With Organic Material Patents (Class 252/79.4)
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Patent number: 12252844Abstract: Method of delignification of plant material, said method comprising: providing said plant material comprising cellulose fibres and lignin; exposing said plant material requiring to a composition comprising: an acid; a capping agent; and a peroxide; for a period of time sufficient to remove substantially all (at least 80%) of the lignin present on said plant material. Also disclosed are compositions to accomplish such delignification and processes using such.Type: GrantFiled: August 18, 2021Date of Patent: March 18, 2025Assignee: SIXRING INC.Inventors: Clay Purdy, Markus Weissenberger, Markus Pagels, Kyle G Wynnyk, Matthew Dewit, Andrew M Corbett
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Patent number: 12173216Abstract: Provided is an etchant composition for a semiconductor substrate which may selectively etch a high-concentration doped layer of an extrinsic semiconductor, and according to the present disclosure, an etchant composition for a semiconductor substrate which, in etching an extrinsic semiconductor substrate including doped layers having different doping concentrations, may etch the high-concentration doped layer at a high selection ratio, and suppress bubble formation during an etching process to allow uniform and stable etching, an etching method using the same, and a manufacturing method of a semiconductor substrate may be provided.Type: GrantFiled: April 22, 2022Date of Patent: December 24, 2024Assignee: ENF TECHNOLOGY CO., LTD.Inventors: Jeong Sik Oh, Hak Soo Kim, Myung Ho Lee
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Patent number: 12134723Abstract: Silicon etching compositions are described and may be used for selectively etching silicon with respect to a silicon insulating film. In particular, the silicon etching compositions can be used to improve the selective etching ratio of silicon from the surface of a semiconductor on which a silicone oxide film and silicon are exposed.Type: GrantFiled: May 5, 2022Date of Patent: November 5, 2024Assignee: ENF TECHNOLOGY CO., LTD.Inventors: Tae Ho Kim, Jeong Sik Oh, Gi Young Kim, Myung Ho Lee, Myung Geun Song
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Patent number: 12110421Abstract: Provided is a composition for semiconductor processing including abrasive particles and at least one additive. The composition may exhibit excellent polishing performance by being applied to a process of polishing a semiconductor wafer, may minimize defects in a polishing target surface, may achieve flat polishing without a difference in flatness between a plurality of different layers when used to polish the externally exposed surfaces of the layers, and may be applied to polishing of the surface of a semiconductor wafer having a through silicon via (TSV). Also provided is a method of fabricating a semiconductor device using the composition.Type: GrantFiled: January 6, 2022Date of Patent: October 8, 2024Assignee: SK ENPULSE CO., LTD.Inventors: Seung Chul Hong, Deok Su Han, Han Teo Park
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Patent number: 12091990Abstract: Sacrificial inserts for use in gas turbine engines to reduce friction and wear damage between compressor fan blades and the fan rotors are disclosed. The consumable metallic shims have low friction and reduce fretting and galling on fan blade roots and fan rotor dovetail slots thereby increasing their operating lives, as well as reduce engine noise and improve engine efficiency. The electroformed, compliant, multi-purpose shims may have variable thickness and, when positioned between the blade dovetail root and the rotor disk dovetail slot, prevent movement and slippage between air foil blades and the rotor.Type: GrantFiled: January 26, 2023Date of Patent: September 17, 2024Assignee: Integran Techi ologies Inc.Inventors: Jonathan McCrea, Gino Palumbo, Klaus Tomantschger, David Lionel Limoges
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Patent number: 11993851Abstract: An aqueous solution for surface treatment, for treating a surface of an alloy, the aqueous solution comprising: a copper compound at a copper ion concentration of 20000 ppm or more and 50000 ppm or less; a heterocyclic nitrogen compound at a concentration of 200 ppm or more and 3000 ppm or less; and a halide ion at a concentration of 2000 ppm or more and 70000 ppm or less.Type: GrantFiled: January 23, 2019Date of Patent: May 28, 2024Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Tomoko Fujii, Kazuhiko Ikeda, Shun Fukazawa
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Patent number: 11732215Abstract: A gellable vehicle surface cleaning composition is provided that includes a non-ionic surfactant combined with gelling components of an inorganic gel forming substance and at least one water soluble polymer in a ratio of the inorganic gel forming substance to the hydrophilic polymer of between 0.1-1:1. The non-ionic surfactant and the gelling components are provided in an aqueous solvent system. The aqueous solvent system includes a first solvent having a Kamlet-Taft solvent polarity ? (K-T ?) value of zero, a second solvent having a K-T ? 0.6-0.85 value, and water present at more than 50 total weight percent. A process of for cleaning a vehicle surface with a stain is also provided that includes the composition to the stain on the vehicle surface a composition and after allowing sufficient time for the composition to lift the stain, the stain and the composition are removed from the vehicle surface.Type: GrantFiled: August 25, 2021Date of Patent: August 22, 2023Assignee: ILLINOIS TOOL WORKS INC.Inventors: Chi Quang Nguyen, John Isidoro Escoto, Jr., John Nemec
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Patent number: 11697767Abstract: Compositions useful for the selective removal of silicon nitride materials relative to polysilicon, silicon oxide materials and/or silicide materials from a microelectronic device having same thereon are provided. The compositions of the invention are particularly useful in the etching of 3D NAND structures.Type: GrantFiled: June 7, 2021Date of Patent: July 11, 2023Assignee: ENTEGRIS, INC.Inventors: Steven Michael Bilodeau, SeongJin Hong, Hsing-Chen Wu, Min-Chieh Yang, Emanuel I. Cooper
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Patent number: 11634632Abstract: The disclosure is related to a composition for etching, a method for manufacturing the composition, and a method for fabricating a semiconductor using the same. The composition may include a first inorganic acid, at least one of silane inorganic acid salts produced by reaction between a second inorganic acid and a silane compound, and a solvent. The second inorganic acid may be at least one selected from the group consisting of a sulfuric acid, a fuming sulfuric acid, a nitric acid, a phosphoric acid, and a combination thereof.Type: GrantFiled: November 3, 2020Date of Patent: April 25, 2023Inventors: Jin Uk Lee, Jae Wan Park, Jung Hun Lim
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Patent number: 11529221Abstract: A predetermined bone site in a patient selected for restoration is exposed, contacted with an aqueous, methylene blue containing phosphoric acid solution for a time period of at least 3 minutes but no more than about 15 minutes, and thereafter cleansed ultrasonically to remove any bacteria that may be present. Preferred phosphoric acid concentration in the aqueous solution is about 37 percent by weight.Type: GrantFiled: April 24, 2020Date of Patent: December 20, 2022Inventor: Alena Butkevica
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Patent number: 11499071Abstract: The disclosure provides chemical mechanical polishing compositions and methods for polishing polysilicon films with high removal rates. The compositions include 1) an abrasive; 2) at least one compound of structure (I): 3) at least one compound of structure (II): and 4) water; in which the composition does not include tetramethylammonium hydroxide or a salt thereof. The variables n, R1-R7, X, Y, and Z1-Z3 in structures (I) and (II) are defined in the Specification. The synergistic effect of the compounds of structures (I) and (II) in these chemical mechanical polishing compositions leads to high polysilicon films material removal rate during polishing.Type: GrantFiled: March 27, 2020Date of Patent: November 15, 2022Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Alexei P. Leonov, Abhudaya Mishra
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Patent number: 11499099Abstract: This disclosure relates to etching compositions containing 1) at least one oxidizing agent; 2) at least one chelating agent; 3) at least one organic solvent; 4) at least one amine compound; and 5) water.Type: GrantFiled: September 2, 2020Date of Patent: November 15, 2022Assignee: Fujifilm Electronic Materials U.S.A., Inc.Inventors: Kazutaka Takahashi, Tomonori Takahashi, William A. Wojtczak
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Patent number: 11469011Abstract: A transparent electrode or a transparent heat trace is manufactured by transferring a silver nanowire formed on a glass substrate to a polymer and a flexible film. When the silver nanowire transferred to the polymer and the flexible film is processed with an iodine mixture, a surface of the silver nanowire is discolored.Type: GrantFiled: November 14, 2018Date of Patent: October 11, 2022Assignee: ITED Inc.Inventor: Jee-Hoon Seo
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Patent number: 11447660Abstract: A polishing composition for use in polishing an object to be polished, which comprises abrasive grains, a dispersing medium, and an additive, wherein the abrasive grains are surface-modified, the additive is represented by the following formula 1: wherein in the formula 1, X1 is O or NR4, X2 is a single bond or NR5, R1 to R5 are each independently a hydrogen atom; a hydroxy group; a nitro group; a nitroso group; a C1-4 alkyl group optionally substituted with a carboxyl group, an amino group, or a hydroxy group; or CONH2; with the proviso that R2 and R5 may form a ring; when X2 is a single bond, R3 is not a hydrogen atom, or R1 to R3 are not a methyl group; and when X2 is NR5 and three of R1 to R3 and R5 are a hydrogen atom, the other one is not a hydrogen atom or a methyl group; and a pH is 5.0 or less.Type: GrantFiled: November 19, 2020Date of Patent: September 20, 2022Assignee: FUJIMI INCORPORATEDInventors: Satoru Yarita, Yukinobu Yoshizaki
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Patent number: 11424368Abstract: A transistor having high field-effect mobility is provided. In order that an oxide semiconductor layer through which carriers flow is not in contact with a gate insulating film, a buried channel structure in which the oxide semiconductor layer through which carriers flow is separated from the gate insulating film is employed. Specifically, an oxide semiconductor layer having high conductivity is provided between two oxide semiconductor layers. Further, an impurity element is added to the oxide semiconductor layer in a self-aligned manner so that the resistance of a region in contact with an electrode layer is reduced. Further, the oxide semiconductor layer in contact with the gate insulating layer has a larger thickness than the oxide semiconductor layer having high conductivity.Type: GrantFiled: August 3, 2020Date of Patent: August 23, 2022Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 11401441Abstract: Provided are Chemical Mechanical Planarization (CMP) formulations that offer high and tunable Cu removal rates and low copper dishing for the broad or advanced node copper or Through Silica Via (TSV). The CMP compositions provide high selectivity of Cu film vs. other barrier layers, such as Ta, TaN, Ti, and TiN, and dielectric films, such as TEOS, low-k, and ultra low-k films. The CMP polishing formulations comprise solvent, abrasive, at least three chelators selected from the group consisting of amino acids, amino acid derivatives, organic amine, and combinations therefor; wherein at least one chelator is an amino acid or an amino acid derivative. Additionally, organic quaternary ammonium salt, corrosion inhibitor, oxidizer, pH adjustor and biocide are used in the formulations.Type: GrantFiled: August 13, 2018Date of Patent: August 2, 2022Assignee: VERSUM MATERIALS US, LLCInventors: Xiaobo Shi, Laura M. Matz, Chris Keh-Yeuan Li, Ming-Shih Tsai, Pao-Chia Pan, Chad Chang-Tse Hsieh, Rung-Je Yang, Blake J. Lew, Mark Leonard O'Neill, Agnes Derecskei
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Patent number: 11112696Abstract: A composition for forming protective films against aqueous hydrogen peroxide solutions, including: a compound of the following formula (1a) or formula (1b) or a compound having a substituent of the following formula (2) and having a molecular weight of 300 or more and less than 800 or a weight-average molecular weight of 300 or more and less than 800; and a solvent, the composition containing the compound of the formula (1a) or formula (1b) of 0.1% by mass to 60% by mass or the compound having the substituent of the formula (2) of 10% by mass to 100% by mass, relative to solids excluding the solvent: (wherein R1 is a C1-4 alkylene or alkenylene group or a direct bond, k is 0 or 1, m is an integer of 1 to 3, and n is an integer of 2 to 4.Type: GrantFiled: September 15, 2017Date of Patent: September 7, 2021Assignee: NISSAN CHEMICAL CORPORATIONInventors: Yuto Hashimoto, Hikaru Tokunaga, Hiroto Ogata, Tomoya Ohashi, Yasushi Sakaida, Takahiro Kishioka
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Patent number: 10920142Abstract: Provided are a polysiloxane-based compound, a selective etching composition with respect to a silicon nitride layer including the polysiloxane-based compound, and a method of manufacturing a semiconductor device including the etching composition. The silicon nitride layer etching composition including the polysiloxane-based compound may selectively etch the silicon nitride layer relative to a silicon oxide layer, and have a significantly excellent etch selectivity ratio, and a small change in etch rate and a small change in etch selectivity ratio with respect to the silicon nitride layer even when time for using the composition increases or the composition is repeatedly used.Type: GrantFiled: June 7, 2019Date of Patent: February 16, 2021Assignee: ENF TECHNOLOGY CO., LTD.Inventors: Dong Hyun Kim, Hyeon Woo Park, Du Won Lee, Jang Woo Cho, Myung Ho Lee
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Patent number: 10781371Abstract: An etchant composition includes phosphoric acid and a silane compound represented by the following Chemical Formula 1: wherein A is an n-valent radical, L is C1-C5 hydrocarbylene, R1 to R3 are independently hydrogen, hydroxy, hydrocarbyl, or alkoxy, in which R1 to R3 exist respectively or are connected to each other by a heteroelement, and n is an integer of 2 to 5.Type: GrantFiled: May 24, 2019Date of Patent: September 22, 2020Assignees: SK Innovation Co., Ltd., SK-Materials Co., Ltd.Inventors: Cheol Woo Kim, Je Ho Lee, Jin Su Ham, Jae Hoon Kwak, Jong Ho Lee
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Patent number: 10741695Abstract: A transistor having high field-effect mobility is provided. In order that an oxide semiconductor layer through which carriers flow is not in contact with a gate insulating film, a buried channel structure in which the oxide semiconductor layer through which carriers flow is separated from the gate insulating film is employed. Specifically, an oxide semiconductor layer having high conductivity is provided between two oxide semiconductor layers. Further, an impurity element is added to the oxide semiconductor layer in a self-aligned manner so that the resistance of a region in contact with an electrode layer is reduced. Further, the oxide semiconductor layer in contact with the gate insulating layer has a larger thickness than the oxide semiconductor layer having high conductivity.Type: GrantFiled: November 14, 2019Date of Patent: August 11, 2020Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventor: Shunpei Yamazaki
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Patent number: 10665500Abstract: Aspects of the disclosure provide a method for manufacturing a semiconductor device. A first structure of first stacked insulating layers including a first via over a contact region is formed. A second structure is formed by filling at least a top region of the first via with a sacrificial layer. A third structure including the second structure and second stacked insulating layers stacked above the second structure is formed. The third structure further includes a second via aligned with the first via and extending through the second stacked insulating layers. A fourth structure is formed by removing the sacrificial layer to form an extended via including the first via and the second via. A plurality of weights associated with the first structure, the second structure, the third structure, and the fourth structure is determined, and a quality of the extended via is determined based on the plurality of weights.Type: GrantFiled: March 13, 2019Date of Patent: May 26, 2020Assignee: Yangtze Memory Technologies Co., Ltd.Inventors: Sha Sha Liu, EnBo Wang, Feng Lu, Li Hong Xiao, Haohao Yang, Zhaosong Li
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Patent number: 10125316Abstract: An etching solution and a manufacturing method of a display are provided. The etching solution includes hydrogen peroxide (H2O2), succinic acid, malonic acid, acetic acid, sulfuric acid, 1-amino-2-propanol, 5-amino-1H-tetrazole, N,N,N?N?-tetrakis(2-hydroxypropyl) ethylenediamine (EDTP) and glycine homogenously mixed in deionized water. Hydrogen peroxide is in an amount of 5-10 wt % of the etching solution, succinic acid is in an amount of 0.5-10 wt % of the etching solution, malonic acid is in an amount of 0.5-10 wt % of the etching solution, acetic acid is in an amount of 1-10 wt % of the etching solution, sulfuric acid is in an amount of 0.5-5 wt % of the etching solution, 1-amino-2-propanol is in an amount of 1-20 wt % of the etching solution, 5-amino-1H-tetrazole is in an amount of 0.01-0.5 wt % of the etching solution, EDTP is in an amount of 1-15 wt % of the etching solution, and glycine is in an amount of 1-5 wt % of the etching solution.Type: GrantFiled: November 15, 2017Date of Patent: November 13, 2018Assignee: INNOLUX CORPORATIONInventors: Po-Yun Hsu, Chi-Che Tsai, Ker-Yih Kao
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Patent number: 10096486Abstract: In one embodiment, a substrate processing liquid contains phosphoric acid as a primary component and contains water and ketone. In another embodiment, a substrate processing method includes processing a substrate in a substrate processing bath with a substrate processing liquid containing phosphoric acid, water and ketone. The method further includes discharging the substrate processing liquid from the substrate processing bath to a circulating flow channel, heating the substrate processing liquid flowing through the circulating flow channel at a temperature between 50° C. and 90° C., and supplying the substrate processing liquid again from the circulating flow channel to the substrate processing bath to circulate the substrate processing liquid under heating.Type: GrantFiled: September 14, 2016Date of Patent: October 9, 2018Assignee: TOSHIBA MEMORY CORPORATIONInventors: Shinsuke Muraki, Katsuhiro Sato, Hiroaki Yamada
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Patent number: 9875904Abstract: The present invention is able to provide: a silicon etching liquid which anisotropically dissolves single crystal silicon, and which is characterized by containing (1) potassium hydroxide or sodium hydroxide, (2) a hydroxyl amine and (3) a cyclic compound represented by general formula (I), which has a thiourea group and wherein N and N? are linked; and a silicon etching method which uses this silicon etching liquid. (In general formula (I), Q represents an organic group having a saturated or unsaturated carbon-carbon bond.) By using the above-described silicon etching liquid, high etching rate can be achieved without lowering the etching rate of silicon and stability of the etching liquid is not impaired even in cases where copper is present in the etching liquid and/or where copper ions are dissolved in the etching liquid.Type: GrantFiled: January 10, 2014Date of Patent: January 23, 2018Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventor: Yoshiko Fujioto
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Patent number: 9679814Abstract: Embodiments of the invention generally relate to epitaxial lift off (ELO) thin films and devices and methods used to form such films and devices. In one embodiment, a method for forming an ELO thin film is provided which includes depositing an epitaxial material over a sacrificial layer on a substrate, adhering a flattened, pre-curved support handle onto the epitaxial material, and removing the sacrificial layer during an etching process. The etching process includes bending the pre-curved support handle to have substantial curvature while peeling the epitaxial material from the substrate and forming an etch crevice therebetween. Compression is maintained within the epitaxial material during the etching process. The flattened, pre-curved support handle may be formed by flattening a pre-curved support material.Type: GrantFiled: May 27, 2015Date of Patent: June 13, 2017Assignee: ALTA DEVICES, INC.Inventors: Melissa Archer, Harry Atwater, Thomas Gmitter, Gang He, Andreas Hegedus, Gregg Higashi, Stewart Sonnenfeldt
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Patent number: 9276128Abstract: A method for manufacturing a semiconductor device includes the steps of forming a first conductive film over a substrate; forming an insulating film over the first conductive film; forming an oxide semiconductor film over the insulating film to overlap with the first conductive film; forming a second conductive film including a metal film containing molybdenum as its main component and a metal film containing copper as its main component over the oxide semiconductor film; and etching the second conductive film by an etchant. At the time of etching the second conductive film by the etchant, the oxide semiconductor film is used as an etching stopper film. In addition, the etchant which can be used for a transistor including the oxide semiconductor film is provided.Type: GrantFiled: October 20, 2014Date of Patent: March 1, 2016Assignee: Semiconductor Energy Laboratory Co., Ltd.Inventors: Yasutaka Nakazawa, Shunsuke Koshioka, Takayuki Cho, Takahiro Sato
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Patent number: 9263296Abstract: A chemical-mechanical polishing (“CMP”) composition (P) comprising (A) inorganic particles, organic particles, or a mixture or composite thereof, (B) at least one type of A/-heterocyclic compound as corrosion inhibitor, (C) at least one type of a further corrosion inhibitor selected from the group consisting of: (C1) an acetylene alcohol, and (C2) a salt or an adduct of (C2a) an amine, and (C2b) a carboxylic acid comprising an amide moiety, (D) at least one type of an oxidizing agent, (E) at least one type of a complexing agent, and (F) an aqueous medium.Type: GrantFiled: March 19, 2012Date of Patent: February 16, 2016Assignee: BASF SEInventors: Bastian Noller, Michael Lauter, Albert Budiman Sugiharto, Yuzhuo Li, Kenneth Rushing, Diana Franz, Roland Böhn
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Patent number: 9048195Abstract: Provided is a polishing fluid that has a fast polishing rate, and can selectively suppress polishing of layers including polysilicon or modified polysilicon during the chemical mechanical polishing in the manufacture of semiconductor integrated circuits, and a polishing method using the same. A polishing fluid used for the chemical mechanical polishing in which each of the components represented by the following (1) and (2) is included, the pH is 1.5 to 5.0, and a polishing workpiece can be polished in a range of a ratio represented by RR (other)/RR (p-Si) when the polishing rate of the first layer is RR (p-Si), and the polishing rate of the second layer is RR (other) of 1.5 to 200. (1) Colloidal silica particles (2) At least one inorganic phosphate compound selected from phosphoric acid, pyrophosphoric acid, and polyphosphoric acid.Type: GrantFiled: July 28, 2011Date of Patent: June 2, 2015Assignee: FUJIFILM CorporationInventor: Tetsuya Kamimura
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Publication number: 20150144591Abstract: The present invention can provide an etching composition for a chemical copper plating for the production of a printed-wiring board according to a semi-additive process, which comprises 0.2 to 5% by mass of hydrogen peroxide, 0.5 to 10% by mass of sulfuric acid, 0.001 to 0.3% by mass of phenylurea, 0.1 to 3 mass ppm of halogen ion and 0.003 to 0.3% by mass of tetrazoles, and wherein the ratio of the dissolution rate of the chemical copper plating (Y) to the dissolution rate of an electrolytic copper plating (X) at a liquid temperature of 30° C. (Y/X) is 4 to 7.Type: ApplicationFiled: November 17, 2014Publication date: May 28, 2015Applicant: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Kenichi TAKAHASHI, Norifumi TASHIRO
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Patent number: 9028708Abstract: An aqueous chemical mechanical polishing (CMP) agent (A) comprising solid particles (a1) containing (a11) a corrosion inhibitor for metals, and (a12) a solid material, the said solid particles (a1) being finely dispersed in the aqueous phase; and its use in a process for removing a bulk material layer from the surface of a substrate and planarizing the exposed surface by chemical mechanical polishing until all material residuals are removed from the exposed surface, wherein the CMP agent exhibits at the end of the chemical mechanical polishing, without the addition of supplementary materials, —the same or essentially the same static etch rate (SER) as at its start and a lower material removal rate (MRR) than at its start, —a lower SER than at its start and the same or essentially the same MRR as at its start or—a lower SER and a lower MRR than at its start; such that the CMP agent exhibits a soft landing behavior.Type: GrantFiled: November 25, 2010Date of Patent: May 12, 2015Assignee: BASF SEInventors: Vijay Immanuel Raman, Yuzhuo Li, Mario Brands, Yongqing Lan, Kenneth Rushing, Karpagavalli Ramji
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Patent number: 9017571Abstract: A dry etching agent according to the present invention preferably contains: (A) 1,3,3,3-tetrafluoropropene; (B) at least one kind of additive gas selected from the group consisting of H2, O2, O3, CO, CO2, COCl2, COF2, CF3OF, NO2, F2, NF3, Cl2, Br2, I2, CH4, C2H2, C2H4, C2H6, C3H4, C3H6, C3H8, HF, HI, HBr, HCl, NO, NH3 and YFn (where Y represents Cl, Br or I; and n represents an integer satisfying 1?n?7); and (C) an inert gas. This dry etching agent has less effect on the global environment and can obtain a significant improvement in process window and address processing requirements such as low side etching ratio and high aspect ratio even without any special substrate excitation operation.Type: GrantFiled: June 24, 2011Date of Patent: April 28, 2015Assignee: Central Glass Company, LimitedInventors: Tomonori Umezaki, Yasuo Hibino, Isamu Mori, Satoru Okamoto, Akiou Kikuchi
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Publication number: 20150104941Abstract: A barrier chemical mechanical planarization polishing composition is provided that includes suitable chemical additives. The suitable chemical additives are organic polymer molecules containing ethylene oxide repeating units having the general molecular structure of where n refers to the total numbers of the repeating unit ranging from 6,818 to 181,817; and the molecular weights of polyethylene oxide ranging from 100,000 to 8,000,000. There is also provided a chemical mechanical polishing method using the barrier chemical mechanical planarization polishing composition.Type: ApplicationFiled: September 30, 2014Publication date: April 16, 2015Inventors: Maitland Gary Graham, JAMES ALLEN SCHLUETER, XIAOBO SHI
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Patent number: 9005472Abstract: An aqueous polishing agent, comprising, as the abrasive, at least one kind of polymer particles (A) finely dispersed in the aqueous phase and having at their surface a plurality of at least one kind of functional groups (a1) capable of interacting with the metals and/or the metal oxides on top of the surfaces to be polished and forming complexes with the said metals and metal cations, the said polymer particles (A) being preparable by the emulsion or suspension polymerization of at least one monomer containing at least one radically polymerizable double bond in the presence of at least one oligomer or polymer containing a plurality of functional groups (a1); graft copolymers preparable by the emulsion or suspension polymerization of at least one monomer containing at least one radically polymerizable double bond in the presence of at least one oligomeric or polymeric aminotriazine-polyamine condensate; and a process for the chemical and mechanical polishing of patterned and unstructured metal surfaces makingType: GrantFiled: January 19, 2011Date of Patent: April 14, 2015Assignee: BASF SEInventors: Vijay Immanuel Raman, Ilshat Gubaydullin, Mario Brands, Yuzhuo Li, Maxim Peretolchin
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Patent number: 9005473Abstract: A method of removing at least a portion of a silicon oxide material is disclosed. The silicon oxide is removed by exposing a semiconductor structure comprising a substrate and the silicon oxide to an ammonium fluoride chemical treatment and a subsequent plasma treatment, both of which may be effected in the same vacuum chamber of a processing apparatus. The ammonium fluoride chemical treatment converts the silicon oxide to a solid reaction product in a self-limiting reaction, the solid reaction product then being volatilized by the plasma treatment. The plasma treatment includes a plasma having an ion bombardment energy of less than or equal to approximately 20 eV. An ammonium fluoride chemical treatment including an alkylated ammonia derivative and hydrogen fluoride is also disclosed.Type: GrantFiled: August 9, 2012Date of Patent: April 14, 2015Assignee: Micron Technology, Inc.Inventors: Mark W. Kiehlbauch, J. Neil Greeley, Paul A. Morgan
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Patent number: 8999194Abstract: The present invention is to provide an etching solution capable of effectively reducing Galvanic effect, wherein the etching solution is obtained by way of dissolving an etchant and a nitrogen containing five-member heterocyclic compound in water. Thus, when at least one first metal (e.g., gold) and at least one second metal (e.g., copper) disposed on a substrate is treated with a wet etching process by using this etching solution, the nitrogen containing five-member heterocyclic compound would form an organic protecting film on the first metal having higher reduction potential, so as to effectively avoid the second metal from being over etched resulted from the Galvanic effect.Type: GrantFiled: February 24, 2014Date of Patent: April 7, 2015Assignee: E-Chem Enterprise Corp.Inventors: Cheng-Ying Tsai, Cheng-Kai Liao, Su-Fei Hsu
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Patent number: 8999193Abstract: Chemical-mechanical polishing (CMP) compositions containing chemical additives and methods of using the CMP compositions are disclosed. The CMP composition comprises abrasive; chemical additive; liquid carrier; optionally an oxidizing agent; a pH buffering agent and salt; a surfactant and a biocide. The CMP compositions and the methods provide enhanced removing rate for “SiC”, SiN” and “SiCxNy” films; and tunable removal selectivity for “SiC” in reference to SiO2, “SiN” in reference to SiO2, “SiC” in reference to “SiN”, or “SiCxNy” in reference to SiO2; wherein x ranges from 0.1 wt % to 55 wt %, y ranges from 0.1 wt % to 32 wt %.Type: GrantFiled: March 15, 2013Date of Patent: April 7, 2015Assignee: Air Products and Chemicals, Inc.Inventors: Xiaobo Shi, James Allen Schlueter, Maitland Gary Graham, Savka I. Stoeva, James Matthew Henry
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Patent number: 8999185Abstract: The present invention provides a process of etching or plating comprising the steps of: i) ink jet printing an alkali removeable water insoluble hot melt ink jet ink onto a substrate to form a resist image; ii) etching or plating the substrate in an aqueous acid medium; and iv) removing the resist image with an aqueous alkali.Type: GrantFiled: August 6, 2007Date of Patent: April 7, 2015Assignee: Sun Chemical CorporationInventor: Nigel Anthony Caiger
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Publication number: 20150083689Abstract: The invention provides a chemical-mechanical polishing composition and a method of chemically-mechanically polishing a substrate with the chemical-mechanical polishing composition. The polishing composition comprises (a) abrasive particles that comprise ceria, zirconia, silica, alumina, or a combination thereof, (b) a metal ion that is a Lewis Acid, (c) a ligand that is an aromatic carboxylic acid, an aromatic sulfonic acid, an aromatic acid amide, an amino acid, or a hydroxy-substituted N-heterocycle, and (d) an aqueous carrier, wherein the pH of the chemical-mechanical polishing composition is in the range of about 1 to about 4.Type: ApplicationFiled: September 24, 2013Publication date: March 26, 2015Inventors: Sudeep PALLIKKARA KUTTIATOOR, Renhe Jia, Jeffrey Dysard
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Publication number: 20150075850Abstract: The object of the present invention is to provide an etching solution composition for etching a metal oxide containing In and a metal oxide containing Zn and In used as a transparent electrode or an oxide semiconductor of an electronic device such as a semiconductor element or a flat panel display (FPD), the etching solution composition being controllable to give a practical etching rate, having high dissolving power toward Zn, and enabling a long solution life due to suppressed variation of the formulation during use. The object is solved by an etching solution composition that enables microfabrication to be carried out for a metal oxide containing In and a metal oxide containing Zn and In used as a transparent electrode or an oxide semiconductor of an electronic device such as a semiconductor element or an FPD, the composition containing water and at least one type of acid, excluding hydrohalic acids, perhalic acids, etc., having an acid dissociation constant pKan at 25° C.Type: ApplicationFiled: September 18, 2014Publication date: March 19, 2015Applicant: Kanto Kagaku Kabushiki KaishaInventors: Takuo Ohwada, Toshikazu Shimizu
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Publication number: 20150076396Abstract: Liquid compositions for etching glass are disclosed herein. The liquid composition may include a non-active etching agent precursor that is inactive with respect to chemically etching glass in an amount of at least 2.5% by weight of the total composition, a binder and a liquid vehicle. The precursor may include an alkali metal salt having an activation temperature of at least 400° C. and when heated to above the activation temperature, the precursor yields an active etching agent suitable for chemical etching of glass.Type: ApplicationFiled: November 25, 2014Publication date: March 19, 2015Inventors: Matti BEN-MOSHE, Michael KHEYFETS
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Publication number: 20150079786Abstract: A solution for processing devices is provided, comprising an activator comprising at least one of pyridine, pyrole, pyrrolidine, pyrimidine, N,N-dimethylformamide, tetraethylamine chloride, 4 pyridinethiol, or other organic compounds with a single N with a lone pair electron activator and an etchant comprising at least one of thionly chloride, Cl2, Br2, I2, SOF2, SOF4, SO2Cl2, SOBr2, S2O6F2, HSO3F, or C2Cl4O2.Type: ApplicationFiled: September 17, 2013Publication date: March 19, 2015Inventors: Samantha S.H. Tan, Alexander Kabansky, Joydeep Guha
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Patent number: 8980122Abstract: The invention relates to a contact release capsule comprising a particle, a chemical payload, and a polymer coating, wherein the particle is impregnated with the chemical payload, and the chemical payload is held inside the particle by the polymer coating until the contact release capsule contacts a surface and a shearing force removes the polymer coating allowing the chemical payload to release outside the particle. The contact release capsule is useful in chemical mechanical planarization slurries. Particularly, the contact release capsule may comprise a glycine impregnated silica nanoparticle coated with a polymer, wherein the contact release capsule is dispersed in an aqueous solution and used in the copper chemical mechanical planarization process. Use of the contact release capsule in a slurry for copper chemical mechanical planarization may significantly improve planarization efficiency, decrease unwanted etching and corrosion, and improve dispersion stability.Type: GrantFiled: July 5, 2012Date of Patent: March 17, 2015Assignee: General Engineering & Research, L.L.C.Inventor: Robin Ihnfeldt
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Patent number: 8974691Abstract: A polishing composition for a silicon wafer and a rinsing composition for a silicon wafer according to the present invention contain a nonionic surfactant of a polyoxyethylene adduct. The HLB value of the polyoxyethylene adduct is 8 to 15. The weight-average molecular weight of the polyoxyethylene adduct is 1400 or less. The average number of moles of oxyethylene added in the polyoxyethylene adduct is 13 or less. The content of the polyoxyethylene adduct in each of the polishing composition and the rinsing composition is 0.00001 to 0.1% by mass.Type: GrantFiled: September 20, 2011Date of Patent: March 10, 2015Assignee: Fujimi IncorporatedInventors: Kohsuke Tsuchiya, Shuhei Takahashi
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Patent number: 8974685Abstract: Provided is a fine-processing agent which, when fine-processing a laminated film stacked at least with a silicon dioxide film and a silicon nitride film, can selectively fine-process the silicon dioxide film. Also provided is a fine-processing method utilizing the fine-processing agent. The fine-processing agent is characterized by including: (a) 0.01-15.0 weight % hydrogen fluoride and/or 0.1-40.0 weight % ammonium fluoride, (b) water, and (c) 0.001-10.00 weight % water-soluble polymer selected from among a group consisting of acrylic acid, ammonium acrylate, acrylic acid ester, acrylamide, styrenesulfonic acid, ammonium styrenesulfonate, and styrenesulfonic acid ester.Type: GrantFiled: May 21, 2009Date of Patent: March 10, 2015Assignee: Stella Chemifa CorporationInventors: Masayuki Miyashita, Takanobu Kujime, Keiichi Nii
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Patent number: 8974692Abstract: Provided are novel chemical mechanical polishing (CMP) slurry compositions for polishing copper substrates and method of using the CMP compositions. The CMP slurry compositions deliver superior planarization with high and tunable removal rates and low defects when polishing bulk copper layers of the nanostructures of IC chips. The CMP slurry compositions also offer the high selectivity for polishing copper relative to the other materials (such as Ti, TiN, Ta, TaN, and Si), suitable for through-silicon via (TSV) CMP process which demands high copper film removal rates.Type: GrantFiled: June 27, 2013Date of Patent: March 10, 2015Assignee: Air Products and Chemicals, Inc.Inventors: Xiaobo Shi, Krishna Murella, James Allen Schlueter, Jae Ouk Choo
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Publication number: 20150053888Abstract: The etching liquid composition of the present invention contains a ferric ion component; a hydrogen chloride component; and a component that is at least one type of compound selected from the group consisting of a compound represented by general formula (1) below and a straight chain or branched chain alcohol having 1 to 4 carbon atoms: wherein R1 and R3 are each independently a hydrogen atom or a straight chain or branched chain alkyl group having 1 to 4 carbon atoms, R2 is a straight chain or branched chain alkylene group having 1 to 4 carbon atoms, and n is a number between 1 and 3.Type: ApplicationFiled: December 25, 2012Publication date: February 26, 2015Inventors: Yuta Taguchi, Kouta Saitoh
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Patent number: 8961807Abstract: Disclosed are a polishing composition and method of polishing a substrate. The composition has low-load (e.g., up to about 0.1 wt. %) of abrasive particles. The polishing composition also contains water and at least one anionic surfactant. In some embodiments, the abrasive particles are alpha alumina particles (e.g., coated with organic polymer). The polishing composition can be used, e.g., to polish a substrate of weak strength such as an organic polymer. An agent for oxidizing at least one of silicon and organic polymer is included in the composition in some embodiments.Type: GrantFiled: March 15, 2013Date of Patent: February 24, 2015Assignee: Cabot Microelectronics CorporationInventors: Lin Fu, Steven Grumbine
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Patent number: 8961814Abstract: Methods and formulations for the selective etching of etch stop layers deposited above metal-based semiconductor layers used in the manufacture of TFT-based display devices are presented. The formulations are based on an alkaline solution. Methods and formulations for the selective etching of molybdenum-based and/or copper-based source/drain electrode layers deposited above metal-based semiconductor layers used in the manufacture of TFT-based display devices are presented. The formulations are based on an alkaline solution.Type: GrantFiled: December 18, 2013Date of Patent: February 24, 2015Assignee: Intermolecular, Inc.Inventors: Jeroen Van Duren, Zhi-Wen Wen Sun
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Publication number: 20150044872Abstract: A method is disclosed for polishing a wafer with a slurry. In the method, the wafer comprises at least one of silicon carbonitride (SiCN) and silicon nitride (SiN), and further comprises one or both of silicon dioxide (SiO2) and poly silicon, and a removal rate of SiCN is greater than a removal rate of poly silicon, and the removal rate of poly silicon is greater than a removal rate of SiO2, and where the slurry comprises up to about 15 wt % of surface-modified colloidal silica particles which have a primary particle size of less than about 35 nm, and the surface-modified colloidal silica particles comprise a plurality of acid moieties or salts thereof.Type: ApplicationFiled: August 6, 2014Publication date: February 12, 2015Applicant: FUJIMI INCORPORATEDInventors: Fusayo SAEKI, Hooi-Sung KIM
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Patent number: 8951434Abstract: A glass etching medium and a method for etching the surface of a glass sheet to modify surface flaw characteristics without degrading the optical quality of the sheet surface, wherein the etching medium is a thickened aqueous acidic fluoride-containing paste comprising at least one dissolved, water-soluble, high-molecular-weight poly (ethylene oxide) polymer thickener.Type: GrantFiled: May 8, 2013Date of Patent: February 10, 2015Assignee: Corning IncorporatedInventors: Timothy Edward Myers, Shyamala Shanmugam, Alan Thomas Stephens, II, Matthew John Towner, Kevin William Uhlig, Lu Zhang