Including Solid, Extended Surface, Fluid Contact Reaction Means; E.g., Inert Raschig Rings, Particulate Absorbent, Particulate Or Monolithic Catalyst, Etc. Patents (Class 422/177)
  • Patent number: 8574335
    Abstract: A holding sealing material includes inorganic fibers, a mat shape, a first end face and a second end face and a penetration portion. The mat shape has a width direction, a length direction and a thickness direction. The first end face and the second end face are each provided approximately in parallel with the width direction. The penetration portion penetrates the holding sealing material in the thickness direction.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: November 5, 2013
    Assignee: Ibiden Co., Ltd.
    Inventors: Hisashi Ando, Takahiko Okabe
  • Patent number: 8568673
    Abstract: A gas analysis device according to the present invention includes a flue-gas extraction pipe for extracting flue gas from a flue gas duct to which flue gas including both of NH4Cl and SO3 is fed, a collector that is provided in the flue-gas extraction pipe, for removing soot dust contained in the extracted flue gas, a roll filter that is provided in the flue-gas extraction pipe, for depositing both of NH4Cl and SO3 contained in the flue gas, and a measurement device for measuring both of NH4Cl and SO3 contained in the flue gas by irradiating a sample including both of NH4Cl and SO3 deposited by the roll filter with X-rays and detecting fluorescent X-rays generated from the sample.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: October 29, 2013
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Seiji Kagawa, Masaru Chiyomaru, Nobuyuki Ukai, Takuya Okamoto, Moritoshi Murakami
  • Patent number: 8568661
    Abstract: An exhaust gas treatment device (1) for an exhaust system of an internal combustion engine, especially of a motor vehicle, has a multipart housing (2), which contains an oxidation-type catalytic converter unit (5) and, downstream therefrom, a particle filter unit (6) one after another in an axial direction extending in parallel to a longitudinal direction (3) of the housing. The housing (2) contains an inlet housing part (7), which has an exhaust gas inlet (8) and the oxidation-type catalytic converter unit (5), and an outlet housing part (9), which has an exhaust gas outlet (10) and into which the particle filter unit (6) axially protrudes.
    Type: Grant
    Filed: June 9, 2010
    Date of Patent: October 29, 2013
    Assignee: Eberspächer Exhaust Technology GmbH & Co. KG
    Inventors: Marcus Werni, Michael Bay, Wolfgang Datz
  • Patent number: 8568675
    Abstract: Provided are catalyst composites that can be used in methods for treating exhaust gas from internal combustion engines, including diesel and gasoline engines, systems including such catalyst composites and methods of using the catalyst composites to treat internal combustion engine exhaust. The catalyst composites may provide diesel oxidation catalysts and three-way catalysts. A catalyst composite is provided which a catalytic material on a carrier, the catalytic material including a palladium component dispersed on a first support comprising at least 60% by weight of a zirconia component, and one or more rare earth oxides selected from the group consisting of lanthana, neodymia, praseodymia, yttria, the first support optionally containing no more than 15% by weight ceria, and being free of alumina. Layered catalyst composites having one or more washcoats on the carrier are also provided.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: October 29, 2013
    Assignee: BASF Corporation
    Inventors: Michel Deeba, Tian Luo, Josephine Ramos
  • Patent number: 8562929
    Abstract: A method for producing ammonia suitable for use as a reductant in a combustion exhaust gas treatment system is provided that includes the electrolytic hydrolysis of urea under mild conditions. The ammonia generator, which includes an electrolysis apparatus including an electrolytic flow cell, an alkaline electrolyte composition, and a recirculation system, may be operatively coupled to an exhaust gas treatment system to provide an apparatus for reducing nitrogen oxides (NOx) and/or particulate in exhaust gases.
    Type: Grant
    Filed: August 23, 2011
    Date of Patent: October 22, 2013
    Assignee: Ohio University
    Inventor: Gerardine G. Botte
  • Patent number: 8557010
    Abstract: Fused particles containing, by weight percent: more than 15% but less than 55% of Al2O3; more than 20% but less than 45% of TiO2; more than 3% but less than 30% of SiO2; less than 20%, in total, of at least one oxide selected from the group consisting of ZrO2, Ce2O3, and HfO2; less than 1% of MgO; and more than 1% but less than 15%, in total, of at least one selected from the group consisting of CaO, Na2O, K2O, SrO, B2O3, and BaO. Also, a ceramic product or material obtained by sintering the fused particles.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: October 15, 2013
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventor: Stephane Raffy
  • Patent number: 8557011
    Abstract: The invention relates to a honeycomb structure including a set of adjacent channels, each channel being in communication with upstream and downstream surfaces, respectively, via upstream and downstream openings, such that said set of channels forms cross-sectional upstream and downstream patterns on said upstream and downstream surfaces, respectively. According to the invention, at least one of the upstream and downstream surfaces has an error-proofing mark extending over fewer than 50 channels and making it impossible to completely stack any one of the upstream and downstream patterns onto the other, the outer perimeter of the upstream and/or downstream pattern being symmetrical or having an asymmetry that extends over fewer than 10 channels. The invention can be used in the filtration of particles contained it the exhaust gases of internal combustion engines, in particular diesel engines.
    Type: Grant
    Filed: July 9, 2010
    Date of Patent: October 15, 2013
    Assignee: General Electric Company
    Inventor: Bernard Bouteiller
  • Patent number: 8557012
    Abstract: Fused particles having the following chemical composition, as a percentage by weight on the basis of the oxides: more than 15% but less than 55% of Al2O3; more than 25% but less than 60% of TiO2; less than 20%, in total, of at least one oxide of an element M1, chosen from MgO and CoO; more than 0.7% but less than 20%, in total, of at least one oxide of an element M2, chosen from the group formed by Fe2O3, Cr2O3, MnO2, La2O3, Y2O3 and Ga2O3; less than 20%, in total, of at least one oxide of an element M3, chosen from the group formed by ZrO2, Ce2O3 and HfO2; and less than 30% of SiO2. Ceramic product or material obtained by sintering said particles.
    Type: Grant
    Filed: July 27, 2010
    Date of Patent: October 15, 2013
    Assignee: Saint-Gobain Centre de Recherches Et d'Etudes Europeen
    Inventor: Stephane Raffy
  • Patent number: 8557009
    Abstract: A method of manufacturing a ceramic diesel particle filter (DPF) and a DPF manufactured by the method, the DPF having a ceramic filter body (1) including gas channels (18, 18?) with planar and porous filter segments (3), which are provided for the exhaust gas stream (2) to flow through them transversely to the face of the filter segments (3). The filter body (1) is formed by sintering at least one ceramic-impregnated fiber web (4) in a firing step under heat such that fibers (5) of the fiber material are burned off and the ceramic material (6) is sintered together to form the porous filter segment (3) between its two surfaces (7, 8). At least one fiber web (4) is corrugated to form the gas channels (18, 18?) and rolled up to form the filter body (1), and the cross section of at least a portion of the gas channels (18, 18?) changes from an inlet end (33) to a discharge end (34).
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: October 15, 2013
    Assignee: Mann+Hummel GmbH
    Inventors: Karin Gerlach, Stefan Tudyka, Jochen Linhart, Andreas Franz
  • Patent number: 8557204
    Abstract: Disclosed herein is a layered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides being separated in a front and rear portion is disclosed. Provided is a catalytic composite material of a single front and two rear layers in conjunction with a substrate, where each of the layers includes a support, all layers comprise a platinum group metal component, and the rear bottom layer is substantially free of an oxygen storage component (OSC).
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: October 15, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: John G. Nunan, Raoul Klingmann, Ryan Andersen, Davion Clark, David H. Moser
  • Patent number: 8557203
    Abstract: A device is described which provides thermally durable NO2 generation in conjunction with efficient heat-up performance for filter regeneration, and low temperature HC (hydrocarbon) and CO activity. Importantly, it provides both functions while minimizing PGM (platinum group metals) utilization and its associated impact on catalyst cost.
    Type: Grant
    Filed: November 3, 2009
    Date of Patent: October 15, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Owen Herman Bailey, Matthew Hedgecock, Frank-Walter Schuetze, Anke Woerz
  • Patent number: 8557207
    Abstract: A method and apparatus for reducing the quantity of pollutant in waste gases, in particular for reducing the quantity of nitrogen oxide in the flue gas of a coal-fired power plant is provided. The process includes the steps of, introducing the waste gas into a catalyzer, to which a quantity of catalytic reduction agent is supplied, measuring the quantity of pollutant at the outlet of the catalyzer, and setting the quantity of pollutant to a setpoint value smaller than a limit value to be complied with, by varying the quantity of reduction agent supplied, wherein the setting of the quantity of pollutant is dynamically regulated as a function of mean values over time, for example half-hour or quarter-hour mean values, of the measured quantity of pollutant determined regularly beforehand.
    Type: Grant
    Filed: August 16, 2012
    Date of Patent: October 15, 2013
    Assignees: Siemens Aktiengesellschaft, STEAG GmbH
    Inventors: Jürgen Endemann, Jörg Gadinger
  • Patent number: 8549747
    Abstract: A method for producing a tubular catalytic converter, which includes a monolith wrapped in a mat and is disposed in a housing, includes forming a stepped longitudinal fold on a longitudinal side of a housing blank, wherein the longitudinal side on both sides of the fold to be formed is clamped by electrodes of opposite polarity across the fold. Electrode pairs on one side of the fold to be formed are then offset with respect to electrodes on the other side of the fold and the electrodes of opposite polarity move closer together, while a current is flowing between the electrodes of opposite polarity, heating the material in the fold. Opposing longitudinal sides of the tubular housing are then materially joined along the stepped longitudinal fold with the overlap to produce the housing for the tubular catalytic converter.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: October 8, 2013
    Assignee: Benteler Automobiltechnik GmbH
    Inventor: Rafael Garcia Gomez
  • Patent number: 8551910
    Abstract: The invention relates to a porous structure comprising a ceramic material comprising mainly or consisting of an oxide material of the pseudobrookite type comprising titanium, aluminum, magnesium and zirconium in proportions such that the phase of the pseudobrookite type substantially satisfies the formula: (Al2TiO5)x(MgTi2O5)y(MgTiZrO5)z. This material satisfies the following composition, in mol % on the basis of just the oxides Al2O3, TiO2, MgO and ZrO2: 90<2a+3m<110; 100+a<3t<210?a; and a+t+m+zr=100, in which: a is the molar content of Al2O3; t is the molar content of TiO2; m is the molar content of MgO; and zr is the molar content of ZrO2.
    Type: Grant
    Filed: July 2, 2009
    Date of Patent: October 8, 2013
    Assignee: Saint-Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Stephane Raffy, Philippe Auroy
  • Patent number: 8551411
    Abstract: An apparatus (10) comprising a lean burn internal combustion engine (12) and an exhaust system (14) comprising at least one catalytic aftertreatment component (18, 20, 22), wherein the at least one catalytic aftertreatment component comprises a catalyst composition comprising an alloy consisting of palladium and gold on a metal oxide support.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: October 8, 2013
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Janet Mary Fisher, John Benjamin Goodwin, Peter Christopher Hinde, Sylvie Cécile Laroze, Agnes Suganya Raj, Raj Rao Rajaram, Emma Ruth Schofield
  • Patent number: 8540793
    Abstract: An exhaust processing device includes a main body tube portion and a closing tube portion. The main body tube portion includes an opening in an axial end thereof, houses a main body exhaust path in an inside thereof, which allows an exhaust gas to pass therethrough. The closing tube portion includes a plate portion and a tubular portion. The plate portion covers the opening of the axial end of the main body tube portion. The tubular portion radially outwardly protrudes from an outer peripheral surface of the main body tube portion, and is integrated with the plate portion. The tubular portion houses an exhaust path in an inside thereof, which communicates with the main body exhaust path. The tubular portion of the closing tube portion includes a first split half portion integrally molded with the plate portion, and a second split half portion joined to the first split half portion.
    Type: Grant
    Filed: May 8, 2009
    Date of Patent: September 24, 2013
    Assignee: Komatsu Ltd.
    Inventors: Yuuki Kasaoka, Tatsushi Itou, Shouhei Nagasaka, Hirofumi Takanuki
  • Patent number: 8539760
    Abstract: An exhaust aftertreatment system that receives an exhaust flow from a lean-burn engine and a method for treating the exhaust flow are described. The exhaust aftertreatment system may include a three-way-catalyst, an oxidation catalyst, and a NH3—SCR catalyst. The three-way-catalyst passively generates NH3 from native NOX contained in the exhaust flow when an A/F mixture supplied to the engine is cycled from lean to rich. The generated NH3 is then stored in the NH3—SCR catalyst to facilitate NOX reduction when the A/F mixture supplied to the engine is cycled back to lean. The oxidation catalyst is located upstream of the NH3—SCR catalyst and operates to lower the NO to NO2 molar ratio of the NOX fed to the NH3—SCR catalyst. The oxidation catalyst comprises perovskite oxide particles.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: September 24, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Wei Li, Chang H Kim, Kevin L. Perry, Paul M. Najt, Kushal Narayanaswamy
  • Patent number: 8535405
    Abstract: The honeycomb structure is provided with a honeycomb structural section, a pair of lateral electrodes on the side face of the honeycomb structural section, and at least one intermediate layer between the honeycomb structural section and the lateral electrodes. The honeycomb structural section has silicon carbide particles having an average particle diameter of 3 to 40 ?m and silicon, and the ratio (Si/SiC) of silicon (Si) to silicon carbide (SiC) is 10/90 to 40/60. The lateral electrodes have an average particle diameter of the silicon carbide particles of 10 to 70 ?m and a Si/SiC ratio of 20/80 to 50/50. The intermediate layer has an average particle diameter of silicon carbide particles and Si/SiC between those of the honeycomb structural section and those of the lateral electrodes. The electric resistance between the lateral electrodes of the honeycomb structural section is 2 to 100?.
    Type: Grant
    Filed: August 22, 2012
    Date of Patent: September 17, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Yasushi Noguchi, Atsushi Kaneda, Takayuki Inoue
  • Patent number: 8535612
    Abstract: Disclosed is a diesel particle filter with a ceramic filter body and a method for producing the filter body. The ceramic filter body includes gas channels provided in a filter section with planar and porous filter walls. The filter walls provide throughflow of the exhaust gas flow perpendicular to the surfaces thereof. The filter body includes at least one catalytic section for catalytic purification of the exhaust gas flow. The filter body together with the filter section and the at least one ceramic section are made in one-piece from at least one ceramic impregnated fiber web. Gas channels are formed by sintering the fiber web at a temperature such that fibers of the fiber material are burned away and the ceramic material is monolithically sinter-bonded in one-piece with the at least one catalytic section and the filter section to produce the filter body.
    Type: Grant
    Filed: March 3, 2008
    Date of Patent: September 17, 2013
    Assignee: Mann + Hummel GmbH
    Inventors: Michael Micke, Sabine Otterbach
  • Patent number: 8529652
    Abstract: A soot particle filter according to the invention can be particularly used in motor vehicles or heating systems using liquid and solid fuels. The device is particularly characterized by a time controlled variable regeneration of the soot particle storage (10) and soot particle burn-off. The device is in particular catalytic. The device comprises at least one filter housing (2) having an input (3), an output (4) and a filter element (6). A soot particle storage chamber (10) is further provided in the filter housing (2) and comprises an access (19) that is particularly angled and tapered toward the inside. The inner chamber of the soot particle storage (10) is lined with precious metal discs (11). Said discs have holes, are angled and/or corrugated. The precious metal discs and/or a precious metal mesh (11) are at least partially catalytically coated. An ignition device (12) is arranged in the filter housing (12), for example a glow plug and/or a glow filament.
    Type: Grant
    Filed: November 19, 2008
    Date of Patent: September 10, 2013
    Inventor: Roswitha Burkhardt
  • Publication number: 20130230441
    Abstract: The selective reduction-type catalyst effectively purifies nitrogen oxides contained in exhaust gas from a lean-burn engine such as a boiler, a gas turbine or a lean-burn engine, a diesel engine, even under high SV, as well as having small pressure loss, by supplying by spraying urea water or ammonia water, as a reducing component, to the selective reduction-type catalyst; and an exhaust gas purification apparatus along with an exhaust gas purification method using the same. The selective reduction-type catalyst for selectively reducing a nitrogen oxide by adding urea or ammonia as a reducing agent of the nitrogen oxide to exhaust gas discharged from a lean-burn engine, characterized by coating a catalyst layer including zeolite containing at least an iron element, and a composite oxide of silica, tungsten oxide, ceria and zirconia, as denitration components, at the surface of a monolithic structure-type substrate.
    Type: Application
    Filed: September 21, 2011
    Publication date: September 5, 2013
    Applicant: N.E. CHEMCAT CORPORATION
    Inventors: Takashi Hihara, Tomoaki Ito, Yasushi Tanaka, Makoto Nagata
  • Patent number: 8524159
    Abstract: A reactor with minimal dead volume especially suited to reverse-flow applications comprises: a) a reactor body; b) a first head engaged with said reactor body; c) a first conduit extending from outside said head to at least partially through said head; and d) a first valve in flow communication with said first conduit controlling fluid flow along a flow path extending from the first valve and through the reactor body. The reactor is especially suited for use in a process for rapid stream-switching of at least two streams in a reverse-flow reactor.
    Type: Grant
    Filed: May 6, 2011
    Date of Patent: September 3, 2013
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventors: Frank Hershkowitz, Richard John Basile, Jeffrey William Frederick, John William Fulton, Paul F. Keusenkothen, Bryan A. Patel, Andrew Richard Szafran
  • Publication number: 20130224082
    Abstract: A catalyst composition includes a heterobimetallic zeolite characterized by a chabazite structure loaded with copper ions and at least one trivalent metal ion other than Al3+. The catalyst composition decreases NOx emissions in diesel exhaust and is suitable for operation in a catalytic converter.
    Type: Application
    Filed: February 24, 2012
    Publication date: August 29, 2013
    Applicant: UT-BATTELLE, LLC
    Inventors: Chaitanya K. Narula, Xiaofan Yang
  • Publication number: 20130224091
    Abstract: A batch composition for making a highly porous honeycomb ceramic catalytic filter article, including base inorganic components including a mixture of a nano-zeolite powder, and an inorganic filler, in amounts defined herein; and super additives including: a mixture of at least two pore formers; a binder; and a metal salt, in amounts defined herein. Also disclosed are extruded catalyst filter articles and methods for making the articles.
    Type: Application
    Filed: April 16, 2013
    Publication date: August 29, 2013
    Applicant: Corning Incorporated
    Inventor: Corning Incorporated
  • Patent number: 8518143
    Abstract: The invention relates to a method for producing a ceramic filter element in an exhaust gas filter for an internal combustion engine, in particular a diesel particulate filter, wherein a base paper carrier web is soaked with a ceramic slip and then burnt out. The base paper carrier web uses a thickness and/or structure that varies over the width and/or length of the base paper carrier web.
    Type: Grant
    Filed: August 10, 2011
    Date of Patent: August 27, 2013
    Assignee: Mann+Hummel GmbH
    Inventors: Jochen Linhart, Sabine Otterbach, Kathrin Lichtenwalter
  • Patent number: 8518333
    Abstract: A honeycomb structured body of the present invention comprises a plurality of cells placed in parallel with one another in a longitudinal direction with a cell wall therebetween, wherein an oxide catalyst is supported on at least one portion of the cell wall, and the honeycomb structured body has an apparent density of about 0.7 g/cm3 or less.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: August 27, 2013
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Tomokazu Oya
  • Patent number: 8513155
    Abstract: An exhaust aftertreatment system for a lean-burn engine may include a lean NOX trap that comprises a catalyst material. The catalyst material may remove NOX gases from the engine-out exhaust emitted from the lean-burn engine. The catalyst material may include a NOX oxidation catalyst that comprises a perovskite compound.
    Type: Grant
    Filed: February 26, 2010
    Date of Patent: August 20, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Wei Li, Chang H Kim, Gongshin Qi
  • Patent number: 8512433
    Abstract: Disclosed are ceramic honeycomb articles which possess a unique microstructure characterized by porosity between 40% and 70%, and the presence of coarse pores exhibiting a depth equivalent to the thickness of the cell wall and a dimensional width, in the plane of the cell wall, exhibiting a diameter that is at least as large as the thickness of the cell wall. The articles exhibits reduced filtration efficiency coupled with low pressure drop across the filter, and a reduced regeneration need. Such ceramic articles are particularly well suited for filtration applications, such as off-road and retro-fit diesel exhaust filters or DPFs. Also disclosed is a method for manufacturing the ceramic article wherein the pore former is capable of forming coarse pores.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: August 20, 2013
    Assignee: Corning Incorporated
    Inventors: Douglas Munroe Beall, Achim Karl-Erich Heibel, Pushkar Tandon, David John Thompson
  • Patent number: 8506892
    Abstract: The present invention relates to an exhaust gas purifying device for a diesel engine, which purifies efficiently Nitrogen Oxides (NOx) and Particulate Matters (PM) contained in exhaust gases of the diesel engine, particularly provides an exhaust gas purifying device disposed in an exhaust passage of a diesel engine, wherein a catalyst part for reducing Nitrogen Oxides and a filter part for removing Particulate Matter are provided sequentially from an upstream for a flow of the exhaust gas and a diesel fuel injector is mounted at a front of the Nitrogen Oxide reduction catalyst part.
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: August 13, 2013
    Assignee: SK Innovation Co., Ltd.
    Inventors: Yong-Woo Kim, Do-Woan Kim, Joon-Seok Min, Seong-Ho Lee, Hong-Seok Jung, Yun-Guen Cho, Hyo-Jun Jeon, Nicholas Kim, Gi-Ho Goh, Sang Hoon Park
  • Publication number: 20130202495
    Abstract: A hydrocarbon trap is provided for reducing cold-start hydrocarbon emissions. The trap contains an acidic absorption material for improving absorption of low molecular weight hydrocarbons. The acidic absorption materials may be used either alone or in combination with zeolites which are integrated into and/or supported on a monolithic substrate. The hydrocarbon trap may be positioned in the exhaust gas passage of a vehicle such that hydrocarbons are adsorbed on the trap and stored until the engine and exhaust reach a sufficient temperature for desorption.
    Type: Application
    Filed: February 7, 2012
    Publication date: August 8, 2013
    Inventors: Jason Aaron Lupescu, Hungwen Jen
  • Publication number: 20130202508
    Abstract: A nickel-based catalyst is provided for reducing carbon monoxide, hydrocarbon emissions, and nitrogen oxides from vehicle exhausts. The catalyst is impregnated directly onto a carrier which is non-reactive with nickel. The nickel is contained on said carrier at a loading of between about 2 to about 20 wt %. When used in a vehicle exhaust gas treatment system, the catalyst provides improved efficiency in reducing CO, HC, and NOx emissions over the use of conventional three-way-catalysts.
    Type: Application
    Filed: February 7, 2012
    Publication date: August 8, 2013
    Inventors: Jeffrey Scott Hepburn, Hungwen Jen, Eva Thanasiu
  • Patent number: 8500840
    Abstract: A cordierite-based ceramic honeycomb filter comprising a honeycomb structure having a large number of flow paths partitioned by porous cell walls, and plugs alternately formed in said flow paths on the exhaust-gas-inlet side or the exhaust-gas-outlet side for permitting an exhaust gas to pass through said porous cell walls to remove particulate matter from the exhaust gas, said porous cell walls having porosity of 45-58%, an average pore size of 15-30 ?m, the volume of pores having pore sizes exceeding 50 ?m being more than 10% and 25% or less of the total pore volume, the volume of pores having pore sizes of 100 ?m or more being 1-8% of the total pore volume, the volume of pores having pore sizes of less than 10 ?m being 3-10% of the total pore volume, and said pores having a pore size distribution deviation ? [=log(D20)?log(D80)] of 0.
    Type: Grant
    Filed: October 14, 2008
    Date of Patent: August 6, 2013
    Assignee: Hitachi Metals, Ltd.
    Inventors: Shunji Okazaki, Toshitaka Ishizawa
  • Patent number: 8501131
    Abstract: An apparatus to introduce a reagent to reduce nitrogen oxides in flue gas including: nozzles mounted to a passage for the flue gas, wherein the nozzles are mounted downstream of a SNCR system and upstream of a SCR system, wherein the nozzles are mounted on one or more walls of the passage and are configured to inject a pressurized fluid into the flue gas; a source of the pressurized fluid which is in fluid communication with the nozzles such that the pressurized fluid flows to the nozzles; a source of a NOx reducing reagent and a mixing device which mixes the reagent with the pressurized fluid such that the pressurized fluid flowing to the nozzles includes the reagent.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: August 6, 2013
    Assignee: General Electric Company
    Inventors: David Kelly Moyeda, Wei Zhou, Antonio Marquez, Xu Guang, Santosh Nareddy
  • Patent number: 8501105
    Abstract: A reaction-based process developed for the selective removal of CO2 from a multicomponent gas mixture to provide a gaseous stream depleted in CO2 compared to the inlet CO2 concentration. The proposed process effects the separation of CO2 from a mixture of gases by its reaction with metal oxides. The Calcium based Reaction Separation for CO2 (CaRS-CO2) process consists of contacting CO2 laden gas with CaO in a reactor such that CaO captures CO2 by the formation of CaCO3. CaCO3 is regenerated by calcination leading to the formation of fresh CaO sorbent and the evolution of a concentrated stream of CO2. The “regenerated” CaO is then recycled for the further capture of CO2. This carbonation-calcination cycle forms the basis of the CaRS-CO2 process. This process also may use a mesoporous CaCO3 structure that attains >90% conversion over multiple carbonation and calcination cycles.
    Type: Grant
    Filed: July 20, 2012
    Date of Patent: August 6, 2013
    Assignee: The Ohio State University
    Inventors: Liang-Shih Fan, Himanshu Gupta, Mahesh V. Iyer
  • Patent number: 8501135
    Abstract: A method of reducing sulfur compounds from an incoming gas stream, comprising flowing the gas stream over a hydrolysis catalyst to convert COS and CS2 to H2S and reduce SO2 to elemental sulfur to form an effluent stream; providing an acidic gas removal unit comprising an absorbent; flowing said effluent stream over said absorbent to produce a stream free of acidic gases; applying an acidic-gas desorption mode to said acidic-gas rich absorbent to produce an acidic gas stream; introducing oxygen to said acidic gas-rich stream; providing a direct oxidation vessel containing catalyst suitable for catalyzing the oxidation of the H2S to sulfur wherein the temperature of the vessel is at or above the sulfur dew point at the reaction pressure; and flowing said acidic gas-rich stream over said catalyst to produce a processed stream having a reduced level of sulfur compounds.
    Type: Grant
    Filed: July 10, 2012
    Date of Patent: August 6, 2013
    Assignee: Archon Technologies Ltd.
    Inventors: Alan Ayasse, Ahmed M. Shahin, Conrad Ayasse
  • Patent number: 8501126
    Abstract: An method and apparatus is disclosed that causes a chemical reaction to reduce emissions. The method includes a mandrel that is plated, bonded, or by other means affixed with a catalyst. The mandrel moves to control a rate of catalyst available to react via a controlled change in contact surface area per unit volume flow to remove or reduce effluent matter.
    Type: Grant
    Filed: May 22, 2012
    Date of Patent: August 6, 2013
    Assignee: Proxxent Technologies, LLC
    Inventors: Nathan Hastings, Stephan E Hastings, Frank T. Klisura
  • Patent number: 8496724
    Abstract: A plugged honeycomb structure including particulate matter (PM) trapping layers disposed on the surfaces of the partition walls extending up to inflow side end faces of the plugging portions that plug outflow cells so that adjacent PM-trapping layers with the partition walls and the plugging portion therebetween are disposed so as to continue on the inflow side end faces of the plugging portions. The PM-trapping layers are extended up to the inflow side end faces of the plugging portions to form protruding portions having a protrusion height corresponding with 0.1 to 2 times the length of a side of the outflow cells from the inflow side end faces of the plugging portions toward the outside of the cell extension direction.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: July 30, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Shingo Tokuda, Yoshimasa Kondo
  • Patent number: 8496895
    Abstract: Disclosed are an exhaust gas treating apparatus and a treating method for a carbon dioxide capture process, in which harmful substances remaining in the exhaust gas discharged from the conventional flue-gas desulfurization process are additionally removed for efficient performance of the carbon dioxide capture process. According to the exhaust gas treating apparatus for a carbon dioxide capture process, it has the effects of minimizing the installation space of desulfurization equipment and reducing the process cost. In addition, by keeping the contaminants contained in the gas introduced in the carbon dioxide capture equipment below a proper level, absorption performance can be improved as degradation of the absorbent used in the carbon dioxide capture process is prevented. After all, it has an advantage of preventing the pollution by the exhaust gas discharged into the atmosphere.
    Type: Grant
    Filed: January 27, 2012
    Date of Patent: July 30, 2013
    Assignee: Korea Institute of Energy Research
    Inventors: Hyung-Keun Lee, Won-Kil Choi, Hang-Dae Jo, Chang-Keun Yi, Sung-Ho Jo, Young-Cheol Park
  • Patent number: 8491846
    Abstract: A honeycomb body is formed of smooth and structured metallic foils. The smooth foils have different average roughnesses or different oxide layer thicknesses than the textured foils. A method for producing the honeycomb body and a motor vehicle having the honeycomb body, are also provided.
    Type: Grant
    Filed: November 8, 2010
    Date of Patent: July 23, 2013
    Assignee: EMITEC Gesellschaft fuer Emissionstechnologie mbH
    Inventor: Rolf Brück
  • Patent number: 8491845
    Abstract: According to one embodiment, described herein is an exhaust gas after-treatment system that is coupleable in exhaust gas stream receiving communication with an internal combustion engine. The exhaust gas after-treatment system includes a low temperature SCR catalyst configured to reduce NOx in exhaust gas having a temperature below a temperature threshold. The system also includes a normal-to-high temperature SCR catalyst configured to reduce NOx in exhaust gas having a temperature above the temperature threshold.
    Type: Grant
    Filed: September 10, 2010
    Date of Patent: July 23, 2013
    Assignee: Cummins IP, Inc.
    Inventors: Padmanabha Reddy Ettireddy, Matthew Henrichsen
  • Patent number: 8491847
    Abstract: An apparatus for purifying exhaust gas exhausted from an internal combustion engine, using two or more honeycomb structure-type catalysts (X) and (Y). The catalyst (X) contains the support material of the zirconium oxide as a main component which loads a Rh component on the support material of zirconium oxide and substantially does not contain a cerium component, and a cerium-containing oxide which substantially does not load the Rh component, and the catalyst (X) does not substantially contain Pt component and Pd component. The catalyst (Y) contains the support material of the cerium-zirconium composite oxide as a main component which loads a Rh component on the support material of cerium-zirconium composite oxide and which contains cerium of 1 to 20% by weight, in an oxide equivalent, and zirconium of 99 to 80% by weight, in an oxide equivalent, and the catalyst (Y) does not substantially contain Pt component and Pd component.
    Type: Grant
    Filed: April 23, 2009
    Date of Patent: July 23, 2013
    Assignee: N.E. Chemcat Corporation
    Inventors: Katsuaki Kato, Yoshiro Hirasawa, Takashi Yamada
  • Patent number: 8486341
    Abstract: Systems and methods for treating exhaust gases are described. The described systems and/or methods for treating exhaust gases could be used with any power plant, engine, hydrocarbon burning system, other NOx producing system, or combinations thereof. A method (400) for treating exhaust gases is provided. The method (400) may include converting (402) ammonia (44) and NOx to nitrogen and water using an ammonia-SCR catalyst (30) after converting (404) ammonia to NOx using an ammonia-to-NOx catalyst (20) located upstream of at least a portion of the ammonia-SCR catalyst (30). The described systems and/or methods create NOx so excess ammonia added to the exhaust stream may be used to convert NOx to nitrogen and water.
    Type: Grant
    Filed: December 9, 2008
    Date of Patent: July 16, 2013
    Assignee: Caterpillar Inc.
    Inventors: James Joshua Driscoll, Michael A. Flinn
  • Patent number: 8486173
    Abstract: A collapsible underhood container for mounting under a vehicle hood with a portion of the collapsible underhood container extending into an area between the hood and an underhood safety plane when in an extended position, the container comprising: a lower housing, an upper container portion and a locking feature. The lower housing is fixed relative to the vehicle and has a bottom and side walls. The upper container portion has walls adjacent to and telescopically slidable on the side walls of the lower housing and a top, with the top located in the area between the hood and the safety plane. The locking feature maintains the upper container relative to the lower housing when in the extended position and releases the upper container portion to slide downward relative to the lower housing to a collapsed position when the hood contacts the upper container.
    Type: Grant
    Filed: June 10, 2010
    Date of Patent: July 16, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Philip J. Fikany, Michael A. Vieau, II
  • Patent number: 8480985
    Abstract: A method and device for the catalytic decomposition of laughing gas in a laughing-gas-bearing gas. The method includes diluting the laughing-gas-bearing gas with a diluting gas, while forming a laughing-gas-bearing charge gas. The laughing-gas bearing charge gas is passed through a heat-exchange step where heat exchange occurs with an exhaust. A heating step occurs for occasional heating of the laughing-gas-bearing charge gas in a fixed-bed reactor for catalytic decomposition of the laughing gas. In some embodiments the diluting gas is dried, and at least a part of the exhaust from the catalytic decomposition of the laughing gas is mixed with the laughing-gas-bearing charge gas upstream of the catalytic decomposition of the laughing gas.
    Type: Grant
    Filed: January 5, 2010
    Date of Patent: July 9, 2013
    Assignee: Linde Aktiengesellschaft
    Inventors: Ulrike Wenning, Hans-Jörg Zander, Anton Wellenhofer, Karl-Heinz Hofmann, Wibke Korn, Franz Beran, Nicole Schödel, Wolfgang Schmehl
  • Patent number: 8480984
    Abstract: A selective catalytic reduction system and method for reducing nitrogen oxide (NOx) emissions comprising a boiler producing flue gas emissions, a particulate control device receiving flue gas emissions from the boiler, a selective catalytic reduction unit (SCR) receiving flue gas emissions from the particulate control device and reducing nitrogen oxide (NOx) emissions, and a heat exchanger located downstream of the selective catalytic reduction unit (SCR) for removing heat from the flue gas for preheating at least one of boiler feed water and combustion air for the boiler.
    Type: Grant
    Filed: June 19, 2012
    Date of Patent: July 9, 2013
    Assignee: 2E Environmental, LLC
    Inventor: Robert Ellery
  • Patent number: 8480781
    Abstract: A ceramic honeycomb structure comprised of at least two separate smaller ceramic honeycombs that have been adhered together by a cement comprised of inorganic fibers and a binding phase wherein the smaller honey-combs and fibers are bonded together by the binding phase which is comprised of an silicate, aluminate or alumino-silicate. The fibers have a multi-modal size distribution in which some fibers have lengths of up to 1000 micons and other fibers have lengths in excess of 1 mm. The cement composition may be made in the absence of other inorganic and organic additives while achieving a shear thinning cement, for example, by mixing oppositely charged inorganic binders in water together so as to make a useful cement composition for applying to the smaller honeycombs to be cemented.
    Type: Grant
    Filed: June 24, 2010
    Date of Patent: July 9, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: Jun Cai, Aleksander J. Pyzik, Michael T. Malanga, Kwanho Yang
  • Patent number: 8480780
    Abstract: A honeycomb filter includes a ceramic laminated body including columnar porous ceramic members and an adhesive layer combining the columnar porous ceramic members with one another. The columnar porous ceramic members each have a partition wall and through holes, the through holes extend in parallel with one another in a length direction of the columnar porous ceramic members, the partition wall separates the through holes and filters particulates in an exhaust gas, and the adhesive layer includes an inorganic binder, an inorganic fiber, inorganic particles and an inorganic balloon.
    Type: Grant
    Filed: January 27, 2012
    Date of Patent: July 9, 2013
    Assignee: Ibiden Co., Ltd.
    Inventors: Atsushi Kudo, Masafumi Kunieda
  • Patent number: 8479493
    Abstract: The oxidation of carbon monoxide (CO) and hydrocarbons (HC) in an oxygen-containing gas stream, such as the exhaust stream from a diesel engine, or other lean-burn engine, may be catalyzed using a combination of mixed oxide particles of cerium, zirconium and copper, and discrete particles of an alumina-supported platinum group metal catalyst. The catalyzed oxidation of CO and HC by this combination of oxidation catalyst particles is effective at temperatures below 300° C.
    Type: Grant
    Filed: May 19, 2011
    Date of Patent: July 9, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Chang H Kim, Iljeong Heo, Se H. Oh, Wei Li, Michelle H Schmid
  • Patent number: 8475751
    Abstract: A device, method of making, and method of using, illustratively wherein a container includes an inlet and an outlet; a catalytic converter intermediate in a path between the inlet and the outlet; at least one surface arranged to ensure at least a majority of gas received from the inlet traverses a first portion of the path from the inlet to the catalytic converter and communicates heat from the catalytic converter to the container; and an optical means arranged to transport visible light, emitted from the catalytic converter during reduction of the smog-generating chemical in the gas, to a location outside the container to indicate whether the catalytic converter is functioning properly.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: July 2, 2013
    Assignee: Green Light Industries, Inc.
    Inventors: Gerald Peter Jackson, Jason Ryan Babcock, Joseph Matthew Zlotnicki
  • Patent number: 8475574
    Abstract: An exhaust treatment system comprises a particulate matter filter, a first heater element, and a second heater element. The particulate matter (PM) filter filters PM from exhaust gas and includes N zones. Each of the N zones includes an inlet area that receives a portion of the exhaust gas. N is an integer greater than one. The first heater element includes a contact area that heats exhaust gas input to an inlet area of a first one of the N zones. The second heater element includes a second contact area that heats exhaust gas input to an inlet area of a second one of the N zones. A ratio of the contact area of the first heater element to the inlet area of the first zone is greater than a ratio of the contact area of the second heater element to the inlet area of the second zone.
    Type: Grant
    Filed: August 5, 2009
    Date of Patent: July 2, 2013
    Inventors: Eugene V. Gonze, Michael J. Paratore, Jr., Garima Bhatia