Unitary (i.e., Nonparticulate) Contact Bed, (e.g., Monolithic Catalyst Bed, Etc.) Patents (Class 422/222)
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Publication number: 20080257713Abstract: The present invention provides efficient catalytic reactors with active boundary layers in a presence of at least one mechanical disturbance and methods of improving the efficiency of the catalytic reaction with the use of at least one mechanical disturbance. The presence of at least one mechanical disturbance would improve the surface contact at the catalytic site and thereby increase the overall efficiency of the catalytic reactors. Such an improvement would require less catalyst material and shorter channels used, thereby decreasing the size of the catalytic reactors.Type: ApplicationFiled: April 11, 2008Publication date: October 23, 2008Inventor: Robert Woodhull Grant
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Patent number: 7438867Abstract: A honeycomb body, particularly a catalyst carrier body that serves to clean an exhaust gas of an internal combustion engine, includes a honeycomb structure joined to a casing tube by a joining techniques. The honeycomb structure is at least partially surrounded by an inner sleeve and at least partially by an outer sleeve. The inner sleeve and the outer sleeve are placed in an axial section between the casing tube and the honeycomb structure. The adjacently disposed components are joined to one another by a plurality of joining locations, and an open spring-damper system is formed by at least one sleeve. A long-life system for fixing a honeycomb structure in a casing tube is thus provided which permits thermal compensating expansions and distinctly reduces the tendency of the honeycomb structure to vibrate with regard to the casing tube. A method for producing such a honeycomb body is also provided.Type: GrantFiled: January 20, 2004Date of Patent: October 21, 2008Assignee: Emitec Gesellschaft fuer Emissionstechnologie mbHInventors: Rolf Brück, Jörg-Roman Konieczny, Lorenzo Pace
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Patent number: 7435274Abstract: There is disclosed a metal particle-dispersed composite oxide comprising a matrix material containing a composite oxide comprising a non-reducible metal oxide and an easily reducible metal oxide, the composite oxide containing 0.01 to 0.25 mol % of at least one additive metal selected from Al, Sc, Cr, B, Fe, Ga, In, Lu, Nb and Si, surface metal particles precipitated on an outer surface of the matrix material containing the composite oxide, and inner metal particles precipitated on an inner surface of the matrix material containing the composite oxide.Type: GrantFiled: February 26, 2004Date of Patent: October 14, 2008Assignee: Kabushiki Kaisha ToshibaInventors: Seiichi Suenaga, Tomohiro Suetsuna, Takayuki Fukasawa, Yasuhiro Goto, Koichi Harada
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Publication number: 20080213142Abstract: There is disclosed a membrane reactor 100 for a shift reaction including a selectively permeable membrane 3 having an H2-selective permeation ability and a catalyst 4 which promotes a chemical reaction, the selectively permeable membrane 3 is a Pd membrane or a Pd alloy membrane, the catalyst 4 is a precious metal catalyst, and the selectively permeable membrane preferably has a thickness of 20 ?m or less. The membrane reactor 100 for the shift reaction simultaneously performs inhibition of a methanation reaction and progression of a shift reaction while preventing deterioration of a thinly formed selectively permeable membrane, whereby hydrogen can efficiently be collected.Type: ApplicationFiled: March 5, 2008Publication date: September 4, 2008Applicants: NGK Insulators, Ltd., IHI CorporationInventors: Koichi Katsurayama, Koki Hamada, Toshiyuki Nakamura, Nobuhiko Mori, Akira Takahashi, Osamu Sakai
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Publication number: 20080181846Abstract: Fuel processors, methods of using fuel processors, and the like, are disclosed.Type: ApplicationFiled: November 28, 2007Publication date: July 31, 2008Applicant: Georgia Tech Research CorporationInventors: Andrei G. Fedorov, Mark Varady, F. Levent Degertekin
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Publication number: 20080181839Abstract: An array of carbon nanotubes is prepared by exposing a catalyst structure to a carbon nanotube precursor. Embodiment catalyst structures include one or more trenches, channels, or a combination of trenches and channels. A system for preparing the array includes a heated surface for heating the catalyst structure and a cooling portion that cools gas above the catalyst structure. The system heats the catalyst structure so that the interaction between the precursor and the catalyst structure results in the formation of an array of carbon nanotubes on the catalyst structure, and cools the gas near the catalyst structure and also cools any carbon nanotubes that form on the catalyst structure to prevent or at least minimize the formation of amorphous carbon. Arrays thus formed may be used for spinning fibers of carbon nanotubes.Type: ApplicationFiled: December 13, 2007Publication date: July 31, 2008Inventors: Paul N. Arendt, Ramond F. DePaula, Yuntian T. Zhu, Igor O. Usov
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Patent number: 7399452Abstract: To provide an exhaust system (100) for an internal combustion engine having a housing (10) in which there are provided at least one exhaust inlet port (15b) and another exhaust discharge port (15a), and a catalyst element (22), which is disposed within the housing (10) of the exhaust system (100) for purifying the exhaust of the internal combustion engine in such a manner that a substantial part of the exhaust at least is caused to flow through the catalyst element (22), that is readily manufacturable at a low cost and still allows for purification of the entire exhaust by the catalyst element without causing power loss to the internal combustion engine, it is suggested that the exhaust gases (27) alternately flow through the catalyst element (22) through an exhaust conducting means (17).Type: GrantFiled: June 16, 2005Date of Patent: July 15, 2008Assignee: Dolmar, GmbHInventors: Harry Radel, Markus Krueger
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Publication number: 20080159931Abstract: A catalytic reactor containing a core structure near the reactor axis and a casing structure near the reactor wall, the two structures differing from each other to promote catalysis and heat transfer, respectively. The casing contains a multiplicity of first devices for directing fluid centrifugally to impinge a reactor wall and second devices for permitting fluid to flow away from a reactor wall as the fluid flows from the inlet to the outlet of the reactor.Type: ApplicationFiled: April 27, 2007Publication date: July 3, 2008Inventor: Jonathan J. Feinstein
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Patent number: 7387651Abstract: A fuel reforming device for reforming an air-fuel mixture includes a mixing chamber to which fuel and air are introduced and which is composed such that an air-fuel mixture flows upward; a reforming reaction chamber which is arranged downstream of the mixing chamber and which includes a reforming catalyst that reforms the air-fuel mixture; an inclined surface for recovering the fuel which has not reached the inside of the reforming reaction chamber; and a fuel recovery pipe and a fuel recovery pump which are used for re-introducing unvaporized fuel and the like collected by the inclined surface to the mixing chamber.Type: GrantFiled: October 1, 2004Date of Patent: June 17, 2008Assignee: Toyota Jidosha Kabushiki KaishaInventors: Kazuhiro Sakurai, Kazuhiro Wakao
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Publication number: 20080134580Abstract: A device for providing a homogenous mixture of fuel and oxidant including an arrangement (5) for feeding liquid fuel to an evaporator, an arrangement (4) for feeding gaseous oxidant into a mixing zone (12) downstream of the evaporator, and a reaction zone downstream of the mixing zone in which a packed structure (3) is arranged. The packed structure can be a ceramic cylindrical molding having a diameter in the range 25 to 35 mm and an axial length in the range 15 to 50 mm or it can have flow conduits that are square in cross-section and have a cell density in the range 400 to 1200 cpsi.Type: ApplicationFiled: December 13, 2005Publication date: June 12, 2008Applicant: WEBASTO AGInventors: Stefan Kah, Andreas Lindermeir, Robert Engel
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Patent number: 7384613Abstract: The present invention relates to a catalyst for an internal combustion engine, particularly of a motor vehicle, with a housing, which is assembled from at least two housing portions, telescopically inserted one into another in the throughflow direction of the housing, which is assembled from two housing portions telescopically inserted one into the other. A first monolith is mounted in a first housing portion, and a second monolith is mounted in a second housing portion. In an insertion region, an outer end section of the second housing portion and an inner end section of the first housing portion inserted into the outer end section mutually overlap. A transition zone, in which the monoliths, are spaced apart from one another in the throughflow direction, is formed within the insertion region.Type: GrantFiled: April 23, 2003Date of Patent: June 10, 2008Assignee: J. Eberspacher GmbH & Co. KGInventors: Holger Prommersberger, Jochen Hägele, Georg Wirth
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Patent number: 7378066Abstract: To carry out a heterogeneously catalyzed reaction, a reaction mixture comprising hydrocarbon and water is fed onto a catalyst that is produced by compressing at least one catalyst powder into a highly compressed layer which forms a shaped body. The reaction mixture is pressed through the catalyst layer with a pressure drop.Type: GrantFiled: May 15, 2003Date of Patent: May 27, 2008Assignee: NuCellSys GmbHInventors: Martin Schuessler, Tomas Stefanovski, Detlef Zur Megede
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Publication number: 20080108715Abstract: The invention relates to a process for removing carbon monoxide from a hydrogenous gas stream by reacting the carbon monoxide with hydrogen to give methane and water in the presence of a heterogeneous catalyst. In this process, the catalyst is present in the form of a thin-layer catalyst on a support material. The invention further relates to an apparatus for carrying out the process.Type: ApplicationFiled: January 9, 2006Publication date: May 8, 2008Applicant: BASF AKTIENGESELLSCHAFTInventors: Mathias Haake, Stefan Kotrel, Michael Karcher, Rudi Blummel
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Patent number: 7361199Abstract: An apparatus removes CO from a hydrogen-rich gas stream in a hydrogen fuel cell system. CO fouls costly catalytic particles in the membrane electrode assemblies. Both a catalyst adapted to perform a water gas shift reaction, and a carbon dioxide adsorbent are disposed in a rotating pressure swing adsorber housing. The adsorption of carbon dioxide shifts equilibrium toward carbon monoxide consumption. A second adsorbent may be disposed in the housing for adsorbing carbon monoxide at low temperatures, and is adapted to desorb carbon monoxide at high temperatures. The present invention advantageously eliminates a unit operation from a space-constrained fuel cell vehicle by combining the WGS catalyst and a CO2 adsorbent in a single reactor/housing. The apparatus further eliminates the use of a PROX reactor, by providing an apparatus which incorporates CO2 adsorption and consequent carbon monoxide consumption in the place of the PROX reactor.Type: GrantFiled: January 7, 2004Date of Patent: April 22, 2008Assignee: General Motors CorporationInventors: Craig S Gittleman, Ramesh Gupta
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Patent number: 7354465Abstract: Devices for cooling and humidifying a reformate stream from a reforming reactor as well as related methods, modules and systems includes a heat exchanger and a sprayer. The heat exchanger has an inlet, an outlet, and a conduit between the inlet and the outlet. The heat exchanger is adapted to allow a flow of a first fluid (e.g. water) inside the conduit and to establish a heat exchange relationship between the first fluid and a second fluid (e.g. reformate from a reforming reactor) flowing outside the conduit. The sprayer is coupled to the outlet of the heat exchanger for spraying the first fluid exiting the heat exchanger into the second fluid.Type: GrantFiled: June 20, 2005Date of Patent: April 8, 2008Assignee: Nuvera Fuel Cells, Inc.Inventors: Jian Lian Zhao, William F. Northrop
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Publication number: 20080072578Abstract: Emissions treatment systems and methods are disclosed, which reduce the carbon monoxide, unburned hydrocarbons, and nitrogen oxides content in the exhaust stream of an internal combustion engine adjusted to a rich combustion ratio. One embodiment of a system comprises an ammonia oxidation catalyst, a supplemental air supply for providing a lean combustion ratio, and at least one three-way catalyst. Another embodiment further comprises a second three-way catalyst located in the exhaust stream.Type: ApplicationFiled: September 20, 2007Publication date: March 27, 2008Inventor: Sanath V. Kumar
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Patent number: 7341610Abstract: A fuel cell system includes a fuel cell unit and a gas-generating system containing at least one reforming unit for obtaining a hydrogen-rich reformate from a fuel. It is possible to supply the reformate at least partly to the anode side of the fuel cell unit. The system may include a first reforming reactor for producing a first reformate with a high outlet temperature; a second reforming reactor for producing a second reformate with a second outlet temperature which is below the first outlet temperature; a mixing element for mixing the first reformate with at least one fuel and located between an outlet of the first reforming reactor and an inlet of the second reforming reactor. The second reformate may be supplied to a gas-purification system and the purified reformate supplied to the fuel cell unit.Type: GrantFiled: June 3, 2005Date of Patent: March 11, 2008Assignee: NuCellSys GmbHInventor: Uwe Griesmeier
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Patent number: 7332139Abstract: Reactions between at least two fluid reactants are performed in a reactor comprising wall elements (1), slot-shaped reaction spaces (3) and cavities (5) for conducting a fluid heat-carrier through. Depending on the process and throughput, a modular structural design is chosen wherein an arbitrary number of wall elements (1) are assembled to a right-parallelepipedal block (24), the reaction spaces (3) are formed between lateral surfaces (2) of right-parallelepipedal wall elements (1), the reactants are introduced into the reaction spaces (3) from edge regions of one side of the block (24) and are conducted through the reaction spaces (3) in parallel flows and the fluid heat-carrier is conducted through the tubular cavities (5) extending in the interior of the wall elements (1).Type: GrantFiled: August 22, 2001Date of Patent: February 19, 2008Assignee: Degussa AGInventors: Rüdiger Schütte, Torsten Balduf, Catrin Becker, Ina Hemme, Birgit Bertsch-Frank, Werner Wildner, Jürgen Rollmann, Georg Markowz
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Patent number: 7326265Abstract: The invention concerns a method for cleaning the upstream surface (14) of a particulate filter (10) of a heat engine exhaust line, the filter (20) being arranged in a casing (12) having an outlet (22) for exhaust gases. The method comprises a step which consists in circulating a liquid flux through the particulate filter (10) from its downstream surface (18) towards its upstream surface (14) viewed from the direction of exhaust gas flow in the filter. The liquid flux circulated through the particulate filter (10) has a flow rate higher than 50 litres/minute and is distributed over the main part of the downstream surface (18) of the particulate filter.Type: GrantFiled: October 12, 2001Date of Patent: February 5, 2008Assignee: Faurecia Systemes d'EchappementInventors: Jean-Philippe Zilliox, Bertrand Figueras
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Patent number: 7323148Abstract: A hydrogen generator capable of operating in any orientation and having no moving parts includes a catalyst retaining structure. The catalyst retaining structure is disposed in a housing and serves to separate the housing into a fuel holding portion and a hydrogen chamber. The catalyst retaining structure also includes one or more pores, each pore being in communication with the fuel holding and hydrogen chambers. A catalyst, that promotes the generation of hydrogen gas upon contact with the fuel, is disposed within the pores. The fuel enters the pores and thereupon generates hydrogen gas which passes into the hydrogen chamber. Contact of the fuel with the catalyst in the pores may be controlled and the position of the fuel-hydrogen interface within the pore may be moved so as to regulate the generation of hydrogen. The catalyst retaining structure can take different forms, including one or more hollow elongated members or plates, and may further incorporate hydrophobic and/or hydrophilic membranes.Type: GrantFiled: November 5, 2003Date of Patent: January 29, 2008Assignee: Millennium Cell, Inc.Inventors: Shailesh A. Shah, Michael T. Kelly
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Patent number: 7318276Abstract: A process and an apparatus for producing a honeycomb body include forming a metallic honeycomb structure having cavities through which a fluid can at least partially flow, and bringing at least one end side of the honeycomb structure into contact with a metallic melt having a lower melting point than the metallic honeycomb structure. The process and the apparatus allow layers of sheet metal to be intimately and permanently joined in an advantageous manner in joining regions by placing at least one end face of a honeycomb structure of the honeycomb body in contact with a metallic melt which has a lower melting point than the honeycomb structure and contains aluminum, for example. A honeycomb body which is produced by the method or the apparatus is also provided.Type: GrantFiled: February 22, 2005Date of Patent: January 15, 2008Assignee: Emitec Gesellschaft Fuer Emissionstechnologie mbHInventors: Rolf Brück, Arndt-Udo Rolle
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Patent number: 7316718Abstract: An arrangement for generating hydrogen gas utilizes differential pressure to transport fuel and spent fuel components without requiring an electrically powered fuel delivery pump.Type: GrantFiled: July 11, 2001Date of Patent: January 8, 2008Assignee: Millennium Cell, Inc.Inventors: Steven C. Amendola, Richard M. Mohring, Phillip J. Petillo, Keith A. Fennimore, Stephen C. Petillo
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Patent number: 7311751Abstract: A filter medium includes at least a first and a second layer. Both first and second layers have a layer volume VLq and a layer filtering surface SLq, where SLq is the accumulation of all mantle surfaces of the fibers present in this layer q. The first layer has a SL1/VL1-ratio of less than 32500 m2/m3, and the second layer has a SL2/VL2-ratio being more than 1.1×SL1/VL1.Type: GrantFiled: December 5, 2002Date of Patent: December 25, 2007Assignee: NV Bekaert SAInventors: Feng Mei, Willy Marrecau
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Publication number: 20070274883Abstract: The present invention relates to a catalytic converter element having a plurality of essentially parallel channels through which gas flows during operation of the catalytic converter element. The channels are bordered by channel walls which have a catalytically active coating arranged thereon in at least some areas where it is exposed to the gas. In some channels the coating thus begins with an axial offset from the admission end. This allows an improved temperature management within the catalytic converter element.Type: ApplicationFiled: May 22, 2007Publication date: November 29, 2007Inventor: Guenter Eberspach
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Patent number: 7300635Abstract: A catalytic reactor comprises a plurality of fluid-impermeable plates defining flow channels between them. Tight fitting within each flow channel is a sheet of corrugated material whose surfaces are coated with catalytic material. At each end of the flow channels are headers to supply gas mixtures to the flow channels, the headers communicating with adjacent channels being separate. The reactor enables different gas mixtures to be supplied to adjacent channels, which may be at different pressures, and the corresponding chemical reactions are also different. Where one of the reactions is endothermic while the other reaction is exothermic, heat is transferred through the wall of the tube separating the adjacent channels, from the exothermic reaction to the endothermic reaction.Type: GrantFiled: January 10, 2001Date of Patent: November 27, 2007Assignee: CompactGTL PLCInventors: Michael Joseph Bowe, John William Stairmand, Ian Frederick Zimmerman, Jason Andrew Maude
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Patent number: 7297249Abstract: A fixed-bed reactor is described for carrying out reactions of fluid reaction mixtures in the presence of a particulate heterogeneous catalyst having a structured packing which forms interstices in the reactor interior, in which the quotient of the hydraulic diameter for the fluid flow through the structured packing and the equivalent diameter of the catalyst particles is in the range from 2 to 20, preferably in the range from 5 to 10, to such an extent that the catalyst particles are introduced into the interstices, loosely distributed and discharged under the action of gravity.Type: GrantFiled: December 4, 2002Date of Patent: November 20, 2007Assignee: BASF AktiengesellschaftInventors: Gerd Kaibel, Christian Miller, Helmut Jansen, Björn Kaibel
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Patent number: 7294317Abstract: A reactor and heat exchanger assembly is provided with the heat exchanger integrally affixed to the reactor exit head and adapted to immediately cool reactor gases from the reactor.Type: GrantFiled: February 8, 2001Date of Patent: November 13, 2007Assignee: SD Lizenzverwertungsgesellschaft mbH & Co.Inventors: Barry Billig, Bhupendra Ranibhai Baria
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Publication number: 20070258872Abstract: A compact catalytic reactor defines a multiplicity of first and second flow channels arranged alternately, the first flow channels being no more than 10 mm deep and providing flow paths for combustible reactants, and containing a catalyst structure (20) to catalyse combustion of the reactants, and having at least one inlet for at least one of the reactants. The first flow channel also includes an insert (40 or 60) adjacent to each inlet, this insert not being catalytic to the combustion reaction; the insert may define gaps which are narrower than the maximum gap size for preventing flame propagation.Type: ApplicationFiled: April 26, 2007Publication date: November 8, 2007Applicant: COMPACTGTL PLCInventors: David James West, Michael Joseph Bowe, Robert Frew Gillespie, Steven Brabon, Robert Peat
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Patent number: 7288231Abstract: The present invention provides chemical reactors and reaction chambers and methods for conducting catalytic chemical reactions having gas phase reactants. In preferred embodiments, these reaction chambers and methods include at least one porous catalyst material that has pore sizes large enough to permit molecular diffusion within the porous catalyst material.Type: GrantFiled: November 21, 2003Date of Patent: October 30, 2007Assignee: Battelle Memorial InstituteInventors: Anna Lee Y. Tonkovich, Yong Wang, Sean P. Fitzgerald, Jennifer L. Marco, Gary L. Roberts, David P. VanderWiel, Robert S. Wegeng
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Patent number: 7282073Abstract: Hydrogen is generated through the use of a fuel solution that is prepared using solid fuel component, e.g., a metal borohydride, and a liquid fuel component, e.g. water. Both of these components are dispensed in response to control signals. The solid fuel component can take different forms, including but not limited to granules, pellets and powder. Various devices, which operate in response to control signals, are disclosed for dispensing predetermined amounts of the solid and liquid components. Advantageously, this solution can be prepared, as needed, so as to obviate the need for storing and disposing of large amounts of highly alkaline fuel and discharged fuel solutions.Type: GrantFiled: April 2, 2002Date of Patent: October 16, 2007Assignee: Millennium Cell, Inc.Inventors: Phillip J. Petillo, Stephen C. Petillo
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Patent number: 7278542Abstract: The invention concerns a filtering medium based on a photocatalytic agent and activated carbon, characterized in that it comprises a permeable support covered with a first layer based on activated carbon, then a separate second layer based on a photocatalytic agent, or vice versa. The invention also concerns a method for making such a filtering medium.Type: GrantFiled: February 12, 2003Date of Patent: October 9, 2007Assignee: Ahlstrom Research and ServicesInventors: Joseph Dussaud, Leonie Bouvier, Fabien Chevalier
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Patent number: 7276214Abstract: A chemical reactor is disclosed and which has a core composed of a stack of metal plates that are diffusion bonded in face-to-face relationship. A plurality of reaction zones are located within the core, as are a plurality of catalyst receiving zones, and both the reaction zones and the catalyst receiving zones are defined by respective aligned apertures in the plates. A first channel arrangement is provided in some of the plates for transporting a first reactant to and between the reaction zones, portions of the first channel arrangement that interconnect the reaction zones being formed over at least a portion of their length as heat exchange channels. A second channel arrangement is provided in others of the plates and is arranged to deliver a second reactant to each of the reaction zones.Type: GrantFiled: January 3, 2003Date of Patent: October 2, 2007Assignee: Meggit (UK) Ltd.Inventors: Anthony Matthew Johnston, Brian Scott Haynes
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Fuel processor module for hydrogen production for a fuel cell engine using pressure swing adsorption
Patent number: 7276095Abstract: A stand-alone fuel processor (10) for producing hydrogen from a hydrocarbon fuel for a fuel cell engine in a vehicle. The fuel processor (10) includes a primary reactor (14) that dissociates hydrogen and other by-products from the hydrocarbon fuel as a reformate gas. The reformate gas is applied to a WGS reactor (48) to convert carbon monoxide and water to hydrogen and carbon dioxide. The WGS reactor (14) may include an adsorbent for adsorbing carbon monoxide. The reformate gas from the WGS reactor (48) is then sent to a rapid-cycle PSA device (12) for adsorbing the undesirable by-products in the gas and generates a stream of pure hydrogen. A liquid water separator (70) separates water from the reformate gas before it is applied to the PSA device (12). The PSA device (12) uses a portion of the separated hydrogen as a desorbing gas to purify the adsorbent in the PSA device (12). The by-products of the reformate gas can be used as a fuel in a combustor (30) that generates heat for the primary reactor (14).Type: GrantFiled: March 14, 2003Date of Patent: October 2, 2007Assignee: General Motors CorporationInventors: Craig S. Gittleman, John B. Ruhl, Yan Zhang, William H. Pettit -
Patent number: 7270689Abstract: A reformer for reacting a raw material gas to be reformed, with an oxidizing agent gas and a reforming agent gas in the presence of an oxidation catalyst and a reforming catalyst to obtain a hydrogen-containing gas, including: a set of catalyst layers consisting of an oxidation catalyst layer and a reforming catalyst layer, and two or more inlets for feeding the oxidizing agent gas to the oxidation catalyst and/or the reforming catalyst in plural stages. The reformer can produce a hydrogen-containing gas without forming a combustion region of a temperature of as high as one thousand and several hundreds centigrade and can be manufactured at a low cost.Type: GrantFiled: July 14, 2004Date of Patent: September 18, 2007Assignees: Toyo Engineering Corporation, K. E. M. CorporationInventors: Hidetsugu Fujii, Fumitake Watanabe, Katsuya Uehara, Yukuo Katayama
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Patent number: 7267804Abstract: The membrane reactor of the present invention generates a desired gas such as hydrogen produced by steam reforming liquid fuels. The membrane reactor provides thermal integration between the heating source and the reaction catalyst by heat conduction through a solid medium. A gas purification system extracts energy from the waste gases to heat the membrane reactor. This, in concert with other control mechanisms provided results in a more efficient gas purification process.Type: GrantFiled: February 27, 2002Date of Patent: September 11, 2007Inventor: Robert E. Buxbaum
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Patent number: 7261866Abstract: The CO remover of this invention includes an air mixer for mixing air with hydrogen-rich gas including carbon monoxide and a selective oxidative catalytic device in which a selective oxidative catalyst bed is formed by filling selective oxidative catalyst into a gas passing tube. The selective oxidative catalytic device includes a gas blending unit for blending gas passing through the central part of the gas passing tube with gas passing through the peripheral part at a point in the selective oxidative catalyst bed in the direction of gas flow. As a result, the reaction apparatus and the CO remover have simple structures. In addition, gas passing through the central part upstream is blended with gas passing through the peripheral part upstream to uniformize the temperature of gas in the gas blending unit, so that high CO selectivity is obtained.Type: GrantFiled: February 18, 2000Date of Patent: August 28, 2007Assignee: Sanyo Electric Co., LtdInventors: Masataka Kadowaki, Yasuo Miyake
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Patent number: 7258845Abstract: A safe, reduced pressure apparatus for generating water vapor from hydrogen and oxygen and feeding high purity moisture to processes such as semiconductor production. The apparatus eliminates the possibility of the gas igniting by maintaining the internal pressure of the catalytic reactor for generating moisture at a high level while supplying moisture gas from the reactor under reduced pressure. A heat dissipation reactor improvement substantially increases moisture generation without being an enlargement in size by efficient cooling of the reactor alumite-treated fins.Type: GrantFiled: February 2, 2001Date of Patent: August 21, 2007Assignee: Fujikin IncorporatedInventors: Tadahiro Ohmi, Nobukazu Ikeda, Yukio Minami, Kouji Kawada, Katunori Komehana, Teruo Honiden, Touru Hirai, Akihiro Morimoto, Toshirou Nariai, Keiji Hirao, Masaharu Taguchi, Osamu Nakamura
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Patent number: 7258843Abstract: An assembly includes a honeycomb body secured by an inner casing tube in a housing, in particular a housing of an exhaust system of an internal combustion engine. The inner casing tube has an overall length which is bounded axially by two edges and is substantially smaller than the axial length of the honeycomb body. The inner casing tube is also disposed in an approximately axially central position around the honeycomb body and is connected, in particular brazed, thereto in at least one axial connection region. The inner casing tube has a region within the axial connection region in which it is connected to the honeycomb body on the inside or attached directly adjacent the latter on the outside and is connected to the housing. Regions of the inner casing tube which are not connected to the housing but are connected to the honeycomb body toward the inside are constructed as radially elastic spring elements.Type: GrantFiled: March 3, 2003Date of Patent: August 21, 2007Assignee: Emitec Gesellschaft fuer Emissionstechnologie GmbHInventors: Rolf Brück, Jörg-Roman Konieczny, Katrin Schaper, Wolfgang Maus
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Patent number: 7252809Abstract: A honeycomb body for the chemical conversion of at least one component of a gas stream, in particular an exhaust-gas stream from an internal combustion engine, includes an inflow passage having an axis, and sheet-metal layers. At least some of the sheet-metal layers are structured to form two sets of crests and passages through which the gas stream can flow. Each of the sets of crests of each of the sheet-metal layers define a respective plane. The sheet-metal layers are segmented in circumferential direction of the honeycomb body. The axis and the plane include an angle of between 45° and 135°, preferably between 70° and 110°. The radial honeycomb body is particularly easy to produce.Type: GrantFiled: May 14, 2003Date of Patent: August 7, 2007Assignee: Emitec Gesellschaft fuer Emissionstechnologie mbHInventors: Rolf Brück, Jörg Zimmermann
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Patent number: 7235218Abstract: A compact catalytic reactor comprises a stack of plates (72, 74, 75) to define a multiplicity of first and second flow channels arranged alternately in the stack; each flow channel in which a chemical reaction is to take place is defined by straight-through channels across at least one plate, each such straight-through channel containing a removable gas-permeable catalyst structure (80) incorporating a metal substrate. The first flow channels (76) are oriented in a direction that is perpendicular to that of the second flow channels (77), and between successive second flow channels in the stack the reactor defines at least three side-by-side first flow channels (76); and the reactor incorporates flow diversion means (80; 88) such that the first fluid must flow through at least three such first flow channels (76) in succession, in flowing from an inlet to an outlet. The overall flow paths can therefore be approximately co-current or counter-current.Type: GrantFiled: April 14, 2005Date of Patent: June 26, 2007Assignee: Compactgtl PLCInventor: Michael Joseph Bowe
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Patent number: 7232848Abstract: An apparatus for converting a gaseous and/or liquid feed fluid to gaseous and/or liquid products using a solid catalyst comprises a reactor, a liquid phase disposed within the reactor volume, a fixed catalyst at least partially disposed in the liquid phase, a cooling system having a cooling element in thermal contact with the liquid phase, a feed inlet positioned to feed the feed fluid into the reactor volume, and a fluid outlet in fluid communication with the liquid phase. The catalyst is contained in a catalyst container and the container may be adjacent to said cooling element, extend through said cooling element, or may surround the catalyst container. The catalyst may be a Fischer-Tropsch catalyst.Type: GrantFiled: September 9, 2002Date of Patent: June 19, 2007Assignee: ConocoPhillips CompanyInventors: Sergio R. Mohedas, Rafael L. Espinoza, Jianping Zhang
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Patent number: 7229598Abstract: A honeycomb body, which is composed in such a manner that a strip of corrugated foil made of heat-resistant stainless steel containing aluminum and a strip of flat foil made of stainless steel are alternately wound or laminated on each other, is incorporated into an outer cylinder made of metal and integrated into one body by means of diffusion bonding, so that a diffusion bonded metallic catalyst carrier can be formed. Surface roughness of the strip of foil after the completion of diffusion bonding is 0.001 to 2.0 ?m when it is expressed by center line average height Ra, and no sintered bridges are formed at both end portions of the diffusion bonded section in the longitudinal direction. The catalyst carrier is manufactured in a condition so that ?b, which is defined by ?b=6.Type: GrantFiled: April 23, 2004Date of Patent: June 12, 2007Assignee: Nippon Steel CorporationInventors: Yasuo Takahashi, Tadayuki Otani, Kazutoshi Iwami, Masayuki Kasuya
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Patent number: 7223373Abstract: A catalytic reactor comprises a plurality of sheets defining flow channels between then. Within each flow channel is a foil of corrugated material whose surfaces are coated with catalytic material. The flow channels extend in transverse dire options, but the foils are shaped to cause the gas in those channels to flow at least partly in counter current to the gas flowing in the other channels. The reactor incorporates header chambers to supply gas mixtures to the flow channels, each header being in the form of a cap attached to the outside of the back and covering a face of the stack. Hence different gas mixtures are supplied to the different channels which may be at different pressures, and the corresponding chemical reactions are also different, and heat is transferred through the sheets separating the adjacent channels. When the catalyst in one set of flow channels becomes spent, it can be replaced by removing a header.Type: GrantFiled: September 23, 2002Date of Patent: May 29, 2007Assignee: Compactgtl PLCInventor: Jason Andrew Maude
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Patent number: 7220290Abstract: The present invention relates to a composition and method for storage and controlled release of hydrogen. In particular, the present invention relates to the use of borohydride based solutions as a hydrogen storage source and a catalyst system to release hydrogen therefrom.Type: GrantFiled: August 11, 2003Date of Patent: May 22, 2007Assignee: Millennium Cell, Inc.Inventors: Steven C. Amendola, Michael Binder, Stefanie L. Sharp-Goldman, Michael T. Kelly, Phillip J. Petillo
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Patent number: 7214352Abstract: A cylindrical reactor containing a radial particle bed suitable for hydrocarbon reforming comprises: a reactor inlet (1) having a means of feeding a charge, numerous perforated, internal conduits (5) arranged around the periphery of the reactor and parallel to the axis of the reactor, which feed particle bed (2) with the charge, a circular collar (8) supporting the conduits in the lower bottom of the reactor, a perforated (7) central collector (3) receiving a reactor effluent connected to an outlet (14).Type: GrantFiled: March 10, 2003Date of Patent: May 8, 2007Assignee: Institut Francais du PetroleInventor: Bernard Poussin
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Patent number: 7211228Abstract: A heater is disposed in contact with a hydrogen storage unit filled with a hydrogen absorption material. The heater includes at least one combustion chamber which includes a catalyst carrier and in which a combustible gas is burned, a combustible gas burning catalyst carried on the catalyst carrier, at least one combustible gas introduction chamber adjoining the combustion chamber with its chamber wall interposed therebetween, a plurality of combustible gas inlets disposed in a dispersed manner in the chamber wall to permit the combustion chamber and the introduction chamber to communicate with each other, and a combustion gas outlet communicating with the combustion chamber. Thus, the degree of uniformity of a temperature profile is decreased.Type: GrantFiled: March 20, 2002Date of Patent: May 1, 2007Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Takanori Suzuki, Fumiaki Aono, Manabu Ito, Izuru Kanoya, Mitsuya Hosoe
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Patent number: 7201883Abstract: A catalytic reactor comprises a plurality of sheets defining flow channels between them. Within each flow channel is a foil of corrugated material whose surfaces are coated with catalytic material. Flow channels for a first gas extend in oblique directions relative to the flow channels for a second gas. The reactor incorporates header chambers to supply gas mixtures to the flow channels, the headers communicating with adjacent channels being separate. The reactor enables different gas mixtures to be supplied to adjacent channels, which may be at different pressures, and the corresponding chemical reactions are also different. Where one of the reactions is endothermic while the other reaction is exothermic, heat is transferred through the sheets separating the endothermic reaction. When the catalyst in one set of flow channels becomes spent, it can be replaced by removing a header.Type: GrantFiled: September 12, 2002Date of Patent: April 10, 2007Assignee: Compactgtl PLCInventors: Michael Joseph Bowe, Clive Derek Lee-Tuffnell
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Patent number: 7189271Abstract: A catalytic reactor comprises a plurality of thin tray-like metal sheets each with a peripheral rim and arranged as a stack to define first gas flow channels between adjacent sheets, alternating with second gas flow channels between adjacent sheets, so as to ensure good thermal contact between gases in the first and the second gas flow channels. Each sheet also defines at least four apertures for flow of gases, and tubes and seal apertures in one sheet to corresponding apertures in the adjacent sheet. The gas flows through the channels may be guided by corrugations, and are preferably in countercurrent in adjacent channels. Appropriate catalysts are coated onto the sheets and in the two gas flow channels.Type: GrantFiled: September 23, 2002Date of Patent: March 13, 2007Assignee: Compactgtl PLCInventor: Jason Andrew Maude
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Patent number: 7189270Abstract: A method and apparatus for conversion of solid and liquid fuels to a synthesis gas, steam and/or electricity in which about 10% to about 40% of a solid fuel and/or a liquid fuel is introduced into a gasifier and gasified, resulting in formation of a synthesis gas. The remaining portion of the solid fuel and/or liquid fuel is introduced into a first stage of a multi-stage combustor, resulting in formation of products of combustion and ash and/or char. The synthesis gas is introduced into a second stage of the multi-stage combustor disposed downstream of the first stage and overfire oxidant is introduced into a third stage of the multi-stage combustor disposed downstream of the second stage. The ash and/or char from the multi-stage combustor is then recycled into the gasifier.Type: GrantFiled: December 10, 2001Date of Patent: March 13, 2007Assignee: Gas Technology InstituteInventors: Bruce Bryan, Iosif Rabovitser
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Patent number: 7186388Abstract: A catalytic reactor comprises a stack of sheets defining flow channels between them. Within each flow channel is a flexible wire structure whose surfaces are coated with catalytic material. Flow channels for a first gas extend along S-shaped curved paths whereas the flow channels for a second gas are straight. The reactor incorporates header chambers to supply gas mixtures to the flow channels, each header chamber being a rectangular cap attached to a face of the stack. The reactor enables different gas mixtures to be supplied to adjacent channels, which nay be at different pressures, and the corresponding chemical reactions are also different. Where one of the reactions is endothermic while the other reaction is exothermic, heat is transferred through the sheets separating the adjacent channels, from the exothermic reaction to the endothermic reaction. When the catalyst in one set of flow channels becomes spent, it can be replaced by removing a header.Type: GrantFiled: October 3, 2002Date of Patent: March 6, 2007Assignee: Compactgtl PLCInventors: Michael Joseph Bowe, Jason Andrew Maude