With Heat Exchange Means Affecting Reaction Chamber Or Reactants Located Therein Patents (Class 422/146)
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Patent number: 6773680Abstract: Five combustion exhaust gas treatment systems capable of removing dust and selenium (Se) in combustion exhaust gas and making harmless are proposed: (1) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se is transformed into insoluble compound, and Se is separated; (2) combustion exhaust gas is cooled to 350° C. or less, dust is separated, Se elution preventive agent is added, and dust is formed into scale; (3) dust in combustion exhaust gas is collected by dust collector, dust is formed into slurry by making use of part of circulation liquid in desulfurization apparatus, and tetravalent Se in dust slurry is transformed into insoluble compound, which is separated into solid and liquid; (4) dust is separated from combustion exhaust gas by dust collector, and it is heated to gasify Se, and is led into desulfurization apparatus, etc.Type: GrantFiled: November 14, 2002Date of Patent: August 10, 2004Assignee: Mitsubishi Jukogyo Kabushiki KaishaInventors: Taku Shimizu, Kazuaki Kimura, Kiyoshi Okazoe, Atsushi Tatani, Naohiko Ukawa, Masao Hino, Susumu Okino, Takashi Haruki, Toru Takashina, Eiji Ochi
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Publication number: 20040151654Abstract: The present invention relates to a method for continuous production of carbon nanotubes in a nano-agglomerate fluidized bed, which comprises the following steps: loading transition metal compounds on a support, obtaining supported nanosized metal catalysts by reducing or dissociating, catalytically decomposing a carbon-source gas, and growing carbon nanotubes on the catalyst support by chemical vapor deposition of carbon atoms. The carbon nanotubes are 4˜100 nm in diameter and 0.5˜1000 &mgr;m in length. The carbon nanotube agglomerates, ranged between 1˜1000 &mgr;m, are smoothly fluidized under 0.005 to 2 m/s superficial gas velocity and 20˜800 kg/m3 bed density in the fluidized-bed reactor. The apparatus is simple and easy to operate, has a high reaction rate, and it can be used to produce carbon nanotubes with high degree of crystallization, high purity, and high yield.Type: ApplicationFiled: November 24, 2003Publication date: August 5, 2004Inventors: Fei Wei, Yao Wang, Guohua Luo, Hao Yu, Zhifei Li, Weizhong Qian, Zhanwen Wang, Yong Jin
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Publication number: 20040151652Abstract: The present invention relates to a method for producing highly pure, granular silicon with a narrow particle-size distribution by decomposing silanes or halosilanes in a fluidised bed and epitaxially growing silicon on silicon seed particles, which method is characterised in that the gas containing silicon is supplied to the reaction chamber in an upward flow and the contents of the fluidised bed are separated in a continuous or discontinuous manner, whereby a particle stream from the fluidised bed is supplied to a separator mounted outside the fluidised bed, particles of the desired size are separated and undersized particles are returned to the fluidised bed. The invention also relates to a device and the use thereof for carrying out said method.Type: ApplicationFiled: March 31, 2004Publication date: August 5, 2004Inventors: Heiko Herold, H. Gunter Holdenried, Leslaw Mleczko, Matthias Pfaffelhuber, Karl-Theodor Konig
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Publication number: 20040109794Abstract: A heated catalyst support device for a reactor including a reactor vessel containing a bed of catalyst particles. The device includes a permeable support plate having a channel extending therethrough, where the support plate is adapted to contact the bed of catalyst particles. The device further includes a heating element extending through the channel in the support plate. A method for starting up a water gas shift reactor is provided that includes applying heat to the bed of catalyst particles using the heating element, measuring a temperature in the bed of catalyst particles. and starting up the water gas shift reactor when the temperature exceeds a saturation temperature for a desired operating pressure.Type: ApplicationFiled: August 11, 2003Publication date: June 10, 2004Applicant: H2GEN INNOVATIONS, INC.Inventors: Franklin D. Lomax, Christopher T. Gricius, John S. Lettow
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Publication number: 20040082824Abstract: A reactor apparatus and related method for controlling at least one process variable in a circulating fluid bed oxygenates to olefins reactor system comprising a riser are provided. The process variable is selected from at least one of (i) space velocity, (ii) average reaction temperature, (iii) conversion of reactant, and (iv) average coke level on catalyst. Typically, a corresponding set point for at least one process variable is selected from (1) reactant feed rate, (2) feed enthalpy, (3) reactor temperature-related function, e.g., mid-temperature or rate of temperature rise along a portion of the reactor, and (4) catalyst hold-up in the riser of the reactor. A corresponding manipulated variable is selected from (a) feed flow control valve(s), (b) feed preheat rate, (c) activity of the catalyst in the reactor, and (d) amount of catalyst in the reaction zone.Type: ApplicationFiled: October 25, 2002Publication date: April 29, 2004Inventor: James R. Lattner
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Patent number: 6709636Abstract: Combustibles such as wastes are gasified in a fluidized bed. A fluidized-bed furnace has a heat recovery region in addition to a combustion region. The temperature of a fluidized bed or the temperature of a freeboard is controlled so as to be kept at a predetermined value by adjusting the heat recovery rate in the heat recovery region.Type: GrantFiled: November 10, 1998Date of Patent: March 23, 2004Assignee: Ebara CorporationInventors: Takahiro Oshita, Tetsuhisa Hirose, Shuichi Nagato, Norihisa Miyoshi, Masamichi Nakashiba
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Patent number: 6698501Abstract: Heat exchangers utilizing flat surfaced passages to contact, contain and utilize fluidized small solid particles is provided. Top and bottom woven wire mesh or perforated sheet corrugated with rounded or flat-sided ridges are attached to respective top and bottom sides of said passage to increase its surface and to prevent said small solid particles from exiting said heat exchanger. A variety of shapes of the small solid particles are provided to further enhance the heat transfer rate. More energy efficient systems of all kinds will result from the use of these smaller heat exchangers.Type: GrantFiled: July 25, 2001Date of Patent: March 2, 2004Inventor: William H. Fleischman
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Patent number: 6699438Abstract: Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.Type: GrantFiled: June 8, 1999Date of Patent: March 2, 2004Assignee: Basell Polyolefine GmbHInventors: Benno Knauer, Peter Hennenberger, Klaus Hilligardt, Eckard Schauss, Horst Bullack
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Patent number: 6652736Abstract: The invention concerns a stripping method for extracting solid fluidized particles whereby the particles to be stripped are subjected to a first stripping in a first chamber (9), then at least a second stripping in a second chamber (10) wherein are provided solid/gas separating means allowing the gaseous fluids derived from the second stripping to directly pass through from the bottom to the top but preventing them from going up again into the first chamber (9). The invention also concerns a device for implementing said method.Type: GrantFiled: April 23, 2001Date of Patent: November 25, 2003Assignee: Total Raffinage Distribution S.A.Inventors: Mariano Del Pozo, Tanneguy Descazeaud, Daniel Barthod
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Patent number: 6649130Abstract: A hybrid reactor arrangement provides a reactive design that achieves higher acrylonitrile yield and lower catalyst circulating rate. The hybrid reactor design first passes a mixture of reactants and catalyst through a circulating bubbling bed reaction section. Heat exchange coils or other cooling medium in the bubbling bed reactor section maintain temperature in a range that will maximize the selectivity of reactants to the acrylonitrile product. The bubbling bed reactor section provides the initial conversion of the reactant. A circulating fluidized bed reaction zone finishes the conversion of reactants to a high yield under conditions that reduce the occurrence of secondary reactions that could otherwise produce unwanted by-products. The circulating fluidized bed reactor section maintains nearly plug flow conditions that allow continued conversion of unreacted feed components through primary reactions while limiting the time for secondary reactions to continue and diminish the final yield of products.Type: GrantFiled: August 10, 2000Date of Patent: November 18, 2003Assignee: UOP LLCInventors: Robert L. Zhou, W. Patrick Dennler, Anil R. Oroskar, Bipin V. Vora, Hayim Abrevaya, Laurence O. Stine
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Patent number: 6645437Abstract: The present invention relates to a device for injecting a hydrocarbon charge into a catalytic cracking reactor comprising in particular an envelope (1), a main (liquid) charge feed tube (3), and an inlet (2) for an auxiliary gaseous fluid. According to the invention, charge feed tube (3) is divided, inside envelope (1), into at least two secondary lines (4) designed to distribute said charge uniformly, each secondary line (4) terminates coaxially with the inlet of an element (7) of the venturi type, and the auxiliary gaseous fluid is mixed with the charge at the inlet of said venturi (7). The present invention applies in particular to catalytic cracking of heavy hydrocarbon charges.Type: GrantFiled: November 12, 1996Date of Patent: November 11, 2003Assignee: Institut Francais du PetroleInventors: Thierry Gauthier, RĂ©gis Bonifay
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Publication number: 20030206830Abstract: A multiple parallel processing assembly has been developed. The assembly has (1) a plurality of vessels for containing material, each vessel having an open end and a fluid permeable end (2) a plurality of bottoms, each bottom having an open end and a closed end with the plurality being supported by a single first support plurality of vessels positioned within the plurality of bottoms; (3) a plurality of tops supported by a single second support with the plurality of tops engaged with the plurality of bottoms to form a plurality of sealed independent chambers; and (4) a plurality of fluid conduits in fluid communication with the chambers.Type: ApplicationFiled: April 29, 2003Publication date: November 6, 2003Inventors: Duncan E. Akporiaye, Arne Karlsson, Ivar M. Dahl, Rune Wendelbo
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Patent number: 6619383Abstract: A vibrated bed of particles is created by vibrating a chamber. Particles are flowed to a ceiling of the chamber and cascade through a gas flowing though the chamber, exchanging heat with the gas. Particles spouted to the ceiling spread there and cascade. Larger particles, raised above the ceiling by a lateral vibrated elevator, cascade from channels beneath openings in the ceiling. A plenum and tubes release protective gas through the vibrated bed. Tubes embedded in the vibrated bed move fluid to exchange heat with the particles in the vibrated beds. Serialized chambers are reversed and particles flow from one chamber to another.Type: GrantFiled: July 25, 2001Date of Patent: September 16, 2003Inventor: Arthur M. Squires
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Patent number: 6613111Abstract: A process and method is provided for operating a small-scale high-throughput gasifier. As is known in the art, the exothermic combustion reactions can be separated from the endothermic gasification reactions. The exothermic combustion reactions can take place in or near the combustor while the endothermic gasification reactions take place in the gasifier. Heat from the exothermic zone is transferred to the endothermic reaction zone by circulation of an inert particulate solid such as sand. In order to increase efficiency by reducing heat loss from the gasifier, the gasifier is concentrically-disposed within the endothermic reaction zone of the combustor.Type: GrantFiled: November 16, 2001Date of Patent: September 2, 2003Assignee: Future Energy Resources CorporationInventor: Mark A. Paisley
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Patent number: 6605475Abstract: Apparatus and methods have been developed to deliver automatically a sample to a reaction vessel, an analytical device or any location where sample introduction or deposition is desired. A sample delivery system of the invention generally includes a housing defining a channel, e.g., a capillary, and a volume controller, which is a temperature control device, in thermal communication with the channel. The channel preferably is closed at one end, and contains an opening for introduction of a sample. The closed end of the channel is associated thermally with the temperature control device. The temperature control device heats and cools a thermally expandable fluid in the channel which controls movement of a sample into, within and out of the channel.Type: GrantFiled: April 16, 1999Date of Patent: August 12, 2003Assignee: Perspective Biosystems, Inc.Inventors: Todd A. Taylor, William W. Carson, Xian-Wei Yao
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Patent number: 6602476Abstract: Apparatus and process for heat exchange with fluid beds comprises heat-exchange tubes located longitudinally with respect to the axis of a fluidization zone with a rectangular pitch, one side of which having a length at least one and a half times the length of the other side and/or with a triangular pitch, having two sides each at least one and a half times the length of the shortest side reduces the impact of the heat-exchange tubes on the fluidization characteristics of the fluid bed. The invention is particularly suitable for oxidation reactions using molecular oxygen-containing gas in the presence of a fluid bed of fluidizable catalyst, such as (a) the acetoxylation of olefins, (b) the oxidation of ethylene to acetic acid and/or the oxidation of ethane to ethylene and/or acetic acid, (c) the ammoxidation of propylene and/or propane to acrylonitrile and (d) the oxidation of C4's to maleic anhydride.Type: GrantFiled: September 28, 2001Date of Patent: August 5, 2003Assignee: BP Chemicals LimitedInventors: Stanley John Becker, Timothy Crispin Bristow, Michele Fiorentino, David Newton, Bruce Leo Williams
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Patent number: 6576470Abstract: The invention pertains to a process for examining chemical reactions in the presence of potentially catalytical substances, wherein reactions are triggered in miniaturized reactors with volumes of 0.001 cm3 to 1 cm3 arranged parallel to each other, and the nature and amount of the reaction mixture are analyzed during the reaction time.Type: GrantFiled: November 22, 1999Date of Patent: June 10, 2003Assignee: Aventis Research & Technologies GmbH & Co KGInventors: Norbert Windhab, Christian Miculka, Hans-Ulrich Hoppe
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Publication number: 20030091486Abstract: Disclosed is an apparatus for the calcination of materials using low temperature heating and indirect heating for calcination. Also disclosed are a variety of processes for calcination of materials which have reduced emissions of pollutants compared to conventional processes.Type: ApplicationFiled: October 1, 2002Publication date: May 15, 2003Applicant: Environmental Projects, Inc.Inventors: Dale Lee Denham, Rudolph Pruszko, Wayne C. Hazen
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Patent number: 6548026Abstract: An apparatus and method for carrying out and monitoring the progress and properties of multiple reactions is disclosed. The method and apparatus are especially useful for synthesizing, screening, and characterizing combinatorial libraries, but also offer significant advantages over conventional experimental reactors as well. The apparatus generally includes multiple vessels for containing reaction mixtures, and systems for controlling the stirring rate and temperature of individual reaction mixtures or groups of reaction mixtures. In addition, the apparatus may include provisions for independently controlling pressure in each vessel. In situ monitoring of individual reaction mixtures provides feedback for process controllers, and also provides data for determining reaction rates, product yields, and various properties of the reaction products, including viscosity and molecular weight.Type: GrantFiled: October 22, 1998Date of Patent: April 15, 2003Assignee: Symyx Technologies, Inc.Inventors: G. Cameron Dales, Johannes A. M. van Beek, Damian A. Hajduk, Ralph B. Nielsen, Paul Mansky
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Publication number: 20030059352Abstract: A method for removing sulfur dioxide from flue gas and forming ammonium salts is described, along with a method for conversion of the ammonium salts into thiosulfate. Also described are an apparatus for absorbing sulfur dioxide from flue gas and an apparatus for converting ammonium salts into thiosulfate. The apparatus for absorbing sulfur dioxide from flue gas includes a multistage scrubber. The apparatus for converting ammonium salts into thiosulfate includes a fluidized bed reactor.Type: ApplicationFiled: August 7, 2001Publication date: March 27, 2003Inventors: Maurice Karras, Douglas Jackson
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Publication number: 20030019613Abstract: Heat exchangers utilizing flat surfaced passages to contact, contain and utilize fluidized small solid particles is provided. Top and bottom woven wire mesh or perforated sheet corrugated with rounded or flat-sided ridges are attached to respective top and bottom sides of said passage to increase its surface and to prevent said small solid particles from exiting said heat exchanger. A variety of shapes of the small solid particles are provided to further enhance the heat transfer rate. More energy efficient systems of all kinds will result from the use of these smaller heat exchangers.Type: ApplicationFiled: July 25, 2001Publication date: January 30, 2003Inventor: William H. Fleischman
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Publication number: 20020194782Abstract: An integrated biomass gasification and fuel cell system wherein the electrochemical reaction in the fuel cell is effected by providing the reactant gases from a gasifier. Fuel gas from the gasifier is directed to the anode of the fuel cell and at least a portion of the exhaust gas from the anode is directed to the combustor. The portion of the exhaust gas from the anode is then combusted to recover residual energy to increase the overall efficiency of integrated biomass gasification and fuel cell system. Also, the oxidant gas from the combustor may be directed to the cathode of the fuel cell.Type: ApplicationFiled: April 15, 2002Publication date: December 26, 2002Inventor: Mark A. Paisley
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Publication number: 20020192124Abstract: A depleted UF6 processing plant including a first fluidized bed reactor configured to react depleted UF6 with steam to produce UO2F2 and hydrogen fluoride, a second fluidized bed reactor connected to the first fluidized bed reactor and configured to react the UO2F2 with steam to produce U3O8, hydrogen fluoride and oxygen, a gas cooler configured to cool the hydrogen fluoride generated in the first and second fluidized bed reactors down to 150 to 300° C., and a fluorine fixing reactor containing granular calcium carbonate and connected to the gas cooler to receive the hydrogen fluoride cooled down to 150 to 300° C. from the gas cooler. The fluorine fixing reactor is configured to form granular calcium fluoride from the granular calcium carbonate and the hydrogen fluoride passing through the fluorine fixing reactor.Type: ApplicationFiled: July 19, 2002Publication date: December 19, 2002Applicant: MITSUBISHI MATERIALS CORPORATIONInventor: Hiromichi Koizumi
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Patent number: 6495707Abstract: A process and apparatus for the continuous production of organometallic compounds from a metal precursor and an alkylating agent. The reactants are delivered separately to a reaction centre (26) in a distillation column (2) wherein the reaction is maintained at a predetermined temperature to allow collection of the vaporised organometallic compound from the top of the column and removal of the waste products from the bottom of the column.Type: GrantFiled: June 18, 2001Date of Patent: December 17, 2002Assignee: Epichem LimitedInventors: Albert Barry Leese, Graham Williams, Lesley Margaret Smith, Simon Andrew Rushworth, Phillip Reeve Jacobs, Elizabeth Ann McKinnell, David Joseph Houlton
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Publication number: 20020182122Abstract: A CFB reactor or combustor having a selective catalytic reduction (SCR) system (150) employed downstream of the CFB reactor or combustor furnace (10) together with a dry scrubber system (220) to achieve enhanced NOx reduction.Type: ApplicationFiled: January 7, 2002Publication date: December 5, 2002Inventors: Donald L. Wietzke, Mikhail Maryamchik, Michael L. Silvey, Michael J. Szmania
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Patent number: 6482366Abstract: An apparatus (10) for calcining a material comprises a calcination vessel (10) which houses a heat exchanger (12). The heat exchanger (12) is arranged to transfer heat to the material from a liquid metal heat exchange fluid arranged to flow through the heat exchanger (12).Type: GrantFiled: March 25, 1999Date of Patent: November 19, 2002Assignees: Commonwealth Scientific and Industrial Research Organisation, Australian Magnesium Corporation PTY LTDInventors: Ivars Mirovics, Malcolm Timothy Frost, Raymond Louis Koenig, Peter James Tait
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Patent number: 6475445Abstract: CaS oxidation has CaS particles oxidized into CaSO4 completely as far as to the interior of the particle. The interior of an oxidation apparatus 1 is partially partitioned by a partition 22 to thereby form a first fluidized bed 20 on the inner side, a second fluidized bed 21 on the outer side and a space portion 23 thereabove. A heat exchanger 27 having a baffle plate is disposed on the inner side of the partition 22 and an in-bed heat exchanger 33 is disposed on the outer side of same. A desulfurizing product-containing fine powder 204 and coarse powder 205 and a mixture gas 206 of nitrogen, oxygen and steam are supplied into the second fluidized bed 21. Also, coal 200 and coal char 201 are supplied into the first fluidized bed 20 from below.Type: GrantFiled: September 13, 1999Date of Patent: November 5, 2002Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Yoshihiko Tsuchiyama, Yuichi Fujioka, Toshihiko Setoguchi, Katsuhiko Shinoda, Kenji Tagashira, Shigeyasu Ishigami, Yoshinori Kobayashi
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Publication number: 20020159922Abstract: A process and apparatus for atomizing a fluid is disclosed. The processes and apparatuses are useful for atomizing a feed oil for a fluid cat cracking (FCC) or other suitable process.Type: ApplicationFiled: May 24, 2002Publication date: October 31, 2002Inventors: Jackson I. Ito, Leonard Schoenman, Dean C. Draemel, Teh C. Ho, George A. Swan, Sandi Schoenman
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Publication number: 20020134019Abstract: An improved system and method is provided for operating a parallel entrainment fluidized bed gasifier system. A first aspect of the present invention relates to a method for reducing ash agglomeration in a parallel entrainment fluidized bed gasifier/combustor system by adding a quantity of MgO to the feedstock used in the gasifier/combustor system. A second aspect of the present invention relates to an apparatus and method for reducing erosion at piping bends in fluidized particulate piping systems which utilizes sand retention cavities positioned to receive and retain a portion of the fluidized particulate. A third aspect of the present invention relates to an apparatus and method for facilitating the flow of sand and char fragments from a first compartment to a second compartment while minimizing the flow of gases between the first and second compartments.Type: ApplicationFiled: December 20, 2001Publication date: September 26, 2002Inventor: Mark A. Paisley
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Publication number: 20020124996Abstract: A recuperative and conductive heat transfer system (10, 10′) that is operative to effect therewith the heating within the second portion (20, 20′) of the heat transfer system (10, 10′) of a “working fluid” flowing through the heat transfer surfaces (32, 32′) as a consequence of the transfer thereto by conduction of heat from a multiplicity of regenerative solids (24, 24′). The multiplicity of regenerative solids (24, 24′) derive their heat from a recuperation thereby within the first portion (12, 12′) of the heat transfer system (10, 10′) from either an internally generated or an externally generated source of heat (22, 22′).Type: ApplicationFiled: December 18, 2000Publication date: September 12, 2002Applicant: ALSTOM Power N.V.Inventors: Glen D. Jukkola, Paul R. Thibeault, Michael S. McCartney
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Patent number: 6416721Abstract: Fluidized bed reactors having centrally positioned heating means, as well as methods for their use, are provided. The subject reactors comprise a centrally positioned heating means (e.g. a susceptor rod) that, during operation, is at least partially immersed in a fluidized bed of particles. The subject reactors are further characterized in that, during use, a temperature gradient is produced within the reactor. The subject reactors find use in a variety of applications.Type: GrantFiled: October 1, 1999Date of Patent: July 9, 2002Assignee: SRI InternationalInventors: Angel Sanjurjo, Kai Hung Lau
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Publication number: 20020085969Abstract: An isothermal reactor for carrying out heterogeneous exothermic or endothermic reactions, comprises within a catalytic bed (3) housed in an appropriate outer shell (2), at least one tube (13) for the passage of a cooling or heating fluid which advantageously extends with a cone shaped helicoidal.Type: ApplicationFiled: December 13, 2001Publication date: July 4, 2002Applicant: METHANOL CASALE S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
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Patent number: 6413477Abstract: Process for gas-phase polymerization carried out in two interconnected polymerization zones, to which one or more &agr;-olefins CH2═CHR are fed in the presence of catalyst under reaction conditions and from which the polymer product is discharged. The process is characterized in that the growing polymer flows through a first polymerization zone under fast fluidization conditions, leaves said first zone and enters a second polymerization zone through which it flows in a densified form under the action of gravity, leaves said second zone and is reintroduced into the first polymerization zone, thus establishing a circulation of polymer around the two polymerization zones. The novel process allows olefins to be polymerized in the gas phase with high productivity per unit volume of the reactor without incurring the problems of the fluidized-bed technologies of the known state of the art.Type: GrantFiled: October 3, 1997Date of Patent: July 2, 2002Assignee: Basell Technology Company BVInventors: Gabriele Govoni, Roberto Rinaldi, Massimo Covezzi, Paolo Galli
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Patent number: 6395248Abstract: The disclosure describes a process for the production of polycrystalline silicon by a thermal decomposition or hydrogen reduction of a reaction gas consisting of silane gas, which comprises additionally introducing hydrogen chloride into the reaction gas and utilizing the reaction heat generated from the reaction between hydrogen chloride and silicon on the inside of the reactor as an additional heat source.Type: GrantFiled: September 10, 1999Date of Patent: May 28, 2002Assignee: Korea Research Institute of Chemical TechnologyInventor: Hee-Young Kim
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Patent number: 6389995Abstract: A method of combustion and a combustion plant in which absorbent is regenerated is described herein. During the combustion of a fuel in a combustion chamber enclosing a fluidized bed, a fuel and an absorbent are supplied to the fluidized bed. The combustion gases generated during the combustion are collected and purified in a separating member by separation of solid material from the combustion gases. The separated solid material is recirculated to the fluidized bed through a channel, and a gaseous medium is supplied in a controlled manner to the separated solid material present in the channel in order to displace the combustion gases and provide a chemical reaction.Type: GrantFiled: December 21, 1998Date of Patent: May 21, 2002Assignee: ABB Carbon ABInventors: Christopher Adams, Jim Anderson, Mats Andersson, Roine Brännström, John Weatherby
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Publication number: 20020034458Abstract: A process of producing hydrogen by autothermal steam reformation of a hydrocarbon comprises the steps of providing a reactor vessel having a fluidized catalyst bed, introducing steam and a gaseous hydrocarbon, introducing oxygen, maintaining the bed temperature below the spontaneous combustion temperature of the hydrocarbon in a fluidized bed, and withdrawing hydrogen by means of a perm selective membrane. An apparatus for producing hydrogen comprises a reactor vessel, steam and hydrocarbon inlets, an oxygen inlet, a fluidized bed of catalyst within the reactor vessel and a perm selective membrane for withdrawing hydrogen from the reactor.Type: ApplicationFiled: October 4, 2001Publication date: March 21, 2002Inventors: Surajit Roy, Barry Pruden, Alaa Adris, John Grace
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Publication number: 20020004612Abstract: Urea is prepared by reacting ammonia and carbon dioxide in an apparatus comprising a vertical condensation and synthesis column and a stripper, to provide a urea synthesis solution comprising urea, unreacted ammonia, unreacted carbon dioxide and water. The urea synthesis solution is transferred from the top of the vertical condensation and synthesis column to the top of a stripper. Carbon dioxide is introduced into the bottom of the stripper and contacted with the urea synthesis solution, thereby separating the unreacted ammonia and the unreacted carbon dioxide from the urea, and providing a mixed gas comprising ammonia, carbon dioxide and water. The mixed gas is transferred into the bottom of the vertical condensation and synthesis column, where it is reacted with liquid ammonia injected into the bottom and a middle of the vertical condensation and synthesis column. The mixed gas and liquid ammonia are condensed and react to form urea.Type: ApplicationFiled: July 5, 2001Publication date: January 10, 2002Applicant: TOYO ENGINEERING CORPORATIONInventors: Tadashi Fukunaka, Kenji Yoshimoto, Kenji Sakai, Yasuhiko Kojima
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Patent number: 6336500Abstract: A method of and apparatus for controlling heat transfer in a fluidized bed reactor having a heat transfer chamber (312) with a bed (314) of solid particles therein, means (320,322) for introducing fluidizing gas into the heat transfer chamber for fluidizing the bed of solid particles therein and heat transfer surfaces (316) in contact with the bed of solid particles in the heat transfer chamber. Heat is transferred to said heat transfer surfaces from the solid particles. The fluidization of the bed of solid particles is varied according to a periodical function, e.g. by control means (34) periodically varying the flow velocity of fluidizing gas being introduced into the heat transfer chamber. Thereby the instantaneous heat transfer, as well as, the effective heat transfer from solid particles to the heat transfer surfaces may be controlled.Type: GrantFiled: December 22, 1997Date of Patent: January 8, 2002Assignee: Foster Wheeler Energia OyInventor: Timo Hyppanen
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Publication number: 20010048901Abstract: A process chamber is placed in connection with a fluidized bed reactor for utilizing internal or external circulation of solid material or both in heat transfer purposes. Said process chamber is located inside the furnace of a circulating fluidized bed reactor adjacent to at least one of the furnace walls. The interior of said process chamber is provided with heat exchanger means for heat transfer from the solid material to heat transfer medium inside the heat exchanger means. The process chamber comprises a top closed barrier wall forming the roof of the process chamber, wherein the inlet of the solid material into the process chamber is arranged to the lower part of the wall of the process chamber and the outlet of the solid material out of the process chamber is arranged to the upper part of the wall of the process chamber.Type: ApplicationFiled: April 9, 2001Publication date: December 6, 2001Inventors: Michael G. Alliston, Ari Kokko, Tero Luomaharju, Timo Mero
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Patent number: 6322755Abstract: The present invention relates to a process for carrying out an exothermic reaction in the presence of a solid catalyst in a three-phase slurry reactor which includes a slurry zone and a freeboard zone. In the slurry zone, the catalyst is kept in suspension in a slurry liquid and in the freeboard zone, a liquid reflux is maintained to remove catalyst from the freeboard zone and, preferably, recycling the catalyst to the slurry zone. The present invention also relates to a three-phase slurry reactor adapted to the process.Type: GrantFiled: August 6, 1997Date of Patent: November 27, 2001Assignee: Shell Oil CompanyInventors: Arend Hoek, Geert Van Der Honing, Johannes Gerardus Laurijssen, Mathijs Maria Gerardus Senden
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Publication number: 20010043888Abstract: A process and apparatus for atomizing a fluid is disclosed. The processes and apparatuses are useful for atomizing a feed oil for a fluid cat cracking (FCC) or other suitable process.Type: ApplicationFiled: April 2, 2001Publication date: November 22, 2001Inventors: Jackson I. Ito, Leoonard Schoenman, Dean C. Draemel, Teh C. Ho, George A. Swan, Sandi Schoenman
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Patent number: 6306981Abstract: A process for the manufacture of olefin polymers in a continuous gas phase polymerization reaction wherein monomer, after passage through the fluidized bed, is cooled to a temperature below its dew point to produce a mixture of cold gas and liquid. All or nearly all of the cold gas is introduced into the bottom of the reactor to serve as the fluidizing gas stream for the fluidized bed. Cold liquid, separated from the mixture, is either injected directly into the peripheral region around the fluidized bed or onto the walls of the expanded section of the reactor to form a liquid film flowing down the wall of the reactor or alternatively, the cold liquid is warmed to form a heated fluid by passing in indirect heat exchange relation with the fluidized bed and is then injected directly into the peripheral region of the fluidized bed or onto the wall of the expanded section of the reactor to form a downward flowing stream of cold liquid.Type: GrantFiled: April 2, 1999Date of Patent: October 23, 2001Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Robert Cecil Brown, Norman Louis Balmer, Larry Lee Simpson
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Publication number: 20010025702Abstract: A method of and apparatus for controlling heat transfer in a fluidized bed reactor having a heat transfer chamber (312) with a bed (314) of solid particles therein, means (320,322) for introducing fluidizing gas into the heat transfer chamber for fluidizing the bed of solid particles therein and heat transfer surfaces (316) in contact with the bed of solid particles in the heat transfer chamber. Heat is transferred to said heat transfer surfaces from the solid particles. The fluidization of the bed of solid particles is varied according to a periodical function, e.g. by control means (34) periodically varying the flow velocity of fluidizing gas being introduced into the heat transfer chamber. Thereby the instantaneous heat transfer, as well as, the effective heat transfer from solid particles to the heat transfer surfaces may be controlled.Type: ApplicationFiled: December 22, 1997Publication date: October 4, 2001Inventor: TIMO HYPPANEN
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Patent number: 6263958Abstract: Heat exchangers that utilize flat surfaced passages to contact, contain and utilize fluidized small solid particles. A variety of flat surfaced small solid particles with high heat transfer surfaces are provided to further enhance the heat transfer rate. Astonishingly high heat transfer coefficients have been reported for surfaces immersed in fluidized beds. More energy efficient systems of all kinds will result from the use of these smaller heat exchangers.Type: GrantFiled: February 23, 1998Date of Patent: July 24, 2001Inventor: William H. Fleishman
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Patent number: 6248297Abstract: An FCC apparatus places a quench chamber above a reactor vessel and a hot stripper below a reactor vessel to provide a progressively decreasing temperature profile up the structure of the FCC arrangement and equipment for sequential reaction control. A riser contains the primary catalytic reactions of the hydrocarbon vapor and delivers the reacted vapors to the reactor structure. Starting from the bottom of the structure the hot stripper has the highest temperature and desorbs or displaces hydrocarbons from the catalyst to terminate long residence time catalytic reactions. Above the hot stripper bulk separation equipment divides the main vapor and catalyst stream to limit residence time of major catalytic reactions. At a yet higher elevation and lower internal temperature quench equipment arrests thermal reactions of the vapor stream. This structure arrangement permits reliable control of reaction time to obtain desired products and enhances mechanical reliability of the structure.Type: GrantFiled: January 6, 1995Date of Patent: June 19, 2001Assignee: UOP LLCInventors: Laurence O. Stine, Charles L. Hemler, Carlos A. Cabrera, David A. Lomas
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Patent number: 6245300Abstract: A horizontal cyclone separator in which a furnace section and a vortex chamber communicating with the furnace section and having an inlet which extends a fraction of the length of the furnace section receives a mixture of the gaseous products of combustion and solids entrained by the gases. A coaxially disposed tube extends partially into the chamber to allow the separated gases to exit the separator. A ring-shaped solids deflector is disposed on the vertical wall opposite the coaxially disposed tube to prevent solids from bouncing off the rear wall towards the center of the separator and into the path of the separated gas stream. The separated solids fall into an outlet trough formed in a lower portion of the furnace section for returning the solids to the furnace section.Type: GrantFiled: August 11, 1994Date of Patent: June 12, 2001Assignee: Foster Wheeler Energy CorporationInventor: Juan Antonio Garcia-Mallol
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Patent number: 6235247Abstract: Systems and apparatus for catalytically oxidizing organic matter, particularly the incomplete combustion products of carbon-containing fuels such as fossil fuels. The systems and apparatus utilize catalytically reactive particles that are suspended by moving air within a reaction chamber and maintained at a temperature sufficient to cause the suspended media particles, typically silica sand, silica gel, or alumina, to become catalytically reactive in the presence of moisture. Typically, the reaction chamber is maintained at a temperature in a range from about 100° C. to about 500° C. Moisture may be provided by the waste exhaust, although additional moisture may be introduced into the reaction chamber in order to maintain reactivity of the catalytically reactive particles. The systems and apparatus can be adapted to be used in combination with diesel engines or other internal combustion engines and industrial burners.Type: GrantFiled: May 7, 1999Date of Patent: May 22, 2001Inventors: Thomas C. Maganas, Alan L. Harrington
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Patent number: 6218484Abstract: A continuous process for the manufacture of olefin polymers in a continuous gas phase polymerization reaction wherein monomer, after passage through the fluidized bed, is cooled to a temperature below its dew point to produce a mixture of cold gas and liquid. All or part of the cold gas is introduced into the bottom of the reactor to serve as the fluidizing gas stream for the fluidized bed. Cold liquid separated from the mixture is warmed to form a heated fluid by passing in indirect heat exchange relation with the fluidized bed and the heated fluid is then injected directly into the bed; combined with the fluidizing gas stream; sprayed on top of the bed or combined with gaseous monomer removed from the fluidized bed for cooling.Type: GrantFiled: January 29, 1999Date of Patent: April 17, 2001Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventors: Robert Cecil Brown, Norman Louis Balmer
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Patent number: 6206088Abstract: A heat exchanger system includes a first heat exchanger followed by a second heat exchanger disposed in a dense fluidized bed, the second heat exchanger being made up of a plurality of nests of tubes disposed along the path of the particles in suspension in the dense fluidized bed. The second heat exchanger is provided with at least two feeds situated on either side of its center, each of the feeds receives a distinct mixture of the input fluid and of the output fluid of the first heat exchanger, so that the temperature of the fluid fed into each of the nests is an increasing function of the distance between it and the inlet via which the particles are fed into the dense fluidized bed.Type: GrantFiled: August 17, 1998Date of Patent: March 27, 2001Assignee: GEC Alsthom Stein IndustrieInventors: Jean-Claude Semedard, Pierre Gauville, Christian Enault
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Patent number: RE37300Abstract: A pressurized internal circulating fluidized-bed boiler is incorporated in a combined-cycle electric generating system in which a fuel such as coal, petro coke or the like is combusted in a pressurized fluidized bed and an exhaust gas produced by the combusted fuel is introduced into a gas turbine. The pressurized internal circulating fluidized-bed boiler includes a pressure vessel, a combustor disposed in the pressure vessel and a main fluidized bed combustion chamber provided with an air diffusion device. A thermal energy recovery chamber is partitioned from the main combustion chamber by an inclined partition wall. A fluidized medium flows into and out of the main combustion chamber and the thermal energy recovery chamber. A free board is provided integrally above the main combustion chamber and the thermal energy recovery chamber so that combustion gas from the main combustion chamber and the thermal energy recovery chamber is mixed in the free board.Type: GrantFiled: May 6, 1998Date of Patent: July 31, 2001Assignee: Ebara CorporationInventors: Shuichi Nagato, Masayuki Horio, Takahiro Oshita, Norihisa Miyoshi, Seiichiro Toyoda, Akira Shimokura, Tomoyuki Shinano, Shugo Hosoda