Including Solid, Extended Surface, Fluid Contact Reaction Means; E.g., Inert Raschig Rings, Particulate Absorbent, Particulate Or Monolithic Catalyst, Etc. Patents (Class 422/177)
  • Patent number: 8871165
    Abstract: A method for combustion of a fuel and treatment of the resulting flue gas includes: combusting a fuel to produce a hot flue gas stream containing at least carbon dioxide (CO2) and sulfur dioxide (SO2), bringing the flue gas stream into contact with solid calcium oxide (CaO) in a carbonation reactor operating at a temperature at which CO2 in the flue gas reacts with CaO to form solid calcium carbonate (CaCO3), heating CaCO3 in a calcination reactor operating at a temperature at which CaCO3 is converted to CaO and CO2, and recirculating CaO formed in the calcination reactor back to the carbonation reactor. Heating can be at least partially effected by indirect heat exchange with hot flue gas from the combustion. Flue gas used for the indirect heat exchange can be subsequently subjected to dry desulfurization before it is brought into contact with CaO in the carbonation reactor.
    Type: Grant
    Filed: October 16, 2013
    Date of Patent: October 28, 2014
    Assignee: ALSTOM Technology Ltd
    Inventors: Olaf Stallmann, Gerhard Heinz, Peter Ulrich Koss
  • Patent number: 8870987
    Abstract: An object of the present invention is to detect any breakdown or failure of a particulate filter more appropriately. A failure detecting apparatus for detecting failure of a particulate filter according to the present invention comprises an acquiring section which acquires an amount of PM contained in an exhaust gas allowed to outflow from the particulate filter; a regeneration process executing section which executes a filter regeneration process for oxidizing and removing PM deposited in the particulate filter; and a failure judging section which judges that the particulate filter is in the failure state if a decreased amount of the amount of PM contained in the exhaust gas acquired by the acquiring section, during a predetermined period of time as started from a point in time at which the execution of the filter regeneration process performed by the regeneration process executing section is completed, is not equal to or larger than a predetermined reference amount.
    Type: Grant
    Filed: November 12, 2010
    Date of Patent: October 28, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Kazuya Takaoka, Daisuke Shibata
  • Patent number: 8865614
    Abstract: A process for producing a ringlike oxidic shaped body by mechanically compacting a pulverulent aggregate introduced into the fill chamber of a die, wherein the outer face of the resulting compact corresponds to that of a frustocone.
    Type: Grant
    Filed: February 28, 2013
    Date of Patent: October 21, 2014
    Assignee: BASF SE
    Inventors: Knut Eger, Jens Uwe Faust, Holger Borchert, Ralf Streibert, Klaus Joachim Mueller-Engel, Andreas Raichle
  • Patent number: 8864875
    Abstract: An exhaust gas treatment system for an internal combustion engine is provided comprising an exhaust gas conduit, a particulate filter (“PF”) device, a hydrocarbon source and an electronic control module including operative logic which when implemented. The PF has a filter structure for removal of particulates in the exhaust gas and is selectively regenerated based on an amount of particulates trapped within the filter structure of the PF device. The control module is in communication with the internal combustion engine and the hydrocarbon source, and receives a regeneration signal indicating the amount of particulates trapped within the filter structure of the PF device. The electronic control module includes control logic for monitoring the internal combustion engine prior to a regeneration event. The electronic control module includes control logic for determining a plurality operating parameters of the internal combustion engine based on the monitoring.
    Type: Grant
    Filed: November 13, 2012
    Date of Patent: October 21, 2014
    Assignee: GM Global Technology Operations LLC
    Inventors: Eugene V. Gonze, Michael J. Paratore, Jr., Julian C. Tan
  • Patent number: 8865084
    Abstract: A pass-through catalytic substrate can comprise a plurality of porous ceramic substrate walls defining flow channels extending between an inlet end and an outlet end of the catalytic substrate. The pass-through catalytic substrate can include a plurality of porous ceramic beveled corner portions positioned at intersecting corners of the substrate walls within the flow channels. In one example, the porous ceramic beveled corner portions each include a heat capacity less than about 1.38 J/cm3/K. In another example, a catalytic washcoat layer can be provided for coating the porous ceramic substrate walls and the porous ceramic beveled corner portions. Methods for producing a pass-through catalytic substrate also provide porous ceramic beveled corner portions.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: October 21, 2014
    Assignee: Corning Incorporated
    Inventors: Keith Norman Bubb, Cameron Wayne Tanner
  • Patent number: 8858904
    Abstract: Described is a catalyzed soot filter wherein the inlet coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the outlet coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the outlet coating is lower than the Pt concentration in the inlet coating and wherein the weight ratio of Pt:Pd in the outlet coating is in the range of from 0:1 to 2:1; and wherein the inlet coating and the outlet coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.5 to 1.5, calculated as ratio of the loading of the inlet coating (in g/inch3 (g/(2.54 cm)3)):loading of the outlet coating (in g/inch3 (g/(2.54 cm)3)). Systems include such catalyzed soot filters, methods of diesel engine exhaust gas treatment and methods of manufacturing catalyzed soot filters are also described.
    Type: Grant
    Filed: February 22, 2011
    Date of Patent: October 14, 2014
    Assignee: BASF Corporation
    Inventors: Alfred Helmut Punke, Gerd Grubert, Yuejin Li, Ruediger Wolff, Stanley Roth, Torsten Müller-Stach, Attilio Siani, Kenneth Voss, Torsten Neubauer
  • Patent number: 8858907
    Abstract: Methods and systems for selective catalytic reduction of NOx with an ammonia reductant and a zeolite catalyst loaded with at least two metals selected from the group of tungsten, cobalt, and vanadium. An exhaust stream including NOx and a reductant stream including ammonia are provided to a catalytic reactor having the metal loaded zeolite catalyst at suitable operating temperatures for NOx reduction of at least 90%.
    Type: Grant
    Filed: July 10, 2013
    Date of Patent: October 14, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ajit B. Dandekar, Richard F. Socha, Richard L. Eckes, S. Beau Waldrup, Jason M. McMullan
  • Patent number: 8857159
    Abstract: An exhaust system includes main line that runs through a three way converter (TWC) and then a lean NOx trap (LNT). The exhaust system further includes a bypass line configured to bypass the TWC. The LNT includes catalyst that is non-uniformly distributed along the longitudinal axis. The catalyst is distributed such that storage sites are weighted toward the upstream end of the LNT and oxidation and reduction sites are weighted toward the downstream end of the LNT.
    Type: Grant
    Filed: November 25, 2009
    Date of Patent: October 14, 2014
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Atul Pant, Karthik Ramanathan
  • Patent number: 8858891
    Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
    Type: Grant
    Filed: October 4, 2013
    Date of Patent: October 14, 2014
    Assignee: BASF Corporation
    Inventors: Chung-Zong Wan, Xiaolai Zheng, Susanne Stiebels, Claudia Wendt, Torsten Neubauer, R. Samuel Boorse
  • Publication number: 20140301931
    Abstract: Disclosed here are material formulations of use in the conversion of exhaust gases, where the formulations may include Iron (Fe), Cobalt (Co), Manganese (Mn), Cerium (Ce), Lanthanum and combinations thereof.
    Type: Application
    Filed: April 4, 2013
    Publication date: October 9, 2014
    Applicant: CDTi
    Inventor: Zahra Nazarpoor
  • Publication number: 20140301909
    Abstract: Compositions and methods for the preparation of ZPGM oxidation catalytic converters are disclosed. ZPGM catalyst systems may be employed within catalytic converters under lean hydrocarbon, air to fuel ratio condition to oxidize toxic gases, such as carbon monoxide and other hydrocarbons that may be included in exhaust gas. ZPGM oxidation catalyst systems are completely free of PGM catalyst and may include: a substrate, a washcoat, and an overcoat. Washcoat may include silver as ZPGM catalyst, and carrier material oxides. Similarly, overcoat may include at least one ZPGM catalyst, carrier material oxides and OSMs. Overcoat of the disclosed ZPGM catalyst system may include copper and cerium as ZPGM catalysts. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM catalyst systems.
    Type: Application
    Filed: April 4, 2013
    Publication date: October 9, 2014
    Applicant: CDTi
    Inventor: Zahra Nazarpoor
  • Patent number: 8852311
    Abstract: The present invention aims to provide a honeycomb structure capable of preventing a plugging failure and forming cracks by heat shock which are caused by a cell having a small cross-section.
    Type: Grant
    Filed: January 18, 2011
    Date of Patent: October 7, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Teruo Komori, Hajime Yoshino
  • Patent number: 8852519
    Abstract: Disclosed is an exhaust gas purifying catalyst in which grain growth of a noble metal particle supported on a support is suppressed. Also, disclosed is a production process of an exhaust gas purifying catalyst, by which the above exhaust gas purifying catalyst can be produced. The exhaust gas purifying catalyst comprises a crystalline metal oxide support and a noble metal particle supported on the support, wherein the noble metal particle is epitaxially grown on the support, and wherein the noble metal particle is dispersed and supported on the outer and inner surfaces of the support. The process for producing an exhaust gas purifying catalyst comprises masking, in a solution, at least a part of the surface of a crystalline metal oxide support by a masking agent, introducing the support into a noble metal-containing solution containing a noble metal, and drying and firing the support and the noble metal-containing solution to support the noble metal on the support.
    Type: Grant
    Filed: July 9, 2010
    Date of Patent: October 7, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Masao Watanabe, Oji Kuno, Nobusuke Kabashima, Keisuke Kishita, Noboru Otake, Hiromochi Tanaka
  • Patent number: 8852518
    Abstract: The present invention is to provide a catalyst for removing nitrogen oxides which is capable of keeping sufficient denitrification performance, i.e., a high removal rate of nitrogen oxides in exhaust gas having a high NO2 content especially under conditions where the ratio of NO2/NO in exhaust gas is 1 or higher, a catalyst molded product therefor, and an exhaust gas treating method. The catalyst is designed for removing nitrogen oxides, which is used to denitrify exhaust gas containing nitrogen oxides having a high NO2 content, which comprises: at least one kind of oxide selected from the group consisting of copper oxides, chromium oxides, and iron oxides as a component for reducing NO2 to NO; and which further comprises: at least one kind of titanium oxide; at least one kind of tungsten oxide; and at least one kind of vanadium oxide as components for reducing NO to N2.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: October 7, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Shigeru Nojima, Kozo Iida, Yoshiaki Obayashi, Masashi Kiyosawa, Masanori Demoto
  • Patent number: 8845973
    Abstract: A particle filter includes channels that are formed by porous walls and run between a first end face and a second end face of the particle filter. The first end face has a hydrolysis coating outside the channels. A device includes at least one exhaust gas line through which an exhaust gas can flow in a flow direction, a nozzle for introducing a reducing agent containing or forming ammonia, and the aforementioned particle filter. The first end face of the particle filter is oriented towards the nozzle. A motor vehicle having the particle filter or the device, is also provided.
    Type: Grant
    Filed: November 9, 2010
    Date of Patent: September 30, 2014
    Assignee: EMITEC Gesellschaft fuer Emissionstechnologie mbH
    Inventor: Rolf Brück
  • Patent number: 8845783
    Abstract: The present invention is intended to detect a failure of a PM filter with a higher degree of accuracy. The present invention is provided with: a PM trapping efficiency calculation part to calculate a PM trapping efficiency (which is a proportion of an amount of particulate matter trapped with respect to an amount of inflow particulate matter) based on an amount of inflow particulate matter obtained by an inflow particulate matter obtaining part, and an amount of outflow particulate matter detected by a PM sensor; and a failure detection part to make a determination that a failure has occurred in the PM filter, in cases where there has appeared a tendency for the PM trapping efficiency to decrease during a period of time until the execution of the following filter regeneration processing is started after the completion of execution of the filter regeneration processing.
    Type: Grant
    Filed: March 26, 2010
    Date of Patent: September 30, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Kazuya Takaoka, Daisuke Shibata, Hiroshi Sawada, Toru Kidokoro
  • Patent number: 8845974
    Abstract: Catalyzed soot filters comprising a wall flow monolith having porous walls, a first washcoat permeating the porous walls and a second washcoat on the porous walls are disclosed. Methods of manufacturing catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: September 30, 2014
    Assignee: BASF Corporation
    Inventors: Yuejin Li, Stanley A. Roth, Alfred H. Punke, Gary A. Gramiccioni
  • Patent number: 8845798
    Abstract: A particulate matter detecting apparatus for an internal combustion engine that can estimate a discharge amount of the particulate matter accurately. The particulate matter detecting apparatus for an internal combustion engine, comprises: a sensor disposed at an exhaust passage of the internal combustion engine, the sensor including a pair of electrodes for detecting particulate matter in an exhaust gas; means for estimating a discharge amount of the particulate matter based on an output of the sensor, and means for acquiring a predetermined parameter that serves as an index for a rate with which the particulate matter in the exhaust gas is deposited on the sensor. The discharge amount estimating means corrects an estimated value of the discharge amount of the particulate matter based on the parameter acquired by the parameter acquiring means.
    Type: Grant
    Filed: December 7, 2010
    Date of Patent: September 30, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Hiroki Nishijima
  • Publication number: 20140271425
    Abstract: Oxidation ZPGM catalyst systems and three way ZPGM catalyst systems are disclosed. ZPGM catalyst systems may oxidize toxic gases, such as carbon monoxide and hydrocarbons, optionally some ZPGM catalyst systems may as well reduce nitrogen oxides that may be included in exhaust gases. ZPGM catalyst systems may include: a substrate, a washcoat, and an overcoat. The washcoat may include at least one ZPGM catalyst and carrier material oxides. Similarly, overcoat may include at least one ZPGM catalyst, carrier material oxides and OSMs. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM catalyst systems.
    Type: Application
    Filed: March 22, 2013
    Publication date: September 18, 2014
    Applicant: CDTI
    Inventor: Zahra Nazarpoor
  • Publication number: 20140271392
    Abstract: Disclosed here are material formulations of use in the conversion of exhaust gases, where the formulations may include Copper (Cu), Cerium (Ce), Tin (Sn), Niobium (Nb), Zirconium (Zr), Calcium (Ca) and combinations thereof.
    Type: Application
    Filed: March 22, 2013
    Publication date: September 18, 2014
    Applicant: CDTI
    Inventor: Zahra Nazarpoor
  • Publication number: 20140271393
    Abstract: Disclosed here are methods of preparing zero platinum group metal catalysts systems with different support oxide material. A ZPGM catalyst system may include a substrate and a washcoat and an impregnation layer, wherein said impregnation layer may include the ZPGM pervoskite catalyst and the washcoat layer may include the support oxides material. Suitable support oxides material may include ZrO2, ZrO2 doped with lanthanide group metals, Nb2O5, Nb2O5—ZrO2, Al2O3 and Al2O3 doped with lanthanide group metals, TiO2 and doped TiO2 or mixtures thereof.
    Type: Application
    Filed: June 6, 2013
    Publication date: September 18, 2014
    Applicant: CDTI
    Inventor: Zahra Nazarpoor
  • Publication number: 20140271391
    Abstract: Compositions and methods for the preparation of ZPGM TWC systems are disclosed. ZPGM TWC systems may be employed within catalytic converters to oxidize toxic gases, such as carbon monoxide and other hydrocarbons, as well as to reduce nitrogen oxides. ZPGM TWC systems are completely free of PGM catalyst and may include: a substrate, a washcoat, and an overcoat. Washcoat may include manganese as ZPGM catalyst, and carrier material oxides. Similarly, overcoat may include at least one ZPGM catalyst, carrier material oxides and OSMs. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM TWC systems. ZPGM TWC systems may include high surface area, low conversion temperature catalysts that may exhibit high efficiency in the conversion of exhaust gases.
    Type: Application
    Filed: March 22, 2013
    Publication date: September 18, 2014
    Applicant: CDTI
    Inventor: Zahra Nazarpoor
  • Publication number: 20140271430
    Abstract: A method for oxidizing a carbonaceous material, the method comprising contacting the carbonaceous material with an effective amount of a catalytic material of formula AxMyWOz, and initiating the oxidization of the carbonaceous material at a first temperature lower than a second temperature at which the carbonaceous material is initiated to oxidize without a catalyst, wherein A is at least one of cesium and potassium, M is different from A and is at least one of cesium, potassium, magnesium, calcium, strontium, barium, iron, cobalt, nickel, ruthenium, rhodium, palladium, silver, osmium, iridium, platinum, gold, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, and bismuth, 0?x?1, 0?y?1, 2.2?z?3, when x=0, y>0, and when y=0, x>0.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 18, 2014
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Chuan LIN, Youhao YANG, QIJIA FU, XUBIN GAO, Xiao ZHANG
  • Publication number: 20140271390
    Abstract: Described are ZPGM catalyst systems which are free of any platinum group metals for reducing emissions of carbon monoxide, nitrogen oxides, and hydrocarbons in exhaust streams. ZPGM catalyst systems may include a substrate, a washcoat, and an overcoat. Both manganese and copper may be provided as catalysts, with copper in the overcoat and manganese preferably in the washcoat. The manganese can also be provided in the overcoat, but when in the overcoat should be stabilized for greatest effectiveness. A carrier material oxide may be included in both washcoat and overcoat. It has been discovered that the ZPGM catalyst systems are effective even without OSM in washcoat and the ZPGM catalysts within washcoat and overcoat may be best prepared by co-milling an aqueous slurry that includes manganese with alumina for the washcoat and copper and cerium salts with alumina and an OSM, for overcoat prior to overcoating and heat treating.
    Type: Application
    Filed: March 22, 2013
    Publication date: September 18, 2014
    Applicant: CDTI
    Inventor: Zahra Nazarpoor
  • Patent number: 8834824
    Abstract: A method is described for treating a gas stream comprising fluorine (F2) gas. In a preferred embodiment, the method comprises adding water vapor to a gas stream and conveying the gas stream and water vapor to a reaction chamber containing a heated bed of material to react with F2 to form an inorganic fluoride while inhibiting formation of CF4 within the reaction chamber, and at least partially evacuating the reaction chamber so that the gas stream is conveyed to and from the reaction chamber at sub-atmospheric pressure.
    Type: Grant
    Filed: September 21, 2006
    Date of Patent: September 16, 2014
    Assignee: Edwards Limited
    Inventors: James Robert Smith, Andrew David Wright
  • Patent number: 8834823
    Abstract: Methods and systems for selective catalytic reduction of NOx with an activated-carbon-supported metal catalyst at an operating temperature of between about between about 500° C. and about 750° C. An exhaust stream including NOx is introduced to a catalytic reactor having the activated-carbon-supported metal catalyst for NOx reduction of at least 90%. A second catalyst reactor can be provided downstream to remove or convert nitrous oxide as desired.
    Type: Grant
    Filed: July 10, 2013
    Date of Patent: September 16, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ajit B. Dandekar, Richard F. Socha, Richard L. Eckes, S. Beau Waldrup
  • Publication number: 20140252270
    Abstract: Systems, compositions, and methods for removing a substance or substances from a material, such as a gas or liquid material, are described. The compositions can comprise composite removal particles. In some embodiments, the composite removal particles can be comprised of support particles made from an inexpensive carrier material, and a reactive particle borne on the support particle. The reactive particle reacts with the substance or substances in the material. The reacted composite removal particles can then be removed from the material, which reduces the amount of the substance or substances present in the material. The composite removal particles are useful for removing pollutants, such as mercury, from exhaust gases, such as flue gas from a power plant combustion unit, and from other materials such as natural gas, liquefied natural gas, fuels, hydrocarbons, petrochemicals, and refinery streams.
    Type: Application
    Filed: March 5, 2014
    Publication date: September 11, 2014
    Inventor: Stephen Edward LEHMAN, JR.
  • Patent number: 8828339
    Abstract: A CO shift catalyst according to the present invention is one that reforms carbon monoxide (CO) in gas. The CO shift catalyst includes: active ingredients including one of molybdenum (Mo) and iron (Fe) as a main ingredient and one of nickel (Ni) and ruthenium (Ru) as an accessory ingredient; and one or at least two oxides of titanium (Ti), zirconium (Zr), and cerium (Ce) as a carrier supporting the active ingredients. The CO shift catalyst can be used for a CO shift reactor 20 that converts CO in gasified gas 12 produced in a gasifier 11 into CO2.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: September 9, 2014
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Toshinobu Yasutake, Masanao Yonemura, Tetsuya Imai
  • Publication number: 20140248200
    Abstract: Provided are emissions treatment systems for an exhaust stream having an ammonia-generating component, such as a NOx storage reduction (NSR) catalyst or a lean NOx trap (LNT) catalyst, and an SCR catalyst disposed downstream of the ammonia-generating catalyst. The SCR catalyst can be a molecular sieve having the CHA crystal structure, for example SSZ-13 or SAPO-34, which can be ion-exchanged with copper. The LNT can be layered, having an undercoat washcoat layer comprising a support material, at least one precious metal, and at least one NOx sorbent selected from the group consisting of alkaline earth elements, rare earth elements, and combinations thereof and a top washcoat layer comprising a support material, at least one precious metal, and ceria in particulate form, the top washcoat layer being substantially free of alkaline earth components. The emissions treatment system is advantageously used for the treatment of exhaust streams from diesel engines and lean burn gasoline engines.
    Type: Application
    Filed: May 9, 2014
    Publication date: September 4, 2014
    Applicant: BASF Corporation
    Inventors: Chung-Zong Wan, Xiaolai Zheng, Susanne Stiebels, Claudia Wendt, Torsten Neubauer, R. Samuel Boorse
  • Patent number: 8821818
    Abstract: A method and apparatus for cleaning carbon oxides, sulfur oxides and nitrogen oxides, from stack gas, from combustion of coal, combustion of natural gas or propane, or from a cement kiln by reaction using calcium zeolite and sodium zeolite catalysts. The method also includes cleaning the catalytic beds with nitrogen to remove the collected reactants and recover a fertilizer product and the catalysts for reusable.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: September 2, 2014
    Assignee: Three D Stack, LLC
    Inventor: James Gary Davidson
  • Patent number: 8821608
    Abstract: Inner cases are connected to outer cases through joining flanges which protrude toward outer peripheries of the outer cases. A plurality of combinations each including filters, the inner cases, and the outer cases are provided. Both the joining flanges are sandwiched and fixed between a pair of sandwiching flanges, thereby connecting the plurality of outer cases to each other.
    Type: Grant
    Filed: June 30, 2010
    Date of Patent: September 2, 2014
    Assignee: Yanmar Co., Ltd.
    Inventor: Masataka Mitsuda
  • Patent number: 8821803
    Abstract: Systems and methods for treating a fluid with a body are disclosed. Various aspects involve treating a fluid with a porous body. In select embodiments, a body comprises ash particles, and the ash particles used to form the body may be selected based on their providing one or more desired properties for a given treatment. Various bodies provide for the reaction and/or removal of a substance in a fluid, often using a porous body comprised of ash particles. Computer-operable methods for matching a source material to an application are disclosed. Certain aspects feature a porous body comprised of ash particles, the ash particles have a particle size distribution and interparticle connectivity that creates a plurality of pores having a pore size distribution and pore connectivity, and the pore size distribution and pore connectivity are such that a first fluid may substantially penetrate the pores.
    Type: Grant
    Filed: December 25, 2012
    Date of Patent: September 2, 2014
    Inventors: Charles E. Ramberg, Stephen A. Dynan, Jack A. Shindle
  • Patent number: 8815455
    Abstract: A hydrogen generator includes: a water evaporation unit configured to mix water with a raw gas; a burner; a combustion exhaust gas flow channel provided on an inner side than the water evaporation unit and through which a combustion exhaust gas from the burner flows; a reforming catalyst layer configured to produce a reformed gas; and a carbon monoxide reduction unit configured to reduce an amount of carbon monoxide contained in the reformed gas. The water evaporation unit includes a flow channel member defining a flow channel through which the raw gas and the water flow. A pitch of the flow channel member is changed according to at least one of an amount of heat exchange between the combustion exhaust gas flow channel and the water evaporation unit and an amount of heat exchange between the water evaporation unit and the carbon monoxide reduction unit.
    Type: Grant
    Filed: May 13, 2009
    Date of Patent: August 26, 2014
    Assignee: Panasonic Corporation
    Inventors: Akira Maenishi, Yuuji Mukai, Hiroki Fujioka
  • Patent number: 8814974
    Abstract: A thin-walled porous ceramic wall-flow filter is disclosed. The filter produces a relatively lower pressure drop coupled with relatively high initial filtration efficiency (FE0), and may enable packaging the filter in a smaller volume. The filter includes a plurality of porous ceramic walls forming cell channels. At least some of the cells are plugged forcing some exhaust gases through the walls, thereby filtering out entrained particulates. The walls have a wall thickness (Twall) wherein 102 ?m?Twall<279 ?m, and a median pore diameter (MPD), and wherein 10<Twall/MPD, and may also be <40. The relatively small median pore diameter (MPD) in comparison to the wall thickness (Twall) allows the use of thinner ceramic walls that provide less flow resistance than thicker walls while maintaining sufficient initial filtration efficiency (FE0). Furthermore, such thin-walled filter structure coupled with unequal inlet/outlet area ratio (Ai/Ao) may allow filter lengths to be additionally shortened.
    Type: Grant
    Filed: August 24, 2007
    Date of Patent: August 26, 2014
    Assignee: Corning Incorporated
    Inventors: Douglas Munroe Beall, Achim Karl-Erich Heibel, Pushkar Tandon
  • Patent number: 8815183
    Abstract: A reactor formed within a honeycomb monolith is disclosed, the monolith having a plurality of parallel cells and comprising one or more process fluid paths lying within closed cells of the monolith and extending laterally from cell to cell, the monolith having porous walls that are coated with a non-porous coating in at least a first zone along the one or more process fluid paths and that remain porous in at least a second zone along the one or more process fluid paths, the porous walls in the second zone adapted to allow permeate in a respective process fluid path to pass through the porous walls.
    Type: Grant
    Filed: August 31, 2010
    Date of Patent: August 26, 2014
    Assignee: Corning Incorporated
    Inventors: James Scott Sutherland, Andrew David Woodfin
  • Patent number: 8815193
    Abstract: A selective non-catalytic reduction apparatus for exhaust gases comprising a reactor for elevated temperature reduction of NOx comprising an injection zone, internal structure zone and rear zone. The internal structure zone includes packing materials and provides a surface area of 5.0 m2/g to 20 m2/g where the packing material is present in the reactor at a level of 10% to 50% of the reactor volume. The reactor provides one or more of the following: (1) a residence time for exhaust gas of 0.1 seconds to 5.0 seconds; (2) a pressure drop of less than or equal to 1400 Pa/m at an exhaust gas velocity of 1.0 meter/second.
    Type: Grant
    Filed: April 29, 2013
    Date of Patent: August 26, 2014
    Assignee: Southwest Research Institute
    Inventors: Maoqi Feng, Rijing Zhan, Jeffrey N. Harris
  • Patent number: 8814969
    Abstract: An exhaust gas emission control system includes a cylindrical inflow body and an inflow pipe into which exhaust gas flows. The exhaust gas emission control system also includes a cylindrical outflow body and an outflow pipe from which the exhaust gas flows. The inflow pipe is provided with a louver member that covers an opening of the inflow body near an upstream side of an exhaust gas flow direction. The louver member is provided with slits and inclined plates capable of changing a flow direction of the exhaust gas passing through the slits into a desired direction.
    Type: Grant
    Filed: February 17, 2012
    Date of Patent: August 26, 2014
    Assignee: Komatsu Ltd.
    Inventors: Shouhei Nagasaka, Hiroki Sato, Issei Hara, Yosuke Obuchi, Tatsushi Itoh, Yuuki Kasaoka
  • Patent number: 8814975
    Abstract: There is provided a honeycomb structure including a honeycomb base material including a porous partition wall parent material; plugged portions; and a porous collecting layer disposed on the surface of the partition wall parent material in the remaining cells. A melting point of a material constituting the collecting layer is higher than that of a material constituting the partition wall parent material, a pore surface area per unit volume of the collecting layer is 2.0 times or more a pore surface area per unit volume of the partition wall parent material, and a thickness of a portion of the collecting layer which penetrates into pores of the partition wall parent material is 6% or smaller of that of each of partition walls including the partition wall parent material and the collecting layer.
    Type: Grant
    Filed: March 20, 2012
    Date of Patent: August 26, 2014
    Assignee: NGK Insulators, Ltd.
    Inventor: Yoshio Kikuchi
  • Patent number: 8808633
    Abstract: A silico-alumino phosphate includes Si, Al, and P. A ratio of an amount of substance of Si to a sum of an amount of substance of Al and an amount of substance of P is approximately 0.22 or more and approximately 0.33 or less. An acid point is approximately 1.2 mmol/g or more. A honeycomb structural body includes a honeycomb unit. The honeycomb unit includes the silico-alumino phosphate and an inorganic binder. The honeycomb unit has a plurality of through-holes divided by a plurality of partition walls and arranged in a longitudinal direction of the honeycomb unit. An exhaust gas conversion apparatus includes the honeycomb structural body, a holding sealing member and a metal pipe. The holding sealing member is provided at an outer peripheral portion of the honeycomb structural body. The honeycomb structural body and the holding sealing member are installed in the metal pipe.
    Type: Grant
    Filed: August 26, 2011
    Date of Patent: August 19, 2014
    Assignee: Ibiden Co., Ltd.
    Inventors: Masafumi Kunieda, Yosuke Matsukawa, Takunari Murakami
  • Patent number: 8808418
    Abstract: A system for treating diesel exhaust is disclosed. The system includes a first filter including layers of filtration material positioned between layers of corrugated metallic foil. The metallic foil defines a honeycomb arrangement of longitudinal passageways from an upstream end to a downstream end and also openings for allowing exhaust to pass between adjacent longitudinal passageways of the metallic foil. The filtration material is positioned such that exhaust between the adjacent longitudinal passageways passes through the filtration material. The metallic foil also includes flow diverting structures to divert flow within the longitudinal passageways through the openings. A second filter is positioned downstream from the first filter. The second filter defines a honeycomb arrangement of longitudinal passageways. The longitudinal passages are selectively plugged adjacent upstream and downstream ends to force flow radially through walls between the longitudinal passages of the second filter.
    Type: Grant
    Filed: July 16, 2012
    Date of Patent: August 19, 2014
    Assignee: Donaldson Company
    Inventors: Wenzhong Zhang, Todd R. Taubert, Timothy L. Ricke, Julian A. Imes
  • Patent number: 8801822
    Abstract: An exhaust gas aftertreatment system for an engine can perform manual regeneration control for regenerating a particulate removal filter by increasing the engine rotation speed. The system can suppress the engine rotation speed increase while maintaining the exhaust gas temperature required to regenerate the particulate removal filter. The system can set the target engine rotation speed to a first set value when a regeneration instruction signal from a manual regeneration switch is received. When, although the engine rotation speed falls within a predetermined engine rotation speed range including the first set value that is the target engine rotation speed for a predetermined time period, the exhaust gas temperature does not reach the filter's regeneration temperature within the predetermined time period, the target engine rotation speed is repeatedly reset by being increased from the first set value by a predetermined rotation speed.
    Type: Grant
    Filed: February 16, 2011
    Date of Patent: August 12, 2014
    Assignee: Yanmar Co., Ltd.
    Inventors: Hideo Shiomi, Taichi Togashi
  • Patent number: 8802016
    Abstract: The present invention relates to a catalyzed soot filter which comprises a wall flow substrate with an inlet end, an outlet end, a substrate axial length extending between the inlet end and the outlet end, and a plurality of passages defined by internal walls of the wall flow substrate wherein the plurality of passages comprise inlet passages having an open inlet end and a closed outlet end, and outlet passages having a closed inlet end and an open outlet end, and wherein the internal walls of the inlet passages comprise a zoned first inlet coating, the internal walls of the outlet passages comprise a zoned first outlet coating, and wherein the first inlet coating and the first outlet coating are present on the wall flow substrate at a coating loading ratio of less than 0.5.
    Type: Grant
    Filed: November 22, 2010
    Date of Patent: August 12, 2014
    Assignee: BASF Catalyst Germany GmbH
    Inventor: Gerd Grubert
  • Patent number: 8802015
    Abstract: An exhaust gas cleaning device (2) for an exhaust system (1) of an internal combustion engine with an exhaust gas cleaning element (7), which is arranged in a first tubular body (3), and with a second tubular body (4), to which the first tubular body (3) is detachably connected via a clamp connection (5). The clamp connection (5) includes a radially outwardly projecting first ring collar (8), formed at the first tubular body (3) and extending circumferentially in a closed form and a radially outwardly projecting second ring collar (9), formed at the second tubular body (4) and extending circumferentially in a closed form. A sealing ring (10) extends circumferentially in a closed form and is axially in contact with the first ring collar (8) and the second ring collar (9). A first ring body (11) is arranged on the outside at the first tubular body (3) and is axially in contact with the first ring collar on the side facing away from the sealing ring (10).
    Type: Grant
    Filed: February 3, 2010
    Date of Patent: August 12, 2014
    Assignee: Eberspächer Exhaust Technology GmbH & Co. KG
    Inventors: Wolfgang Datz, Michael Krause
  • Patent number: 8801818
    Abstract: A method for cleaning and checking a particle filter of a motor vehicle is provided. In a first step soot particles which have collected in the particle filter are burnt off. In a second step ash located in the particle filter is blown out using compressed air. A cleaning device for a particle filter of a motor vehicle is also provided.
    Type: Grant
    Filed: May 14, 2012
    Date of Patent: August 12, 2014
    Assignee: Daimler AG
    Inventors: Andreas Albrecht, Peter Benz, Charles W. Emley, Uwe Gaertner, Christian Medau
  • Patent number: 8802017
    Abstract: In a honeycomb filter 20, partition portions and trapping layers are formed such that a pore volume difference that is obtained from pore distributions measured by mercury porosimetry and is a difference in volume of pores having a diameter of 10 ?m or less between the downstream portion and the upstream portion of the honeycomb filter, is in the range of 0.01 cm3/g or more and 0.08 cm3/g or less. In the honeycomb filter, in the downstream portion, a first pore volume peak is present in a first pore diameter range of 2 ?m or more and 9 ?m or less and a second pore volume peak that is higher than the first pore volume peak is present in a second pore diameter range of 10 ?m or more and 25 ?m or less.
    Type: Grant
    Filed: March 12, 2012
    Date of Patent: August 12, 2014
    Assignee: NGK Insulators, Ltd.
    Inventors: Takashi Mizutani, Shingo Iwasaki
  • Patent number: 8795619
    Abstract: A catalyst for purification of exhaust gas, in which a noble metal is supported on a metal oxide support, has a basic site content of 1 mmol/L-cat or less, as determined on the basis of an amount of CO2 desorbed per liter of the catalyst as measured by a CO2 temperature-programmed desorption method.
    Type: Grant
    Filed: May 8, 2008
    Date of Patent: August 5, 2014
    Assignees: Toyota Jidosha Kabushiki Kaisha, Cataler Corporation
    Inventors: Tadashi Suzuki, Satoru Kato, Naoki Takahashi, Takaaki Kanazawa, Masanori Yamato, Kazuhiro Yoshimoto, Michihiko Takeuchi, Yuuji Matsuhisa
  • Patent number: 8795621
    Abstract: Methods and systems are provided for selective catalytic reduction of NOx with a low molecular low molecular weight aldehyde, e.g., acetaldehyde, as a reductant using a catalyst system including two catalysts. An exhaust stream containing an amount of NO from a combustion operation is provided. A portion of the exhaust stream is introduced to a first catalyst to convert the NO to NO2. The exhaust stream from the first catalyst with NO2 and a reductant stream containing a low molecular weight aldehyde, e.g., acetaldehyde, are introduced to the second catalyst to convert the NO2 to N2. The first catalyst can be bulk Co3O4, Ru or Pt loaded on alumina; the second catalyst can be various zeolites, or zeolites loaded with potassium.
    Type: Grant
    Filed: July 10, 2013
    Date of Patent: August 5, 2014
    Assignee: ExxonMobil Research and Engineering
    Inventors: Ajit B. Dandekar, Richard F. Socha, Richard L. Eckes, S. Beau Waldrup, Jason M. McMullan
  • Publication number: 20140205508
    Abstract: A filter is configured for efficient combustion of particulates accumulated on a catalyst layer 7 in both a rapid combustion range and a slow combustion range. The catalyst layer 7 on an exhaust gas passage wall of a filter 1 includes a mixture of a Rh-doped Ce-containing composite oxide particle material loaded with Pt and a composite particle material loaded with Pt. In mixed particles of this mixture, Zr-containing composite oxide particles containing no Ce and activated alumina particles are mixed together and agglomerated.
    Type: Application
    Filed: August 1, 2012
    Publication date: July 24, 2014
    Applicant: MAZDA MOTOR CORPORATION
    Inventors: Takashi Baba, Koichiro Harada, Hiroshi Yamada, Masahiko Shigetsu, Akihide Takami
  • Patent number: 8784759
    Abstract: The present invention relates to a nitrogen oxide storage catalyst comprising: a substrate; a first washcoat layer disposed on the substrate, the first washcoat layer comprising metal oxide support particles and a nitrogen oxide storage material comprising at least one metal compound selected from the group consisting of alkaline earth metal compounds, alkali metal compounds, rare earth metal compounds, and mixtures thereof, at least a portion of said at least one metal compound being supported on the metal oxide support particles; and a second washcoat layer disposed over the first washcoat layer, said second washcoat layer comprising Rh, wherein the first washcoat layer contains substantially no Rh, and wherein the second washcoat layer is disposed on 100-x % of the surface of the first washcoat layer, x ranging from 20 to 80.
    Type: Grant
    Filed: June 9, 2011
    Date of Patent: July 22, 2014
    Assignee: BASF SE
    Inventor: Marcus Hilgendorff
  • Patent number: 8784741
    Abstract: An electrically-heated catalytic converter comprises a catalyst support which produces heat when electric current is applied, a holding mat made of an electrical insulating material, the holding mat being provided so as to cover an outer circumference of the catalyst support, and a case which houses the catalyst support and holds the catalyst support via the holding mat. The catalytic converter treats gas flowing in the case by a catalyst supported on the catalyst support. The holding mat has a water-absorbing property. An insulation layer made of an electrical insulating material is provided between the case and the holding mat.
    Type: Grant
    Filed: April 6, 2010
    Date of Patent: July 22, 2014
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Mamoru Yoshioka, Noriaki Kumagai, Naoya Takagi, Tatsuo Iida, Yasuo Kinoshita