Abstract: Active catalysts for the treatment of a low temperature exhaust gas stream are provided for the direct decomposition removal of NOx from an exhaust gas stream. The catalyst system may include a mixed oxide composition including cerium oxide and nickel oxide CeO2—NiO. The exhaust gas stream may be provided at a temperature of from about 400° C. to about 650° C. Methods for making the catalyst include co-precipitation techniques, using KOH as a precipitating agent. The catalyst system is configured to catalyze a decomposition of the NOx to generate N2 without the presence of a reductant. The catalyst may be a cubic structure, with nickel incorporated in a cubic lattice of cerium. The catalyst composition may be represented as Ce0.5Ni0.5O2.

Abstract: The present invention relates to a three-way catalytic converter for reducing harmful exhaust components of gasoline-powered internal combustion engines, and to a corresponding method for exhaust gas purification. The catalytic converter is characterized by a particularly inhomogeneous distribution of the oxygen-storing material present.

Abstract: The present invention is concerned with the use of certain oxygen storage components. In particular, the use of special mixed oxides as oxygen storage components in exhaust catalysis is disclosed.

Abstract: The present invention is concerned with oxygen storage materials. In particular an oxygen storage material (OSM) is proposed which comprises a certain mixed oxide as the oxygen storage component. The oxygen storage material can be used in conventional manner in three-way catalysts or NOx-storage catalysts for example.

Abstract: The present invention is directed to a catalyst system for the reduction of the harmful exhaust-gas constituents hydrocarbons (THC), carbon monoxide (CO), nitrogen oxides (NOx), and the environmentally detrimental secondary emissions ammonia (NH3) and nitrous oxide (N2O) of combustion engines operated using gasoline and to a corresponding method for exhaust-gas purification. The system is characterized by a particular arrangement of catalysts and is used in the case of engines which are operated with predominantly, on average, stoichiometric air/fuel mixtures. Here, a three-way catalyst produced in accordance with the current prior art is preferably installed in a close-coupled position. In the underfloor position, there is situated an SCR catalyst produced in accordance with the current prior art, followed by a further three-way catalyst produced in accordance with the current prior art.

Abstract: This application provides a metallurgical extraction technique, comprising: a) re-pulping a feed filter cake to make a filter cake slurry; b) grinding the filter cake slurry; c) leaching the ground filter cake slurry in a hot alkaline cyanide solution to provide dissolved platinum group metals; d) liquid-solid separating of the dissolved platinum group metals; and e) recovering the dissolved platinum group metals by cementing the dissolved platinum group metals with a precipitating metal comprising an aluminum or a zinc; wherein the feed filter cake has the platinum group metals at a total amount from 0.1 to 1.5 wt % and a halide anion content from zero to less than 4 wt %. This application provides a process for platinum group metal recovery, comprising: converting a catalyst which was in contact with a water reactive ionic liquid catalyst into a non-water reactive filter cake and extracting the platinum group metals.

Abstract: The present invention provides a catalyst composition for producing hydrogen and preparation method and use thereof, wherein the catalyst composition comprises a catalytic component and a supporter having a pyrochlore structure. By using the catalyst composition of the present invention, carbon deposition can be reduced and the oxidative steam reforming of ethanol could be operated for a long period of time with high ethanol conversion rate and selectivity of hydrogen.

Abstract: A dual-layer catalyst includes a substrate, a first layer disposed on the substrate, and a second layer disposed on the first layer. The first layer includes a first catalyst for storing NOx when the first catalyst has a temperature below an active temperature of a second catalyst. The first catalyst is to release the stored NOx when the first catalyst is heated to the active temperature of the second catalyst. The second layer includes the second catalyst for ammonia Selective Catalytic Reduction of the released NOx. The dual-layer catalyst is to be included in a catalytic converter and a catalyst system for reducing NOx emissions from a diesel engine, the NOx emissions including NOx emitted during a predetermined cold-start time period.

Abstract: The present invention relates to a catalyst composition for purifying exhaust gas and an exhaust gas purifying catalyst which contain a manganese-containing composite oxide, and an object of the invention is to provide a novel catalyst composition which can sufficiently function as an exhaust gas purifying catalyst even without supporting a precious metal as a catalytically active component. To achieve the object, there is proposed a catalyst composition for purifying exhaust gas including particles containing a manganese-containing composite oxide and particles containing a metal of Group 5 to Group 11 having an electron in the d orbital (however, Mn, Pt, Rh, and Pd are excluded) or an oxide of the metal in a mixed state.

Abstract: The present invention relates to a catalytically effective composition for a multilayer catalyst for exhaust gas after-treatment of combustion facilities and to a multilayer catalyst containing the catalytically effective composition. Moreover, the invention relates to an exhaust gas after-treatment system and to a vehicle which both contain the catalyst according to the invention.

Abstract: The present invention provides an exhaust gas treatment system comprising an oxidation catalyst and an SCR catalyst, wherein the oxidation catalyst comprises an inert ceramic or metal honeycomb body and a catalytically active coating comprising a platinum group metal supported on a refractory support oxide and lanthanum wherein lanthanum is present in an amount of at least 13% by weight calculated as La2O3 and based on the weight of the refractory support material.

Abstract: The present technology relates to perovskite materials for oxygen storage. In one aspect, the perovskite material includes at least one platinum group metal (PGM) and at least one perovskite compound selected from the group consisting of formula (a): LaxMO3 and formula (b): La(1-y)SryMO3, wherein: M is selected from the group consisting of Co, Cu, Fe, Mn and Ni; x is about 0.7 to about 1.1; and y is 0 to about 0.8, and wherein M, x, and y are independently variable for each one of said perovskite compounds. In one exemplary method, the perovskite materials of the technology are employed to treat automotive exhaust gas. In one embodiment, the perovskite materials are included in the washcoat of an automotive catalytic converter.

Abstract: A poison-resistant catalytic converter includes a washcoat having a support material comprised of titania and/or silica and a plurality of platinum group metal particles disposed in the support material. The washcoat is disposed on a substrate having a plurality of cells that define respective apertures. The catalytic converter is resistant to poisoning from sulfur and phosphorous compounds while operating at low temperatures. Applications include spark ignited internal combustion engines in combined heat and power systems, vehicles, combustion turbines, boilers and other applications for utilities, industry and vehicle emissions control.

Abstract: Disclosed are washcoats, coated substrates formed from such washcoats, and catalytic converters for use in diesel applications, such as heavy duty diesel applications. Methods of preparing the coated substrates are also disclosed.

Abstract: A method utilizes a three-way catalytic converter, having a catalyst formed from a plurality of particles each including a first metal oxide center, a second metal oxide monolayer, and a catalytically active metal to decrease concentration of hydrocarbons, carbon monoxide, and nitrogen oxides in exhaust gas during stoichiometric, rich, and lean conditions, wherein a molar ratio of metal in the monolayers to metal in the centers is between about 0.01 and 0.2.

Abstract: A catalytic converter with excellent OSC performance and Nox purification performance. The catalytic converter includes a substrate with a cell structure and a catalyst layer formed on a cell wall surface of the substrate. The catalyst layer has a catalyst layer arranged on the upstream side and a catalyst layer arranged on the downstream side in an exhaust gas flow direction on the substrate. The catalyst layer on the upstream side includes a support containing an Al2O3—CeO2—ZrO2 ternary composite oxide (ACZ material) and an Al2O3—ZrO2 binary composite oxide (AZ material), and at least Rh that is a noble metal catalyst carried on the support, and the catalyst layer on the downstream side includes a support and Pd or Pt that is a noble metal catalyst carried on the support. In the support in the catalyst layer on the upstream side, the mass proportion of ACZ material/(ACZ material+AZ material) is in the range of 0.33 to 0.

Abstract: An example of a catalytic converter includes a catalyst to improve low temperature oxidation of carbon monoxide (CO) and hydrocarbons. The catalyst includes a support, which includes a porous alumina structure and a rare earth metal oxide promoter impregnated into pores of the porous alumina structure. The rare earth metal oxide promoter is selected from the group consisting of CeO2 and CeO2—ZrO2. A platinum group metal (PGM) is bonded to the support.

Abstract: An oxidation catalyst for treating an exhaust gas from a diesel engine and an exhaust system comprising the oxidation catalyst are described. The oxidation catalyst comprises: a first washcoat region for oxidizing carbon monoxide (CO) and hydrocarbons (HCs), wherein the first washcoat region comprises a first platinum group metal (PGM) and a first support material; a second washcoat region for oxidizing nitric oxide (NO), wherein the second washcoat region comprises platinum (Pt), manganese (Mn) and a second support material; and a substrate having an inlet end and an outlet end; wherein the second washcoat region is arranged to contact the exhaust gas at the outlet end of the substrate and after contact of the exhaust gas with the first washcoat region.

Abstract: An exhaust gas purification system for an internal combustion engine is provided with a filter including a selective catalytic reduction NOx catalyst carried thereon. Further, a post-catalyst is provided for an exhaust gas passage disposed on a downstream side from the filter. The post-catalyst has an oxidizing function, and the post-catalyst has such a function that the production of N2 based on the oxidation of ammonia is facilitated in a predetermined first temperature area. A filter regeneration process execution unit is programmed to control the temperature of the post-catalyst to be in the first temperature area while adjusting the temperature of the filter to be in a predetermined second temperature area lower than a filter regeneration temperature during a certain period of time.

Abstract: The present disclosure is directed at a ruthenium based catalyst for NOx reduction. More specifically, ruthenium based catalysts are used for NOx reduction in an internal combustion engine to reduce NOX to nitrogen, at relatively high conversion and selectivity, using carbon monoxide and hydrogen as reductants. The ruthenium based catalyst has particular utility in exhaust gas recirculation such as in dedicated exhaust gas recirculation (D-EGR) systems.

Abstract: An object of the present invention is to provide an exhaust gas purification catalyst for purifying exhaust gas, in particular, fine composite-metal particles contained therein, and a method for producing the same; the exhaust gas purification catalyst according to the present invention includes fine composite-metal particles containing Rh and Pd, wherein, when the fine composite-metal particles in the exhaust gas purification catalyst are analyzed by STEM-EDX, the average ratio of the amount of Pd with respect to the total amount of Rh and Pd in the fine composite-metal particles is 1.7 atomic % or more and 24.8 atomic % or less.

Abstract: A catalyst system for reducing N2O emissions in the exhaust system of a vehicle is provided and comprises a support in communication with the exhaust gas stream, with the support including an exhaust gas inlet and an exhaust gas outlet. The support has at least one exhaust gas passage therethrough. The support, which may be in the form of a monolithic, multi-cell honeycomb construction, comprises a first catalytic zone and a second catalytic zone positioned downstream from the first zone. The first catalytic zone includes rhodium or a rhodium-enriched catalyst, while the second catalytic zone includes palladium or a palladium-enriched catalyst.

Abstract: A layered catalyst composite for the treatment of exhaust gas emissions, effective to provide lean NOx trap functionality and three-way conversion functionality is described. Layered catalyst composites can comprise catalytic material on a substrate, the catalytic material comprising at least two layers. The first layer comprising rare earth oxide-high surface area refractory metal oxide particles, an alkaline earth metal supported on the rare earth oxide-high surface area refractory metal oxide particles, and at least one first platinum group metal component supported on the rare earth oxide-high surface area refractory metal oxide particles. The second layer comprising a second platinum group metal component supported on a first oxygen storage component (OSC) and/or a first refractory metal oxide support and, optionally, a third platinum group metal supported on a second refractory metal oxide support or a second oxygen storage component.

Abstract: Crystalline molecular sieves and their synthesis using quaternary N-methyl-diisoalkylammonium cations as organic structure directing agents are disclosed. The structure directing agent has the following structure (1): in which R1 is selected from hydrogen, a methyl group, an ethyl group, a propyl group, and a hydroxymethyl group; and R2, R3, R4 and R5 are independently selected from a methyl group, an ethyl group, and a propyl group.

Abstract: A method of stabilizing electromagnetically charged particles, which includes coating electromagnetically charged particles with a protective layer; and etching the protective layer to produce a porous protective layer on the electromagnetically charged.

Abstract: An oxidation catalyst for treating an exhaust gas from a compression ignition engine, which oxidation catalyst comprises: a first washcoat region comprising platinum (Pt) and a first support material, wherein the first washcoat region is substantially free of a hydrocarbon adsorbent; a second washcoat region comprising platinum (Pt), palladium (Pd) and a second support material, wherein the second washcoat region has a ratio by mass of platinum (Pt) to palladium (Pd) of 4:1 to 1:1; a hydrocarbon adsorbent; and a substrate; wherein the first washcoat region is arranged to contact inlet exhaust gas before the hydrocarbon adsorbent, and the first washcoat region is arranged to contact inlet exhaust gas before the second washcoat region.

Abstract: A three-way catalyst composition, and its use in an exhaust system for internal combustion engines, is disclosed. The three-way catalyst composition comprises rhodium, a cerium-containing oxide, and a supported palladium component. The supported palladium component comprises palladium, barium, and cobalt and alumina. The three-way catalyst composition shows improved light-off performance.

Abstract: A supported precious metal catalyst for the high-temperature combustion of a hydrocarbon includes 1-10% by weight in total of one or more precious metals on a refractory metal oxide support material, and 1-20% by weight in total of one or more stabilizing metals selected from rare earths and Groups IA, IIA, and IIIA of the periodic table of the elements, wherein at least part of the precious metal is present as a mixed metal oxide with one or more of the stabilizing metals.

Abstract: A method of making for aluminosilicate zeolite SSZ-98 is disclosed using a structure directing agent selected from trimethylphenylammonium cations, cationic 1,4-diazabicyclo[2.2.2]octane, and combinations thereof.

Abstract: A three-way catalyst is disclosed. The three-way catalyst comprises a palladium component comprising palladium and a ceria-zirconia-alumina mixed or composite oxide, and also comprises a rhodium component comprising rhodium and a zirconia-containing material. The palladium component and the rhodium component are coated onto a silver-containing extruded molecular sieve substrate. The invention also includes an exhaust system comprising the three-way catalyst. The three-way catalyst results in improved hydrocarbon storage and conversion, in particular during the cold start period.

Abstract: An exhaust system for a diesel engine is disclosed. The exhaust system may include a diesel oxidation catalyst (DOC) configured to receive exhaust gases from the engine and oxidize hydrocarbons in the exhaust gases and a passive NOx adsorber (PNA) downstream from the DOC and configured to store NOx from the exhaust gases at temperatures up to 150° C. A selective catalytic reduction (SCR) system may be downstream from the PNA and configured to reduce NOx in the exhaust gases. The PNA may be configured to release the stored NOx at temperatures above 200° C. The DOC upstream of the PNA may reduce the amount of N2O that is generated by the PNA by oxidizing hydrocarbons before they reach the PNA.

Abstract: An emissions control device for a compression ignition engine is described. The emissions control device comprises: (a) a first catalyst comprising an electrically heatable substrate and a first composition disposed on the electrically heatable substrate, wherein the first composition comprises alumina and a first platinum group metal (PGM); and (b) a second catalyst comprising a substrate and a second composition disposed on the substrate, wherein the second composition comprises alumina and a second platinum group metal (PGM); wherein the loading of the first composition is less than the loading of the second composition.

Abstract: An oxidation catalyst for treating an exhaust gas from a diesel engine, which oxidation catalyst comprises: a first washcoat region comprising a first platinum group metal (PGM), a first support material and a NOx storage component; a second washcoat region comprising platinum (Pt), manganese (Mn) and a second support material; and a substrate having an inlet end and an outlet end.

Abstract: An exhaust gas controlling catalyst includes zirconia particles; ceria particles which contact the zirconia particles, of which a mean particle size is smaller than a mean particle size of the zirconia particles; and an active metal that is supported on at least the ceria particles in a dispersed manner.

Abstract: The object of the present invention is to provide an exhaust gas purifying catalyst, exhibits excellent performance for methane purification. The object can be solved by the exhaust gas purifying catalyst comprising a substrate and a catalyst layer provided on the substrate, in which the catalyst layer comprises at least one member selected from the group consisting of vanadium, niobium and tantalum; and platinum, and/or palladium.

Abstract: In an exhaust gas purification catalyst system for use in an automobile including an exhaust gas purification catalyst product disposed in both a front section and a rear section, the exhaust gas purification catalyst product of the front section has a layered catalyst including a lower layer which contains aluminum borate.

Abstract: Close-coupled catalysts (CCC) for TWC applications are disclosed. The novel CCCs are implemented using light-weighted ceramic substrates in which a thin coating employing a low loading of Iron (Fe)-activated Rhodium (Rh) material composition, with Iron loadings and an OSM of Ceria-Zirconia, are deposited onto the substrates. Different CCC samples are produced to determine and/or verify improved light-off (LO) and NOX conversion of the CCCs. Other CCC samples produced are a CCC including a standard (non-activated) Rh thin coating and a heavily loaded CCC with a single coating of Pd/Rh material composition. The CCC samples are aged under dyno-aging using the multi-mode aging cycle and their performance tested using a car engine with ports on the exhaust to measure the emissions, according to the testing protocol in the Environmental Protection Agency Federal Test Procedure 75. During testing, the thin coatings of Fe-activated Rh exhibit improved light-off and NOx conversion efficiency.

Abstract: An exhaust gas purify catalyst includes a substrate (1), an oxidation catalyst layer (2) formed on the substrate (1) and containing zeolite and at least one catalytic metal, an LNT layer (3) formed on the oxidation catalyst layer (2) and containing an NOx storage material and at least one catalytic metal, and an NOx reduction layer (4) formed on the LNT layer (3) and containing Rh acting as a catalytic metal and at least one of alumina or zirconia, wherein the NOx reduction layer (4) has a larger content of Rh than that in each of the oxidation catalyst layer (2) and the LNT layer (3).

Abstract: Synergized Platinum Group Metals (SPGM) catalyst system for TWC application is disclosed. Disclosed SPGM catalyst system may include a washcoat that includes stoichiometric Cu—Mn spinel structure, supported on doped ZrO2, and an overcoat that includes PGM, such as platinum (Pt) supported on carrier material oxides, such as alumina. SPGM catalyst system shows significant improvement in nitrogen oxide reduction performance under lean and also rich operating conditions. Additionally, disclosed SPGM catalyst system exhibits enhanced catalytic activity for carbon monoxide conversion. Furthermore, disclosed SPGM catalyst systems are found to have enhanced catalytic activity compared to PGM catalyst system, showing that there is a synergistic effect between PGM catalyst, such as Pt, and Cu—Mn spinel within disclosed SPGM catalyst system, which help in activity and thermal stability of disclosed SPGM catalyst.

Abstract: A diesel oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the reduction of nitrogen oxides (NOx) is described. More particularly, the present invention is directed to a washcoat composition comprising high silica to alumina zeolite and platinum and palladium such that the zeolite minimizes negative interactions of these platinum group metals with the zeolite.

Abstract: A three-way catalytic material that reduces NOx in an oxidizing atmosphere and a process for reducing NOx in an oxidizing atmosphere. The material is a mixed metal oxide catalyst and can be made from a doped barium cerate matrix with a chemical formula of BaAyDzCe(1-y-z)O3-?, where A is a precious metal or a combination of two or more precious metals and D is at least one transition metal. The coefficient y has a value between 0.0 and 0.20, inclusive, and the coefficient z has a value between 0.0 and 0.20, inclusive, and ? has a value between 0.00 and 0.20, inclusive.

Abstract: The present invention provides a non-PGM catalyst for burning carbon soot without using a noble metal, the non-PGM catalyst comprising: a cerium-praseodymium complex oxide and an iron oxide, the cerium-praseodymium complex oxide impregnated with silver (Ag). The cerium-praseodymium complex oxide illustratively consists of 60 to 95 wt % of cerium oxide and 5 to 40 wt % of praseodymium oxide, and silver (Ag) impregnated in the complex oxide is 1.5 to 3.0 parts by weight of the total weight of the complex oxide. The iron oxide may be an oxide in a form of particles separate from the cerium-praseodymium complex oxide in which silver is impregnated, and may be 0.5 to 2 parts by weight of the total weight of the cerium praseodymium complex oxide.

Abstract: The object of the present invention is to provide a novel exhaust gas purifying catalyst having excellent NOx purification performance. The object can be achieved by an exhaust gas purifying catalyst comprising: a substrate; and a catalyst layer disposed on the substrate which comprises a first carrier, and platinum and a first palladium supported on the first carrier; in which the weight ratio of the platinum to the first palladium is 3:1 to 8:1.

Abstract: The present invention describes a three-way-catalyst system comprising a first three-way catalyst on an inert catalyst support which is a double-layer catalyst comprising a first layer on the inert catalyst support, comprising active alumina, a cerium/zirconium mixed oxide and palladium and a second layer applied to the first layer and in direct contact with the exhaust gas to be purified, comprising active alumina and rhodium and being free of cerium and cerium containing materials and a second three-way-catalyst located upstream of the first three-way catalyst.

Abstract: A double-layer three-way catalyst is presented, which is formed from a catalytic coating applied directly to an inert honeycomb and a catalytically active coating thereon, and is suitable especially for cleaning of exhaust gases of motor vehicles with gasoline-operated internal combustion engines. The catalyst contains, in each layer, an active aluminum oxide and a cerium/zirconium mixed oxide, both of which are catalytically activated by palladium. The second layer on the gas side contains not only palladium but also rhodium, which is applied to the active aluminum oxide and the cerium/zirconium mixed oxide of the second layer in addition to the palladium. The cerium/zirconium mixed oxide of the second layer has a higher zirconium oxide content than the cerium/zirconium mixed oxide of the first layer. The catalyst is notable for exceptional activity coupled with outstanding aging stability.

Abstract: Systems and methods for managing aftertreatment systems that include passive NOx adsorption devices and SCR catalyst elements are disclosed. Temperature generation devices upstream of the passive NOx adsorption devices facilitate control of the aftertreatment systems to improve fuel economy and NOx conversion efficiency.

Abstract: A method is described for preparing a catalyst suitable for use in a steam reforming process, including the steps of: (i) spraying a slurry containing a particulate catalyst compound, including one or more catalytic metals selected from the group consisting of Ni, Cu, Pt, Pd, Rh, Ru and Au, on to the surface of a shaped support in a pan coater to form a coated shaped support material having the catalytic metal in a surface layer, (ii) drying and optionally calcining the coated shaped support material to form a catalyst precursor, and (iii) optionally reducing the metal or metals in the catalyst precursor to a lower oxidation state to form the catalyst. The egg-shell catalyst is useful for performing a steam reforming reaction.

Abstract: A method of preparing a catalyst coating solution may realize high purification performance by preventing the active surface of a catalyst from being reduced, and may greatly improve the durability of a catalyst by preventing soot from directly coming into contact with a catalyst layer containing a precious metal so that the catalyst layer can continuously exhibit proper purification performance. A method of manufacturing a catalyst body using the catalyst coating solution, and a catalyst body manufactured by the method are also described.

Abstract: A NOx trap, and its use in an exhaust system for internal combustion engines, is disclosed. The NOx trap comprises a substrate and three layers on the substrate. The first layer comprises a first platinum group metal, a first NOx storage component, and a first support; the second layer comprises a second platinum group metal, a second NOx storage component, and a second support; and the third layer comprises rhodium and a third support. The platinum group metal loading in the first layer is from 1 to 40 percent of the platinum group metal loading in the second layer. In addition, the first NOx storage component and the second NOx storage component are the same, and the first support and the second support are the same. The NOx trap is less prone to deactivation over numerous desulfation/NOx trap regeneration cycles.

Abstract: The present invention describes a double-layer three-way catalyst on an inert catalyst support comprising a first layer in direct contact with the inert catalyst support, comprising active alumina, a cerium/zirconium mixed oxide and palladium and a second layer applied to the first layer and in direct contact with the exhaust gas to be purified, comprising active alumina and rhodium, characterized in that the second layer is free of cerium and cerium containing materials, the use of such catalyst for cleaning the exhaust gases of a motor vehicle equipped with a gasoline engine and an exhaust gas treatment system comprising such catalyst up stream of a gasoline particulate filter (GPF).