Indirect Heat-exchange Tube Within Reaction Chamber With A Nonreactant Heat-exchange Fluid Passing Therethrough Patents (Class 422/200)
-
Patent number: 7722831Abstract: A micro component steam reformer system for producing hydrogen-enriched gas to power a fuel cell adapted for scalable power requirements wherein fluid flow is configured in a circuit whereby, in serially interconnected fluid flow modules, a vaporized hydrocarbon is mixed with fuel cell off gas having a hydrogen component and combusted to heat vaporizers and a steam reformer, vaporized hydrocarbons and water vapor are introduced as a feed stock into the steam reformer to produce a syn-gas, which is cooled and purified, and the resulting principally hydrogen gas is introduced into a hydrogen fuel cell having an interconnection within the circuit in which off gas from the fuel cell is processed to provide hydrogen and water for use in the system cycle.Type: GrantFiled: September 25, 2006Date of Patent: May 25, 2010Inventors: James Seaba, Christopher J. Brooks
-
Publication number: 20100105956Abstract: The invention relates to improvements in internal loop reactors. The reactor of the invention is characterized by a plurality of cooling tubes which form the annulus between the riser and the downcomer path of said internal loop reactor. The reactor also provides improvements in hydroformylation reactions using the improved reactor.Type: ApplicationFiled: January 5, 2010Publication date: April 29, 2010Inventors: Ronald Dean Garton, Matthew Findlay, Krishnan Sankaranarayanan, Arie Van Vliet
-
Publication number: 20100092374Abstract: Process for the continuous catalytic complete or partial oxidation of a starting gas containing from 0.1 to 66% by volume of sulphur dioxide plus oxygen, in which the catalyst is kept active by means of pseudoisothermal process conditions with introduction or removal of energy; apparatus for the continuous catalytic complete or partial oxidation of a starting gas containing sulphur dioxide and oxygen having at least one tube contact apparatus in the form of an upright heat exchanger composed of at least one double-walled tube whose catalyst-filled inner tube forms a reaction tube, with heat being transferred in cocurrent around the reaction tube and an absorber for separating off SO3 downstream of the tube contact apparatus; the reactivity of the catalyst being preset by mixing with inert material.Type: ApplicationFiled: October 13, 2007Publication date: April 15, 2010Applicant: BAYER TECHNOLOGY SERVICES GMBHInventors: Bernd Erkes, Martin Kürten, Verena Haverkamp
-
Publication number: 20100068128Abstract: The invention relates to a reactor (1) and a process for continuously preparing H2S by converting a reactant mixture which comprises essentially gaseous sulfur and hydrogen over a catalyst, comprising a sulfur melt (9) at least in a lower subregion (8) of the reactor (1), into which gaseous hydrogen is introduced. The catalyst is arranged in at least one U-shaped tube (21) which is partly in contact with the sulfur melt (9), the at least one U-shaped tube (21) having at least one entry orifice (23) on a limb (26) above the sulfur melt (9), through which the reactant mixture can enter the U-shaped tube (21) from a reactant region (10) of the reactor (1), having a flow path within the at least one U-shaped tube, along which the reactant mixture can be converted in a reaction region comprising the catalyst (22), and having at least one exit orifice (24) in another limb (27) through which a product can exit into a product region (7).Type: ApplicationFiled: January 14, 2008Publication date: March 18, 2010Applicant: BASF SEInventors: Andreas Wölfert, Herald Jachow, Heinz Driess
-
Patent number: 7674933Abstract: A method for modernizing a urea production plant including a urea synthesis reactor, a stripping unit and at least one condensation unit. The method includes providing: means in the condensation unit for substantially condensing at least a portion of a flow comprising ammonia and carbon dioxide in vapor phase leaving the stripping unit; a second stripping unit; means for feeding a first portion of a reaction mixture flow comprising urea, carbamate and free ammonia in aqueous solution leaving the reactor to the first stripping unit; means for feeding a second portion of the reaction mixture flow leaving the reactor to the second stripping unit; and means for feeding at least a portion of a flow comprising ammonia and carbon dioxide in vapor phase leaving the second stripping unit directly to the synthesis reactor. A de-bottlenecking of the high-pressure section downstream of the synthesis reactor may be achieved, improving production capacity.Type: GrantFiled: March 19, 2008Date of Patent: March 9, 2010Assignee: Urea Casale S.A.Inventor: Federico Zardi
-
Patent number: 7670574Abstract: A method of cooling syngas in a gasifier is provided. The method includes channeling cooling fluid through at least one tube-bundle that includes at least three tubes coupled together within a radiant syngas cooler and extends through a reaction zone of the gasifier, and circulating reactant fluid around the at least one tube-bundle to facilitate transferring heat from the reactant fluid to the cooling fluid.Type: GrantFiled: January 19, 2007Date of Patent: March 2, 2010Assignee: General Electric CompanyInventors: George Albert Goller, Daniel Anthony Nowak
-
Patent number: 7666366Abstract: The invention relates to improvements in internal loop reactors. The reactor of the invention is characterized by a plurality of cooling tubes which form the annulus between the riser and the downcomer path of said internal loop reactor. The reactor also provides improvements in hydroformylation reactions using the improved reactor.Type: GrantFiled: July 10, 2006Date of Patent: February 23, 2010Assignee: ExxonMobil Chemical Patents Inc.Inventors: Ronald Dean Garton, Matthew Findlay, Krishnan Sankaranarayanan, Arie Van Vliet
-
Publication number: 20100016455Abstract: Modular reactor for exothermic/endothermic chemical reactions which take place in three-phase systems, comprising a series of modules, superimposed with respect to each other, fixed to each other by means of coupling flanges, each module consisting of an external cylindrical body and a series of tube bundles, for the circulation of a thermal-exchange fluid, positioned inside said body.Type: ApplicationFiled: December 18, 2007Publication date: January 21, 2010Inventors: Vincenzo Piccolo, Susi Bonomi, Marzio Piazza
-
Publication number: 20100008834Abstract: There is described a microfluid system with a microchannel structure for the passage of fluids and a further channel structure separated from the microstructure by means of at least one separating wall for the passage of a heat transfer fluid. The risk of internal leakage in the microfluid system can be recognized in time, by separation of the microchannel structure from a cavity of at least one point by a further separating wall, said separating wall being at least locally weaker than the separating wall between the microchannel structure and the further channel structure and said cavity is connected to a detector device for detection of ingressing fluid.Type: ApplicationFiled: July 24, 2006Publication date: January 14, 2010Inventors: Astrid Lohf, Waldemar Wenzel
-
Patent number: 7645437Abstract: A method and apparatus, constructed of ceramics and other corrosion resistant materials, for decomposing sulfuric acid into sulfur dioxide, oxygen and water using an integrated boiler, superheater, and decomposer unit comprising a bayonet-type, dual-tube, counter-flow heat exchanger with a catalytic insert and a central baffle to increase recuperation efficiency.Type: GrantFiled: October 17, 2007Date of Patent: January 12, 2010Assignee: Sandia CorporationInventors: Robert Moore, Paul S. Pickard, Edward J. Parma, Jr., Milton E. Vernon, Fred Gelbard, Roger X. Lenard
-
Patent number: 7642377Abstract: Systems and methods for producing urea are provided. A method for producing urea can include exchanging heat from a syngas comprising hydrogen and carbon dioxide to a urea solution comprising urea and ammonium carbamate. The heat transferred can be sufficient to decompose at least a portion of the ammonium carbamate. In one or more embodiments, the syngas can be reacted with liquid ammonia to provide a carbon dioxide lean syngas and an ammonium carbamate solution. The ammonium carbamate solution can be heated to a temperature of about 180° C. or more. At least a portion of the ammonium carbamate in the heated ammonium carbamate solution can be dehydrated to provide the urea solution.Type: GrantFiled: July 21, 2008Date of Patent: January 5, 2010Assignee: Kellogg Brown & Root LLCInventor: Vishnu D. Singh
-
Patent number: 7638038Abstract: A method for controlling the pseudo-isothermicity of a chemical reaction in a respective reaction zone. (9) in which the use of heat exchangers (6) is foreseen having an operating heat exchange fluid flowing through them and in which heat exchange critical areas (9a) are identified, the method being distinguished by the fact that it reduces and controls, in the critical areas (9a) of the reaction zone, the value of the heat exchange coefficient between the operating fluid and the zone (9), through thermal insulation of the portions (6a, 6b) of such exchangers extending in such areas (9a).Type: GrantFiled: October 2, 2002Date of Patent: December 29, 2009Assignee: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
-
Patent number: 7635456Abstract: A syngas reforming reactor has a shell-and-tube configuration wherein the shell-side fluid flow path through the tube bundle has a longitudinal configuration. The reactor can include a shell-side inlet fluid distributor plate below the lower end of the tube bundle, and a flow sleeve in an enlarged-diameter discharge annulus at an upper end adjacent the tube sheet to prevent short-circuiting of the shell-side fluid into the shell-side fluid outlet. The tube bundle can include a plurality of ring baffles and lattice baffles. The longitudinal flow configuration can provide a lower shell-side pressure drop and lower cost compared to a conventional cross-flow reforming exchanger.Type: GrantFiled: August 8, 2006Date of Patent: December 22, 2009Assignee: Kellogg Brown & Root LLCInventors: Robert Stevens Burlingame, Lloyd Edward Cizmar, Larry Gene Hackemesser, Laura Beth Aguilar
-
Patent number: 7635399Abstract: A fuel reformer which is relatively simple in structure and can be manufactured at a low cost is provided.Type: GrantFiled: June 27, 2003Date of Patent: December 22, 2009Assignee: Ebara CorporationInventor: Qingquan Su
-
Publication number: 20090311151Abstract: Coker heater operation is improved by on-line spalling of coker heater pipes. In one embodiment an off-line pipe is added to the on-line coker heater pipes. When an on-line pipe is to be spalled, flow is diverted to the offline pipe allowing for full operation of the coker heater. In another embodiment, a thermal transfer resistant zone plate is movably mounted in the radiant section of the coker heater. By moving the zone plate from an operating position to a spalling position and adjusting the temperature of the plurality of burners, the temperature of the pipes in the zone of the heater radiant section to be spalled can be lowered, while the temperature in the remaining zones of the heater radiant section are fully operational.Type: ApplicationFiled: August 24, 2009Publication date: December 17, 2009Applicant: Alliance Process Partners, LLCInventor: Robert L. Gregory
-
Patent number: 7632778Abstract: An apparatus for producing hydrogen, which comprises: a. a heated steam reforming stage (1) with a reforming catalyst to convert gaseous or vaporizable hydrocarbons and water into hydrogen, carbon monoxide and further reformer products; b. at least one stage downstream of the steam reforming stage for the catalytic conversion of the mixture of hydrogen, carbon monoxide and excess steam leaving the steam reforming stage (shift stage) (2); and c. a fine purification stage (3) downstream of the shift stage(s) for the catalytic lowering of the residual carbon monoxide content of the conversion products by selective methanization, is described. In the apparatus, the shift stage (2) and the fine purification stage (3) are configured as a unitary hollow body (exothermic catalyst stage).Type: GrantFiled: January 17, 2005Date of Patent: December 15, 2009Assignee: Süd-Chemie AGInventors: Klaus Wanninger, Peter Britz, Nicolas Zartenar
-
Patent number: 7619114Abstract: A method for revamping a urea plant of the type comprising a synthesis section (2) having a urea synthesis reactor (5), a thermal stripping unit (7) and at least one horizontal condensation unit (6), a treatment section (3) operating at medium pressure and a recovery section (4) operating at low pressure foresees the transformation of said at least one horizontal condensation unit (6) into a vertical condensation unit of the submerged type comprising a tube bundle and the provision of means (37, 41) for feeding a flow comprising ammonia and carbon dioxide in vapor phase and a flow of condensation liquid comprising carbamate simultaneously and independently in each of the tubes of said tube bundle with circulation inside said tubes in equicurrent from the bottom towards the top, and means (39, 50) for feeding at least one part of the feed carbon dioxide into said stripping unit (7) for use as stripping agent.Type: GrantFiled: November 12, 2007Date of Patent: November 17, 2009Assignee: Urea Casale S.A.Inventor: Giorgio Pagani
-
Publication number: 20090274594Abstract: Methods and systems for a feed injector are provided. The feed injector includes a conduit including a flow passage extending along a longitudinal axis of the conduit to a distal end opening and a cooling passage integral to the conduit circumscribing the distal end opening. The cooling passage is configured to channel a flow of coolant circumferentially about the distal end opening wherein the cooling passage comprising a plurality of axially-spaced flow chambers.Type: ApplicationFiled: April 30, 2008Publication date: November 5, 2009Inventors: Cliff Yi Guo, Shashishekara Sitharamarao Talya, Scott R. Parent
-
Publication number: 20090257928Abstract: A system for producing hydrogen features a reactor including a reaction channel adapted to receive a reaction stream including a mixture of supercritical water and a hydrocarbon fuel. A catalyst is positioned in the reaction channel so that a product stream containing hydrogen is produced by a reaction in the reaction channel when the mixture is exposed to the catalyst; wherein the catalyst contains a catalytically active metal and a promoter in a metal format, selected from the group consisting of potassium, sodium, rubidium, lithium, cesium, beryllium, magnesium, calcium, strontium, and barium.Type: ApplicationFiled: April 8, 2009Publication date: October 15, 2009Inventors: Zhijun Jia, Mark Wood, Clay Thiele
-
Publication number: 20090253815Abstract: Implementing at least one endothermic and/or exothermic reaction in a compact reactor which has passages for conducting gaseous and/or liquid media, through which passages the reactants of the endothermic or exothermic reaction as well as a heating medium or coolant are sent, whereby a) The endothermic reaction is implemented in heat exchange with a heating medium, b) The endothermic reaction is implemented in heat exchange with an exothermic reaction, or c) The exothermic reaction is implemented in heat exchange with a coolant. The heat exchange between the media mentioned in a) to c) is carried out indirectly and via a third gaseous and/or liquid medium (moderation medium).Type: ApplicationFiled: April 3, 2009Publication date: October 8, 2009Applicant: LINDE AKTIENGESELLSCHAFTInventor: Thomas Hecht
-
Patent number: 7597797Abstract: Coker heater operation is improved by on-line spalling of coker heater pipes. In one embodiment an off-line pipe is added to the on-line coker heater pipes. When an on-line pipe is to be spalled, flow is diverted to the off-line pipe allowing for full operation of the coker heater. In another embodiment, a thermal transfer resistant zone plate is movably mounted in the radiant section of the coker heater. By moving the zone plate from an operating position to a spalling position and adjusting the temperature of the plurality of burners, the temperature of the pipes in the zone of the heater radiant section to be spalled can be lowered, while the temperature in the remaining zones of the heater radiant section are fully operational.Type: GrantFiled: January 8, 2007Date of Patent: October 6, 2009Assignee: Alliance Process Partners, LLCInventor: Robert L. Gregory
-
Patent number: 7588738Abstract: The invention relates to series reactor beds containing different oligomerization catalysts and having independent temperature control, and processes for the oligomerization of light olefins to heavier olefins using such series reactor beds.Type: GrantFiled: August 23, 2005Date of Patent: September 15, 2009Assignee: ExxonMobil Chemical Patents Inc.Inventors: Stephen Harold Brown, Jon Edmond Randoph Stanat, Jose Manuel Vargas, Stephen W. Beadle, Georges Marie K. Mathys, John Stephen Godsmark, Raphael Frans Caers
-
Patent number: 7553460Abstract: A process for cracking hydrocarbon feedstock containing resid comprising: heating the feedstock, mixing the heated feedstock with a fluid and/or a primary dilution steam stream to form a mixture, flashing the mixture to form a vapor phase and a liquid phase which collect as bottoms and removing the liquid phase, separating and cracking the vapor phase, and cooling the product effluent.Type: GrantFiled: March 2, 2007Date of Patent: June 30, 2009Assignee: Exxonmobil Chemical Patents Inc.Inventors: Richard C. Stell, Jennifer L. Bancroft, Arthur R. Dinicolantonio, Subramanian Annamalai, James N. McCoy, Paul F. Keusenkothen, George Stephens, John R. Messinger, James Mitchell Frye, Nick G. Vidonic, George J. Balinsky
-
Publication number: 20090162265Abstract: A microreactor assembly comprising a fluidic interconnect backbone and plurality of fluidic microstructures is provided. The fluidic microstructures are supported by respective portions of the fluidic interconnect backbone, The microreactor assembly comprises a plurality of non-polymeric interconnect seals associated with the interconnect input and output ports. The interconnect input port of the fluidic interconnect backbone is interfaced with the microchannel output port of a first fluidic microstructure at one of the non-polymeric interconnect seals. The interconnect output port of the fluidic interconnect backbone is interfaced with the microchannel input port of a second fluidic microstructure at another of the non-polymeric interconnect seals.Type: ApplicationFiled: December 22, 2008Publication date: June 25, 2009Inventors: Stephane Poissy, Ronan Tanguy
-
Publication number: 20090136391Abstract: Systems and methods for producing ammonia. The system can include a first shell having two or more discrete catalyst beds disposed therein, a second shell disposed about the first shell, a first heat exchanger disposed external to the first shell and in fluid communication therewith, a second heat exchanger disposed external to the second shell and in fluid communication therewith, and a flow path disposed within the first shell. A first portion can be reacted in the presence of the catalyst to provide an ammonia effluent. The heat of reaction from the ammonia effluent can be exchanged within the first heat exchanger and the second heat exchanger. The heated second portion of the feed gas can be introduced to the first shell and can be reacted in the presence of the catalyst.Type: ApplicationFiled: April 22, 2008Publication date: May 28, 2009Inventors: SHASHI P. SINGH, Yue Jing
-
Publication number: 20090130001Abstract: A method for fabricating a syngas cooler is provided. The method includes coupling a tube cage within the syngas cooler, and coupling a plurality of platens to the tube cage to facilitate steam production in the syngas cooler. At least a first platen has at least one of a length that is larger than a length of a second platen, a non-linear geometry, and an angular position that is oblique with respect to a wall of the syngas cooler.Type: ApplicationFiled: November 16, 2007Publication date: May 21, 2009Applicant: General Electric CompanyInventors: James Michael Storey, Aaron John Avagliano, Fulton Jose Lopez, John Luigi Battaglioli, Scott Parent
-
Patent number: 7534339Abstract: A shell-and tube reactor including at least one reaction tube with a measuring means, substantially same solid particles being filled in the reaction tubes with or without the measuring means, a length of the filled solid particle layer, and a pressure drop thereof while passing a gas through the reaction tube, per each reaction tube, being substantially the same, respectively. By measuring the temperature of the catalyst particle layer, such a temperature as a representative can be gasped.Type: GrantFiled: August 3, 2006Date of Patent: May 19, 2009Assignee: Nippon Shokubai Co., LtdInventors: Yukihiro Matsumoto, Takeshi Nishimura, Sei Nakahara, Naoto Kasaya
-
Patent number: 7527661Abstract: A hydrogen generator comprising a hydrogen membrane reactor, a fuel supply, a reaction fuel supply line, an air supply, an air supply line, a combustion fuel supply line, a tail gas supply line, a combustion by-product line for transporting combustion by-products from the combustion chamber, and a reaction product line. A membrane assembly to be joined to a reactor chamber of a hydrogen generator, which comprises a membrane; and a membrane support comprising a sintered porous metal. A reactor assembly comprising a reaction chamber containing a porous metal substrate, two membrane assemblies, a fuel supply, a reaction fuel supply line, and a tail gas supply line and a reaction product line. Methods associated with the hydrogen generator, membrane assembly and reactor assembly.Type: GrantFiled: April 18, 2005Date of Patent: May 5, 2009Assignee: Intelligent Energy, Inc.Inventors: Anand Chellappa, Thomas R. Vencill, Michael Roy Powell, Ned A. Godshall
-
Publication number: 20090104488Abstract: The invention relates to a plate (10a) intended to be integrated in a stack of plates in a heat exchanger system, the plate comprising a plurality of channels (38) distributed in rows (40), each row comprising side walls (42) arranged opposite one another and spaced apart from one another in a first direction (44), so that two directly consecutive side walls delimit one of the channels (38), the rows being arranged opposite one another and spaced apart from one another in a second direction (46) which is perpendicular to the first. Furthermore, in the fluid circulation zone (20) of the plate incorporating the channels (38), only the latter are coated with a catalyst allowing a chemical reaction.Type: ApplicationFiled: April 18, 2007Publication date: April 23, 2009Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, RENAULT S.A.S.Inventors: Jean-Antoine Gruss, Emmanuelle Duval-Brunel, Andre Van Veen, Claude Mirodatos
-
Patent number: 7521028Abstract: An improved catalytic reactor includes a housing having a plate positioned therein defining a first zone and a second zone, and a plurality of conduits fabricated from a heat conducting material and adapted for conducting a fluid therethrough. The conduits are positioned within the housing such that the conduit exterior surfaces and the housing interior surface within the second zone define a first flow path while the conduit interior surfaces define a second flow path through the second zone and not in fluid communication with the first flow path. The conduit exits define a second flow path exit, the conduit exits and the first flow path exit being proximately located and interspersed. The conduits define at least one expanded section that contacts adjacent conduits thereby spacing the conduits within the second zone and forming first flow path exit flow orifices having an aggregate exit area greater than a defined percent of the housing exit plane area.Type: GrantFiled: October 27, 2005Date of Patent: April 21, 2009Assignee: Precision Combustion, Inc.Inventors: Lance Smith, Shahrokh Etemad, Hasan Karim, William C. Pfefferle
-
Patent number: 7517507Abstract: The steam reformer has a double-cylinder structure having an inner cylinder and an outer cylinder surrounding the inner cylinder. The inner cylinder contains a high-temperature reaction section and an adjacent section being adjacent to the high-temperature reaction section. The high-temperature reaction section contains a mixed-catalyst bed prepared by mixing a steam reforming catalyst and an oxidation catalyst, and an oxygen-containing gas introduction section. A heat transfer suppresser is structured to suppress heat transfer from the high-temperature reaction section to the adjacent section or to the oxygen-containing gas introduction section. With the heat-transfer suppressor, the thermal diffusion from the high-temperature reaction section to peripheral area is effectively suppressed.Type: GrantFiled: March 11, 2004Date of Patent: April 14, 2009Assignee: T.RAD Co., Ltd.Inventors: Takeshi Kuwabara, Yoshio Tomizawa, Jun Ono, Yasushi Yoshino
-
Publication number: 20090084036Abstract: The invention relates to heat exchanger tubes acting like resonant tubes of a Helmholtz resonator and used as swirl tubes. They are capable of drastically increasing heat transfer in the boundary layers determining the heat flow to be exchanged as a result of their geometrically deformed surfaces.Type: ApplicationFiled: October 12, 2008Publication date: April 2, 2009Inventor: Oliver Neumann
-
Publication number: 20090087359Abstract: A micro-reactor system assembly comprises a stack of at least n process modules (1-6), wherein n is an integer equal to or greater than 1, made from a rigid first material and comprising at least one reactive fluid passage (1A, 1B, 2A, 3A, 6A) for accommodating and guiding a reactive fluid, and at least n+1 heat exchange modules (7, 8) made from a ductile second material other than said first material and comprising at least one heat exchange fluid passage (7A, 8A) for accommodating and guiding a heat exchange fluid, wherein each process module (1-6) is sandwiched between two adjacent heat exchange modules (7, 8).Type: ApplicationFiled: March 29, 2007Publication date: April 2, 2009Inventors: Dominique Roberge, Nikolaus Bieler, Bertin Zimmermann, Rainald Forbert
-
Patent number: 7511101Abstract: A plug flow reactor having an inner shell 27 surrounded by outer shell 21 and having at least one annular flow passage 35 therebetween can be used to prepare compositions, including polymers. The plug flow reactor also includes inlet port 36, an outlet port 37 and a plurality of exchanger tubes 26 wherein the exchanger tubes are in fluid communication to the at least one annular flow passage. Polystyrene and high impact polystyrene can be prepared using the reactor.Type: GrantFiled: May 13, 2005Date of Patent: March 31, 2009Assignee: Fina Technology, Inc.Inventors: Thanh T. Nguyen, Jay L. Reimers
-
Publication number: 20090081088Abstract: The invention is a device for conditioning a comminuted light alloy feedstock to heat and remove impurities from the feedstock. The conditioner device includes a reaction chamber having a substrate feed port for feeding the comminuted light alloy feedstock into the reaction chamber and a discharge port for allowing the conditioned feedstock to exit the reaction chamber. A scrubber gas baffle is positioned at one end of the reaction chamber and coupled to a scrubber gas injector which is configured to inject a scrubber gas through the scrubber gas baffle at a volume and rate of flow sufficient to fluidize the feedstock in the reaction chamber. A scrubber gas heater is also provided for heating the scrubber gas to a temperature sufficient to condition the feedstock as desired.Type: ApplicationFiled: August 20, 2008Publication date: March 26, 2009Inventors: Ashley Stone, Martin Kestle
-
Publication number: 20090074635Abstract: A metallic tube for heating a medium or subject outside thereof or inside it by transfer of heat energy through walls of the tube, in which heat is absorbed or emitted at least to a substantial degree by radiation on one or both of the inner and outer surfaces of the tube, is of a material forming a layer of essentially Al2O3 on the surfaces thereof when heated to at least approximately 750° C. At least one of the external and the internal surface of the tube is coated by one of a metal, metal alloy and metal compound, which after oxidation forms a layer having an emissivity coefficient exceeding 0.7, or by a layer essentially consisting of a metal oxide which has an emissivity coefficient exceeding 0.7.Type: ApplicationFiled: November 15, 2006Publication date: March 19, 2009Applicant: SANDVIK INTELLECTUAL PROPERTY ABInventors: Claes Ohngren, Bo Jonsson
-
Patent number: 7501101Abstract: Microchannel apparatus comprising a header and plural flow microchannels is described in which orifices connect the header and the flow microchannels. The orifices constrict flow. The ratio of the cross-sectional area of each of the orifices to the cross-sectional area of the flow microchannels connected to the orifices is between 0.0005 and 0.1. Also described is microchannel apparatus for conducting unit operations in which a device comprises two arrays of microchannels, and a unit operation is conducted on a fluid as it passes through the first set of microchannels and into a header where a second unit operation is performed, and then the fluid stream passes into the second array of microchannels where the first unit operation is again performed. Methods of conducting unit operations in the apparatuses are also described.Type: GrantFiled: September 30, 2005Date of Patent: March 10, 2009Assignee: Battelle Memorial InstituteInventors: Robert S. Wegeng, Ward E. TeGrotenhuis, Greg A. Whyatt
-
Publication number: 20090047193Abstract: A method for operating a syngas cooler is provided. The method includes channeling a flow of syngas into an annular cooling chamber having a longitudinal axis, injecting a cooling fluid into a manifold such that the cooling fluid is channeled substantially circumferentially about the annular cooling chamber, and discharging the cooling fluid from the manifold such that the cooling fluid contacts a surface of the cooling chamber at a predetermined angle relative to the axis of the cooling chamber.Type: ApplicationFiled: August 15, 2007Publication date: February 19, 2009Inventors: Judeth Helen Brannon Corry, Yulianto Salahuddin Mohsin
-
Publication number: 20090043122Abstract: The invention provides a process for efficient and reliable preparation of organic peroxides, preferably dialkyl peroxides, peroxycarboxylic acids, peroxycarboxylic esters, diacyl peroxides, peroxycarbonate esters, peroxydicarbonates, ketone peroxides and perketals with the aid of at least one static micromixer and an apparatus for performing the process.Type: ApplicationFiled: October 13, 2006Publication date: February 12, 2009Applicants: Ehrfeld Mikrotechnik BTS GmbH, Pergan Hilfsstoffe Fur Industrielle Prozesse GmbHInventors: Alexander Azzawi, Hans-Ernst Mehesch, Edgar Von Zadow, Stefan Kirsch, Bernhard Wormland, Martin Sondermann
-
Patent number: 7488458Abstract: An apparatus (10) for converting a hydrocarbon-containing flow of matter (4) to a hydrogen-enriched fluid flow (10) includes a heating apparatus (5) for production of a heating stream (6), whereby the flow of matter (4) is converted to the hydrogen-enriched fluid flow (10) in a first converter (2) as well as in a second converter (3) arranged behind the first converter in a flow direction. A heating element (8) that is flowed-through by the heating stream (6) is provided for heating at least one of the two converters (2, 3). The invention provides an improved system efficiency, in that a disadvantageous cooling of the second converter (2) is effectively avoided. This is achieved according to the present invention in that at least in one operating phase, the heating stream (6) flows to the second converter (3) completely in a counterflow to the flow of matter (4).Type: GrantFiled: July 2, 2003Date of Patent: February 10, 2009Assignee: Robert Bosch GmbHInventors: Gesine Arends, Peter Riegger
-
Patent number: 7481984Abstract: A system for heating and/or converting at least one medium, such as an evaporator, a reactor or a heat exchanger, has layers arranged in a stack which layers are formed by pressing catalyst material. Devices are provided for dividing the stack into a number of separate function areas.Type: GrantFiled: September 15, 2000Date of Patent: January 27, 2009Assignee: NuCellSys GmbHInventor: Martin Schuessler
-
Patent number: 7481856Abstract: A reactor for autothermal reforming of hydrocarbons that allows a reduction of excess-air factor ? during the reforming without resulting in a reduced conversion of the hydrocarbons in an end region of the reaction zone. The reactor includes at least one reaction zone in which is arranged at least one catalyst structure for the reformation so that the educts involved in the reformation are converted while flowing through the reaction zone. A heating device is included for heating the end region of the reaction zone to accelerate the conversion of the hydrocarbons.Type: GrantFiled: December 4, 2002Date of Patent: January 27, 2009Assignee: Daimler AGInventors: Andreas Docter, Bernhard Vogel, Steffen Oliver Wieland
-
Patent number: 7481857Abstract: Process and reaction unit for isothermal shift conversion of a carbon monoxide containing feed gas, the process comprising the steps of introducing the feed gas in a reaction unit into reactor tubes with a fixed bed of a shift conversion catalyst in a reaction zone; contacting the feed gas with the catalyst at conditions being effective in carbon monoxide shift conversion reaction with steam reactant to hydrogen and cooling the reaction by indirect heat exchange with a cooling agent by passing the cooling agent in a falling film along shell side of the reactor tubes and removing heated cooling agent from the falling film; passing hydrogen when it is formed by the shift conversion reaction through a hydrogen selective membrane to a permeate zone; withdrawing hydrogen from the permeate zone and carbon monoxide depleted feed gas from the reaction zone.Type: GrantFiled: June 15, 2006Date of Patent: January 27, 2009Assignee: Haldor Topsoe A/SInventors: Thomas Rostrup-Nielsen, Erik Løgsted-Nielsen
-
Patent number: 7481859Abstract: Process for cooling an exothermic reaction zone by introducing a stream of water and a hydrocarbon-containing stream into a plurality of humidifying tubes extending through a catalytic exothermic reaction zone of a catalytic fixed bed with solid catalyst, introducing a process stream into the reaction zone for one or more catalytic exothermic reactions, passing the stream of water in a falling film along the inner circumference of the humidifying tubes, humidifying the hydrocarbon-containing stream with water in the humidifying tubes in indirect heat exchange with the exothermic reaction zone, withdrawing cooled reaction product of the exothermic reaction from the reaction zone, withdrawing the heated humidified, hydrocarbon-containing stream from the humidifying tubes, and transferring the heated humidified, hydrocarbon-containing process stream for further processing.Type: GrantFiled: February 28, 2005Date of Patent: January 27, 2009Assignee: Haldor Topsoe A/SInventors: Thomas Rostrup-Nielsen, John Bøgild Hansen
-
Patent number: 7476367Abstract: A stacked catalytic reactor is provided comprising of a plurality of housings, each housing defining a cavity having an entrance in fluid communication therewith, each housing further defining a plurality of first passages wherein each such first passage is in fluid communication with the cavity and each such first passage defines an exit. The plurality of housings are placed adjacent one to the other such that a second cavity and second passages are defined between successive housings, each second passage defines an exit, and the first passage exits and the second passage exits are interstratified and proximate one to the other. The stacked catalytic reactor employs backside cooling of a catalyst deposited therein in order to oxidize a fluid in the presence of a catalyst and transfer some heat of reaction into a second fluid and isolate the fluid to be reacted from the backside cooling fluid and then combine both fluids.Type: GrantFiled: April 20, 2005Date of Patent: January 13, 2009Assignee: Precision Combustion, Inc.Inventors: Shahrokh Etemad, Lance Smith
-
Patent number: 7473404Abstract: A device for exchange and/or reaction between at least two fluids is taught and described herein comprising at least a first space of selected thickness and including side walls defining a first chamber provided with a central part at least partly recessed for a first fluid flow and at least a second chamber for a second fluid flow, the first and second chambers being separated by a first exchanging wall adapted to ensure exchange and/or reaction between fluids of thermal and/or mass transfer type.Type: GrantFiled: October 7, 2003Date of Patent: January 6, 2009Assignees: Alfa Laval Vicarb, Electricite de France - Service NationalInventors: Fabrice Chopard, Marc Berthou, Christian Aussudre
-
Patent number: 7468167Abstract: A method for quickly starting up a reactor and a reactor system therefor are provided. A shell-and-tube reactor in the system is adapted to circulate a heat medium having a solid point in the range of 50-250° C. to the outside of the reaction tubes and characterized by initiating temperature elevation of the reactor by introducing a gas of a temperature in the range of 100-400° C. to the reaction tubes' side and then circulating the heat medium in a heated state to the outside of the reaction tubes. By introducing a gas of an elevated temperature preparatorily to the reaction tubes, it is made possible to prevent the heat medium after circulation from being solidified again and enable the reactor to be quickly started up.Type: GrantFiled: September 7, 2005Date of Patent: December 23, 2008Assignee: Nippon Shokubai Co., Ltd.Inventors: Yukihiro Matsumoto, Takeshi Nishimura, Hideki Sogabe, Kazuhiko Sakamoto, Osamu Dodo
-
Publication number: 20080292517Abstract: The present invention concerns an isothermal reactor (1) comprising a substantially cylindrical shell (2), at least one catalytic bed (10) supported in the shell (2) and at least one heat exchange unit (13) supported in the bed (10), the heat exchange unit (13) comprising a plurality of exchangers (14) substantially box shaped, of essentially elongated rectangular and flattened structure, each of the exchangers (14) having opposite long sides (14a) parallel to the cylindrical shell (2) axis and opposite short sides (14b, 14c) extended perpendicularly with respect to the shell axis and comprising furthermore an inner chamber (18) through which a heat exchange operating fluid in intended to flow, wherein at least one exchanger (14) of such at least one heat exchange unit (13) is internally equipped with a plurality of separation baffles (19) extended from a short side (14b or 14c) of the exchanger to the opposite short side (14c or 14b) and in a predetermined spaced relationship with respect to the latter, defiType: ApplicationFiled: October 31, 2006Publication date: November 27, 2008Applicant: Methanol Casale S.A.Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
-
Patent number: 7455817Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of modules stacked end-to-end along a common axis. Each module includes a shell having an interior space defining a passageway for the flow of gas from a first end of the shell to a second end of the shell opposite the first end, and a processing core being contained within the interior space for effecting a chemical, thermal, or physical change to a gas stream passing axially through the module. the multi-step process includes: providing a fuel processor having a plurality of modules stacked end-to-end along a common axis; and feeding the hydrocarbon fuel successively through each of the modules in an axial direction through the tubular reactor to produce the hydrogen rich gas.Type: GrantFiled: December 5, 2001Date of Patent: November 25, 2008Assignee: Texaco Inc.Inventors: Curtis L. Krause, James K. Wolfenbarger, Paul F. Martin
-
Patent number: 7449037Abstract: A method for carrying out endothermic or exothermic gas phase reactions by using a tube bundle reactor with a tube bundle of catalyst-filled reaction tubes comprises the following steps: a) Introducing a reaction gas mixture into the reaction tubes; b) Dividing-up of the reaction gas mixture flow flowing through each of the reaction tubes into at least two partial flows, each partial flow having the same composition; c) Feeding-in of each partial flow at a different point along the catalyst filling with an existing flow resistance; d) Determining the desired partial flow volume for each partial flow (V1, V2, V3, V4); e) Calculating the pressure at the point of the first division of the reaction gas mixture (9); f) Calculating the pressure in the catalyst filling (12) at the point of feeding-in of each partial flow (V1, V2, V3, V4); and g) Setting of flow resistance for each point of feeding-in in such a way that the flow resistance at the desired partial flow volume corresponds to the pressure difference betType: GrantFiled: August 12, 2005Date of Patent: November 11, 2008Assignee: MAN DWE GmbHInventors: Manfred Lehr, Franz Egner, Michael Claussen, Markus Maly