Utilizing As Solid Sorbent, Catalyst, Or Reactant A Material Containing A Transition Element Patents (Class 423/213.2)
  • Publication number: 20130294989
    Abstract: Ag/Al2O3 materials may be packaged in a suitable flow-through reactor, close coupled to the exhaust manifold of a diesel engine, and upstream of other exhaust gas treatment devices, such as a diesel oxidation catalyst and a selective reduction catalyst for NOx. The silver/alumina catalyst material uses hydrogen in a cold-start engine exhaust and serves to oxidize NO to NO2 in the relatively low temperature, hydrocarbon-containing, exhaust during a short period following the engine cold start, and to temporarily store NOx during the start-up period. After the exhaust has heated downstream catalytic devices, the silver yields its nitrogen oxides for conversion to nitrogen by the then-operating devices before NOx is discharged to the atmosphere.
    Type: Application
    Filed: October 31, 2012
    Publication date: November 7, 2013
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: CALVIN K. KOCH, GONGSHIN QI, STEVEN J. SCHMIEG, WEI LI
  • Patent number: 8568678
    Abstract: The reductive removal of nitrogen oxides from the exhaust gas from internal combustion engines operated predominantly under lean conditionstakes place in a selective catalytic reduction (SCR) of the nitrogen oxides by means of ammonia or a compound which can be decomposed into ammonia as reducing agent. Conventional SCR catalysts typically have a relatively narrow working temperature window, usually 350° C. to 520° C., in which good nitrogen oxide conversions can be achieved with sufficient selectivity. SCR catalyst formulations whose working window is in the temperature range from 150° C. to 350° C. generally not be used at higher temperatures since they oxidize the ammonia required as reducing 18 agent to nitrogen oxides at above 350° C. To cover the entire exhaust gas temperature range typical of vehicles having been operating internal combustion enginesextending from 200° C. to 600° C.
    Type: Grant
    Filed: June 6, 2007
    Date of Patent: October 29, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Nicola Soeger, Lothar Mussmann, Ralf Sesselmann, Katja Adelmann, Wolfgang Schneider
  • Patent number: 8568674
    Abstract: Oxidation catalyst composites for the treatment of exhaust gas emissions, such as the abatement of unburned hydrocarbons (HC), and carbon monoxide (CO) and the oxidation of NO to NO2 are disclosed The catalyst composites comprise two washcoat layers containing two different compositions of platinum group metals to optimize the NO2 exiting the catalyst composite. The key to improvement in NO oxidation is to have one catalyst layer that contains Pt while being substantially free of Pd. Methods and systems utilizing the catalyst composites are also disclosed.
    Type: Grant
    Filed: August 10, 2012
    Date of Patent: October 29, 2013
    Assignee: BASF Corporation
    Inventors: Shiang Sung, Stanley A. Roth, Claudia Wendt, Susanne Stiebels, Helke Doering
  • Patent number: 8568677
    Abstract: The present invention relates to the use of a zeolite catalyst comprising at least one transition metal and in addition sulfur and/or phosphorus atoms for reducing the content of nitrogen oxides in a gas, and also to a process for reducing the content of nitrogen oxides in a gas by bringing this gas into contact with such a zeolite catalyst.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: October 29, 2013
    Assignee: BASF SE
    Inventors: Stephan Deuerlein, Tobias Rosendahl
  • Patent number: 8562925
    Abstract: An arrangement for controlling injection of a reducing agent in an exhaust line of a combustion engine (1): An injection system (8-12) injects the reducing agent into the exhaust line (3). A first catalyst (13) reduces the amount of nitrogen oxides in the exhaust gases in the exhaust line (3) using the reducing agent. A second catalyst (14) downstream of the first catalyst (13) in the exhaust line (3) converts ammonia in the exhaust gases to nitrogen gas and nitrous oxide. A nitrous oxide sensor (17) monitors the amount of nitrous oxide in the exhaust line (3) downstream of the second catalyst (14). A control unit (10) of the injection system (8-12) adjusts the amount (q) of reducing agent injected into the exhaust line (3) if the sensor (17) detects that the amount of nitrous oxide is not within a selected range (A).
    Type: Grant
    Filed: July 11, 2011
    Date of Patent: October 22, 2013
    Assignee: Scania CV AB
    Inventor: Håkan Sarby
  • Patent number: 8562924
    Abstract: Methods and systems for treating NOx-containing exhaust from an internal combustion engine. An exhaust aftertreatment system has at least a PM control device and a downstream selective reduction catalyst (SCR) device. By using a bypass line to divert engine-out exhaust around the PM control device, or by introducing NO or NO2 from a non-engine source, the NO/NOx ratio into the SCR device can be controlled to a desired ratio for improved SCR efficiency.
    Type: Grant
    Filed: October 20, 2012
    Date of Patent: October 22, 2013
    Assignee: Southwest Research Institute
    Inventor: Charles E. Roberts, Jr.
  • Publication number: 20130272937
    Abstract: A chabazite-type zeolite having copper and an alkali earth metal supported thereon. The alkali earth metal is preferably at least one metal selected from the group consisting of calcium, magnesium and barium. Moreover, the SiO2/Al2O3 molar ratio is preferably from 10 to 50, and the copper/aluminum atomic ratio is preferably from 0.15 to 0.25. This type of chabazite-type zeolite exhibits a higher nitrogen oxide purification rate after a hydrothermal durability treatment than those of conventional chabazite-type zeolite catalysts on which only copper is supported.
    Type: Application
    Filed: December 27, 2011
    Publication date: October 17, 2013
    Applicant: TOSOH CORPORATION
    Inventors: Keisuke Tokunaga, Yuuki Ito
  • Publication number: 20130266497
    Abstract: The present invention relates to a process for improving the catalytic activity of a copper-promoted zeolitic catalyst with chabazite structure, to a copper-promoted zeolitic catalyst with chabazite structure and to a process for reducing nitrogen oxides in an offgas stream.
    Type: Application
    Filed: December 14, 2011
    Publication date: October 10, 2013
    Applicant: UMICORE AG & CO. KG
    Inventors: Michael Seyler, Nicola Soeger, Katja Adelmann, Thomas R. Pauly, Gerald Jeske
  • Patent number: 8551432
    Abstract: A method for injecting ammonia into an exhaust gas stream downstream of a diesel engine includes providing an exhaust gas passageway (11) from the diesel engine to an ambient (14). The exhaust gas passageway (11) includes an NOx Slip Catalyst (NSC) 20 downstream of an NOx Particulate Filter (NPF) 18. The method includes emitting exhaust gas (EG) through the exhaust gas passageway (11), and selectively injecting ammonia (NH3) upstream of the NPF 18, upstream of the NSC (20), both upstream of the NPF and the NSC, or not injecting ammonia, depending on the temperature of the exhaust gas at the NPF and at the NSC.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: October 8, 2013
    Assignee: International Engine Intellectual Property Company, LLC.
    Inventors: Brad J. Adelman, Vadim Olegovich Strots, Shyam Santhanam
  • Patent number: 8551433
    Abstract: A SCR catalyst system, comprising a first SCR catalyst (1) and a second SCR catalyst (2) which is disposed in the exhaust gas tract downstream of the first SCR catalyst (1). At least one metering device (12) for metering in a reducing agent solution is disposed in the exhaust gas tract upstream of a first SCR catalysis element (13) of said first SCR catalyst (1). The SCR catalyst system does not require a device for metering a reducing agent solution into a second SCR catalysis element (21) of the second SCR catalyst (2).
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: October 8, 2013
    Assignee: Robert Bosch GmbH
    Inventors: Andreas Fritsch, Andreas Holzeder
  • Publication number: 20130259779
    Abstract: Particles of mixed oxides of cerium, zirconium, and copper (CeZrCuOx) may be prepared as catalysts and used to preferentially catalyze the oxidation of CO in exhaust streams containing CO and NH3. In one practice, this CeZrCuOx catalyst may be used in combination with a close-coupled PGM catalyst which promotes the formation of NH3 in the exhaust during fuel-rich operation, and at least one under-floor NH3-SCR catalyst, which catalyzes the reduction of NOx in the exhaust stream during fuel-lean operation using NH3 as a reductant. During fuel-rich engine operation, the exhaust stream may be doped with oxygen downstream of the PGM catalyst and passed in contact with particles of the CeZrCuOx catalyst so that residual CO in the exhaust may be oxidized to CO2, without oxidation or other conversion of the NH3.
    Type: Application
    Filed: March 30, 2012
    Publication date: October 3, 2013
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: Chang H. KIM, Gongshin QI
  • Patent number: 8545780
    Abstract: A catalyst material including a catalyst carrier including a porous alumina support and a hindrance layer on the alumina support, the hindrance layer comprising one or more of a sulfate, carbonate, hydroxide, or oxide of barium, strontium, or calcium is described. The catalyst carrier further includes a rare earth oxide. The catalyst material can further comprise a platinum group metal. The catalyst material is useful for methods and systems of abating pollutants from automotive exhaust gas.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: October 1, 2013
    Assignee: BASF Corporation
    Inventors: Shau-Lin F. Chen, Gary A. Gramiccioni, Wiley Feng, Eric An, Scott Zhao
  • Patent number: 8545779
    Abstract: A method for catalytic oxidation of NO to NO2 in the sulfur-containing exhaust gases of lean-burn engines, such as diesel engines is disclosed. The catalysts are oxide perovskites with a credible likelihood of being sulfur-tolerant.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: October 1, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Richard J. Blint, Chang H. Kim
  • Patent number: 8545796
    Abstract: The invention is directed to compositions and processes for the production of silica-stabilized ultrafine anatase titanias and which may further comprise tungsten and vanadia. The surface stabilization may be by treatment of the TiO2 particles with a low molecular weight and/or small nanoparticle form of silica such as, in preferred embodiments, a tetra(alkyl)ammonium silicate or silicic acid, which serves to efficiently maintain the anatase phase and prevent crystal growth under severe thermal and hydrothermal conditions, even in the presence of vanadia. The vanadia catalysts produced from the novel titanias have equal or improved catalytic activity for selective catalytic reduction of NOx compared to conventional vanadia supported silica-titania based catalysts. The invention is further directed to diesel emission catalytic devices comprising the novel titania-based catalyst compositions.
    Type: Grant
    Filed: July 31, 2009
    Date of Patent: October 1, 2013
    Assignee: Cristal USA Inc.
    Inventor: David M. Chapman
  • Publication number: 20130251611
    Abstract: The present invention is directed to a process for the production of ion-exchanged (metal-doped, metal-exchanged) Zeolites and Zeotypes, In particular, the method applied uses a sublimation step to incorporate the ion within the channels of the Zeolitic material. Hence, according to this dry procedure no solvent is involved which obviates certain drawbacks connected with wet exchange processes known in the art.
    Type: Application
    Filed: December 8, 2011
    Publication date: September 26, 2013
    Applicant: UMICORE AG & CO. KG
    Inventors: Fei Wen, Barry W.L. Southward, Liesbet Jongen, Alexander Hofmann, Daniel Herein
  • Patent number: 8539760
    Abstract: An exhaust aftertreatment system that receives an exhaust flow from a lean-burn engine and a method for treating the exhaust flow are described. The exhaust aftertreatment system may include a three-way-catalyst, an oxidation catalyst, and a NH3—SCR catalyst. The three-way-catalyst passively generates NH3 from native NOX contained in the exhaust flow when an A/F mixture supplied to the engine is cycled from lean to rich. The generated NH3 is then stored in the NH3—SCR catalyst to facilitate NOX reduction when the A/F mixture supplied to the engine is cycled back to lean. The oxidation catalyst is located upstream of the NH3—SCR catalyst and operates to lower the NO to NO2 molar ratio of the NOX fed to the NH3—SCR catalyst. The oxidation catalyst comprises perovskite oxide particles.
    Type: Grant
    Filed: September 14, 2010
    Date of Patent: September 24, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Wei Li, Chang H Kim, Kevin L. Perry, Paul M. Najt, Kushal Narayanaswamy
  • Patent number: 8540952
    Abstract: An exhaust system, and a catalyzed substrate for use in an exhaust system, is disclosed. The exhaust system comprises a lean NOx trap and the catalyzed substrate. The catalyzed substrate has a first zone, having a platinum group metal loaded on a support, and a second zone, having copper or iron loaded on a zeolite. The first zone or second zone additionally comprises a base metal oxide or a base metal loaded on an inorganic oxide. Also provided are methods for treating an exhaust gas from an internal combustion engine using the exhaust system. The exhaust system is capable of storing NH3 generated in rich purging, reacting the NH3 with slip NOx, controlling H2S released from NOx trap desulfation, and oxidizing slip hydrocarbons and carbon monoxide. When the catalyzed substrate is a filter substrate, it is also capable of removing soot from exhaust system.
    Type: Grant
    Filed: June 18, 2012
    Date of Patent: September 24, 2013
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Daniel Swallow, Andrew Francis Chiffey, Paul Richard Phillips
  • Patent number: 8540953
    Abstract: Utilizing the finding that the state of adsorption of NH3 on a selective reduction type NOx catalyst includes a weakly adsorbed state in which the adsorbed NH3 is useful for a reduction reaction of NOx and a strongly adsorbed state in which the adsorbed NH3 is not useful for the reduction reaction of NOx unless the state of adsorption is changed into the weakly adsorbed state, the apparatus of the invention includes an actual weakly-adsorbed amount-calculation NH3 that is adsorbed on the selective reduction type NOx catalyst in the weakly adsorbed state, and a dispensation control portion that performs a dispensation control of the reductant dispensed by a reductant-dispensation portion, according to the actual weakly adsorbed amount calculated by the actual weakly adsorbed amount calculation portion.
    Type: Grant
    Filed: July 6, 2011
    Date of Patent: September 24, 2013
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Shunsuke Toshioka, Shinya Hirota, Koichiro Fukuda, Takafumi Yamauchi
  • Patent number: 8535628
    Abstract: To overcome the problem of a conventional catalyst and to provide an exhaust gas purifying catalyst that meets the requirement concerning Hg oxidation activity and SO2 oxidation activity; i.e., an exhaust gas purifying catalyst which specifically reduces percent SO2 oxidation, while maintaining percent Hg oxidation at a high level. The invention provides an exhaust gas purifying catalyst which comprises a composition containing oxides of (i) titanium (Ti), (ii) molybdenum (Mo) and/or tungsten (W), (iii) vanadium (V), and (iv) phosphorus (P), wherein the catalyst contains Ti, Mo and/or W, and V in atomic proportions of 85 to 97.5:2 to 10: 0.5 to 10, and has an atomic ratio of P/(sum of V and Mo and/or W) of 0.5 to 1.
    Type: Grant
    Filed: December 31, 2012
    Date of Patent: September 17, 2013
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Yasuyoshi Kato, Keiichiro Kai, Naomi Imada
  • Patent number: 8535627
    Abstract: The present invention is directed at ketone/water mixtures for treating gas mixtures containing nitric oxides (NOx). The chemical reduction of NOx by the ketone/water mixture affords a relatively less objectionable combustion waste product for discharge into the atmosphere. The gas mixture for treatment of the ketone/water mixture may be preferably regulated to have a level of oxygen of at or below 5.0 vol. %.
    Type: Grant
    Filed: December 12, 2012
    Date of Patent: September 17, 2013
    Assignee: Southwest Research Institute
    Inventors: Maoqi Feng, Rijing Zhan
  • Patent number: 8535629
    Abstract: Provided is a catalyst comprising (a) a zeolite material having a mean crystal size of at least about 0.5 ?m, having a CHA framework that contains silicon and aluminum, and having a silica-to-alumina mole ratio (SAR) of about 10 to about 25; and (b) an extra-framework promoter metal (M) disposed in said zeolite material as free and/or exchanged metal, wherein the extra-framework promoter metal is copper, iron, and mixtures thereof, and is present in a promoter metal-to-aluminum atomic ratio (M:Al) of about 0.10 to about 0.24 based on the framework aluminum; and optionally comprising (c) at least about 1 weight percent of cerium in said zeolite material, based on the total weight of the zeolite, wherein said cerium is present in a form selected from exchanged cerium ions, monomeric ceria, oligomeric ceria, and combinations thereof, provided that said oligomeric ceria has a particle size of less than 5 ?m.
    Type: Grant
    Filed: December 2, 2011
    Date of Patent: September 17, 2013
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Todd Howard Ballinger, Philip Gerald Blakeman, Guy Richard Chandler, Hai-Ying Chen, Julian Peter Cox, Joseph M. Fedeyko, Alexander Nicholas Michael Green, Paul Richard Phillips, Stuart David Reid, Erich C. Weigert, James Alexander Wylie
  • Publication number: 20130236380
    Abstract: Disclosed are three-way catalysts that are able to simultaneously convert nitrogen oxides, carbon monoxide, and hydrocarbons in exhaust gas emissions into less toxic compounds. Also disclosed are three-way catalyst formulations comprising palladium (Pd)-containing oxygen storage materials. In some embodiments, the three-way catalyst formulations of the invention do not contain rhodium. Further disclosed are improved methods for making Pd-containing oxygen storage materials. The relates to methods of making and using three-way catalyst formulations of the invention.
    Type: Application
    Filed: August 8, 2012
    Publication date: September 12, 2013
    Applicant: CLEAN DIESEL TECHNOLOGIES, INC.
    Inventors: Stephen J. Golden, Randal Hatfield, Jason D. Pless, Johnny T. Ngo
  • Patent number: 8529853
    Abstract: The present invention relates to application of catalysts for the Selective Catalytic Reduction of oxides of Nitrogen using N-containing reductant. The catalysts are characterized as phase pure lattice oxide materials into which catalytically active cations are incorporated at high levels of dispersion such that conventional analysis reveals a highly phase pure material. The materials are further characterized by high activity, hydrothermal durability and poison tolerance in the intended application.
    Type: Grant
    Filed: March 19, 2011
    Date of Patent: September 10, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Barry W. L. Southward, John G. Nunan
  • Patent number: 8524180
    Abstract: The invention provides a process for minimizing the emission of particulate matter and precursors thereof from a flue gas stream of an engine comprising particulate matter and precursors thereof and at least one gaseous component. The process includes the steps of obtaining a flue gas stream of an engine comprising particulate matter and precursors thereof; increasing the moisture content of the stream by contacting it with a first aqueous medium in an amount and at a temperature at which at least 50% of the water content of the first aqueous medium is evaporated; whereby a moisture laden gas stream, optionally containing suspension droplets, is formed; cooling the moisture laden gas stream whereby suspension droplets are formed; and applying a centrifugal force to the moisture laden gas stream and to the suspension droplets to effect the swirling thereof, whereby a treated gaseous stream and an aqueous stream are formed.
    Type: Grant
    Filed: October 1, 2009
    Date of Patent: September 3, 2013
    Assignees: Vortex Ecological Technologies Ltd., Clue AS, Clean Marine AS
    Inventors: Riki Canari, Aharon Eyal, Nils Christian Hoy-Petersen, Matitiahu Fichman, Carl Christian Hauge, Carmi Raz
  • Patent number: 8524181
    Abstract: The invention relates to a device for the qualitative and/or quantitative determination of at least one component of a chemically reducible gas mixture, an exhaust gas catalytic converter utilizing such a device, a vehicle including such a catalytic converter, a process for preparing such a device, a process for monitoring the NOx emissions of a vehicle, and the use of such a device.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: September 3, 2013
    Assignee: Deutsches Zentrum Fuer Luft-und Raumfahrt e.V.
    Inventors: Bilge Saruhan-Brings, Mathias Christian Stranzenbach, Christoph Leyens
  • Patent number: 8524182
    Abstract: Disclosed is a catalyzed soot filter with layered design wherein the first coating of the filter comprises an oxidation catalyst comprising platinum (Pt) and optionally palladium (Pd), wherein the second coating of the filter comprises an oxidation catalyst comprising Pd and optionally Pt, wherein the Pt concentration in the second coating is lower than the Pt concentration in the first coating, and wherein the weight ratio of Pt:Pd in the second coating is in the range of from 1:1 to 0:1; and wherein the first coating and the second coating are present on the wall flow substrate at a coating loading ratio in the range of from 0.25 to 3, calculated as ratio of the loading of the first coating (in g/inch3 (g/(2.54 cm)3)): loading of the second coating (in g/inch3 (g/(2.54 cm)3)).
    Type: Grant
    Filed: May 11, 2012
    Date of Patent: September 3, 2013
    Assignees: BASF SE, BASF Corporation
    Inventors: Gerd Grubert, Alfred Punke, Torsten Neubauer, Ruediger Wolff, Stanley Roth, Yuejin Li, Torsten Müller-Stach, Marcus Hilgendorff
  • Patent number: 8524183
    Abstract: A composition is described that includes oxides of zirconium, cerium and another rare earth different from cerium, having a cerium oxide content not exceeding 50 wt % and, after calcination at 1000° C. for 6 hours, a maximal reducibility temperature not exceeding 500° C. and a specific surface of at least 45 m2/g. The composition can be prepared according to a method that includes continuously reacting a mixture that includes compounds of zirconium, cerium and another rare earth having a basic compound for a residence time not exceeding 100 milliseconds, wherein the precipitate is heated and contacted with a surfactant before calcination.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: September 3, 2013
    Assignee: Rhodia Operations
    Inventors: Simon Ifrah, Emmanuel Rohart, Julien Hernandez, Stéphane Denaire
  • Patent number: 8518354
    Abstract: A mixture of urea, water and ammonium carbamate is formulated for use in the catalytic reduction of oxides of nitrogen in diesel exhaust. The mixtures may be formulated to optimize the amount of reductant in the mixture and the freezing point of the formulation. These formulations are especially useful in combination with Selective Catalytic Reduction systems and are well suited for use on heavy-duty trucks and heavy duty equipment used off-road. Some of these formations include between about 15.0 wt. % to about 40.0 wt. % urea; between about 15.0 wt. % to about 40.0 wt. % ammonium carbamate; and between about 40.0 wt. % to about 60.0 wt. % water. The formulation may be monitored for ammonia content and/or freezing point and the composition of the formulation may be adjusted to optimize the freezing point and ammonia content.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: August 27, 2013
    Assignee: Deere & Company
    Inventors: Ponnayan Ayyappan, Tom Harris, Danan Dou
  • Patent number: 8518355
    Abstract: A method of using a catalyst comprises exposing a catalyst to at least one reactant in a chemical process. The catalyst comprises copper and a small pore molecular sieve having a maximum ring size of eight tetrahedral atoms. The chemical process undergoes at least one period of exposure to a reducing atmosphere. The catalyst has an initial activity and the catalyst has a final activity after the at least one period of exposure to the reducing atmosphere. The final activity is within 30% of the initial activity at a temperature between 200 and 500° C.
    Type: Grant
    Filed: December 4, 2012
    Date of Patent: August 27, 2013
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Paul Joseph Andersen, Hai-Ying Chen, Joseph Michael Fedeyko, Erich Weigert
  • Publication number: 20130213018
    Abstract: Disclosed are, inter alia, methods of forming coated substrates for use in catalytic converters, as well as washcoat compositions and methods suitable for using in preparation of the coated substrates, and the coated substrates formed thereby. The catalytic material is prepared by a plasma-based method, yielding catalytic material with a lower tendency to migrate on support at high temperatures, and thus less prone to catalyst aging after prolonged use. Also disclosed are catalytic converters using the coated substrates, which have favorable properties as compared to catalytic converters using catalysts deposited on substrates using solution chemistry. Also disclosed are exhaust treatment systems, and vehicles, such as diesel vehicles, particularly light-duty diesel vehicles, using catalytic converters and exhaust treatment systems using the coated substrates.
    Type: Application
    Filed: August 17, 2012
    Publication date: August 22, 2013
    Applicant: SDCmaterials, Inc,
    Inventors: Qinghua YIN, Xiwang QI, Maximilian A. BIBERGER, Jayashir SARKAR
  • Patent number: 8512658
    Abstract: The present invention relates to a method for exhaust gas after-treatment for essentially lean-burn internal combustion engines and also a corresponding advantageous exhaust gas after-treatment system. In particular, the present invention relates to reducing the proportion of the greenhouse gas N20 in the total exhaust gas from a corresponding internal combustion system using at least one NOx storage catalyst as exhaust gas purification element. The objective of the invention is to operate the N20 depletion catalyst located downstream of the NOx storage catalyst under lambda=<1 conditions when the N20 formed by the NOx storage catalyst reaches the N20 depletion catalyst.
    Type: Grant
    Filed: April 5, 2011
    Date of Patent: August 20, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Stephan Eckhoff, Frank Adam, Christian Lammarck
  • Patent number: 8512657
    Abstract: A filter for filtering particulate matter (PM) from exhaust gas emitted from a positive ignition engine or a compression ignition engine, which filter comprising a porous substrate having inlet surfaces and outlet surfaces, wherein the inlet surfaces are separated from the outlet surfaces by a porous structure containing pores of a first mean pore size, wherein the porous substrate is coated with a washcoat comprising a plurality of solid particles wherein the porous structure of the washcoated porous substrate contains pores of a second mean pore size, and wherein the second mean pore size is less than the first mean pore size.
    Type: Grant
    Filed: August 31, 2011
    Date of Patent: August 20, 2013
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Louise Clare Arnold, Robert James Brisley, Christopher Gough Morgan
  • Publication number: 20130210617
    Abstract: A composition based on cerium and niobium oxide in a proportion of niobium oxide of 2% to 20% is described. This composition can include zirconium oxide, optionally 50% of cerium oxide, 2% to 20% of niobium oxide, and at most 48% of zirconium oxide. Also described, is the use of the composition for treating exhaust gases.
    Type: Application
    Filed: July 5, 2011
    Publication date: August 15, 2013
    Applicant: Rhodia Operations
    Inventors: Julien Hernandez, Rui Jorge Coelho Marques, Emmanuel Rohart
  • Patent number: 8506912
    Abstract: A nickel-based catalyst is provided for reducing carbon monoxide, hydrocarbon emissions, and nitrogen oxides from vehicle exhausts. The catalyst is impregnated directly onto a carrier which is non-reactive with nickel. The nickel is contained on said carrier at a loading of between about 2 to about 20 wt %. When used in a vehicle exhaust gas treatment system, the catalyst provides improved efficiency in reducing CO, HC, and NOx emissions over the use of conventional three-way-catalysts.
    Type: Grant
    Filed: February 7, 2012
    Date of Patent: August 13, 2013
    Assignee: Ford Global Technologies, LLC
    Inventors: Jeffrey Scott Hepburn, Hungwen Jen, Eva Thanasiu
  • Publication number: 20130202507
    Abstract: The present invention relates to a method for the treatment of an exhaust gas comprising NOx, wherein the method comprises the step of subjecting the exhaust gas to an exhaust gas treatment system comprising, in order of the exhaust stream: (a) a first NOx storage catalytic converter (2, 2?); (b) a catalytic converter (3) for selective catalytic reduction (SCR) downstream of the first NOx storage catalytic converter; and (C) a catalytic converter (4) having oxygen storage capacity downstream of the SCR catalytic converter; wherein the exhaust gas treatment system is operated in alternating rich and lean phases, wherein the rich phase is terminated when the amount of reducing components leaving the first NOx storage catalytic converter is at least 0.
    Type: Application
    Filed: November 10, 2008
    Publication date: August 8, 2013
    Inventors: Stephan Echoff, Ruediger Hoyer, Susanne Philipp, Ina Grisstede, Wilfried Mueller, Friedemann Rohr
  • Publication number: 20130195741
    Abstract: Catalyzed soot filters comprising a wall flow monolith having a washcoat comprising an alkali base metal composite disposed on the monolith. Methods of manufacturing and using catalyzed soot filters and diesel engine exhaust emission treatment systems are also disclosed.
    Type: Application
    Filed: January 30, 2012
    Publication date: August 1, 2013
    Applicant: BASF Corporation
    Inventors: Michel Deeba, M. Shahjahan Kazi
  • Publication number: 20130195743
    Abstract: A method is described for treating a gas including nitrogen oxides (NOx). The method can include conducting a reduction reaction of the nitrogen oxides with a nitrogen reducing agent. Further described, is a catalyst used for the reduction reaction which is a catalytic system including a composition based on cerium oxide and including niobium oxide in a proportion by a mass of from 2% to 20%.
    Type: Application
    Filed: September 28, 2011
    Publication date: August 1, 2013
    Applicants: MAGNESIUM ELEKTRON LIMITED, RHODIA OPERATIONS
    Inventors: Julien Hernandez, Emmanuel Rohart, Rui Jorge Coelho Marques, Deborah Jayne Harris, Clare Jones
  • Publication number: 20130195742
    Abstract: The invention relates to a mixed salt composition which is useful as a CO2 sorbent. The mixed salt composition comprises a Mg salt, and at least one Group IA element salt, where the Mg and Group IA element are present at a molar ratio of from 3:1 to 8:1. The resulting composition can adsorb about 20% or more of CO2 in a gas. Via varying the molar ratios of the components, and the Group IA element, one can develop compositions which show optional functionality at different conditions. The composition is especially useful in the adsorptive capture of CO2 on mobile sources, such as transportation vehicles, where it can be recovered during regeneration of the adsorbent composition and the CO2 used as a coolant gas, as a reactant in manufacture of fuel, and so forth.
    Type: Application
    Filed: January 18, 2013
    Publication date: August 1, 2013
    Applicant: RESEARCH TRIANGLE INSTITUTE
    Inventor: RESEARCH TRIANGLE INSTITUTE
  • Patent number: 8496896
    Abstract: The present invention relates improving the performance of nitrogen oxide reduction by exposing rich exhaust to catalysts systems comprising a catalyst, wherein the catalyst systems are free of platinum group metals. The present invention also relates to improving reduction of carbon monoxide and hydrocarbon in exhaust by introducing air into a portion of the exhaust between a first catalyst system and a second catalyst system. The present invention also relates to improving nitrogen oxide, carbon monoxide and hydrocarbon reduction by (1) exposing rich exhaust to a first catalysts system, wherein the exhaust has an R value of greater than 1.0 and the first catalyst system comprises a catalyst and is free of platinum group metals and (2) introducing air into a portion of the exhaust in between the first catalyst system and a second catalyst system, wherein the second catalyst system is free of platinum group metals.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: July 30, 2013
    Assignees: Catalytic Solutions, Inc., ECS Holdings, Inc.
    Inventors: Stephen J. Golden, Randal Hatfield, Johnny Ngo, Jason Pless
  • Publication number: 20130189172
    Abstract: The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise selectively catalytically reductive (SCR-active) mixed oxide consisting of cerium oxide, zirconium oxide, rare earth sesquioxide and niobium oxide and optionally tungsten oxide. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, mixed magnesium/aluminum oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.
    Type: Application
    Filed: November 14, 2011
    Publication date: July 25, 2013
    Applicant: UMICORE AG & CO. KG
    Inventors: Paul Spurk, Nicola Soeger, Elena Mueller, Stephan Malmberg
  • Patent number: 8491860
    Abstract: Systems and methods are provided for a layered emission control device coupled to an exhaust manifold. Various formulations may be incorporated in a plurality of layers of the device to enable various emission control functions to be grouped within spatial constraints. For example, a first layer may include a first, oxidizing catalyst, a second layer may include a HC trap, and a third layer may include a second, different oxidizing catalyst, the second layer positioned between the first and third layers. The layers may be organized to reduce functional interference and improve functional synergy between the various emission control functions.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: July 23, 2013
    Assignee: Ford Global Technologies, LLC
    Inventors: Christine Kay Lambert, Douglas Allen Dobson
  • Patent number: 8481453
    Abstract: An apparatus and method for treating diesel exhaust gases are described. The system consists of two functionalities, the first being a selective catalytic reduction (SCR) catalyst system and the second being a capture material for capturing catalyst components such as vanadia that have appreciable volatility under extreme exposure conditions. The SCR catalyst component is typically based on a majority phase of titania, with added minority-phase catalyst components comprising of one or more of the oxides of vanadium, silicon, tungsten, molybdenum, iron, cerium, phosphorous, copper and/or manganese vanadia. The capture material typically comprises a majority phase of high surface area oxides such as silica-stabilized titania, alumina, or stabilized alumina, for example.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: July 9, 2013
    Assignee: Millenium Inorganic Chemicals, Inc.
    Inventor: David M. Chapman
  • Patent number: 8475753
    Abstract: The present invention relates to an exhaust-gas aftertreatment system which comprises a preferably catalytically active particle filter (wall-flow filter) which is followed in turn by a throughflow monolith (flow-through monolith) which is preferably provided with a catalytically active function. Both components have the same storage functions for gaseous substances present in the exhaust gas of internal combustion engines. The system is suitable in particular for the simultaneous removal of particles and pollutants from the exhaust gas of both predominantly lean-operated internal combustion engines and also of internal combustion engines operated predominantly with a stoichiometric air/fuel mixture. Likewise described is a process for the production and the use of such a system for exhaust-gas aftertreatment.
    Type: Grant
    Filed: August 20, 2010
    Date of Patent: July 2, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Stephan Eckhoff, Wilfried Mueller, Joerg-Michael Richter, Stefan Franoschek, Martin Votsmeier
  • Patent number: 8475754
    Abstract: An engine exhaust gas purification device comprising control unit having successively arranged switching device (1), counter-current heat exchanger (3) and at least one exhaust gas purification component (2). The switching device (1) has a first position where a flow path (6) of the exhaust gas to the exhaust gas purification component (2) is opened and a second position where a flow path (6) of the exhaust gas to the exhaust gas purification component (2) is blocked and the exhaust gas flows along a further flow path (7) where the exhaust gas is heated and conveyed, via a flow path (20) of the exhaust gas purification component (2), and exits the exhaust gas purification unit (5) through outlet channels (4) of the counter-current heat exchanger (3). The switching device, the exhaust gas purification component, the counter-current heat exchanger and the flow paths are integrated in a compact exhaust gas treatment unit.
    Type: Grant
    Filed: August 8, 2012
    Date of Patent: July 2, 2013
    Assignee: Universitaet Stuttgart Institut fuer Chemische
    Inventors: Gerhart Eigenberger, Ulrich Nieken, Matthias Rink, Stefan Matschke
  • Patent number: 8475752
    Abstract: The lean NOx trap catalyst composition of the present invention comprises distinct layers, or zone configuration or multi-brick arrangement. The top layer, front zone or front brick is free of any alkali or alkaline earth NOx trapping components. The under layer, rear zone or rear brick may contain any desirable NOx trapping component in contact with a precious metals group catalyst (e.g., Pt). Catalysts of this invention show wide temperature operation window with superior low temperature performance.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: July 2, 2013
    Assignee: BASF Corporation
    Inventor: Chung Z. Wan
  • Publication number: 20130164201
    Abstract: A composition based on cerium, zirconium and tungsten is described. The composition has a content expressed as an oxide, of which cerium is from 5% to 30% of the composition, tungsten is from 2% to 17% of the composition, and the remainder of the composition is zirconium. After aging at 750° C. under an air atmosphere including 10% water, it has a two-phase crystallographic structure having a tetragonal zirconia phase and a monoclinic zirconia phase, with no presence of a crystalline phase including tungsten. The composition can be used as a catalyst, especially in an SCR process.
    Type: Application
    Filed: May 17, 2011
    Publication date: June 27, 2013
    Applicants: MAGNESIUM ELEKTRON LIMITED, RHODIA OPERATIONS
    Inventors: Julien Hernandez, Emmanuel Rohart, Rui Jorge Coelho Marques, Deborah Jane Harris, Clare Jones
  • Patent number: 8473177
    Abstract: Some exemplary embodiments include hybrid vehicle systems including an engine operable to output exhaust, an exhaust aftertreatment system configured to receive the exhaust from the engine, the exhaust aftertreatment system including an SCR catalyst operable to reduce NOx in the exhaust and an electrical heater operable to heat the SCR catalyst, a motor/generator operable in a braking mode to receive torque to slow the vehicle and output electrical power, an energy storage device operable to output electrical power to drive the motor/generator and receive electrical power from the motor/generator, and a controller operable to control the electrical heater to heat the SCR catalyst using electrical power from the motor/generator in the braking mode.
    Type: Grant
    Filed: August 15, 2011
    Date of Patent: June 25, 2013
    Assignee: Cummins, Inc.
    Inventors: Mahesh Madurai Kumar, Morgan M. Andreae, Neal W. Currier
  • Publication number: 20130156669
    Abstract: Disclosed is a catalyst composition for reducing NOx through two steps including reacting NOx with H2 thus producing ammonia which is then reacted with NOx, instead of direct NOx reduction by H2, and a method of reducing NOx using the catalyst composition.
    Type: Application
    Filed: December 21, 2012
    Publication date: June 20, 2013
    Applicant: HEESUNG CATALYSTS CORPORATION
    Inventor: Heesung Catalysts Corporation
  • Publication number: 20130156668
    Abstract: The invention relates to a catalyst for removal of nitrogen oxides from the exhaust gas of diesel engines, and to a process for reducing the level of nitrogen oxides in the exhaust gas of diesel engines. The catalyst consists of a support body of length L and of a catalytically active coating which in turn may be formed from one or more material zones. The material zones comprise a copper-containing zeolite or a zeolite-like compound. The materials used include chabazite, SAPO-34, ALPO-34 and zeolite ?. In addition, the material zones comprise at least one compound selected from the group consisting of barium oxide, barium hydroxide, barium carbonate, strontium oxide, strontium hydroxide, strontium carbonate, praseodymium oxide, lanthanum oxide, magnesium oxide, magnesium/aluminum mixed oxide, alkali metal oxide, alkali metal hydroxide, alkali metal carbonate and mixtures thereof. Noble metal may optionally also be present in the catalyst.
    Type: Application
    Filed: September 8, 2011
    Publication date: June 20, 2013
    Applicant: UMICORE AG & CO. KG
    Inventors: Paul Spurk, Nicola Soeger, Elena Mueller, Stephan Malmberg
  • Patent number: 8460626
    Abstract: The inventive composition, according to a first embodiment, consists essentially of a cerium oxide and a zirconium oxide in an atomic ratio Ce/Zr of at least 1. According to a second embodiment, said composition is based on cerium oxide, zirconium oxide with an atomic ratio Ce/Zr of at least 1 and at least one rare earth oxide other than cerium. After calcination at 1100° C., said composition has a specific surface of at least 9 m2/g in the second embodiment. The inventive composition can be used as a catalyst especially for the treatment of waste gases from internal combustion engines.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: June 11, 2013
    Assignee: Rhodia Electronics and Catalysis
    Inventors: Olivier Larcher, Emmanuel Rohart