Oxide Containing Patents (Class 419/19)
  • Patent number: 5262398
    Abstract: A ceramic oxide superconductive composite material comprising a ceramic oxide superconductor and a non-superconductive material comprising at least one element which does not react with any of the elements of the ceramic oxide superconductor has improved superconductive properties such as a higher critical temperature and a larger critical current density.
    Type: Grant
    Filed: December 16, 1992
    Date of Patent: November 16, 1993
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Masayuki Nagata, Minoru Yokota, Ken-ichi Sato
  • Patent number: 5259860
    Abstract: A sintered metal part has a magnesium metasilicate mineral, or a magnesium metasilicate mineral and a magnesium orthosilicate mineral, or at least one of a magnesium metasilicate mineral and a magnesium orthosilicate mineral and at least one of boron nitride and manganese sulfide dispersed throughout the metal matrix. An iron-based sintered sliding member is of a structure that free graphite and an intercrystalline inclusion have been dispersed throughout the metal matrix that consists essentially of, in weight ratio, 1.5 to 4% of carbon, 1 to 5% of copper, 0.1 to 2% of tin, 0.1 to 0.5% of phosphorus, 0.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: November 9, 1993
    Assignee: Hitachi Powdered Metals Co., Ltd.
    Inventors: Yutaka Ikenoue, Ryoji Satoh, Koichiro Hayashi, Katsunao Chikahata
  • Patent number: 5234487
    Abstract: Tungsten-titanium sputter targets of at least 95% theoretical density are provided with little or no .beta.(Ti, W) phase constituent. Such targets will minimize troublesome particulate emissions during sputter coating conditions.
    Type: Grant
    Filed: April 15, 1991
    Date of Patent: August 10, 1993
    Assignee: Tosoh SMD, Inc.
    Inventors: Charles E. Wickersham, Jr., John J. Mueller
  • Patent number: 5223480
    Abstract: A novel method for forming homogeneous silver high temperature superconductor (HTS) composites. The novel method comprises a chemical coprecipitation of silver, barium, yttrium, and copper salts solutions, followed by calcination and milling processes. The novel method has an advantage of retaining all the virtues immanent in a composite HTS, for example, increased critical current density (Jc), and improved mechanical properties, while bypassing extant and deficient methodologies for forming a composite, the deficient composites characterized by heterogeneity.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: June 29, 1993
    Assignee: Eastman Kodak Company
    Inventors: Ashok K. Agarwala, Paul A. Christian, Kenneth B. Quinn
  • Patent number: 5199971
    Abstract: The present invention relates to parts, such as a drive gear and driven gear, for use in a rotary gear pump exhibiting good sliding characteristics against a pump case made of light metals such as aluminum alloys. These parts are obtained by subjecting aluminum alloy powders, which have been solidified at a cooling rate of 100.degree. C./sec or more, or aluminum alloy powders having particle diameters of 350 .mu.m or less, to powder compacting and hot extrusion and optionally further to hot forging, or subjecting the aluminum alloy powders to powder forging.
    Type: Grant
    Filed: December 19, 1989
    Date of Patent: April 6, 1993
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventor: Kiyoaki Akechi
  • Patent number: 5194099
    Abstract: A sinter magnet based on Fe-Nd-B with improved coercive field strength and reduced temperature dependency thereof consists of 25 to 50 wt. % Nd, 0.5 to 2 wt. % B, 0 to 5 wt. % Al, 0.5 to 3 wt. % O, remainder Fe and usual impurities and has an oxygen content which is adjusted by the addition of oxygen or of oxygen-containing compounds, especially of an Al and/or Nd oxide, before the dense sintering. It is obtainable by the melting together of the pure components with formation of a pre-alloy, pulverisation of the pre-alloy, alignment of the powder in a magnetic field and pressing to a green formed body, sintering at 1040.degree. to 1100.degree. C. and subsequent annealing at 600.degree. to 700.degree. C., whereby one adds the oxygen as Al or Nd oxide or via the grinding and/or sintering atmosphere.
    Type: Grant
    Filed: May 23, 1990
    Date of Patent: March 16, 1993
    Assignees: 501 Max-Planck-Gesellschaft zur Forderung der Wissenschaften E.V., 502 Robert Bosch GmbH
    Inventors: Friedrich Esper, Waldemar Draxler, Gunter Petzow, Andreas Buchel, Klaus-Dieter Durst, Ernst-Theo Henig, Gerhard Schneider, Helmut Kronmuller
  • Patent number: 5190709
    Abstract: A process for reaction injection molding of ceramic articles is disclosed. The process comprises (a) injecting a fluid, non-dilatant mixture comprising a ceramic powder, a metal powder or mixtures thereof, and a curable ceramic precursor that is a liquid below its curing temperature, into a heated mold, (b) curing the ceramic precursor to produce a hardened molded article, (c) heating the hardened molded article under a suitable atmosphere to a temperature sufficient to convert the ceramic precursor to a ceramic, and (d) sintering the ceramic to the desired density.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: March 2, 1993
    Assignee: Hercules Incorporated
    Inventor: Alexander Lukacs, III
  • Patent number: 5183631
    Abstract: A composite material is provided which includes a discrete phase including grains made of a first substance; and a continuous phase including a thin coating film made of a second substance and formed on the surface of each of the grains. The thin coating film has a mean thickness smaller than the mean particle size of the grains. The grains are separated substantially from each other by the thin coating film. The porosity of the composite material is 5% or less.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: February 2, 1993
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Koichi Kugimiya, Yasuhiro Sugaya, Osamu Inoue, Mitsuo Satomi, Ken Hirota
  • Patent number: 5174953
    Abstract: A method is disclosed of making a sintered composite unitary artifact having an alpha-alumina component fast with a metal component. Particulate alpha-alumina and a glass-forming additive are mixed together; and a green artifact is pressed having an alumina portion formed from the mixture and a metal portion formed from a particulate metal. The green artifact is then heated under a non-oxidizing atmosphere to a temperature at which both portions undergo densification. This provides a sintered artifact having a debased alpha-alumina component sintered to a metal artifact.
    Type: Grant
    Filed: October 9, 1991
    Date of Patent: December 29, 1992
    Assignee: Lillywyte Societe Anonyme
    Inventors: Jonathan L. Albain, Adrian W. Paterson
  • Patent number: 5173107
    Abstract: The invention relates to a composite hard metal body of hard material, a binder and embedded reinforcing material, as well as to a process for the production of the composite hard metal body by methods of powder metallurgy.In order to create a composite hard metal body with improved toughness under load, improved hardness and a lower fracture susceptibility, the invention proposes to build in monocrystalline, preferably needle-shaped and/or platelet-shaped reinforcing materials, coated with an inert layer with respect to the binder metal phase and consisting of borides and/or carbides, and/or nitrides and/or carbonitrides of the elements of Groups IVa or Va or mixtures thereof and/or coated monocrystalline reinforcing material of SiC, Si.sub.3 N.sub.4, Si.sub.2 N.sub.2 O, Al.sub.2 O.sub.3, ZrO.sub.2, AlN and/or BN.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: December 22, 1992
    Assignee: Krupp Widia GmbH
    Inventors: Klaus Dreyer, Hans Kolaska
  • Patent number: 5167913
    Abstract: A method of forming an adherent layer of metallurgy on a ceramic substrate which includes the steps of obtaining a ceramic material containing a polymeric binder and copper metallurgy patterns within the ceramic body. In one embodiment of the invention, the ceramic body also contains MgO.Thereafter, a surface layer of metallurgy is formed on the surface of the ceramic body. In one embodiment, the surface layer is nickel and in another embodiment, the surface layer is copper or gold.Then, the ceramic body undergoes a sintering cycle which includes the steps of pyrolysis, binder burnoff and, lastly, densification and, in some cases, crystallization. During densification and crystallization, there is a predetermined steam atmosphere which meets the following requirements: a partial pressure of oxygen less than that necessary to satisfy the equilibrium equation 4Cu+O.sub.2 =2Cu.sub.2 O; and a partial pressure of oxygen less than or equal to that necessary to satisfy the equilibrium equation 2Ni+O.sub.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: December 1, 1992
    Assignee: International Business Machines Corporation
    Inventors: John Acocella, Philip L. Flaitz, Raj N. Master, Chandrasekhar Narayan, Sarah H. Knickerbocker, Paul H. Palmateer, Sampath Purushothaman, Srinivasa S. N. Reddy
  • Patent number: 5162098
    Abstract: This invention relates generally to a novel method of manufacturing a composite body, such as a ZrB.sub.2 -ZrC-Zr (optional) composite body, by utilizing a post-treatment process and to the novel products made thereby. More particularly, the invention relates to a method of modifying a composite body comprising one or more boron-containing compounds (e.g., a boride or a boride and a carbide) which has been made by the reactive infiltration of a molten parent metal into a bed or mass containing boron carbide, and optionally one or more inert fillers, to form the body.
    Type: Grant
    Filed: May 7, 1991
    Date of Patent: November 10, 1992
    Assignee: Lanxide Technology Company, LP
    Inventors: Terry D. Claar, Gerhard H. Schiroky, William B. Johnson
  • Patent number: 5156805
    Abstract: A ferritic alloy with a wear resistive oxide scale is obtained through the steps of pressing a ferritic alloy powder containing aluminum into a powder compact of a desired configuration, sintering the powder compact in a non-oxidizing atmosphere to provide a resulting sintered product, and heat-treating the sintered product in an oxidizing gas atmosphere in order to precipitate in the surface thereof alumina in the form of an alumina scale as the wear resistive oxide scale which is responsible for improved surface hardness or wear resistance. Due to the inherent porous nature of the sintered product, the oxidizing gas can readily penetrate deep into the surface of sintered product to facilitate the oxidization of the product surface into the alumina scale, in addition to that the oxidization depth can be controlled such as by the density of the product, which makes it possible to readily control the thickness of the alumina scale.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: October 20, 1992
    Assignee: Matsushita Electric Works, Ltd.
    Inventors: Junji Imai, Shuji Yamada, Tadashi Hamada, Hajime Kojima, Masao Tanahashi
  • Patent number: 5152959
    Abstract: The present invention relates to a process for forming a composite strip material without any sintering step. The process includes blending a powdered high conductivity material such as powdered copper with a powdered low thermal expansion phase material such as a nickel-iron alloy, compacting the powders to form a green composite strip, heating the green strip to a hot rolling temperature and hot rolling the heated strip to a desired gauge. The heated strip is reduced less than about 45% to minimize the deformation of the low thermal expansion phase particles.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: October 6, 1992
    Assignee: AMETEK Speciality Metal Products Division
    Inventor: Clive R. Scorey
  • Patent number: 5145835
    Abstract: A process for fabricating worked superconducting ceramic material of a mean grain size not more than 10 um is disclosed, which comprises the steps of: (a) preparing a metal casing containing a starting powder material having a composition for forming an oxide superconductor; (b) calcining the starting powder material contained in the casing at a temperature range of 850.degree. to 950.degree. C.; (c) subjecting said casing to a HIP treatment; (d) subjecting said casing containing hot deformed material to cold deformation processing; and (e) subjecting said casing to stress relief treatment by annealing in the presence of oxygen.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: September 8, 1992
    Assignee: Mitsubishi Materials Corporation
    Inventors: Takuo Takeshita, Sadaaki Hagino, Tatsuro Ajima, Motokazu Suzuki
  • Patent number: 5132081
    Abstract: A method for manufacturing an impregnated cathode comprising the steps of forming a porous pallet having a plurality of pores by sintering metal powder at a high temperature in a reducing atmosphere and fitting the porous pallet tightly in a cathode ring made of a metal containing an oxidizable material such as silicon, nickel or chromium. In the porous pallet, an electron radiating material is impregnated which is able to react with the oxidizable material of the cathode ring, so that an fixing between the pallet and the cathode ring is achieved by the reaction between the electron radiating material and the oxidizable material. In accordance with the method, the thickness of the cathode body can be greatly reduced, thereby enabling the performance of the impregnated cathode to be improved. Also, the manufacturing process can be simplified, thereby improving the productivity.
    Type: Grant
    Filed: December 27, 1991
    Date of Patent: July 21, 1992
    Assignee: Goldstar Co., Ltd.
    Inventor: Kyung S. Lee
  • Patent number: 5130206
    Abstract: Extra loss is introduced in coupled cavity and klystron RF circuits by applying a surface coating to selected parts of circuit elements used in the circuits. The coating is applied in the form of a slurry, which is then sintered. The slurry comprises a mixture of an iron-base powder (such as a stainless steel) and a dielectric glass ceramic, suspended in a binder dissolved in a solvent. Circuits with the loss coating are easier to match than by other prior art techniques. The loss coating of the invention reduces the fabrication cost of coupled-cavity traveling wave tubes, while improving the performance by minimizing the gain ripple. Higher average power operation is possible, due to elimination of loss buttons previously employed in the prior art.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: July 14, 1992
    Assignee: Hughes Aircraft Company
    Inventors: Sunder S. Rajan, Ivo Tammaru, Steve L. Bosma, John W. Eldridge
  • Patent number: 5128827
    Abstract: An improved electronic device having metal-glazing type end terminations comprising a surface metal phase of Sn or Zn, is produced by sintering a paste material containing a matrix metal powder (Cu and/or Ni), a fluxing metal powder and an organic binding material, so that the surface portion serves to improve wettability and solderability of the end termination owing to its composition being similar to solder.
    Type: Grant
    Filed: March 20, 1991
    Date of Patent: July 7, 1992
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Yoichiro Yokotani, Seiichi Nakatani, Koichi Kugimiya
  • Patent number: 5124119
    Abstract: A beryllium metal matrix phase includes up to 70% by volume of beryllium oxide single crystals dispersed therein. The composites are useful for electronics applications because of their light weight, high strength and effective thermal properties.
    Type: Grant
    Filed: February 12, 1991
    Date of Patent: June 23, 1992
    Assignee: Brush Wellman Inc.
    Inventor: Fritz C. Grensing
  • Patent number: 5120351
    Abstract: This invention is a ferrite molding made by a manufacturing method of molding and sintering ferrite particles, which are made by pre-sintering of magnetic materials including iron oxide, together with metallic particles mixed therein by a hydrostatic pressing at extra-high pressure, whereby metal fills in between the ferrite particles. The ferrite molding has improved ductility so as to resist chipping and breaking and has extremely low hydroscopicity so as to maintain its characteristics.
    Type: Grant
    Filed: April 9, 1991
    Date of Patent: June 9, 1992
    Assignee: Kitagawa Industries Co., Ltd.
    Inventor: Hiroji Kitagawa
  • Patent number: 5120350
    Abstract: A reinforced metal composite comprised of a mixture of fused yttria and a metal matrix selected from the group consisting of Ti, Nb, Fe, Co, Ni, Ti alloy, Co based alloys aluminides of Ti, aluminides of Ni, aluminides of Nb and their mixtures. Preferably, the metal matrix is Ti or a Ti alloy which has a low Cl content (e.g. less than 0.15 wt. % Cl).
    Type: Grant
    Filed: July 3, 1990
    Date of Patent: June 9, 1992
    Assignee: The Standard Oil Company
    Inventors: Edward C. Supan, Joseph F. Dolowy, Jr., Bradley A. Webb
  • Patent number: 5118342
    Abstract: A partially hardened sintered body such as a rocker arm comprises powder forming a main body and a capsule-like powder composite disposed adjacent to the powder and composed of core particles made of a material harder than the powder and covering particles covering the core particles and made of the same material as the powder. The powder and the capsule-like powder composite are solidified into the partially hardened sintered body.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: June 2, 1992
    Assignee: Isuzu Motors Limited
    Inventors: Tadashi Kamimura, Akira Tsujimura
  • Patent number: 5114469
    Abstract: A process for producing high-strength, substantially nonporous alloys by means of a three-component mixture, including admixing a first component of one or more low-melting temperature metals or alloys thereof, a second component of one or more high-melting temperature metals or alloys thereof, and a substantially inert third component of one or more refractory compounds, subjecting the mixture to changes in temperature so as to form a mixture capable of being shaped at a temperature well below the melting or decomposition temperature of the highest melting metal and the inert refractory compound.
    Type: Grant
    Filed: December 10, 1987
    Date of Patent: May 19, 1992
    Assignee: General Dynamics Corporation Air Defense Systems Division
    Inventor: Sam M. Weiman
  • Patent number: 5110349
    Abstract: A cutting insert of a sintered carbonitride alloy and with a complicated geometry, the insert having improved efficiency. This is obtained by giving the powder non-uniform compaction during pressing of the powder into a press-body so that the ultimate working edges will have a higher relative density than the surrounding, more "supporting" material in the press-body. By these means are often obtained surface defects in the form of cracks because of dissolved strains during the sintering.
    Type: Grant
    Filed: November 14, 1990
    Date of Patent: May 5, 1992
    Assignee: Sandvik AB
    Inventors: Kenneth Westergren, Gerold Weinl, Rolf Oskarsson
  • Patent number: 5110688
    Abstract: The present invention relates to a method of fabricating various types of bearing materials and the bearing materials produced thereby. The processes of the invention may be used to produce porous self-lubricating bearings, laminated composite bearings (babbitt bearings) and bearings for high temperature application. The processes of the invention involve the use of micro-pyretic synthesis to achieve bearing materials with improved bearing properties, including higher bearing capacity and toughness.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: May 5, 1992
    Assignee: University of Cincinnati
    Inventors: Jainagesh A. Sehkar, A. K. Bhattacharya, Hung P. Li
  • Patent number: 5102863
    Abstract: A process for fabricating superconducting composite wire by the steps of placing a superconductive precursor admixture capable of undergoing a self propagating combustion in stoichiometric amounts sufficient to form a superconductive product within a metal tube, sealing one end of said tube, igniting said superconductive precursor admixture whereby said superconductive precursor admixture endburns along the length of the admixture, and cross-section reducing said tube at a rate substantially equal to the rate of burning of said superconductive precursor admixture and at a point substantially planar with the burnfront of the superconductive precursor mixture, whereby a clad superconductive product is formed in situ, the product characterized as superconductive without a subsequent sintering stage, is disclosed.
    Type: Grant
    Filed: March 19, 1991
    Date of Patent: April 7, 1992
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Richard B. Cass, Kevin C. Ott, Dean E. Peterson
  • Patent number: 5100869
    Abstract: A metal oxide-type superconductive material is produced by a process which comprises a first step of subjecting a powder raw material containing given proportions of metal elements to be contained in said metal oxide-type superconductive material, to mechanical grinding and alloying simultaneously to obtain an alloy powder and a second step of heat-treating the alloy powder in an oxygen-containing gas atmosphere to obtain a metal oxide.The superconductive material obtained has a high density, a low porosity, a high strength and a high critical current density.
    Type: Grant
    Filed: March 10, 1989
    Date of Patent: March 31, 1992
    Assignees: Tsuyoshi Masumoto, Hoya Corporation
    Inventors: Tsuyoshi Masumoto, Akihisa Inoue, Kunio Matsuzaki, Keiji Moroishi
  • Patent number: 5096450
    Abstract: A method for fabricating an impregnated type cathode comprises the steps of mixing metal powder having a high melting point and a heat proof property, and electron emission substance powder in a dry state, pressing the mixed powder to provide a pressed mixture, and applying an isostatic pressure to the pressed mixture contained in a sealed capsule. At the mixing stage, the metal powder is heated by a high temperature lower than the melting point, and at the mixing stage, a sintered mixture is obtained. In this method, the steps are simplified and decreased in number to decrease a fabricating cost. Furthermore, no influence occurs in electron emission due to hydrooxides.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: March 17, 1992
    Assignee: NEC Kansai, Ltd.
    Inventors: Toshikazu Sugimura, Yoshio Takeshima, Hidefumi Yamamoto, Masaaki Yabuta, Masami Horiuchi
  • Patent number: 5091020
    Abstract: A method for making rare earth element, iron and boron sintered permanent magnets, and a particle mixture for use therein. A hydrided 100% dross or particle mixture of virgin alloy particles and scrap alloy particles and/or dross alloy particles are dehydrided and sintered to produce a substantially fully dense article for use as a permanent magnet.
    Type: Grant
    Filed: November 20, 1990
    Date of Patent: February 25, 1992
    Assignee: Crucible Materials Corporation
    Inventor: Andrew S. Kim
  • Patent number: 5089354
    Abstract: A copper alloy composite material which comprises a copper alloy matrix and at least one additive selected from solid materials having self-lubricity and wear-resistant materials and uniformly dispersed in the alloy matrix is described. The composite material has improved wear resistance and anti-seizing properties.
    Type: Grant
    Filed: December 11, 1990
    Date of Patent: February 18, 1992
    Assignee: Chuetsu Metal Works, Co., Ltd.
    Inventors: Kunio Nakashima, Ryouichi Ishigane, Takayuki Tanaka, Ken-ichi Ichida
  • Patent number: 5077246
    Abstract: A method for the preparation of ceramic composites containing at least aluminum oxide and aluminum boride, and the composite materials that result from the method. Intimate mixtures of finely-divided powdered aluminum metal and anhydrous boric oxide, with ratios (by weight) of about 0.5 to twenty parts of aluminum metal to one part of boric oxide, are subjected to a temperature to cause a complete reaction between the starting materials. If the ratio is above about 1.25 parts of aluminum to one part of boric oxide, the resultant product will include aluminum in addition to the aluminum oxide and aluminum boride. The ratio is selected to provide the desired hardness and toughness. Ratios between about 1 and 1.2 provide a composite having the highest hardness, with greater amounts of aluminum metal providing increased toughness. Several compositions are described, with hot pressing typically being used to provide the desired heating cycle.
    Type: Grant
    Filed: June 4, 1990
    Date of Patent: December 31, 1991
    Assignee: Apollo Concepts, Inc.
    Inventors: Samuel C. Weaver, Sally G. Padron
  • Patent number: 5077269
    Abstract: A target used for forming a thin film of a quinary superconductive oxide contains metal copper ranging between about 8% and about 40% by volume dispersed into a quaternary or a quinary complex oxide, and the metal copper improves the thermal conductivity and the electrical conductivity of the target, so that cracks are less liable to take place in the target and the target is applicable to a d.c. sputtering system, thereby decreasing the production cost of the thin film.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: December 31, 1991
    Assignee: Mitsubishi Metal Corporation
    Inventors: Tadashi Sugihara, Yukihiro Ohuchi, Takuo Takeshita
  • Patent number: 5074907
    Abstract: Enhanced crystallographic texture is developed in an alpha or alpha-beta titanium alloy having a dispersion of particles therein, by heating the alloy to essentially the all beta phase range and mechanically hot working the alloy in this range. The mechanical working is preferably accomplished by extrusion, rolling, or forging. The particles are stable during working, and prevent the formation of random texture in recrystallized beta phase grains at the working temperature. The particles are preferably oxides formed from rare earth elements such as erbium or yttrium, that are introduced into the alloy during manufacture. The alloys processed according to the invention are preferably prepared by powder metallurgy to achieve a uniform microstructure prior to working. A particularly suitable alpha-beta (but near alpha) titanium alloy contains aluminum, zirconium, hafnium, tin, columbium, molybdenum, tungsten, ruthenium, germanium, silicon, and erbium.
    Type: Grant
    Filed: August 16, 1989
    Date of Patent: December 24, 1991
    Assignee: General Electric Company
    Inventors: Richard A. Amato, Andrew P. Woodfield, Michael F. X. Gigliotti, Jr., John R. Hughes, Lee C. Perocchi
  • Patent number: 5073302
    Abstract: A varistor material comprising two crystalline phases of ZnO and ZnMn.sub.2 O.sub.4, wherein Zn and Mn are present at such a ratio that 3 to 7% by mol of ZnO is contained per 100% by mol of ZnO+MnO and the nonlinear index (.alpha.) of the varistor properties is at least 10; and a process for the production of the same, which comprises adding a manganese compound to ZnO at such a ratio as to give a content of MnO, sintering the mixture at 1100.degree. to 1350.degree. C., and further annealing the obtained sintered material at a temperature lower than the sintering temperature by at least 50.degree. C. and higher than 1000.degree. C. are disclosed.
    Type: Grant
    Filed: June 14, 1989
    Date of Patent: December 17, 1991
    Assignee: Somar Corporation
    Inventors: Akihide Igari, Zenbee Nakagawa
  • Patent number: 5070591
    Abstract: Metal and ceramic particles of various morphologies are clad with a coating from the transition metal group consisting of silver, gold, copper, nickel, iron, cobalt, aluminum etc., or combinations thereof, to provide improved coated particles for microelectronics or metal matrix composites or other uses. Refractory metal precursor core particles, such as tungsten, molybdenum, niobium and zirconium, as examples, are provided from a composite of tungsten and copper, for example, made by pressurizing and infiltrating or liquid phase sintering of molten copper into a porous tungsten skeleton. Precursor chip particles derived from a tungsten impregnated billet are used as starter particles which may be further enhanced by cogrinding in an attritor ball mill with smaller copper particles to thereby produce an enhanced copper clad-coating of tungsten particles with predetermined percent by weight of copper and tungsten content.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: December 10, 1991
    Inventors: Nathaniel R. Quick, James C. Kenney
  • Patent number: 5069713
    Abstract: A non-sintered permanent magnet is formed by a cold compacting technique or by resin bonding using particles of a stoichiometric alloy (e.g. R.sub.2 Fe.sub.14 B where R is at least one rare earth and/or yttrium, particularly La, Ce, Pr, ND or Y or a mixture thereof) which have been coated with a reaction product of the alloy or a non-magnetic metal such as Sn, Ga, Zn, Al, or Cu. The use of a stoichiometric alloy avoids the presence of a reactive grain boundary phase normally present in non-stoichiometric alloys.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: December 3, 1991
    Assignee: The University of Birmingham
    Inventors: Ivor R. Harris, Syed H. Safi
  • Patent number: 5069866
    Abstract: A method of preparing a compound pipe, the wall of which comprises an inner layer of a first material and an outer layer of a second material. Powders of the two materials are isostatically hot pressed to form a cylindrical tubular blank in which the first material forms an inner layer and the second material forms an outer layer, the blank after heating to a suitable temperature being extruded over a mandrel.
    Type: Grant
    Filed: May 31, 1990
    Date of Patent: December 3, 1991
    Assignee: ABB Stal AB
    Inventor: Ragnar Ekbom
  • Patent number: 5067986
    Abstract: A process for producing coarse, longitudinally oriented column crystals with improved temperature change resistance and ductility in the transverse direction in a workpiece of any cross-section from an oxide-dispersion-strengthened nickel-base superalloy, which exists in fine-grained form, by annealing in the temperature range between 1000.degree. and 1200.degree. C., cooling to room temperature and isothermally annealing for coarse grain in the range between 1230.degree. C. and 1280.degree. C.
    Type: Grant
    Filed: May 15, 1990
    Date of Patent: November 26, 1991
    Assignee: Asea Brown Boveri Ltd.
    Inventors: Reinhard Fried, Peter Jongenburger
  • Patent number: 5059387
    Abstract: Shaped parts are formed from a powder having the desired chemistry of the finished part by mixing the powder with a thermosetting condensation resin that acts as a binder. The resin may be partially catalyzed, or additives or surfactants added to improve rheology, mixing properties, or processing time. Upon heating, the inherently low viscosity mixture will solidify without pressure being applied to it. A rigid form is produced which is capable of being ejected from a mold. Pre-sintered shapes or parts are made by injection molding, by using semi-permanent tooling, or by prototyping. Binder removal is accomplished by thermal means and without a separate debinding step, despite the known heat resistance of thermosetting resins. Removal is due to the film forming characteristic of the binder leaving open the part's pores, by providing oxidizing conditions within the part's pores as the part is heated, and by insuring that the evolving resin vapor diffuses through the pores by heating the part in a vacuum.
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: October 22, 1991
    Assignee: Megamet Industries
    Inventor: Gregory M. Brasel
  • Patent number: 5059489
    Abstract: A structure comprising a mixture of metals and metal alloys which are sintered into a hard porous body is presented. The structure can be useful for many different chemical and physical purposes, such as for catalysis, desorption and absorption, and selective leaching of the structure components into solutions.
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: October 22, 1991
    Assignee: Corning Incorporated
    Inventors: Charles Q. Buckwalter, Jr., Irwin M. Lachman, Mallanagouda D. Patil, Jimmie L. Williams
  • Patent number: 5057340
    Abstract: A ceramic-based coating is provided on a sealing surface of a sealing assembly component by processing and applying a powder mixture of ceramic particles and metal binder, encasing the coating of powder on the sealing surface by applying a metallic cover thereover, evacuating the atmosphere between the cover and coating, hot isostatic pressing the component and coating, cooling the component and coating, and after cooling thereof removing the cover from the coating.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: October 15, 1991
    Assignee: Westinghouse Electric Corp.
    Inventors: Natraj C. Iyer, Eleanor Gettliffe
  • Patent number: 5049355
    Abstract: Process for producing a ductile, high strength, oxide dispersion hardened sintered alloy based on a metal having a high melting point. In the past, oxide dispersion has played only a minor role in comparison with other known processes for increasing strength. The process disclosed permits cost effective production of metallic materials which possess a strength hitherto unattainable by oxide dispersion and a higher ductility than prior art materials. As a result, the metallic and nonmetallic foreign components in the sintered alloy can be restricted to the relatively small quantities of dispersoids and any dissolved residual oxygen. The process consists in an annealing treatment and calls for a specific choice of basis metal and suitable oxide dispersoid.
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: September 17, 1991
    Assignee: Schwarzkopf Development Corporation
    Inventors: Udo Gennari, Wolfgang Glatzle
  • Patent number: 5045276
    Abstract: An injection molded powder metallurgy product of highly satisfactory quality is obtained by a method which comprises injection molding mixture obtained by kneading a metal powder with a binder, depriving the molded mass of the binder while keeping the molded mass at least in contact with ceramic powder, projecting beads on the molded mass free from the binder, and thereafter sintering the molded mass studded with the beads.
    Type: Grant
    Filed: October 11, 1990
    Date of Patent: September 3, 1991
    Assignee: Sumitomo Metal Mining Company Limited
    Inventor: Yoshio Kijima
  • Patent number: 5043320
    Abstract: A powder-in-tube method is disclosed for making a composite superconducting oxide wire which comprises loading a copper tube with a mixture composed of rare earth metal oxide, BaO.sub.2 and copper oxide or the finished superconductor powder and subjecting the loaded tube to drawing and a heat treatment at a temperature of up to 950.degree. C., wherein prior to loading the copper tube, the tube is oxidized at least on its inside to form a copper oxide layer having a thickness of 1 to 100 .mu.m and then a silver intermediate layer is inserted to the oxidized copper tube.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: August 27, 1991
    Assignee: Asea Brown Boveri AG
    Inventors: Gundolf Meyer, Erwin Schonfeld, Clemens Verpoort
  • Patent number: 5041414
    Abstract: Continuous malleable superconductive material which can be machined, rolled and soldered, being the product of sintering at an elevated temperature and pressure of a metal plated powder of a compound QBa.sub.2 Cu.sub.3 O.sub.7-x wherein Q is yttrium or europium, where x is smaller than one. The metal is advantageously silver and the plating process is one without the use of electricity. A preferred range of silver content is about 5 to 32 weight per cent, and the silver forms an essentially continuous phase in the superconductive material. Sintering can be done at from about 350.degree. and 950.degree. C., with a preferred range of 400.degree. to 900.degree. C. The superconductive material of the invention exhibits transition to zero-resisitivity state and the Meissner effect.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: August 20, 1991
    Assignee: Yeda Research and Development Company Limited
    Inventor: Shymon Reich
  • Patent number: 5041159
    Abstract: An improved method of forming a nickel plaque wherein an assemblage of particles of a nickel alloy are oxidized and sintered in a preselected atmosphere such that the alloying material is exclusively substantially internally oxidized and the resultant product sintered to provide a sintered porous plaque containing nickel metal and oxidized alloying material.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: August 20, 1991
    Assignee: Energy Research Corporation
    Inventors: Joel D. Doyon, Lawrence M. Paetsch, Mark Benedict, D. Lynn Johnson
  • Patent number: 5041416
    Abstract: A superconductor metal matrix composite formable into an electrical current carrying material. A superconductive particulate is intermixed with a normal metal matrix, pressed into form and heated to form the composite. The metal matrix surrounds the superconductive particulate to prevent loss of oxygen from the superconductive particulate so the particulate retains its superconductive properties. The metal matrix also becomes superconductive due to proximity effect.
    Type: Grant
    Filed: October 16, 1990
    Date of Patent: August 20, 1991
    Assignee: FMC Corporation
    Inventor: Charles N. Wilson
  • Patent number: 5039476
    Abstract: A method for the production of a metallic powder molding material is disclosed which comprises a step of imparting mechanical energy due to at least one of such physical actions as vibration, pulverization, attrition, rolling, shocks, agitation, and mixing a metallic particles in a vessel whose interior is held under vacuumized atmosphere or an atmosphere of inert gas thereby enabling the metallic particles to contact each other and acquire improvement in surface quality and a step of hot molding the metallic particles thereby producing a molding material.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: August 13, 1991
    Assignee: Ube Industries, Ltd.
    Inventors: Mitsuru Adachi, Akio Okamoto, Hideki Iwai, Yoshiharu Waku
  • Patent number: 5033939
    Abstract: Shaped parts are formed from a powder having the desired chemistry of the finished part by mixing the powder with a thermosetting condensation resin that acts as a binder. The resin may be partially catalyzed, or additives or surfactants added to improve rheology, mixing properties, or processing time. Upon heating, the inherently low viscosity mixture will solidify without pressure being applied to it. A rigid form is produced which is capable of being ejected from a mold. Pre-sintered shapes or parts are made by injection molding, by using semi-permanent tooling, or by prototyping. Binder removal is accomplished by thermal means and without a separate debinding step, despite the known heat resistance of thermosetting resins. Removal is due to the film forming characteristic of the binder leaving open the part's pores, by providing oxidizing conditions within the part's pores as the part is heated, and by insuring that the evolving resin vapor diffuses through the pores by heating the part in a vacuum.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: July 23, 1991
    Assignee: Megamet Industries
    Inventor: Gregory M. Brasel
  • Patent number: 5032353
    Abstract: Structural components of at least one intermetallc compound and having complicated contours, are made by the steps of preparing a powder mixture of elemental metal powders including at least one powder of a low melting metal element or component and one powder of a high melting metal element or component that subsequently are to form the intermetallic compound. The powder mixture is then sintered to form a sintered body which is machined to a contour close to the finished contour and to dimensions close to the final dimensions. The so machined and shaped part is enveloped with an envelope of the high melting metal element or component. The enveloped part is subjected to a hot isostatic reaction pressing whereby the intermetallic compound is formed.
    Type: Grant
    Filed: October 26, 1990
    Date of Patent: July 16, 1991
    Assignee: MTU Motoren-und Turbinen-Union Muenchen GmbH
    Inventors: Wilfried Smarsly, Raimund Lackermeier