Cobalt Base Patents (Class 420/435)
  • Patent number: 6277305
    Abstract: The present invention relates to cobalt(II) oxide containing metallic cobalt, to a process for the production thereof and to the use thereof.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: August 21, 2001
    Assignee: H. C. Starck GmbH & Co. KG
    Inventors: Astrid Görge, Juliane Meese-Marktscheffel, Dirk Naumann, Armin Olbrich, Frank Schrumpf
  • Patent number: 6270593
    Abstract: Mn alloy materials for magnetic materials contain 500 ppm or less, preferably 100 ppm or less, oxygen, 100 ppm or less, probably 20 ppm or less, sulfur, and preferably a total of 1000 ppm or less, more preferably 500 ppm or less, impurities (elements other than Mn and the alloying component). The alloying component that forms an alloy with Mn is one or two or more elements selected from the group consisting of Fe, Ir, Pt, pd, Rh, Ru, Ni, Cr and Co. Sputtering targets formed from the Mn alloy materials for use in depositing magnetic thin film, and the thin films so produced.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: August 7, 2001
    Assignee: Japan Energy Corporation
    Inventors: Yuichiro Shindo, Tsuneo Suzuki
  • Patent number: 6221183
    Abstract: A high-strength low-thermal-expansion alloy consisting of, by weight, 0.06 to 0.50% C, 25 to 65% in total of one or both of 65% or less Co and less than 30% Ni, and balance of Fe as a main component, other optional elements and unavoidable impurities, and having a primary phase of austenite phase and martensite phase induced by working. A wire is made from the alloy.
    Type: Grant
    Filed: November 15, 1993
    Date of Patent: April 24, 2001
    Assignee: Hitachi Metals, Ltd.
    Inventors: Koji Sato, Rikizo Watanabe, Takehiro Ohno, Yoshiki Masugata, Minoru Takuwa, Shigeaki Sato, Yoshimi Senda
  • Patent number: 6197437
    Abstract: A composite barrel for use in extrusion or injection molding is disclosed. The composite barrel includes an outer housing having a cylindrical bore that extends throughout the length of the outer housing. A wear-resistant lining is disposed on an interior surface that defines the cylindrical bore. The lining is fabricated from an alloy that includes a base metal and phosphorus and the lining may contain hard abrasion-resistant particulate, such as tungsten carbide. The base metal is nickel or cobalt or a mixture of nickel and cobalt. The alloy is typically applied by centrifugal casting and can be cast in a nitrogen-rich atmosphere without creating undesirable lining porosity. Such linings can be made for a fraction of the cost of comparable linings that must be cast under vacuum or in an atmosphere of argon.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: March 6, 2001
    Assignee: Wall Colmonoy Corporation
    Inventors: David Martin Bielec, Samuel Conrad DuBois, Subramaniam Rangaswamy
  • Patent number: 6190516
    Abstract: A planar ferromagnetic sputter target is provided for use as cathode in the magnetron sputtering of magnetic thin films, wherein the ferromagnetic material has localized regions of differing magnetic permeability. A solid, unitary, planar sputter target is formed from a ferromagnetic material, such as cobalt, nickel, iron or an alloy thereof, and this planar target is subjected to mechanical deformation, heat treatment, and/or thermal-mechanical treatment to create regions within the sputter target having different permeability than adjacent regions. The permeability differences in the ferromagnetic sputter target guides the path of the magnetic flux flow through the target to thereby increase the magnetic leakage flux at the target sputtering surface.
    Type: Grant
    Filed: October 6, 1999
    Date of Patent: February 20, 2001
    Assignee: Praxair S.T. Technology, Inc.
    Inventors: Wei Xiong, Hung-Lee Hoo, Peter McDonald
  • Patent number: 6162551
    Abstract: A joining alloy of the invention is based on Co, Ni, or their alloy, and contains 1.0 to 2.3% by mass of C and 15.5 to 34.7% by mass of W. Using HIP, the joining alloy in the form of a casting or powders is integrated with a WC--Co or WC--Ni type cemented carbide via diffusion joining. Using HIP, it is also possible to obtain a composite material having an integral structure in which a cemented carbide and the joining alloy, and the joining alloy and steel are joined together via diffusion joining. The joining alloy may additionally contain up to 30% by mass of Fe, up to 3% by mass of Si and up to 3% by mass of Mn as well as up to 10% by mass of at least one selected from Cr, Mo, V, Nb, Ti, Zr, and Ta. It is thus possible to obtain a joining alloy having an improved joining strength without producing a brittle phase therein even upon joined to the WC--Co or WC--Ni type cemented carbide, and its composite material.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: December 19, 2000
    Assignee: Daido Tokushuko Kabushiki Kaisha
    Inventor: Yasushi Watanabe
  • Patent number: 6146474
    Abstract: An iron--cobalt alloy the chemical composition of which comprises, by weight: 35%.ltoreq.Co.ltoreq.55%; 0.5%.ltoreq.V.ltoreq.2.5%; 0.02%.ltoreq.Ta+2.times.Nb.ltoreq.0.2%; 0.0007%.ltoreq.B.ltoreq.0.007%; C.ltoreq.0.05%; the balance being iron and impurities resulting from the smelting operation.
    Type: Grant
    Filed: January 15, 1999
    Date of Patent: November 14, 2000
    Assignee: Imphy Ugine Precision
    Inventors: Lucien Coutu, Laurent Chaput
  • Patent number: 6132891
    Abstract: There is disclosed an amorphous soft magnetic material represented by a composition formula:Co.sub.x Zr.sub.y Pd.sub.z M.sub.a wherein M denotes at least one element selected from a group consisting of niobium, chromium, vanadium, tantalum, tungsten, molybdenum; and0.82.ltoreq.x.ltoreq.0.940.04.ltoreq.y.ltoreq.0.100.01.ltoreq.z.ltoreq.0.080.01.ltoreq.a.ltoreq.0.10.The amorphous soft magnetic material, which has a high saturated magnetic flux density, a low coercive force, a high magnetic permeability and excellent wear and corrosion resistances, can be obtained by adding at least one or more of the elements of the Va and VIa groups to a Co--Zr--Pd amorphous soft magnetic material.
    Type: Grant
    Filed: July 6, 1992
    Date of Patent: October 17, 2000
    Assignee: Sony Corporation
    Inventors: Tatsuo Kumura, Yukari Utsumi, Hideaki Karamon
  • Patent number: 6126760
    Abstract: An evaporation material is used in manufacturing a VTR tape, a vertical magnetic recording thin film or the like. The evaporation material is a wire comprising a cobalt metal a cobalt--nickel alloy containing not more than 30 weight % of nickel, or a cobalt--chromium alloy containing not more than 30 weight % of chromium. This wire has a diameter of at least 1.0 mm and not more than 10 mm, a tensile strength of at least 400 MPa and not more than 1500 MPa, and an elongation and a reduction of area of at least 5%. The evaporation material has a prescribed crystal structure, with a face centered cubic lattice ratio of at least 0.1 and not more than 1. It is possible to obtain a wire having the above properties by heating the metal material to at least Tu.degree. C. and thereafter performing plastic working of reduction in area of at least 10% in a single pass at a temperature of at least Td.degree. C. and not more than (Tu+200).degree. C.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: October 3, 2000
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yukihiro Oishi, Susumu Yamamoto, Teruyuki Murai, Nozomu Kawabe
  • Patent number: 6124047
    Abstract: A soft magnetic film comprises a Co--M--T--C alloy wherein a film structure is predominantly made of an amorphous phase and element M and C are chemically combined. The use of this film as a lower core layer in an MR/inductive composite-type thin film magnetic head ensures high saturation magnetic flux density, high resistivity, low magnetostriction constant and appropriate magnetic field, and leads to improvements in core and shield functions of the lower core layer.
    Type: Grant
    Filed: July 29, 1998
    Date of Patent: September 26, 2000
    Assignee: Alps Electric Co., Ltd.
    Inventor: Naoya Hasegawa
  • Patent number: 6093262
    Abstract: A ferromagnetic, high strength, corrosion resistant material for use in electromagnetic equipment. The material comprises Cobalt or Nickel or a combination of these elements in an amount equal to or greater than 60% by weight, with the balance comprising one of a group consisting of Beryllium, Lithium, Aluminum, or Titanium. In different embodiments of the invention, 3% or less of the material comprises Beryllium, with the balance comprising Nickel or Cobalt. The material provides adequate yield strength for use downhole in wellbores, is highly resistant to corrosion induced by downhole well fluids and sea water, and has high ferromagnetic characteristics suitable for use in solenoid valves and other downhole well equipment.
    Type: Grant
    Filed: June 23, 1998
    Date of Patent: July 25, 2000
    Assignee: PES, Inc.
    Inventor: Brett Bouldin
  • Patent number: 6039920
    Abstract: A process for making iron, cobalt and/or nickel base alloys containing rhenium. The process involves melting together the components that form the alloys, at least one of the components being a rhenium master alloy having 30 to 70 wt % rhenium, then casting the resultant melt and allowing the melt to solidify. Possible difficulties such as the formation of rhenium heptoxide are avoided by using a master alloy containing (i) rhenium and (ii) iron, cobalt and/or nickel, instead of sintered rhenium as the rhenium source during the melting step.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: March 21, 2000
    Assignee: W. C. Heraeus GmbH & Co. KG
    Inventors: Michael Koch, Wulf Kock, David Francis Lupton, Friedhold Scholz
  • Patent number: 6004661
    Abstract: An amorphous magnetic material possesses a composition essentially expressed by (Fe.sub.1-a-b N.sub.a M.sub.b).sub.100-x-y Si.sub.x B.sub.y (M denotes at least one kind of element selected from Mn, Cr, Co, Nb, V, Mo, Ta, W and Zr, 0.395.ltoreq.a.ltoreq.0.7, 0.ltoreq.b.ltoreq.0.21, 1-a-b<a, 6.ltoreq.x.ltoreq.18 at %, 10.ltoreq.y.ltoreq.18 at %, respectively). An amorphous magnetic material which has such a Ni rich Fe-Ni base possesses a Curie temperature T.sub.c of 473 to 573K, the maximum magnetic flux density B.sub.m of 0.5 to 0.9T. A ratio of residual magnetic flux density B.sub.r and the maximum magnetic flux density B.sub.m can be controlled according to a required characteristics, and, in the case of being used in a saturable core, is set at 0.60 or more. With an amorphous magnetic material of an inexpensive Fe-Ni base, magnetic characteristics applicable in a high frequency region, thermal stability, surface smoothness can be realized.
    Type: Grant
    Filed: June 24, 1998
    Date of Patent: December 21, 1999
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Kazumi Sakai, Takao Kusaka, Yasuaki Moriya
  • Patent number: 5976715
    Abstract: The invention is embodied in a soft magnetic thin film article comprising an iron--chromium-nitrogen (Fe--Cr--N) based alloy and methods for making such article. The soft magnetic thin film article is formed using an iron--chromium--nitrogen based alloy with tantalum in one embodiment and with at least one of the elements titanium (Ti), zirconium (Zr), hafnium (Hf), vanadium (V), molybdenum (Mo), niobium (Nb) or tungsten (W) in another embodiment. The article is formed such that the alloy has a relatively high saturation magnetization (e.g., greater than approximately 15 kG) and a relatively low coercivity (e.g., less than approximately 2.0 oersteds) in an as-deposited condition or, alternatively, with a very low temperature treatment (e.g., below approximately 150.degree. C.). The inventive films are suitable for use in electromagnetic devices, for example, in microtransformer cores, inductor cores and in magnetic read-write heads.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: November 2, 1999
    Assignee: Lucent Techologies Inc.
    Inventors: Li-Han Chen, Sungho Jin, Wei Zhu, Robert Bruce van Dover
  • Patent number: 5968450
    Abstract: The present invention provides a scandium containing hydrogen absorption alloy having an alloy phase which is represented by the following formula;(Sc.sub.x A.sub.1-x)(B'.sub.y B".sub.2-y).sub.zwherein A is at least one of Ti, Zr, rare-earth elements, a mixture of Ti and at least one of Zr, Ta, Nb, Hf, Ca and rare-earth elements, and a mixture of Zr and at least one of Ti, Ta, Nb, Hf, Ca and rare-earth elements; B'is at least one of Ni, Fe, Co and a mixture of at least one of Ni, Fe and Co and at least one of Al, Ga, Si and In; B" is at least one of Mn, V, Cr, Nb, Ti and a mixture of at least one of Mn, V, Cr, Nb and Ti and at least one of Al, Ga, Si and In; x represents 0<x.ltoreq.1; y represents 0<y<2; and z represents 0.75.ltoreq.z.ltoreq.1.2, and the alloy phase includes at least one of a part which belongs to a C15 type Laves phase and a part which belongs to a C14 type Laves phase, and a hydrogen absorption electrode which includes the alloy.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: October 19, 1999
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Masato Yoshida, Takitaro Yamaguchi, Takao Ogura
  • Patent number: 5916518
    Abstract: An improved cobalt-base braze alloy composition and method for diffusion brazing are provided for use in repairing superalloy articles, such as gas turbine engines, power generation turbines, refinery equipment, and heat exchangers. The improved cobalt-base braze alloy composition includes nickel; at least one element selected from the group of rhenium, palladium, and platinum; at least one element selected from the group of boron and silicon; and the remaining balance consists of cobalt. This composition may also include aluminum, and the composition may be combined with one or more powdered base metal superalloy compositions to form an improved diffusion braze alloy mixture. In the improved method for repairing superalloy articles, the foregoing mixture is applied to a region of the superalloy article to be repaired. The mixture is then heated to melt the cobalt-base braze alloy, thereby joining the base metal superalloy powder particles together, and joining the entire mixture to the region being repaired.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: June 29, 1999
    Assignee: Allison Engine Company
    Inventor: Richard Patrick Chesnes
  • Patent number: 5908514
    Abstract: A new magnetic alloy exhibits high Hc and Ms while exhibiting excellent corrosion resistance, thereby providing ideal physical properties for high density recording applications. Other parameters of the media, such as SNR, PW50, and S are at least maintained, if not also improved. The alloy contains cobalt and up to 10 at. % Ni, up to 20 at. % Pt, up to 10 at. % Ta, up to 10 at. % Ti, and optionally up to 6 at. % B. The ratio of the tantalum to titanium in the alloy is between 3:1 and 1:3. The alloy is deposited by vacuum deposition (typically sputtering) on a similarly deposited non-magnetic alloy under layer. Nitrogen and/or oxygen may be introduced into the alloy during deposition to improve SNR. Other corrosion-resistant thin film alloys may also be obtained by the inclusion of Ta and Ti.
    Type: Grant
    Filed: October 24, 1996
    Date of Patent: June 1, 1999
    Inventors: Rajiv Yadav Ranjan, Tu Chen, Tsutomu Tom Yamashita, John Ko-Jen Chen
  • Patent number: 5858125
    Abstract: A magnetoresistive material of the present invention has a structure in which many clusters are surrounded by a crystal phase of Cu and/or Ag, where each cluster has a grain size of 20 nm or less and composed of an amorphous phase containing at least one ferromagnetic metal element T as a main component selected from Fe, Co and Ni, and at least one element M selected from Ti, Zr, Hf, V, Nb, Ta, Mo and W.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: January 12, 1999
    Assignee: Alps Electric Co., Ltd.
    Inventor: Naoya Hasegawa
  • Patent number: 5810983
    Abstract: A process for producing a high purity cobalt is provided comprising the following steps. An aqueous solution of cobalt chloride having a hydrochloric acid concentration of 7 to 12N is provided. The solution includes either or both of Fe and Ni as impurities. The solution is contacted with an anion exchange resin so that cobalt is adsorbed on the resin. Cobalt is eluted from the resin with hydrochloric acid at a concentration of 1 to 6N. The solution containing the eluted cobalt is dried or otherwise concentrated to produce a purified aqueous solution of cobalt chloride having a pH of 0 to 6. Organic materials are preferably removed from the purified solution by active carbon treatment. Electrolytic refining is conducted with the purified aqueous solution as an electrolyte to obtain electrodeposited cobalt. A high purity cobalt sputtering target can be obtained wherein Na content is 0.05 ppm or less; K content is 0.
    Type: Grant
    Filed: January 28, 1997
    Date of Patent: September 22, 1998
    Assignee: Japan Energy Corporation
    Inventors: Yuichiro Shindo, Tsuneo Suzuki
  • Patent number: 5801630
    Abstract: A harmonic-type EAS marker includes a wire segment formed of cobalt alloy. To form the wire segment, the cobalt alloy is cast as an amorphous wire, die-drawn to a smaller diameter, and then annealed with application of longitudinal tension. The annealed wire is cut to produce wire segments which have a magnetic hysteresis loop with a large Barkhausen discontinuity at a lower threshold level than has previously been achieved.
    Type: Grant
    Filed: November 8, 1996
    Date of Patent: September 1, 1998
    Assignee: Sensormatic Electronics Corporation
    Inventors: Wing K. Ho, Jiro Yamasaki
  • Patent number: 5769969
    Abstract: A rare earth-iron-nitrogen magnet alloy contains a rare earth element (at least one of the lanthanoids including Y), iron and nitrogen as its main components, or may further contain at least one of Ti, V, Cr, Mn, Cu, Zr, Nb, Mo, Hf, Ta, W, Al, Si and C as another main component M. The main phase of the alloy also contains 0.001 to 0.1% by weight of at least one of Li, Na, X, Rb, Cs, Mg, Ca, Sr and Ba.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: June 23, 1998
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Takashi Ishikawa, Atsushi Kawamoto
  • Patent number: 5767485
    Abstract: A sheathed heater comprises a heater disposed in a sheath tube by way of an insulation powder and is connected in series with a heat resistor and a current regulation resistor. The current regulation resistor is made from a cobalt-copper alloy which contains a copper component in the range from 1.0% to 14% by weight.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: June 16, 1998
    Assignee: NGK Spark Plug Co., Ltd.
    Inventor: Chiaki Kumada
  • Patent number: 5759229
    Abstract: A process for recovering valuable components of a residue from a stream of used catalyst, discharged from a plant for the liquid-phase, homogeneously catalyzed oxidation of alkylaromatic compounds under pressure, to produce polycarboxylic aromatic acids. The residue containing mainly cobalt (Co) and manganese (Mn) compounds is injected into a molten metal bath in combination with enough oxygen gas to convert essentially all carbon in the residue mainly to CO. The residue may also be sludge from a pond in which the residue is stored. The Co content of the molten metal is determined by how much of the Mn in the residue is to be rejected from the molten metal. The Mn rejected is distributed between a slag overlying the molten metal and the effluent which leaves the bath. In the slag, the Mn is trapped as manganese oxide (MnO); in the effluent Mn leaves as manganese dibromide (MnBr.sub.2).
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: June 2, 1998
    Inventor: David Feitler
  • Patent number: 5728279
    Abstract: Target for a magnetron-cathode sputtering apparatus is made from a cobalt base alloy containing additional elements in such concentrations that intermetallic phases are formed with at least one of these elements and intermetallic phases are observed on the basis of the phase diagram in the state of equilibrium at the operating temperature of the target. The grain boundaries, sub-grain boundaries, twin-grain boundaries or slip bands of the cobalt mixed crystal forming the matrix are decorated with the elements forming the intermetallic phases. X-ray diffraction diagrams made from the target display reflections of an intermetallic phase which is largely absent in the cast state and which forms only during a heat treatment in the temperature range below the solidus temperature of the alloy by a solid state reaction.
    Type: Grant
    Filed: December 15, 1994
    Date of Patent: March 17, 1998
    Assignee: Leybold Materials GmbH
    Inventors: Martin Schlott, Martin Weigert, Kwei Teng, Bruce Gehman
  • Patent number: 5631094
    Abstract: A new magnetic alloy exhibits high Hc and Ms while exhibiting excellent corrosion resistance, thereby providing ideal physical properties for high density recording applications. Other parameters of the media, such as SNR, PW50, and S are at least maintained, if not also improved. The alloy contains cobalt and up to 10 at. % Ni, up to 20 at. % Pt, up to 10 at. % Ta, up to 10 at. % Ti, and optionally up to 6 at. % B. The ratio of the tantalum to titanium in the alloy is between 3:1 and 1:3. The alloy is deposited by vacuum deposition (typically sputtering) on a similarly deposited non-magnetic Ni alloy under layer. Nitrogen and/or oxygen may be introduced into the alloy during deposition to improve SNR. Other corrosion-resistant thin film alloys may also be obtained by the inclusion of Ta and Ti.
    Type: Grant
    Filed: December 1, 1994
    Date of Patent: May 20, 1997
    Assignee: Komag, Incorporated
    Inventors: Rajiv Y. Ranjan, Tu Chen, Tsutomu T. Yamashita, John K.-J. Chen
  • Patent number: 5626973
    Abstract: A magneto-optical layer sensitive to a light with a short wavelength such as 400 to 550 nm and having a perpendicular magnetization can be deposited on a substrate at a room temperature. The magneto-optical layer is of a tertiary polycrystalline having a composition, for example, Co.sub. aPt.sub.b Ru.sub.c where 20.ltoreq.a.ltoreq.70, 10.ltoreq.b.ltoreq.70, 10.ltoreq.c.ltoreq.60 and a+b+c=100 or Co.sub.d Pt.sub.e Re.sub.f where d.ltoreq.80, 5.ltoreq.e, 5.ltoreq.f, 40.ltoreq.4d-5f and d+e+f=100, and has an easy magnetization axis perpendicular to the main surface of the layer.
    Type: Grant
    Filed: August 4, 1994
    Date of Patent: May 6, 1997
    Assignee: Teijin Limited
    Inventors: Yoshihiko Takeda, Tomokazu Umezawa, Kiyoshi Chiba
  • Patent number: 5587026
    Abstract: Disclosed is a ferromagnetic film consisting of an alloy represented by a formula Co.sub.x Fe.sub.y T.sub.z, where T is an element selected from the group consisting of Ta, Ti, Zr, Hf, Mo, and W, and x, y, and z represent atomic % and satisfy 73<x<94, 5<y<15, 1<z<12, and x+y+z=100. This ferromagnetic film has high saturation magnetic flux density, and soft magnetism not to be degraded by high-temperature annealing, and which is suitably applied to a magnetic head.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: December 24, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hitoshi Iwasaki, Yuichi Ohsawa, Reiko Kondoh
  • Patent number: 5578266
    Abstract: Disclosed are a hydrogen storage alloy which contains carbon in a proportion of from 30 to 500 ppm and is represented by the stoichiometric formula A.sub.x B.sub.5.0, wherein A is La or a mixture of La with at least one rare earth metal other than La, B is at least one metal selected from a group consisting of Al, Co, Cr, Cu, Fe, Mn, Ni, Ti, V, Zn and Zr, and x is a rational number in the range 0.95.ltoreq..times..ltoreq.1.00; and has a texture in which only the intermetallic compound phase named AB.sub.5 phase is present and every other intermetallic compound phase is absent: and a method of producing said alloy and an electrode using the same.
    Type: Grant
    Filed: September 19, 1994
    Date of Patent: November 26, 1996
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yasushi Takai, Kazuhiro Yamada, Takashi Toide, Shigenobu Tajima
  • Patent number: 5576098
    Abstract: A thin film magnetic head includes an upper magnetic core film and a lower magnetic core film laminated one on another through a magnetic gap layer. The upper and lower magnetic core films are multilayer thin films, respectively, each of which is composed of a plurality of magnetic thin film layers and a plurality of non-magnetic thin film layers, alternately laminated one on another. The magnetic core films and have single domain structures, respectively, and the use of such magnetic core films realizes a thin film magnetic head having high permeability at high frequencies and improved high frequency characteristics and attains high recording density.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: November 19, 1996
    Assignee: Fuji Electric Co., Ltd.
    Inventors: Yuko Arimoto, Takabumi Fumoto, Keiji Okubo, Osamu Saito, Toyoji Ataka, Hisashi Yamasaki
  • Patent number: 5565830
    Abstract: A rare earth-cobalt supermagnetostrictive alloy having a composition represented by the general formula, in atomic fraction: R (Co.sub.1-x Fe.sub.x).sub.x, wherein 0.001.ltoreq.x.ltoreq.0.8, 0.2.ltoreq.z.ltoreq.15, and R is at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu and is consisting essentially of a cubic system whose easy axis of magnetization is generally <100> or <110> oriented; or R (Co.sub.1-x Fe.sub.x).sub.x, wherein 0.001.ltoreq.x.ltoreq.0.8, 0.2.ltoreq.z.ltoreq.15, and R is at least one element selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb, and Lu. Such an alloy exhibits satisfactory magnetostriction in a wide range of temperatures from room temperature to liquid nitrogen temperature.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: October 15, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masashi Sahashi, Tadahiko Kobayashi
  • Patent number: 5560786
    Abstract: Novel thin film materials comprised of certain Co-based alloys containing phosphorous, i.e., Co-Cr-P-Pt or Co-Cr-P-Ni alloy, which can provide a high coercive force and a high squareness ratio are disclosed. These magnetic thin film alloys exhibit excellent magnetic properties without heating the substrate or applying bias thereto during the film formation and when glass is used for the substrate as well as an Al alloy disk.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: October 1, 1996
    Assignee: Korea Institute of Science and Technology
    Inventors: Kyung H. Shin, Taek D. Lee, Hong G. Sohn, Pyung W. Chang, Chang M. Park
  • Patent number: 5539380
    Abstract: A glassy metal alloy consists essentially of the formula Co.sub.a Fe.sub.b Ni.sub.c M.sub.d B.sub.e Si.sub.f C.sub.g, where M is selected from molybdenum and chromium and "a", "b", "c", "d", "e", "f" and "g" are in atom percent, "a" ranges from about 40 to about 43, "b" ranges from about 35 to about 42 and "c" ranges from 0 to about 5, "d" ranges from 0 to about 3, "e" ranges from about 10 to about 25, "f" ranges from 0 to about 15 and "g" ranges from 0 to about 2. The alloy can be cast by rapid solidification into ribbon, annealed to enhance magnetic properties thereof, and formed into a marker that is especially suited for use in magneto-mechanically actuated article surveillance systems. Advantageously, the marker is characterized by relatively linear magnetization response in the frequency regime wherein harmonic marker systems operate magnetically.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 23, 1996
    Assignee: AlliedSignal Inc.
    Inventors: Ryusuke Hasegawa, Ronald Martis
  • Patent number: 5496631
    Abstract: Disclosed herein is a perpendicular magnetic film comprising a spinel thin film which is formed on a substrate, which contains Fe as the main ingredient and further contains Co and Ni, and which has a coercive force of less than 3000 Oe, the plane (400) thereof being predominantly oriented in parallel with said substrate, the spacing of the plane (400) being not more than 2.082 .ANG., the molar ratio of Co to Fe being 0.005 to 0.32 and the molar ratio of Ni to Co being at least 0.6.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: March 5, 1996
    Assignee: Toda Kogyo Corporation
    Inventor: Kousaku Tamari
  • Patent number: 5495231
    Abstract: A glassy metal alloy consists essentially of the formula Co.sub.a Fe.sub.b Ni.sub.c M.sub.d B.sub.e Si.sub.f C.sub.g, where M is selected from molybdenum and "a", "b", "c", "d", "e", "f" and "g" are in atom percent, "a" ranges from about 40 to about 43, "b" ranges from about 35 to about 42 and "c" ranges from 0 to about 5, "d" ranges from 0 to about 3, "e" ranges from about 10 to about 25, "f" ranges from 0 to about 15 and "g" ranges from 0 to about 2. The alloy can be cast by rapid solidification into ribbon or otherwise formed into a marker that is especially suited for use in magneto-mechanically actuated article surveillance systems. Advantageously, the marker is characterized by relatively linear magnetization response in the frequency regime wherein harmonic marker systems operate magnetically. Voltage amplitudes detected for the marker are high, and interference between surveillance systems based on mechanical resonance and harmonic re-radiance is virtually eliminated.
    Type: Grant
    Filed: April 13, 1995
    Date of Patent: February 27, 1996
    Assignee: AlliedSignal Inc.
    Inventor: Ryusuke Hasegawa
  • Patent number: 5484491
    Abstract: Disclosed is a ferromagnetic film consisting of an alloy represented by a formula (M.sub.a T.sub.b).sub.x N.sub.y, wherein M consists of Co and Fe, T is an element selected from the group of transition metals consisting of Ta and Nb, N is nitrogen, a, b, x, and y represent at % and satisfy 85<a<95, 5<b<15, a+b=100, 82<x<97.5, 2.5<y<18, and x+y=100, and the Fe content of M satisfies 2.5.ltoreq.Fe.ltoreq.12.5 at %. This ferromagnetic film has high saturation magnetic flux density, and soft magnetism not to be degraded by high-temperature annealing, and which is suitably applied to a magnetic head.
    Type: Grant
    Filed: January 31, 1994
    Date of Patent: January 16, 1996
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hitoshi Iwasaki, Yuichi Ohsawa, Reiko Kondoh
  • Patent number: 5466307
    Abstract: This invention relates to a rare earth containing multicomponent magnetic alloy powder consisting of no less than six components. During its preparation by reduction and diffusion process, one or more than one dispersing agent is added to the mixture of starting materials so that the allowable range of operational parameters is widened, the stability of product quality improved and the production cost reduced. Extensive studies have been made on the behavior of copper and calcium during processing making it possible to make precise compositional control of the final product. Rare earth permanent magnetic alloy powder of the R.sub.2 Co.sub.17 type prepared in accordance with the method of this invention ensures satisfactory quality and consistency.
    Type: Grant
    Filed: July 6, 1993
    Date of Patent: November 14, 1995
    Assignee: Shanghai Yue Long Non-Ferrous Metals Limited
    Inventors: Maofu Tong, Jiancheng Xiong, Xiangdong Geng
  • Patent number: 5401307
    Abstract: A protective coating resistant to corrosion at medium and high temperatures is applied on a nickel-based or cobalt-based superalloy component. The protective coating essentially consists of the following elements (in percent by weight): 25 to 40% nickel, 28 to 32% chromium, 7 to 9% aluminum, 1 to 2% silicon, 0.3 to 1% of at least one reactive element of the rare earths, at least 5% cobalt; and impurities, as well as selectively from 0 to 15% of at least one of the elements of the group consisting of rhenium, platinum, palladium, zirconium, manganese, tungsten, titanium, molybdenum, niobium, iron, hafnium, and tantalum. The total share of the elements of the group is from 0 to a maximum of 15% and a remainder of at least 5% cobalt. The component and the coating applied thereon have a ductile brittle transition temperature below 500.degree. C.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: March 28, 1995
    Assignee: Siemens Aktiengesellschaft
    Inventors: Norbert Czech, Friedhelm Schmitz
  • Patent number: 5358576
    Abstract: In amorphous materials including at least one iron-transition metal of Fe, Co, and Ni, and at least one metalloid of B, C, Si, and P, excellent magnetic characteristics can be provided subject to the condition that 0.5 to 10 atomic % of the above-described iron-transition metals are substituted by Mn. In addition, when the amorphous material partially substituted with Mn as described above is further comprised of at least one element selected from Groups IIIa, IVa, Va, and VIa in the periodic table, the crystallization temperature is considerably raised.
    Type: Grant
    Filed: June 6, 1980
    Date of Patent: October 25, 1994
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Harufumi Senno, Hiroshi Sakakima, Masatsugu Yamaguchi, Eiichi Hirota
  • Patent number: 5338508
    Abstract: There is provided alloy steel powders for the injection molding use manufactured by the atomizing method which are characterized by their substantially spherical particle shape and average particle diameters of 20 microns or less, a compound for the injection molding use which contains the alloy steel powders and one or more organic binders, a process for manufacturing sintered materials in performing injection molding of compound and subsequently debinding the obtained injection molded part followed by sintering the debound part, at least the first stage of the sintering step is performed in reduced pressure atmosphere, and the sintered material having a relative density ratio of 92% or more.
    Type: Grant
    Filed: October 16, 1992
    Date of Patent: August 16, 1994
    Assignee: Kawasaki Steel Corporation
    Inventors: Minoru Nitta, Yoshisato Kiyota, Yukio Makiishi, Hiroshi Ohtsubo, Toshio Watanabe, Yasuhiro Habu
  • Patent number: 5290509
    Abstract: A hydrogen-absorbing alloy electrode for an alkaline storage cell, the electrode including a hydrogen-absorbing alloy expressed by a composition formula ReBxMy, wherein Re is at least one element selected from a group consisting of rare earth elements and alkali earth elements, B is boron, and M is at least one element selected from a group consisting of Ni, Co, Mn, Al, Cr, Fe, Cu. Sn, Sb, Mo, V, Nb, Ta, Zn, Zr and Ti. The alloy consists essentially of an RM.sub.y main metal phase, and a subordinate boron-containing phase, such as a compound phase of boron and a IV-a, V-a, or VI-a group metal.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: March 1, 1994
    Assignee: Sanyo Electric Co., Ltd.
    Inventors: Nobuhiro Furukawa, Kazuro Moriwaki, Mitsuzo Nogami, Seiji Kameoka, Motoo Tadokoro
  • Patent number: 5282946
    Abstract: A sputtering target of platinum-cobalt alloy is disclosed which contains 10 to 55% by weight of platinum; 1 to 15% by weight of a first additional element selected from the group consisting of nickel and tantalum; no more than 1.5% by weight of a second additional element selected from the group consisting of boron, titanium, lanthanum, cerium, neodymium, beryllium, calcium, zirconium, and silicon; no more than 20% by weight of chromium; and balance cobalt. A method for manufacturing the sputtering target is also disclosed. In the method, a platinum-cobalt alloy containing specific ingredients in predetermined amounts is first prepared. Then, the platinum-cobalt alloy is subjected to hot plastic working with a thickness reduction of no less than 30%. Subsequently, the alloy thus hot worked is subjected to a cold plastic working with a thickness reduction of no less than 5% at a temperature less than the recrystallization temperature of the alloy.
    Type: Grant
    Filed: June 25, 1992
    Date of Patent: February 1, 1994
    Assignee: Mitsubishi Materials Corporation
    Inventors: Makoto Kinoshita, Jun Tamura, Masaki Morikawa, Kunio Kishida, Toshinori Ishii, Akifumi Mishima
  • Patent number: 5242762
    Abstract: In a magnetic recording medium including a substrate and an alloy thin film magnetic layer formed on the substrate, the magnetic layer is composed of Co.sub.100-y (Pt.sub.100-x Pd.sub.x).sub.y where x is set to 0<x.ltoreq.80 (atomic %), and y is set to 10.ltoreq.y.ltoreq.35 (atomic %). Accordingly, a sufficiently high coercive force in an in-plane direction and a sufficiently high saturation magnetization can be obtained, and the magnetic recording medium can be produced at a low cost.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: September 7, 1993
    Assignee: Sony Corporation
    Inventor: Akira Kouchiyama
  • Patent number: 5238481
    Abstract: A heat-resistant sintered hard alloy comprises 35% to 95% by weight of a WCoB type complex boride in a cobalt base alloy. The alloy contains 1.5% to 4.1% boron, 19.1% to 69.7% tungsten, optionally to 25% chromium, the balance being cobalt and a maximum of 1% impurities. Nickel, iron and/or copper may be substituted for portions of the cobalt content.
    Type: Grant
    Filed: January 23, 1992
    Date of Patent: August 24, 1993
    Assignee: Toyo Kohan Co., Ltd.
    Inventors: Kenichi Takagi, Masao Komai, Yoshihiko Isobe
  • Patent number: 5200002
    Abstract: An amorphous, low-retentivity alloy contains cobalt, manganese, silicon and boron. The alloy has the composition(Co.sub.a Ni.sub.b T.sub.c Mn.sub.d Fe.sub.e).sub.100-t (Si.sub.x B.sub.y M.sub.z).sub.t,whereby T is at least one of the elements chromium, molybdenum, tungsten, vanadium, niobium, tantalumn, titanium, zirconium and hafnium and M is at least one of the elements phosphorous, carbon, aluminum, gallium, indium, germanium, tin, lead, arsenic, antimony, bismuth and beryllium and the following relationships apply: 0.39.ltoreq.a.ltoreq.0.99; 0.ltoreq.b.ltoreq.0.40; 0.ltoreq.c.ltoreq.0.08; 0.01.ltoreq.d.ltoreq.0.13; 0.ltoreq.e.ltoreq.0.02; 0.01.ltoreq.d+e.ltoreq.0.13; a+b+c+d+e=1; 18.ltoreq.t.ltoreq.35; 8.ltoreq.xt.ltoreq.24; 4.ltoreq.yt.ltoreq.24; 0.ltoreq.zt.ltoreq.8; and x+y+z=1. The inventive alloy is distinguished by a saturation magnetostriction .ltoreq.5.multidot.10.sup.-6 and is particularly suited for magnetic screens, sound heads and magnetic cores.
    Type: Grant
    Filed: June 5, 1980
    Date of Patent: April 6, 1993
    Assignee: Vacuumschmelze GmbH
    Inventor: Hans-Reiner Hilzinger
  • Patent number: 5183517
    Abstract: An improved permanent magnet composition comprising 22 to 28 wt % R, 5 to 16 wt % iron, 0.2 to 6.5 wt % copper, 0.1 to 6 wt % manganese, 0.5 to 6 wt % A, 0.1 to 2 wt % B and the balance cobalt, in which R is at least one of rare earth elements including yttrium, A is at least one of zinc and zirconium and B is at least one element selected from the group of aluminum, bismath and thallium.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: February 2, 1993
    Assignee: Fuji Electrochemical Co., Ltd.
    Inventors: Takaaki Yasumura, Teruo Kiyomiya, Yasutoshi Mizuno, Kazuo Matsui
  • Patent number: 5164025
    Abstract: There is provided a soft magnetic alloy having a composition expressed by formula Co.sub.x M.sub.z C.sub.w, wherein M represents one or more than one of the metal elements including Ti, Zr, Hf, Nb, Ta, Mo, V and W, and x, w and z represent the ratios in terms of atom % of the respective elements in the overall composition satisfying55.ltoreq.x.ltoreq.96,2.ltoreq.x.ltoreq.25,0.1.ltoreq.x.ltoreq.20 andx+z+w=100and metallurgically consisting of crystalline particles with an average diameter of less than 0.05 .mu.m. The alloy partially contains carbide(s) of element(s) M in the crystal phase. A magnetic head comprising such a soft magnetic alloy film shows an excellent saturated flux density that can accommodate the requirement of high recording density and other requirements.
    Type: Grant
    Filed: March 6, 1992
    Date of Patent: November 17, 1992
    Assignee: Alps Electric Co., Ltd.
    Inventor: Naoya Hasegawa
  • Patent number: 5151137
    Abstract: A magnetic alloy with ultrafine crystal grains having a composition represented by the general formula:Co.sub.100.sub.-x-y-z-a-b Fe.sub.a M.sub.x B.sub.y X.sub.z T.sub.b (atomic %)wherein M represents at least one element selected from Ti, Zr, Hf, V, Nb, Mo, Ta, Cr, W and Mn, X represents at least one element selected from Si, Ge, P, Ga, Al and N, T represents at least one element selected from Cu, Ag, Au, platinum group elements, Ni, Sn, Be, Mg, Ca, Sr and Ba, 0<a.ltoreq.30, 2.ltoreq.x.ltoreq.15, 10.ltoreq.y.ltoreq.25, 0.ltoreq.z.ltoreq.10, 0<b.ltoreq.10, and 12<x+y+z+b.ltoreq.35. Such a magnetic alloy can be produced by producing an amorphous alloy having the above composition, and subjecting the resulting amorphous alloy to a heat treatment to cause crystallization, thereby providing the resulting alloy having a structure, at least 50% of which is occupied by crystal grains having an average grain size of 500 .ANG. or less.
    Type: Grant
    Filed: November 16, 1990
    Date of Patent: September 29, 1992
    Assignee: Hitachi Metals Ltd.
    Inventors: Yoshihito Yoshizawa, Yoshio Bizen, Kiyotaka Yamauchi, Toshikazu Nishiyama, Shigekazu Suwabe
  • Patent number: 5114503
    Abstract: A magnetic core comprised of an amorphous alloy ribbon wound into a toroidal shape, wherein the said amorphous alloy has a composition of the formula:(Co.sub.1-x-y-z Fe.sub.x Ni.sub.y Mn.sub.z).sub.100-a-b-c M.sub.a Si.sub.b B.sub.cwherein M is at least one element selected from the group consisting of Nb, Cr and Mo, and x, y, z, a, b and c are numbers which satisfy relations of 0<a.ltoreq.6, 13.ltoreq.b.ltoreq.16, 7.ltoreq.b.ltoreq.10, 0<x.ltoreq.0.1, 0.ltoreq.y.ltoreq.0.2 and 0.ltoreq.x.ltoreq.0.13 respectively, said amorphous alloy after heat treatment having a rectangular ratio Br/Bs of at least 80%, a Bs value in a range of 5 KG to 8 KG and a stress relief ratio of at least 75%.
    Type: Grant
    Filed: March 24, 1987
    Date of Patent: May 19, 1992
    Assignee: Hitachi Metals, Inc.
    Inventors: Yoshihito Yoshizawa, Kiyotaka Yamauchi
  • Patent number: 5084115
    Abstract: A hard magnetic alloy free of rare earths, consisting of 14-20% of a transition metal (Zr or Hf), 1-5% silicon, 0.3-5.6% boron, and the remainder essentially cobalt, the alloy having a microstructure substantially devoid of nonmagnetic phases and consisting of a high proportion of (Co-Si).sub.11 TM.sub.2 phase and a lesser proportion of (Co-Si).sub.23 TM.sub.6 phase, such phases being distributed throughout in a regular manner in a fine grain. Substitution agents of nickel or iron may be used for up to 10% of the cobalt, substitutional agents of vanadium or niobium may be used for up to 5% of the TM, and aluminum, copper, or gallium for up to 2% of the silicon. The alloy has high coercivity, high temperture stability, and excellent corrosion resistance. The alloy may be processed directly by extrusion with reduced requirements for boron and silicon.
    Type: Grant
    Filed: September 14, 1989
    Date of Patent: January 28, 1992
    Assignee: Ford Motor Company
    Inventors: George C. Hadjipanayis, Chuan Gao, Donald L. Gramlich
  • Patent number: 5084795
    Abstract: A metal-in-gap type magnetic head having a small undulation of reproduction output caused by a pseudo-gap and method of manufacture thereof are provided, wherein the magnetic head employs as a back core a ferrite (particularly, a ferrite containing Sn) and employs in a metal portion which constitutes a front core an alloy film (particularly, a composition transition alloy film) having a composition expressed by T-M-X-N, where T is at least one metal element selected from a group consisting of Fe, Co and Ni, M is at least one metal element selected from a group consisting of Nb, Zr, Ti, Ta, Hf, Cr, Mo, W and Mn, X is at least one metalloid element selected from a group consisting of B, Si and Ge, and N is nitrogen.
    Type: Grant
    Filed: February 5, 1990
    Date of Patent: January 28, 1992
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Hiroshi Sakakima, Keita Ihara, Koichi Osano