Abstract: Disclosed is a battery with reduced contact resistance at the contact surfaces between the separator and the electrodes, a battery separator capable of reducing contact resistance with the electrodes, and a production method thereof. The battery includes a positive electrode, a negative electrode, a separator interposed therebetween, and an electrolyte. The separator has a matrix structure of nanofibers formed by electrospinning and has a form of a sheet having a first surface and a second surface opposite thereto. When the average maximum fiber diameter of the nanofibers in the plane direction of the separator is compared between in vicinities of the first and second surfaces and at a center portion in the thickness direction of the separator, average maximum fiber diameters Ds1 and Ds2 of the nanofibers in the vicinity of the first and second surfaces are smaller than an average maximum fiber diameter Dc of the nanofibers at the center portion in the thickness direction of the separator.

Abstract: The present invention provides an all ceramics solid oxide cell, comprising an anode layer, a cathode layer, and an electrolyte layer sandwiched between the anode layer and the cathode layer, wherein the electrolyte layer comprises doped zirconia and has a thickness of from 40 to 300 ?m; wherein the anode layer and the cathode layer both comprise doped ceria or both comprise doped zirconia; and wherein the multilayer structure formed of the anode layer, the electrolyte layer and the cathode layer is a symmetrical structure. The present invention further provides a method of producing said solid oxide cell.

Abstract: Thin-film solid state batteries architectures and methods of manufacture are provided. Architectures include solid-state batteries with one or more cathodes, electrolytes, anodes deposited onto a substrate. Architectures may be used for solid state lithium batteries. The various fabrication techniques may be used to create a solid state battery is millimeters thick or smaller. These thin-film batteries may be small, light, and have a high energy density.

Abstract: A battery cell assembly is provided. The battery cell assembly includes a cooling fin having first and second plate portions and a first thermally conductive layer. The first and second plate portions are coupled to one another and extend longitudinally along a central axis. The first plate portion has a first thickness. The second plate portion has a second thickness greater than the first thickness. The first thermally conductive layer is disposed on a first outer surface of the first plate portion. The cooling fin thermally communicates with the cooling plate. The battery cell assembly further includes a first battery cell disposed against the first thermally conductive layer and the second plate portion of the cooling fin.

Abstract: Provided are a method of preparing an electrode assembly, in which both sides of a single current collector are coated to form an anode and a cathode, and the current collector is then bent into a vertical sectional zigzag shape and integrated in a state of disposing a separator at interfaces between facing electrode patterns, an electrode assembly prepared by the above method, and a secondary battery comprising the electrode assembly.

Abstract: Disclosed is a method of manufacturing a battery electrode in which a positive electrode lead tab and a negative electrode lead tab each of which is integrally formed with a collector formed of a metal foil and has excellent characteristics. The method includes separating a battery electrode having a desired size from a strip-shaped electrode in which an active material is intermittently applied onto a collector. The strip-shaped electrode includes an n-th application part, an n-th non-application part adjoining the n-th application part, and an (n+1)-th application part that adjoins the n-th non-application part on an opposite side at which the n-th application part adjoins the n-th non-application part (n is a positive integer). The battery electrode is cut out from the strip-shaped electrode, including at least the n-th application part, n-th non-application part, and (n+1)-th application part.

Abstract: Provided is a jelly-roll type electrode assembly pattern-coated with active materials manufactured by winding and compressing a separator and an anode and a cathode arranged on both sides of the separator. The anode includes anode flat coated portion coated with an anode active material and anode curved uncoated portion not coated with the anode active material, which are alternately formed. The cathode includes a cathode flat coated portion coated with a cathode active material and a cathode curved uncoated portion not coated with the cathode active material, which are alternately formed.

Abstract: A method of manufacturing a solid type secondary battery and a solid type secondary battery manufactured using the same, in which positive and negative electrodes include silicon carbide and silicon nitride, nonaqueous electrolyte includes ion exchange resin or ion exchange inorganic substance, the method including the steps of manufacturing a positive electrode print layer 2, a negative electrode print layer 3, and a nonaqueous electrolyte print layer 4 by mixing each pigment powder of 100 parts by weight for materials of the positive electrode layer, the negative electrode layer, and the nonaqueous electrolyte layer with water-soluble silicon resin of 1 to 50 parts by weight and water of 10 to 100 parts by weight; sequentially performing layered printing for each print layer; and drying the stack.

Abstract: Disclosed is a method for manufacturing a separator. The method includes (S1) preparing a porous planar substrate having a plurality of pores, (S2) preparing a slurry containing inorganic particles dispersed therein and a polymer solution including a first binder polymer and a second binder polymer in a solvent, and coating the slurry on at least one surface of the porous substrate, (S3) spraying a non-solvent incapable of dissolving the second binder polymer on the slurry, and (S4) simultaneously removing the solvent and the non-solvent by drying. According to the method, a separator with good bindability to electrodes can be manufactured in an easy manner. In addition, problems associated with the separation of inorganic particles in the course of manufacturing an electrochemical device can be avoided.

Abstract: Provided are a lithium secondary battery including a cathode, an anode, a separator, and a gel polymer electrolyte, wherein the gel polymer electrolyte includes an acrylate-based polymer and a charge voltage of the battery is in a range of 4.3 V to 5.0 V, and a method of preparing the lithium secondary battery. A high-voltage lithium secondary battery of the present invention has excellent capacity characteristics at a high voltage of 4.3 V or more.

Abstract: A lithium-ion battery having an anode including an array of nanowires electrochemically coated with a polymer electrolyte, and surrounded by a cathode matrix, forming thereby interpenetrating electrodes, wherein the diffusion length of the Li+ ions is significantly decreased, leading to faster charging/discharging, greater reversibility, and longer battery lifetime, is described. The battery design is applicable to a variety of battery materials. Methods for directly electrodepositing Cu2Sb from aqueous solutions at room temperature using citric acid as a complexing agent to form an array of nanowires for the anode, are also described. Conformal coating of poly-[Zn(4-vinyl-4?methyl-2,2?-bipyridine)3](PF6)2 by electroreductive polymerization onto films and high-aspect ratio nanowire arrays for a solid-state electrolyte is also described, as is reductive electropolymerization of a variety of vinyl monomers, such as those containing the acrylate functional group.

Abstract: A power storage device with favorable battery characteristics and a manufacturing method thereof are provided. The power storage device includes at least a positive electrode and a negative electrode provided so as to face the positive electrode with an electrolyte provided therebetween. The positive electrode includes a collector and a film containing an active material over the collector. The film containing the active material contains LieFefPgOh satisfying relations 3.5?h/g?4.5, 0.6?g/f?1.1, and 0?e/f?1.3 and LiaFebPcOd satisfying relations 3.5?d/c?4.5, 0.6?c/b?1.8, and 0.7?a/b?2.8. The film containing the active material contains the LiaFebPcOd satisfying the relations 3.5?d/c?4.5, 0.6?c/b?1.8, and 0.7?a/b?2.8 in a region which is in contact with the electrolyte.

Abstract: A system and method of forming a thin film battery includes a substrate, a first current collector formed on the substrate, a cathode layer formed on a portion of the first current collector, a solid layer of electrolyte material formed on the cathode layer, a silicon-metal thin film anode layer formed on the solid layer of electrolyte material and a second current collector electrically coupled to the silicon-metal thin film anode layer. A method and a system for forming the thin film battery are also disclosed.

Abstract: A method is disclosed for producing a battery with a metallic housing and an electrical insulation layer covering the outside of the housing. The method includes: providing a metallic housing or housing part for a battery; corona treating the outside of the housing or of the housing part, with simultaneous extraction of the gases and particles which arise; and applying the electrical insulation layer onto the treated outside of the housing or housing part.

Abstract: The present invention provides a method of manufacturing a cell separator in which a protective layer mainly composed of at least one type of granular ceramic is formed on a surface of a porous sheet base material. The method includes preparation of a water-based paste obtained by mixing a solid material containing the granular ceramic and a binder with an aqueous solvent to which at least one type of alcohol has been added, and formation of a protective layer in a state in which the alcohol has been eliminated by coating the prepared water-based paste onto a surface of the porous sheet base material, and further includes formation of the protective layer so that the solids content in the protective layer is higher than the solids content in the water-based paste by an amount of elimination of the alcohol, and is at least 55% by mass.

Abstract: This invention relates to a method of manufacturing an electrode for a secondary battery, which enables cost savings and the manufacture of products having various sizes and shapes. The method includes (A) preparing an electrode plate, (B) cutting the electrode plate to conform to the width of the electrode, thus providing a unit electrode plate, and (C) removing at least one of the corner regions of the unit electrode plate.

Abstract: A multi-functional, laminated composite comprises a plurality of cloth layers (3) penetrated by an infused matrix, wherein at least one cell (1) for energy storage is supported by and integrally built up from at least one of the cloth layers (3), the cell (1) being embedded in the matrix. The cell may comprise first and second electrodes (6,7) separated by a porous, separator layer (2) that has a liquid electrolyte-permeable, matrix-free intra-electrode region to which the electrolyte (2?) may be added before or after resin infusion to activate the cell. The structural composite may have integrated energy storage comprising a lithium-ion rechargeable cell, optionally of printed construction.

Abstract: A battery-dedicated electrode foil (32) includes an aluminum electrode foil (33) in which metal aluminum is exposed, and corrosion-resistant layers (34A, 34B) that are formed on surfaces (33a, 33b) of the aluminum electrode foil, and that are in direct contact with the metal aluminum that forms the aluminum electrode foil, and that is made of tungsten carbide.

Abstract: The present invention relates to methods for forming one or more thin film layers on a substrate, to form a multilayer product such as a lithium battery cell. The method involves passing a gas stream comprising at least one doping agent and at least one entrained source material through a plasma; impinging the gas stream on a substrate; and reactively depositing the at least one doping agent, and the at least one entrained source material on the substrate. The present invention provides a method of fabricating a power cell having a plurality of layers, and a method of fabricating a battery by electrically connecting a current collecting layer of a first power cell to a current collecting layer of a second power cell.

Abstract: A durable electrode material suitable for use in Li ion batteries is provided. The material is comprised of a continuous network of graphite regions integrated with, and in good electrical contact with a composite comprising graphene sheets and an electrically active material, such as silicon, wherein the electrically active material is dispersed between, and supported by, the graphene sheets.

Abstract: Disclosed is a positive electrode material for nonaqueous electrolyte secondary batteries, which comprises a porous body composed of a material containing a polyanion. Also disclosed is a method for producing such a positive electrode material for nonaqueous electrolyte secondary batteries. When a carbon coating is formed on the surface of a material containing a polyanion of lithium iron phosphate or the like by a conventional method, the capacity during low rate discharge is improved but the capacity is not sufficient. In the present invention, the positive electrode material for nonaqueous electrolyte secondary batteries, which comprises a porous body composed of a material containing a polyanion, has a structure wherein the inner walls of the pores of the porous body are provided with a layered carbon, for improving the discharge capacity.

Abstract: A negative-electrode active material layer having a line-and-space structure is formed by applying an application liquid containing a negative-electrode active material in stripes on a surface of a negative-electrode current collector using a nozzle-scan coating method and drying the application liquid (Steps S101, S102). Subsequently, by a spin coating method, an application liquid containing a solid electrolyte material is applied (Step S103) and heated at a temperature lower than a glass-transition temperature of the electrolyte material to be dried. Further, an application liquid containing a positive-electrode active material is applied (Step S105) and a positive-electrode current collector is laminated (Step S106) and, then, a laminated body is heated to or above the glass-transition temperature of the electrolyte material to cause the solid electrolyte to flow and adhere to the active material layers.

Abstract: A fuel cell comprises at least two current collectors, an electrically insulating separator element and solid electrolyte. Each current collector comprises at least one transverse passage passing through it from a first surface to a second surface and the separator element comprising opposite first and second faces is arranged between the current collectors. A plurality of transverse channels pass through the separator element from the first face to the second face and the ionically conducting solid electrolyte occupies the volume bounded by the channels of the separator element and by the passages of the current collectors. The separator element is formed by a thermoplastic polymer material and hard particles are arranged in the transverse channels.

Abstract: A lithium secondary battery provided by the present invention includes a spirally wound electrode body in which a positive electrode sheet and a negative electrode sheet are spirally wound with a separator sheet 40 interposed therebetween, wherein on a sheet surface of at least any one from among the positive electrode sheet, negative electrode sheet, and separator sheet 40 constituting the spirally wound electrode body, a porous layer 60 is formed along a longitudinal direction of the sheet 40, and the porous layer 60 is thicker in a spiral winding direction of the spirally wound electrode body in a winding center portion 62 than in a winding outer portion 64.

Abstract: A lithium ion (Li-ion) battery cell includes a prismatic housing that includes four sides formed by side walls coupled to and extending from a bottom portion of the housing. The housing is configured to receive and hold a prismatic Li-ion electrochemical cell element. The housing includes an electrically nonconductive polymeric (e.g., plastic) material. Additionally, a heat sink is overmolded by the polymeric material of the housing, such that the heat sink is retained in an outer portion of the sides of the housing and the heat sink is exposed along the bottom portion of the housing.

Abstract: Methods for reductively polymerizing vinylic based monomers from a solution thereof onto the surface of an electrode material, resulting in thin, electrically insulating solid-polymer electrolyte coatings strongly bound to the surface of the electrode material, are described. The strong bond permits a second electrode to be coated directly onto the solid-polymer electrolyte, thereby incorporating the required components for a Li-ion battery cell. At least one initiator species, which is readily reduced by accepting an electron from the electrode material, is included in electropolymerization deposition solution for permitting the polymerization of vinylic species that would otherwise not electrochemically polymerize without damage to either the electrode material or to the solvents employed.

Abstract: Provided is an electric storage device including a positive electrode, a negative electrode, a separator disposed between the positive electrode and the negative electrode, a nonaqueous electrolyte solution in which an electrolyte is dissolved in a nonaqueous solvent, wherein an inorganic filler layer is disposed between the positive electrode and the negative electrode and the nonaqueous electrolyte solution contains lithium difluorobis(oxalato)phosphate.

Abstract: Electrodes and methods of forming electrodes are described herein. The electrode can be an electrode of an electrochemical cell or battery. The electrode includes a current collector and a film in electrical communication with the current collector. The film may include a carbon phase that holds the film together. The electrode further includes an electrode attachment substance that adheres the film to the current collector.

Abstract: Provided is a secondary battery with improved safety through filling a polymer in a hardened state, and a method of manufacturing the same. The method of manufacturing a secondary battery according to the present disclosure includes preparing a polymer slurry by adding a polymer particle to an electrolyte solution, injecting the polymer slurry to a battery casing in which an electrode assembly is received, changing the polymer slurry to a polymer solution by heating the battery casing, and hardening the polymer solution by cooling the battery casing.

Abstract: Active material for a negative electrode of a rechargeable zinc alkaline electrochemical cell is made with zinc metal particles coated with tin and/or lead. The zinc particles may be coated by adding lead and tin salts to a slurry containing zinc particles, a thickening agent and water. The remaining zinc electrode constituents such as zinc oxide (ZnO), bismuth oxide (Bi2O3), a dispersing agent, and a binding agent such as Teflon are then added. The resulting slurry/paste has a stable viscosity and is easy to work with during manufacture of the zinc electrode. Further, the zinc electrode is much less prone to gassing when cobalt is present in the electrolyte. Cells manufactured from electrodes produced in accordance with this invention exhibit much less hydrogen gassing, by as much as 60-80%, than conventional cells. The cycle life and shelf life of the cells is also enhanced, as the zinc conductive matrix remains intact and shelf discharge is reduced.

Abstract: A positive electrode (1) has a positive electrode current collector, and a positive electrode mixture layer formed on at least one surface of the positive electrode current collector. The positive electrode mixture layer contains a positive electrode active material, a water-based binder, and a conductive agent. The positive electrode active material includes a lithium-transition metal composite oxide having an erbium compound adhered to a surface of the lithium-transition metal composite oxide, and the water-based binder includes a latex rubber.

Abstract: An electrode of an energy storage device with less deterioration by charge and discharge can be manufactured. In addition, an energy storage device which has large capacity and high endurance can be manufactured. A manufacturing method of an electrode of an energy storage device is provided in which a high-wettability regions and a low-wettability region are formed at a surface of a current collector, a composition containing silicon, germanium, or tin is discharged to the high-wettability regions and then baked to form separate active materials over a surface of the current collector. Thus, an electrode of an energy storage device with less deterioration due to charge and discharge can be manufactured.

Abstract: Provided is a rechargeable lithium battery that includes a positive electrode including a positive active material; a negative electrode including a negative active material; a separator interposed between the positive electrode and the negative electrode; and an electrolyte solution, wherein the positive active material includes lithium metal oxide and a compound represented by the following Chemical Formula 1 and coated on a surface of the lithium metal oxide, and the separator includes a porous substrate and a coating layer including ceramic and disposed on at least one side of the porous substrate. Li1+xAlxM2?x(PO4)3??[Chemical Formula 1] In Chemical Formula 1, M is at least one metal selected from Ti, Cr, Ga, Fe, Sc, In, Y, Mg, and Si, and 0<x?0.7.

Abstract: Disclosed is a lithium battery, including a positive electrode plate, a negative electrode plate, and a polyolefin separator disposed therebetween. An organic-inorganic hybrid film disposed between the polyolefin separator and the positive electrode plate, and/or disposed between the polyolefin separator and the negative electrode plate. The organic-inorganic hybrid film includes inorganic oxide particles and a fluorinated polymer binder, wherein the inorganic oxide particles and the fluorinated polymer binder have a weight ratio of about 40:60 to 80:20.

Abstract: A battery system comprises a plurality of substantially planar layers extending over transverse areas. The plurality of layers comprises at least one cathode layer, at least one anode layer, and at least one separator layer therebetween.

Abstract: The first aspect of the present invention provides a method of manufacturing an active material capable of improving the discharge capacity of a lithium-ion secondary battery. The method of manufacturing an active material in accordance with the first aspect of the present invention comprises the steps of heating a phosphate source, a vanadium source, and water so as to form an intermediate containing phosphorus and vanadium and having a specific surface area of at least 0.1 m2/g but less than 25 m2/g; and heating the intermediate, a water-soluble lithium salt, and water. The second aspect of the present invention provides a method of manufacturing an active material capable of improving the rate characteristic of a lithium-ion secondary battery.

Abstract: The present invention provides a positive electrode (30) for lithium secondary batteries, including: a barrier layer, having a conductive material and at least one type of water-insoluble polymer that is soluble in organic solvents but insoluble in water, as a binder; and a positive electrode active material layer, being a positive electrode active material layer (35) stacked on the barrier layer, and having a positive electrode active material and at least one type of aqueous polymer that is insoluble in organic solvents but soluble or dispersible in water, as a binder. A content of the water-insoluble polymer in the barrier layer is 55 to 85 mass % with respect to 100 mass % of a total amount of the conductive material plus the water-insoluble polymer.

Abstract: When a bipolar battery is manufactured, a bipolar electrode and a separator are prepared first. Then, one electrode (for example, a positive electrode) out of positive and negative electrodes is applied with such an amount of electrolyte as being exposed on a surface of the one electrode. Then, the separator is arranged on the surface of the one electrode applied with the electrolyte, thus forming a sub-assembly unit. Then, a plurality of the sub-assembly units are layered, and the electrolyte applied to the one electrode is made to permeate through the separator to the other electrode, thus forming an assembly unit.

Abstract: Preparation process of electrode for battery, comprising first application step for forming first linear part by relatively moving first nozzle which discharges first active material linearly with respect to current collector to form a plural of first linear parts on current collector, first drying step for drying first linear parts, second application step for forming second linear part between first linear parts by relatively moving second nozzle which discharges second active material with respect to current collector, and second drying step for drying first linear part and second linear part, wherein height H1 of first linear part and height H2 of second linear part satisfies the relational inequality (1): H1<H2. The active material layer has high aspect ratio, and gives lithium ion secondary battery excellent in high charge-discharge performance.

Abstract: Provided are a substrate on which carbon nanotubes each having one end connected to the substrate can be formed at a high synthetic rate and from which the carbon nanotubes are less likely to be peeled off. The substrate is a substrate for forming the carbon nanotubes and includes a buffer layer 13 formed on at least one of surfaces of a substrate main body 14 and containing aluminum atoms and fluorine atoms. The carbon nanotube complex includes the substrate and a plurality of carbon nanotubes 11 each having one end connected to a surface of the buffer layer 13.

Abstract: An electrolyte for a rechargeable lithium battery that includes a lithium salt and a non-aqueous organic solvent including a compound represented by the following Chemical Formula 1 is described: The compound represented by Chemical Formula 1 is included at greater than or equal to 0.001 volume % and less than 1 volume % based on a total volume of the non-aqueous organic solvent. A rechargeable lithium battery including the electrolyte is also described.

Abstract: Provided is a method of producing a silicon material, comprising: slicing a silicon substrate with a fixed-abrasives wire to obtain a mixing slurry; and treating the mixing slurry by solid-liquid separation, so as to isolate a silicon material from the mixing slurry, which is applicable for a lithium-ion battery. With the simplified method, the production cost of silicon material is remarkably reduced. Furthermore, an anode material of a lithium-ion battery and a method of producing an anode electrode of a lithium-ion battery are provided. Since the silicon material produced by the method has high purity and fine granules, the extreme volumetric expansion of silicon under heat is largely reduced, and thus the cycle stability, electrical performance, and quality of a lithium-ion battery comprising the silicon material are improved.

Abstract: A three-chamber eletrochemical cell comprises a central chamber, two lateral chambers, and a central part for conveying a fluid solution into and out from the central chamber, the central part being symmetric with respect to a mid-plane of the cell.

Abstract: In a lithium ion secondary battery, a negative electrode sheet is made of a metal foil and an active material layer containing active material particles. The negative active material layer includes a facing portion that faces a positive active material layer and a non-facing portion that does not face the same. The negative active material particles can be oriented in a magnetic field direction. When an angle between an extending direction of a major axis of the cross section of each particle and the metal foil is ?, the number of particles with the angle ? of 60°-90° is MA, the number of negative active material particles with the angle ? of 0°-30° is MB, and a value MA/MB is assumed to be an orientation degree (AL) of particles, the negative active material layer is made such that an orientation degree (AL1) in the non-facing portion is 1.2 or more.

Abstract: Provided is a method of producing a silicon-containing composition in mass production, comprising steps of: slicing a silicon substrate with a free-abrasive wire to obtain a mixing slurry; separating the mixing slurry into a liquid mixture and a solid mixture; and sorting the solid mixture by particle size and removing the cutting wire granules from the solid mixture, so as to obtain the silicon-containing composition applicable for a lithium-ion battery. Furthermore, an anode material of a lithium-ion battery and a method of producing an anode electrode of a lithium-ion battery are provided. According to the method, a few abrasives of the wire sawing tool remain in the nano-scale or micro-scale silicon-containing composition, and thus the problems of extreme volumetric expansion under heat and high production cost are overcome. The produced silicon-containing composition is applicable for a lithium-ion battery.

Abstract: An exemplary manufacturing method for a battery is provided in the present invention. The manufacturing method includes step S1: providing a high polymer solution; step S2: providing a negative-electrode structure; step S3: providing a separation structure; step S4: assembling the negative-electrode and the separation structure into a housing; and step S5: inserting a current collector into the housing and filling a positive-electrode material therein to form a positive-electrode structure. At least one of the negative-electrode structure and the positive-electrode structure comprise chlorophyll. Thus, the manufacturing process of the battery is simple, and economical, and natural and non-toxic substances are used. Unlike the manufacturing process of conventional batteries, the battery manufactured according to embodiments of the present invention will not cause environmental pollution even when it is discarded after being used.

Abstract: The invention relates to a microbattery that comprises a stack on a substrate, covered by an encapsulation layer and comprising first and second current collector/electrode assemblies, a solid electrolyte and electrical connections of the second current collector/electrode assembly to an external electrical load. The electrical connections are formed by at least two electrically conductive barriers passing through the encapsulation layer from an inner surface to an outer surface of the encapsulation layer. Each of the barriers has a lower wall in direct contact with a front surface of the second current collector/electrode assembly and an upper wall opening onto the outer surface of the encapsulation layer. The barriers form a compartmentalization network within the encapsulation layer.

Abstract: An electrochemical apparatus (e.g. a battery (cell)) including an aqueous electrolyte and one or two electrodes (e.g., an anode and/or a cathode), one or both of which includes a Prussian Blue analogue (PBA) material of the general chemical formula AxP[R(CN)6-jLj]z.nH2O, where: A is a cation; P is a metal cation; R is a transition metal cation; L is a ligand that may be substituted in the place of a CN? ligand; 0?x?2; 0?z?1; and 0?n?5, one or both electrodes including a PBA coating to decrease capacity loss.

Abstract: An electrochemical device (e.g., a battery (cell)) including: an aqueous electrolyte and one or two electrodes (e.g., an anode and/or a cathode), one or both of which is a Prussian Blue analogue material of the general chemical formula AxP[R(CN)6-jLj]z.nH2O, where: A is a cation; P is a metal cation; R is a transition metal cation; L is a ligand that may be substituted in the place of a CN? ligand; 0?x?2; 0?z?1; and 0?n?5, the electrode including a polymer coating to reduce capacity loss.

Abstract: Electrode structures and methods of formation are provided. The formation process may include an initial high rate discharge to precondition the electrode active surface. The resulting electroactive surface may have reduced pitting and defects resulting in more uniform utilization of the electrode during subsequent cycling.