Including Means To Strip Reaction Mass From, Or To Regenerate, The Particulate Matter (including Fluidized Bed Regenerators, Per Se) Patents (Class 422/144)
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Publication number: 20140171685Abstract: A catalytic reactor including a chamber (1) and separation means (2) arranged inside the chamber (1), said separation means defining at least one reaction area (3) and at least one regeneration area (4), the reaction area (3) being supplied with a reaction flow (15, 16) and connected, at the outlet thereof, to a first gas tapping device (13), the regeneration area (4) being supplied with a regeneration flow (17) and connected, at the outlet thereof, to a second gas tapping device (10), the reactor being suitable for including a fluidized bed of catalyst particles (5) in the reaction area (3), the separation means (2) enabling the catalyst particles to pass from the reaction area (3) to the regeneration area (4), and the reactor making it possible to move catalyst particles into the regeneration area (4) so as to enable the return thereof to the reaction area (3).Type: ApplicationFiled: July 9, 2012Publication date: June 19, 2014Applicant: ARKEMA FRANCEInventors: Jean-Luc Dubois, Grégory Patience
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Patent number: 8747759Abstract: A process and apparatus for mixing streams of regenerated and carbonized catalyst involves passing a catalyst stream into and out of a chamber in a lower section of a riser. The chamber fosters mixing of the catalyst streams to reduce their temperature differential before contacting hydrocarbon feed.Type: GrantFiled: December 12, 2011Date of Patent: June 10, 2014Assignee: UOP LLCInventors: Lisa M. Wolschlag, Lev Davydov, Paolo Palmas, Robert L. Mehlberg, Mohammad-Reza Mostofi-Ashtiani, Daniel R. Johnson, Chad R. Huovie, Michael S. Sandacz, Peter J. Van Opdorp, Thomas W. Lorsbach, Karthikeyan Paramanandam
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Patent number: 8747758Abstract: A process and apparatus for mixing streams of regenerated and carbonized catalyst involves passing a catalyst stream into and out of a chamber in a lower section of a riser. The chamber fosters mixing of the catalyst streams to reduce their temperature differential before contacting hydrocarbon feed.Type: GrantFiled: December 12, 2011Date of Patent: June 10, 2014Assignee: UOP LLCInventors: Lev Davydov, Lisa M. Wolschlag, Paolo Palmas, Robert L. Mehlberg, Mohammad-Reza Mostofi-Ashtiani, Daniel R. Johnson, Chad R. Huovie, Michael S. Sandacz, Peter J. Van Opdorp, Thomas W. Lorsbach, Karthikeyan Paramanandam
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Patent number: 8747757Abstract: A process for preparing granular polysilicon using a fluidized bed reactor is disclosed. Upper and lower spaces of the bed are the reaction zone and heating zone, respectively, wherein the height of the reaction gas outlet is the reference height. Reactor productivity is maximized by sufficiently providing the heat required and stably maintaining the reaction temperature in the reaction zone, without impairing the mechanical stability of the fluidized bed reactor. This is achieved through electrical resistance heating in the heating zone where an internal heater is installed between the reaction gas supplying means and the inner wall of the reactor tube, thereby heating the fluidizing gas and the silicon particles in the heating zone. The heat generated is transferred to the reaction zone by supplying the fluidizing gas at a rate silicon particles can be intermixed between the reaction zone and the heating zone in a continuous, fluidized state.Type: GrantFiled: August 9, 2007Date of Patent: June 10, 2014Assignee: Korea Research Institute of Chemical TechnologyInventors: Hee Young Kim, Kyung Koo Yoon, Yong Ki Park, Won Choon Choi
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Publication number: 20140150654Abstract: Regenerator for catalytic cracking unit comprising a first part occupied by a dense fluidized bed of catalyst and a second part positioned above the first part and occupied by a fluidized bed of low solid particles density, the said second part comprising one internal device covering, by projection onto the plane of the cross section of the said vessel of the regenerator, at least 80% of the said cross section, the said regenerator being equipped with at least one cyclone for separating gases/solids in the mixture derived from the low-density bed, the said cyclone being placed outside the vessel of the regenerator.Type: ApplicationFiled: August 14, 2012Publication date: June 5, 2014Applicant: TOTAL RAFFINAGE FRANCEInventors: Juan-David Llamas, Guillaume Berric
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Patent number: 8722565Abstract: A method for applying a washcoat suspension to a support structure. To provide coatings with largely uniform thickness starting from washcoat suspensions, the method uses a device (10) set up to produce, by means of a process gas (40), a fluid bed of support structures in which the support structures circulate elliptically or toroidally, the method comprising the steps of: a) charging the device (10) with support structures and producing a support-structure fluid bed by means of a process gas (40), wherein the support structures circulate in the fluid bed elliptically or toroidally, preferably toroidally; b) impregnating the support structures with a washcoat suspension by spraying the support structures circulating elliptically or toroidally in the fluid bed with the washcoat suspension; c) drying the support structures sprayed with the washcoat suspension; and d) optionally calcining the support structures loaded with the solids contents of the washcoat suspension.Type: GrantFiled: June 2, 2008Date of Patent: May 13, 2014Assignee: Sued-Chemie IP GmbH & Co. KGInventors: Gerhard Mestl, Christian Gückel, Marvin Estenfelder, Bastian Käding
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Publication number: 20140121434Abstract: The present invention provides a fluidized bed reactor and its use for producing olefins from oxygenates, the fluidized bed reactor comprises: a reaction zone located in the lower portion of the fluidized bed reactor and comprising a lower dense phase zone and an upper riser, wherein the dense phase zone and the riser are connected with each other transitionally; a separation zone located in the upper portion of the fluidized bed reactor and comprising a settling chamber, a fast gas-solid separation means, a cyclone and a gas collecting chamber, wherein the riser extends upwardly into the separation zone and is connected at its outlet with the inlet of the fast gas-solid separation means, the fast gas-solid separation means is connected at its outlet with the inlet of the cyclone via a fast gas passage, the cyclone is connected at its outlet with the gas collecting chamber, and the gas collecting chamber is located below the reactor outlet and connected therewith; and a catalyst recycle line for recycling theType: ApplicationFiled: May 30, 2012Publication date: May 1, 2014Applicants: Tsinghua University, Fude (Beijing) Chemical & Industry Co., Ltd.Inventors: Fei Wei, Xiaobo Wei, Yao Wang, Chang Zhu
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Patent number: 8702972Abstract: A process is disclosed for the separation of solids from gases in a mixture which is most particularly applicable to an FCC apparatus. The mixture of solids and gases are passed through a conduit and exit through a swirl arm that imparts a swirl motion having a first annular direction to centripetally separate the heavier solids from the lighter gases. The mixture then enters a gas recovery conduit in which at least one plate radially extending from an inner wall impedes rotational motion of the mixture. The mixture enters cyclones at the other end of the gas recovery conduit without substantial swirling motion.Type: GrantFiled: August 28, 2009Date of Patent: April 22, 2014Assignee: UOP LLCInventors: Lawrence A. Lacijan, Hadjira Iddir
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Patent number: 8696792Abstract: A fluidized reactor system for removing impurities from a gas and an associated process are provided. The system includes a fluidized absorber for contacting a feed gas with a sorbent stream to reduce the impurity content of the feed gas; a fluidized solids regenerator for contacting an impurity loaded sorbent stream with a regeneration gas to reduce the impurity content of the sorbent stream; a first non-mechanical gas seal forming solids transfer device adapted to receive an impurity loaded sorbent stream from the absorber and transport the impurity loaded sorbent stream to the regenerator at a controllable flow rate in response to an aeration gas; and a second non-mechanical gas seal forming solids transfer device adapted to receive a sorbent stream of reduced impurity content from the regenerator and transfer the sorbent stream of reduced impurity content to the absorber without changing the flow rate of the sorbent stream.Type: GrantFiled: September 28, 2010Date of Patent: April 15, 2014Assignee: Research Triangle InstituteInventors: Gunnar Henningsen, Teddy Merrill Knowlton, John George Findlay, Jerry Neal Schlather, Brian S. Turk
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Patent number: 8696995Abstract: Methods and apparatus for preventing coke formation in a plenum are provided. The apparatus can include a turbulator for use in a plenum. The turbulator can include a deflector disposed inside the plenum proximate an inlet to the plenum from a cyclone, wherein the plenum and the cyclone are disposed in a fluid catalytic cracker.Type: GrantFiled: February 9, 2011Date of Patent: April 15, 2014Assignee: Kellogg Brown & Root LLCInventors: Phillip K. Niccum, Ginger Eskew
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Patent number: 8692045Abstract: A process for producing light olefins is provided. A feedstock enters a pre-reaction zone and contacts a catalyst comprising at least one silicon-aluminophosphate molecular sieve and produces a gas-phase stream; the gas-phase stream and the catalyst enter at least one riser, and the gas-phase stream and the catalyst pass from an outlet of the at least one riser and enter a gas-solid rapid separation zone; the separated gas-phase stream enters a separation section; a first portion of the separated catalyst returns to the pre-reaction zone, and a second portion is regenerated in a regenerator; wherein an inlet of the at least one riser extends into the pre-reaction zone, about 60% to about 90% of the height of the at least one riser passes through a heat exchange zone, and the outlet extends into the gas-solid rapid separation zone.Type: GrantFiled: November 16, 2011Date of Patent: April 8, 2014Assignees: China Petroleum & Chemical Corporation, Shanghai Research Institute of Petrochemical TechnologyInventors: Guozhen Qi, Siqing Zhong, Wei Chen, Zhinan Yu
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Patent number: 8691155Abstract: Embodiments of a hydrocarbon conversion apparatus are provided, as are embodiments of a hydroprocessing conversion process. In one embodiment, the hydrocarbon conversion apparatus includes a reaction vessel having a reaction chamber and a feed distribution chamber. A riser fluidly couples the feed distribution chamber to the reaction chamber, and a catalyst recirculation standpipe fluidly couples the reaction chamber to the feed distribution chamber. The catalyst recirculation standpipe forms a catalyst recirculation circuit with the reaction chamber, the feed distribution chamber, and the riser. A catalyst is circulated through the catalyst recirculation circuit during operation of the hydrocarbon conversion apparatus.Type: GrantFiled: March 18, 2011Date of Patent: April 8, 2014Assignee: UOP LLCInventors: Paolo Palmas, Daniel Robert Johnson, Clayton C. Sadler
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Patent number: 8657902Abstract: Apparatuses for separating solid catalyst particles from a Fluid Catalytic Cracking (FCC) vapor are provided. In one embodiment, an apparatus includes a vessel formed with a vessel wall. A conduit is positioned within the vessel and is configured to direct flow of an FCC vapor-solid stream. The apparatus also includes a channel positioned within the vessel and in fluid communication with the conduit. The channel has a channel inlet with an inlet cross-sectional area and a channel outlet with an outlet cross-sectional area less than about 75% of the inlet cross-sectional area. The channel outlet is configured to direct the vapor-solid stream tangentially toward the vessel wall to separate the solid catalyst particles from the FCC vapor.Type: GrantFiled: December 19, 2011Date of Patent: February 25, 2014Assignee: UOP LLCInventor: Bing Sun
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Publication number: 20140030154Abstract: A system includes a reactor-adsorber configured to receive a gas, a regenerator configured to receive a saturated CO2 adsorption material from the reactor-adsorber, a first solids pressurizing feeder configured to convey the saturated CO2 adsorption material from the reactor-adsorber to the regenerator, and a second solids pressurizing feeder configured to convey a regenerated CO2 adsorption material from the regenerator to the reactor-adsorber. The reactor-adsorber includes a catalyst material configured to catalyze a water gas shift reaction of the gas to generate a hydrogen-rich gas, and a CO2 adsorption material configured to adsorb CO2 from the hydrogen-rich gas to generate the saturated CO2 adsorption material. The regenerator is configured to regenerate the saturated CO2 adsorption material to provide the regenerated CO2 adsorption material and CO2.Type: ApplicationFiled: July 27, 2012Publication date: January 30, 2014Applicant: General Electric CompanyInventor: Thomas Frederick Leininger
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Patent number: 8603406Abstract: An apparatus and process are presented for drying a catalyst in a reactor-regenerator system. The process includes a continuous operating system with catalyst circulating between a reactor and regenerator, and the catalyst is dried before returning the catalyst to the reactor. The process uses air that is split between the drying stage and the combustion stage without adding equipment outside of the regenerator, minimizing energy, capital cost, and space requirements.Type: GrantFiled: August 30, 2010Date of Patent: December 10, 2013Assignee: UOP LLCInventors: David N. Myers, Daniel N. Myers, Paolo Palmas, Laura E. Leonard, Wolfgang A. Spieker
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Patent number: 8601958Abstract: The invention relates to a plant and a process for the looping-type combustion of solid carbon-containing fuels with a carbon dioxide (CO2) flow output. Said process carries out the conversion of carbon without the help of solid carriers of the MyOx type, or of sulphate/sulphide type, and comprises the steps of: (i) Oxidation, wherein the carbon-containing solids are contacted with a gaseous flow comprising oxygen, for a time period and at a temperature sufficient to allow formation of a surface oxidized complex; (ii) Desorption, wherein the surface oxidized complexes generated by adsorption of oxygen in item (i) are released in a gaseous form by decomposition in the absence of O2.Type: GrantFiled: September 8, 2009Date of Patent: December 10, 2013Assignee: Consiglio Nazionale delle RicercheInventors: Piero Salatino, Osvalda Seneca
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Publication number: 20130280138Abstract: Fluid catalytic cracking units having risers with improved hydrodynamics through the use of baffles are described. The baffles break up the high concentration of catalyst in the slower moving outer annulus and redistribute it into the faster moving, more dilute center of the riser flow.Type: ApplicationFiled: April 20, 2012Publication date: October 24, 2013Applicant: UOP LLCInventors: Daniel R. Johnson, Lev Davydov
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Patent number: 8551324Abstract: The present invention describes a process for the production of gasoline in a fluid catalytic cracking unit having at least one principal reactor operating using feeds with a low Conradson Carbon and a high hydrogen content, said process comprising recycling a coking cut either to a side chamber branching off the stripper or within the stripper itself by means of a tubular vessel within said stripper.Type: GrantFiled: October 13, 2011Date of Patent: October 8, 2013Assignee: IFP Energies nouvellesInventors: Frederic Feugnet, Romain Roux
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Publication number: 20130236367Abstract: Production of polycrystalline silicon in a substantially closed-loop process is disclosed. The processes generally include decomposition of trichlorosilane produced from metallurgical grade silicon.Type: ApplicationFiled: April 26, 2013Publication date: September 12, 2013Applicant: MEMC ELECTRONIC MATERIALS, INC.Inventors: Satish Bhusarapu, Yue Huang, Puneet Gupta
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Patent number: 8506891Abstract: An apparatus is disclosed for catalytically converting two feed streams. The feed to a first catalytic reactor may be contacted with product from a second catalytic reactor to effect heat exchange between the two streams and to transfer catalyst from the product stream to the feed stream. The feed to the second catalytic reactor may be a portion of the product from the first catalytic reactor.Type: GrantFiled: November 9, 2009Date of Patent: August 13, 2013Assignee: UOP LLCInventors: Laura E. Leonard, Jibreel A. Qafisheh, Robert L. Mehlberg
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Patent number: 8480965Abstract: Injection nozzles for use in a gas distribution device are disclosed. In one aspect, the injection nozzle may include: a tube having a fluid inlet and a fluid outlet; wherein the inlet comprises a plurality of flow restriction orifices. In another aspect, embodiments disclosed herein relate to an injection nozzle for use in a gas distribution device, the injection nozzle including: a tube having a fluid inlet and a fluid outlet; wherein the fluid inlet comprises an annular orifice surrounding a flow restriction device. Injection nozzles according to embodiments disclosed herein may be disposed in a gas distribution manifold used in a vessel, for example, for conducting polymerization reactions, spent catalyst regeneration, and coal gasification, among others.Type: GrantFiled: December 8, 2011Date of Patent: July 9, 2013Assignee: Lummus Technology Inc.Inventors: Leonce Francis Castagnos, Jr., Ting Yee Chan, Norman Paul Kolb, Ronald Eugene Pieper
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Patent number: 8470252Abstract: A process to upgrade heavy oil and convert the heavy oil into lower boiling hydrocarbon products is provided. The process employs a catalyst slurry comprising catalyst particles with an average particle size ranging from 1 to 20 microns. In the upgrade process, spent slurry catalyst in heavy oil is generated as an effluent stream, which is subsequently recovered/separated from the heavy oil via membrane filtration. Residual hydrocarbons, i.e., heavy oil and solvent employed in the filtration for the heavy oil extraction are removed from the catalyst particles in a drying zone which employs at least two drying apparatuses to volatize residual hydrocarbons in the catalyst. Valuable metals can be recovered from catalyst particles for subsequent re-use in a catalyst synthesis unit, generating a fresh slurry catalyst.Type: GrantFiled: April 13, 2012Date of Patent: June 25, 2013Assignee: Chevron U.S.A. Inc.Inventor: Seyi A. Odueyungbo
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Publication number: 20130156650Abstract: A system for distributing particulate material into a particulate vessel includes a particulate material distributor for introducing the particulate material into the particulate vessel. The particulate material distributor includes a declined header that defines a plurality of orifices that are spaced along a length of the declined header for accommodating flow of particulate material from the declined header. The system also includes a vessel level controller for controlling a level of the particulate material in the particulate vessel. The vessel level controller controls flow of the particulate material through one or more of the orifices in the declined header through adjustment of the level of particulate material in the particulate vessel between the plurality of orifices in the declined header. A FCC unit including the system is also provided, along with a method for distributing particulate material into a particulate vessel using the system.Type: ApplicationFiled: December 19, 2011Publication date: June 20, 2013Applicant: UOP LLCInventor: Patrick D. Walker
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Patent number: 8431081Abstract: Solvent extraction is used to remove wax and contaminants from an iron-based Fischer-Tropsch catalyst in a natural circulation continuous-flow system. The wax-free catalyst is then subjected to controlled oxidation to convert the iron to its initial oxidized state, Fe2O3. Reactivation of the oxide catalyst precursor is carried out by addition of synthesis gas.Type: GrantFiled: May 10, 2011Date of Patent: April 30, 2013Assignee: Rentech, Inc.Inventors: Belma Demirel, Mark S. Bohn, Charles B. Benham, James E. Siebarth, Mark D. Ibsen
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Patent number: 8425849Abstract: A reclaiming apparatus 106 includes: a sealed container 106a that is an absorbent reservoir for storing therein a part of an absorbent that has absorbed CO2 in flue gas, and a heater that heats the absorbent stored in the sealed container 106a. The reclaiming apparatus 106 distributes a part of the absorbent stored in the sealed container 106a, and brings the distributed absorbent into counter-current contact with steam. Because a part of the absorbent stored in the absorbent reservoir is brought into counter-current contact with the steam, absorbent component contained therein becomes volatilized, and is separated from depleted materials. In this manner, the absorbent component can be extracted from the depleted materials, and a loss of the absorbent can be reduced.Type: GrantFiled: April 1, 2010Date of Patent: April 23, 2013Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Masaki Iijima, Masahiko Tatsumi, Yasuyuki Yagi, Kouki Ogura
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Publication number: 20130068138Abstract: A process for lowering the carbon content in ash includes introducing the ash having a carbon content of 1 to 20 wt.-% into a reactor where the ash is burnt at a temperature between 700 and 1100° C. Fuel is also introduced into the reactor. During combustion, microwave radiation is fed into the reactor. At least part of the energy released during the combustion is recovered.Type: ApplicationFiled: May 30, 2011Publication date: March 21, 2013Applicant: OUTOTEC OYJInventors: Nikola Anastasijevic, Guenter Schneider
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Patent number: 8398751Abstract: Systems and methods for the separation of a particulate-fluid suspension are provided. An apparatus for the separation of a particulate-fluid suspension can include an enclosed vessel having two or more sections disposed coaxially along a common longitudinal centerline, wherein a first section has a first cross sectional area and a second section has a second cross sectional area. A plurality of apertures can be disposed about the second section. The apparatus can have a cylindrical surface, parallel to the longitudinal centerline of the apparatus, disposed within the first section. A fluid distribution channel having a plurality of apertures can be disposed either about an exterior surface or an interior of the apparatus. A plurality of fluid conduits can provide fluid communication between the fluid distribution channel and the plurality of apertures distributed about the second section.Type: GrantFiled: December 21, 2011Date of Patent: March 19, 2013Assignee: Kellogg Brown & Root LLCInventors: Yong-Lin Yang, Eusebius Gbordzoe
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Patent number: 8383052Abstract: Catalyst regenerators and methods for using same. The regenerator can include a regenerator housing containing a dense phase catalyst bed for receiving a catalyst to be regenerated. A heater can be disposed in the regenerator and can have a fuel nozzle configured to eject a mixture of fuel and an oxygen-lean gas for combustion to supplement the heat to satisfy the reactor heat demand when a light feedstock cracked that may not provide sufficient coke formation on the catalyst to fully satisfy the reactor heat demand.Type: GrantFiled: April 16, 2010Date of Patent: February 26, 2013Assignee: Kellogg Brown & Root LLCInventor: Phillip K. Niccum
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Patent number: 8383051Abstract: The present invention provides a compact riser separation system for Fluid Catalytic Cracking reactors possessing an external riser system wherein the riser enters the reactor from outside the reactor vessel.Type: GrantFiled: July 22, 2009Date of Patent: February 26, 2013Assignee: Stone & Webster Process Technology, Inc.Inventors: Eusebius Anku Gbordzoe, Chris Robert Santner
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Patent number: 8372997Abstract: According to the invention, powders of low hygroscopicity are prepared by granulation of an aqueous solution (1) in a fluidized bed (140). A compound formed from crystalline grains whose moisture content is defined and stable is obtained. The invention applies especially to organometallic complexes of glycine with a metal.Type: GrantFiled: August 17, 2009Date of Patent: February 12, 2013Assignee: Pancosma Societe Anonyme pour l'Industrie des Produits BiochimiquesInventors: Jean-Philippe Meunier, Sébastien Oguey
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Publication number: 20130017142Abstract: The present invention provides a carbon nanomaterial production apparatus 1 that includes a reaction tube 2 into which raw material gas and carrier gas are supplied and accordingly in which carbon nanomaterial is grown, a connection tube 4 that is connected to the reaction tube 2 and through which an aerosol-like mixture of the carbon nanomaterial and the carrier gas passes, and a collection tube 3 that is connected to the connection tube 4 and collects the carbon nanomaterial from the mixture. The collection tube 3 includes a discharge section 32 that is located above a junction 33 with the connection tube 4 and discharges the carrier gas contained in the mixture to outside, and a trapping section 31 that is located below the junction 33 with the connection tube 4 and traps the carbon nanomaterial that is separated from the mixture by gravitational sedimentation.Type: ApplicationFiled: February 17, 2011Publication date: January 17, 2013Applicants: HITACHI CHEMICAL COMPANY, LTD., The University of TokyoInventors: Suguru Noda, Toshio Osawa, Dong Young Kim, Eisuke Haba, Shunsuke Ueda
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Patent number: 8354065Abstract: This device is an FCC Catalyst Charge Heater. The device uses a catalyst cooler to preheat FCC feedstocks. It can be used with or without an FCC Catalyst Heater in the regenerator to satisfy the FCC unit heat balance while maximizing liquid volume yield and reducing FCC emissions.Type: GrantFiled: January 20, 2010Date of Patent: January 15, 2013Assignee: Marathon Petroleum Company LPInventors: Jeff Sexton, David A. Lomas
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Patent number: 8349753Abstract: An improved spent catalyst regenerator which contains sub-troughs branching off from the main trough, distribution troughs which extend outward from the sides of the main trough and the sub-troughs, and downflow tubes extending downward from the bottom of the main trough and sub-troughs.Type: GrantFiled: March 23, 2011Date of Patent: January 8, 2013Assignee: Stone & Webster Process Technology, Inc.Inventors: Chris Santner, Eusebius Gbordzoe, Harvey McQuiston
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Patent number: 8337801Abstract: A process for producing calcine products includes dead roasting a metal sulfide concentrate having a low sulfur content. The concentrate is roasted in a circulating fluidized bed at a temperature of about 950 to 1050° C. A waste gas of the fluidized bed is passed through at least one of a recuperator and a Venturi drier so as to respectively provide at least one of a preheating of at least a portion of air fluidizing the fluidized bed and a drying of at least a portion of the concentrate to be roasted. The calcine product obtained in the fluidized bed with a sulfur content of less than 1 wt-% is provided for further processing.Type: GrantFiled: July 10, 2009Date of Patent: December 25, 2012Assignee: Outotec OyjInventors: Joerg Hammerschmidt, Bernd Kerstiens, Peter Sturm
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Patent number: 8323477Abstract: A process for mixing regenerated and carbonized catalyst involves obstructing upward flow of catalyst by one or more baffles between a catalyst inlet and a feed distributor. Each catalyst stream may be passed to opposite sides of a riser. Baffles obstruct upward flow to effect mixing of regenerated and carbonized catalyst to obtain a more uniform temperature and catalyst mixture before contacting the feed.Type: GrantFiled: September 30, 2008Date of Patent: December 4, 2012Assignee: UOP LLCInventors: Keith A. Couch, Kelly D. Seibert, Robert L. Mehlberg, Daniel R. Johnson
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Publication number: 20120298556Abstract: A method for circulating a cooled regenerated catalyst comprises the following steps: a regenerated catalyst derived from a regenerator (5) is cooled to 200-720° C. by a catalyst cooler (8A), which either directly enters into a riser reactor (2) without mixing with hot regenerated catalyst, or enters the same after mixing with another portion of uncooled hot regenerated catalyst and thereby obtaining a hybrid regenerated catalyst with its temperature lower than that of the regenerator; a contact reaction between a hydrocarbon raw materials and the catalyst is performed in the riser reactor (2); the reaction product is introduced into a settling vessel (1) to separated the catalyst and oil gas; the separated catalyst ready for regeneration is stream-stripped in a stream stripping phase (1A) and enters the regenerator (5) for regeneration through charring; after cooling, the regenerated catalyst returns to the riser reactor (2) for recycling.Type: ApplicationFiled: February 11, 2010Publication date: November 29, 2012Inventors: Li Li, Qunzhu Li
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Patent number: 8321082Abstract: In a hybrid vehicle, control is executed to operate an engine with fuel injection being performed, when an unexecuted percentage of catalyst degradation suppression control is equal to or greater than a threshold value of the unexecuted percentage, when a power storage percentage of a battery is equal to or greater than a threshold value of the power storage percentage and the battery is charging, and also when a vehicle speed is equal to or greater than a threshold value of the vehicle speed and a cumulative air amount is equal to or greater than a threshold value of the cumulative air amount, when a catalyst temperature is less than a first threshold temperature and equal to or greater than a second threshold temperature, when the catalyst temperature is equal to or greater than the first threshold temperature, when there is a braking request while the engine is operating.Type: GrantFiled: September 13, 2011Date of Patent: November 27, 2012Assignee: Toyota Jidosha Kabushiki KaishaInventor: Yasushi Ando
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Patent number: 8318101Abstract: The invention relates to an oil-derived hydrocarbon converter comprising a catalytic cracking vessel (1) in the presence of catalyst particles in fluidized phase and a regenerator, for regenerating said catalyst particles by burning off the coke deposited on them, said catalyst circulating between said cracking vessel and said regenerator, said regenerator being a reactor (2) integrated into a combustion installation for steam generation comprising carbon dioxide capture.Type: GrantFiled: December 22, 2006Date of Patent: November 27, 2012Assignee: ALSTOM Technology LtdInventors: Jean-Xavier Morin, Corinne Beal, Silvestre Suraniti
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Patent number: 8299314Abstract: The present invention is directed to a method and system for integrating a catalyst regeneration system with a plurality of hydrocarbon conversion apparatuses, preferably, a plurality of multiple riser reactor units. One embodiment of the present invention is a reactor system including a plurality of reactor units, at least one reactor unit preferably comprising a plurality of riser reactors. The system also includes a regenerator for converting an at least partially deactivated catalyst to a regenerated catalyst. A first conduit system transfers the at least partially deactivated catalyst from the reactor units to the regenerator, and a second conduit system transfers regenerating catalysts from the regenerator to the plurality of reactor units. Optionally, catalysts from a plurality of hydrocarbon conversion apparatuses may be directed to a single stripping unit and/or a single regeneration unit.Type: GrantFiled: April 18, 2007Date of Patent: October 30, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: James H. Beech, Michael Peter Nicoletti, James R. Lattner, Dennis George Alexion, Peter K. Paik
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Patent number: 8292977Abstract: The invention has its object to arbitrarily adjust an amount of particles to be circulated without changing a flow rate of a gasification agent to thereby enhance gasification efficiency in a fluidized bed gasification furnace. The fluidized bed gasification furnace 107 comprises first and second chambers 113 and 114 in communication with each other in a fluidized bed 105. The hot particles 102 separated in the separator 104 and raw material M are introduced into the first chamber 113. The particles 102 introduced from the first chamber 113 through interior in the fluidized bed 105 to the second chamber 114 are supplied in an overflow manner to the fluidized bed combustion furnace 100.Type: GrantFiled: March 2, 2007Date of Patent: October 23, 2012Assignee: IHI CorporationInventors: Toshiyuki Suda, Yoshiaki Matsuzawa, Toshiro Fujimori
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Patent number: 8287613Abstract: Gas-solids separator comprises a tubular housing, an inlet for introducing a gas-solids mixture at one end of said housing, which inlet is executed such that it imparts a swirl to the gas-solids mixture, a solids outlet opening at the opposite end of said housing, and a co-axially positioned tubular gas outlet conduit placed at an end of said housing, which separator further comprises a vortex stabilizer, comprising a pin placed on a stabilizing plate, in which separator the pin runs along the axis of the tubular housing and in which a passageway is provided through the stabilizer plate and the pin.Type: GrantFiled: May 27, 2008Date of Patent: October 16, 2012Assignee: Shell Oil CompanyInventors: Ye-Mon Chen, Hubertus Wilhelmus Albertus Dries, Kee-Khoon Foo
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Patent number: 8282886Abstract: An improved process and system for the endothermic dehydrogenation of an alkane stream is described. The process and system for catalytic dehydrogenation comprise a back-mixed fluidized bed reactor. The alkane stream is dehydrogenated in a single reactor stage by contacting the alkane stream with a back-mixed fluidized bed of catalyst. Deactivated catalyst is withdrawn from the back-mixed fluidized reactor and heated to produce hot regenerated catalyst. The hot regenerated catalyst is returned to the back-mixed fluidized bed reactor at a rate sufficient to maintain the back-mixed fluidized bed reactor at substantially isothermal conditions.Type: GrantFiled: January 25, 2011Date of Patent: October 9, 2012Assignee: UOP LLCInventors: Bryan K. Glover, Julie A. Zarraga, Michael A. Schultz
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Patent number: 8282885Abstract: An FCC apparatus may include a distributor disposed in a recess in a wall of the riser for distributing gaseous hydrocarbon feed to a riser. The distributor may be shielded from upwardly flowing catalyst by a shield. An array of nozzles from the distributor may extend through openings in the shield.Type: GrantFiled: June 29, 2010Date of Patent: October 9, 2012Assignee: UOP LLCInventors: Paolo Palmas, Paul S. Nishimura
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Patent number: 8263008Abstract: A process and apparatus for improving flow properties of crude may include processing a first crude stream, which may in turn include cracking the first crude stream with catalyst to form a cracked stream and spent catalyst, hydrotreating a portion of the cracked stream and then mixing the hydrotreated stream with an unprocessed second crude stream.Type: GrantFiled: December 18, 2008Date of Patent: September 11, 2012Assignee: UOP LLCInventors: Brian W. Hedrick, Daniel B. Gillis
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Patent number: 8241408Abstract: Disclosed is a CO capturing device for improving CO removal efficiency and use of a dry solid absorbent. The device comprises a CO recovery reactor 1 to permit CO containing gas externally supplied to be in contact with a dry solid absorbent to capture CO; a recovery cyclone 4 connected to the recovery reactor 1 to exhaust CO-free gas while separating a solid portion containing CO; a fluidized bed type regeneration reactor 2 which receives the solid portion through a solid feeding pipe 5 connected to the recovery cyclone 4 and divides the solid portion into CO and the other part containing the dry solid absorbent by using a fluidizing gas fed through a fluidizing gas supply pipe 8; a regeneration cyclone 6 to exhaust the separated CO outside in order to use CO in the regeneration reactor 2; and a water vapor pretreatment device 3 connected to the regeneration reactor 2 to absorb H O in the dry solid absorbent and feedback the H O containing absorbent to the recovery reactor 1.Type: GrantFiled: February 13, 2007Date of Patent: August 14, 2012Assignee: Korea Institute of Energy ResearchInventors: Chang-Keun Yi, Gyong-Tae Jin, Do-Wen Sun, Dal-Hee Bae, Jae-Hyeon Park, Sung-Ho Jo, Ho-Jung Ryu, Seoung-Yong Lee
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Patent number: 8236247Abstract: Material withdrawal apparatus, methods, and systems of regulating material inventory in one or more units are provided. A material withdrawal apparatus includes a heat exchanger and transport medium junction configured to provide transport medium to transport the withdrawn material from the unit to the heat exchanger. Another material withdrawal apparatus includes a heat exchanger and shock coolant junction configured to provide shock coolant to the material withdrawn from the unit. Another material withdrawal apparatus includes a heat exchanger, shock coolant junction, and transport medium junction. Another embodiment of a material withdrawal apparatus includes a vessel and shock coolant junction. Another material withdrawal apparatus includes a vessel and transport medium junction. The vessel includes a wall, liner with heat insulating refractory material, fill port, and a discharge port.Type: GrantFiled: December 23, 2009Date of Patent: August 7, 2012Assignee: Intercat Equipment, Inc.Inventors: Martin Evans, Ronald Butterfield
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Patent number: 8231834Abstract: In one exemplary embodiment, a unit for regenerating a hydrocarbon conversion catalyst for a hydrocarbon conversion zone can generally include passing the hydrocarbon conversion catalyst through, sequentially, a catalyst-disengaging zone having a first atmosphere, an adsorption zone having a second atmosphere, and a regeneration zone including a combustion zone; introducing an inert gas between the first atmosphere and the second atmosphere; and passing a flue gas from the combustion zone to the adsorption zone.Type: GrantFiled: May 18, 2010Date of Patent: July 31, 2012Assignee: UOP LLCInventors: David M. Fecteau, Leon Yuan
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Patent number: 8202412Abstract: The present invention is an improved regenerated catalyst bend assembly for a fluid catalytic cracking unit. In a preferred embodiment, the reduced elevation (“RE-bend” or “REL-bend”) regenerated catalyst return line assembly of the present invention has an outlet elevation that is lower than the inlet elevation of the RE-bend or REL-bend regenerated catalyst return line assembly, and a process for utilizing the assembly in a fluid catalytic cracking unit. The present invention is especially useful in the modification of existing fluid catalytic cracking units to lower the elevation of the outlet of the regenerated catalyst return line assembly, thereby providing needed space to increase the fluid catalytic cracking reactor riser length.Type: GrantFiled: July 17, 2007Date of Patent: June 19, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Brian A. Cunningham, Christopher G. Smalley, Rathna P. Davuluri, Dana W. Nouri
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Patent number: 8192614Abstract: Apparatus and method are provided for separating and stripping suspensions comprising catalyst particles transported in vapors from the fluid catalytic cracking riser/reactor. Particles are disentrained from vapor in a vortex zone 112 of the primary cyclonic separator 100. The disentrained particles enter a stripping zone 126, wherein the particles are contacted with a stripping gas 136 to recover vapors entrained and adsorbed onto the catalyst. The stripping gas 136 enters stripping zone 126 via perforations in the wall of the cyclone 100. The stripping gas 136 limits the residual catalytic conversion of hydrocarbon vapors and formation of delta-coke on the catalyst. Stripped catalyst is delivered from the cyclone stripping zone 126 via a dipleg 130 connected to a bottom of the cyclone 100, and enters an FCC stripping vessel. Solids-lean stripping gas and vapors from the catalyst particles are blended with the carrier fluid and discharged from the cyclone.Type: GrantFiled: September 9, 2004Date of Patent: June 5, 2012Assignee: Kellogg Brown & Root LLCInventors: Phillip Kent Niccum, Iwan Hirsan Chan, Richard Brian Miller, Steven Arthur Tragesser
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Patent number: 8173567Abstract: Disclosed is a catalyst distributor and process for spreading catalyst over a regenerator vessel. Nozzles disposed angular to a header of the distributor spread catalyst throughout a full cross section of the catalyst bed.Type: GrantFiled: December 16, 2008Date of Patent: May 8, 2012Assignee: UOP LLCInventors: Paolo Palmas, Lawrence A. Lacijan, Sujay R. Krishnamurthy, Mohammad-Reza Mostofi-Ashtiani, Paul S. Nishimura, Lisa M. Wolschlag