With Organic Material Patents (Class 252/79.4)
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Patent number: 7955522Abstract: An extraction aid has been found which provides for enhanced contaminate removal, such as metals and amines, from crude oils that uses components that are desirable in desalting processes as the components are water soluble, have low toxicity, are highly biodegradeable and exhibit high thermal stability. According to one embodiment of the invention, an extraction aid that provides enhanced extraction properties is comprised of a blend of acids, particularly water soluble acids. More specifically, a combination of two acids chosen from the group consisting of acetic acid, sulfuric acid, glycolic acid, citric acid and methanesulfonic acid.Type: GrantFiled: February 26, 2008Date of Patent: June 7, 2011Assignee: General Electric CompanyInventors: Alan E. Goliaszewski, Cato R. McDaniel
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Patent number: 7955519Abstract: The invention provides compositions and methods for planarizing or polishing a surface. One composition comprises about 0.01 wt. % to about 20 wt. % ?-alumina particles, wherein the ?-alumina particles have an average diameter of 200 nm or less, and 80% of the ?-alumina particles have a diameter of about 500 nm or less, an organic acid, a corrosion inhibitor, and water. Another composition comprises ?-alumina particles, an organic acid, dual corrosion inhibitors of triazole and benzotriazole, wherein the wt. % ratio of the triazole to benzotriazole is about 0.1 to about 4.8, and water.Type: GrantFiled: September 30, 2005Date of Patent: June 7, 2011Assignee: Cabot Microelectronics CorporationInventors: Yuchun Wang, Jason Aggio, Bin Lu, John Parker, Renjie Zhou
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Publication number: 20110124195Abstract: Provided are a chemical mechanical polishing (CMP) composition used for polishing a semiconductor device which contains polysilicon film and insulator, and a chemical mechanical polishing method thereof. The CMP composition is especially useful in a isolation CMP process for semiconductor devices. Provided is a highly selective CMP composition containing a polysilicon polish finisher which can selectively polish semiconductor insulators since it uses a polysilicon film as a polish finishing film.Type: ApplicationFiled: July 22, 2009Publication date: May 26, 2011Applicant: TECHNO SEMICHEM CO., LTD.Inventors: Hyu-Bum Park, Dae-Sung Kim, Jong-Kwan Park, Jung-Ryul Ahn
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Publication number: 20110117751Abstract: Composition and method to remove undoped silicon-containing materials from microelectronic devices at rates greater than or equal to the removal of doped silicon-containing materials.Type: ApplicationFiled: March 6, 2009Publication date: May 19, 2011Applicant: ADVANCED TECHNOLOGY MATERIALS, INC.Inventors: Prerna Sonthalia, Emanuel I. Cooper, David Minsek, Peng Zhang, Melissa A. Petruska, Brittany Serke, Trace Quentin Hurd
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Patent number: 7942945Abstract: The proposed slurry can be used to planarize polymeric candidate ILD materials such Benzocylobutene (BCB), SILK, Polyimide, etc. The slurry consists of colloidal suspension of nanoparticle abrasives made up of Tetraethylorthosilicate (TEOS)-derived silica and Zirconium-dioxide (ZrO2), its derivatives and any materials modified from ZrO2 and/or TEOS, in a chemically active medium. The base solution of the slurry consists of deionized (Dl) water, buffering agents like inorganic buffer comprised of inorganic acids such as TRIS-Hcl, its derivatives and variants, cleansing agents, surface modified catalysts, and surface reagents. The organic solvents like isopropyl alcohol, methanol, and other organic alcohols ranging from 0.0005 to 0.05% are employed for active dissolution of the chemical surface complex formed as a result of the slurry chemical action. The inorganic buffer is so chosen that the complex salts resulting from the reaction impart hydrophobicity to the polished thin film surface.Type: GrantFiled: March 27, 2006Date of Patent: May 17, 2011Assignee: University of South FloridaInventors: Parshuram B. Zantye, Arun Kumar, Ashok Kumar
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Patent number: 7938982Abstract: A process for etching silicon wafers using a caustic etchant in the form of an aqueous solution comprising water, a hydroxide ion source, and a chelating agent. The process produces silicon wafers substantially free from diffused metal ions.Type: GrantFiled: January 2, 2008Date of Patent: May 10, 2011Assignee: MEMC Electronic Materials, Inc.Inventors: Mark G. Stinson, Henry F. Erk, Guoqiang Zhang
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Publication number: 20110104840Abstract: The present invention is concerned with etchant or etching solutions and additives therefor, a process of preparing the same, a process of patterning a substrate employing the same, a patterned substrate thus prepared in accordance with the present invention and an electronic device including such a patterned substrate. An etchant solution according to the present invention for patterned etching of at least one surface or surface coating of a substrate comprises nitric acid, a nitrite salt, a halogenated organic acid represented by the formula C(H)n(Hal)m[C(H)o(Hal)p]qC?2H, where Hal represents bromo, chloro, fluoro or b iodo, where n is 0, 1, 2 or 3, and m is 0, 1, 2 or 3, with the proviso that m+n=3; o is 0 or 1, p is 1 or 2, with the proviso that o+p=2; q is 0 or 1, with the proviso that q+m=1, 2, 3 or 4; and balance water.Type: ApplicationFiled: November 30, 2005Publication date: May 5, 2011Applicant: KONINKLIJKE PHILIPS ELECTRONICS, N.V.Inventors: Dirk Burdinski, Harold Brans
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Patent number: 7922926Abstract: The invention provides a chemical-mechanical polishing composition consisting essentially of flumed alumina, alpha alumina, silica, a nonionic surfactant, an additive compound selected from the group consisting of glycine, alanine, iminodiacetic acid, and maleic acid, hydrogen peroxide, and water. The invention further provides a method of chemically-mechanically polishing a substrate comprising contacting a substrate with a polishing pad and the chemical-mechanical polishing composition, moving the polishing pad and the polishing composition relative to the substrate, and abrading at least a portion of the substrate to polish the substrate.Type: GrantFiled: January 8, 2008Date of Patent: April 12, 2011Assignee: Cabot Microelectronics CorporationInventors: Selvaraj Palanisamy Chinnathambi, Ping-Ha Yeung, Brian Reiss
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Publication number: 20110045741Abstract: Disclosed is a chemical-mechanical polishing composition used in a process for chemical-mechanical polishing of silicon oxide layer having severe unevenness with large step-height. The composition includes abrasive particles of metal oxide; and at least one compound(s) selected from the group consisting of amino alcohols, hydroxycarboxylic acid having at least 3 of the total number of carboxylic acid group(s) and hydroxyl group(s) or their salts, or a mixture thereof. A polymeric organic acid, a preservative, a lubricant and a surfactant may be further contained. The composition shortens the vapor-deposition time of a layer to be polished, saves the raw material to be vapor-deposited, shortens the chemical-mechanical polishing time, and saves the slurry employed.Type: ApplicationFiled: April 28, 2006Publication date: February 24, 2011Applicant: TECHNO SEMICHEM CO., LTD.Inventors: Jung-Ryul Ahn, Jong-Kwan Park, Seok-Ju Kim, Eun-Il Jeong, Deok-Su Han, Hyu-Bum Park, Kui-Jong Baek, Tae-Kyeong Lee
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Patent number: 7887714Abstract: There is provided an abrasive used for polishing a substrate which comprises silica as a main component, for example a rock crystal, a quartz glass for photomask, for CMP of an organic film, Inter Layer Dielectric (ILD) and shallow trench isolation of a semiconductor device, or for polishing a hard disk made of glass. A sol which particles are dispersed in a medium, wherein the particles have a particle size of 0.005 to 1 ?m and comprise as a main component crystalline cerium oxide of the cubic system and as an additional component a lanthanum compound, a neodymium compound or a combination thereof, wherein the additional component is contained in X/(Ce+X) molar ratio of 0.001 to 0.5 in which X is lanthanum atoms, neodymium atoms or a combination thereof.Type: GrantFiled: December 17, 2001Date of Patent: February 15, 2011Assignee: Nissan Chemical Industries, Ltd.Inventors: Isao Ota, Kenji Tanimoto, Tohru Nishimura
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Patent number: 7875558Abstract: The present invention is directed to a microetching composition comprising a source of cupric ions, acid, a nitrile compound, and a source of halide ions. Other additive, including organic solvents, a source of molybdenum ions, amines, polyamines, and acrylamides may also be included in the composition of the invention. The present invention is also directed to a method of microetching copper or copper alloy surfaces to increase the adhesion of the copper surface to a polymeric material, comprising the steps of contacting a copper or copper alloy surface with the composition of the invention, and thereafter bonding the polymeric material to the copper or copper alloy surface.Type: GrantFiled: August 14, 2007Date of Patent: January 25, 2011Inventors: Kesheng Feng, Nilesh Kapadia, Steven A. Castaldi
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Publication number: 20110008967Abstract: The present invention relates to a CMP slurry that is able to reduce dishing generation, when it is applied to polishing or planarization of silicon oxide layer, for example, and a polishing method. The CMP slurry includes a polishing abrasive, a linear anionic polymer, a compound including a phosphoric acid group, and water, and the ratio of CMP polishing speed to a silicon oxide layer: CMP polishing speed to a silicon nitride layer is 30:1 to 50:1.Type: ApplicationFiled: March 3, 2009Publication date: January 13, 2011Applicant: LG CHEM, LTD.Inventors: Jong-Pil Kim, Seung-Beom Cho, Jun-Seok Noh, Jang-Yul Kim
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Patent number: 7858527Abstract: An additive composition for a slurry contains a first salt of polymeric acid including a first polymeric acid having a first weight average molecular weight and a first base material, and a second salt of polymeric acid including a second polymeric acid having a second weight average molecular weight and a second base material. A slurry composition is prepared by mixing the additive composition, a polishing particle composition, and water. When implementing a chemical mechanical polishing using the slurry composition, a favorable polishing selectivity is realized.Type: GrantFiled: September 26, 2007Date of Patent: December 28, 2010Assignee: Samsung Electronics Co., Ltd.Inventors: Nam-Soo Kim, Sang-Mun Chon, Young-Sam Lim, Kyoung-Moon Kang, Sei-Cheol Lee, Jae-Hyun So, Dong-Jun Lee
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Publication number: 20100314576Abstract: The invention provides a composition for chemical-mechanical polishing. The composition comprises an abrasive, a first metal rate polishing modifier agent, a second metal rate polishing modifier agent, and a liquid carrier. In one embodiment, the first metal rate polishing modifier agent has a standard reduction potential less than 0.34 V relative to a standard hydrogen electrode, and the second metal rate polishing modifier agent has a standard reduction potential greater than 0.34 V relative to a standard hydrogen electrode. In other embodiments, the first and second metal rate polishing modifier agents are different oxidizing agents.Type: ApplicationFiled: August 11, 2010Publication date: December 16, 2010Inventors: Francesco DE REGE THESAURO, Steven Grumbine, Phillip Carter, Shoutian Li, Jian Zhang, David Schroeder, Ming-Shih Tsai
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Publication number: 20100301010Abstract: The present invention provides an etchant composition suitable for etching metals Cu/Mo, wherein the composition comprises 1 to 25 wt % of hydrogen peroxide on the basis of the total weight of the composition; 0.1 to 15 wt % of amino acid on the basis of the total weight of the composition; 0.1 to 15 wt % of a pH stabilizer on the basis of the total weight of the composition; 0.01 to 2 wt % of fluorine-containing acid on the basis of the total weight of the composition; 0.01 to 3 wt % of an acidic pH adjuster on the basis of the total weight of the composition; and an aqueous medium. The present invention also provides a process for etching metals Cu/Mo with the etchant composition of the present invention.Type: ApplicationFiled: October 2, 2008Publication date: December 2, 2010Applicant: BASF SEInventors: Cheng Wei Lin, Mo Hsun Tsai
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Publication number: 20100304573Abstract: The present invention relates to new storage-stable solutions which can be used in semiconductor technology to effect specific etching of copper metallization layers and also Cu/Ni layers. With the new etch solutions it is possible to carry out etching and patterning of all-copper metallizations, layers of copper/nickel alloys, and also successive copper and nickel layers.Type: ApplicationFiled: August 7, 2006Publication date: December 2, 2010Applicant: BASF SEInventors: Martin Fluegge, Raimund Mellies, Thomas Goelzenleuchter, Marianne Schwager, Ruediger Oesten
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Patent number: 7842193Abstract: According to an aspect of the invention, there is provided a polishing liquid for polishing a barrier metal material on an interlayer insulation material, the polishing liquid having a pH of from 2.0 to 6.0 and including an aqueous solution containing a compound represented by the following formula (1), and polishing particles containing silicon oxide and dispersed in the aqueous solution: R1—(CH2)m—(CHR2)n—COOH (1) wherein m+n?4; R1 represents a hydrogen atom, a methyl group, an ethyl group or a hydroxyl group; R2 represents a methyl group, an ethyl group, a benzene ring or a hydroxyl group; and when a plurality of R2s are present in the formula (1), they are the same or different from one another.Type: GrantFiled: September 28, 2006Date of Patent: November 30, 2010Assignee: FUJIFILM CorporationInventor: Kenji Takenouchi
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Publication number: 20100288731Abstract: The invention concerns processes and solutions for the treatment of copper alloy surfaces, which are subsequently to be firmly bonded to polymeric material. The solution is used, in particular for firmly bonding lead frames to encapsulating molding compounds (polymeric material). The solution contains an oxidant, at least one acid, at least one adhesion-enhancing compound characterized in that the solution additionally contains fluoride ions in an amount of at least 100 mg per litre and chloride ions in an amount of 5 to 40 mg per litre. The solution is particularly useful for treatment of copper alloy surfaces, containing alloying elements selected from the group consisting of Si, Ni, Fe, Zr, P, Sn and Zn.Type: ApplicationFiled: January 31, 2007Publication date: November 18, 2010Inventors: Christian Wunderlich, Jürgen Barthelmes, Kiyoshi Watanabe, Din-Ghee Neoh, Patrick Lam
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Publication number: 20100288725Abstract: Surface texturing of the transparent conductive oxide (TCO) front contact of a thin film photovoltaic (TFPV) solar cell is needed to enhance the light-trapping capability of the TFPV solar cells and thus improving the solar cell efficiency. Embodiments of the current invention describe chemical formulations and methods for the wet etching of the TCO. The formulations and methods may be optimized to tune the surface texturing of the TCO as desired.Type: ApplicationFiled: March 22, 2010Publication date: November 18, 2010Inventors: Zhi-Wen Sun, Nitin Kumar, Guizhen Zhang, Minh Anh Nguyen, Nikhil Kalyankar
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Patent number: 7824568Abstract: A solution for forming a polishing slurry, the polishing slurry and related methods are disclosed. The solution for forming a polishing slurry may include 1H-benzotriazole (BTA) dissolved in an ionic surfactant such as a sodium alkyl sulfate solution, and perhaps a polyacrylic acid (PAA) solution. The solution can be filtered and used in a polishing slurry. This approach to solubilizing BTA results in a high BTA concentration in a polishing slurry without addition of foreign components to the slurry or increased safety hazard. In addition, the solution is easier to ship because it is very stable (e.g., can be frozen and thawed) and has less volume compared to conventional approaches. Further, the polishing slurry performance is vastly improved due to the removal of particles that can cause scratching.Type: GrantFiled: August 17, 2006Date of Patent: November 2, 2010Assignee: International Business Machines CorporationInventors: Joseph K. V. Comeau, Marina M. Katsnelson, Matthew T. Tiersch, Eric J. White
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Publication number: 20100267315Abstract: The present invention provides a polishing composition for polishing copper or copper alloy, comprising: an oxidizing agent (A); at least one acids (B) selected from amino acids, carboxylic acids of 8 or less carbon atoms, or inorganic acids; a sulfonic acid (C) having an alkyl group of 8 or more carbon atoms; a fatty acid (D) having an alkyl group of 8 or more carbon atoms; and an N-substituted imidazole (E) represented by the following general formula (1). (In the formula (1), Ra, Rb, and Rc represent H or an alkyl group of 1 to 4 carbon atoms, and Rd represents a group selected from the group consisting of a benzyl group, a vinyl group, an alkyl group of 1 to 4 carbon atoms, and a group in which a portion of H of these groups has been substituted with OH or NH2.Type: ApplicationFiled: November 12, 2008Publication date: October 21, 2010Applicant: SHOWA DENKO K.K.Inventors: Takashi Sato, Hiroshi Takahashi, Yoshitomo Shimazu, Yuji Itoh
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Patent number: 7816313Abstract: A photoresist residue remover composition is provided that removes a photoresist residue formed by a resist ashing treatment after dry etching in a step of forming, on a substrate surface, wiring of any metal of aluminum, copper, tungsten, and an alloy having any of these metals as a main component, the composition including one or two or more types of inorganic acid and one or two or more types of inorganic fluorine compound. There is also provided a process for producing a semiconductor circuit element wherein, in a step of forming wiring of any metal of aluminum, copper, tungsten, and an alloy having any of these metals as a main component, the photoresist residue remover composition is used for removing a photoresist residue formed by a resist ashing treatment after dry etching.Type: GrantFiled: April 8, 2008Date of Patent: October 19, 2010Assignees: Kanto Kagaku Kabushiki Kaisha, Kabushiki Kaisha ToshibaInventors: Hiroshi Kawamoto, Mikie Miyasato, Takuo Oowada, Norio Ishikawa
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Publication number: 20100252775Abstract: An indium cap layer is formed by blanket depositing indium onto a surface of metallic interconnects separated by interlayer dielectric, and then selectively chemically etching the indium located on the interlayer dielectric leaving an indium cap layer. Etchants containing a strong acid are provided for selectively removing the indium.Type: ApplicationFiled: June 21, 2010Publication date: October 7, 2010Applicant: International Business Machines CorporationInventors: Maurice McGlashan-Powell, Eugene J. O'Sullivan, Daniel Charles Edelstein
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Publication number: 20100230631Abstract: A metal film such as an aluminum film or an aluminum alloy film is etched with good controllability, preventing a resist from bleeding, to have a proper taper configuration and superior flatness. A water solution containing a phosphoric acid, a nitric acid, and an organic acid salt is used as an etching liquid composition used to etch the metal film on a substrate. The organic acid salt is composed of one kind selected from a group consisting of an aliphatic monocarboxylic acid, an aliphatic polycarboxylic acid, an aliphatic oxicarboxylic acid, an aromatic monocarboxylic acid, an aromatic polycarboxylic acid and an aromatic oxycarboxylic acid, and one kind selected from a group consisting of an ammonium salt, an amine salt, a quaternary ammonium salt, and an alkali metal salt. In addition, a concentration of the organic acid salt ranges from 0.1% to 20% by weight.Type: ApplicationFiled: July 16, 2008Publication date: September 16, 2010Inventors: Tsuguhiro Tago, Tomotake Matsuda, Mayumi Kimura, Tetsuo Aoyama
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Patent number: 7790618Abstract: An aqueous solution is useful for selective removal in the presence of a low-k dielectric. The aqueous solution comprises by weight percent 0 to 25 oxidizer; 0.00002 to 5 multi-component surfactant, the multi-component surfactant having a hydrophobic tail, a nonionic hydrophilic portion and an anionic hydrophilic portion, the hydrophobic tail having 6 to 30 carbon atoms and the nonionic hydrophilic portion having 10 to 300 carbon atoms; 0 to 15 inhibitor for a nonferrous metal; 0 to 50 abrasive; 0 to 20 complexing agent for a nonferrous metal; and water.Type: GrantFiled: December 22, 2004Date of Patent: September 7, 2010Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.Inventor: Jinru Bian
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Patent number: 7785487Abstract: The aqueous slurry is useful for chemical mechanical polishing semiconductor substrates having copper interconnects. The aqueous slurry includes by weight percent, 0.01 to 25 oxidizing agent, 0.1 to 50 abrasive particles, 0.001 to 3 polyvinyl pyrrolidone, 0.01 to 10 inhibitor for decreasing static etch of the copper interconnects, 0.001 to 5 phosphorus-containing compound for increasing removal rate of the copper interconnects, 0.001 to 10 complexing agent formed during polishing and balance water; and the aqueous slurry has a pH of at least 8.Type: GrantFiled: August 15, 2006Date of Patent: August 31, 2010Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.Inventors: Terence M. Thomas, Qianqiu Ye
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Patent number: 7776230Abstract: The invention provides a chemical-mechanical polishing system for polishing a substrate comprising (a) a polishing component selected from an abrasive, a polishing pad, or both an abrasive and a polishing pad, (b) an aqueous carrier, and (c) the halogen adduct resulting from the reaction of (1) an oxidizing agent selected from the group consisting of iodine, bromine, and a combination thereof, and (2) a carbon acid having a pKa of about 3 to about 14, wherein the halogen adduct is present in a concentration of about 0.01 mM or more in the aqueous carrier. The invention also provides a method of polishing a substrate comprising (i) providing the aforementioned chemical-mechanical polishing system, (ii) contacting the substrate with the polishing system, and (iii) abrading at least a portion of the surface of the substrate with the polishing system to polish the substrate.Type: GrantFiled: February 9, 2007Date of Patent: August 17, 2010Assignee: Cabot Microelectronics CorporationInventors: Steven Grumbine, Francesco De Rege Thesauro
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Publication number: 20100197201Abstract: Disclosed is a metal-polishing liquid comprising: a metal-oxide-dissolving agent; a metal-oxidizing agent; a metal anticorrosive; a water-soluble polymer having a weight-average molecular weight of 8,000 or higher and having an anionic functional group and a nonionic functional group; and water, and having a pH within the range of 2.5 or higher but 5.0 or less. The metal-polishing liquid is effective in reducing the frictional force in polishing which generates during CMP. And is highly effective in flattening the surface of a work to be polished.Type: ApplicationFiled: July 28, 2008Publication date: August 5, 2010Inventors: Yutaka Nomura, Masato Fukasawa, Hiroshi Nakagawa
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Publication number: 20100184291Abstract: The present invention relates to an aqueous slurry composition for chemical mechanical polishing that can show good polishing rate to the target layer, and yet has a high polishing selectivity and can maintain superior surface condition of the target layer after polishing, and a chemical mechanical polishing method. The aqueous slurry composition for chemical mechanical polishing (CMP) includes abrasives; an oxidant; a complexing agent; and a polymeric additive including at least one selected from the group consisting of a polypropyleneoxide, a propyleneoxide-ethyleneoxide copolymer, and a compound represented by Chemical Formula 1.Type: ApplicationFiled: February 26, 2009Publication date: July 22, 2010Applicant: LG CHEM, LTD.Inventors: Dong-Mok Shin, Eun-Mi Choi, Seung-Beom Cho, Hyun-Chul Ha
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Publication number: 20100176336Abstract: Chemical polishing solutions and methods are disclosed for the chemical polishing of GaAs wafers. An exemplary chemical polishing solution consistent with the innovations herein may comprise dichloroisocyanurate, sulfonate, acid pyrophosphate, bicarbonate and carbonate. An exemplary chemical polishing method may comprise polishing a wafer in a chemical polishing apparatus in the presence of such a chemical polishing solution. Chemical polishing solutions and methods herein make it possible, for example, to improve wafer quality, decrease costs, and/or reduce environmental pollution.Type: ApplicationFiled: September 29, 2009Publication date: July 15, 2010Applicant: AXT, INC.Inventors: Tan Kaixie, Gu Yan, Wang Yuanli
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Publication number: 20100178765Abstract: The present invention provides a metal polishing liquid capable of CMP at a high Cu polishing rate and solving the problems: (a) generation of scratches attributable to solid particles, (b) generation of deteriorations in flatness such as dishing and erosion, (c) complexity in a washing process for removing abrasive particles remaining on the surface of a substrate after polishing, and (d) higher costs attributable to the cost of a solid abrasive itself and to waste liquid treatment, as well as a method of polishing a film to be polished by using the same.Type: ApplicationFiled: December 27, 2006Publication date: July 15, 2010Inventors: Yutaka Nomura, Hiroshi Nakagawa, Sou Anzai, Ayako Tobita, Takafumi Sakurada, Katsumi Mabuchi
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Patent number: 7754611Abstract: A chemical mechanical polishing method is disclosed. The method includes forming a film on a wafer having at least one trench structure thereon; polishing the surface of the film by providing a polishing composition to provide a first polished surface; rinsing the first polished surface with a rinse composition to provide a rinsed surface; and polishing the rinsed surface by providing a second polishing composition to provide a second polished surface.Type: GrantFiled: February 28, 2006Date of Patent: July 13, 2010Assignee: Macronix International Co., Ltd.Inventors: Chun Fu Chen, Yung Tal Hung, Yun Chi Yang
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Publication number: 20100164106Abstract: Provided is a CMP slurry composition for barrier polishing for manufacturing copper interconnects, the composition including abrasive particles, a copper surface protective agent, a copper corrosion inhibitor, an oxidizing agent, and a pH adjustor, wherein the abrasive particles are non-spherical colloidal silica having a ratio of an average primary particle size to an average secondary particle size of about 0.6 or less and the copper surface protective agent is a carboxyl-functionalized water-soluble polymer.Type: ApplicationFiled: December 28, 2009Publication date: July 1, 2010Applicant: Cheil Industries Inc.Inventors: Tae Young LEE, In Kyung LEE, Byoung Ho CHOI, Yong Soon PARK
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Publication number: 20100167546Abstract: A composition and associated method for chemical mechanical planarization of a metal-containing substrate (e.g., a copper substrate) are described herein which afford high and tunable rates of metal removal as well as low dishing and erosion levels during CMP processing.Type: ApplicationFiled: December 8, 2009Publication date: July 1, 2010Applicant: DoPont Air Products Nanomaterials LLCInventors: Xiaobo Shi, Bentley J. Palmer, Rebecca A. Sawayda
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Publication number: 20100159698Abstract: A combination, composition and associated method for chemical mechanical planarization of a tungsten-containing substrate are described herein which afford tunability of tungsten/dielectric selectivity and low selectivity for tungsten removal in relation to dielectric material. Removal rates for both tungsten and dielectric are high and stability of the slurry (e.g., with respect to pH drift over time) is high.Type: ApplicationFiled: December 3, 2009Publication date: June 24, 2010Applicant: DuPoint Air Products Nanomaterials LLCInventors: Rachel Dianne McConnell, Ann Marie Meyers
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Publication number: 20100151684Abstract: The present invention relates to a slurry composition for primary chemical mechanical polishing that can show more improved WIWNU (Within Wafer Non-Uniformity) while exhibiting excellent polishing rate and polishing selectivity, and a chemical mechanical polishing method. The slurry composition for primary chemical mechanical polishing comprises an abrasive; an oxidant, an organic acid; a specific corrosion inhibitor, and, a polymeric additive comprising polyvinylpyrrolidone having weight average molecular weight of about 3000 to 100000, and has polishing selectivity of polishing rates between a copper layer:a tantalum layer of about 30:1 or more.Type: ApplicationFiled: December 3, 2009Publication date: June 17, 2010Applicant: LG CHEM LTD.Inventors: Eun-Mi CHOI, Dong-Mok SHIN, Seung-Beom CHO
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Patent number: 7731864Abstract: Described herein are embodiments of a slurry used for the chemical mechanical polishing a substrate that includes aluminum or an aluminum alloy features having a width of less than 1 um. The slurry includes a precipitated silica abrasive having a diameter of less than or equal to 100 nm and a chelating buffer system comprising citric acid and oxalic acid to provide a pH of the slurry in the approximate range of 1.5 and 4.0.Type: GrantFiled: June 29, 2005Date of Patent: June 8, 2010Assignee: Intel CorporationInventors: Allen Daniel Feller, Anne E. Miller
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Patent number: 7727415Abstract: A fine treatment agent according to the present invention is a fine treatment agent for the fine treatment of a multilayer film, including a tungsten film and a silicon oxide film comprising at least one from among hydrogen fluoride, nitric acid, ammonium fluoride and ammonium chloride. Thus, a fine treatment agent which makes fine treatment on a multilayer film, including a tungsten film and a silicon oxide film, possible by controlling the etching rate and a fine treatment method using the same can be provided.Type: GrantFiled: December 19, 2005Date of Patent: June 1, 2010Assignee: Stella Chemifa CorporationInventors: Hirohisa Kikuyama, Masahide Waki, Kanenori Ito, Takanobu Kujime, Keiichi Nii, Rui Hasebe, Hitoshi Tsurumaru, Hideki Nakashima
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Publication number: 20100130013Abstract: A CMP method for polishing a phase change alloy on a substrate surface including positioning the substrate comprising a phase change alloy material on a platen containing a polishing pad and delivering a polishing slurry to the polishing pad. The polishing slurry includes colloidal particles with a particle size less than 60 nm, in an amount between 0.2% to about 10% by weight of slurry, a pH adjustor, a chelating agent, an oxidizing agent in an amount less than 1% by weight of slurry, and polyacrylic acid. The substrate on the platen is polished to remove a portion of the phase change alloy. A rinsing solution for rinsing the substrate on the platen includes deionized water and at least one component in the deionized water where the component selected from the group consisting of polyethylene imine, polyethylene glycol, polyacrylic amide, alcohol ethoxylates, polyacrylic acid, an azole containing compound, benzo-triazole, and combinations thereof.Type: ApplicationFiled: November 19, 2009Publication date: May 27, 2010Applicant: APPLIED MATERIALS, INC.Inventors: Feng Q. Liu, Alain Duboust, Wen-Chiang Tu, Chenhao Ge, Kun Xu, Yuchun Wang, Yufei Chen
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Publication number: 20100120250Abstract: The present invention relates to a metal polishing slurry containing abrasive grains, a metal-oxide-dissolving agent, and water, wherein the abrasive grains contain two or more abrasive grain species different from each other in average secondary particle diameter. Using the metal polishing slurry of the present invention, a metal polishing slurry can be obtained which gives a large polishing rate of an interlayer dielectric layer, and is high in the flatness of the polished surface. This metal polishing slurry can provide suitable method for a semiconductor device which is excellent in being made finer and thinner and in dimension precision and in electric characteristics, is high in reliability, and can attain a decrease in costs.Type: ApplicationFiled: February 22, 2008Publication date: May 13, 2010Applicant: HITACHI CHEMICAL CO., LTD.Inventors: Jin Amanokura, Takafumi Sakurada, Sou Anzai, Takashi Shinoda, Shigeru Nobe
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Publication number: 20100120209Abstract: An etchant composition is provided. The etchant composition includes about 40 to about 65 wt % of phosphoric acid, about 2 to about 5 wt % of nitric acid, about 2 to about 20 wt % of acetic acid, about 0.1 to about 2 wt % of a compound containing phosphate, about 0.1 to about 2 wt % of a compound simultaneously containing an amino group and a carboxyl group, and a remaining weight percent of water for the total weight of the composition.Type: ApplicationFiled: April 29, 2009Publication date: May 13, 2010Inventors: Young-Joo CHOI, Bong-Kyun KIM, Byeong-Jin LEE, Jong-Hyun CHOUNG, Sun-Young HONG, Nam-Seok SUH, Hong-Sick PARK, Ky-Sub KIM, Seung-Yong LEE, Joon-Woo LEE, Young-Chul PARK, Young-Jun JIN, Seung-Jae YANG, Hyun-Kyu LEE, Sang-Hoon JANG, Min-Ki LIM
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Patent number: 7708904Abstract: The disclosure is directed to a processing fluid including an aliphatic hydrocarbon component having an average chain length of 8 to 16 carbons and about 0.0001 wt % to about 50.0 wt % of a Lewis active component.Type: GrantFiled: October 3, 2005Date of Patent: May 4, 2010Assignee: Saint-Gobain Ceramics & Plastics, Inc.Inventors: Douglas E. Ward, Jason A. Sherlock
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Publication number: 20100099260Abstract: A chemical mechanical polishing aqueous dispersion includes (A) colloidal silica having an average particle size calculated from the specific surface area determined by the BET method of 10 to 60 nm, (B) an organic acid having two or more carboxyl groups and one or more hydroxyl groups in one molecule, and (C) a quaternary ammonium compound shown by the following general formula (1), wherein R1 to R4 individually represent hydrocarbon groups, and M? represents an anion, the chemical mechanical polishing aqueous dispersion having a pH of 3 to 5.Type: ApplicationFiled: February 20, 2008Publication date: April 22, 2010Applicant: JSR CORPORATIONInventors: Taichi Matsumoto, Tomikazu Ueno, Michiaki Andou
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Publication number: 20100019292Abstract: A transistor having a metal nitride layer pattern, etchant and methods of forming the same is provided. A gate insulating layer and/or a metal nitride layer may be formed on a semiconductor substrate. A mask layer may be formed on the metal nitride layer. Using the mask layer as an etching mask, an etching process may be performed on the metal nitride layer, forming the metal nitride layer pattern. An etchant, which may have an oxidizing agent, a chelate agent and/or a pH adjusting mixture, may perform the etching. The methods may reduce etching damage to a gate insulating layer under the metal nitride layer pattern during the formation of a transistor.Type: ApplicationFiled: August 31, 2009Publication date: January 28, 2010Inventors: Sang-Yong Kim, Ji-Hoon Cha, Woo-Gwan Shim, Chang-Ki Hong, Sang-Jun Choi
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Publication number: 20090302003Abstract: An aqueous solution for polishing and deburring includes pure water; carboxylic acid of 200 gram per liter to 300 gram per liter; sulfuric acid ions of 200 gram per liter to 500 gram per liter; phosphoric acid ions of 100 gram per liter to 300 gram per liter; and nitric acid ions of 50 gram per liter to 200 gram per liter. Also, a process for polishing and deburring a part made of pure nickel or nickel-200 in the solution includes removing oily substance from the part; washing the part by water; pouring the solution into a bath and submerging the part in the solution so that the part is brought into contact with the solution; neutralizing the solution remained on the surface of the part to prevent the part from oxidizing; and drying the part to obtain a finished part.Type: ApplicationFiled: June 5, 2008Publication date: December 10, 2009Inventors: Ching-An Huang, Chwen-Lin Shih
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Publication number: 20090289217Abstract: A polishing composition which achieves surfaces with high planarity and the reduction of corrosions in the wiring metal surface at the same time is provided. Such compositions include (A) an oxidizing agent; (B) at least one acid selected from an amino acid, a carboxylic acid of no more than 8 carbon atoms, and an inorganic acid; (C) a sulfonic acid having a concentration of 0.01% by mass or more and having an alkyl group of 8 or more carbon atoms; (D) a fatty acid having a concentration of 0.001% by mass or more and having an alkyl group of 8 or more carbon atoms; and (E) at least one compound selected from a pyridine carbonyl compound, a nonionic water-soluble polymer, 2-pyrrolidone, N-methylpyrrolidone, 1,3-dimethyl-2-imidazolidinone, gramine, adenine, N,N?-diisopropylethylenediamine, N,N?-bis(2-hydroxyethyl)ethylenediamine, N,N?-dibenzylethylenediamine, and N,N?-diphenylethylenediamine.Type: ApplicationFiled: July 26, 2007Publication date: November 26, 2009Applicant: SHOWA DENKO K.K.Inventors: Takashi Sato, Hiroshi Takahashi, Yoshitomo Shimazu, Yuji Ito
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Publication number: 20090286360Abstract: The present embodiments relate to an etchant and a method of fabricating an electric device including a thin film transistor. The etchant includes a fluorine ion (F?) source, hydrogen peroxide (H2O2), a sulfate, a phosphate, an azole-based compound, and a solvent. The etchant and method of fabricating an electric device including a thin film transistor, can etch a multi-layered film including copper layer, and a titanium or titanium alloy layer in a batch and can provide a thin film transistor having a good pattern profile at high yield. When reusing the etchant, uniform etching performance can be maintained with a long replacement period of the etchant, and therefore costs can be saved.Type: ApplicationFiled: March 24, 2008Publication date: November 19, 2009Inventors: Gyoo-Chul Jo, Kwang-Nam Kim
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Patent number: 7601273Abstract: A polishing slurry composition including an abrasive, a pH-adjusting agent, a water-soluble thickening agent, and a chelating agent, wherein the chelating agent includes at least one of an acetate chelating agent and a phosphate chelating agent, and a method of using the same.Type: GrantFiled: March 6, 2006Date of Patent: October 13, 2009Assignees: Cheil Industries, Inc., MEMC Korea Co., Ltd.Inventors: Hyun Soo Roh, Tae Won Park, Tae Young Lee, In Kyung Lee, Chin Ho Lee, Young Woo Kim, Moon Ro Choi, Jong Seop Kim
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Publication number: 20090246967Abstract: A semiconductor surface treatment agent containing a fluorine compound, a water-soluble organic solvent and an inorganic acid, with the balance being water and a method for manufacturing a semiconductor device by etching a high dielectric constant insulating material using the subject semiconductor surface treatment agent are provided. According to the present invention, it is possible to selectively and efficiently etch a high dielectric constant insulating material to be used in a transistor formation process of the semiconductor device manufacture; and it is also possible to achieve etching with ease within a short period of time even for a high dielectric constant insulating material to which etching is hardly applied.Type: ApplicationFiled: November 30, 2006Publication date: October 1, 2009Inventors: Kazuyoshi Yaguchi, Kenji Shimada, Kojiro Abe
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Publication number: 20090227075Abstract: An etchant composition that allows simplification and optimization of semiconductor manufacturing process is presented, along with a method of patterning a conductive layer using the etchant and a method of manufacturing a flat panel display using the etchant. The etchant includes nitric acid, phosphoric acid, acetic acid, and an acetate compound in addition to water.Type: ApplicationFiled: February 24, 2009Publication date: September 10, 2009Inventors: Bong-Kyun Kim, Hong-Sick Park, Jong-Hyun Choung, Sun-Young Hong, Ji-Sun Lee, Byeong-Jin Lee, Kui-Jong Baek, Tai-Hyung Lee, Yong-Sung Song