Titanium Base Patents (Class 420/417)
  • Publication number: 20030049154
    Abstract: This invention relates to a high temperature melting composition and a method of using the composition for brazing high temperature niobium-based substrates, such as niobium-based refractory metal-intermetallic compositions (RMIC), including but not restricted to niobium-silicide composite alloys. The high temperature melting composition can include one or more alloys. The alloys include a base element selected from titanium, tantalum, niobium, hafnium, silicon, and germanium. The alloys also include at least one secondary element that is different from the base element. The secondary element can be selected from chromium, aluminum, niobium, boron, silicon, germanium and mixtures thereof. When two or more alloys are included in the composition, it is preferable, but not required, to select at least one lower melting alloy and at least one higher melting alloy. The composition is preferably a homogeneous mixture of the two or more alloys combined in powder form.
    Type: Application
    Filed: May 23, 2001
    Publication date: March 13, 2003
    Inventors: Raymond R. Xu, Amit Chatterjee
  • Patent number: 6511587
    Abstract: A process for the prearation of a sputtering target which comprises sub-stoichiometric titanium dioxide, TiOx, where x is below 2 having an electrical resistivity of less than 0.5 ohm.cm, optionally together with niobium oxide, which process comprises plasma spraying titanium dioxide, TiO2, optionally together with niobium oxide, onto a target base in an atmosphere which is oxygen deficient and which does not contain oxygen-containing compounds, the target base being coated with TiOx, which is solidified by cooling under conditions which prevent the sub-stoichiometric titanium dioxide from combining with oxygen.
    Type: Grant
    Filed: December 5, 2001
    Date of Patent: January 28, 2003
    Assignee: Bekaert VDS
    Inventor: Johan Emile Marie Vanderstraeten
  • Publication number: 20020189404
    Abstract: An improved process for successful and homogeneous incorporation of ruthenium and iridium into titanium and titanium alloy melts, ingots, and castings via traditional melting processes (e.g., VAR and cold-hearth) has been developed. This result is achieved through the use of low-melting point Ti-Ru or Ti-Ir binary master alloys within the general composition range of ≦45 wt. % Ru and with a preferred composition of Ti-(15-40 wt. % Ru), or within the general composition range of ≦61 wt. % Ir and with a preferred composition of TI-(20-58 wt. % Ir). Primary features are its lower melting point than pure titanium, lower density than pure Ru and Ir metals, and the ability to be readily processed into granular or powder forms.
    Type: Application
    Filed: May 7, 2002
    Publication date: December 19, 2002
    Inventors: Ronald W. Schutz, Kuang-O Yu, Richard L. Porter, Frank P. Spadafora
  • Publication number: 20020179197
    Abstract: In order to improve castability of a titanium alloy, 0.1-5 wt %, preferably 0.5-3 wt %, of bismuth is doped, based on the weight of bismuth and the titanium alloy. The titanium alloy is for making a dental casting or a medical implant.
    Type: Application
    Filed: June 26, 2002
    Publication date: December 5, 2002
    Applicant: Jiin-Huey Chern LIN
    Inventors: Jiin-Huey Chern Lin, Chien-Ping Ju, Wen-Wei Cheng
  • Patent number: 6461686
    Abstract: A process for the preparation of a sputtering target which comprises sub-stoichiometric titanium dioxide, TiOx, where x is below 2 having an electrical resistivity of less than 0.5 ohm·cm, optionally together with niobium oxide, which process comprises plasma spraying titanium dioxide, TiO2, optionally together with niobium oxide, onto a target base in an atmosphere which is oxygen deficient and which does not contain oxygen-containing compounds, the target base being coated with TiOx, which is solidified by cooling under conditions which prevent the sub-stoichiometric titanium dioxide from combining with oxygen.
    Type: Grant
    Filed: July 14, 1999
    Date of Patent: October 8, 2002
    Assignee: Bekaert VDS
    Inventor: Johan Emile Marie Vanderstraeten
  • Publication number: 20020139667
    Abstract: The invention includes a method of forming a material which comprises at least two elements. More specifically, the method comprises providing an electrolytic cell comprising a cathode, an anode, and an electrolytic solution extending between the cathode and anode. A metallic product is electrolytically formed within the electrolytic cell. The forming of the metallic product comprises primarily electrorefining of a first element of the at least two elements and primarily electrowinning of a second element of the at least two elements. The invention also includes a mixed metal product comprising at least two elements, such as a product comprising tantalum and titanium.
    Type: Application
    Filed: March 29, 2001
    Publication date: October 3, 2002
    Inventor: Guangxin Wang
  • Patent number: 6428634
    Abstract: A method of processing a Ni—Ti—Nb based alloy which contains from about 4 to about 14 atomic percent Nb and in which the ratio of atomic percent Ni to atomic percent Ti is from about 3.8 to 1.2, comprising working the alloy sufficient to impart a textured structure to the alloy, at a temperature below the recrystallisation temperature of the alloy. Preferably, the alloy is worked at least 10%, by a technique such as rolling or drawing, or another technique which produces a similar crystal structure. The alloy has increased stiffness compared with Ni—Ti binary alloys with superelastic properties.
    Type: Grant
    Filed: April 24, 1997
    Date of Patent: August 6, 2002
    Assignee: Ormco Corporation
    Inventors: Petrus A. Besselink, Rohit C. L. Sachdeva
  • Patent number: 6409792
    Abstract: An improved process for successful and homogeneous incorporation of ruthenium and iridium into titanium and titanium alloy melts, ingots, and castings via traditional melting processes (e.g., VAR and cold-hearth) has been developed. This result is achieved through the use of low-melting point Ti-Ru or Ti—Ir binary master alloys within the general composition range of ≦45 wt. % Ru and with a preferred composition of Ti-(15-40 wt. % Ru), or within the general composition range of ≦61 wt. % Ir and with a preferred composition of TI-(20-58 wt. % Ir). Primary features are its lower melting point than pure titanium, lower density than pure Ru and Ir metals, and the ability to be readily processed into granular or powder forms.
    Type: Grant
    Filed: November 6, 2000
    Date of Patent: June 25, 2002
    Assignee: RMI Titanium Company
    Inventors: Ronald W. Schutz, Kuang-O Yu, Richard L. Porter, Frank P. Spadafora
  • Patent number: 6409852
    Abstract: A biocompatible titanium alloy with low modulus comprising &agr;″ phase as a major phase and containing from about 6 to about 9 wt % of molybdenum, from 0 to about 1 wt % of an alloying element and the balance titanium. The alloying element is niobium and/or zirconium. The biocompatible titanium alloy is suitable for use as a material for a medical prosthetic implant.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: June 25, 2002
    Inventors: Jiin-Huey Chern Lin, Chien-Ping Ju, Wen-Fu Ho
  • Patent number: 6401537
    Abstract: A method for inspecting a titanium-based alloy that comprises alpha phase grains to detect flaws in the titanium-based alloy, the titanium-based alloy comprises an alpha phase that is provided by thermomechanically processing the alloy to provide a microstructure which comprises the alpha phase that defines an average grain size and a crystallographic orientation of the grains of the alpha phase that is highly randomized. The method comprises ultrasonically inspecting the titanium-based alloy using an ultrasonic beam, the ultrasonic beam comprising a cross-sectional area that is less than the average grain size of the alpha phase in the titanium-based alloy; and determining flaws based on the step of ultrasonic inspecting.
    Type: Grant
    Filed: July 2, 1999
    Date of Patent: June 11, 2002
    Assignee: General Electric Company
    Inventors: Michael Francis Xavier Gigliotti, Jr., Robert Snee Gilmore, John Broddus Deaton, Jr., John Alan Sutliff
  • Patent number: 6402859
    Abstract: The diamter of &bgr;-titanium alloy wire is reduced by cold wire-drawing and the &bgr;-titanium alloy wire is subjected to heat treatment. The heat treatment comprises the first aging process for precipitation strengthening and the second aging process for removing processing strain. &bgr;-titanium alloy wire is heat-treated under the supply of tension at the second aging process.
    Type: Grant
    Filed: September 6, 2000
    Date of Patent: June 11, 2002
    Assignee: Terumo Corporation
    Inventors: Naoki Ishii, Takashi Kaneko, Shin Sumimoto, Hideki Yamamoto, Ichiro Nagao
  • Patent number: 6399215
    Abstract: We disclose ultrafine-grained titanium. A coarse-grained titanium billet is subjected to multiple extrusions through a preheated equal channel angular extrusion (ECAE) die, with billet rotation between subsequent extrusions. The resulting billet is cold processed by cold rolling and/or cold extrusion, with optional annealing. The resulting ultrafine-grained titanium has greatly improved mechanical properties and is used to make medical implants.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: June 4, 2002
    Assignee: The Regents of the University of California
    Inventors: Yuntian T. Zhu, Terry C. Lowe, Ruslan Z. Valiev, Vladimir V. Stolyarov, Vladimir V. Latysh, Georgy J. Raab
  • Patent number: 6344170
    Abstract: The present invention relates to a sintered body of a carbonitride alloy with titanium as main component which has improved properties particularly when used as cutting tool material in general finishing cutting operations requiring high deformation resistance in combination with relatively high toughness. This has been achieved by combining a carbonitride based hard phase of specific chemical composition with an extremely solution hardened Co-based binder phase.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: February 5, 2002
    Assignee: Sandvik AB
    Inventors: Ulf Rolander, Gerold Weinl, Anders Piirhonen, Marco Zwinkels
  • Patent number: 6340445
    Abstract: A sintered body of a carbonitride alloy with titanium as main component which has improved properties particularly when used as cutting tool material in light finishing cutting operations at high cutting speed. This has been achieved by combining a carbonitride based hard phase of specific chemical composition with an extremely solution hardened Co-based binder phase.
    Type: Grant
    Filed: May 3, 2000
    Date of Patent: January 22, 2002
    Assignee: Sandvik AB
    Inventors: Anders Piirhonen, Marco Zwinkels, Ulf Rolander, Gerold Weinl
  • Patent number: 6338764
    Abstract: To provide a hydrogen absorbing alloy having a BCC (body-centered cubic structure) as a crystal structure, and particularly a hydrogen-absorbing alloy for a nickel-hydride cell having excellent discharge capacity and durability (cycle characteristics), said hydrogen-absorbing alloy having a composition expressed by the general formula Ti(100−a−b−c−d)CraVbNicXd, where X is at least one member selected from the group consisting of Y (yttrium), lanthanoids, Pd and Pt, and each of a, b, c and d is represented, in terms of at %, by the relations 8≦a≦50, 30<b≦60, 5≦c≦15, 2≦d≦10 and 40≦a+b+c+d≦90, wherein the crystal structure of a principal phase is a body-centered cubic structure, and further, the alloy contains at least one of Mo and W in place of V and at least one member selected from the group consisting of Y (yttrium), lanthanoids, Pd and Pt, and its crystal structure is converted to the body-centered cubic structure by heat-treatment.
    Type: Grant
    Filed: April 29, 1999
    Date of Patent: January 15, 2002
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Toshihiro Mori, Hideki Iba
  • Patent number: 6334913
    Abstract: A corrosion-resistant Ti alloy includes Pd in an amount of 0.020-0.050 mass %, and includes one or more platinum group elements other than Pd in an amount of one-third or more of the mass of Pd, with the balance being composed of allowable components and Ti. This alloy exhibits excellent corrosion-resistance. If the Fe content is 0.05% or less and O content is 0.05% or less, excellent cold-workability can be obtained. If the Pd content is 0.030% or less, not only cold-workability and corrosion-resistance but also resistance against hydrogen absorption can be obtained.
    Type: Grant
    Filed: December 27, 1999
    Date of Patent: January 1, 2002
    Assignee: Kobe Steel, Ltd.
    Inventors: Takashi Yashiki, Hideto Ohyama
  • Patent number: 6309595
    Abstract: This invention includes a method and an apparatus for producing high purity titanium and high purity titanium so produced. The high purity titanium comprises titanium and less than 0.1 ppm, by weight, total of sodium, potassium, aluminum, iron, chromium, zirconium, vanadium and nickel.
    Type: Grant
    Filed: December 19, 1997
    Date of Patent: October 30, 2001
    Assignee: The AltalGroup, Inc
    Inventors: Harry Rosenberg, Nigel Winters, Yun Xu
  • Patent number: 6258184
    Abstract: A BCC type hydrogen-absorbing alloy, which uses a ferroalloy, is advantageous from the aspect of the production cost and exhibits excellent hydrogen absorption and desorption characteristics due to a fine structure constituted by spinodal decomposition even when the iron component is increased. The hydrogen-absorbing alloy is expressed by the general formula AxVayBz, where A is at least one of Ti and Zr, Va is at least one member of the Group Va elements of the Periodic Table consisting of V, Nb and Ta, and B contains at least Fe and is at least one member selected from the group consisting of Cr, Mn, Co, Ni, Cu, Al, Mo and W, each of x, y and z satisfies the relation, in terms of of the atomic number ratio, 0≦x≦70, 0≦y≦50, x+y+z=100, and x/z=0.25 to 2.0, the phase of the body-centered cubic structure is at least 50% in terms of the phase fraction and its lattice constant is at least 0.2950 nm but not greater than 0.3100 nm.
    Type: Grant
    Filed: April 13, 1999
    Date of Patent: July 10, 2001
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Hideki Iba, Toshihiro Mori, Yasuhide Kurimoto
  • Patent number: 6210634
    Abstract: The crude Ti particles prepared by molten salt electrolysis or Iodide method are classified into each particle diameter according to contents of impurities, and the crude Ti particles having a desired particle diameter are selected from the crude Ti particles classified depending on each particle diameter. Otherwise, the crude Ti particles are acid-treated. Then they are electron-beam-melted. Through the above production process, there is prepared a highly purified Ti material having an oxygen content of not more than 350 ppm, Fe, Ni and Cr contents of not more than 15 ppm each, Na and K contents of not more than 0.5 ppm each, a reduction of area as a material characteristic of not less than 70%, and a thermal conductivity of not less than 16 W/m K. In short, the highly purified Ti material satisfying high purity, good processability and good thermal conductivity can be obtained.
    Type: Grant
    Filed: March 29, 1999
    Date of Patent: April 3, 2001
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takashi Ishigami, Mituo Kawai, Noriaki Yagi
  • Patent number: 6197085
    Abstract: A method for forming dendritic metal powders, comprising the steps of: (1) heating a powder comprising non-dendritic particles, under conditions suitable for initial stage sintering, to form a lightly sintered material; and (2) breaking the lightly sintered material to form a powder comprising dendritic particles. In one embodiment, the lightly sintered material is broken by brushing the material through a screen. Another aspect of the present invention comprises the dendritic particles that are produced by the method described above. These particles can comprise any suitable metal, such as transition metals, rare earth metals, main group metals or metalloids or an alloy of two or more such metals. The particles can also comprise a ceramic material, such as a metal oxide. These particles are characterized by a dendritic, highly anisotropic, morphology arising from the fusion of substantially non-dendritic particles, and by a low apparent density relative to the substantially non-dendritic starting material.
    Type: Grant
    Filed: October 8, 1998
    Date of Patent: March 6, 2001
    Assignee: Millipore Corporation
    Inventors: Robert S. Zeller, Christopher J. Vroman
  • Patent number: 6193856
    Abstract: A sputtering target comprising a substrate and a target material formed on the substrate, wherein the target material comprises a metal oxide of the chemical formula MOx as the main component, wherein MOx is a metal oxide which is deficient in oxygen as compared with the stoichiometric composition, and M is at least one metal selected from the group consisting of Ti, Nb, Ta, Mo, W, Zr and Hf, a process for its production, and a method for forming a film having a high refractive index.
    Type: Grant
    Filed: March 12, 1998
    Date of Patent: February 27, 2001
    Assignee: Asahi Glass Company Ltd.
    Inventors: Otojiro Kida, Akira Mitsui, Eri Suzuki, Hisashi Osaki, Atsushi Hayashi
  • Patent number: 6063211
    Abstract: A high strength, high ductility titanium alloy comprising O, N and Fe as strengthening elements and the balance substantially Ti, the contents of the strengthening elements satisfying the following relationships (1) to (3):(1) from 0.9 to 2.3% by weight of Fe,(2) up to 0.05% by weight of N, and(3) an oxygen equivalent value Q, which is defined by the formula mentioned below, of 0.34 to 1.00Q=[O]+2.77[N]+0.1[Fe]wherein [O] is an oxygen content (% by weight), [N] is a nitrogen content (% by weight) and [Fe] is an iron content (% by weight), the titanium alloy having a tensile strength of at least 700 MPa and an elongation of at least 15%. Part of Fe may be replaced with Cr and/or Ni. Fe, Cr and Ni may be introduced from a carbon steel or stainless steel, or they may be introduced from sponge titanium containing these elements.
    Type: Grant
    Filed: February 7, 1997
    Date of Patent: May 16, 2000
    Assignees: Nippon Steel Corporation, Toho Titanium Co., Ltd.
    Inventors: Seiichi Soeda, Hideki Fujii, Hiroyuki Okano, Michio Hanaki
  • Patent number: 6053992
    Abstract: A mechanism that uses the shape recovery of a shape memory alloy for sealing openings or high pressure passages. A component made of a shape memory alloy can be processed in its martensitic state to have a reduced dimension smaller than that of the opening or the passage to be sealed. Upon heating, shape recovery takes place which is associated with the reverse crystalline phase transformation of martensite. The shape recovery of the previously processed shape memory alloy component yields a diameter which is greater than that of the opening or passage to be sealed. The shape recovery provides the dimensional interference and force required for sealing.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: April 25, 2000
    Assignee: Memry Corporation
    Inventors: Ming H. Wu, L. McD. Schetky
  • Patent number: 6027585
    Abstract: A process of preparing a titanium-tantalum alloy including forming a suite mixture of essentially pure titanium powder and essentially pure tantalum powder, melting the mixture of titanium powder and tantalum powder by plasma torch melting under a pressure greater than atmospheric pressure to form a titanium-tantalum solution, and casting the molten solution of titanium-tantalum to form a solid homogeneous titanium-tantalum product is disclosed.The process can further include hot-rolling the cast solid homogeneous titanium-tantalum product to form a sheet of the titanium-tantalum product.
    Type: Grant
    Filed: March 14, 1995
    Date of Patent: February 22, 2000
    Assignee: The Regents of the University of California office of Technology Transfer
    Inventors: R. Alan Patterson, Paul S. Dunn, John F. Bingert, James D. Cotton
  • Patent number: 6024852
    Abstract: The present invention provides a sputtering target which generates a reduced quantity of particles during a sputtering and a method for producing such a sputtering target.Mirror treatment is carried out to a sputter surface 2 which is sputtered when forming a thin film, so that the sputter surface 2 has an arithmetic mean roughness Ra of 0.01 .mu.m or below. A sputtering target 1 with such a smooth sputter surface 2 having a small surface roughness enables to reduce a number of particles generated during a sputtering.
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: February 15, 2000
    Assignee: Sony Corporation
    Inventors: Hidemasa Tamura, Norio Yokoyama, Eiichi Shimizu, Fumio Sasaki
  • Patent number: 6007923
    Abstract: A joined tubular body comprises a titanium alloy pipe of which crystal grain is hard to coarsen at the time of welding or hot-extruding, which consists by weight percentage of at least one element selected from 0.01.about.10% of S, 0.01.about.10% of Se and 0.01.about.10% of Te (the total sum does not exceed 10%), one or both of 0.01.about.10% REM and 0.01.about.10% of Ca (the total sum does not exceed 10%), and the above pipe is joined to a titanium alloy pipe consisting of the above elements and also at least one element selected from Al.ltoreq.10%, V.ltoreq.25%, Sn.ltoreq.15%, Co.ltoreq.10%, Cu.ltoreq.10%, Ta.ltoreq.15%, Mn.ltoreq.10%, Hf.ltoreq.10%, W.ltoreq.10%, Si.ltoreq.0.5%, Nb.ltoreq.20%, Zr.ltoreq.10%, Mo.ltoreq.15%, and 0.ltoreq.0.1% (the total sum does not exceed 30%).
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: December 28, 1999
    Assignee: Daido Tokushuko Kabushiki Kaisha
    Inventors: Takao Shimizu, Seiya Asari, Noriyoshi Yokota
  • Patent number: 5968291
    Abstract: This invention relates to a hydrogen-absorbing alloy, and particularly provides a hydrogen-absorbing alloy having a body-centered cubic structure which has a periodical structure formed by spinodal decomposition, has a large hydrogen storage amount, has excellent hydrogen desorption characteristics and can mitigate activation conditions, the alloy comprises at least two elements of alloy components, wherein the relational curve between chemical free energy of solid solutions and an alloy composition has a shape describing an upwardly convexed curve, or said alloy comprises two solid solutions having a regular periodical structure formed by spinodal decomposition within a region satisfying the relation d.sup.2 G/dX.sub.B.sup.2 <0 (where G is chemical free energy and X.sub.B is a solute alloy concentration) as the principal phase.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: October 19, 1999
    Assignees: Toyota Jidosha Kabushiki Kaisha, Director-General of Agency of Industrial Science and Technology
    Inventors: Hideki Iba, Etsuo Akiba
  • Patent number: 5897830
    Abstract: A consumable billet for melting and casting a metal matrix composite component is made of a consolidated powder metal matrix composite having a titanium or titanium alloy matrix reinforced with particles. The preferred billet is a blended and sintered powder metal composite billet incorporating titanium carbide or titanium boride into a Ti--6Al--4V alloy.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: April 27, 1999
    Assignee: Dynamet Technology
    Inventors: Stanley Abkowitz, Susan M. Abkowitz, Paul F. Weihrauch, Harold L. Heussi, Walter Zimmer
  • Patent number: 5885375
    Abstract: The present invention provides a high strength titanium alloy useful as a material for products such as ornaments, products such as ornaments made of the titanium alloy, and a method for producing the products using the titanium alloy as a material. The high strength titanium alloy is capable of attaining high machinability, and the product made of the titanium alloy is excellent in beauty and decorativeness while being hard to made flawed or concaved. According to the present invention, the titanium alloy includes iron of 0.20 to 0.8 mass percent and oxygen of 0.20 to 0.6 mass percent, or iron of 0.2 to 1.0 mass percent, oxygen of 0.15 to 0.6 mass percent and silicon of 0.20 to 1.0 mass percent, with the balance of titanium and inevitable impurities. A method for producing a product using the titanium alloy as a material includes a steps of hot forging the titanium alloy at a temperature of (.beta.-transformation temperature -200.degree. C.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: March 23, 1999
    Assignees: Kabushiki Kaisha Kobe Seiko Sho, Citizen Watch Co., Ltd.
    Inventors: Atsushi Takemura, Hachiro Kushida, Norio Hashimoto, Tadao Enomoto, Hideo Taguchi
  • Patent number: 5871595
    Abstract: Biocompatible titanium base alloys for medical devices which are intended to remain on or in a living human being for an extended period of time, such as surgical and medical implants. The alloys are free from toxic elements such as Al, Ni, Co, Fe, Cr, Mo, and W. They are quaternary alloys of Ti with between about 2.5% up to 13% Zr, about 20% to about 40% Nb, about 4.5% to about 25% Ta, all percentages being by weight, the balance being Ti and the total of Ta plus Nb being between about 35% and 52% by weight. The ration of Nb/Ta is between 2 and 13. These alloys may also contain limited amounts of non-toxic interstitial elements, such as C, N, and O. The relative proportions of Ti, Zr, Ta, and Nb are such that the modulus of elasticity is below 65 GPa.
    Type: Grant
    Filed: January 31, 1997
    Date of Patent: February 16, 1999
    Assignee: Osteonics Corp.
    Inventors: Toseef Ahmed, Henry J. Rack
  • Patent number: 5868879
    Abstract: A mixed oxide ceramic product is made directly from a metal alloy of titanium, zirconium and/or hafnium and niobium, tantalum or hafnium, where the normally combustible alloy of titanium and zirconium or hafnium is passivated by the addition of more than about 7 atomic percent of niobium and/or tantalum and or vanadium which alloy can then be heated in air at atmospheric pressure to a temperature of from about 800 degrees C. to about 1500 degrees C. to produce an adherent monolithic ceramic containing product.
    Type: Grant
    Filed: May 28, 1996
    Date of Patent: February 9, 1999
    Assignee: Teledyne Industries, Inc.
    Inventors: Darryl Dean Amick, John C. Haygarth, Hershel R. Henson
  • Patent number: 5866254
    Abstract: A reinforcement-containing metal-matrix composite material is formed by dispersing pieces of reinforcement material throughout a melt of a bulk-solidifying amorphous metal and solidifying the mixture at a sufficiently high rate that the solid metal matrix is amorphous. Dispersing is typically accomplished either by melting the metal and mixing the pieces of reinforcement material into the melt, or by providing a mass of pieces of the reinforcement material and infiltration of the molten amorphous metal into the mass. The metal preferably has a composition of about that of a eutectic composition, and most preferably has a composition, in atomic percent, of from about 45 to about 67 percent total of zirconium plus titanium, from about 10 to about 35 percent beryllium, and from about 10 to about 38 percent total of copper plus nickel.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: February 2, 1999
    Assignee: Amorphous Technologies International
    Inventors: Atakan Peker, William L. Johnson, Robert Schafer, David M. Scruggs
  • Patent number: 5840440
    Abstract: Disordered multicomponent hydrogen storage material characterized by extraordinarily high storage capacity due to a high density of useable hydrogen storage sites (greater than 10.sup.23 defect sites/cc) and/or an extremely small crystallite size. The hydrogen storage material can be employed for electrochemical, fuel cell and gas phase applications. The material may be selected from either of the modified LaNi.sub.5 or modified TiNi families formulated to have a crystallite size of less than 200 Angstroms and most preferably less than 100 Angstroms.
    Type: Grant
    Filed: November 20, 1995
    Date of Patent: November 24, 1998
    Assignee: Ovonic Battery Company, Inc.
    Inventors: Stanford R. Ovshinsky, Michael A. Fetcenko, Jun Su Im, Kwo Young, Benjamin S. Chao, Benjamin Reichman
  • Patent number: 5830288
    Abstract: Additions of a first alloy constituent of at least one element from the group consisting of Y, Sc, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, or any combinations of them, and a second alloy constituent of at least one element from the group consisting of C, Si, Ge, Sn and Pb, or any combinations of them, to Ti-base alloys can be employed so as to result in an alloy containing an very fine, substantially homogeneous oxide dispersoid of the first constituent, and produce alloys having improved tensile properties, especially tensile elongation. The dispersoid results from the decomposition of an intermediate phase dispersoid comprising a compound of the first and second constituents which results from rapid solidification of the alloy from a melt. It is preferred that the second alloy constituent should be at a concentration sufficient to form the intermediate phase with all of the element or elements comprising the first alloy constituent.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: November 3, 1998
    Assignee: General Electric Company
    Inventors: Michael Francis Xavier Gigliotti, Jr., Ernest Leroy Hall
  • Patent number: 5779823
    Abstract: A titanium silicide material based on Ti.sub.5 Si.sub.3 intermetallic compound exhibits substantially improved oxidative stability at elevated temperatures. In particular, carbon is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.6 weight % C) effective to impart substantially improved oxidative stability at elevated temperatures, such as about 1000.degree. C. Boron is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.3 weight % B) to this same end.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: July 14, 1998
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Andrew J. Thom, Mufit Akinc
  • Patent number: 5772803
    Abstract: A torsionally reacting spring, such as a helical spring, a torsion bar, or a torsion tube, requires the ability to torsionally deform elastically during service and return to its original, undeformed shape. The torsionally reacting spring is made of a bulk-deforming amorphous alloy which may be cooled from the melt at a cooling rate of less than about 500.degree. C. per second, yet retain an amorphous structure. A preferred bulk-solidifying amorphous alloy has a composition, in atomic percent, of from about 45 to about 67 percent total of zirconium plus titanium, from about 10 to about 35 percent beryllium, and from about 10 to about 38 percent total of copper plus nickel, plus incidental impurities, the total of the percentages being 100 atomic percent.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: June 30, 1998
    Assignee: Amorphous Technologies International
    Inventors: Atakan Peker, William L. Johnson, David M. Scruggs
  • Patent number: 5728277
    Abstract: A hydrogen occlusion electrode comprising a compact of a mixture powder including a titanium-nickel alloy which contains oxygen.
    Type: Grant
    Filed: April 1, 1997
    Date of Patent: March 17, 1998
    Assignee: Agency of Industrial Science & Technology
    Inventors: Tetsuo Sakai, Hiroyuki Takeshita, Hideaki Tanaka, Nobuhiro Kuriyama, Itsuki Uehara
  • Patent number: 5693289
    Abstract: A titanium silicide material based on Ti.sub.5 Si.sub.3 intermetallic compound exhibits substantially improved oxidative stability at elevated temperatures. In particular, carbon is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.6 weight % C) effective to impart substantially improved oxidative stability at elevated temperatures, such as about 1000.degree. C. Boron is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.3 weight % B) to this same end.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: December 2, 1997
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Andrew J. Thom, Mufit Akinc
  • Patent number: 5683523
    Abstract: A light-weight super high vacuum vessel is disclosed in which a super high vacuum pressure over 10.sup.-10 Torr or over 10.sup.-11 Torr can be achieved using a simple evacuation system and/or with a sealing structure. The super high vacuum vessel contains a member comprising: from 0.02 wt. % to 1.00 wt. % of at least one platinum-group metal selected from the group consisting of Pd, Pt, Rh, Ru, Re, and Os; from 0.1 wt. % to 3.0 wt. % of at least one transition metal selected from the group consisting of Co, Fe, Cr, Ni, Mn, and Cu; from 0.1 wt. % to 3.0 wt. % of at least one rare earth series element selected from the group consisting of La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Ho, Er, and Y; impurity elements of C, N, and O, C being equal to or less than 0.05 wt. %, N being equal to or less than 0.05 wt. %, O being equal to or less than 0.08 wt. %; and Ti and inevitable impurities.
    Type: Grant
    Filed: August 10, 1995
    Date of Patent: November 4, 1997
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Megumi Nakanose, Seiji Ishimoto, Katsuichi Kikuchi, Kiyotaka Fujita
  • Patent number: 5667751
    Abstract: This invention relates to a catalytic fuel composition capable of reducing pollutants in the combustion gasses generated upon combustion of the same. A catalytic material is combined with a liquid, petroleum-based fuel, mixed and solid particles are separated out to give the catalytic fuel product. The catalytic material predominantly comprises a plagioclase feldspar belonging mainly to the albite-anorthite series, and contains small amount of mica, kaolinite and serpentine, and optionally contains magnetite. An alloy material is also disclosed, comprising a mixture of the above-described catalytic material and a metal. The alloy material exhibits unique properties relative to the metal component alone, such as increased tensile strength, improved heat resistance, improved acid resistance, improved corrosion resistance, as well as exhibiting unusual conductive properties.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: September 16, 1997
    Inventor: Jack H. Taylor, Jr.
  • Patent number: 5613849
    Abstract: A dental care material comprising a titanium sintered body has no harmful effects on the human body and easily produces products with complicated shapes having a high level of strength. A mixture of titanium powder and an organic binder is injection molded and subjected to binder removal and sintering processes to form a bracket for orthodontic or dental implant materials. Pure titanium powder, with an average granule diameter of no more than 40 .mu.m, a carbon content by weight of no more than 0.3%, and an oxygen content by weight of no more than 0.6%, preferably is used to produce a titanium sintered body of combined carbon and oxygen content by weight of no more than 1.0%. Colored layers can be formed on the surface of the titanium sintered body using various methods as needed.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: March 25, 1997
    Assignees: Injex Corporation, Matsumoto Dental College
    Inventors: Naoki Tanaka, Hiroshi Ohtsubo, Michio Ito
  • Patent number: 5597515
    Abstract: A process for producing a conductive, fluorine-doped titanium dioxide product which is doped throughout, said process comprising the steps of: (a) reacting the precursors in a system to form fluorine-doped TiO.sub.2, said precursors consisting essentially of a titanium alkoxide and a fluorine source; (b) reducing the fluorine-doped titanium dioxide product at a temperature sufficient to form said conductive, fluorine-doped titanium dioxide product; and (c) recovering the reduced product.
    Type: Grant
    Filed: September 27, 1995
    Date of Patent: January 28, 1997
    Assignee: Kerr-McGee Corporation
    Inventors: James W. Kauffman, Bruce R. Palmer
  • Patent number: 5580518
    Abstract: A titanium silicide material based on Ti.sub.5 Si.sub.3 intermetallic compound exhibits substantially improved oxidative stability at elevated temperatures. In particular, carbon is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.6 weight % C) effective to impart substantially improved oxidative stability at elevated temperatures, such as about 1000.degree. C. Boron is added to a Ti.sub.5 Si.sub.3 base material in an amount (e.g. about 0.3 to about 3.3 weight % B) to this same end.
    Type: Grant
    Filed: July 12, 1994
    Date of Patent: December 3, 1996
    Assignee: Iowa State University Research Foundation
    Inventors: Andrew J. Thom, Mufit Akinc
  • Patent number: 5580431
    Abstract: A composite wire microelectrode for making electro-chemical measurements, and method of making same. The microelectrode includes an inner conductive sensing wire and an outer tube that is oxidized to form a dielectric, self-healing oxide layer around the sensing wire.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: December 3, 1996
    Assignee: Associated Universities, Inc.
    Inventors: Hugh S. Isaacs, Antonio J. Aldykiewicz, Jr.
  • Patent number: 5578266
    Abstract: Disclosed are a hydrogen storage alloy which contains carbon in a proportion of from 30 to 500 ppm and is represented by the stoichiometric formula A.sub.x B.sub.5.0, wherein A is La or a mixture of La with at least one rare earth metal other than La, B is at least one metal selected from a group consisting of Al, Co, Cr, Cu, Fe, Mn, Ni, Ti, V, Zn and Zr, and x is a rational number in the range 0.95.ltoreq..times..ltoreq.1.00; and has a texture in which only the intermetallic compound phase named AB.sub.5 phase is present and every other intermetallic compound phase is absent: and a method of producing said alloy and an electrode using the same.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: November 26, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yasushi Takai, Kazuhiro Yamada, Takashi Toide, Shigenobu Tajima
  • Patent number: 5573607
    Abstract: A metal matrix composite of aluminum, magnesium or titanium, and their alloys, containing particles of a silicon boride composition. A preferred form of the boride is silicon hexaboride. A small amount of carbon can be present in the silicon boride composition as Si--B--C. The particles can be pre-blended with particles of the metal prior to melting, or can be added after the melting of the metal. Because of the similar specific gravity of silicon boron compounds and aluminum, very little stirring is required to achieve a homogeneous mixture in the melt. This substantially reduces formation of oxide and hydrogen inclusions. Improved machinability is achieved through utilization of rounded particles. The composite has improved strength, stiffness and reduced thermal coefficient of expansion, thus making the composite composition more useful in industry.
    Type: Grant
    Filed: May 6, 1995
    Date of Patent: November 12, 1996
    Assignee: Millennium Materials, Inc.
    Inventor: Samuel C. Weaver
  • Patent number: 5567532
    Abstract: A diamond-containing metal-matrix composite material is formed by dispersing pieces of diamond throughout a melt of a bulk-solidifying amorphous metal and solidifying the mixture. The mixture may then be remelted and resolidified at a rate sufficiently high that the metal matrix retains an amorphous structure upon cooling. The metal preferably has a composition of about that of a eutectic composition, and most preferably has a composition, in atomic percent, of from about 45 to about 67 percent total of zirconium plus titanium, from about 10 to about 35 percent beryllium, and from about 10 to about 98 percent total of copper plus nickel. The diamond is preferably low-grade or artificial diamond.
    Type: Grant
    Filed: August 1, 1994
    Date of Patent: October 22, 1996
    Assignee: Amorphous Alloys Corp.
    Inventors: Atakan Peker, William L. Johnson, Robert Schafer, David M. Scruggs
  • Patent number: 5514490
    Abstract: An improved lithium secondary battery using a novel layered titanium phosphate having the formula of TiO(OH)(H.sub.2 PO.sub.4), or LTP, as anode material, and LiCoO.sub.2, LiNiO.sub.2, or other appropriate material, as cathode. A stable operating voltage of 3-volt can be obtained from the resultant lithium secondary battery. The layered titanium phosphate is prepared by first reacting a tetramethylammonium hydroxide (N(CH.sub.3).sub.4 OH) solution containing orthophosphoric acid with titanium dioxide in a low temperature hydrothermal reaction to form a tetramethylammonium form of layered titanium phosphate, or NMe.sub.4 TP, which serves as the precursor of LTP. The precursor NMe.sub.4 TP is then placed in a concentrated hydrochloric acid at room temperature to obtain a high purity LTP via a cation exchange reaction. Each of the Li.sub.
    Type: Grant
    Filed: August 30, 1994
    Date of Patent: May 7, 1996
    Assignee: Industrial Technology Research Institute
    Inventors: Jin-Ming Chen, Yingjeng J. Li, Weir-Mirn Hurng, M. Stanley Whittingham
  • Patent number: 5514332
    Abstract: Titanium having a thermal shrinkage factor close to that of Nb.sub.3 Sn superconducting wire, whereby it gives rise to little degradation of the properties of the superconducting wire and also offers a good balance between strength and toughness at liquid helium temperature, making it highly suitable as a conduit pipe material used as a seal for liquid helium for high-magnetic-field superconducting coil applications. The present invention focusses on the major effect on strength and toughness of titanium material that the oxygen content has, and appropriately controls the oxygen and other impurities content of pure titanium to provide titanium material comprising, in mass %, 0.07 to 0.13 percent O, up to 0.10 percent Fe, up to 0.10 percent C+N, and up to 0.
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: May 7, 1996
    Assignees: Nippon Steel Corporation, Japan Atomic Energy Research Institute
    Inventors: Takao Horiya, Shigeru Ohkita, Toshiaki Nishida, Hirofumi Yoshimura, Naoomi Yamada, Masayuki Yamamoto, Hideo Nakajima, Toshinari Andou
  • Patent number: 5501917
    Abstract: Improved multicomponent alloys for hydrogen storage and rechargeable hydride electrode applications, and in particular for rechargeable hydride battery applications, according to the formula: A.sub.a B.sub.b Ni.sub.c D.sub.y M.sub.x R.sub.z, and the hydride thereof, where A is at least one element selected from the group consisting of Ti, Zr, Hf, Y, V, Nb, Pd, Mg, Be, and Ca; B is at least one element selected from the group consisting of Mg, Al, V, Wb, Ta, Cr, Mn, Si, C, B, and Mo; D is at least one element selected from the group consisting of W, Fe, Co, Cu, Zn, Ag, Sb and Sn; M is at least one element selected from the group consisting of Li, Na, K, Rb, Cs, P, S, Sr, and Ba; R is at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, and Yb; and where a, b, c, x, y and z are defined by: 0.10.ltoreq.a.ltoreq.0.85, 0.02.ltoreq.b.ltoreq.0.85, 0.02.ltoreq.c.ltoreq.0.85, 0.01.ltoreq.x.ltoreq.0.30, 0.ltoreq.y.ltoreq.0.25, 0.ltoreq.z.ltoreq.0.12 and a+b+c+x+y=1.00.
    Type: Grant
    Filed: January 28, 1994
    Date of Patent: March 26, 1996
    Inventor: Kuochih Hong