Oxide Containing Patents (Class 419/19)
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Patent number: 4871437Abstract: Cermet electrode compositions and methods for making are disclosed which comprise NiO--NiFe.sub.2 O.sub.4 --Cu--Ni. Addition of an effective amount of a metallic catalyst/reactant to a composition of a nickel/iron/oxide, NiO, copper, and nickel produces a stable electrode having significantly increased electrical conductivity. The metallic catalyst functions to disperse the copper and nickel as an alloy continuously throughout the oxide phase of the cermet to render the electrode compositon more highly electrically conductive than were the third metal not present in the base composition. The third metal is preferably added to the base composition as elemental metal and includes aluminum, magnesium, sodium and gallium. The elemental metal is converted to a metal oxide during the sintering process.Type: GrantFiled: November 3, 1987Date of Patent: October 3, 1989Assignee: Battelle Memorial InstituteInventors: Steven C. Marschman, Norman C. Davis
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Patent number: 4871394Abstract: Sintered copper friction facing suitable for operation in oil and quieter in operation than current facing of this type has a void volume not less than 30% of the total volume. It can be made by employing, as the copper to form the facing matrix, copper powder which is in dendritic form and of apparent density not greater than 1.3 gram/cm.sup.3.Type: GrantFiled: November 8, 1988Date of Patent: October 3, 1989Assignee: Ferodo LimitedInventors: Ralph Baker, Stephen N. Foulkes
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Patent number: 4871438Abstract: Cermet electrode compositions comprising NiO-NiFe.sub.2 O.sub.4 -Cu-Ni, and methods for making, are disclosed. Addition of nickel metal prior to formation and densification of a base mixture into the cermet allows for an increase in the total amount of copper and nickel that can be contained in the NiO-NiFe.sub.2 O.sub.4 oxide system. Nickel is present in a base mixture weight concentration of from 0.1% to 10%. Copper is present in the alloy phase in a weight concentration of from 10% to 30% of the densified composition. Such cermet electrodes can be formed to have electrical conductivities well in excess of 100 ohm.sup.-1 cm.sup.-1. Other alloy and oxide system cermets having high content metal phases are also expected to be manufacturable in accordance with the invention.Type: GrantFiled: November 3, 1987Date of Patent: October 3, 1989Assignee: Battelle Memorial InstituteInventors: Steven C. Marschman, Norman C. Davis
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Patent number: 4863683Abstract: A manufacturing method for a multilayered ceramic body using Cu, Ni, Co or Fe as a conductor material, and a conductor forming paste of particular composition of CuO, NiO, CoO or Fe.sub.2 O.sub.3 as the main component, the paste being applied to the multilayered body. The manufacturing method comprises: a process of forming the multilayered body with conductor paste of CuO, NiO, CoO or Fe.sub.2 O.sub.3 as the main component and insulating paste formed of glass and/or ceramic, so that a binder is removed from the laminate by heat treatment in an oxidizing atmosphere; a process of heat treatment for reducing the oxide; and a sintering process for sintering the laminate in a nitrogen atmosphere.Type: GrantFiled: June 24, 1987Date of Patent: September 5, 1989Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Seiichi Nakatani, Satoru Yuhaku, Hideyuki Okinaka, Toru Ishida, Osamu Makino, Tatsuro Kikuchi
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Patent number: 4861372Abstract: Disclosed is a roller for use in a rotary compressor, which roller comprising a sintered body consisting essentially of 0.5-2.0% by weight of C, 1.0-5.0% by weight of Cu, 0.5-3.5% by weight of Cr, 0.1-1.0% by weight of Co, 0.1-1.0% by weight of W and a balance Fe and unavoidable impurities. Hard particles of Cr-Co-W alloy are dispersed in one of pearlitic and tempering martensitic matrix, and sintered pores of the sintered body are sealed with tri-iron tetroxide. Resultant sintered body has high wear resistance and scuffing resistance capable of being used as an inverter type compressor.Type: GrantFiled: November 14, 1988Date of Patent: August 29, 1989Assignee: Nippon Piston Ring Co., Ltd.Inventor: Soichi Shimomura
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Patent number: 4859239Abstract: An electrode, and method of producing same, including tungsten which has been heated in wet hydrogen at 1050.degree. C. for 5 to 10 minutes, then heated at about 1500.degree. C. for about three hours in a vacuum, and then further heated at about 2800.degree. C. for about 5 minutes in a vacuum.Type: GrantFiled: December 20, 1988Date of Patent: August 22, 1989Assignee: GTE Products CorporationInventor: Edmund M. Passmore
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Patent number: 4859238Abstract: Electrical contacts are formed from a silver-iron material which contains 3 to 30% by weight of iron and one or more of the components manganese, copper, zinc, antimony, bismuth oxide, molybdenum oxide, tungsten oxide or chromium nitride in amount totalling 0.05 to 5 weight percent, the balance being silver. These materials are suitable for forming electrical contacts of a wide variety. Tantalum is an optional component which may also be utilized particularly when 0.2 percent to 2 percent zinc is present.Type: GrantFiled: June 3, 1988Date of Patent: August 22, 1989Assignee: Degussa AktiengesellschaftInventors: Wolfgang Weise, Roger Wolmer, Peter Braumann
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Patent number: 4851188Abstract: An abrasive, wear resistant layer is applied to the tip surface of a superalloy gas turbine blade by high temperature sintering operation which produces a high strength bond between the layer and the blade, minimizes gamma prime phase growth, and prevents recrystallization in the blade. Important features of the invention include removing plastic strain damage from the tip surface prior to the sintering operation, using induction heating techniques to sinter a layer of metal powder particles and ceramic particulates to the blade tip surface, and shielding the airfoil and root portion of the blade from the radiant heating source during the sintering operation while at the same time, conductively removing heat from the blade.Type: GrantFiled: December 21, 1987Date of Patent: July 25, 1989Assignee: United Technologies CorporationInventors: Robert P. Schaefer, Walter F. Gustafson, David A. Rutz, Kenneth E. Taylor
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Patent number: 4847044Abstract: A softer metal such as aluminum, or a metal forming a metal aluminide, or an alloy containing these metals is added to a metal aluminide composite during fabrication to promote easy consolidation of the metal aluminide matrix with the reinforcing phase. The metal aluminide may be titanium aluminide, nickel aluminide, or iron aluminide. The softer metal, the metal aluminide matrix, and the reinforcing phase are pressed together at a temperature above the softening temperature of the softer metal. The softened metal promotes flow and consolidation of the matrix and the reinforcement at relatively low temperatures. The composite is held at an elevated temperature to diffuse and convert the soft metal phase into the metal aluminide matrix. By consolidating at a lower temperature, cracking tendencies due to thermal expansion differences between the matrix and reinforcement is reduced. By consolidating at a lower pressure, mechanical damage to the fibers is avoided.Type: GrantFiled: April 18, 1988Date of Patent: July 11, 1989Assignee: Rockwell International CorporationInventor: Amit K. Ghosh
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Patent number: 4838936Abstract: Spiral parts, such as orbiting and fixed scroll plates having involute wraps, for use in scroll compressors, the parts having low coefficient of thermal expansion and high tensile strength and Young's modulus, are formed by combining a self-lubricating power into aluminum raw material powder prior to compression and forging. As an alternative to and in conjunction with the foregoing, temperatures during preform heating and in the die for forging are controlled to be in respective ranges of 300.degree. to 500.degree. C. and 150.degree. to 500.degree. C. Aluminum alloy fine powder preferably has a particle diameter no larger than 350 .mu.m. The self-lubricating powder preferably forms 1 to 25% of the mix by volume, and contains at least one member selected from the group consisting of graphite, BN, and MoS.sub.2.Type: GrantFiled: May 23, 1988Date of Patent: June 13, 1989Assignee: Sumitomo Electric Industries, Ltd.Inventor: Kiyoaki Akechi
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Patent number: 4836978Abstract: A production method of a vacuum circuit breaker electrode comprises the steps of mixing conductive metal powder, and refractory material powder with a higher melting point than said conductive metal powder, compacting the resultant mixture to form a compact, presintering the compact in a atmosphere of high purity hydrogen, sealing a presintered body in a capsule while exhausting, heating and degassing, and subjecting the sealed capsule to hot isostatic pressing treatment. The conductive metal powder is one or both of Cu and Ag. The hot isostatic pressing treatment is effected at a temperature higher than a melting point of the conductive metal so that the presintered body is sintered under liquid phase, and a part of molten conductive metal component is seeped out on a sintered body surface.Type: GrantFiled: September 2, 1987Date of Patent: June 6, 1989Assignee: Hitachi, Ltd.Inventors: Ryuji Watanabe, Hisashi Andoh, Kiyoji Iwashita, Kinko Shimizu
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Patent number: 4834939Abstract: A silver base electrical contact material is described which contains a dispersion of particles consisting of cadmium oxide and nickel. The nickel particles are surrounded by a continuous adherent coating of nickel oxide which eliminates the detrimental reaction which would otherwise occur between nickel and cadmium oxide. The invention contact materials have improved lives and are fabricated by any one of several different powder metallurgy techniques.Type: GrantFiled: May 2, 1988Date of Patent: May 30, 1989Assignee: Hamilton Standard Controls, Inc.Inventor: Norman S. Bornstein
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Patent number: 4830930Abstract: There are disclosed a surface refined sintered alloy body which comprises a hard phase containing at least one selected from the group consissting of carbides, carbonitrides, carbooxides, carbonitrooxides of the metals of the groups 4a, 5a and 6a of the periodic table and a binding phase containing at least one selected from iron group metals, characterized in that the concentration of the binding phase in the surface layer (of from 10 .mu.m to 500 .mu.m from the surface of the sintered alloy) is highest at the outermost surface thereof and approaches the concentration of the inner portion, the concentration of the binding phase decreasing from the outermost surface to a point at least 5 .mu.m from the surface; and a method for making the same by applying decarburization treatment at the surface of the sintered alloy at temperatures within the solid-liquid co-existing region of the binding phase after sintering or in the process of sintering.Type: GrantFiled: April 7, 1988Date of Patent: May 16, 1989Assignee: Toshiba Tungaloy Co., Ltd.Inventors: Yasuro Taniguchi, Ko Sasaki, Mitsuo Ueki, Keiichi Kobori
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Patent number: 4812289Abstract: Refractory metal oxide particles are dispersed in an aluminum melt which is then cast to form a dispersion hardened aluminum alloy composition. A master mix of carrier metal particles surrounding individual oxide particles is pressed into a billet. The billet is dissolved in the melt in the presence of a wetting metal.Type: GrantFiled: December 7, 1987Date of Patent: March 14, 1989Assignee: Technical Research Assoc., Inc.Inventor: Guy B. Alexander
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Patent number: 4810289Abstract: A process of hot isostatic pressing of powders to form electrical contacts is characterized by the steps: (A) mixing powders, 1 in the Drawing, from metal containing powder or metal containing powder plus carbon powder, where at least one of Ag and Cu is present, (B) thermal cleaning treatment of the powder, 2 in the Drawing, (C) granulating the thermally treated powder, 3 in the Drawing, (D) uniaxially pressing the powders without heating, 5 in the Drawing, to provide a compact, (E) placing at least one compact in a pressure-transmitting, pressure-deformable container, 6 in the Drawing, and surrounding each compact with fine particles of a separating material, (F) evacuating air from the container, 7 in the Drawing, (G) sealing the compacts inside the container, 8 in the Drawing, (H) hot isostatic pressing, 9 in the Drawing, the compacts through the pressure transmitting material at a pressure from 352 kg/cm.sup.2 to 2,115 kg/cm.sup.2 and a temperature from 0.5.degree. C. to 100.degree. C.Type: GrantFiled: April 4, 1988Date of Patent: March 7, 1989Assignee: Westinghouse Electric Corp.Inventors: Norman S. Hoyer, Natraj C. Iyer
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Patent number: 4810463Abstract: Ceramic materials in the form of powdered .gamma.-Al.sub.2 O.sub.3 are surface modified by addition of the salts or oxides of nickel or tungsten prior to contact of the ceramic with polymer binder suspensions. The sintering and densification of said ceramic materials produces ceramic bodies substantially free from carbonaceous residues.Type: GrantFiled: September 12, 1986Date of Patent: March 7, 1989Assignee: Syracuse UniversityInventors: James A. Schwarz, Yao-Jyh R. Huang
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Patent number: 4793968Abstract: A sintered metal part which has a pressed and sintered core; the part is coated with a sintered metal surface layer; the layer has a property different from that of the metal part; the interior regions of the core are free of the metal constituting the coating; and process for making the parts.Type: GrantFiled: June 27, 1984Date of Patent: December 27, 1988Assignee: Sermatech International, Inc.Inventors: Mark F. Mosser, Bruce G. McMordie
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Patent number: 4793967Abstract: The present invention is directed to a cermet material comprising a matrix of aluminum alloy with ceramic particles distributed therein. The cermet is adapted for use as a semiconductor substrate and is manufactured using powder technology procedures. The cermet comprises from about 40 to about 60 volume % of aluminum or aluminum alloy, from an effective amount up to about 10 volume % of binder for enhancing bonding between the aluminum alloy and ceramic particles, and the balance essentially ceramic particles.Type: GrantFiled: December 31, 1987Date of Patent: December 27, 1988Assignee: Olin CorporationInventors: Michael J. Pryor, Eugene Shapiro, Deepak Mahulikar
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Patent number: 4793874Abstract: A permanent magnetic alloy essentially consists of 10 to 40% by weight of R, 0.1 to 8% by weight of boron, 50 to 300 ppm by weight of oxygen and the balance of iron, where R is at least one component selected from the group consisting of yttrium and the rare-earth elements.An alloy having this composition has a high coercive force .sub.I H.sub.C and a high residual magnetic flux density and therefore has a high maximum energy product.Type: GrantFiled: February 6, 1987Date of Patent: December 27, 1988Assignee: Kabushiki Kaisha ToshibaInventors: Tetsuhiko Mizoguchi, Koichiro Inomata, Toru Higuchi, Isao Sakai
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Patent number: 4781886Abstract: A method is disclosed for producing a high hardness refractory metal part, the method comprising hot isostatic pressing a refractory metal part having a density greater than about 98% of the theoretical density in the presence of a pressurizing gas having an atomic size great enough to strain the lattice of the refractory metal at a pressure to exceed the yield strength of the metal to result in the densification of the part to a density of greater than about 98% of the theoretical density. The part is then rapidly cooled. The resulting part has a hardness approaching the hardness of mechanically worked material.Type: GrantFiled: February 29, 1988Date of Patent: November 1, 1988Assignee: GTE Products CorporationInventors: Thomas J. Patrician, Vito P. Sylvester
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Patent number: 4780437Abstract: A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.Type: GrantFiled: February 11, 1987Date of Patent: October 25, 1988Assignee: The United States of America as represented by the United States Department of EnergyInventor: James L. Smith
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Patent number: 4777014Abstract: Self-supporting bodies are produced by reactive infiltration of a parent metal with a boron source typically resulting in a composite comprising a parent metal boride and metal. The mass to be infiltrated may contain one or more inert fillers admixed with the boron source to produce a composite by reactive infiltration, which composite comprises a matrix of metal and parent metal boride embedding the filler. The relative amounts of reactants and process conditions may be altered or controlled to yield a body containing varying volume percents of ceramic, metal and/or porosity.Type: GrantFiled: March 7, 1986Date of Patent: October 11, 1988Assignee: Lanxide Technology Company, LPInventors: Marc S. Newkirk, Michael K. Aghajanian, Danny R. White
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Patent number: 4776902Abstract: Compositions for the production of rare earth-ferromagnetic-metal permanent magnets comprise mixtures of rare earth-ferromagnetic metal alloy powder and a lesser amount of a powdered second-phase sintering aid, wherein there is added up to about 2 percent by weight of a particulate refractory oxide, carbide, or nitride additive. Permanent magnets are prepared by mixing the components, aligning the mixture in a magnetic field, pressing and sintering. The refractory material inhibits grain growth in the second phase during sintering, improving the magnetic properties of the major phase.Type: GrantFiled: April 28, 1986Date of Patent: October 11, 1988Assignee: Union Oil Company of CaliforniaInventor: Mohammad H. Ghandehari
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Patent number: 4775598Abstract: A process is described in which hollow spheres or hollow-sphere composites (moldings) having high-strength walls are produced. Additional layers are applied to metallized spherical lightweight particles having a core of foamed polymer. In order to increase the strength of the wall of the spherical particle and the strength of the molding, metallized lightweight spherical particles having a metal wall thickness of 5 to 20 microns are treated (coated) with a dispersion of particulate metal or metal oxide or particulate ceramic or refractory material, the lightweight spherical particles coated in a thickness from 15 to 500 microns are dried, the dried particles are heated to a temperature of about 400.degree. C. to effect a pyrolysis of the polymer core, and the particles are subsequently sintered at a temperature from 900.degree. to 1400.degree. C.Type: GrantFiled: November 25, 1987Date of Patent: October 4, 1988Assignee: Norddeutsche Affinerie AkitiengesellschaftInventor: Manfred Jaeckel
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Patent number: 4772449Abstract: A method of making a cathode suitable for an electrochemical cell of the type having a molten sodium anode, a beta"-alumina separator, and a cathode which comprises one or more transition metals selected from the group comprising Fe, Ni, Co, Cr and Mn. The method comprises heating a particulate starting material comprising at least one member of the group of transition metals in an oxidizing atmosphere to cause its particles to become at least partially oxidized, and to adhere together to form a unitary porous matrix. This matrix is then heated in a reducing atmosphere at least partially to reduce the oxide formed during the formation of the matrix, and the reduced matrix is then impregnated with a sodium aluminium chloride molten salt electrolyte. Sodium chloride in dispersed form is incorporated into the matrix, preferably by mixing sodium chloride in particulate form with the particulate transition metal starting material, before the heating in an oxidizing atmosphere to form the matrix.Type: GrantFiled: June 5, 1987Date of Patent: September 20, 1988Assignee: Lilliwyte Societe AnonymeInventors: Roger J. Bones, David A. Teagle, Stephen D. Brooker
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Patent number: 4770701Abstract: Amorphous metal-ceramic and microcrystalline metal-ceramic composites are synthesized by solid state reaction-formation methods. These metal-ceramic composites are characterized by a composition that ranges from about 75 to about 99.9 percent ceramic in about 0.1 to about 25 percent amorphous or microcrystalline metal binder phase.Type: GrantFiled: April 30, 1986Date of Patent: September 13, 1988Assignee: The Standard Oil CompanyInventors: Richard S. Henderson, Michael A. Tenhover
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Patent number: 4764341Abstract: The bonding of nickel, cobalt, copper or any number of metals to oxide ceramics is achieved whereby the substrate and associated metallurgy are co-sintered. The invention teaches the use of an intermediary oxide such as Al2O3, Cr2O3, TiO2 or ZrO2 which will adhere to the substrate and in the presence of firing ambients form a complex ternary oxide with the overlying metal thereby creating the desired bond. The eutectic can be created during the firing cycle without the undesired consequence of oxidizing the metal. The so-called intermediary oxides can be oxidized in situ, deposited as oxides, or introduced into either the ceramic composition or the metal paste.Type: GrantFiled: April 27, 1987Date of Patent: August 16, 1988Assignee: International Business Machines CorporationInventors: Philip L. Flaitz, Raj N. Master, Paul H. Palmateer, Srinivasa S. N. Reddy
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Patent number: 4756752Abstract: A method for forming a high density body from a powder material of metallic and non-metallic compositions and combinations thereof comprising confining a quantity of the powder material in a flexible mold structure, subjecting the powder material in the mold structure to a predetermined pressure along one axis while confining the material against movement in directions normal to the axis so as to form a compact body of the powder material and subsequently heating the compact body to a predetermined temperature so as to further compact the body. A quantity of glass is heated so that it will flow and transmit pressure following which the heated body is immersed in the heated glass and the flowable glass is subjected to a pressure high enough to further compact the body. The resulting densified body is uniformly compressed in the directions of three mutually perpendicular axes extending through the body.Type: GrantFiled: November 4, 1987Date of Patent: July 12, 1988Assignee: Star Cutter CompanyInventor: Lewis J. Barnard
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Patent number: 4756753Abstract: An aluminum matrix composite containing evenly dispersed reinforcement particles in the aluminum matrix wherein the contents of oxygen and carbon are controlled so that their volume percentage is not larger than 20% and wherein the contents of the reinforcement particles, oxygen and carbon are controlled so that their volume percentage is not larger than 40%. The control of oxygen and carbon is effected by carrying out the main process at a non-oxidizing atmosphere and minimizing the addition of an anti-seizure agent required to facilitate the mechanical alloying treatment.Type: GrantFiled: August 26, 1987Date of Patent: July 12, 1988Assignee: Showa Aluminum Kabushiki KaishaInventor: Tsunemasa Miura
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Patent number: 4752333Abstract: The invention concerns alloys comprising a matrix based on at least one conductor metal M, formed by a homogeneous dispersion in the matrix of stable coherent particles of one or more associations of ions of type M, M', O in which M represents the metal or metals of the matrix, M' represents a different metal from M, which is capable of undergoing internal oxidation, and O represents oxygen.It also concerns the process for the production of such alloys which comprises subjecting a starting alloy powder to the action of an oxidizing agent formed by a powder with a granulometry of the order of 1 .mu.m of a metal oxide capable by thermal decomposition of providing the oxygen necessary for the internal oxidization of M', the starting alloy being based on at least one metal M, if appropriate hardened by one or more elements R or A as defined hereinbefore.Use of such alloys for the electrical, electronic and connection arts.Type: GrantFiled: January 9, 1987Date of Patent: June 21, 1988Assignee: TrefimetauxInventors: Jules Caisso, Martine Cahoreau, Edmond Dedieu, Michel Grosbras
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Patent number: 4749545Abstract: This invention relates to metal matrix composites containing at least 40% v/v of a hard material such as SiC and a matrix of aluminium, magnesium or alloys of either. The invention also covers a method of making such composites by ball milling powders of the respective components. Other mixing techniques do not enable such a high proportion of hard material to be incorporated into the composite. The composites are useful to produce components resistant to wear.Type: GrantFiled: March 26, 1987Date of Patent: June 7, 1988Assignee: British Petroleum Co. p.l.c.Inventors: Alan R. Begg, Andrew D. Tarrant
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Patent number: 4743511Abstract: This invention provides a shaped, graded, cermet article comprising at least one continuous ceramic phase and at least one discontinuous metal phase, the ratio of ceramic/metal being controlled and varied over the thickness of the article. The ceramic phase preferably is microcrystalline.Type: GrantFiled: September 21, 1987Date of Patent: May 10, 1988Assignee: Minnesota Mining and Manufacturing CompanyInventors: Harold G. Sowman, David R. Kaar
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Patent number: 4724121Abstract: (1) A process comprising spray drying a powder-containing slurry, the slurry containing a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, while reducing the tendency for oxidation of the constituent by including as a liquid constituent of the slurry an organic liquid; (2) a process comprising spray drying a powder-containing slurry, the powder having been pretreated to reduce content of a powder constituent susceptible of oxidizing under the temperature conditions of the spray drying, the pretreating comprising heating the powder to react the constituent; and (3) a process comprising reacting ceramic powder, grinding the reacted powder, slurrying the ground powder, spray drying the slurried powder, and blending the dried powder with metal powder.Type: GrantFiled: April 25, 1985Date of Patent: February 9, 1988Assignee: Aluminum Company of AmericaInventor: John D. Weyand
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Patent number: 4722825Abstract: A method of producing a metal/ceramic composite structure in which an uncolidated metal or metal alloy powder is loaded into a sealable glass mold comprising a hollow ceramic sleeve and a sealable outer glass envelope surrounding the ceramic sleeve and forming with the outer wall of the ceramic sleeve a sealable chamber for the metal or metal alloy powder, wherein the glass is a type which becomes plastic when heated. The air in the mold is removed under vacuum and the mold is sealed and placed into a free flowing refractory powder in a crucible and consolidated by sintering under atmospheric pressure (CAP.RTM. process). Removal of the glass envelope leaves a composite article having a consolidated metal or metal alloy layer surrounding and placing a hollow ceramic liner (sleeve) under both radial and axial compression. A ceramic-line metal gun barrel insert can be produced by using a ceramic sleeve with rifling on its inner surface.Type: GrantFiled: July 1, 1987Date of Patent: February 2, 1988Assignee: The United States of America as represented by the Secretary of the NavyInventor: David Goldstein
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Patent number: 4722826Abstract: A method for utilizing a powder metallurgy ("P/M") slurry by employing water atomized metallic powders and subsequently reducing the oxide levels therein to acceptable levels. The slurry comprises a carbon containing binder. The slurry is consolidated and sintered under controlled conditions to reduce the oxide levels.Type: GrantFiled: September 15, 1986Date of Patent: February 2, 1988Assignee: Inco Alloys International, Inc.Inventor: Jon M. Poole
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Patent number: 4715892Abstract: The present invention is directed to a cermet material comprising a matrix of metal or alloy with ceramic particles distributed therein. The cermet includes a glass binder for bonding between the metal or alloy and the ceramic particles.Type: GrantFiled: October 30, 1986Date of Patent: December 29, 1987Assignee: Olin CorporationInventor: Deepak Mahulikar
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Patent number: 4714586Abstract: A method is disclosed for preparing a dimensionally stable electrode structure, particularly nickel-chromium anodes, for use in a molten carbonate fuel cell stack. A low-chromium to nickel alloy is provided and oxidized in a mildly oxidizing gas of sufficient oxidation potential to oxidize chromium in the alloy structure. Typically, a steam/H.sub.2 gas mixture in a ratio of about 100/1 and at a temperature below 800.degree. C. is used as the oxidizing medium. This method permits the use of less than 5 weight percent chromium in nickel alloy electrodes while obtaining good resistance to creep in the electrodes of a fuel cell stack.Type: GrantFiled: January 29, 1986Date of Patent: December 22, 1987Assignee: The United States of America as represented by the United States Department of EnergyInventors: Thomas E. Swarr, Wayne G. Wnuck
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Patent number: 4714468Abstract: A dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization containing a fine oxide dispersion, and characterized, after fabrication by gas atomization, thermomechanical processing and further high temperature exposure, by excellent corrosion resistance, high fatigue strength, high ductility and high temperature stability; a process for producing said alloy and prostheses formed from said alloy.Type: GrantFiled: January 27, 1987Date of Patent: December 22, 1987Assignee: Pfizer Hospital Products Group Inc.Inventors: Kathy K. Wang, Larry J. Gustavson, John H. Dumbleton
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Patent number: 4713215Abstract: The powdered material contains oxygen in the oxide and/or adsorbed form and the oxygen present is reduced in a first pre-sintering stage and the cohesion of the material is ensured in a second sintering stage. The pre-sintering stage is carried out under a reducing atmosphere based on hydrogen and neutral gas whose flow rate F.sub.G is higher than or equal to: ##EQU1## in which relation: S.sub.P =section of the layer of powder to be sintered in sq.mD.sub.P =voluminal mass of the powder in kg/cu mX(O.sub.2)i=percentage of oxygen mass in the powder before the pre-sintering stage, in the oxide and/or adsorbed form,P(H.sub.2)i=voluminal percentage of hydrogen in the gas introduced into the furnace,P(H.sub.2)f=the smallest voluminal percentage of hydrogen in the atmosphere in the furnace at a point where the oxides have been completely reduced,v.sub.S =speed of feed of the material in the furnace expressed in m/hr,.alpha. is a constantF.sub.G being expressed in cu.m/hr.Type: GrantFiled: May 15, 1987Date of Patent: December 15, 1987Assignee: L'Air LiquideInventor: Michel Madsac
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Patent number: 4707184Abstract: A gas permeable or porous article of irregular configuration comprising a sintered structure of dispersion strengthened metal or metal alloy particles. The present invention also relates to a novel method for making such article.Type: GrantFiled: May 31, 1985Date of Patent: November 17, 1987Assignee: SCM Metal Products, Inc.Inventors: Don H. Hashiguchi, Erhard Klar
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High speed steel sintering powder made from reclaimed grinding sludge and objects sintered therefrom
Patent number: 4705565Abstract: A method of producing a sintering powder made from high speed steel and alumina. This sintering powder is sinterable over a broader range of temperatures than conventional high speed steel sintering powders and at lower temperatures, thereby making sintered objects which are crack resistant and also highly wear resistant. Additionally, the sintering powder flows readily when poured into a mold for production of a green object for sintering.Type: GrantFiled: June 25, 1986Date of Patent: November 10, 1987Inventors: Robert J. Beltz, Joseph D. Dankoff -
Patent number: 4704251Abstract: Method for the production of a wear resistant part of a soil working tool comprising forming a mixture of 67-90% by volume of iron particles consisting of at least 97% Fe and 10-33% by volume of hard particles having a desired particle size distribution, and subsequently pressing the mixture at a pressure of at least 3500 kp/cm.sup.2 to form a compact, sintering the compact at a temperature of 900.degree.-1200.degree. C., and optionally sinter forging the sintered compact. The sintered part consists of an iron matrix in which hard particles with a predetermined particle size distribution are embedded.Type: GrantFiled: July 14, 1986Date of Patent: November 3, 1987Assignee: Teknologisk InstitutInventor: Ole Kr mer
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Patent number: 4701301Abstract: A process for producing an internal-oxidized alloy, which comprises allowing a plasma generated in the presence of oxygen, a gas of an oxygen atom-containing compound or a mixture of oxygen and a gas of an oxygen atom-containing compound to act on an alloy consisting of at least two metal elements, thereby selectively oxidizing at least one metal element other than the matrix metal in said alloy. Particles of the internal-oxidized alloy thus obtained can, if necessary, be molded into a desired shape and sintered. Said process enables one to produce an internal-oxidized alloy at a high speed at a temperature of not more than 0.9 Tm (Tm: the melting point of the starting alloy) and does not require the step of separating an internal-oxidizing agent which step is required in the conventional process.Type: GrantFiled: July 16, 1986Date of Patent: October 20, 1987Assignees: Japan Synthetic Rubber Co., Ltd., Applied Science Research InstituteInventors: Hideyuki Kuwahara, Bunji Kondo, Jun Takada, Kenji Yanagihara, Mituo Kimura, Masahiro Niinomi
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Patent number: 4693863Abstract: A powder metallurgy consolidation process and apparatus for carrying out said process produces integral metal bodies by heating metal powder of a predetermined composition to a temperature sufficient to cause solid state interparticle bonding, while simultaneously maintaining a reactive fluid in contact with the metal powder. The metal powder is compacted to a density greater than 90% of the full theoretical density of the composition after the reactive fluid has been removed. The reactive fluid is selected to modify the powder particle surface chemistry in order to improve bondability and to obtain other properties as desired. Metal bodies which have been consolidated by the process are sufficiently dense to be mechanically hot worked and exhibit exceptionally low retained gas content.Type: GrantFiled: April 9, 1986Date of Patent: September 15, 1987Assignee: Carpenter Technology CorporationInventors: Gregory J. Del Corso, Robert E. Carnes, David Esposito
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Patent number: 4689197Abstract: A denture with a metallic microstructure and with low shrinkage and porosity is produced by metallurgical sintering by providing a multimodal size distribution of coarse and fine fractions of metal powder, optionally also with glass or ceramic powder, converting this powder mixture with water into a slip, modelling the denture with this, and sintering the slip at a temperature which exceeds the solidus temperature of at least one component of the powder mixture.Type: GrantFiled: April 4, 1986Date of Patent: August 25, 1987Assignee: Degussa AktiengesellschaftInventors: Werner Groll, Josef Rothaut, Angela Klaus, Rudi Steinke
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Patent number: 4689077Abstract: A method is disclosed for manufacturing a reaction sintered composite article which comprises at least one ceramic component. The method comprises preparing a particulate mixture of precursor powders leading to the formation of said composite material upon reaction sintering, pressing said particulate mixture to a self-sustaining body, heating said body up to a temperature below the temperature at which the reaction sintering is initiated, comminuting the heat treating body, selecting particles of a suitable grain size distribution, pressing said particles into shapes of desired size and configuration, and heating said shapes up to a temperature at which the reaction sintering is initiated. The reaction sintered body comprises borides, carbides, nitrides or silicides of a transition metal of the groups IVb, Vb or VIb of the periodic table (comprising titanium, hafnium, zirconium, vanadium, niobium, tantalum, chromium, molybdenum and tungsten), and a metal oxide.Type: GrantFiled: May 19, 1986Date of Patent: August 25, 1987Assignee: ELTECH Systems CorporationInventors: Michel Chevigne, Dominique Darracq, Jean-Pol Wiaux
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Patent number: 4673435Abstract: An alumina composite body comprising a plurality of elongated alumina elements oriented in random directions and interconnected so as to constitute a porous matrix, and aluminum and silicon tightly filling the porous matrix; and a method of manufacturing an alumina composite body comprising reacting a body of silica, or a body of a silicon compound such as silicon carbide or silicon nitride which has been at least partially oxidized to produce silica, with aluminum so as to change the silica into alumina.Type: GrantFiled: April 24, 1986Date of Patent: June 16, 1987Assignee: Toshiba Ceramics Co., Ltd.Inventors: Masayoshi Yamaguchi, Kazunori Meguro, Shuitsu Matsuo, Yasumi Sasaki
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Patent number: 4668290Abstract: A dispersion strengthened cobalt-chromium-molybdenum alloy produced by gas atomization containing a fine oxide dispersion, and characterized, after fabrication by gas atomization, thermomechanical processing and further high temperature exposure, by excellent corrosion resistance, high fatigue strength, high ductility and high temperature stability; a process for producing said alloy and prostheses formed from said alloy.Type: GrantFiled: August 13, 1985Date of Patent: May 26, 1987Assignee: Pfizer Hospital Products Group Inc.Inventors: Kathy K. Wang, Larry J. Gustavson, John H. Dumbleton
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Patent number: 4661154Abstract: A process for the production by power metallurgy of a material based on an aluminum alloy, a solid lubricant and at least one ceramic is disclosed. The process is characterized by using a ceramic in powder form with a granulometry of between 1 and 10 .mu.m.This invention finds application in the manufacture of components which are subjected to friction, in particular under hot condition, such as engine liners. These components provide an optimum compromise coefficient of friction and resistance to seizure and wear.Type: GrantFiled: January 27, 1986Date of Patent: April 28, 1987Assignee: Cegedur Societe de Transformation de l'Aluminum PechineyInventor: Jean-Francois Faure
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Patent number: 4659547Abstract: The invention resides in a process of preparing an inhomogeneous sintered body by adjoining metal powder with refractory ceramic powder at normal powder metallurgical pressures and sintering conditions. The invention is characterized thereby that the sintered body is manufactured in one layer or several layers having displaced mixing ratio between the ceramics and the metal and that the binding between ceramics and metal is strengthened with monoaluminium phosphate or a monoaluminium phosphate former. The sintered body can be used for example as heat shielding.Type: GrantFiled: January 8, 1986Date of Patent: April 21, 1987Assignee: Hoganas ABInventors: Lars-Erik Svensson, Ove Thornblad