Abstract: The invention relates to a process for producing gel-spun ultra high molecular weight polyethylene (UHMWPE) fibres having high tensile strengths and improved creep rates wherein the UHMWPE used in said process is characterized by a difference in the phase angle according to Formula (1) ??=?0.001??100 of at most 42°, wherein ?0.001 is the phase angle at an angular frequency of 0.001 rad/sec; and ?100 is the phase angle at an angular frequency of 100 rad/sec as measured with a frequency sweep dynamic rheological technique at 150° C. on a 10% solution of UHMWPE in paraffin oil, provided that ?100 is at most 18°. The invention further relates to gel-spun UHMWPE fibres produced thereof. The gel-spun UHMWPE fibres of the invention have a tensile strength of at least 4 GPa, and a creep rate of at most 5×10?7 sec?1 as measured at 70° C. under a load of 600 MPa.

Abstract: A gasket assembly (20) and method for forming the gasket assembly (20) for sealing two mating surfaces (46,48) over a complex geometrical contact region. The gasket assembly (20) is formed by a hollow silicone rubber tube (22) having a naturally straight configuration but easily bent into complex configurations without kinking. The tube (22) is filled with a curable liquid rubber compound (30) and then the ends (24,26) of the tube (22) are joined in end-to-end fashion to form a continuous loop. The joined ends (24,26) of the tube (22) can be reinforced with a connector (34,134) and then locally cured on a preliminary operation so that the liquid rubber compound (30) does not escape. The tube (22) is then laid up in a mold (40) having a complex geometrical feature (42) which replicates the complex geometrical contact region of the two mating surfaces (46,48) to be subsequently sealed.

Abstract: The mixture of the invention contains, for 100 parts in weight of (A)+(B): (A) 10 to 90 parts in weight of at least one non-nanostructured olefinic thermoplastic polymer; (B) 90 to 10 parts in weight of a formulation of at least one elastomer having unsaturated double bonds and capable of reacting with a cross-linking or vulcanization agent, said formulation containing a crosslinking or vulcanization system of said elastomer(s), at least one plasticizer, and the standard additives present in elastomer formulations; (C) up to 100 parts in weight, relative to (A)+(B), of at least one copolymer grafted with polyamide blocks, said copolymer comprising a polyolefin trunk and at least 1.

Abstract: There is disclosed a method of producing a pre-oxidation fiber in the production of the pre-oxidation fiber by subjecting a polyacrylic precursor fiber to pre-oxidation processing in an oxidizing atmosphere, including shrinking the precursor fiber as a pretreatment of pre-oxidation at a load of 0.58 g/tex or less in the temperature range of 220 to 260° C. under conditions in which the degree of cyclization (I1620/I2240) of the precursor fiber measured by a Fourier transform infrared spectrophotometer (FT-IR) does not exceed 7%, initially-drawing the precursor fiber at a load of 2.7 to 3.5 g/tex in an oxidizing atmosphere at 230 to 260° C. in the ranges of the degree of cyclization of not exceeding 27% and of the density of not exceeding 1.2 g/cm3, and then subjecting the pre-oxidation fiber to pre-oxidation treatment.

Abstract: Nanofibers are fabricated by introducing a polymer solution into a dispersion medium and shearing the dispersion medium. Droplets of the polymer solution are spun into elongated fibers that are insoluble in the dispersion medium.

Abstract: This invention relates to a method of making flat sheet asymmetric membranes, including cellulose diacetate/cellulose triacetate blended membranes, polyimide membranes, and polyimide/polyethersulfone blended membranes by formulating the polymer or the blended polymers dopes in a dual solvent mixture containing 1,3 dioxolane and a second solvent, such as N,N?-methylpyrrolidinone (NMP). The dopes are tailored to be closed to the point of phase separation with or without suitable non-solvent additives such as methanol, acetone, decane or a mixture of these non-solvents. The flat sheet asymmetric membranes are cast by the phase inversion processes using water as the coagulation bath and annealing bath. The dried membranes are coated with UV curable silicone rubber. The resulting asymmetric membranes having a skin thickness of less than 100 nm, exhibit excellent permeability and selectivity compared to the intrinsic dense film performances.

Abstract: An optical film comprising a transparent support and a layer having internal scattering properties, wherein the optical film has an image sharpness, as measured in an optical comb width of 0.5 mm in conformity to JIS K7105, of from 30.0% to 99.9%, a haze value as caused by surface scattering of less than 3%, and a haze value as caused by internal scattering of from 15 to 40%.

Abstract: A fluffy nano-material and method of manufacture are described. At 2000× magnification the fluffy nanomaterial has the appearance of raw, uncarded wool, with individual fiber lengths ranging from approximately four microns to twenty microns. Powder-based nanocatalysts are dispersed in the fluffy nanomaterial. The production of fluffy nanomaterial typically involves flowing about 125 cc/min of organic vapor at a pressure of about 400 torr over powder-based nano-catalysts for a period of time that may range from approximately thirty minutes to twenty-four hours.

Abstract: The present invention provides a method for producing a PTFE fiber that makes it possible, unlike the emulsion spinning process, to obtain a polytetrafluoroethylene (PTFE) fiber, particularly a long PTFE fiber, without using a matrix material, is more productive than conventional production methods such as a slit yarn process, and is capable of enhancing mechanical properties and the degree of freedom in diameter of the obtained fiber. The method for producing the PTFE fiber of the present invention includes the step of reducing a diameter of a string-shape PTFE-containing solid material (a first solid material) by drawing the first solid material at a temperature equal to or higher than a melting point of PTFE. The first solid material can be obtained from a PTFE-containing solid material (a second solid material) containing water and a surfactant, by reducing an amount of the water contained in the second solid material.

Abstract: A method of moulding an object of indefinite length. A first portion of molten material is injected into a mould comprising a stationary platen and a moving platen and solidifies to form a first portion of solid material at a first position. The moving platen is moved in a given direction to open the mould and move the material in said given direction to a second position in communication with the mould. The moving platen is then moved in the opposite direction to close the mould. A further portion of molten material is injected into the mould and solidifies to form a further portion of solid material intimately bonded to said first portion. The steps are repeated to form an object comprising the first portion and further portions of material bonded together as a linear array of indefinite length.

Abstract: A method of making a thermotropic liquid crystal polymer film includes continuously heat treating of the thermotropic liquid crystal polymer film 2 while the latter is jointed to a sheet-like support member 4, and subsequently separating the heat-treated thermotropic liquid crystal polymer film 2 from the support member 4. The continuous heat treatment of the thermotropic liquid crystal polymer film 2 then jointed to the support member 4 is carried out for a predetermined heating time within the range of 5 to 60 seconds at a predetermined heating temperature T° C. equal to or higher than the melting point Tm° C. of the thermotropic liquid crystal polymer film less 15° C. (i.e., Tm?15° C.), but lower than the melting point Tm° C. (thus, Tm?15° C.?T° C.<Tm° C.), to thereby increase the thermal expansion coefficient of the thermotropic liquid crystal polymer film.

Abstract: A method of forming a sound attenuating material includes heating a densified, rebulkable nonwoven web at a sufficient temperature and for a sufficient time to rebulk the nonwoven web to an open, lofty form; compressing the rebulked nonwoven web to a predetermined thickness; and cooling the compressed nonwoven web at a sufficient temperature and for a sufficient time to cause the compressed nonwoven web to maintain the predetermined thickness. The cooled, compressed nonwoven web may further be formed into a desired shape. One or more additional layers of material may be laminated to the densified, rebulkable nonwoven web substantially simultaneously with the heating step. The nonwoven web may be heated to a temperature above the melt point of at least one component fiber of the nonwoven web and heating may be accomplished by heating one or both sides of the nonwoven web.

Abstract: The present invention relates to shape memory materials and to a method for controlling shape change in shape memory materials. In particular, the invention relates to a method and a system for forming complex shapes from shape memory materials and to shape memory materials having complex shapes.

Abstract: Provided is a process for manufacturing a polyamide yarn exhibiting good dyeability, while utilizing polyamide waste. The recycled polyamide yarn with a high waste polymer content is used for making quality articles by a low cost method, which is further friendly to the preservation of the environment.

Abstract: A polycrystalline granulated silicon is made of particles which have a density of greater than 99.9% of the theoretical solid density and therefore have a pore content of less than 0.1% and have a surface roughness Ra of less than 150 nm.

Abstract: A woven panel is formed from at least one first polymer yarn and at least one second polymer yarn wherein the second polymer yarn has a core. The core yarns provide mechanical strength for the woven material in supporting the coreless yarns when used in load bearing articles such as the seat or back portions of an article of furniture.

Abstract: The invention concerns an installation for producing a nonwoven fabric comprising a spun bond lathe depositing a web of filaments on a first conveyor, the mat being consolidated on a first mobile element by entangling means. The invention is characterized in that it comprises means for passing, without any change in ratio, the mat of filaments on a first mobile element whereon the mat is consolidated by hydro-entangling means.

Abstract: A method for fabricating a carbon nanotube yarn includes providing a plurality of carbon nanotube arrays; pulling out, by using a tool, a first carbon nanotube structure from one of the carbon nanotube arrays; pulling out a subsequent carbon nanotube structure from another one of the carbon nanotube arrays; joining a leading end of the subsequent carbon nanotube structure to a trailing portion of the carbon nanotube structure already formed by contacting the leading end of the subsequent carbon nanotube structure with the trailing portion of the already-formed carbon nanotube structure, with the contact occurring along a common lengthwise direction of the two carbon nanotube structures, thereby forming a lengthened carbon nanotube structure; repeating the pulling and the joining until the lengthened carbon nanotube structure has a desired length; and treating the lengthened carbon nanotube structure with an organic solvent.

Abstract: A sensor producing apparatus comprised of an extractor for extracting a nano fiber from a solution and a driving device to relatively move the substrate and the extractor, a method for forming a sensor, and a sensor with a nano structure are provided.

Abstract: A method and apparatus for forming a sheet are disclosed. A melt is cooled and a sheet is formed on the melt. This sheet has a first thickness. The sheet is then thinned from the first thickness to a second thickness using, for example, a heater or the melt. The cooling may be configured to allow solutes to be trapped in a region of the sheet and this particular sheet may be thinned and the solutes removed. The melt may be, for example, silicon, silicon and germanium, gallium, or gallium nitride.

Abstract: A continuous forming apparatus for molding foam material into foam products that includes a first endless belt and a second endless belt that cooperates with the first endless belt to mold the foam material. The continuous forming apparatus may also include a first plurality of cleats and a second plurality of cleats opposed to the first plurality of cleats that support the first endless belt and the second endless belt respectively. The first plurality of cleats may include a three-dimensional abutment surface that provides transverse and lateral support to the first endless belt. Additionally, the continuous forming apparatus may include a first frame disposed to support the first plurality of cleats, a second frame disposed to support the second plurality of cleats, and a drive mechanism for imparting motion to the first endless belt, the second endless belt, the first plurality of cleats, and the second plurality of cleats.

Abstract: A method for jointing a rubbery-core-inserted braid is provided. In the method, a mold made of a pair of templates is prepared, wherein the templates may be closed in such a manner that trenches can constitute a through hole into which the braid is fittable. The method includes a step of fitting an end of the braid into the trench in one of the templates, while fitting the other end of the braid into the trench, thereby approaching both the ends of the braids each other, a step of interposing a thermoplastic resin between both the ends, and a step of heating and melting the thermoplastic resin in a state where the mold is closed, causing the melted resin to penetrate into the ends of the braids, and solidifying the melted resin, thereby jointing the ends of the braids to each other.

Abstract: To provide a stretch-formed sheet of ultra-high molecular weight polyolefin having excellent transparency and mechanical properties, while being relatively thick. A stretch-formed sheet of ultra-high molecular weight polyolefin having a thickness of 0.2 mm or greater and having an internal haze of 70% or less in the direction of the thickness, is prepared by stretching at least in one direction a formed article of ultra-high molecular weight olefin having a density of 925 kg/m3 or less and containing a polymer of ultra-high molecular weight polyolefin having an intrinsic viscosity of 7 dl/g or greater as measured in a 135° C. decalin solution, at a temperature of less than the melting point (Tm) of the ultra-high molecular weight polyolefin and at ordinary temperature or higher.

Abstract: An apparatus and method for depositing synthetic fibers to form a non-woven web includes guiding the synthetic fibers by a blowing stream through a drawing unit for depositing on a deposit belt. Multiple guidance elements are arranged inside the guidance distance between a blast opening of the drawing unit and the deposit belt, and form a guidance channel above the deposit belt. The guidance elements form a channel opening at a distance from the blast opening of the drawing unit. In order to achieve constant strength in the deposition of the fiber strands, the distance between the outlet of the drawing unit and the channel opening of the guidance channel is larger than half the guidance distance, and the guidance width of an open space formed between the outlet of the drawing unit and the channel opening of the guidance channel is larger than the guidance channel.

Abstract: According to an aspect of the present invention, a stent is provided, which contains at least one filament that has a longitudinal axis and comprises a bioabsorbable polymeric material. Polymer molecules within the bioabsorbable polymeric material are provided with a helical orientation which is aligned with respect to the longitudinal axis of the filament. The stent is at least partially bioabsorbed by a patient upon implantation or insertion of the stent into the patient.

Abstract: A package includes at least one layer of foamed thin film and an opening feature formed in the layer of foamed thin film. The foamed thin film has a caliper of from about 10 microns to about 250 microns thick. The foamed thin film comprises from about 5% to about 50% density reduction as compared to a non-foamed thin film of substantially the same caliper and substantially the same composition. The package may include foamed thin film made of a plastic resin and a whitening additive that is added to plastic resin. The whitening additive is selected to produce a foamed thin film having an opacity value of from about 35% to about 99%. The whitening agent is of substantially the same composition and is present in substantially the same amount as would be selected to produce substantially the same light reflectivity in a non-foamed thin film of substantially the same caliper and substantially the same composition.

Abstract: Poly(lactic acid) polymer compositions each contain an appropriate poly(lactic acid) polymer and a suitable plasticizer having a polyether and/or polyester segment in combination. The compositions exhibit satisfactory flexibility and show very small amount of the evaporation, migration and extraction (bleedout) of the plasticizer and losing transparency upon heating. The poly(lactic acid) polymer compositions are useful as formed plastics such as films.

Abstract: Some embodiments of the present invention include elastomeric films with a basis weight of about 40 gsm or less or about 25 gsm or less. Other embodiments include elastomeric laminates comprising the elastomeric film bonded to one or more substrates (such as nonwoven fabrics). Methods of the making the elastomeric films and elastomeric laminates are also provided.

Abstract: Disclosed is a cold-water soluble starch and a process for preparing same. Generally, the process comprises providing a hydroxyalkyl starch and applying a shearing force to the starch in an extruder in the presence of moisture, the force and the moisture each being sufficient to gelatinize at least substantially all of the granules of the starch to thereby form a sheared starch. The starch is heated to its gelatinization temperature after the starch has passed partially through the barrel of the extruder, with the moisture being maintained at a level sufficiently high to allow gelatinization but sufficiency low to protect the starch from becoming too sticky to extrude. The extruded starch product thus formed may be used in connection with a number of film-forming, coating, and other applications.

Abstract: A method of feeding a composite molten resin capable of easily forming a multi-kind-multi-layer preform. An apparatus for feeding the composite molten resin has a nozzle portion which includes an outer discharge port in which an outermost annular flow path through which a main layer-forming molten resin flows, meets an outer annular flow path through which a sub-layer-forming molten resin flows inside of the outermost annular flow path; and an inner discharge port in which a shell layer-forming molten resin annularly flowing inside of the outer conflux path, meets the core layer-forming molten resin flowing inside the shell layer; the outer discharge port and the inner discharge port being arranged in this order from the downstream toward the upstream in a direction in which the molten resins flow; wherein provision is made of a shaft-like opening/closing valve for opening and closing the inner discharge port, and a gear pump for intermittently discharging the sub-layer-forming molten resin.

Abstract: The present invention relates to reinforced polyamide molding compounds containing high-melting partially aromatic polyamides and flat glass fibers, in particular with a rectangular cross section, i.e., glass fibers with a noncircular cross-sectional area and a dimension ratio of the main cross-sectional axis to the secondary cross-sectional axis of 2 to 6, in particular 3 to 6, most especially preferably from 3.5 to 5.0. The present invention also relates to a method for manufacturing polyamide molding compounds and molded articles manufactured therefrom, i.e., in particular injection-molded parts. The inventive molded parts have a high transverse stiffness and transverse strength.

Abstract: The present invention provides elastic polyurethane yarns which possess excellent elongation, recoverability, heat resistance and chemical resistance, as well as a method of manufacturing the same. The elastic polyurethane yarns comprise a polyurethane being composed mainly of a polymeric diol and a diisocyanate, and contains through incorporation a compound having within the molecule a phosphorus-nitrogen interatomic bond(s). The process can produce the elastic polyurethane yarns by adding to a solution of the polyurethane a compound having within the molecule a phosphorus-nitrogen interatomic bond(s), followed by spinning.

Abstract: A system for providing shape and/or surface features to a moldable material includes, in an exemplary embodiment, at least two first opposed flat endless belts spaced apart a first distance, with each having an inner surface and an outer surface. The system also includes at least two second opposed flat endless belts disposed substantially orthogonal to the first two opposed endless belts and spaced apart a second distance. A mold cavity is defined at least in part by the inner surfaces of the at least two opposed flat endless belts. The system further includes a drive mechanism for imparting motion to at least two of the opposed flat endless belts.

Abstract: The invention relates to a process for making a monofilament-like product from a precursor containing at least one strand of fibres made from ultra-high molar mass polyethylene, comprising a) exposing the precursor to a temperature within the melting point range of the polyethylene for a time sufficient to at least partly fuse adjacent fibres and b) simultaneously stretching the precursor, wherein the precursor is mechanically compressed during fusing. The monofilament-like product thus made has a smoother surface appearance, and improved abrasion resistance, for example a reduced tendency to pilling during use as fishing line, than known similar products; making it very suitable for use as fishing line and the like. The invention further relates to a monofilament-like product obtainable by said process, and to semi-finished and end-use products comprising said monofilament-like product.

Abstract: The present invention provides for a plastic sheet, especially one used in the construction of a plastic trash bag, which provides improved tear propagation properties. The plastic sheet has a plurality of protuberances in the plastic sheet, the protuberances defining a first set of substantially parallel curvilinear lines in a first direction, and optionally, a second set of curvilinear lines in a second direction. The plurality of protuberances can be either indentations or protrusions in the plastic sheet, preferably formed through an embossing process. Preferably, the protuberances are circular in shape, but not necessarily uniform, and alternate between indentations and protrusions along the first, and possibly the second, curvilinear lines with the curvilinear lines preferably being wave-shaped.

Abstract: A hose (1) comprising a core tube (2), a reinforcement layer (3) surrounding the core tube (4), and a cover (4) surrounding the reinforcement layer, wherein at least one of the core tube (2) and cover (4) are made of a thermoplastic material comprising one or more thermoplastic polyether-polyester block copolymers, and said thermoplastic material has a Shore D hardness no less than about 60.

Abstract: Process for producing single layer and multilayer polyolefin foam pipes with improved compression resistance having a polyolefin foam layer which consists of mixtures of modified propylene polymers having strain hardening behaviour or propylene homopolymers with a stereospecificity index >98% or propylene copolymers with a stereospecificity index of the homopolymer matrix of >96%. The polyolefin foam pipes include coated steel pipes for transporting crude oil or gas products or district heating applications, single layer pipes for insulation purposes and for non- or low-pressure applications and multilayer plastic pipes for the transportation of hot or cold fluids.

Abstract: Blood-derived plastic articles prepared from compositions including blood and, in some embodiments, at least one crosslinking agent and/or at least one biological response modifier, that can be useful for biological applications such as wound repair and tissue grafts; methods of making and using the same; methods for assessing the concentration of a biological response modifier in an article; and systems for preparing blood-derived plastic articles are provided.

Abstract: A rear end portion of a leading TAC film and a front end portion of a following TAC film are dissolved in acetone and connected. After being stretched in a tenter, the TAC films are sent to an edge slitting device. In the edge slitting device, both side edges of the TAC films that are held with clips are slit along slit lines. The slit side edges are cut into pieces by a cutter blower and then shredded into chips by a crusher. Since the slit side edges of the leading and following TAC films are welded with acetone, they can be recycled as being connected.

Abstract: The invention relates to a method for the production of a cutting filament for a device used to cut vegetation such as a strimmer or border cutter. The filament is made of a synthetic material having extended molecular chains. According to the invention (a), the filament (10) is brought to a controlled viscous state, (b) the filament is stretched according to the length thereof in order to perform a first longitudinal molecular orientation (01), (c) a cross-sectional change, resulting in a partial reorientation of molecular chains in a transversal direction (02), is imposed upon the filament, whereupon filaments having multiple molecular orientations are produced, having improved mechanical properties (e.g. a better resistance to tearing).

Abstract: A fiber optic cable comprising at least one light transmitter extending longitudinally along the cable and a body encompassing the light transmitter. The body includes an exposed surface having an array of fastener elements extending therefrom. The fastener elements arranged and constructed to engage mating fastener elements associated with a supporting surface to selectively secure the cable to the supporting surface.

Abstract: A composition containing a proton-conductive copolymer, a polymer electrolyte membrane containing the composition; a method of producing the membrane; and a fuel cell employing the membrane. The composition includes: a proton-conductive copolymer comprising a first styrene repeating unit, a second styrene repeating unit, and a dimethylsiloxane repeating unit; and a cross-linked polymer obtained from a cross-linking reaction between a siloxane oligomer having an unsaturated bond and a cross-linking agent. The cross-linked polymer has the same properties as the dimethylsiloxane repeating unit of the proton-conductive copolymer.

Abstract: Articles comprising a fibrous support of nanofibers and an interfacially polymerized polymer layer disposed on a surface of the fibrous support are useful, e.g., as fluid separation membranes.

Abstract: The invention relates to a process for making a carbon nanotubes/ultra-high molar mass polyethylene (CNTs/UHPE) composite fibre comprising the steps of a) pre-treating CNTs with an acidic aqueous solution; b) making a composition containing pre-treated CNTs dispersed in a solution of UHPE in a spin solvent; and c) spinning the composition obtained into fibres; wherein step b) comprises making a dispersion of pre-treated CNTs in an alcohol, and mixing this dispersion with a mixture of UHPE and spin solvent. With this process CNTs/UHPE composite fibres showing improved tensile properties are obtained at relatively low CNTs content. A further advantage is that no or hardly any additional components, like dispersion aids, need to be added to make a stable dispersion of CNTs in the spin composition. The invention also relates to a CNTs/UHPE composite fibre obtainable by the process according to the invention, and to semi-finished or end-use articles containing said composite fibre.

Abstract: A material layering device. A material layering device may include a first pinning roller and a second pinning roller. The distance between the first pinning roller and the second pinning roller is less than a diameter of an substrate. The device also includes a return system, wherein the return system comprises a plurality of rollers. The device also includes a belt, which may have a first loop portion disposed between and protruding beyond the first pinning roller and the second pinning roller. The first loop portion also wraps about an intended substrate along an arc greater than about 180 degrees. The device further includes a feed portion coupled to the first loop and extending outwardly from the second pinning roller opposite the first loop and providing a surface upon which a sheet can be placed. Furthermore, the device also includes an adjustment mechanism coupled to one of the rollers.

Abstract: Provided is a continuous production method of a polyamide with stabilized polymerization degree and good quality, particularly an aromatic-containing polyamide.

Abstract: A method of making a bioplastic, and a bioplastic produced thereby, by using human plasma in which human plasma is clotted, either dried through its gel phase or dried and powdered, and processed into a bioplastic with the addition of at least one plasticizer followed by forming and heating to form a final bioplastic construct.

Abstract: The invention relates to a process for making a multi-filament polyethylene yarn via a gel-spinning process, Wherein a spin finish is applied at least once in an amount of 0.1-10 mass % based on the filament, to a filament that contains less than 50 mass % of solvent; the spin finish comprising at least 95 mass % of at least one volatile compound having a boiling point at 0.1 MPa pressure of from 30 to 250° C.; and the spin finish is subsequently removed by exposing the filament to a temperature of below the melting temperature of the filament. With this process a yarn is made that has a very low amount of residues on the surface of the fibres, without the need for a washing or extraction step, showing good mechanical properties, and very suited for e.g. biomedical applications. The invention further relates to a process for converting polyolefin fibres into a semi-finished or end-use product.

Abstract: The present invention provides a laminate structure. The laminate structure includes a peripheral edge, an internal edge or both. Trim can be provided at the edges.

Abstract: A resin film of a two-layer-construction comprising: (a) a resin layer R1 including a non-stretched resin film which contains a thermoplastic polyester resin containing 3 to 30 percent by weight in a weight fraction in the entire resin of a granular resin with a grain diameter of 0.1 to 5 ?m, the granular resin being a modified polyolefin resin containing 2 to 20 percent by weight of a functional group derived from carboxylic acid in terms of carboxylic acid, and (b) a polyester resin layer R0 containing at least one of polyethylene terephthalate and isophthalic acid copolymerized polyethylene terephthalate, as a basic skeleton, wherein the resin layer R1 and the resin layer R2 are laminated to each other.