Utilizing As Solid Sorbent, Catalyst, Or Reactant A Material Containing A Transition Element Patents (Class 423/213.2)
  • Patent number: 10513436
    Abstract: Methods, systems and apparatus relate to producing synthesis gas or carbon and hydrogen utilizing a reduced catalyst CuO—Fe2O3. The method comprises introducing CH4; reducing the CuO—Fe2O3 with the introduced CH4, yielding at least a reduced metal catalyst; oxidizing the reduced metal with O2 yielding CuO—Fe2O3; and generating heat that would be used for the hydrogen and carbon or syngas production with the reduced catalyst CuO—Fe2O3.
    Type: Grant
    Filed: December 12, 2016
    Date of Patent: December 24, 2019
    Assignee: U.S. Department of Energy
    Inventors: Ranjani Siriwardane, Hanjing Tian
  • Patent number: 10507457
    Abstract: The present invention relates to a honeycomb structure having promoter particles and a binder phase interposed between the promoter particles, and a method for manufacturing the same. The promoter particles contain at least first promoter particles made of a ceria-zirconia solid solution. The binder phase, in each of which a number of inorganic binder particles are aggregated with each other, with ?-alumina being a main component, contain one or two of Fe and Cr dissolved in ?-alumina. The honeycomb structure has a specific surface area at a ratio of 90% or more of after heating to before heating at a temperature of 1200° C.
    Type: Grant
    Filed: April 20, 2016
    Date of Patent: December 17, 2019
    Assignee: DENSO CORPORATION
    Inventors: Youichi Kadota, Yasushi Takayama
  • Patent number: 10501347
    Abstract: A method of treating water to oxidize organic contaminants comprises heat transfer system includes heating liquid water to a temperature of at least 190° F. at a pressure to keep the heated water in a liquid phase, and contacting the heated water with oxygen and an oxidation catalyst including a noble metal on a porous support comprising a bi-modal pore size distribution including pore sizes from 1 nm to 20 nm and pore sizes from 100 nm to 1000 nm. The resulting catalytic oxidation of the organic contaminants results in the release of gaseous reaction products resulting from the oxidation reaction, which are separated from the treated water in a phase separator to produce a treated water final product.
    Type: Grant
    Filed: November 30, 2015
    Date of Patent: December 10, 2019
    Assignee: HAMILTON SUNDSTRAND SPACE SYSTEMS INTERNATIONAL, INC.
    Inventors: Ping Yu, Timothy A. Nalette
  • Patent number: 10500562
    Abstract: A passive NOX adsorbent includes: palladium, platinum or a mixture thereof and a mixed or composite oxide including the following elements in percentage by weight, expressed in terms of oxide: 10-90% by weight zirconium and 0.1-50% by weight of least one of the following: a transition metal or a lanthanide series element other than Ce. Although the passive NOX adsorbent can include Ce in an amount ranging from 0.1 to 20% by weight expressed in terms of oxide, advantages are obtained particularly in the case of low-Ce or a substantially Ce-free passive NOx adsorbent.
    Type: Grant
    Filed: April 5, 2018
    Date of Patent: December 10, 2019
    Assignees: Magnesium Elektron Ltd., University of Kentucky Research Foundation
    Inventors: Deborah Jayne Harris, David Alastair Scapens, John G. Darab, Mark Crocker, Yaying Ji
  • Patent number: 10456746
    Abstract: A selective catalytic reduction filter (SCRF) including a wall-flow substrate having inlet channels and outlet channels is provided. A first selective catalytic reduction (SCR) catalyst zone is present in the inlet channels, and a second SCR catalyst zone is present in the outlet channels. The first SCR catalyst zone includes an iron-exchanged zeolite catalyst, and the second SCR catalyst zone includes a copper-exchanged zeolite catalyst. Exhaust gas treatment systems including the SCRF and methods of reducing production of nitrous oxide (N2O) during selective catalytic reduction of an exhaust gas stream using the SCRF are also provided herein.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: October 29, 2019
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Shouxian Ren, Gongshin Qi
  • Patent number: 10458368
    Abstract: An exhaust gas system for a gasoline engine with an exhaust gas pipe connectible to an outlet manifold, with an inlet pipe connectible to an inlet manifold, whereas a main exhaust catalyst is provided within the exhaust gas pipe wherein at least one first exhaust gas recirculation pipe is provided which branches off from the exhaust gas pipe and ends in the inlet pipe, whereas at least one particle filter is positioned within the first exhaust gas recirculation pipe and/or within the exhaust gas pipe upstream of the first exhaust gas recirculation pipe, wherein optionally at least a second exhaust gas recirculation pipe is provided, whereas at least one particle filter is provided which is positioned within the second exhaust gas recirculation pipe and/or which is positioned within the exhaust gas pipe upstream of the second exhaust gas recirculation pipe.
    Type: Grant
    Filed: May 26, 2015
    Date of Patent: October 29, 2019
    Assignee: TENNECO GMBH
    Inventor: Michael Fischer
  • Patent number: 10449494
    Abstract: Method for determining a true amount of active product entering a catalytic device of a vehicle exhaust line includes: introducing, into the exhaust gas stream upstream of the device, an active flow rate of active product so that the contaminant and active product are absent at the measurement probe at the outlet of the device, increasing the active flow rate until the second probe measures a given escape content of the product, stabilizing the escape of product, via the measurement provided by the probe, at the given escape content, introducing a theoretical additional test flow rate of product into the exhaust gas stream upstream of the device, waiting until the total content of product measured in response at the second probe has stabilized, and measuring this stabilized total content, and determining the stabilized true additional test flow rate of active product entering the device.
    Type: Grant
    Filed: April 14, 2014
    Date of Patent: October 22, 2019
    Assignees: CONTINENTAL AUTOMOTIVE FRANCE, CONTINENTAL AUTOMOTIVE GMBH
    Inventor: Steven Maertens
  • Patent number: 10434471
    Abstract: Active catalysts for the treatment of a low temperature exhaust gas stream are provided containing copper oxides dispersed on a spinel oxide for the direct, lean removal of nitrogen oxides from the exhaust gas stream. The low temperature, direct decomposition is accomplished without the need of a reductant molecule. In one example, CuOx may be dispersed as a monolayer on a metal oxide support, such as Co3O4 spinel oxide, synthesized using an incipient wetness impregnation technique. The CuOx/Co3O4 catalyst system converts nitric oxide to nitrogen gas with high product specificity, avoiding the production of a significant concentration of the undesirable N2O product.
    Type: Grant
    Filed: April 17, 2017
    Date of Patent: October 8, 2019
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Torin C. Peck, Michael Jones, Krishna R. Gunugunuri, Charles Alexander Roberts
  • Patent number: 10428708
    Abstract: The present invention relates to a nitrogen oxide storage catalyst composed of at least two catalytically active washcoat layers on a support body, wherein a lower washcoat layer A comprises cerium oxide, an alkaline earth metal compound and/or an alkali metal compound, and platinum and palladium, and an upper washcoat layer B disposed atop the washcoat layer A comprises cerium oxide, platinum and palladium, and no alkali metal or alkaline earth metal compound, and to a method of converting NOx in exhaust gases from motor vehicles which are operated with lean-burn engines.
    Type: Grant
    Filed: August 4, 2015
    Date of Patent: October 1, 2019
    Assignee: UMICORE AG & CO. KG
    Inventors: Thomas Utschig, Ruediger Hoyer, Elena Mueller
  • Patent number: 10428717
    Abstract: Provided is a method for diagnosing whether an oxidation catalyst has degraded, based on an output value from one diagnostic sensor with higher accuracy. When a ratio of nitrogen monoxide that is oxidized by a catalyst and discharged downstream of the catalyst as nitrogen dioxide, with respect to nitrogen monoxide contained in an exhaust gas supplied upstream of the catalyst in an exhaust path is defined as a NO conversion rate, a diagnostic sensor configured to output an electromotive force corresponding to the NO conversion rate as a diagnostic output is provided downstream of the catalyst in the exhaust path, and whether the catalyst has degraded beyond an acceptable limit is diagnosed by comparing the diagnostic output with a threshold value predetermined depending on a temperature of the catalyst.
    Type: Grant
    Filed: July 3, 2017
    Date of Patent: October 1, 2019
    Assignee: NGK Insulators, Ltd.
    Inventors: Kosuke Monna, Taku Okamoto, Noriko Hirata
  • Patent number: 10407314
    Abstract: A process of manufacturing a chabazite-type zeolite is provided having high heat resistance without having a large crystal size. A catalyst is also provided that contains such a chabazite-type zeolite and exhibits high nitrogen oxide reduction properties, and in particular high nitrogen oxide reduction properties in low temperatures below 200° C., even after exposure to high temperature and high humidity. A chabazite-type zeolite is provided having a silica to alumina molar ratio of no less than 15, a silanol group to silicon molar ratio of no more than 1.6×10?2, an average crystal size of 0.5 ?m to less than 1.5 ?m, and a ratio of 50%-volume particle size to 10%-volume particle size of no more than 3.2. The chabazite-type zeolite preferably contains at least one of copper and iron.
    Type: Grant
    Filed: February 20, 2018
    Date of Patent: September 10, 2019
    Assignee: TOSOH CORPORATION
    Inventors: Keita Nakao, Ko Ariga, Hidekazu Aoyama, Satoshi Nakamura
  • Patent number: 10392994
    Abstract: An aftertreatment system comprises a first passageway having a first temperature and a second passageway having a second temperature different than the first temperature. A turbine is disposed downstream from the first passageway and upstream from the second passageway. The turbine is in fluidic communication with the first passageway and the second passageway. The turbine is structured to receive an exhaust gas from the first passageway, generate energy using the exhaust gas flowing through the turbine and communicate the exhaust gas to the second passageway. The aftertreatment system also includes an insertion device structured to insert an exhaust reductant into the first passageway. A selective catalytic reduction system is configured to receive the exhaust gas from the second passageway and treat the exhaust gas. The first temperature can be higher than the second temperature.
    Type: Grant
    Filed: December 2, 2015
    Date of Patent: August 27, 2019
    Assignee: Cummins, Inc.
    Inventors: John K. Heichelbech, John G. Buechler, Richard J. Ancimer, Thomas M. Yonushonis
  • Patent number: 10391478
    Abstract: A NOx adsorber catalyst composition, a NOx adsorber catalyst and its use in an emission treatment system for internal combustion engines, is disclosed. The NOx adsorber catalyst composition a support material and one or more platinum group metals disposed on the support material, wherein the support material comprises a mixed dopant NOx storage enhancer.
    Type: Grant
    Filed: October 4, 2017
    Date of Patent: August 27, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Desiree Duran-Martin, Rebecca Maksymowicz, Jonathan Radcliffe, Raj Rajaram
  • Patent number: 10384197
    Abstract: A composition useful in oxidative desulfurization of gaseous hydrocarbons is described. It comprises a CuZnAl—O mixed oxide, and an H form of a zeolite. The mixed oxide can contain one or more metal oxide promoters. The H form of the zeolite can be desilicated, and can also contain one or more transition metals.
    Type: Grant
    Filed: July 26, 2016
    Date of Patent: August 20, 2019
    Assignees: SAUDI ARABIAN OIL COMPANY, BORESKOV INSTITUTE OF CATALYSIS
    Inventors: Omer Refa Koseoglu, Yaming Jin, Zinfer Ismagilov, Svetlana Yashnik, Mikhail Kerzhentsev, Valentin Parmon
  • Patent number: 10376839
    Abstract: It is an object to provide an exhaust gas purification catalyst for a lean burn engine having sufficient NOx purification performance. The exhaust gas purification catalyst for a lean burn engine according to the present invention has a catalyst component including noble metal and ceria supported on a three-dimensional structure. In the whole catalyst, the supported amount of ceria per 1 L of catalyst is 140 to 300 g/L, and in the whole catalyst, is 50 to 98% by mass with respect to the whole coated amount. Furthermore, it is characterized that 50% by mass or more of ceria is included in the same catalyst layer in which noble metal is included, and the amount of noble metal included in the catalyst layer is 0.1% by mass or more with respect to the amount of ceria included in the catalyst layer.
    Type: Grant
    Filed: January 19, 2015
    Date of Patent: August 13, 2019
    Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.
    Inventors: Takahiro Umeno, Masaya Hanzawa, Yoshiyuki Hayashi
  • Patent number: 10369548
    Abstract: A catalyzed soot filter, in particular for the treatment of Diesel engine exhaust, comprises a coating design which ensures soot particulates filtration, assists the oxidation of carbon monoxide (CO), and produces low H2S emissions during normal engine operations and regeneration events.
    Type: Grant
    Filed: March 11, 2015
    Date of Patent: August 6, 2019
    Assignees: BASF SE, BASF Corporation
    Inventors: Gerd Grubert, Alfred H. Punke, Torsten Neubauer, Marcus Hilgendorff, Chung-Zong Wan, Yuejin Li, Matthew Caudle
  • Patent number: 10358964
    Abstract: Exhaust purification system and methods for the reduction of emissions from an exhaust stream, including an upstream catalyst coupled with a passive NOx adsorber catalyst; means to contact the exhaust stream with ozone, to react NO in the exhaust stream with the ozone to produce NO2; and an SCR catalyst.
    Type: Grant
    Filed: December 19, 2017
    Date of Patent: July 23, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Ceren Aydin, Sougato Chatterjee, Raymond Conway, Mojghan Naseri
  • Patent number: 10351512
    Abstract: A method of producing an organic compound, which contains a step of performing a deodorization step using a flow reaction in a flow passage to remove, from a reaction liquid, a malodorous material generated or remaining in a reaction step, wherein the organic compound is an industrially useful compound.
    Type: Grant
    Filed: September 28, 2016
    Date of Patent: July 16, 2019
    Assignee: FUJIFILM Wako Pure Chemical Corporation
    Inventors: Akira Kemmoku, Yayoi Haga, Fumio Kawamoto
  • Patent number: 10335770
    Abstract: A layered emission control device for an engine system is provided, including a plurality of catalytic layers, the catalytic layers optionally or additionally comprising sublayers, each sublayer having a distinct composition. Advantages of such a device include providing increased treatment rates of one or more engine exhaust gas species over a wide range of engine exhaust operating conditions, while reducing exhaust emissions, and reducing a size of the emissions control system.
    Type: Grant
    Filed: June 15, 2017
    Date of Patent: July 2, 2019
    Assignee: Ford Global Technologies, LLC
    Inventor: Douglas Allen Dobson
  • Patent number: 10335776
    Abstract: An oxidation catalyst composite, methods, and systems for the treatment of exhaust gas emissions from a diesel engine are described. More particularly, an oxidation catalyst composite including a first washcoat layer comprising a Pt component and a Pd component, and a second washcoat layer including a refractory metal oxide support containing manganese, a zeolite, and a platinum component is described.
    Type: Grant
    Filed: December 16, 2013
    Date of Patent: July 2, 2019
    Assignee: BASF Corporation
    Inventors: Shiang Sung, Stanley A. Roth, Claudia Zabel, Susanne Stiebels, Andreas Sundermann, Olga Gerlach
  • Patent number: 10329986
    Abstract: An aftertreatment assembly includes a selective catalytic reduction (SCR) device having a catalyst and configured to receive an exhaust gas. A controller is operatively connected to the SCR device. The controller having a processor and a tangible, non-transitory memory on which is recorded instructions for executing a method of model-based monitoring of the SCR device. The method relies on a physics-based model that may be implemented in a variety of forms. The controller is configured to obtain at least one estimated parameter, and at least one threshold parameter based at least partially on a catalyst degradation model. The catalyst degradation model is based at least partially on a predetermined threshold storage capacity (?T). A catalyst status is determined based on a comparison of the estimated and threshold parameters. The operation of the assembly is controlled based at least partially on the catalyst status.
    Type: Grant
    Filed: July 18, 2017
    Date of Patent: June 25, 2019
    Assignee: GM Global Technology Operations LLC.
    Inventors: Yue-Yun Wang, Yongjie Zhu, Alessia Tuninetti
  • Patent number: 10272421
    Abstract: The present invention relates to a catalytic wall-flow monolith for use in an emission treatment system, the monolith comprising a porous substrate and having a first face and a second face defining a longitudinal direction therebetween and first and second pluralities of channels extending in the longitudinal direction, the first plurality of channels provides a first plurality of inner surfaces and is open at the first face and closed at the second face, and the second plurality of channels is open at the second face and closed at the first face, a first catalytic material is distributed within the porous substrate, a microporous membrane is provided in the first plurality of channels on a first portion, extending in the longitudinal direction, of the first plurality of inner surfaces, and the first portion extends from the first face for 75 to 95% of a length of the first plurality of channels.
    Type: Grant
    Filed: June 27, 2016
    Date of Patent: April 30, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Guy Richard Chandler, Paul Richard Phillips
  • Patent number: 10265684
    Abstract: Coated gasoline particulate filters (cGPFs) that are produced according to varied material compositions and catalyst configurations are disclosed. The cGPFs include Fe—Ce (rich)-activated Rh compositions that provide greater catalytic functionality. These cGPFs are incorporated within engine systems as components of TWC systems for controlling and reducing engine exhaust emissions. The conversion performance of these TWC systems is assessed and compared employing worldwide harmonized light duty test cycle (WLTC) protocol within a gasoline fueled internal combustion engine. These TWC systems exhibit a significant catalytic performance when compared with the catalytic performance of a PGM-based Original Equipment Manufacturer (OEM) catalyst employed in TWC applications. Further, TWC catalysts are produced including Fe-activated Rh layers comprising dopant elements.
    Type: Grant
    Filed: May 4, 2017
    Date of Patent: April 23, 2019
    Assignee: CDTI ADVANCED MATERIALS, INC.
    Inventor: Randal L. Hatfield
  • Patent number: 10258978
    Abstract: A porous ceramic substrate for use as a particle filter, with a porosity of at least 50%, which includes a non-uniform coating layer of an oxide component in contact with a surface of the ceramic substrate, which oxide component is distributed on the surface and in dead-end pores of the ceramic substrate and creates the non-uniform coating layer on the substrate support, wherein the coating layer has a substantially smooth surface. Such substrate is typically a particle filter or part of a particle filter, e.g. a DPF.
    Type: Grant
    Filed: August 14, 2014
    Date of Patent: April 16, 2019
    Assignee: DINEX A/S
    Inventors: Thomas Wolff, Ramona Deinlein, Lars Christian Larsen
  • Patent number: 10252248
    Abstract: The oxide-containing particles (transition metal oxide-containing cerium dioxide particle) exert a catalyst performance, and include at least an iron oxide containing an iron component and a manganese oxide containing a manganese component on a surface of each of cerium dioxide particles, wherein the iron oxide and manganese oxide have smaller particle diameters than that of the cerium dioxide particles, and the content rate of the iron oxide and the manganese oxide is within the range of from 15.0% by mass to 35.0% by mass.
    Type: Grant
    Filed: March 17, 2017
    Date of Patent: April 9, 2019
    Assignee: NGK Insulators, Ltd.
    Inventors: Yunie Izumi, Kenji Morimoto
  • Patent number: 10254249
    Abstract: A method to predict the catalytic activity of a metal oxide of formula MxOy where x is a number from 1 to 3 and y is a number from 1 to 8 is provided. The metal of the metal oxide has redox coupled oxidation states wherein the redox transformation is between oxidation states selected from the group consisting of a diamagnetic oxidation state (Md+) and a paramagnetic oxidation state (Mp+), a paramagnetic oxidation state (Mp+) and a ferromagnetic oxidation state (Mf+), and a paramagnetic oxidation state (Mp+) and an antiferromagnetic oxidation state (Ma+)where d, p, f and a are independently numbers from 1 to 6 and one of the oxidation states (Md+), (Mp+), (Mf+), and (Ma+) is formed by reduction by the O2?. The magnetic susceptibility of the metal oxide as a sample in an oxygen environment at a specified temperature is correlated with a value of (Md+ or Mp+ or Mf+ or Ma+)/g (O2 rich).
    Type: Grant
    Filed: July 11, 2017
    Date of Patent: April 9, 2019
    Assignees: The University of Manitoba, Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Vinod K. Paidi, Johan A. Van Lierop, Charles A. Roberts
  • Patent number: 10226762
    Abstract: Provided is a catalytic washcoat having a catalyst component and an alumina binder, wherein the catalyst component includes an aluminosilicate molecular sieve having a beta (BEA) and/or chabazite (CHA) framework, and about 1 to about 10 weight percent of a base metal component comprising iron and/or copper, wherein said weight percent is based on the weight of the aluminosilicate molecular sieve.
    Type: Grant
    Filed: June 15, 2015
    Date of Patent: March 12, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Stuart David Reid, Alexander Nicholas Michael Green, Guy Richard Chandler
  • Patent number: 10213775
    Abstract: A NOx absorber catalyst for treating an exhaust gas from a lean burn engine. The NOx absorber catalyst comprises a molecular sieve catalyst comprising a noble metal and a molecular sieve, wherein the molecular sieve contains the noble metal; an oxygen storage material for protecting the molecular sieve catalyst; and a substrate having an inlet end and an outlet end.
    Type: Grant
    Filed: October 5, 2016
    Date of Patent: February 26, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Andrew Francis Chiffey, Jack Corps, Laura Mitchell-Downie, Francois Moreau, Matthew O'Brien
  • Patent number: 10173173
    Abstract: Provided is an ammonia slip catalyst article having supported palladium in a top or upstream layer for oxidation of carbon monoxide and/or hydrocarbons, an SCR catalyst either in the top layer or in a separate lower or downstream layer, and an ammonia oxidation catalyst in a bottom layer. Also provided are methods for treating an exhaust gas using the catalyst article, wherein the treatment involves reducing the concentrations of ammonia and optionally carbon monoxide and/or hydrocarbons in the exhaust gas.
    Type: Grant
    Filed: February 2, 2017
    Date of Patent: January 8, 2019
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Paul Joseph Andersen, Hai-Ying Chen, Julian Peter Cox, Kevin Doura, Joseph Michael Fedeyko, Erich Conlan Weigert
  • Patent number: 10167248
    Abstract: Disclosed is a process for performing a chemical reaction selected from reductive amination and hydrogenation of a first functional group in an organic feed substrate, which feed substrate comprises at least one further functional group containing a halogen atom, wherein the halogen atom is selected from the list consisting of chlorine, bromine, iodine, and combinations thereof, in the presence of hydrogen and a heterogeneous catalyst comprising at least one metal from the list of Pd, Rh, and Ru, together with at least a second metal from the list consisting of Ag, Ni, Co, Sn, Cu and Au. The process is preferably applied for the reductive amination of 2-chloro-benzaldehyde to form 2-chloro-benzyldimethylamine, as an intermediate in the production of agrochemically active compounds and microbiocides of the methoximinophenylglyoxylic ester series.
    Type: Grant
    Filed: August 26, 2014
    Date of Patent: January 1, 2019
    Assignee: Taminco BVBA
    Inventors: Kristof Moonen, Bart Vandeputte, Daan Scheldeman, Kim Dumoleijn
  • Patent number: 10160916
    Abstract: A thermal medium-circulated heat exchanger type reactor comprises: a tube unit configured such that synthesis gas is supplied to a cobalt catalyst layer filled with the cobalt metal foam catalysts each including a metal foam coated with cobalt catalyst powder to conduct a reaction; a shell unit configured to cover the tube unit such that thermal medium oil having a predetermined temperature is circulated to control reaction heat generated from a Fischer-Tropsch synthesis reaction; and an electric heater provided at the circumference of the shell unit to heat a cobalt catalyst layer to reduce and pretreat the cobalt catalyst layer.
    Type: Grant
    Filed: March 21, 2016
    Date of Patent: December 25, 2018
    Assignee: KOREA INSTITUTE OF ENERGY RESEARCH
    Inventors: Jung-Il Yang, Heon Jung, Dong-Hyun Chun, Ji-Chan Park
  • Patent number: 10156173
    Abstract: A dosing module control system includes a central controller, a flow observer, and a switching doser controller. The central controller is configured to obtain a target flow rate and a target pressure. The flow observer is configured to determine a flow rate gain. The switching doser controller is configured to communicate with the central controller and the flow observer. The switching doser controller is configured to receive the target flow rate and the target pressure from the central controller, receive the flow rate gain from the flow observer, determine a compensated flow rate based on the target flow rate, the target pressure, and the flow rate gain, and determine at least one of an injector duty cycle associated with the determined compensated flow rate, or a pump frequency associated with the determined compensated flow rate. The pump is configured to communicate with the switching doser controller.
    Type: Grant
    Filed: May 25, 2018
    Date of Patent: December 18, 2018
    Assignee: Cummins Emission Solutions Inc.
    Inventors: Masoud Ziabakhsh Deilami, Nassim Khaled
  • Patent number: 10150103
    Abstract: The invention relates to: a catalytic composition that is active in the selective catalytic reduction of nitric oxides, containing an iron-containing MFI-type zeolite and an iron-containing BEA-type zeolite, wherein the weight average particle size d50 of the MFI-type zeolite and the BEA-type zeolite is different; a method for producing an SCR catalyst; and the SCR catalyst produced in this way. The adhesion of the coating is improved in that the weight average particle sizes of the MFI-type and BEA-type zeolites are different.
    Type: Grant
    Filed: February 24, 2016
    Date of Patent: December 11, 2018
    Assignee: Clariant International Ltd.
    Inventors: Markus Reichinger, Gerd Maletz, Andreas Bentele, Martin Schneider, Klaus Wanninger, Kristof Eisert
  • Patent number: 10143965
    Abstract: Active catalysts for the treatment of a low temperature exhaust gas stream are provided containing palladium oxides dispersed on a spinel oxide for the direct, lean removal of nitrogen oxides from the exhaust gas stream. The low temperature (from about 400° C. to about 650° C.), direct decomposition is accomplished without the need of a reductant molecule. In one example, PdO may be dispersed on a surface of a metal oxide support, such as Co3O4 spinel oxide, synthesized using wet impregnation techniques. The PdO/Co3O4 catalyst system converts nitric oxide to nitrogen gas with high product specificity, avoiding the production of a significant concentration of the undesirable N2O product.
    Type: Grant
    Filed: May 9, 2017
    Date of Patent: December 4, 2018
    Assignee: Toyota Motor Engineering & Manufacturing North America, Inc.
    Inventors: Krishna Gunugunuri, Charles Alexander Roberts, Torin C. Peck
  • Patent number: 10143968
    Abstract: The object of the present invention is to provide a high-performance exhaust gas purifying catalyst that can achieve oxygen absorption/release capacity and NOx purification performance. The object is solved by an exhaust gas purifying catalyst, which comprises a ceria-zirconia composite oxide having a pyrochlore-type ordered array structure in the upstream part of the catalyst coating layer, in which the ceria-zirconia composite oxide contains at least one additional element selected from the group consisting of praseodymium, lanthanum, and yttrium at 0.5 to 5.0 mol % of the total cation amount, and has a molar ratio of (cerium+the additional element):(zirconium) of 43:57 to 48:52.
    Type: Grant
    Filed: December 11, 2015
    Date of Patent: December 4, 2018
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATION
    Inventors: Hiromasa Suzuki, Takeru Yoshida, Masahide Miura, Isao Chinzei, Mitsuyoshi Okada, Toshitaka Tanabe, Akihiko Suda, Hirotaka Ori, Akiya Chiba, Kosuke Iizuka, Akira Morikawa
  • Patent number: 10137414
    Abstract: An oxidation catalyst composite, methods and systems for the treatment of exhaust gas emissions from an advanced combustion engine, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx) from a diesel engine and an advanced combustion diesel engine are disclosed. More particularly, washcoat compositions are disclosed comprising at least two washcoat layers, a first washcoat comprising a palladium component and a first support containing cerium and a second washcoat containing platinum and one or more molecular sieves.
    Type: Grant
    Filed: August 3, 2016
    Date of Patent: November 27, 2018
    Assignee: BASF Corporation
    Inventors: Jeffrey B. Hoke, Joseph C. Dettling
  • Patent number: 10125646
    Abstract: An exhaust system for treating an exhaust gas produced by a diesel engine comprises: (a) an emissions control device (ECD) for oxidizing carbon monoxide (CO) and/or hydrocarbons (HCs), wherein the emissions control device comprises a platinum group metal (PGM) and a substrate, wherein the PGM is platinum, palladium or a combination thereof; (b) an injector for introducing an ammonia precursor into the exhaust gas, which is downstream of the ECD; (c) a first selective catalytic reduction (SCR) catalyst downstream of the injector, wherein the first SCR catalyst comprises a substrate and a first SCR composition, wherein the substrate is either a flow-through substrate or a filtering substrate; (d) a second SCR catalyst downstream of the first SCR catalyst, wherein the second SCR catalyst comprises a flow-through substrate and a second SCR composition; and wherein at least one of the ECD and the first SCR reduction catalyst has a filtering substrate.
    Type: Grant
    Filed: April 13, 2016
    Date of Patent: November 13, 2018
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Mojghan Naseri, Ceren Aydin, Shadab Mulla, Raymond Conway
  • Patent number: 10118127
    Abstract: Provided is a method for reducing N2O emissions in an exhaust gas comprising contacting an exhaust gas containing NH3 and an inlet NO concentration with an SCR catalyst composition containing small pore zeolite having an SAR of about 3 to about 15 and having about 1-5 wt. % of an exchanged transition metal.
    Type: Grant
    Filed: February 6, 2017
    Date of Patent: November 6, 2018
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Guy Richard Chandler, Hai-Ying Chen, Jillian Elaine Collier, Joseph Michael Fedeyko, Alexander Nicholas Michael Green
  • Patent number: 10113462
    Abstract: An exhaust aftertreatment system configured to reduce nitrous oxide (N2O) formation includes a first selective catalytic reduction (SCR) catalyst. The first SCR catalyst is configured for low N2O formation and low ammonia (NH3) storage capacity. A second SCR catalyst is positioned downstream of the first SCR catalyst. The second SCR catalyst is configured for high NH3 storage capacity.
    Type: Grant
    Filed: April 22, 2016
    Date of Patent: October 30, 2018
    Assignee: Cummins Inc.
    Inventors: Rohan A. Siddhanthi, Bryon D. Staebler, Krishna Kamasamudram
  • Patent number: 10112179
    Abstract: The present invention provides for a structure for use in a thermo chemical fuel production process, said structure having a void phase and a solid phase, wherein the structure has an effective total optical thickness for solar radiation or effective total optical thickness for infrared radiation of from 0.1 to 10, wherein the solid phase has a geometrical specific surface area of more than 2*103 m?1 and wherein the solid phase comprises and preferably consists of a reactive material.
    Type: Grant
    Filed: April 23, 2014
    Date of Patent: October 30, 2018
    Assignee: ETH Zurich
    Inventors: Aldo Steinfeld, Jonathan Scheffe, Philipp Furler, Ulrich Vogt, Michal Gorbar
  • Patent number: 10105691
    Abstract: Hydrocarbon (HC) traps are disclosed. The HC trap may include a first zeolite material having an average pore diameter of at least 5.0 angstroms and configured to trap hydrocarbons from an exhaust stream and to release at least a portion of the trapped hydrocarbons at a temperature of at least 225° C. The HC trap may also include a second zeolite material having an average pore diameter of less than 5.0 angstroms or larger than 7.0 angstroms. One or both of the zeolite materials may include metal ions, such as transition, Group 1A, or platinum group metals. The HC trap may include two or more discrete layers of zeolite materials or the two or more zeolite materials may be mixed. The multiple zeolite HC trap may form coke molecules having a relatively low combustion temperature, such as below 500° C.
    Type: Grant
    Filed: March 31, 2016
    Date of Patent: October 23, 2018
    Assignee: Ford Global Technologies, LLC
    Inventors: Jason Aaron Lupescu, Giovanni Cavataio
  • Patent number: 10076748
    Abstract: Provided is an exhaust gas purification catalyst that purifies nitrogen oxides, comprising a catalyst support and cerium oxide loaded thereon, wherein the catalyst support contains: at least one of zeolite selected from the group consisting of chabazite, SAPO-34 and SSZ-13, and 1 wt % to 10 wt % wt % of copper, iron or a mixture thereof based on the weight of the catalyst; and the amount of the cerium oxide is 1 wt % to 30 wt % based on the weight of the catalyst, and the cerium oxide has a crystallite diameter of 0.1 nm to 2.5 nm.
    Type: Grant
    Filed: October 6, 2014
    Date of Patent: September 18, 2018
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Kei Morohoshi, Tatsuya Miyazaki
  • Patent number: 10076725
    Abstract: A wall-flow-type exhaust gas purification catalyst with an oxygen storage material that has an increased OSC and exhibits its OSC without a compromise provides an exhaust gas purification catalyst having a wall-flow-type substrate, a first catalytic layer and a second catalytic layer. The first catalytic layer is provided to an internal portion of a partition wall in contact with an entrance cell. The second catalytic layer is provided to an internal portion of a partition wall in contact with an exit cell. Each of the first and second catalytic layers has an oxygen storage material. The ratio (D1/D2) of the coating density D1 of the first catalytic layer to the coating density D2 of the second catalytic layer is 1.1 to 1.8.
    Type: Grant
    Filed: February 16, 2016
    Date of Patent: September 18, 2018
    Assignees: CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Ryota Onoe, Shingo Sakagami, Yasutaka Nomura, Yuta Morishita, Junji Kuriyama, Hiroshi Sekine, Daisuke Ochiai, Naoto Miyoshi, Masahiko Takeuchi, Akemi Sato
  • Patent number: 10071368
    Abstract: An exhaust gas purification catalyst capable of stably maintaining and exhibiting excellent catalytic performance includes a wall-flow-type substrate, a first catalytic layer and a second catalytic layer. The first catalytic layer is provided to an internal portion of a partition wall in contact with an entrance cell. The second catalytic layer is provided to an internal portion of a partition wall in contact with an exit cell. The ratio (D2/D1) of the coating density D2 of the second catalytic layer to the coating density D1 of the first catalytic layer is 1.01 to 1.4.
    Type: Grant
    Filed: February 16, 2016
    Date of Patent: September 11, 2018
    Assignee: CATALER CORPORATION
    Inventors: Ryota Onoe, Shingo Sakagami, Yasutaka Nomura, Yuta Morishita, Junji Kuriyama, Hiroshi Sekine
  • Patent number: 10066533
    Abstract: A device is provided, which makes it possible to perform a failure diagnostics for a filter more accurately even in the case of an internal combustion engine which is constructed to be capable of using both of gaseous fuel and liquid fuel. The device of the invention comprises judging means which judges any failure of the filter by comparing the added-up amount of the particulate matter contained in the exhaust gas as detected by a PM amount detecting sensor during a predetermined period and the added-up amount of the particulate matter contained in the exhaust gas as estimated by PM amount estimating means during the predetermined period, wherein the PM amount estimating means estimates the added-up amount of the particulate matter contained in the exhaust gas on the basis of the predetermined parameter and only a fuel injection amount of the liquid fuel out of a fuel injection amount of the gaseous fuel and the fuel injection amount of the liquid fuel.
    Type: Grant
    Filed: July 8, 2015
    Date of Patent: September 4, 2018
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Tomoyuki Kogo, Makoto Ogiso, Taiga Hagimoto
  • Patent number: 10060315
    Abstract: A diesel particulate filter coated with selective catalytic reduction includes: a support in which channels are formed from a front side to a rear side, a perovskite catalyst, and a selective catalytic reduction. In particular, the channels include an inlet channel which has an opened inlet and a closed outlet, and an outlet channel which is disposed adjacent to the inlet channel and has a closed inlet and an opened outlet. The perovskite catalyst is provided in an inner surface of the inlet channel, and the selective catalytic reduction is provided in an inner surface of the outlet channel. The perovskite catalyst is represented as La1-xAgxMnO3 (here, 0<X<1).
    Type: Grant
    Filed: May 27, 2016
    Date of Patent: August 28, 2018
    Assignee: HYUNDAI MOTOR COMPANY
    Inventor: Jin Woo Choung
  • Patent number: 10047651
    Abstract: Selective catalytic reduction filter (SCRF) devices and systems incorporating the same are provided. Systems can include an exhaust gas source, an exhaust gas conduit capable of receiving an exhaust gas stream from the exhaust gas source, and an SCRF device in fluid communication therewith. The SCRF device can include a filter, a selective catalytic reduction (SCR) catalyst disposed on at least portion of the filter, and a soot oxidizing catalyst (SOC) material disposed on at least a portion of one or more of the filter and the SCR catalyst. The SOC material can include one or more transition metal oxides, excluding platinum group metals. The SOC material can include one or more of a titanium oxide, an iron oxide, a tungsten oxide, a cerium oxide, and acidic zirconia. The SOC material can be in amorphous form. The SOC material can be biased towards to the upstream side of the filter.
    Type: Grant
    Filed: December 6, 2016
    Date of Patent: August 14, 2018
    Inventors: Rahul Mital, David Brown, Wei Li, Jianwen Li
  • Patent number: 10022667
    Abstract: An aftertreatment system includes a first oxidation catalyst, a second oxidation catalyst, and a turbocharger. The first oxidation catalyst is upstream of the turbocharger and includes a first oxidation catalyst formulation. The second oxidation catalyst is downstream of the turbocharger and includes a second oxidation catalyst formulation different than the first oxidation catalyst formulation. The second oxidation catalyst formulation is configured to promote conversion of nitric oxide (NO) to nitrogen dioxide (NO2).
    Type: Grant
    Filed: July 28, 2017
    Date of Patent: July 17, 2018
    Assignee: Cummins Inc.
    Inventors: Yuhui Zha, John K Heichelbech, Michael J. Cunningham
  • Patent number: 10005069
    Abstract: The present invention pertains to novel core-shell particles comprising a core of alumina and a shell of cobalt oxide, characterized in that they are spherical with a number average diameter, as measured by TEM, of between 10 and 30 nm. This invention also pertains to the method for preparing these core-shell particles and to their uses in the manufacture of a catalyst.
    Type: Grant
    Filed: June 21, 2016
    Date of Patent: June 26, 2018
    Assignee: Total Raffinage Marketing
    Inventors: Vincenzo Roberto Calderone, Nirappurackal Raveendran Shiju, Gad Rothenberg, Daniel Curulla-Ferre
  • Patent number: 9987619
    Abstract: A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.
    Type: Grant
    Filed: May 31, 2013
    Date of Patent: June 5, 2018
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Kaneshalingam Arulraj, Ralf Dotzel, Rainer Leppelt, Jorg Werner Muench, Alexandra Tsami Goodwin, Gudmund Smedler