Group Viii Element Patents (Class 423/213.5)
  • Patent number: 9480948
    Abstract: An exhaust gas purification catalyst apparatus, which is superior in oxidation performance of, in particular, nitrogen monoxide, among hydrocarbons, carbon monoxide, nitrogen oxides and particulate components such as soot, included in exhaust gas from a lean burn engine, and combustion performance of light oil. The exhaust gas purification apparatus arranged with an oxidation catalyst (DOC) comprising a noble metal component for oxidizing carbon monoxide, hydrocarbons, in particular, nitrogen monoxide among nitrogen oxides, and for combusting light oil, a catalyzed soot filter (CSF) including a noble metal component for collecting a particulate component such as soot and removing by combustion (oxidation). The oxidation catalyst (DOC) has a catalyst layer where platinum (Pt), palladium (Pd) and barium oxide (BaO) are supported on alumina (Al2O3) having a pore size of 12 to 120 nm, and ratio of platinum and palladium is 1:1 to 11:2 in weight equivalent.
    Type: Grant
    Filed: April 9, 2013
    Date of Patent: November 1, 2016
    Assignee: N.E. CHEMCAT CORPORATION
    Inventors: Toshinori Okajima, Makoto Nagata
  • Patent number: 9475038
    Abstract: This disclosure is directed to uses for a new crystalline molecular sieve designated SSZ-99. SSZ-99 is synthesized using a methylethyldiisopropylammonium cation as a structure directing agent.
    Type: Grant
    Filed: February 19, 2015
    Date of Patent: October 25, 2016
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Stacey Ian Zones, Dan Xie, Cong-Yan Chen, Ann Jia-Bao Liang
  • Patent number: 9475004
    Abstract: The present disclosure describes rhodium iron catalysts of use in catalyst systems. Disclosed here are TWCs configured to include a substrate and one or more of a washcoat layer, an impregnation layer, and/or an overcoat layer. Disclosed herein are one or more of a washcoat layer and/or an overcoat layer formed using a slurry that includes one or more of an oxygen storage material, a refractory support oxide, iron, and rhodium. Disclosed herein are methods of preparing catalysts wherein a washcoat layer is deposited onto the substrate, one or more impregnation layers may be deposited onto the washcoat layer, one or more overcoat layers may be deposited onto the impregnation washcoat layer, and one or more additional impregnation layers may be deposited onto the one or more washcoat layers.
    Type: Grant
    Filed: June 5, 2015
    Date of Patent: October 25, 2016
    Assignee: Clean Diesel Technologies, inc.
    Inventors: Randal L. Hatfield, Stephen J. Golden, Johnny T. Ngo
  • Patent number: 9461324
    Abstract: Provided is an autothermal reforming catalyst for a fuel cell, including: a monolithic catalyst; and a support formed on the monolithic catalyst, wherein the support is a metal foam, a metal mesh or a monolithic structure.
    Type: Grant
    Filed: April 2, 2014
    Date of Patent: October 4, 2016
    Assignee: H&POWER, INC.
    Inventors: Jin Woo Park, Woo Jin Kang, In Yong Kang, Joong Myeon Bae
  • Patent number: 9452421
    Abstract: A method of making a catalyst comprises: mixing three or more catalytically active components with water to form an impregnating solution; contacting a support with the impregnating solution; impregnating the catalytically active components onto the support to form an impregnated support; and calcining the impregnated support to form a catalyst. Another method of making a catalyst comprises: co-impregnating a support with three or more catalytically active components in an impregnating solution to form an impregnated support; and calcining the impregnated support to form the catalyst.
    Type: Grant
    Filed: March 5, 2014
    Date of Patent: September 27, 2016
    Assignee: SAUDI BASIC INDUTRIES CORPORATION
    Inventors: James William Kauffman, Patricia Ann Hooks, Balamurali Krishna Nair
  • Patent number: 9440223
    Abstract: An exhaust gas purification catalyst is provided with a substrate and a catalyst coating layer formed on the surface of the substrate. The catalyst coating layer is formed into a layered structure having upper and lower layers, with a lower layer being closer to the surface of the substrate and an upper layer being relatively farther therefrom. The catalyst coating layer is provided with Rh and Pd as precious metal catalysts and is provided with an OSC material having an oxygen storage capacity as a support. The Rh is disposed in the upper layer of the catalyst coating layer, and the Pd is disposed in both the upper layer and the lower layer of the catalyst coating layer. At least a portion of the Pd in the upper layer and in the lower layer is supported on the OSC material. The mass ratio of the Pd disposed in the upper layer to the Pd disposed in the lower layer is not more than 0.4.
    Type: Grant
    Filed: December 26, 2012
    Date of Patent: September 13, 2016
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Yuki Aoki
  • Patent number: 9427730
    Abstract: Bimetallic Synergized Platinum Group Metals (SPGM) catalyst systems for TWC application are disclosed. Disclosed bimetallic SPGM catalyst systems may include a washcoat with a Cu—Mn spinel structure and an overcoat that includes PGMs, such as Pd/Rh or Pt/Rh supported on carrier material oxides, such as alumina. Bimetallic SPGM catalyst systems show significant improvement in nitrogen oxide reduction performance under lean operating conditions, which allows a reduced consumption of fuel. Additionally, disclosed bimetallic SPGM catalyst systems exhibit enhanced catalytic activity for carbon monoxide conversion. Furthermore, bimetallic SPGM catalyst systems are found to have enhanced catalytic activity for fresh, hydrothermally aged and fuel cut aged conditions compared to PGM catalyst system, showing that there is a synergistic effect between PGM catalyst and Cu—Mn spinel within the disclosed SPGM catalyst system which help in performance and thermal stability of disclosed SPGM catalyst systems.
    Type: Grant
    Filed: November 17, 2014
    Date of Patent: August 30, 2016
    Assignee: Clean Diesel Technologies, Inc.
    Inventors: Zahra Nazarpoor, Stephen J. Golden
  • Patent number: 9427732
    Abstract: Disclosed are washcoats, coated substrates formed from such washcoats, and catalytic converters for use in diesel applications, such as heavy duty diesel applications. Methods of preparing the coated substrates are also disclosed.
    Type: Grant
    Filed: October 22, 2014
    Date of Patent: August 30, 2016
    Assignee: SDCmaterials, Inc.
    Inventors: Qinghua Yin, Xiwang Qi, Maximilian A. Biberger
  • Patent number: 9421528
    Abstract: A catalyst that is not only capable of efficiently treating CO even at a low exhaust gas temperature, but also capable of exerting favorable CO purification efficiency in a low-temperature exhaust gas even in a case of being exposed for a long time to an engine exhaust gas that is a high temperature and contains HC, CO, NOx, water vapor and the like; and an exhaust gas treatment technique are described. The catalyst for purifying exhaust gas contains: a noble metal; an oxide containing as a base material A at least two kinds of elements selected from the group consisting of aluminum, zirconium and titanium; and an oxide containing as a base material B at least one kind of element selected from the group consisting of silicon, cerium, praseodymium and lanthanum; in which the base material A and the base material B satisfy a specific formula.
    Type: Grant
    Filed: February 24, 2014
    Date of Patent: August 23, 2016
    Assignee: UMICORE SHOKUBAI JAPAN CO., LTD.
    Inventors: Yosuke Goto, Naohiro Kato, Yuta Akasaka, Shota Kawashima
  • Patent number: 9416017
    Abstract: A method is disclosed for making a new crystalline molecular sieve designated SSZ-98. SSZ-98 has the ERI framework type and is synthesized using a N,N?-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent.
    Type: Grant
    Filed: July 3, 2014
    Date of Patent: August 16, 2016
    Assignee: Chevron U.S.A. Inc.
    Inventors: Dan Xie, Stacey Ian Zones, Christopher Michael Lew, Tracy Margaret Davis
  • Patent number: 9409786
    Abstract: A new crystalline molecular sieve designated SSZ-98 is disclosed. SSZ-98 has the ERI framework type and is synthesized using a N,N?-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent.
    Type: Grant
    Filed: July 3, 2014
    Date of Patent: August 9, 2016
    Assignee: CHEVRON U.S.A. INC.
    Inventors: Dan Xie, Stacey Ian Zones, Christopher Michael Lew, Tracy Margaret Davis
  • Patent number: 9403157
    Abstract: A three-way catalyst including a mixture of nickel and copper is provided for reducing carbon monoxide, hydrocarbon emissions, and nitrogen oxides from vehicle engine exhausts. The catalyst is impregnated onto a carrier substrate which is non-reactive with nickel and copper. When used in a vehicle exhaust gas treatment system, the nickel-copper catalyst provides improved efficiency in reducing CO, HC, and NOx emissions over the use of conventional three-way-catalysts and provides enhanced oxygen storage capacity (OSC) and water-gas-shift (WGS) functions.
    Type: Grant
    Filed: April 29, 2013
    Date of Patent: August 2, 2016
    Assignee: Ford Global Technologies, LLC
    Inventors: Hungwen Jen, Eva Thanasiu, Jeffrey Scott Hepburn
  • Patent number: 9393551
    Abstract: Disclosed is a catalyst for reforming a tar-containing gas, wherein the catalyst contains at least one composite oxide as oxide containing nickel, magnesium, cerium and aluminum and the content of alumina as a single compound is limited to 5% by mass or less.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: July 19, 2016
    Assignee: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Kimihito Suzuki, Kenichiro Fujimoto
  • Patent number: 9358504
    Abstract: The present invention provides a non-PGM catalyst for burning carbon soot without using a noble metal, the non-PGM catalyst comprising: a cerium-praseodymium complex oxide and an iron oxide, the cerium-praseodymium complex oxide impregnated with silver (Ag). The cerium-praseodymium complex oxide illustratively consists of 60 to 95 wt % of cerium oxide and 5 to 40 wt % of praseodymium oxide, and silver (Ag) impregnated in the complex oxide is 1.5 to 3.0 parts by weight of the total weight of the complex oxide. The iron oxide may be an oxide in a form of particles separate from the cerium-praseodymium complex oxide in which silver is impregnated, and may be 0.5 to 2 parts by weight of the total weight of the cerium praseodymium complex oxide.
    Type: Grant
    Filed: August 10, 2015
    Date of Patent: June 7, 2016
    Assignees: Hyundai Motor Company, Heesung Catalysts Corporation
    Inventors: Sung Mu Choi, Jung Min Seo, Hyun Sik Han, Eun Seok Kim, Jeong Bae Lee
  • Patent number: 9346019
    Abstract: The present invention relates to a diesel particle filter which has a coating active in oxidation catalysis and which is characterized in that said diesel particle filter comprises a material zone which removes platinum traces contained in the exhaust-gas flow, and to the use of said diesel particle filter in the purification of exhaust gases of diesel engines.
    Type: Grant
    Filed: April 17, 2013
    Date of Patent: May 24, 2016
    Assignee: Umicore AG & CO. KG
    Inventors: Marcus Pfeifer, Michael Schiffer, Franz Dornhaus, Stephan Basso, Frank-Walter Schuetze
  • Patent number: 9308516
    Abstract: Provided is a novel catalyst carrier for exhaust gas which relates to an OSC material containing a ceria-zirconia composite oxide and is able to enhance the low temperature properties and to exert excellent OSC even at the time of engine start and excellent exhaust gas purification performance. A catalyst carrier for exhaust gas containing a fluorite type ceria-zirconia composite oxide and ceria formed from the fluorite type ceria-zirconia composite oxide by phase separation proposed.
    Type: Grant
    Filed: July 12, 2013
    Date of Patent: April 12, 2016
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Ohki Houshito, Yunosuke Nakahara
  • Patent number: 9303544
    Abstract: A method of detecting a thermal event is provided that relies not only on monitored exhaust temperatures, but also on temperature gradients propagating in the direction of exhaust flow. Specifically, the method of detecting a thermal event in a vehicle exhaust system includes monitoring at least one operating parameter at multiple locations spaced in exhaust flow of the vehicle exhaust system. The method then includes initiating a protective action if the monitoring indicates that at least one respective predetermined temperature requirement and a respective predetermined temperature gradient requirement are exceeded at two of the multiple temperature sensor locations within a predetermined time period.
    Type: Grant
    Filed: January 18, 2012
    Date of Patent: April 5, 2016
    Assignee: GM Global Technology Operations LLC
    Inventors: Benjamin Radke, Vincent J. Tylutki, Janean E. Kowalkowski
  • Patent number: 9283519
    Abstract: A wall-flow filter for filtering particulate matter from a flowing exhaust gas comprises a catalyst for catalyzing both the conversion of solid carbon in the particulate matter by oxygen and the selective reduction of oxides of nitrogen in the exhaust gas with a nitrogenous reductant, which catalyst comprising optionally stabilized ceria and at least one metal selected from (i) tungsten and (ii) both tungsten and iron.
    Type: Grant
    Filed: February 1, 2011
    Date of Patent: March 15, 2016
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Jillian Elaine Collier, Ralf Dotzel, Sylvie Cécile Laroze, Rainer Leppelt, Paul James Millington, Jörg Werner Münch, Raj Rao Rajaram, Hubert Schedel
  • Patent number: 9273593
    Abstract: An ECU alternatively changes a target air-fuel ratio At to a rich side and a lean side by active air-fuel ratio control. The ECU measures an oxygen storage capacity OSC of an exhaust purification catalyst based on an oscillation period of the target air-fuel ratio At and the target aft-fuel ratio At, and executes a deterioration determination with respect to the exhaust purification catalyst based on the measurement value. When executing the deterioration determination, the ECU closes a waste gate valve to prevent a decrease in the accuracy of the deterioration determination that is caused by two kinds of exhaust gas whose flow paths are different from each other arriving at the area surrounding an air-fuel ratio sensor.
    Type: Grant
    Filed: December 24, 2010
    Date of Patent: March 1, 2016
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Akira Sato
  • Patent number: 9254475
    Abstract: An exhaust gas purification catalyst includes a composite oxide support, and a precious metal catalyst supported on the composite oxide support. The composite oxide support includes alumina, zirconia, ceria, a first additive element oxide and a second additive element oxide. The first additive element oxide contains an additive element selected from the group consisting of rare earth elements excluding cerium and alkali earth elements. The second additive element oxide contains an additive element selected from the group consisting of rare earth elements excluding cerium and alkali earth elements. In the composite oxide support, alumina is contained in a range of 30 to 40% by mass and zirconia is contained in a range of 36 to 46% by mass.
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: February 9, 2016
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Yoshinori Saito, Yuki Aoki, Toshitaka Tanabe, Miho Hatanaka, Naoki Takahashi, Akira Morikawa
  • Patent number: 9207202
    Abstract: A gas sensor element has a solid electrolyte of an oxygen ion conductivity, a target gas electrode formed on one surface of the solid electrolyte, a reference gas electrode formed on the other surface of the solid electrolyte, a porous diffusion resistance layer through which the target gas passes to reach the target gas electrode, and a catalyst layer formed on an outer surface of the porous diffusion resistance layer. The target gas electrode is formed around the porous diffusion resistance layer. The catalyst layer contains noble metal catalysts. The noble metal catalysts contain at least rhodium and palladium. A content of rhodium is not less than 10 mass % and a content of palladium is not less than 20 mass % to the entire of the noble metal catalysts.
    Type: Grant
    Filed: April 23, 2010
    Date of Patent: December 8, 2015
    Assignees: DENSO CORPORATION, NIPPON SOKEN, INC.
    Inventors: Yasufumi Suzuki, Masatoshi Ikeda
  • Patent number: 9194266
    Abstract: A power system includes a dual fuel engine, a first fuel source configured to provide a first fuel to the engine, and a second fuel source configured to provide a second fuel to the engine different than the first fuel. The power system also includes an exhaust system configured to receive combustion exhaust from the engine. The exhaust system includes a reduction catalyst comprising palladium catalyst material and an oxidation catalyst comprising cobalt catalyst material. Additionally, changing a ratio of the first fuel provided to the engine relative to the second fuel changes a NOx conversion efficiency of the reduction catalyst.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: November 24, 2015
    Assignee: Caterpillar Inc.
    Inventors: Ronald Graham Silver, Paul Sai Keat Wang, David T. Montgomery
  • Patent number: 9180437
    Abstract: Provided are a method of preparing a magnesium oxide structure and a magnesium oxide structure prepared by using the method. The magnesium oxide structure has meso-macro pores, a large specific surface area, and high strength, thereby enabling production of a catalyst with high catalytic activity.
    Type: Grant
    Filed: November 9, 2012
    Date of Patent: November 10, 2015
    Assignee: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Sang Woo Kim, In Ho Kim, Dong Ju Moon
  • Patent number: 9114385
    Abstract: A NOx absorber catalyst comprising a substrate monolith coated with one or more washcoat layers and comprising a first component comprising a nitrogen oxide storage component, at least one precious metal and a dispersed rare earth oxide supported on a refractory support material, and a second component comprising a precious metal supported on a bulk reducible oxide that is substantially free of nitrogen oxide storage material, wherein the precious metal present in the second component comprises Pt, Pd or a combination of both Pt and Pd and wherein the bulk reducible oxide is an oxide, a composite oxide or a mixed oxide comprising at least one of manganese, iron, cobalt, copper, tin or cerium.
    Type: Grant
    Filed: December 21, 2011
    Date of Patent: August 25, 2015
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Robert James Brisley, Kenneth David Camm, Noelia Cortes Felix, Fiona-Mairead McKenna, Paul James Millington, Elizabeth Hazel Mountstevens, Daniel Swallow
  • Patent number: 9062265
    Abstract: A diesel fuel composition comprising, as an additive, a quaternary ammonium salt formed by the reaction of a compound of formula (A): and a compound formed by the reaction of a hydrocarbyl-substituted acylating agent and an amine of formula (B1) or (B2): wherein R is an optionally substituted alkyl, alkenyl, aryl or alkylaryl group; R1 is a C1 to C22 alkyl, aryl or alkylaryl group; R2 and R3 are the same or different alkyl groups having from 1 to 22 carbon atoms; X is an alkylene group having from 1 to 20 carbon atoms; n is from 0 to 20; m is from 1 to 5; and R4 is hydrogen or a C1 to C22 alkyl group.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: June 23, 2015
    Assignee: Innospec Limited
    Inventors: Jacqueline Reid, Vincent Burgess, Simon Mulqueen
  • Patent number: 9044734
    Abstract: The present invention relates to a layered diesel oxidation catalyst (DOC) comprising: a) a carrier substrate; b) a diesel oxidation catalytic material comprising b1) a first layer located on the carrier substrate, the first layer comprising palladium impregnated on a support material comprising ceria in an amount of at least 45 weight-% based on the total weight of the support material, and optionally comprising platinum; b2) a second layer located on the first layer, the second layer comprising palladium and platinum each impregnated on a support material comprising a metal oxide; wherein the platinum to palladium weight ratio of the first layer is lower than the platinum to palladium weight ratio of the second layer.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: June 2, 2015
    Assignees: BASF SE, BASF CORPORATION
    Inventors: Gerd Grubert, Torsten Neubauer, Alfred Punke, Marcus Hilgendorff, Torsten Müller-Stach, Olga Gerlach, Xinyi Wei, Jeffrey Hoke, Shiang Sung, Stanley Roth
  • Publication number: 20150147251
    Abstract: Synergized Platinum Group Metals (SPGM) catalyst system for TWC application is disclosed. Disclosed SPGM catalyst system may include a washcoat with a Cu—Mn spinel structure and an overcoat that includes PGM supported on carrier material oxides, such as alumina. SPGM catalyst system shows significant improvement in nitrogen oxide reduction performance under stoichiometric operating conditions and especially under lean operating conditions, which allows a reduced consumption of fuel. Additionally, disclosed SPGM catalyst system also enhances the reduction of carbon monoxide and hydrocarbon within catalytic converters. Furthermore, disclosed SPGM catalyst systems are found to have enhanced catalyst activity compared to commercial PGM catalyst system, showing that there is a synergistic effect among PGM catalyst and Cu—Mn spinel within the disclosed SPGM catalyst system.
    Type: Application
    Filed: September 29, 2014
    Publication date: May 28, 2015
    Inventors: Zahra Nazarpoor, Stephen J. Golden
  • Publication number: 20150139875
    Abstract: The invention relates to a method for preventing the contamination by platinum of an SCR catalyst in an exhaust-gas treatment system, said system comprising an oxidation catalyst containing platinum on the inflow side of the SCR catalyst. The outflow side of the oxidation catalyst comprises a material zone which removes traces of platinum contained in the exhaust-gas stream.
    Type: Application
    Filed: June 10, 2013
    Publication date: May 21, 2015
    Applicant: Umicore AG & CO. KG
    Inventors: Frank-Walter Schuetze, Marcus Pfeifer, Michael Schiffer, Martin Symalla, Christoph Hengst
  • Publication number: 20150139874
    Abstract: The present invention is directed to a lean NOx trap diesel oxidation catalyst for the treatment of exhaust gas emissions, such as the oxidation of unburned hydrocarbons (HC), and carbon monoxide (CO) and the trapping and reduction of nitrogen oxides (NOx). Catalytic composites can comprise a catalytic material on a carrier, the catalytic material comprising a first NOx trap layer that comprises a NOx sorbent and one or more precious metal components located on the carrier and a second NOx trap layer containing hydrocarbon trapping functionality located over the first NOx trap layer that comprises a NOx sorbent, one or more precious metal components, and a zeolite, for example a beta zeolite, wherein the zeolite is substantially free of framework aluminum. Such zeolites are characterized by high crystallinity and/or by being substantially free of framework aluminum to minimize surface acidity.
    Type: Application
    Filed: April 6, 2012
    Publication date: May 21, 2015
    Inventors: Xiaolai Zheng, Chung-Zong Wan, Patrick Burk
  • Patent number: 9034286
    Abstract: An exhaust system for a compression ignition engine comprising an oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from the compression ignition engine, wherein the oxidation catalyst comprises: a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; an alkaline earth metal component; a support material comprising a modified alumina incorporating a heteroatom component; and a substrate, wherein the platinum group metal (PGM) component, the alkaline earth metal component and the support material are disposed on the substrate.
    Type: Grant
    Filed: November 21, 2013
    Date of Patent: May 19, 2015
    Assignee: Johnson Matthey Public Limited Company
    Inventors: David Bergeal, Andrew Francis Chiffey, John Benjamin Goodwin, Daniel Hatcher, Francois Moreau, Agnes Raj, Raj Rao Rajaram, Paul Richard Phillips, Cathal Prendergast
  • Patent number: 9034287
    Abstract: Described are catalyst compositions, catalytic articles, exhaust gas treatment systems and methods that utilize the catalytic articles. The catalyst composition comprises a washcoat including a zeolite, refractory metal oxide support particles, and a platinum group metal supported on the refractory metal oxide support particles. Greater than 90% of the refractory metal oxide particles supporting PGM have a particle size greater than 1 ?m and a d50 less than 40 microns.
    Type: Grant
    Filed: March 11, 2014
    Date of Patent: May 19, 2015
    Assignee: BASF CORPORATION
    Inventors: Olga Gerlach, Andreas Sundermann, Jeffrey B. Hoke
  • Publication number: 20150125369
    Abstract: The invention relates to a coated particle filter (3), in particular wall-flow filter, having a length (L). According to the invention, at least two zones (4, 5) which have different coatings are provided along the length (L). The invention also relates to a catalytic converter (2), wherein the catalytic converter (2) is formed with a coating which has a washcoat coating layer as a lower coating layer, onto which palladium is deposited. The invention finally relates to a device (1) for the purification of exhaust gases, in particular exhaust gases of diesel-engined motor vehicles, comprising a catalytic converter (2) and a coated particle filter (3) of length (L) positioned downstream of the catalytic converter (2), wherein the particle filter (3) and the catalytic converter (2) are designed in accordance with the invention.
    Type: Application
    Filed: April 26, 2013
    Publication date: May 7, 2015
    Inventor: Bernhard Kahlert
  • Publication number: 20150125370
    Abstract: The present invention describes a double-layer three-way catalyst on an inert catalyst support comprising a first layer in direct contact with the inert catalyst support, comprising active alumina, a cerium/zirconium mixed oxide and palladium and a second layer applied to the first layer and in direct contact with the exhaust gas to be purified, comprising active alumina and rhodium, characterized in that the second layer is free of cerium and cerium containing materials, the use of such catalyst for cleaning the exhaust gases of a motor vehicle equipped with a gasoline engine and an exhaust gas treatment system comprising such catalyst up stream of a gasoline particulate filter (GPF).
    Type: Application
    Filed: June 5, 2013
    Publication date: May 7, 2015
    Applicant: UMICORE AG & CO. KG
    Inventors: Raoul Klingmann, Joel Despres, Martin Roesch, Joerg-Michael Richter, Stephanie Spiess
  • Publication number: 20150125371
    Abstract: The present invention describes a three-way-catalyst system comprising a first three-way catalyst on an inert catalyst support which is a double-layer catalyst comprising a first layer on the inert catalyst support, comprising active alumina, a cerium/zirconium mixed oxide and palladium and a second layer applied to the first layer and in direct contact with the exhaust gas to be purified, comprising active alumina and rhodium and being free of cerium and cerium containing materials and a second three-way-catalyst located upstream of the first three-way catalyst.
    Type: Application
    Filed: June 5, 2013
    Publication date: May 7, 2015
    Applicant: UMICORE AG & CO. KG
    Inventors: Marcus Schmidt, Joel Despres, Martin Roesch, Raoul Klingmann, Joerg-Michael Richter
  • Patent number: 9005560
    Abstract: A method to produce a NOx trap composition, and its use in a NOx trap and in an exhaust system for internal combustion engines, is disclosed. The NOx trap composition is produced by heating an iron-containing zeolite in the presence of an inert gas and an organic compound to produce a reductively calcined iron/zeolite. A palladium compound is then added to the reductively calcined iron/zeolite, and the resulting Pd—Fe/zeolite is then calcined at 400 to 600° C. in the presence of an oxygen-containing gas to produce the NOx trap composition. The NOx trap composition shows low temperature NO capacity below 200° C., as well as an additional NO storage temperature window in the 200 to 250° C. range.
    Type: Grant
    Filed: February 18, 2014
    Date of Patent: April 14, 2015
    Assignee: Johnson Matthey Public Limited Company
    Inventor: Fiona-Mairead McKenna
  • Publication number: 20150098879
    Abstract: An apparatus comprising a compression ignition engine and an exhaust system therefor comprising at least one exhaust system component for treating exhaust gas and means for generating an exotherm for heating the at least one exhaust system component, which exotherm generating means consisting essentially of a catalyst and means for injecting hydrocarbon into exhaust gas for combustion on the catalyst, which catalyst consisting essentially of both a palladium (Pd) component and a platinum (Pt) component, and an optional support material, disposed on a substrate monolith.
    Type: Application
    Filed: December 15, 2014
    Publication date: April 9, 2015
    Inventors: Bernard Paul Gabriel Ghislain Marie OGER, Paul Richard PHILLIPS, Martyn Vincent TWIGG, Andrew Peter WALKER
  • Publication number: 20150093312
    Abstract: Disclosed are, inter alia, methods of forming coated substrates for use in catalytic converters, as well as washcoat compositions and methods suitable for using in preparation of the coated substrates, and the coated substrates formed thereby, which in some cases use iron-exchanged zeolite particles that provide enhanced performance such as lower light-off temperatures and lower pollutant levels in exhaust gases. The catalytic material is prepared by a plasma-based method, yielding catalytic material with a lower tendency to migrate on support at high temperatures, and thus less prone to catalyst aging after prolonged use. Also disclosed are catalytic converters using the coated substrates, which have favorable properties as compared to catalytic converters using catalysts deposited on substrates using solution chemistry.
    Type: Application
    Filed: July 24, 2014
    Publication date: April 2, 2015
    Inventors: Qinghua YIN, Xiwang QI, Maximilian A. BIBERGER, David LEAMON
  • Patent number: 8992869
    Abstract: A treatment device configured to receive a flow of exhaust from a power source is disclosed. The treatment device may have a first layer, a second layer, and a substrate layer. The first layer may include a selective catalytic reduction layer, and the second layer may be disposed downstream of the first layer and include an oxidation catalyst support. The substrate layer may be disposed adjacent to the second layer. Additionally, an additive may be disposed downstream of the first layer. The additive may be operative to substantially prohibit migration of a component of the second layer to the first layer upon treatment of the flow of exhaust by the oxidation catalyst support.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: March 31, 2015
    Assignee: Caterpillar Inc.
    Inventors: Joshua L Ratts, Ronald Graham Silver
  • Publication number: 20150086456
    Abstract: Described are compositions and catalytic articles comprising both a copper-promoted 8-ring small pore molecular sieve and an iron-promoted 8-ring small pore molecular sieve. The catalytic articles are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.
    Type: Application
    Filed: December 8, 2014
    Publication date: March 26, 2015
    Inventors: Jaya L. Mohanan, Patrick Burk, Michael Breen, Barbara Slawski, Makoto Nagata, Yasuyuki Banno, Eunseok Kim
  • Patent number: 8986635
    Abstract: Methods are disclosed for reducing or preventing a selective catalytic reduction (SCR) catalyst disposed on a first substrate monolith in an exhaust system of a lean-burn internal combustion engine from becoming poisoned with platinum group metal (PGM) which may volatilize from a catalyst composition comprising PGM disposed on at least one second substrate monolith upstream of the SCR catalyst. The methods comprise adsorbing volatilized PGM in at least one PGM trapping material, which is disposed on a third substrate monolith disposed between the first substrate monolith and the second substrate monolith.
    Type: Grant
    Filed: March 6, 2014
    Date of Patent: March 24, 2015
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Philip Gerald Blakeman, Sougato Chatterjee, Andrew Francis Chiffey, Jane Gast, Paul Richard Phillips, Raj Rao Rajaram, Andrew Peter Walker
  • Patent number: 8986637
    Abstract: An emission control catalyst composition comprising a supported bimetallic catalyst consisting of gold and a metal selected from the group consisting of platinum, rhodium, ruthenium, copper and nickel is disclosed. Also disclosed is a catalytic convertor comprising a substrate monolith coated with the emission control catalyst composition and a lean burn internal combustion engine exhaust gas emission treatment system comprising the catalytic convertor. A variety of processes for preparing the catalyst composition are claimed.
    Type: Grant
    Filed: November 6, 2013
    Date of Patent: March 24, 2015
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Janet Mary Fisher, David Thompsett
  • Patent number: 8980209
    Abstract: Described are catalyst compositions, catalytic articles, methods of manufacturing catalytic articles and exhaust gas treatment systems and methods that utilize the catalytic articles. The catalyst composition comprises an oxidation catalyst comprising a washcoat layer including a platinum group metal supported on a refractory metal oxide support and porous molecular sieve particles having internal pores, the molecular sieve particles protected by a protecting material selected from an organic wax encapsulating the molecular sieve particles, a polymer encapsulating the molecular sieve particles, an inorganic oxide deposited on the surface of the molecular sieve particles, or an organic compound filling the internal pores of the molecular sieve particles, wherein the protecting material prevents interaction of the molecular sieve particles with the platinum group metal.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: March 17, 2015
    Assignee: BASF Corporation
    Inventors: Jeffrey B. Hoke, Oleg Ilinich, Michael Breen
  • Publication number: 20150071839
    Abstract: A motor vehicle emission control system includes a three zone catalytic converter component having a honeycomb support body with catalytically active coating having a precious metal content applied on the channel walls. The first coating zone extends in the longitudinal direction from the inlet-side end to a first coating boundary and has a first precious metal content. The second coating zone extends in the longitudinal direction from the first coating boundary to a second coating boundary situated downstream from the first coating boundary and has a second precious metal content that is lower than the first precious metal content. The third coating zone extends from the second coating boundary to the outlet-side end and has a third precious metal content that is lower than the second precious metal content. The coating has oxidation catalyst activity and is free of rhodium.
    Type: Application
    Filed: January 29, 2013
    Publication date: March 12, 2015
    Inventors: Alexander Massner, Inderpal Singh, Frank Zimmermann
  • Publication number: 20150071851
    Abstract: Described is a selective catalytic reduction catalyst comprising an iron-promoted 8-ring small pore molecular sieve. Systems and methods for using these iron-promoted 8-ring small molecular sieves as catalysts in a variety of processes such as abating pollutants in exhaust gases and conversion processes are also described.
    Type: Application
    Filed: November 10, 2014
    Publication date: March 12, 2015
    Inventors: Jaya L. Mohanan, Patrick Burk, Michael Breen, Barbara Slawski, Makoto Nagata, Yasuyuki Banno, Eunseok Kim
  • Publication number: 20150064085
    Abstract: A CO slip catalyst, for treating an exhaust gas from a lean burn internal combustion engine, is disclosed. The CO slip catalyst comprises palladium and a ceria-containing material. The invention also includes a method for oxidizing excess CO in an exhaust gas, wherein the excess CO results from the periodic contact of an upstream catalyst under rich exhaust conditions. The method comprises contacting the excess CO in the exhaust gas with a CO slip catalyst at a temperature in the range of 100 to 700° C.
    Type: Application
    Filed: August 28, 2014
    Publication date: March 5, 2015
    Inventors: ERICH CONLAN WEIGERT, SHADAB SHARIF MULLA, TODD HOWARD BALLINGER, JEFFERY SCOTT RIECK, JULIAN PETER COX, HAI-YING CHEN
  • Patent number: 8968690
    Abstract: Disclosed herein is a layered three-way catalytic system being separated in a front and a rear portion having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides. Provided is a catalyst composite comprising a single front catalytic layer and two rear catalytic layers in conjunction with a substrate, where the single font layer and the rear bottom layer comprise a Pd component, the rear top layer comprises a Rh component, and the rear bottom layer is substantially free of an oxygen storage component (OSC).
    Type: Grant
    Filed: November 21, 2011
    Date of Patent: March 3, 2015
    Assignee: Umicore AG & Co. KG
    Inventors: John G. Nunan, Raoul Klingmann, Ryan J. Andersen, Davion Onuga Clark, David Henry Moser
  • Patent number: 8951931
    Abstract: The noble metal fine particle supported catalyst of the present invention includes a substrate, and a porous membrane formed on the substrate. The porous membrane contains support particles, noble metal fine particles, and an inorganic binder. In the porous membrane, the noble metal fine particles are supported on surfaces of the support particles, and the support particles form secondary particles each having a porous structure. The porous membrane is formed by binding, with the inorganic binder, the secondary particles formed of the support particles so that a gap is present at least partly between the secondary particles adjacent to each other.
    Type: Grant
    Filed: February 28, 2011
    Date of Patent: February 10, 2015
    Assignee: Nippon Sheet Glass Company, Limited
    Inventors: Ryohei Ogawa, Kiyoshi Miyashita
  • Patent number: 8940259
    Abstract: A catalyzed soot filter for a diesel engine comprises a wall flow substrate having a substrate axial length, wherein surfaces of both the internal walls of a plurality of inlet and a plurality of outlet channels comprise a catalytic washcoat of at least one on-wall coating composition for oxidizing NO in exhaust gas to NO2, wherein the washcoat on the inlet channels extends for an axial inlet coating length from an open inlet end to a downstream inlet coating end, the washcoat on the outlet channels extends for an axial outlet coating length from an upstream outlet end to an open outlet end, the axial inlet coating length and the axial outlet coating length are both less than the substrate axial length and the outlet coating length is greater than the inlet coating length.
    Type: Grant
    Filed: October 31, 2013
    Date of Patent: January 27, 2015
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Gavin Michael Brown, Andrew Francis Chiffey, David Marvell
  • Patent number: 8940260
    Abstract: An exhaust after-treatment system is described. Generally speaking, the system includes separate primary and secondary NOx reducing systems for delivering reductant (e.g. urea and ammonia) to an exhaust stream, a sensor system for determining relevant operating conditions and an electronic control module for activating the reducing systems. The two NOx reducing systems include flow control modules coupled to the electronic control module. Methods for reducing NOx in an exhaust stream are also described. Generally speaking, the methods include the steps of determining a need for NOx reduction in an exhaust stream, determining temperature of exhaust stream, and injecting at least one of a primary reductant and a secondary reductant into the exhaust stream based on the determined temperature of the exhaust stream. Typically, the primary reductant comprises urea and the secondary reductant comprises ammonia.
    Type: Grant
    Filed: April 18, 2012
    Date of Patent: January 27, 2015
    Assignee: International Engine Intellectual Property Company, LLC.
    Inventors: Edward M. Derybowski, Brad J. Adelman, Shyam Santhanam
  • Patent number: 8932546
    Abstract: A catalytically active particulate filter is proposed which is suitable for use in an exhaust gas cleaning system for diesel engines. The particulate filter removes diesel soot particles from the exhaust gas and is also effective to oxidize carbon monoxide and hydrocarbons and to convert nitrogen monoxide at least proportionally into nitrogen dioxide. The particulate filter comprises a filter body (3) and two catalytically active coatings (1) and (2) which contain platinum and palladium, or platinum or palladium respectively, wherein the platinum content of the second catalytically active coating (2) is higher than the platinum content of the first catalytically active coating (1).
    Type: Grant
    Filed: January 29, 2013
    Date of Patent: January 13, 2015
    Assignee: Umicore AG & Co. KG
    Inventors: Stephanie Frantz, Ulrich Goebel, Franz Dornhaus, Michael Schiffer