Titanium Base Patents (Class 420/417)
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Patent number: 7438849Abstract: A titanium alloy includes at least one alloying element whose molybdenum equivalent “Moeq” is from 3 to 11% by mass, at least one interstitial solution element selected from the group consisting of O, N and C in an amount of from 0.3 to 3% by mass, and the balance of Ti, when the entirety is taken as 100% by mass. Its content of Al is controlled to 1.8% by mass or less, and it is ? single phase at room temperature at least.Type: GrantFiled: September 17, 2003Date of Patent: October 21, 2008Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Shigeru Kuramoto, Tadahiko Furuta, Junghwan Hwang, Rong Chen, Nobuaki Suzuki, Kazuaki Nishino, Takashi Saito
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Patent number: 7435282Abstract: A method of producing a non-metal element or a metal or an alloy thereof from a halide or mixtures thereof. The halide or mixtures thereof are contacted with a stream of liquid alkali metal or alkaline earth metal or mixtures thereof in sufficient quantity to convert the halide to the non-metal or the metal or alloy and to maintain the temperature of the reactants at a temperature lower than the lesser of the boiling point of the alkali or alkaline earth metal at atmospheric pressure or the sintering temperature of the produced non-metal or metal or alloy. A continuous method is disclosed, particularly applicable to titanium.Type: GrantFiled: April 20, 2002Date of Patent: October 14, 2008Assignee: International Titanium Powder, LLCInventors: Donn Reynolds Armstrong, Stanley S. Borys, Richard P. Anderson
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Publication number: 20080238289Abstract: A thermo-optically functional composition is disclosed. The composition includes a solid solution of at least two materials selected such that the composition emits thermal radiation, wherein each material is selected from the group consisting of metal carbides, metal nitrides, metal oxides, metal borides, metal silicides and combinations thereof, wherein each metal is selected from the group consisting of tungsten or tungsten alloys, hafnium or hafnium alloys, niobium or niobium alloys, tantalum or tantalum alloys, titanium or titanium alloys, zirconium or zirconium alloys, and combinations of two or more thereof.Type: ApplicationFiled: March 30, 2007Publication date: October 2, 2008Applicant: GENERAL ELECTRIC COMPANYInventors: SERGIY ZALYUBOVSKIY, WILLIAM PAUL MINNEAR, VIKAS MIDHA
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Patent number: 7422644Abstract: The present invention provides non-axially symmetrical manufactured parts of thickness less than 10 mm, made of ? or quasi-? titanium alloy, having a core microstructure constituted by whole grains presenting a slenderness ratio greater than 4 and an equivalent diameter lying in the range 10 ?m to 300 ?m. The invention also provides a method of manufacturing the parts by forging.Type: GrantFiled: March 3, 2006Date of Patent: September 9, 2008Assignee: Snecma MoteursInventors: Blandine Barbier, Philippe Gallois, Claude Mons, Agathe Venard, Pascal Vignolles
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Publication number: 20080199348Abstract: A Ti powder is made b y the subsurface reduction of TiCl4 by a stream of liquid of sodium in excess of stoichiometric sufficient to maintain substantially all the reactive products below the sintering temperatures thereof followed by distillation to produce a powder with a packing fraction in the range of from about 4% to about 11%. Also disclosed is a solid product made from the Ti powder.Type: ApplicationFiled: April 24, 2008Publication date: August 21, 2008Applicant: International Titanium Powder, LLCInventors: Donn Reynolds Armstrong, Stanley S. Borys, Richard Paul Anderson
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Publication number: 20080193323Abstract: An object of the present invention is to develop a shape memory and superelastic alloy that does not contain nickel, and has superelasticity and shape memory properties even if being subjected to heat treatment in spite of high biocompatibility, moreover having high cold workability. The Ti—Nb—Zr base alloy is comprising an alloy composition consisting of 40 to 60 wt % Ti, 18 to 30 wt % Nb, 18 to 30 wt % Zr, and 0.77 to 3.7 wt % at least one metal additional element selected from Al, Sn, In and Ga. The Ti—Nb—Zr base alloy is a practical alloy in which the principal components form a strong and dense oxidation film to exhibit high biocompatibility, and also the alloy has superelasticity and shape memory properties, high cold workability, and high low-temperature properties.Type: ApplicationFiled: November 18, 2005Publication date: August 14, 2008Applicants: JAPAN BASIC MATERIAL CO., LTD., TOHOKU UNIVERSITYInventors: Xin Min Wang, Akihisa Inoue, Hiroyuki Tada, Tatsue Arakawa
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Publication number: 20080187455Abstract: A titanium powder or alloy powder produced by introducing a TiCl4 vapor into a continuum or flowing stream of sodium metal at a velocity not less than sonic velocity of the vapor wherein the sodium is present in an amount greater than stoichiometric sufficient to maintain substantially all the reaction products below the sintering temperature thereof and wherein said Ti powder has a packing fraction in the range of from about 4% to about 11%. The powders without fines have a particle diameter in the range of from about 3.3 to about 1.3 microns based on a calculated size of a sphere from a BET surface area in the range of from about 0.4 to about 1.0 m2/g.Type: ApplicationFiled: April 9, 2008Publication date: August 7, 2008Applicant: International titanium Powder, LLCInventors: Donn Reynolds Armstrong, Stanley R. Borys, Richard P. Anderson
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Publication number: 20080152533Abstract: A method of producing passivated Ti or Ti alloy particles with oxygen concentrations of less than about 900 parts per million (ppm), which includes introducing a halide vapor of Ti or the metal constituents of the alloy at sonic velocity or greater into a stream of liquid alkali or liquid alkaline earth metal or mixtures thereof forming a reaction zone in which the halide is reduced by the liquid metal present in sufficient excess of stoichiometric such that Ti or Ti alloy powder from the reduction of the halide by the liquid metal is friable. After filtration and distillation excess liquid metal is removed from the Ti or Ti alloy powder that is then maintained at elevated temperature for a time sufficient to grow the particles to average diameters calculated from BET surface area measurement greater than about one micron. After cooling the Ti or Ti alloy powder to temperature of about 80° C.Type: ApplicationFiled: December 22, 2006Publication date: June 26, 2008Applicant: INTERNATIONAL TITANIUM POWDER, LLCInventors: William Ernst, Lance Jacobsen
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Publication number: 20080145687Abstract: A method of producing titanium metal from a titanium-containing material includes the steps of producing a solution of M?TiF6 from the titanium-containing material, selectively precipitating M?2TiF6 from the solution by the addition of (M?)aXb and using the selectively precipitated M?2TiF6 to produce titanium. M? is a cation of the type which forms a hexafluorotitanate, M? is selected from ammonium and the alkali metal cations, X is an anion selected from halide, sulphate, nitrite, acetate and nitrate and a and b are 1 or 2.Type: ApplicationFiled: December 14, 2005Publication date: June 19, 2008Inventor: Gerard Pretorius
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Publication number: 20080081763Abstract: Crosslinked polymer compositions have backbones with first and second divalent saturated aliphatic moieties, a divalent saturated aliphatic secondary alcohol moiety, and a trivalent saturated aliphatic moiety. Hydrolytically labile ester bonds joined together these moieties. These polyesters may be polycondensation reaction products of a diol, a triol and a diacid. A molar ratio of the first divalent saturated aliphatic moiety, the divalent saturated aliphatic secondary alcohol moiety, and the trivalent saturated aliphatic moiety to the second divalent saturated aliphatic moiety is in the range of about 0.85 to about 1.5. Preferably, these polyesters are non-cytotoxic, biocompatible, bioabsorbable, or exhibit shape memory behavior with at least one transition temperature of greater than about 30° C. and less than about 100° C. and most preferably exhibit each of these qualities. The compositions may be adapted for a wide variety of uses, including medical applications.Type: ApplicationFiled: February 26, 2007Publication date: April 3, 2008Inventors: Brian J. Swetlin, Kenneth A. Mazich
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Publication number: 20080081213Abstract: An amorphous alloy member including an irregular region having a center line average roughness Ra of about 0.1 ?m to about 1000 ?m on a surface, at least the irregular region including an amorphous alloy having an amorphous phase at a volume ratio of about 50% to about 100%. A process for manufacturing the amorphous alloy member, and an authenticity determination device and an authenticity determination method using the amorphous alloy member.Type: ApplicationFiled: April 26, 2007Publication date: April 3, 2008Applicants: FUJI XEROX CO., LTD., YKK CORPORATIONInventors: Kensuke Ito, Takashi Nagayasu, Tomonari Sugata, Tadashi Shimizu, Tetsuya Kimura
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Publication number: 20080010828Abstract: A method of making a forged piston includes the steps of providing a workpiece made of an aluminum alloy, a magnesium alloy or a titanium alloy; and forging the workpiece with stress applied thereto in a predetermined direction (forging direction). The method further includes, before the step of forging, the step of working the workpiece such that fiber flows of the workpiece are nonparallel to the predetermined direction.Type: ApplicationFiled: June 22, 2007Publication date: January 17, 2008Applicant: YAMAHA HATSUDOKI KABUSHIKI KAISHAInventors: Hiroshi YAMAGATA, Hirotaka KURITA
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Patent number: 7261782Abstract: A titanium alloy obtained by a cold-working step, in which 10% or more of cold working is applied to a raw titanium alloy, comprising a Va group element and the balance of titanium substantially, and an aging treatment step, in which a cold-worked member, obtained after the cold-working step, is subjected to an aging treatment so that the parameter “P” falls in a range of from 8.0 to 18.5 at a treatment temperature falling in a range of from 150° C. to 600° C.; and characterized in that its tensile elastic limit strength is 950 MPa or more and its elastic deformation capability is 1.6% or more. This titanium alloy is of high elastic deformation capability as well as high tensile elastic limit strength, and can be utilized in a variety of products extensively.Type: GrantFiled: December 5, 2001Date of Patent: August 28, 2007Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: JungHwan Hwang, Tadahiko Furuta, Kazuaki Nishino, Takashi Saito
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Patent number: 7259124Abstract: The present invention discloses a hydrogen storage medium including a composite of an alloy and a catalyst/expandable graphite. The expandable graphite can be replaced by activated carbon. The catalyst content is 1-50% based on the weight of the medium, which can be Pd, Pt, Cu, Co or Ni. The alloy can be a Mg-based alloy, Ti-based alloy, La-based alloy, Mn-based alloy or Fe-based alloy. The present invention also discloses a process for preparing a hydrogen storage composite.Type: GrantFiled: February 7, 2005Date of Patent: August 21, 2007Assignee: Industrial Technology Research InstitiuteInventors: Pei-Shan Yen, Ching-Sung Hsiao, Kong-Wei Cheng, Jau-Chyn Huang
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Patent number: 7219412Abstract: The invention includes superconducting titanium-containing compositions having less than 200 ppm, by weight, of a combined total of interstitial materials selected from the group consisting of nitrogen, oxygen, carbon and hydrogen. The invention also includes methods of forming superconducting titanium-containing superconducting compositions containing less than 100 ppm, by weight, of a combined total of interstitial materials selected from the group consisting of nitrogen, oxygen, carbon and hydrogen.Type: GrantFiled: June 2, 2004Date of Patent: May 22, 2007Assignee: Honeywell International Inc.Inventors: Yun Xu, Stephen P. Turner, Mathew S. Cooper, Wei Guo, David B. Love, Edward Cawley
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Patent number: 7175721Abstract: The invention relates to a method for producing high-performance Cr—Ti—V hydrogen storage alloys utilizing a thermit process, whereby residence of adversely affecting impurities is inhibited, addition of not less than 10 at % of Ti as an alloy component is realized, and thermal burden on the crucible used in the method is reduced. The method includes the steps of: (A) providing an alloy material (1) comprising a Cr oxide, a V oxide, and a reducing agent Al, and an alloy material (2) comprising Ti; (B) placing the alloy materials in a crucible for thermit reduction so that the alloy material (1) is placed above the alloy material (2); (C) igniting the alloy material (1) placed in step (B) and melting all metal elements contained in the alloy materials the with heat of the thermit reaction of the alloy material (1); and (D) making the alloy melt obtained in step (C) into an alloy.Type: GrantFiled: April 25, 2002Date of Patent: February 13, 2007Assignee: Santoku CorporationInventors: Hiroaki Takata, Yutaka Oka, Junichi Nakagawa, Akira Neoda
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Patent number: 7160503Abstract: A metal matrix composite was fabricated by adding particles of calcium hexaboride to a metal of aluminum, magnesium or titanium and their alloys. The resulting metal matrix composite is light weight has improved strength, increased elastic modulus and reduced thermal coefficient of expansion, thus making the metal matrix composite more useful in industry. A metal matrix composite is also formed by mixing particles of aluminum, magnesium, titanium or combinations thereof with particles of silicon lexaboride, calcium hexaboride, silicon tetraboride, calcium tetraboride or combinations thereof. The blended particles are processed according to powder metallurgical techniques to produce a metal matrix composite material.Type: GrantFiled: May 8, 2002Date of Patent: January 9, 2007Assignee: Saffil LimitedInventor: Samuel C. Weaver
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Patent number: 7108757Abstract: A reversible hydrogen storage alloy capable of storing large amounts of hydrogen and delivering reversibly large amounts of hydrogen at temperatures ranging from 0° C. up to 40° C. The hydrogen storage alloy is generally composed of titanium, vanadium, and chromium. The alloy may further include manganese. Modifier elements such as zirconium, iron, nickel, molybdenum, ruthenium, and/or cobalt, and scavenger elements such as misch metal, calcium, and/or magnesium may be included in the alloy to improve performance.Type: GrantFiled: August 8, 2003Date of Patent: September 19, 2006Assignee: Ovonic Hydrogen Systems LLCInventors: Baoquan Huang, Stanford R. Ovshinsky
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Patent number: 7037389Abstract: The present invention provides non-axially symmetrical manufactured parts of thickness less than 10 mm, made of ? or quasi-? titanium alloy, having a core microstructure constituted by whole grains presenting a slenderness ratio greater than 4 and an equivalent diameter lying in the range 10 ?m to 300 ?m. The invention also provides a method of manufacturing the parts by forging.Type: GrantFiled: February 28, 2003Date of Patent: May 2, 2006Assignee: Snecma MoteursInventors: Blandine Barbier, Philippe Gallois, Claude Mons, Agathe Venard, Pascal Vignolles
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Patent number: 7014722Abstract: In finifsh-cogging a high-purity titanium material into a cylindrical form as the final shape, if cylindrical cogging is performed in all stages of warm forging or if cylindrical cogging is performed in the initial stage of the warm forging, there is no need of peripherally restricting the cylindrical cogging material, so that even if longitudinal upset-forging is effected with an upsetting ratio of 2, the condition that the major diameter/minor diameter ratio of the section after forging is not more than 1.01 can be satisfied, developing superior upset-forgeability. This makes it possible, in producing disk-like targets for sputtering, to minimize cutting loss produced during the rolling and machining and to maximize the yield of products; therefore, the material can be widely used as a semiconductor material for electrodes and the like using a high-purity titanium material.Type: GrantFiled: August 10, 2000Date of Patent: March 21, 2006Assignee: Sumitomo Titanium CorporationInventors: Nobuhiro Arimoto, Tadashi Ogasawara, Isao Uemura, Youji Mitani, Takashi Oonishi
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Patent number: 6979375Abstract: A titanium alloy member is characterized in that it comprise 40% by weight or more titanium (Ti), a IVa group element and/or a Va group element other than the titanium, wherein a summed amount including the IVa group element and/or the Va group element as well as the titanium is 90% by weight or more, and one or more members made in an amount of from 0.2 to 2.0% by weight and selected from an interstitial element group consisting of oxygen, nitrogen and carbon, and that its basic structure is a body-centered tetragonal crystal or a body-centered cubic crystal in which a ratio (c/a) of a distance between atoms on the c-axis with respect to a distance between atoms on the a-axis falls in a range of from 0.9 to 1.1. This titanium alloy member has such working properties that conventional titanium alloys do not have, is flexible, exhibits a high strength, and can be utilized in a variety of products.Type: GrantFiled: May 1, 2001Date of Patent: December 27, 2005Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Tadahiko Furuta, Yoshiki Seno, JungHwan Hwang, Kazuaki Nishino, Takashi Saito
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Patent number: 6918971Abstract: A sheet, a plate, a bar or wire is made of Ti and has high ductility and low material anistropy in a plane of a sheet or plate, or in a sectional plane of a bar or a wire and contains Fe, in mass, at 0.15-0.5%, N at 0.015-0.041 and 0, with the balance Ti and unavoidable impurities. When the Fe content is defined as [Fe], the N content as [N] and the 0 content as [0], the oxygen equivalent value Q=[0]+2.77[N]+0.1 [Fe] is 0.11-0.28.Type: GrantFiled: August 22, 2002Date of Patent: July 19, 2005Assignee: Nippon Steel CorporationInventors: Hideki Fujii, Isamu Takayama, Yoshito Yamashita, Mitsuo Ishii, Kazuhiro Takahashi
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Patent number: 6863987Abstract: Titanium resistant to discoloration in an atmospheric environment characterized by having an average carbon concentration of 14 at % or less in a range to a depth of 100 nm from the surface and having an oxide film of a thickness of 12 to 40 nm at its surface. Titanium resistant to discoloration in an atmospheric environment characterized in that, in X-ray diffraction of its surface, a ratio (X1/X2) of a (200) peak intensity X1 of TiC to a (110) peak intensity X2 of titanium is not more than 0.18 and by having an oxide film of a thickness of 12 to 40 nm at its surface.Type: GrantFiled: February 23, 2001Date of Patent: March 8, 2005Assignee: Nippon Steel CorporationInventors: Michio Kaneko, Teruhiko Hayashi, Kazuhiro Takahashi, Kiyonori Tokuno, Junichi Tamenari, Kinichi Kimura, Hiroshi Shimizu, Shoichi Maruyama
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Patent number: 6849231Abstract: There is provided an ?-? type titanium alloy having a normal-temperature strength equivalent to, or exceeding that of a Ti-6Al-4V alloy generally used as a high-strength titanium alloy, and excellent in hot workability including hot forgeability and subsequent secondary workability, and capable of being hot-worked into a desired shape at a low cost efficiently. There is disclosed an ?-? type titanium alloy having high strength and excellent hot workability wherein 0.08-0.25% C is contained, the tensile strength at room temperature (25° C.) after annealing at 700° C. is 895 MPa or more, the flow stress upon greeble test at 850° C. is 200 MPa or less, and the tensile strength/flow stress ratio is 9 or more. A particularly preferred ?-? type titanium alloy comprises 3-7% Al and 0.08-025% C as ?-stabilizers, and 2.0-6.0% Cr and 0.3-1.0% Fe as ?-stabilizers.Type: GrantFiled: September 30, 2002Date of Patent: February 1, 2005Assignee: Kobe Steel, Ltd.Inventors: Soichiro Kojima, Hideto Oyama
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Patent number: 6849230Abstract: A mixture of two particulate phases used in the production of a green compact that can be sintered at higher temperatures. The first phase contains particles that consist of a metal and/or a metal allow and/or a metal compound. The second phase contains particles from the group of the inorganic compounds that do not release any decomposition products at temperatures of more than 400° C., that are interstitially soluble in the sintering metal phase, and/or that react with the second phase to stable compounds. The mixture, by providing the second phase, is effective in supporting the fine structure of the first phase against the forces of surface tensions during the sintering process. During sintering, the second phase remains thermally stable and substantially chemically inert with respect to the first phase.Type: GrantFiled: September 14, 1999Date of Patent: February 1, 2005Assignee: Stratec Medical AGInventor: Heinrich Feichtinger
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Patent number: 6833058Abstract: The invention encompasses methods of forming titanium-based mixed-metal materials and zirconium-based mixed-metal materials utilizing one or more of a reduction process, electrolysis process and iodide process. The invention also encompasses a sputtering target comprising zirconium and one or more elements selected from the group consisting of Al, B, Ba, Be, Ca, Ce, Co, Cs, Dy, Er, Fe, Gd, Hf, Ho, La, Mg, Mn, Mo, Nb, Nd, Ni, Pr, Sc, Sm, Sr, Ta, Ti, V, W, Y, and Yb. The invention also encompasses a sputtering target comprising titanium and boron.Type: GrantFiled: October 24, 2000Date of Patent: December 21, 2004Assignee: Honeywell International Inc.Inventors: Stephen P. Turner, Joseph E. Green, Rodney L. Scagline, Yun Xu
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Publication number: 20040244888Abstract: To provide a titanium alloy which is a high-strength low-alloy with a 750 MPa or more in terms of tensile strength. A production method is capable of producing the titanium alloy by using a low-priced, low-grade sponge titanium as a raw material. This high-strength low-alloy titanium alloy has an alloy composition containing O of from 0.2 to 0.8%, C of from 0.01 to 0.15%, N of from 0.01 to 0.07%, Fe of from 0.3 to 1.0% and the balance being substantially Ti. At the time of production, a low-grade sponge Ti containing N of 0.01% or more and Fe of 0.2% or more is used in at least a portion of raw materials to allow it to be a source of the aforementioned Ni and Fe components.Type: ApplicationFiled: March 9, 2004Publication date: December 9, 2004Inventors: Hiroyuki Horimura, Kosuke Doi, Akihiro Suzuki, Hisao Kamiya
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Publication number: 20040243133Abstract: Various elements and alloys selected to achieve both biocompatibility and low melting point for use in infiltrating a porous matrix. The infiltrated porous matrix may be made of ceramic, metal, bioglass, or other suitable material. The infiltrated matrix may be used as a biomedical implant, such as for bone repair and regeneration. The matrix may be manufactured using solid free form fabrication techniques such as three-dimensional printing.Type: ApplicationFiled: March 5, 2004Publication date: December 2, 2004Applicant: Therics, Inc.Inventor: Peter A. Materna
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Patent number: 6786984Abstract: This present invention relates to an alloy comprising Sn, at least one of Ti and Zr and at least one of Nb and Ta as the major elements. The total percentage of the Nb and Ta in the alloy material is preferably from 8 to 20 atom % and the percentage of the Sn in the alloy material is preferably from 2 to 6 atom %. The alloy material is preferably Ni-free and has shape memory characteristics or superelasticity.Type: GrantFiled: November 9, 2000Date of Patent: September 7, 2004Assignee: Tomy IncorporatedInventors: Shuji Hanada, Sadao Watanabe, Naoya Masahashi, Hideki Hosoda, Kikuo Nishi
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Publication number: 20040170519Abstract: A titanium auto part having a strength equal to the conventional JIS Type 2 and Type 3 and a phase structure enabling design of similar parts and processes and having a high residual ductility after being worked. A titanium auto part characterized by containing, by wt %, Fe: 0.15 to 0.5%, nitrogen: 0.015 to 0.04%, oxygen, and the balance of titanium and unavoidable impurities, wherein, when the Fe content is [Fe], the nitrogen content is [N], and the oxygen content is [O], the oxygen equivalent value Q=[O]+2.77 [N]+0.1 [Fe] is Q: 0.11 to 0.28%. Q: 0.11 to 0.20% is preferable. As the auto part, the invention is suitably applied to any of a muffler, exhaust pipe, motorcycle frame, motorcycle rear fork, and motorcycle front fork inner pipe.Type: ApplicationFiled: December 10, 2003Publication date: September 2, 2004Inventors: Hideki Fujii, Kazuhiro Takahashi, Marui Yuji, Takahashi Kyo
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Patent number: 6771490Abstract: A metal frame for electronic hardware and a method of manufacturing such a frame wherein at least a portion of the frame is made of bulk-solidifying amorphous alloys or bulk-solidifying amorphous alloy-composites is provided. The metal frames of the invention are preferably made of bulk-forming amorphous alloys or bulk-forming amorphous alloy-composites having an elastic limit for the metal frame of at least about 1.5%, and preferably greater than about 2.0%, a &Dgr;Tsc of more than 30° C., and at least one of the following properties: a hardness value of about 4 GPA or more, and preferably 5.5 GPA or more; a yield strength of about 2 GPa or more; a fracture toughness of about 10 ksi-sqrt(in) (sqrt:squre root) or more, and preferably 20 ksi sqrt(in) or more; and a density of at least 4.5 g/cc or more.Type: GrantFiled: June 7, 2002Date of Patent: August 3, 2004Assignee: Liquidmetal TechnologiesInventors: Atakan Peker, William L. Johnson
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Patent number: 6767418Abstract: A Ti—Zr type alloy manifesting excellent plastic workability at normal temperature fit for the use in general industry, allowing improvement in corrosion resistance fit for the use in medical treatment, offering improved corrosion resistance in an acidic solution, particularly a HCl solution, and having flexibility as evinced by a low Young's modulus on a par with a bone; and a medical appliance such as a guide wire to be directly inserted into a blood vessel of a human body under the X-ray fluoroscopy and a stent retained in a human body for a long time, which are made of the Ti—Zr type alloy are provided. The Ti—Zr type alloy of the present invention consists of 25 to 50% by weight of Ti, 25 to 60% by weight of Zr, 5 to 30% by weight of Nb, and 5 to 40% by weight of Ta, provided that the weight ratio of Zr to Ti be in the range of 0.5 to 1.5 and the weight ratio of Nb to Ta be in the range of 0.125 to 1.5.Type: GrantFiled: April 17, 2000Date of Patent: July 27, 2004Assignees: Terumo Kabushiki Kaisha, Japan Basic Material Co., Ltd., Akihisa InoueInventors: Tao Zhang, Kazuya Sato, Kei Kurosaka, Yuzi Ogata, Xinmin Wang, Takashi Kaneko, Yuu Kasori
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Publication number: 20040136859Abstract: In order to improve castability of a titanium alloy, 0.01-5 wt %, preferably 0.1-3 wt %, of bismuth is introduced into the titanium alloy, based on the weight of bismuth and the titanium alloy. The titanium alloy is suitable for making a dental casting or a medical implant by casting.Type: ApplicationFiled: January 5, 2004Publication date: July 15, 2004Applicant: CANA LAB CORPORATIONInventors: Jiin-Huey Chern Lin, Chien-Ping Ju, Wen-Wei Cheng, Dan Jae Lin, Chih-Min Lee
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Patent number: 6759134Abstract: A process for forming a metallic article having a black ornamental surface includes the steps of metallurgically providing an alloy containing between about 51 and 70 about percent by weight of titanium, between about 3 and about 17 percent by weight of niobium, and the balance of a metal selected from the group consisting of zirconium, tantalum, molybdenum, hafnium zirconium, chromium, and mixtures thereof. The alloy is then casted and/or metal worked into a workpiece having a desired geometry and surface texture. The workpiece thereof is then baked in a kiln or oven in a substantially air atmosphere of between about 450 and about 850 degrees C. for a period of between about one and about 29 minutes. Resultant of such baking, there is produced a durable black surface layer consisting substantially of an oxide of niobium which is adhered to the substrate of the workpiece which remains unoxidized.Type: GrantFiled: April 30, 2002Date of Patent: July 6, 2004Inventor: Edward Rosenberg
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Patent number: 6755948Abstract: A titanium sputtering target that contains a concentration of oxygen in an amount of 20 ppm or less and has a maximum grain diameter of 20 &mgr;m or less. The target permits a sputtering operation to be accomplished substantially free from the formation of particles or the occurrence of an abnormal discharge phenomenon. In addition, the target contains a reduced amount of contaminants and is soft.Type: GrantFiled: April 1, 2002Date of Patent: June 29, 2004Assignee: Nikko Materials Company, LimitedInventors: Hideaki Fukuyo, Yuichiro Shindo, Hideyuki Takahashi
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Patent number: 6752882Abstract: A biocompatible binary titanium-niobium (Ti—Nb) alloy having a low modulus and a high strength, and containing &agr;″ phase as a major phase is disclosed. The binary Ti—Nb alloy contains 10-30 wt % of Nb, preferably 13-28 wt % of Nb, and the balance titanium, which is suitable for making a medical implant such as an orthopedic implant or dental implant.Type: GrantFiled: April 30, 2002Date of Patent: June 22, 2004Inventors: Jiin-Huey Chern Lin, Chien-Ping Ju, Chih-Min Lee
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Publication number: 20040115083Abstract: A high-strength titanium alloy of the present invention includes Ti as a major component, 15 to 30 at % Va group element, and 1.5 to 7 at % oxygen (O) when the entirety is taken as 100 atomic % (at %), and its tensile strength is 1,000 MPa or more.Type: ApplicationFiled: September 26, 2003Publication date: June 17, 2004Inventors: Tadahiko Furuta, Kazuaki Nishino, Takashi Saito, JungHwan Hwang
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Patent number: 6726787Abstract: Quenching a work piece made of a titanium alloy having a temperature higher than 800° C. to a temperature lower than 500° C. at a cooling rate greater than 10° C./second between 800° C. and 500° C. is used to render the cooled work piece containing &agr;″ phase as a major phase. The titanium alloy composition contains at least one isomorphous beta stabilizing element selected from Mo, Nb, Ta and W; and the balance Ti, wherein said composition has a Mo equivalent value from about 6 to about 9. The work piece is preferably a medical device.Type: GrantFiled: December 26, 2002Date of Patent: April 27, 2004Inventors: Jiin-Huey Chern Lin, Chien-Ping Ju, Chih-Min Lee
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Patent number: 6692586Abstract: This invention relates to a high temperature melting composition and a method of using the composition for brazing high temperature niobium-based substrates, such as niobium-based refractory metal-intermetallic compositions (RMIC), including but not restricted to niobium-silicide composite alloys. The high temperature melting composition can include one or more alloys. The alloys include a base element selected from titanium, tantalum, niobium, hafnium, silicon, and germanium. The alloys also include at least one secondary element that is different from the base element. The secondary element can be selected from chromium, aluminum, niobium, boron, silicon, germanium and mixtures thereof. When two or more alloys are included in the composition, it is preferable, but not required, to select at least one lower melting alloy and at least one higher melting alloy. The composition is preferably a homogeneous mixture of the two or more alloys combined in powder form.Type: GrantFiled: May 23, 2001Date of Patent: February 17, 2004Assignee: Rolls-Royce CorporationInventors: Raymond R. Xu, Amit Chatterjee
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Publication number: 20030192628Abstract: A Ti—Ni shape memory alloy with ductility, including Ti of 50˜66 atomic % in a composition, and in which precipitation of Ti2Ni phases at grain boundaries is suppressed.Type: ApplicationFiled: May 5, 2003Publication date: October 16, 2003Inventors: Akira Ishida, Shuichi Miyazaki
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Patent number: 6632396Abstract: Titanium-based alloy contains, % by mass: aluminum 2.2 to 3.8; vanadium 4.5 to 5.9; moloybdenum 4.5 to 5.9; chromium 2.0 to 3.6; iron 0.2 to 0.8; zirconium 0.0l to 0.08; carbon 0.01 to 0.25; oxygen 0.03 to 0.25; titanium being the balance. The alloy possesses high ability to volume deformation in cold state (is easily rolled into rods), does not have tendency to form high-melting inclusions and is efficiently enforced with thermal treatment with obtaining of high level of strength and plasticity characteristics.Type: GrantFiled: September 13, 2001Date of Patent: October 14, 2003Inventors: Vladislav Valentinovich Tetjukhin, Jurv Ivanovich Zakharov, Igor Vasilievich Levin
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Patent number: 6623543Abstract: A method for forming dendritic metal powders, comprising the steps of: (1) heating a powder comprising non-dendritic particles, under conditions suitable for initial stage sintering, to form a lightly sintered material; and (2) breaking the lightly sintered material to form a powder comprising dendritic particles. In one embodiment, the lightly sintered material is broken by brushing the material through a screen. Another aspect of the present invention comprises the dendritic particles that are produced by the method described above. These particles can comprise any suitable metal, such as transition metals, rare earth metals, main group metals or metalloids or an alloy of two or more such metals. The particles can also comprise a ceramic material, such as a metal oxide. These particles are characterized by a dendritic, highly anisotropic, morphology arising from the fusion of substantially non-dendritic particles, and by a low apparent density relative to the substantially non-dendritic starting material.Type: GrantFiled: November 28, 2000Date of Patent: September 23, 2003Assignee: Mykrolis CorporationInventors: Robert S. Zeller, Christopher J. Vroman
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Patent number: 6607693Abstract: A titanium alloy according to the present invention is characterized in that it comprises an element of Va group (the vanadium group) in an amount of 30-60% by weight and the balance of titanium substantially, exhibits an average Young's modulus of 75 GPa or less, and exhibits a tensile elastic limit strength of 700 MPa or more. This titanium alloy can be used in a variety of products, which are required to exhibit a low Young's modulus, a high elastic deformability and a high strength, in a variety of fields.Type: GrantFiled: February 12, 2001Date of Patent: August 19, 2003Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Takashi Saito, Tadahiko Furuta, Kazuaki Nishino, Hiroyuki Takamiya
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Patent number: 6596228Abstract: Described is a method and apparatus for producing high purity titanium and high purity titanium so produced. The process contemplates producing titanium sponge in a container and performing titanium fused salt electrolysis in situ in the same container to produce high purity titanium crystal, and where especially low oxygen content is desired, to treat the high purity titanium crystal as produced with iodine.Type: GrantFiled: October 29, 2001Date of Patent: July 22, 2003Assignee: Honeywell International Inc.Inventors: Harry Rosenberg, Nigel Winters, Yun Xu
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Publication number: 20030103861Abstract: A modified Ti—Mn2 hydrogen storage alloy. The alloy generally is comprised of Ti and Mn. A generic formula for the alloy is: TiQ−XZrXMnZ−YAY, where A is generally one or more of V, Cr, Fe, Ni and Al. Most preferably A is one or more of V, Cr, and Fe. The subscript Q is preferably between 0.9 and 1.1, and most preferably Q is 1.0. The subscript X is between 0.0 and 0.35, more preferably X is between 0.1 and 0.2, and most preferably X is between 0.1 and 0.15. The subscript Y is preferably between 0.3 and 1.8, more preferably Y is between 0.6 and 1.2,and most preferably Y is between 0.6 and 1.0. The subscript Z is preferably between 1.8 and 2.1,and most preferably Z is between 1.8 and 2.0. The alloys are generally single phase materials, exhibiting a hexagonal C14 Laves phase crystalline structure.Type: ApplicationFiled: November 30, 2001Publication date: June 5, 2003Inventors: Ned T. Stetson, Jun Yang, Benjamin Chao, Vitaliy Myasnikov, Zhaosheng Tan
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Publication number: 20030098099Abstract: There is provided an &agr;-&bgr; type titanium alloy having a normal-temperature strength equivalent to, or exceeding that of a Ti-6Al-4V alloy generally used as a high-strength titanium alloy, and excellent in hot workability including hot forgeability and subsequent secondary workability, and capable of being hot-worked into a desired shape at a low cost efficiently. There is disclosed an &agr;-&bgr; type titanium alloy having high strength and excellent hot workability wherein 0.08-0.25% C is contained, the tensile strength at room temperature (25° C.) after annealing at 700° C. is 895 MPa or more, the flow stress upon greeble test at 850° C. is 200 MPa or less, and the tensile strength/flow stress ratio is 9 or more. A particularly preferred &agr;-&bgr; type titanium alloy comprises 3-7% Al and 0.08-025% C as &agr;-stabilizers, and 2.0-6.0% Cr and 0.3-1.0% Fe as &bgr;-stabilizers.Type: ApplicationFiled: September 30, 2002Publication date: May 29, 2003Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO (KOBE STEEL, LTD,)Inventors: Soichiro Kojima, Hideto Oyama
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Publication number: 20030094222Abstract: Quenching a work piece made of a titanium alloy having a temperature higher than 800° C. to a temperature lower than 500° C. at a cooling rate greater than 10° C./second between 800° C. and 500° C. is used to render the cooled work piece containing &agr;″ phase as a major phase. The titanium alloy composition contains at least one isomorphous beta stabilizing element selected from Mo, Nb, Ta and W; and the balance Ti, wherein said composition has a Mo equivalent value from about 6 to about 9. The work piece is preferably a medical device.Type: ApplicationFiled: December 26, 2002Publication date: May 22, 2003Applicant: Jiin-Huey Chern LinInventors: Jiin-Huey Chern Lin, Chien-Ping Ju, Chih-Min Lee
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Patent number: 6562207Abstract: Sputter target, method of manufacture of same and sputter coating process using the target as a sputtering source are disclosed. The sputter target comprises an Me/Si multi-phase, consolidated blend wherein the Si component is present in a very small amount of about trace—0.99 mole Si:1 mole Me. Preferably, Me comprises one or more of Ta, Ti, Mo, or W. The targets are made from the requisite powders via HIP consolidation to provide densities of greater than 98 % of the theoretical density. The targets are especially useful in reactive cathodic sputtering systems employing N2 as the reactive gas to form amorphous Me/Si/N layers.Type: GrantFiled: January 14, 2000Date of Patent: May 13, 2003Assignee: Tosoh SMD, Inc.Inventor: Eugene Y. Ivanov
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Titanium alloy having high ductility, fatigue strength and rigidity and method of manufacturing same
Publication number: 20030084970Abstract: A titanium alloy is provided wherein metal boride is uniformly crystallized and/or precipitated in the matrix. The heating temperature in the finishing hot working is set smaller than the &bgr; transus temperature by not less than 10° C., thereby causing the matrix to include an equiaxial &agr; structure in a rate of not less than 40 vol %. This titanium alloy has excellent properties, i.e., high rigidity, ductility and fatigue strength, which are all required for structural components, and therefore can be widely applied to a mechanical component such as an engine of an automobile, a structural component in an aircraft as well as a component for a high speed rail vehicle.Type: ApplicationFiled: November 26, 2002Publication date: May 8, 2003Inventors: Nozomu Ariyasu, Satoshi Matsumoto -
Publication number: 20030075020Abstract: The invention relates to a method for producing a grain refiner on the basis of an aluminum-titanium-boron prealloy. According to the inventive method, starting materials that contain Ti and B are introduced into an aluminum melt while TiB2 particles are formed, and the prealloy melt produced is allowed to solidify. The prealloy is set in motion at a temperature between the liquidus temperature (TLAl3Ti) of the Al3Ti phase and the solidus temperature (TSV) of the prealloy for a period (&Dgr;td) sufficient to disperse the TiB2 particles in the melt. The melt is simultaneously cooled off at a first rate of cooling (v1) so that the TiB2 particles function as the nuclei for the Al3Ti phase that is formed below the liquidus temperature (TLAl3Ti) and the surface of the TiB2 particles is at least partially covered by an Al3Ti coating.Type: ApplicationFiled: September 3, 2002Publication date: April 24, 2003Inventors: Walter Hotz, Heinrich Homberger