dow Chemical Company
    Inventor: Herman S. Gilbert
  • Patent number: 4320025
    Abstract: A cavitation-inhibiting, nonfreezing, cooling and/or heat-transfer liquid comprises a glycol and a cavitation-inhibiting effective amount of at least one phosphonocarboxylic acid of the formula ##STR1## wherein R is H or C.sub.1-6 alkyl, the latter optionally substituted by carboxy,R.sub.1 is H or C.sub.1-3 alkyl, the latter optionally substituted by carboxy,X is C.sub.1-3 alkylene optionally substituted by COOH or PO.sub.3 H.sub.2 groups, andn is 0 or 1.
    Type: Grant
    Filed: October 20, 1980
    Date of Patent: March 16, 1982
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventor: Klaus Diebel
  • Patent number: 4312768
    Abstract: Water-based hydraulic fluids and metalworking lubricants are disclosed which are thickened with a polyether polyol having a molecular weight of about 1000 to about 75,000 modified with an alpha-olefin epoxide having about 12 to about 18 carbon atoms. Unexpectedly, synergistic thickening results from a combination of said polyether polyol with the components of a water-based hydraulic fluid or metalworking lubricant. The particularly effective components of the hydraulic fluid or metalworking lubricant are the phosphate ester and water-soluble amine corrosion inhibitor components. The hydraulic fluid and metalworking fluids of the invention also contain a water-soluble polyoxyethylated ester of an aliphatic acid and a monohydric or polyhydric aliphatic alcohol, either one or both said acid and said alcohol being polyoxyethylated, a sulfurized molybdenum or antimony compound and a metal deactivator as well as other adjuvants conventional in this art.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: January 26, 1982
    Assignee: BASF Wyandotte Corporation
    Inventors: Assadullah Nassry, Jerrold F. Maxwell, John W. Compton, Edward J. Panek, Pauls Davis
  • Patent number: 4287078
    Abstract: A material formed by the reaction of (1) a poly-2-hydroxyalkyl derivative of a polyol having at least five hydroxyl groups, with at least three, and preferably nearly all, of said hydroxyl groups being substituted with one or more 2-hydroxyalkyl groups and (2) a polyglycidyl ether of a polyol, preferably a di- or triglycidyl ether of a polyoxyalkylene diol or triol. These materials have surfactant and defoaming abilities, and are useful in hard surface cleaning, textile and paper applications, and as defoaming agents. The compounds are especially useful as defoaming agent for glycol based antifreeze mixtures, and such antifreeze mixtures are also provided.
    Type: Grant
    Filed: January 28, 1980
    Date of Patent: September 1, 1981
    Assignee: BASF Wyandotte Corporation
    Inventors: William K. Langdon, Lester G. Lundsted
  • Patent number: 4257902
    Abstract: Substantially oil-free aqueous industrial fluids comprise (A) up to as much as 99.9 percent by weight water, (B) at least one substantially water-insoluble functional additive stably dispersed in the water and (C) at least one substantially water-soluble liquid organic dispersing agent, said dispersing agent being capable of dispersing said functional additive in said fluid and are useful as liquids in a variety of industrial applications, such as hydraulic systems and metal shaping operations. Typically, these compositions also contain at least one water-soluble polymeric thickener and at least one corrosion inhibitor. Methods for preparing these fluids from concentrates are also disclosed.
    Type: Grant
    Filed: July 27, 1977
    Date of Patent: March 24, 1981
    Assignee: Singer & Hersch Industrial Development (Pty.) Ltd.
    Inventor: Haimi N. Singer
  • Patent number: 4241016
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising an alcohol, a corrosion inhibiting amount of a water-soluble organosiloxane-silicate copolymer corrosion inhibitor and an organic basic pH buffer capable of buffering pH in the range of about 9 to about 11 comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are used as coolants either undiluted or upon dilution with about 25 percent to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: October 9, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4241015
    Abstract: A single-phase antifreeze or coolant concentrate is disclosed comprising an alcohol, a silicone-silicate copolymer and an organic basic pH buffer and corrosion inhibitor comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used as coolants either undiluted or upon dilution with about 30 to about 90 percent by weight of water based upon the total weight of the coolant. The alcohol is preferably ethylene glycol. The coolant compositions are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: October 9, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4241011
    Abstract: This invention relates to single-phase antifreeze and coolant concentrates comprising an alcohol, a metal salt of a carboxysiloxane and an organic basic pH buffer and corrosion inhibitor comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used as coolants either undiluted or upon dilution with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers and are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: September 24, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4241014
    Abstract: A single-phase antifreeze or coolant concentrate is disclosed comprising a major proportion of at least one alcohol, at least one water-soluble silicate, and an organic basic pH buffer and corrosion inhibitor comprising at least one hydroxybenzoic acid. The concentrates can be used without dilution but are preferably used, upon dilution with water. The concentrates are generally diluted for use in with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The alcohol-based antifreeze and coolant compositions of the invention are effective in the protection against corrosion of all metals and alloys used in industrial processes and are especially effective when used to inhibit the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: October 9, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4241013
    Abstract: A single-phase antifreeze or coolant concentrate is disclosed comprising an alcohol, an aminosilicone-silicate copolymer and an organic basic buffer and corrosion inhibitor comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used as coolants either undiluted or upon dilution with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers and are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: October 9, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4241012
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising (1) an alcohol, (2) at least one of an amino siloxane, an amino silane or both an amino siloxane and an amino silane and a siloxane of the formula: ##EQU1## wherein R.sup.6 is a monovalent hydrocarbon group and e has a value of from 1 to 3, and (3) a hydroxybenzoic acid basic pH buffer preferably comprising para or ortho hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used, upon dilution with about 30 to about 90 percent by weight of water based upon the weight of said concentrate, as antifreeze compositions for internal combustion engines. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers and are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: September 24, 1979
    Date of Patent: December 23, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4234440
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising an alcohol, a silicone-silicate copolymer and an organic basic pH buffer and corrosion inhibitor comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used as coolants either undiluted or upon dilution with about 30 to about 90 percent by weight of water based upon the total weight of the coolant. The alcohol is preferably ethylene glycol. The coolant compositions are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: January 2, 1979
    Date of Patent: November 18, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4225447
    Abstract: An emulsifiable concentrate for use in water-in-oil fire-resistant hydraulic fluids, comprises lubricant and a polyalkenylsuccinic acid or anhydride or a salt thereof.
    Type: Grant
    Filed: January 8, 1979
    Date of Patent: September 30, 1980
    Assignee: Mobil Oil Corporation
    Inventors: Derek A. Law, Robert H. Davis, Harry J. Andress
  • Patent number: 4219433
    Abstract: Metal corrosion inhibitor comprising (a) benzoic acid and/or a benzoate, (b) a trialkanolamine, (c) phosphoric acid and/or a phosphate, and (d) at least one selected from mercaptobenzothiazole, its salts, benzotriazole and tolyltriazole, which can exhibit excellent anti-corrosive property to various metals for a long term and can be diluted with an aqueous liquor and can be employed in combination with usual anti-freezing agents.
    Type: Grant
    Filed: September 19, 1978
    Date of Patent: August 26, 1980
    Assignee: Otsuka Chemical Co., Ltd.
    Inventors: Isao Manabe, Akiyoshi Inubushi
  • Patent number: 4210548
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising an alcohol, a corrosion inhibiting amount of a water-soluble organosiloxane-silicate copolymer corrosion inhibitor and an organic basic pH buffer capable of buffering pH in the range of about 9 to about 11 comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are used as coolants either undiluted or upon dilution with about 25 percent to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: January 2, 1979
    Date of Patent: July 1, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4210547
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising an alcohol, an aminosilicone-silicate copolymer and an organic basic buffer and corrosion inhibitor comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used as coolants either undiluted or upon dilution with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers and are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: January 2, 1979
    Date of Patent: July 1, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4210549
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising a major proportion of at least one alcohol, at least one water-soluble silicate, and an organic basic pH buffer and corrosion inhibitor comprising at least one hydroxybenzoic acid. The concentrates can be used without dilution but are preferably used, upon dilution with water. The concentrates are generally diluted for use in with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The alcohol-based antifreeze and coolant compositions of the invention are effective in the protection against corrosion of all metals and alloys used in industrial processes and are especially effective when used to inhibit the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: January 2, 1979
    Date of Patent: July 1, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4209416
    Abstract: This invention relates to single-phase antifreeze or coolant concentrates comprising (1) an alcohol, (2) at least one of an amino siloxane, an amino silane or both an amino siloxane and an amino silane and a siloxane of the formula: ##EQU1## wherein R.sup.6 is a monovalent hydrocarbon group and e has a value of from 1 to 3, and (3) a hydroxybenzoic acid basic pH buffer preferably comprising para or ortho hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used, upon dilution with about 30 to about 90 percent by weight of water based upon the weight of said concentrate, as antifreeze compositions for internal combustion engines. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers and are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: January 2, 1979
    Date of Patent: June 24, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4209415
    Abstract: This invention relates to single-phase antifreeze and coolant concentrates comprising an alcohol, a metal salt of a carboxysiloxane and an organic basic PH buffer and corrosion inhibitor comprising a hydroxybenzoic acid or mixtures thereof. The concentrates are preferably used as coolants either undiluted or upon dilution with about 25 to about 90 percent by weight of water based upon the total weight of the concentrate. The alcohol is preferably ethylene glycol. The coolant compositions are effective in providing protection against corrosion of all metals and alloys used in industrial heat exchangers and are especially effective in inhibiting the corrosion of aluminum internal combustion engine and radiator components.
    Type: Grant
    Filed: January 2, 1979
    Date of Patent: June 24, 1980
    Assignee: BASF Wyandotte Corporation
    Inventors: Stanley T. Hirozawa, Edward F. O'Brien, Joe C. Wilson
  • Patent number: 4151099
    Abstract: The present invention relates to the use, as a hydraulic fluid or metalworking lubricant, of compositions having water as a base and yet possessing superior lubricating and wear preventing characteristics. The fluids of the invention comprise (1) a water-soluble polyoxyethylated ester of an aliphatic acid and a monohydric or polyhydric aliphatic alcohol, either one or both said acid and said alcohol being polyoxyethylated (2) a sulfurized molybdenum or antimony compound or alternatively mixtures of (1) and (2) with (3) a phosphate ester. The compositions can be thickened, if desired, using for instance polyglycol, polyacrylic and polyvinyl alcohol type thickeners. The use of corrosion inhibitors, metal deactivators and other adjuvants conventional in this art is also contemplated.
    Type: Grant
    Filed: January 3, 1977
    Date of Patent: April 24, 1979
    Assignee: BASF Wyandotte Corporation
    Inventors: Assadullah Nassry, Jerrold F. Maxwell
  • Patent number: 4101429
    Abstract: Lubricating oil compositions are provided which comprise: (A) a major amount of oil of lubricating viscosity, and (B) an effective amount dissolved therein of each of (1) a zinc primary dihydrocarbyl dithiophosphate; (2) a mixture of (a) certain dimeric acids and (b) the reaction product of a monocarboxylic acid, certain polyalkylene polyamines and an alkenyl succinic anhydride; and (3) a substantially neutral zinc salt of a dihydrocarbyl sulfonic acid. These lubricating oil compositions are useful as functional fluids in a variety of systems as coolants, hydraulic fluids, turbine oils, spindle oils and the like.
    Type: Grant
    Filed: July 21, 1977
    Date of Patent: July 18, 1978
    Assignee: Shell Oil Company
    Inventor: August H. Birke
  • Patent number: 4087290
    Abstract: Austenitized ferrous metal, such as carbon steel, is quenched by means of an aqueous solution of a salt of polyacrylic acid which develops an extremely stable and uniform water vapor envelope surrounding the steel. Rate of cooling is controlled by (1) the molecular weight of the salt, (2) concentration of the salt in the solution, (3) solution temperature, and (4) the degree of agitation of the quenchant solution. In the case of carbon steel, by proper selection of the above variables, the austenitic structure of the hot steel may be directly transformed into non-martensitic structures of improved ductility, machinability and cold working properties, such as fine striped pearlite, without the necessity of further heat treatments, such as tempering, following quenching.The quenching solution may also be used to quench parts formed of alloy steel to obtain a martensitic structure without unwanted cracking and distortion. Non-ferrous metals may also be quenched using the polyacrylate quenching solution.
    Type: Grant
    Filed: July 3, 1975
    Date of Patent: May 2, 1978
    Assignee: E. F. Houghton & Co.
    Inventors: Karl-Heinz Kopietz, Francis S. Munjat
  • Patent number: 4077894
    Abstract: A glycol-based antifreeze formulation containing as a defoaming agent, from 0.001% to about 1.0% by weight of a mixture containing a compound of the formula ##STR1## WHEREIN R is an alkyl, alkoxyalkyl, hydroxyalkyl, or dihydroxyalkyl group having from 1 to 6 carbon atoms, R.sup.1 is hydrogen, methyl or ethyl, R.sup.2 is an alkyl group having 1 to 8 carbon atoms, p is an integer from 1 to 20, and n is an integer from 1 to 14; and a compound of the formulaRO--(C.sub.6 H.sub.10 O.sub.5).sub.p --Hwherein R and p are as defined above.
    Type: Grant
    Filed: December 27, 1976
    Date of Patent: March 7, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: William Keith Langdon, Daniel Ronan Dutton
  • Patent number: 4077895
    Abstract: A glycol-based antifreeze formulation containing as a defoaming agent, from 0.001% to about 1.
    Type: Grant
    Filed: January 3, 1977
    Date of Patent: March 7, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: William Keith Langdon, Daniel Ronan Dutton
  • Patent number: 4033892
    Abstract: A fluid composition which is capable of exhibiting a substantial increase in apparent viscosity under the influence of an electric field and which is of the type wherein solid particles of a chemical substance are dispersed in an electrically non-conducting oleaginous vehicle, the chemical substance being a polyhydric alcohol which contains acid groups and which has an open structure wherein a significant amount of water is adsorbed.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: July 5, 1977
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
    Inventor: James Edward Stangroom
  • Patent number: 4026812
    Abstract: Additives made by reaction of (A) at least one phosphorus acid compound of the formula: ##STR1## wherein each X is independently oxygen or divalent sulfur, M is hydrogen or an equivalent of metal or ammonium cation, R is a hydrogen atom or a hydrocarbyl or hydrocarbyloxy or hydrocarbyl mercapto group of about one to about thirty carbon atoms and R' is XM or R with the proviso that the total number of carbon atoms in both R and R' is at least two, with (B) at least one sulfo-containing compound of the formulae: ##STR2## wherein y is one or two, R.sup.3 is hydrogen or lower alkyl group, R.sup.2 is a divalent or trivalent hydrocarbyl group, R.sup.4 is a trivalent hydrocarbyl group, and Q is --OH, --OR.sup.3, --OM, an alkylene polyamine residue, or N(R.sub.3).sub.2, are novel and useful and have utility as, for example, additives for water-containing hydraulic fluids.
    Type: Grant
    Filed: November 24, 1975
    Date of Patent: May 31, 1977
    Assignee: The Lubrizol Corporation
    Inventor: William Monroe LeSuer
  • Patent number: 3981813
    Abstract: A hydraulic fluid comprising a major proportion of a hydrocarbon oil having a viscosity of about 10-200 centistokes at 100.degree.F. and a minor proportion of a metal sulfonate, a higher molecular weight alkyl- or alkenyl-succinic acid or anhydride, a lower molecular weight alkyl- or alkenyl-succinic acid or anhydride, a nonionic emulsifier, and a hindered hydrocarbyl phenol.
    Type: Grant
    Filed: May 12, 1975
    Date of Patent: September 21, 1976
    Assignee: Standard Oil Company (Indiana)
    Inventors: Marvin J. Den Herder, Thomas Martin Warne
  • Patent number: 3974081
    Abstract: A fluid having a mineral lubricating oil base and containing an oil soluble, saturated aliphatic or aromatic hydrocarbon ester having from 10 to 60 carbon atoms which, if desired, can be used in combination with an aliphatic alcohol of from 8 to 13 carbon atoms. The ester alone and ester-alcohol combination imparts to the fluid the property of swelling seals in automatic transmissions, power transmissions and rotary engines, and thereby improves retention of the fluid in these mechanical structures.
    Type: Grant
    Filed: July 31, 1974
    Date of Patent: August 10, 1976
    Assignee: Exxon Research and Engineering Company
    Inventors: Alfred J. Rutkowski, John P. Szykowski
  • Patent number: 3948792
    Abstract: A method and composition for reducing the amount of and softening silicate scale formation in automobile and diesel coolant systems where a silicate containing anti-corrosion formula is used which comprises adding to said formula an effective amount of a polymeric dispersant which is a water-soluble carboxylic acid polymer selected from a vinyl addition polymer and a carboxymethyl cellulose. The addition of polymeric dispersants to silicate containing corrosion inhibition formula such as the boron-nitrite type ameliorates or changes the character of the crystalline precipitate to a softer amorphous type and enables the utilization of anti-corrosion formulas at dosages of from about 2,000 up to 20,000 ppm without platingout side effects. Specially preferred dispersants are maleic anhydride copolymers and carboxymethyl cellulose. The advantages of the present invention may be realized in mixed precipitates containing silicate and also anions such as carbonate, phosphate, sulfate, etc.
    Type: Grant
    Filed: December 13, 1973
    Date of Patent: April 6, 1976
    Assignee: Nalco Chemical Company
    Inventors: Robert G. Watsen, Edwin S. Troscinski
  • Patent number: 3939088
    Abstract: A water-in-oil emulsion finding use as a stable functional fluid comprises about 19 to about 50 weight percent water, about 80 to about 49 weight percent mineral oil and a small amount of a hydrocarbyl-substituted succinic acid mono ester of a polyoxyethylene mono-ol. The mono-ol has an average molecular weight of about 200-1,000 and the hydrocarbyl substituent is from about 750 to about 2,000 average molecular weight.
    Type: Grant
    Filed: March 25, 1974
    Date of Patent: February 17, 1976
    Assignee: Chevron Research Company
    Inventors: Alfred Goldschmidt, Robert A. Stayner
  • Patent number: 3931029
    Abstract: A novel antifreeze composition is provided which comprises a water soluble liquid alcohol freezing point depressant and an inhibitor. The freezing point depressant is preferably at least one water soluble alcohol containing from one to four carbon atoms inclusive and from one to four hydroxy groups inclusive such as ethylene glycol. The inhibitor comprises at least one substance selected from the group consisting ofA. compounds corresponding to the following structural formula: ##SPC1##Wherein R.sub.1 is an alkylene radical containing from zero to 12 carbon atoms inclusive, R.sub.2 is an alkyl radical containing from one to 10 carbon atoms inclusive and R.sub.3 is an alkylene radical containing from one to 12 carbon atoms inclusive, andB. the mono- and di-metal salts, the mono- and di-ammonium salts, and the mono- and di-amides of compounds corresponding to the above structural formula.
    Type: Grant
    Filed: October 15, 1974
    Date of Patent: January 6, 1976
    Assignee: BASF Wyandotte Corporation
    Inventors: Daniel R. Dutton, John W. Compton